CN102485872A - Super-condensed laundry detergent - Google Patents
Super-condensed laundry detergent Download PDFInfo
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- CN102485872A CN102485872A CN2010105758775A CN201010575877A CN102485872A CN 102485872 A CN102485872 A CN 102485872A CN 2010105758775 A CN2010105758775 A CN 2010105758775A CN 201010575877 A CN201010575877 A CN 201010575877A CN 102485872 A CN102485872 A CN 102485872A
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Abstract
The invention relates to a super-condensed laundry detergent. The super-condensed laundry detergent is prepared by using a neutral formula, thus the super-condensed laundry detergent has no damage to skin or fabrics, has strong detersive power and can remove a plurality of stains, contains no phosphor and no sodium alkyl benzene sulfonate and can protect the environment and human health, can be used for low temperature washing, has excellent resistance to hard water, is easy to wash and rinse, and can save energy and water. The super-condensed laundry detergent comprises the following ingredients: 30-50 weight parts of fatty alcohol polyoxyethylene ether, 10-25 weight parts of aliphatic acid methyl acetic sulfonate, 5-25 weight parts of solvent, 0.1-2.0 weight parts of enzyme preparation, 2-10 weight parts of solubiliser, 0.1 weight parts of Kathon antiseptic, 1.0-5.0 weight parts of triethanolamine, a few amount of citric acid and essence, and 1-17 weight parts of water.
Description
Technical field:
The present invention relates to a kind of liquid washing agent that will be used for the daily cleanings of clothing lining such as cotton, fiber crops, nylon, terylene, especially relate to a kind of ultra concentrated laundry detergent.
Background technology:
General family fabric detergent commonly used mainly is seen as solid from form; Be divided into soap and washing powder, yet all there are some shortcomings in these two kinds of products, soap in various degree: main cleansing is a sodium soap; And the general hardness ratio of family expenses bath water is higher; Can cause like this generating the extremely low calcium of solubleness, magnesium soap salt, have higher Kraft point, cause the loss of normal temperature washing function; Stick to and can make the textile fiber oxidation on the textiles, become sour, embrittlement, shorten textiles work-ing life.In addition, with regard to its soap finished product itself also can generation of cracks, flavescence and generation peculiar smell.Washing powder: main ingredient is a sodium alkyl benzene sulfonate; Solubility property is bad at normal temperatures; Influence the performance of its detersive power under coldcondition, and be that high tower dusts in process of production, energy consumption is higher; Add and wherein contain a large amount of fillers one sodium sulfate and auxiliary agent tripoly phosphate sodium STPP, be unfavorable for environmental protection.
And common liquid washing agent; Although solved the shortcoming that soap and washing powder exist; And have the accessibility of producing and using, but all have certain defective in various degree, mostly adopt the tensio-active agent of non-renewable coal or petroleum derivation to prepare; Compounded technology is not high, causes detersive power undesirable; Be dirt-removing functions single (not enzyme-containing formulation), can not cater to the multi-functional requirement that the human consumer is gone up day by day;
The gross activity thing content low (being lower than 15%) of prescription, cost performance is undesirable.Therefore people's expectation develop a kind of can compliance with environmental protection requirements; The full-service fluid washing composition that better cost performance is arranged again simultaneously; Make product existing good social responsibility in exploitation; Simultaneously not only economical but also material benefit and Sustainable development property, but such liquid washing agent public reported with excellent scourability is not arranged up to now as yet.
Summary of the invention:
The object of the present invention is to provide a kind of ultra concentrated laundry detergent, it is neutral prescription, does not hinder skin, does not damage clothing; Strong detergency can be removed multiple spot; Without phosphorus, no sodium alkyl benzene sulfonate, protection environment and HUMAN HEALTH; Can be used for cold washing, and have good anti-performance of hard water, be prone to wash, be prone to float, energy-conservation water-saving.
For realizing above-mentioned purpose, the technical scheme that the present invention adopts is:
A kind of ultra concentrated laundry detergent is characterized in that comprising the raw material of following weight part: AEO 30--50, the cruel sodium sulfonate 10---25 of fatty acid methyl, solvent 5-25, zymin 0.1-2.0, solubilizing agent 2-10, triumphant loose sanitas 0.1, trolamine 1.0-5.0, Hydrocerol A and essence a little and water 1-17.
