CN101798552B - Fabric detergent with colour-preserving function and preparation method thereof - Google Patents

Fabric detergent with colour-preserving function and preparation method thereof Download PDF

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Publication number
CN101798552B
CN101798552B CN 201010165619 CN201010165619A CN101798552B CN 101798552 B CN101798552 B CN 101798552B CN 201010165619 CN201010165619 CN 201010165619 CN 201010165619 A CN201010165619 A CN 201010165619A CN 101798552 B CN101798552 B CN 101798552B
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sodium
deionized water
ether
essence
glucoside
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CN101798552A (en
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吴韫珺
崔丽平
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BEIJING LUSAN CHEMICAL Co Ltd
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BEIJING LUSAN CHEMICAL Co Ltd
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Abstract

The invention provides a fabric detergent with colour-preserving function and preparation method thereof. The detergent contains sodium fatty alcohol ether sulphate, laurylamide propyl betaine, alkyl glucoside, fatty alcohol polyoxyethylene (9) ether, sodium alpha-olefin sulphonate, 3-methooxyl-3-methyl-1-butyl alcohol, 1-vinyl pyrrolidone, 1-vinyl copolymer, sodium chloride, 1, 2-benzisothiazolin-3-one, essence, citric acid monohydrate and deionized water. The invention obtain favourable detergency in clothing washing process while realizing colour-preserving effect; the detergent is environmentally friendly, cleaning and colour-preserving are completed in one step, the detergent is non-toxic and non-irritant, and resource is saved.

Description

A kind of fabric detergent with colour-preserving function and preparation method thereof
Technical field
The invention belongs to the detergent composition field, specifically have fabric detergent of colour-preserving function and preparation method thereof.
Background technology
In recent years, the human consumer uses gained popularity of the special washing liquid of functional type.The partly cause of these washing liquid increased popularity is: the human consumer wishes easily and quickly to give fabric various character in laundry processes.
Clothes will experience various tests: sweat stain, tan by the sun etc., change so must often often wash.Current, colored fabric still keeps large per-cent in the clothing of family and human consumer's washing, and these colour clothes show the undesirable trend of outward appearance and colour loss at a plurality of all after dates through laundry processes.These external losses are in a plurality of cycles through laundry processes, or only all after dates of minority may reveal.Therefore, the spendable life-span of colour clothes is owing to being lowered through washing process.
Therefore, need a kind of laundry detergent on the market; Use this washing composition by routine, can reduce or reduce because outward appearance and the colour loss that washing process produces, but also the clothing of having degenerated in the past washed, outward appearance and color provides obvious outward appearance to improve.
Summary of the invention
The purpose of this invention is to provide a kind of fabric detergent with colour-preserving function and preparation method thereof, contain polyoxyethylenated alcohol sodium sulfate, lauryl amido propyl betaine, alkyl-glucoside, aliphatic alcohol polyethenoxy (9) ether, α-sodium olefin sulfonate, MMB, 1-vinyl pyrrolidone in this washing composition, 1-ethylenic copolymer, sodium-chlor, BIT, essence, Citric acid monohydrate Food grade, deionized water; The present invention plays fixation when reaching good detersive power in the clothes washing process, protects the effect of look; Environmentally friendly, clean, protect look and once finish, and also nontoxic non-stimulated, economize on resources.
The objective of the invention is to be realized by following technical proposals:
A kind of preparation method with fabric detergent of colour-preserving function, contain polyoxyethylenated alcohol sodium sulfate, lauryl amido propyl betaine, alkyl-glucoside, aliphatic alcohol polyethenoxy (9) ether, α-sodium olefin sulfonate, MMB, 1-vinyl pyrrolidone in this washing composition, 1-ethylenic copolymer, sodium-chlor, BIT, essence, Citric acid monohydrate Food grade, deionized water; The weight ratio of each component is in this washing composition:
Polyoxyethylenated alcohol sodium sulfate 10.0~25.5
Lauryl amido propyl betaine 2.0~4.0
Alkyl-glucoside 4.5~8.0
Aliphatic alcohol polyethenoxy (9) ether 0.5~8.0
α-sodium olefin sulfonate 0.5~5.0
MMB 1.0~5.0
1-vinyl pyrrolidone, 1-ethylenic copolymer 0.05~1.0
Sodium-chlor 2.0~6.0
BIT 0.1
Essence 0.1~0.3
Citric acid monohydrate Food grade 0.05~0.2
Deionized water 30.0~85.0.
