CN104818167A - Anhydrous laundry detergent and preparation method thereof - Google Patents
Anhydrous laundry detergent and preparation method thereof Download PDFInfo
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- CN104818167A CN104818167A CN201510204372.0A CN201510204372A CN104818167A CN 104818167 A CN104818167 A CN 104818167A CN 201510204372 A CN201510204372 A CN 201510204372A CN 104818167 A CN104818167 A CN 104818167A
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Abstract
The invention discloses anhydrous laundry detergent and a preparation method thereof. The anhydrous laundry detergent comprises 8 to 12% of ethoxylated lauryl alcohol sulfate, 16 to 24% of non-ionic surfactant, 2 to 6% of potassium aliphatate soap, 0.1 to 0.5% of enzyme, 0.1 to 0.3% of sodium citrate, 0.1 to 0.5% of essence, 0.02 to 0.12% of preservative, 0.03 to 0.14% of pigment and 57 to 73% of solvent. The anhydrous laundry detergent is mild and free of stimulation, the consumption is less, the efficiency is high and the cleaning capability is high, the production cost is low, and the popularization and the application can be achieved.
Description
Technical field
The invention belongs to daily-use chemical industry technical field, be specifically related to a kind of anhydrous washing liquid and preparation method thereof.
Background technology
In the product of clothes washing, washing powder accounts for main status always, but washing powder in use can not dissolve completely, and residue easily causes clothing to damage, and not easily rinsing; And washing powder is generally alkaline, large to skin irritation, therefore in recent years, the technology content of washing liquid is higher, is convenient to add various effective constituent, clothing can be made after washing fluffy, soft, smooth glossy, and have effect of degerming and lasting lasting, gentleness does not hinder hand, soil removability is strong, biodegradable, uses the advantages such as comprehensive cost is low simultaneously, be subject to the favor of human consumer, share of market sustainable growth.
Washing liquid, main component is nonionic surface active agent, and its structure comprises water-wet side and hydrophobic end, and wherein hydrophobic end is combined with spot, then by physical motion (as hand rubbing, machine movement), spot is separated with fabric.Tensio-active agent reduces the tension force of water simultaneously, enables water reach fabric face, effective constituent is played a role.
At present, laundry liquid product on the market increases just rapidly, the water content of general washing liquid is 80 ~ 90%, and in order to pursue higher clean power, many businessmans are proposed Superconcentrated washing liquid, double concentrated washing liquid etc., the innovation of Geng You businessman is proposed the solidifying pearl of laundry, the solidifying pearl of green wave laundry is the combination of low water formula and water-solubility membrane, is machine washing design, can quantitatively uses, it also has 2 times of clean power, and its consumption is only the half of ordinary liquid laundry detergent.So the enrichment of washing liquid, quantification are the Main way of future development.But the selection and comparison of current anhydrous washing liquid is single.
Chinese patent application CN 104312754 A discloses a kind of anhydrous washing liquid and preparation method thereof, and it comprises α olefin sulfonate, nonionogenic tenside (fatty alcohol-polyoxyethylene ether or Fatty acid methyl ester ethoxylate), liquid complex enzyme (one or more the combination in liquid protease, lipase or cellulase) and auxiliary agent.It is powdered anhydrous washing liquid, strong detergency, detersive power is about 4 times of standard washing liquid detersive power, but the preparation process of this anhydrous washing liquid needs heating, raw material add needs with spraying form, also need ageing 4 ~ 5h after stirring, therefore the making of this anhydrous washing liquid consuming time, power consumption, production cost is high, is unfavorable for applying.
In sum, research and develop a kind of low cost, few consumption and the anhydrous washing liquid with high effect cleaning power seem with the selection enriching human consumer and be even more important.
Summary of the invention
The object of the present invention is to provide a kind of anhydrous washing liquid, its cost is low, consumption is few and have high effect cleaning power.
The present invention is by the following technical programs to realize above-mentioned purpose, a kind of anhydrous washing liquid, comprises the component of following weight percent meter: polyoxyethylenated alcohol sodium sulfate 8 ~ 12%, nonionogenic tenside 16 ~ 24%, fatty acid potassium soap 2 ~ 6%, enzyme 0.1 ~ 0.5%, Trisodium Citrate 0.1 ~ 0.3%, essence 0.1 ~ 0.5%, sanitas 0.02 ~ 0.12%, pigment 0.03 ~ 0.14%, solvent 57 ~ 73%.