Above-mentioned AEO is the ethoxylate of straight or branched Fatty Alcohol(C12-C14 and C12-C18), and the average adduct number of E0 is 6-10.
Above-mentioned fatty acid methyl vinegar sodium sulfonate is that palm fibre is put oily deutero-and chats about-1, the cruel sodium salt of a one sulfo-fatty acid first.Above-mentioned solvent is ethanol, terepthaloyl moietie or Ucar 35, or the mixture of ethanol, terepthaloyl moietie and Ucar 35.Above-mentioned solubilizing agent is that alkyl adjoins pyrrolidone.
Above-mentioned zymin is lypase or proteolytic enzyme.
Above-mentioned water is deionized water or softening water.
A kind of making method of ultra concentrated laundry detergent is characterized in that may further comprise the steps:
(1) gets the raw materials ready by above-mentioned each constituent mass proportioning;
(2) in batch tank, add solvent, and heat, temperature is controlled to 50-60 ℃, adds AEO then, is stirred to dissolving fully;
(3) under condition of stirring, add the cruel sodium sulfonate of fatty acid methyl, fully until dissolving; (4) stop heating, add trolamine and solubilizing agent, stirred 5--10 minute;
(5) continuing under the condition of stirring, add entry, triumphant loose sanitas and essence a little; (6) under the stirring at low speed condition, add zymin, stirred 10--skilful minute;
(7) work in-process carry out the ageing processing;
(8) sampling Detection, finished product packing.
Compared with prior art, the advantage and the effect that have of the present invention is following:
1, the present invention is a kind of MES ultra concentrated clothes liquid detergent that contains; Not only derive with natural reproducible resource and MES that Environmental compatibility is good as the major surfaces promoting agent, and be mixed with the gross activity object height in five times of super concentrated liquid washing composition of 60%, and be added with zymin through special operating procedure; And employing enzyme stabilization technique; Improve the scourability and the cost performance of liquid washing agent, product has an ideal shelf-life simultaneously, in addition comprehensively; Without phosphorus, no TX10, no white dyes, the more environmental protection of filling a prescription.2, washing composition of the present invention is low viscous emulsion liquid, and is without phosphorus in the prescription, and no white dyes meets household detergent environmental labelling product technical requirements (HJ 458-2009); It is simple to have technology, and preparation is convenient, is easy to produce in batches; Shelf-life is long, and characteristics such as product price ratio ideal can be widely used in the normal temperature washing of various clothings; Hand washing and machine washing are all suitable, and hand-wash and do not hinder hand, have the advantages of good skin consistency.
Embodiment:
The present invention is through adopting palm fibre to put oil or Oleum Cocois derived fatty acid first vinegar sodium sulfonate as main AS; Carry out compatibility with nonionogenic tenside and solubilizing agent; And through adding zymin and other auxiliary agent, the production that has come quintuple super concentrated liquid washing composition through scientific and reasonable blending process.Prescription:
The raw material that comprises following weight part: AEO 30--50, fatty acid methyl vinegar sodium sulfonate 10-25, solvent 5-25, zymin 0.1-2.0, solubilizing agent 2-10, triumphant loose sanitas 0.1, trolamine 1.0-5.0, Hydrocerol A and essence a little and water 1-17.Wherein AEO is the ethoxylate of straight or branched Fatty Alcohol(C12-C14 and C12-C18), and the average adduct number of E0 is 7-10.The cruel sodium sulfonate of fatty acid methyl is that palm fibre is put oily deutero-C16-1, a one sulfo-fatty acid first vinegar sodium salt.Solvent is ethanol, terepthaloyl moietie or Ucar 35, or the mixture of ethanol, terepthaloyl moietie and Ucar 35.Solubilizing agent is that alkyl adjoins pyrrolidone.Zymin is lypase or proteolytic enzyme.Water is deionized water or softening water.