Detersive power of the present invention reaches national sector standard QB1224 requirement; The present invention is according to the examining report of national light industry makeup articles for washing quality examination Beijing Station, and submitted sample is according to Q/HDLSH 043-2008 " dress material washes agent by liquid " [washing liquid (III)] standard detection, the project conformance with standard requirement of examining.
The objective of the invention is to be realized by following another technical scheme:
A kind of preparation method with fabric detergent of colour-preserving function, contain polyoxyethylenated alcohol sodium sulfate, lauryl amido propyl betaine, alkyl-glucoside, aliphatic alcohol polyethenoxy (9) ether, α-sodium olefin sulfonate, MMB, 1-vinyl pyrrolidone in this washing composition, 1-ethylenic copolymer, sodium-chlor, BIT, essence, Citric acid monohydrate Food grade, deionized water; The weight ratio of each component is in this washing composition:
Polyoxyethylenated alcohol sodium sulfate 10.0~25.5
Lauryl amido propyl betaine 2.0~4.0
Alkyl-glucoside 4.5~8.0
Aliphatic alcohol polyethenoxy (9) ether 0.5~8.0
α-sodium olefin sulfonate 0.5~5.0
MMB 1.0~5.0
1-vinyl pyrrolidone, 1-ethylenic copolymer 0.05~1.0
Sodium-chlor 2.0~6.0
BIT 0.1
Essence 0.1~0.3
Citric acid monohydrate Food grade 0.05~0.2
Deionized water 30.0~85.0.
This preparation method's step is as follows successively:
A. with described deionized water wherein 70%~85% be heated to 60 ℃~80 ℃, then under agitation add described polyoxyethylenated alcohol sodium sulfate, lauryl amido propyl betaine, alkyl-glucoside, aliphatic alcohol polyethenoxy (9) ether, α-sodium olefin sulfonate, MMB, 1-vinyl pyrrolidone according to said ratio, 1-ethylenic copolymer obtains mixture A to fully dissolving;
Add described BIT, essence, sodium-chlor, residue deionized water, Citric acid monohydrate Food grade when B. described mixture A being cooled to 35 ℃~45 ℃ and stir, obtain mixture B;
C. described mixing solutions B was left standstill 100~120 minutes, namely get described fabric detergent with colour-preserving function, carry out again can and produce.
Compared with the prior art the present invention has following beneficial effect:
1, among the present invention, tensio-active agent and laking agent is compound, synergy, in clean textile, can be able to reduce or reduce outward appearance and the colour loss that produces owing to washing process, but also the clothing of having degenerated for former washed outward appearance and color provides obvious outward appearance to improve;
2, the present invention is take anion surfactant with good decontamination, emulsification and foaming power as main, with gentle, the low nonionogenic tenside that stimulates, have softness, amphoterics, penetration enhancer, laking agent antistatic and wettability are composite, synergy, when reaching good detersive power fixation, protect look.
3, detersive power of the present invention reaches national sector standard QB1224 requirement; The present invention is according to the examining report of national light industry makeup articles for washing quality examination Beijing Station, and submitted sample is according to Q/HDLSH 043-2008 " dress material washes agent by liquid " [washing liquid (III)] standard detection, the project conformance with standard requirement of examining.
4, good water solubility of the present invention, flexibility is good, and it is remarkable to protect chromatic effect, can protect fabric, reduce the washing cost;
5, the present invention is environmentally friendly, nontoxic non-stimulated, decontamination, protect look, softness is once finished, thereby economize on resources, raise the efficiency.