As the preferred embodiment of the present invention, described anhydrous washing liquid is made up of the component of following weight percent meter: polyoxyethylenated alcohol sodium sulfate 10%, nonionogenic tenside 20%, fatty acid potassium soap 3%, enzyme 0.2%, Trisodium Citrate 0.1%, essence 0.1%, sanitas 0.08%, pigment 0.07%, solvent 66.45%.
Further, described nonionogenic tenside is one in fatty acid methyl ester ethoxylate, aliphatic alcohol polyethenoxy (9) ether and aliphatic alcohol polyethenoxy (7) ether or its combination.
Further, described nonionogenic tenside is the composition of fatty acid methyl ester ethoxylate and aliphatic alcohol polyethenoxy (9) ether, and the weight ratio of described fatty acid methyl ester ethoxylate and aliphatic alcohol polyethenoxy (9) ether is 1 ~ 5: 1.
Further, the weight ratio of described fatty acid methyl ester ethoxylate and aliphatic alcohol polyethenoxy (9) ether is 3: 1.
Further, described enzyme is proteolytic enzyme and diastatic composition, and described proteolytic enzyme and diastatic weight ratio are 2:1.
Further, described solvent is one in glycerine, ethanol and Virahol or its combination.
Further, described solvent is the composition of ethanol and glycerine, and the weight ratio of described ethanol and glycerine is 1: 20 ~ 25.
Present invention also offers the preparation method of described anhydrous washing liquid, comprise the following steps: in solvent, add nonionogenic tenside, stir, add fatty acid potassium soap, polyoxyethylenated alcohol sodium sulfate again, stir, finally add Trisodium Citrate, enzyme, sanitas, essence, pigment stir.
The anhydrous washing liquid of the present invention is highly concentrated liquid washing composition, using the composition of fatty acid methyl ester ethoxylate and aliphatic alcohol polyethenoxy (9) ether, polyoxyethylenated alcohol sodium sulfate as primary surfactant, coordinate proteolytic enzyme and diastatic composition again, can the spot fast and on fabric work, have albumen and starch spot and efficiently single-minded wash away effect, each component is worked in coordination with simultaneously, and stable system, can extend the quality guaranteed period of product.
Therefore, compared with prior art, advantage of the present invention is:
1, the anhydrous washing liquid of the present invention is according to the detersive power of half consumption in GB/T 13174-2008 " dress material washes the mensuration of agent detersive power and anti-stain deposition capability again by liquid " detersive power measuring method all higher than standard washing liquid detersive power, reaches the effect of high-effective cleansing.
2, the anhydrous washing liquid of the present invention is not moisture, and each component is worked in coordination with, and has stabilization to the activity of enzyme, thus can extend the quality guaranteed period of product.
3, the anhydrous washing liquid of the present invention can be packaged in water-solubility membrane due to water-free characteristic, is made into the washing liquid capsule particle of meeting instant, the quantitative sizing packaging of water, starts and quantitatively use washing composition, conveniently laundry mode.
4, the process for preparation of the anhydrous washing liquid of the present invention carries out stirring at normal temperature, without the need to heating, without the need to powerful equipment, belongs to energy-saving production, greatly reduces production cost.
Embodiment
Further describe the present invention below by way of embodiment, but the present invention is not limited only to following examples.Within the scope of the invention or not departing from content of the present invention, spirit and scope, anhydrous washing liquid of the present invention and preparation method thereof is suitably improved, replaces the identical component of effect, will become apparent to those skilled in the art that they are all deemed to be included within scope of the present invention.
embodiment 1, the anhydrous washing liquid of the present invention and preparation thereof
Formula: the weight ratio of polyoxyethylenated alcohol sodium sulfate 100g, nonionogenic tenside 200g(fatty acid methyl ester ethoxylate and aliphatic alcohol polyethenoxy (9) ether is 3: 1), fatty acid potassium soap 30g, enzyme 2g(proteolytic enzyme and diastatic weight ratio be 2:1), the weight ratio of Trisodium Citrate 1g, essence 1g, sanitas 0.8g, pigment 0.7g, solvent 664.5g(ethanol and glycerine is 1: 23).
Preparation: add nonionogenic tenside in solvent, stir, then add fatty acid potassium soap, polyoxyethylenated alcohol sodium sulfate, stir, finally adds Trisodium Citrate, enzyme, sanitas, essence, pigment stirs.
embodiment 2, the anhydrous washing liquid of the present invention and preparation thereof
Formula: the weight ratio of polyoxyethylenated alcohol sodium sulfate 80g, nonionogenic tenside 240g(fatty acid methyl ester ethoxylate and aliphatic alcohol polyethenoxy (9) ether is 5: 1), fatty acid potassium soap 20g, enzyme 5g(proteolytic enzyme and diastatic weight ratio be 2:1), the weight ratio of Trisodium Citrate 1g, essence 1g, sanitas 0.2g, pigment 1.4g, solvent 651.4g(ethanol and glycerine is 1: 20).