Making method:
(1) gets the raw materials ready by above-mentioned each constituent mass proportioning;
(2) in batch tank, add solvent, and heat, temperature is controlled to 50-60 ℃, adds AEO then, is stirred to dissolving fully;
(3) under condition of stirring, add the cruel sodium sulfonate of fatty acid methyl, fully until dissolving;
(4) stop heating, add trolamine and solubilizing agent, stirred 5-10 minute;
(5) continuing under the condition of stirring, add entry, triumphant loose sanitas and essence a little;
(6) under the stirring at low speed condition, add zymin, stirred 10--15 minute;
(7) work in-process carry out the ageing processing;
(8) sampling Detection, finished product packing.
Embodiment 1:
Get 16.5 kilograms in 30 kilograms of AEOs, 25 kilograms of the cruel sodium sulfonates of fatty acid methyl, 25 kilograms of ethanol, proteinase-10 .1 kilogram, 2 kilograms of solubilizing agent, 0.1 kilogram of triumphant loose sanitas, 1 kilogram of trolamine, Hydrocerol A and essence a little (conventional amount used) and water, raw material is made into the washing composition finished product by above-mentioned preparation method.
Embodiment 2:
Get 13 kilograms in 40 kilograms of AEOs, 20 kilograms of fatty acid methyl vinegar sodium sulfonates, 20 kilograms of ethanol, 1 kilogram in proteolytic enzyme, 4 kilograms of solubilizing agent, 0.1 kilogram of triumphant loose sanitas, 1.5 kilograms of trolamines, Hydrocerol A and essence a little (conventional amount used) and water, raw material is made into the washing composition finished product by above-mentioned preparation method.
Embodiment 3:
Get 7 kilograms in 50 kilograms of AEOs, 10 kilograms of fatty acid methyl vinegar sodium sulfonates, 5 kilograms of ethanol, 2 kilograms in proteolytic enzyme, 10 kilograms of solubilizing agent, 0.1 kilogram of triumphant loose sanitas, 5.0 kilograms of trolamines, Hydrocerol A and essence a little (conventional amount used) and water, raw material is made into the washing composition finished product by above-mentioned preparation method.
Fatty acid methyl vinegar sodium sulfonate is to be the tensio-active agent that raw material is processed with the natural fats and oils among the present invention, has good scourability and very strong dispersion of calcium soap, readily biodegradable.For well, anti-performance of hard water is best with cocoyl to detersive power, in middle high hardness water with the brown tung oil base; MES demonstrates powerful washing decontamination advantage; Be superior to LAS, AOS under the equal dosage, approaching with AES, the MES formulation product is lower than LAS to the pungency of 8 skins in addition.Shortcoming be the Kraft point of MES higher with meet the alkali facile hydrolysis, and along with its Kraft point of growth of carbochain can be higher, the low-temperature stability that causes filling a prescription is undesirable, is unfavorable for the marketization of end product.The present invention carries out compatibility through employing and nonionogenic tenside and solubilizing agent, has solved the high low temperature stability problem as main AS liquid washing agent with MES effectively.AEO: have clearing power preferably, good to the detersive power of oily dirt, synthon are prevented the ability of recontaminate is strong.The electrolytical ability of stability in hard water and resisting high-concentration is all more intense.T 46155 nonionogenic tenside biggest advantage is the adjustability of hydrophobic group and hydrophilic group part.Through selecting for use different E0 numbers to adapt to various kinds of substrates, reach best clearing power, have good cold washing property in addition.Shortcoming is to the too late AS of the place to go ability of solid-like dirt, and price is high.Through adopting straight or branched, carbon number is C12-C14 among the present invention, and E0 mean number is the Kraft point and the removal ability of raising washing composition to oily dirt that the nonionogenic tenside of 5-10 reduces MES, and also has the function of stabilized enzyme formulations.
Zymin: the zymin of adding in the washing composition usually has proteolytic enzyme, lypase and glycase; Although it has the ideal clean effect to extraordinary dirt,, all exist interaction between zymin and tensio-active agent, auxiliary agent, solubilizing agent, water and they because washing composition is especially in liquid washing agent; Can influence the vigor of enzyme even can cause enzyme deactivation; Therefore, not only at the raw material that carries out to select for use when the compatibility component is selected with enzyme compatibility, but also should adopt rational blending process; So that keep enzyme activity effectively.