Embodiment
Embodiment 1:
A kind of fabric detergent with colour-preserving function, contain polyoxyethylenated alcohol sodium sulfate, lauryl amido propyl betaine, alkyl-glucoside, aliphatic alcohol polyethenoxy (9) ether, α-sodium olefin sulfonate, MMB, 1-vinyl pyrrolidone in this washing composition, 1-ethylenic copolymer, sodium-chlor, BIT, essence, Citric acid monohydrate Food grade, deionized water; The weight ratio of each component is in this washing composition:
Polyoxyethylenated alcohol sodium sulfate 10.0~25.5
Lauryl amido propyl betaine 2.0~4.0
Alkyl-glucoside 4.5~8.0
Aliphatic alcohol polyethenoxy (9) ether 0.5~8.0
α-sodium olefin sulfonate 0.5~5.0
MMB 1.0~5.0
1-vinyl pyrrolidone, 1-ethylenic copolymer 0.05~1.0
Sodium-chlor 2.0~6.0
BIT 0.1
Essence 0.1~0.3
Citric acid monohydrate Food grade 0.05~0.2
Deionized water 30.0~85.0.
The used weight unit of present embodiment is kilogram, also can be gram;
Each component described in the present embodiment for being technical grade;
Each component described in the present embodiment is the conventional products of selling on the market;
In the present embodiment, each component in the described fabric detergent with colour-preserving function can be in the ratio range that provides flexible combination, do not enumerate one by one at this.
Polyoxyethylenated alcohol sodium sulfate in the present embodiment, aliphatic alcohol polyethenoxy (9) ether, α-sodium olefin sulfonate, MMB be composite to have good wetting, foaming, dispersion, emulsifying capacity, the soil removability that the system of giving is good can effectively be removed the dirts such as greasy dirt that clothing is infected with, dish stain.
Lauryl amido propyl betaine, alkyl-glucoside can reduce the pungency of system in the present embodiment, and foam is fine and smooth, gentle, the texture of giving fabric sofetening, and can protect the color of fabric.
1-vinyl pyrrolidone in the present embodiment, 1-ethylenic copolymer are colour protecting agent, with the compound compatibility of other component, play fixation, color-protecting function when reaching good detersive power; This 1-vinyl pyrrolidone, the commodity of 1-ethylenic copolymer are called Sokalan HP 66 K, are produced by BASF AG; This 1-vinyl pyrrolidone, the English of 1-ethylenic copolymer is called 1-Vinyl-2-pyrrolidon, 1-Vinylimidazol-Copolymer.
The detersive power of present embodiment reaches national sector standard QB1224 requirement; Present embodiment is according to the examining report of national light industry makeup articles for washing quality examination Beijing Station, the submitted sample of present embodiment [trade(brand)name: washing liquid (dynamic in riotous profusion)] is according to Q/HDLSH 043-2008 " dress material washes agent by liquid " [washing liquid (III)] standard detection, the project conformance with standard requirement of examining.
Embodiment 2:
Present embodiment is the preferred version on embodiment 1 basis, and the quality of raw materials used (component) is identical with embodiment 1, and the weight ratio of each component is in the described washing composition:
Polyoxyethylenated alcohol sodium sulfate 24.0
Lauryl amido propyl betaine 2.0
Alkyl-glucoside 6.0
Aliphatic alcohol polyethenoxy (9) ether 0.5
α-sodium olefin sulfonate 0.5
MMB 0.5
1-vinyl pyrrolidone, 1-ethylenic copolymer 0.5
Sodium-chlor 2.5
BIT 0.1
Essence 0.3
Citric acid monohydrate Food grade 0.12
Deionized water 62.98.
The used weight unit of present embodiment is kilogram, also can be gram.
Embodiment 3:
Present embodiment is the preferred version on embodiment 1 basis, and the quality of raw materials used (component) is identical with embodiment 1, and the weight ratio of each component is in the described washing composition:
Polyoxyethylenated alcohol sodium sulfate 25.0
Lauryl amido propyl betaine 3.0
Alkyl-glucoside 4.5
Aliphatic alcohol polyethenoxy (9) ether 2.0
α-sodium olefin sulfonate 0.5
MMB 5.0
1-vinyl pyrrolidone, 1-ethylenic copolymer 0.5
Sodium-chlor 2.0
BIT 0.1
Essence 0.15
Citric acid monohydrate Food grade 0.2
Deionized water 57.05.
The used weight unit of present embodiment is kilogram, also can be gram.