Preparation: add nonionogenic tenside in solvent, stir, then add fatty acid potassium soap, polyoxyethylenated alcohol sodium sulfate, stir, finally adds Trisodium Citrate, enzyme, sanitas, essence, pigment stirs.
embodiment 3, the anhydrous washing liquid of the present invention and preparation thereof
Formula: the weight ratio of polyoxyethylenated alcohol sodium sulfate 120g, nonionogenic tenside 160g(fatty acid methyl ester ethoxylate and aliphatic alcohol polyethenoxy (9) ether is 1: 1), fatty acid potassium soap 60g, enzyme 1g(proteolytic enzyme and diastatic weight ratio be 2:1), the weight ratio of Trisodium Citrate 3g, essence 5g, sanitas 1.2g, pigment 0.3g, solvent 649.5g(ethanol and glycerine is 1: 25).
Preparation: add nonionogenic tenside in solvent, stir, then add fatty acid potassium soap, polyoxyethylenated alcohol sodium sulfate, stir, finally adds Trisodium Citrate, enzyme, sanitas, essence, pigment stirs.
comparative example 1,
Choose the embodiment 2 in CN 104312754 A specification sheets.
the detersive power of test example one, the anhydrous washing liquid of the present invention detects
According to GB/T 13174-2008 " dress material washes the mensuration of agent detersive power and the anti-stain deposition capability again by liquid " detersive power to the washing liquid of embodiment 1 ~ 3, comparative example 1, and the detersive power placed after 2 months detects at 37 DEG C, wherein the consumption of embodiment 1 ~ 3, comparative example 1 washing liquid is the half of standard washing liquid consumption.Detected result is as following table 1.
The detected result of each washing liquid detersive power of table 1
From upper table 1, the detersive power of each washing liquid is detected after having prepared, the detersive power of the anhydrous washing liquid of the embodiment of the present invention 1 ~ 3 is all better than comparative example 1, especially the strongest with the detersive power of embodiment 1, its consumption is a half of standard washing liquid consumption, and detersive power is 4.5 times of standard washing liquid detersive power.Simultaneously, place at 37 DEG C after 2 months, the detersive power of comparative example 1 declines obviously, and the detersive power of the embodiment of the present invention 1 ~ 3 only slightly declines, especially minimum with the fall of embodiment 1 detersive power, illustrate that each component of the anhydrous washing liquid of the present invention is worked in coordination with, stable system, can extend the quality guaranteed period of product.
The washing liquid of the present invention and comparative example 2 all belongs to anhydrous washing liquid, but the anhydrous washing liquid of the present invention is highly concentrated liquid washing composition, the latter is solid, and when clothes washing, this liquid scrubbing is more soluble and can the spot fast and on fabric work, and therefore detersive power of the present invention is stronger; In addition, solid preparation needs spraying dry and the ageing some time, and the anhydrous washing liquid normal temperature of the present invention can carry out also without the need to spraying dry and ageing, saves time, energy-conservation; The anhydrous washing liquid of the present invention can be issued to the effect of more high-effective cleansing in the situation of low cost.
Below be only the preferred embodiment of the present invention, it should be pointed out that above-mentioned preferred implementation should not be considered as limitation of the present invention, protection scope of the present invention should be as the criterion with claim limited range.For those skilled in the art, without departing from the spirit and scope of the present invention, can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (9)
1. an anhydrous washing liquid, it is characterized in that, comprise the component of following weight percent meter: polyoxyethylenated alcohol sodium sulfate 8 ~ 12%, nonionogenic tenside 16 ~ 24%, fatty acid potassium soap 2 ~ 6%, enzyme 0.1 ~ 0.5%, Trisodium Citrate 0.1 ~ 0.3%, essence 0.1 ~ 0.5%, sanitas 0.02 ~ 0.12%, pigment 0.03 ~ 0.14%, solvent 57 ~ 73%.
2. anhydrous washing liquid as claimed in claim 1, it is characterized in that, described anhydrous washing liquid is made up of the component of following weight percent meter: polyoxyethylenated alcohol sodium sulfate 10%, nonionogenic tenside 20%, fatty acid potassium soap 3%, enzyme 0.2%, Trisodium Citrate 0.1%, essence 0.1%, sanitas 0.08%, pigment 0.07%, solvent 66.45%.