Claims (8)
1. ultra concentrated laundry detergent is characterized in that comprising the raw material of following weight part: AEO 30-50, fatty acid methyl vinegar sodium sulfonate 10-25, solvent 5-25, zymin 0.1-2.0, solubilizing agent 2-10, triumphant loose sanitas 0.1, trolamine 1.0-5.0, Hydrocerol A and essence a little and water 1-17.
2. ultra concentrated laundry detergent according to claim 1 is characterized in that: AEO is the ethoxylate of straight or branched Fatty Alcohol(C12-C14 and C12-C18), and the average adduct number of E0 is 7-10.
3. ultra concentrated laundry detergent according to claim 1 and 2 is characterized in that: the cruel sodium sulfonate of fatty acid methyl is that palm fibre is put oily deutero-C
16-18The cruel sodium salt of a one sulfo-fatty acid first.
4. ultra concentrated laundry detergent according to claim 3 is characterized in that: solubilizing agent is ethanol, terepthaloyl moietie or Ucar 35, or the mixture of ethanol, terepthaloyl moietie and Ucar 35.
5. ultra concentrated laundry detergent according to claim 4 is characterized in that: the Kraft point depressant is that alkyl adjoins pyrrolidone.
6. ultra concentrated laundry detergent according to claim 5 is characterized in that: zymin is lypase or proteolytic enzyme.
7. ultra concentrated laundry detergent according to claim 6 is characterized in that: water is deionized water or softening water.
8. the making method of a ultra concentrated laundry detergent is characterized in that may further comprise the steps:
(1) gets the raw materials ready by above-mentioned each constituent mass proportioning;
(2) in batch tank, add solubilizing agent, and heat, temperature is controlled to 50-60 ℃, adds AEO then, is stirred to dissolving fully;
(3) under condition of stirring, add fatty acid methyl vinegar sodium sulfonate, fully until dissolving;
(4) stop heating, add trolamine and Kraft point depressant, stirred 5--10 minute;
(5) continuing under the condition of stirring, add entry, triumphant loose sanitas and essence a little;
(6) under the stirring at low speed condition, add zymin, stirred 10--15 minute;
(7) work in-process carry out the ageing processing; (8) sampling Detection, finished product packing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010105758775A CN102485872A (en) | 2010-12-06 | 2010-12-06 | Super-condensed laundry detergent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010105758775A CN102485872A (en) | 2010-12-06 | 2010-12-06 | Super-condensed laundry detergent |
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| CN102485872A true CN102485872A (en) | 2012-06-06 |
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| CN2010105758775A Pending CN102485872A (en) | 2010-12-06 | 2010-12-06 | Super-condensed laundry detergent |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104830561A (en) * | 2015-03-16 | 2015-08-12 | 周小燕 | Super-concentrated low-foam high-efficient laundry detergent |
| CN110724606A (en) * | 2019-11-05 | 2020-01-24 | 王海军 | Super-concentrated detergent and preparation method thereof |
| CN113930298A (en) * | 2021-11-04 | 2022-01-14 | 广东优凯科技有限公司 | Stable concentrated liquid detergent composition with high surfactant content and preparation method thereof |
-
2010
- 2010-12-06 CN CN2010105758775A patent/CN102485872A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104830561A (en) * | 2015-03-16 | 2015-08-12 | 周小燕 | Super-concentrated low-foam high-efficient laundry detergent |
| CN110724606A (en) * | 2019-11-05 | 2020-01-24 | 王海军 | Super-concentrated detergent and preparation method thereof |
| CN113930298A (en) * | 2021-11-04 | 2022-01-14 | 广东优凯科技有限公司 | Stable concentrated liquid detergent composition with high surfactant content and preparation method thereof |
| CN113930298B (en) * | 2021-11-04 | 2024-02-20 | 广东优凯科技有限公司 | Concentrated liquid detergent composition with high surfactant content and stability and preparation method thereof |
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Application publication date: 20120606 |