Embodiment 4:
Present embodiment is the preferred version on embodiment 1 basis, and the quality of raw materials used (component) is identical with embodiment 1, and the weight ratio of each component is in the described washing composition:
Polyoxyethylenated alcohol sodium sulfate 25.5
Lauryl amido propyl betaine 4.0
Alkyl-glucoside 5.0
Aliphatic alcohol polyethenoxy (9) ether 0.5
α-sodium olefin sulfonate 0.5
MMB 3.0
1-vinyl pyrrolidone, 1-ethylenic copolymer 1.0
Sodium-chlor 2.4
BIT 0.1
Essence 0.2
Citric acid monohydrate Food grade 0.2
Deionized water 57.8.
The used weight unit of present embodiment is kilogram, also can be gram.
Embodiment 5:
Present embodiment is the preferred version on embodiment 1 basis, and the quality of raw materials used (component) is identical with embodiment 1, and the weight ratio of each component is in the described washing composition:
Polyoxyethylenated alcohol sodium sulfate 12.0
Lauryl amido propyl betaine 3.5
Alkyl-glucoside 6.0
Aliphatic alcohol polyethenoxy (9) ether 5.0
α-sodium olefin sulfonate 5.0
MMB 1.0
1-vinyl pyrrolidone, 1-ethylenic copolymer 1.0
Sodium-chlor 6.0
BIT 0.1
Essence 0.3
Citric acid monohydrate Food grade 0.1
Deionized water 60.0.
The used weight unit of present embodiment is kilogram, also can be gram.
Embodiment 6:
Present embodiment is the preferred version on embodiment 1 basis, and the quality of raw materials used (component) is identical with embodiment 1, and the weight ratio of each component is in the described washing composition:
Polyoxyethylenated alcohol sodium sulfate 10.0
Lauryl amido propyl betaine 2.0
Alkyl-glucoside 8.0
Aliphatic alcohol polyethenoxy (9) ether 8.0
α-sodium olefin sulfonate 4.0
MMB 1.0
1-vinyl pyrrolidone, 1-ethylenic copolymer 0.5
Sodium-chlor 5.5
BIT 0.1
Essence 0.1
Citric acid monohydrate Food grade 0.05
Deionized water 60.75.
The used weight unit of present embodiment is kilogram, also can be gram.
Embodiment 7:
Present embodiment is the preparation method of embodiment 1~6.
A kind of preparation method with fabric detergent of colour-preserving function, contain polyoxyethylenated alcohol sodium sulfate, lauryl amido propyl betaine, alkyl-glucoside, aliphatic alcohol polyethenoxy (9) ether, α-sodium olefin sulfonate, MMB, 1-vinyl pyrrolidone in this washing composition, 1-ethylenic copolymer, sodium-chlor, BIT, essence, Citric acid monohydrate Food grade, deionized water; The weight ratio of each component is in this washing composition:
Polyoxyethylenated alcohol sodium sulfate 10.0~25.5
Lauryl amido propyl betaine 2.0~4.0
Alkyl-glucoside 4.5~8.0
Aliphatic alcohol polyethenoxy (9) ether 0.5~8.0
α-sodium olefin sulfonate 0.5~5.0
MMB 1.0~5.0
1-vinyl pyrrolidone, 1-ethylenic copolymer 0.05~1.0
Sodium-chlor 2.0~6.0
BIT 0.1
Essence 0.1~0.3
Citric acid monohydrate Food grade 0.05~0.2
Deionized water 30.0~85.0.
This preparation method's step is as follows successively:
A. with described deionized water wherein 70%~85% be heated to 60 ℃~80 ℃, be preferably 70 ℃, then under agitation add described polyoxyethylenated alcohol sodium sulfate, lauryl amido propyl betaine, alkyl-glucoside, aliphatic alcohol polyethenoxy (9) ether, α-sodium olefin sulfonate, MMB, 1-vinyl pyrrolidone according to said ratio, 1-ethylenic copolymer obtains mixture A to fully dissolving; This mixed solution A is formulated in the material still, need to stir successively when adding described each component;
Add described BIT, essence, sodium-chlor, residue deionized water, Citric acid monohydrate Food grade when B. described mixture A being cooled to 35 ℃~45 ℃ and stir, obtain mixture B; When preparing this mixing solutions B, need to stir successively when adding described each component; The pH value of described solution B is 7.0~8.0;
C. described mixing solutions B was left standstill 100~120 minutes, be preferably 110 minutes, until described mixing solutions B temperature is lower than 35 ℃, namely get described fabric detergent with colour-preserving function; Carrying out can produces again.