3. anhydrous washing liquid as claimed in claim 1 or 2, is characterized in that, described nonionogenic tenside is one in fatty acid methyl ester ethoxylate, aliphatic alcohol polyethenoxy (9) ether and aliphatic alcohol polyethenoxy (7) ether or its combination.
4. anhydrous washing liquid as claimed in claim 3, it is characterized in that, described nonionogenic tenside is the composition of fatty acid methyl ester ethoxylate and aliphatic alcohol polyethenoxy (9) ether, and the weight ratio of described fatty acid methyl ester ethoxylate and aliphatic alcohol polyethenoxy (9) ether is 1 ~ 5: 1.
5. anhydrous washing liquid as claimed in claim 4, is characterized in that, the weight ratio of described fatty acid methyl ester ethoxylate and aliphatic alcohol polyethenoxy (9) ether is 3: 1.
6. anhydrous washing liquid as claimed in claim 1 or 2, is characterized in that, described enzyme is proteolytic enzyme and diastatic composition, and described proteolytic enzyme and diastatic weight ratio are 2:1.
7. anhydrous washing liquid as claimed in claim 1 or 2, is characterized in that, described solvent is one in glycerine, ethanol and Virahol or its combination.
8. anhydrous washing liquid as claimed in claim 7, is characterized in that, described solvent is the composition of ethanol and glycerine, and the weight ratio of described ethanol and glycerine is 1: 20 ~ 25.
9. one kind prepare as arbitrary in claim 1 ~ 8 as described in the method for anhydrous washing liquid, it is characterized in that, comprise the following steps: in solvent, add nonionogenic tenside, stir, add fatty acid potassium soap, polyoxyethylenated alcohol sodium sulfate again, stir, finally add Trisodium Citrate, enzyme, sanitas, essence, pigment stir.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201510204372.0A CN104818167B (en) | 2015-04-28 | 2015-04-28 | A kind of anhydrous liquid detergent and preparation method thereof |
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| CN201510204372.0A CN104818167B (en) | 2015-04-28 | 2015-04-28 | A kind of anhydrous liquid detergent and preparation method thereof |
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| CN104818167A true CN104818167A (en) | 2015-08-05 |
| CN104818167B CN104818167B (en) | 2016-07-06 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106753930A (en) * | 2016-12-05 | 2017-05-31 | 广西大学 | A kind of liquid detergent |
| CN110408487A (en) * | 2019-08-27 | 2019-11-05 | 如皋市涤诺皂业有限公司 | A kind of padded equipment liquid detergent and preparation method thereof with pearly-lustre |
| CN110467971A (en) * | 2019-08-30 | 2019-11-19 | 广州市拓瑞科技有限公司 | A kind of environmentally protective sterilizing waterless nano liquid detergent and preparation method thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111518626A (en) * | 2020-04-17 | 2020-08-11 | 周萍 | Waterless laundry solvent based on 5G mobile laundry station |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040063598A1 (en) * | 2000-08-17 | 2004-04-01 | Hans-Juergen Riebe | Mechanically stable, liquid formulation washing, rinsing or cleaning agent doses |
| CN104312754A (en) * | 2014-10-14 | 2015-01-28 | 南风化工集团股份有限公司 | Water-free laundry detergent and preparation method thereof |
-
2015
- 2015-04-28 CN CN201510204372.0A patent/CN104818167B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040063598A1 (en) * | 2000-08-17 | 2004-04-01 | Hans-Juergen Riebe | Mechanically stable, liquid formulation washing, rinsing or cleaning agent doses |
| CN104312754A (en) * | 2014-10-14 | 2015-01-28 | 南风化工集团股份有限公司 | Water-free laundry detergent and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 吴京淼: "《服装洗涤化料与应用》", 31 August 2009 * |
| 颜红侠等: "《日用化学品制造原理与技术》", 28 February 2011 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106753930A (en) * | 2016-12-05 | 2017-05-31 | 广西大学 | A kind of liquid detergent |
| CN110408487A (en) * | 2019-08-27 | 2019-11-05 | 如皋市涤诺皂业有限公司 | A kind of padded equipment liquid detergent and preparation method thereof with pearly-lustre |
| CN110467971A (en) * | 2019-08-30 | 2019-11-19 | 广州市拓瑞科技有限公司 | A kind of environmentally protective sterilizing waterless nano liquid detergent and preparation method thereof |
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| CN104818167B (en) | 2016-07-06 |
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