In above-mentioned process for preparation, should note whole clean operation environment health, dustproof.
The equipment that adopts in the present embodiment is conventional equipment, all can buy in market to obtain.

Claims (7)

1. fabric detergent with colour-preserving function, it is characterized in that: in this washing composition by polyoxyethylenated alcohol sodium sulfate, lauryl amido propyl betaine, alkyl-glucoside, aliphatic alcohol polyethenoxy (9) ether, α-sodium olefin sulfonate, MMB, 1-vinyl pyrrolidone, 1-ethylenic copolymer, sodium-chlor, BIT, essence, Citric acid monohydrate Food grade, deionized water are prepared from; The weight ratio of each component is in this washing composition:
Polyoxyethylenated alcohol sodium sulfate 10.0~25.5
Lauryl amido propyl betaine 2.0~4.0
Alkyl-glucoside 4.5~8.0
Aliphatic alcohol polyethenoxy (9) ether 0.5~8.0
α-sodium olefin sulfonate 0.5~5.0
MMB 1.0~5.0
1-vinyl pyrrolidone, 1-ethylenic copolymer 0.05~1.0
Sodium-chlor 2.0~6.0
BIT 0.1
Essence 0.1~0.3
Citric acid monohydrate Food grade 0.05~0.2
Deionized water 30.0~85.0.
2. the fabric detergent with colour-preserving function according to claim 1, it is characterized in that: the weight ratio of each component is in this washing composition:
Polyoxyethylenated alcohol sodium sulfate 25.5
Lauryl amido propyl betaine 4.0
Alkyl-glucoside 5.0
Aliphatic alcohol polyethenoxy (9) ether 0.5
α-sodium olefin sulfonate 0.5
MMB 3.0
1-vinyl pyrrolidone, 1-ethylenic copolymer 1.0
Sodium-chlor 2.4
BIT 0.1
Essence 0.2
Citric acid monohydrate Food grade 0.2
Deionized water 57.8.
3. the fabric detergent with colour-preserving function according to claim 1, it is characterized in that: the weight ratio of each component is in this washing composition:
Polyoxyethylenated alcohol sodium sulfate 12.0
Lauryl amido propyl betaine 3.5
Alkyl-glucoside 6.0
Aliphatic alcohol polyethenoxy (9) ether 5.0
α-sodium olefin sulfonate 5.0
MMB 1.0
1-vinyl pyrrolidone, 1-ethylenic copolymer 1.0
Sodium-chlor 6.0
BIT 0.1
Essence 0.3
Citric acid monohydrate Food grade 0.1
Deionized water 60.0.
4. the fabric detergent with colour-preserving function according to claim 1, it is characterized in that: the weight ratio of each component is in this washing composition:
Polyoxyethylenated alcohol sodium sulfate 10.0
Lauryl amido propyl betaine 2.0
Alkyl-glucoside 8.0
Aliphatic alcohol polyethenoxy (9) ether 8.0
α-sodium olefin sulfonate 4.0
MMB 1.0
1-vinyl pyrrolidone, 1-ethylenic copolymer 0.5
Sodium-chlor 5.5
BIT 0.1
Essence 0.1
Citric acid monohydrate Food grade 0.05
Deionized water 60.75.
5. preparation method with fabric detergent of colour-preserving function, it is characterized in that: this washing composition is by polyoxyethylenated alcohol sodium sulfate, lauryl amido propyl betaine, alkyl-glucoside, aliphatic alcohol polyethenoxy (9) ether, α-sodium olefin sulfonate, MMB, 1-vinyl pyrrolidone, 1-ethylenic copolymer, sodium-chlor, BIT, essence, Citric acid monohydrate Food grade, deionized water are prepared from; The weight ratio of each component is in this washing composition:
Polyoxyethylenated alcohol sodium sulfate 10.0~25.5
Lauryl amido propyl betaine 2.0~4.0
Alkyl-glucoside 4.5~8.0
Aliphatic alcohol polyethenoxy (9) ether 0.5~8.0
α-sodium olefin sulfonate 0.5~5.0
MMB 1.0~5.0
1-vinyl pyrrolidone, 1-ethylenic copolymer 0.05~1.0
Sodium-chlor 2.0~6.0
BIT 0.1
Essence 0.1~0.3
Citric acid monohydrate Food grade 0.05~0.2
Deionized water 30.0~85.0;
This preparation method's step is as follows successively:
A. with described deionized water wherein 70%~85% be heated to 60 ℃~80 ℃, then under agitation add described polyoxyethylenated alcohol sodium sulfate, lauryl amido propyl betaine, alkyl-glucoside, aliphatic alcohol polyethenoxy (9) ether, α-sodium olefin sulfonate, MMB, 1-vinyl pyrrolidone according to said ratio, 1-ethylenic copolymer obtains mixture A to fully dissolving; This mixed solution A is formulated in the material still, need to stir successively when adding described each component;
Add described BIT, essence, sodium-chlor, residue deionized water, Citric acid monohydrate Food grade when B. described mixture A being cooled to 35 ℃~45 ℃ and stir, obtain mixture B; When preparing this mixing solutions B, need to stir successively when adding described each component; The pH value of described solution B is 7.0~8.0;
C. described mixing solutions B is left standstill 100 ~ 120 minutes, until described mixing solutions B temperature is lower than 35 ℃, namely get described fabric detergent with colour-preserving function; Carrying out can produces again.
6. fabric detergent with colour-preserving function, it is characterized in that: in this washing composition by polyoxyethylenated alcohol sodium sulfate, lauryl amido propyl betaine, alkyl-glucoside, aliphatic alcohol polyethenoxy (9) ether, α-sodium olefin sulfonate, MMB, 1-vinyl pyrrolidone, 1-ethylenic copolymer, sodium-chlor, BIT, essence, Citric acid monohydrate Food grade, deionized water are prepared from; The weight ratio of each component is in this washing composition:
Polyoxyethylenated alcohol sodium sulfate 25.0
Lauryl amido propyl betaine 3.0
Alkyl-glucoside 4.5
Aliphatic alcohol polyethenoxy (9) ether 2.0
α-sodium olefin sulfonate 0.5
MMB 5.0
1-vinyl pyrrolidone, 1-ethylenic copolymer 0.5
Sodium-chlor 2.0
BIT 0.1
Essence 0.15
Citric acid monohydrate Food grade 0.2
Deionized water 57.05.
7. fabric detergent with colour-preserving function, it is characterized in that: in this washing composition by polyoxyethylenated alcohol sodium sulfate, lauryl amido propyl betaine, alkyl-glucoside, aliphatic alcohol polyethenoxy (9) ether, α-sodium olefin sulfonate, MMB, 1-vinyl pyrrolidone, 1-ethylenic copolymer, sodium-chlor, BIT, essence, Citric acid monohydrate Food grade, deionized water are prepared from; The weight ratio of each component is in this washing composition:
Polyoxyethylenated alcohol sodium sulfate 24.0
Lauryl amido propyl betaine 2.0
Alkyl-glucoside 6.0
Aliphatic alcohol polyethenoxy (9) ether 0.5
α-sodium olefin sulfonate 0.5
MMB 0.5
1-vinyl pyrrolidone, 1-ethylenic copolymer 0.5
Sodium-chlor 2.5
BIT 0.1
Essence 0.3
Citric acid monohydrate Food grade 0.12
Deionized water 62.98.
CN 201010165619 2010-05-07 2010-05-07 Fabric detergent with colour-preserving function and preparation method thereof Expired - Fee Related CN101798552B (en)

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CN101152123A (en) * 2007-09-03 2008-04-02 中盐东兴盐化股份有限公司 Bath salt plaster for women and children
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CN107049868A (en) * 2017-05-03 2017-08-18 中国农业科学院兰州畜牧与兽药研究所 A kind of pet detergent with sterilizing and preparation method thereof
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