CN103725446B - A kind of have medicated clothing cleaning agent increasing New function and preparation method thereof - Google Patents

A kind of have medicated clothing cleaning agent increasing New function and preparation method thereof Download PDF

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CN103725446B
CN103725446B CN201310719917.2A CN201310719917A CN103725446B CN 103725446 B CN103725446 B CN 103725446B CN 201310719917 A CN201310719917 A CN 201310719917A CN 103725446 B CN103725446 B CN 103725446B
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ether
aliphatic alcohol
alcohol polyethenoxy
cleaning agent
essence
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CN103725446A (en
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张辉
其木格
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Beijing green umbrella Technology Co., Ltd
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BEIJING LUSAN CHEMICAL Co Ltd
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Abstract

The invention provides a kind of cleaning agent with medicated clothing increasing New function, the raw material of described cleaning agent includes aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (9) ether, short-chain branch type aliphatic alcohol polyethenoxy (8) ether, alkyl-glucoside, lauryl amidopropyl betaine, excellent Si Te-1, RC smooth agent, citric acid, BIT, essence and deionized water. Described cleaning agent can simultaneously complete decontamination and increase new, the present invention passes through the organic silicone oil interaction to fabric fibre surface, fiber is formed very firmly oriented adsorption effect, utilize dye migration technology, make the dye migration within fabric fibre, thus faded dark clothes fabric color is recovered true qualities.

Description

A kind of have medicated clothing cleaning agent increasing New function and preparation method thereof
Technical field
The invention belongs to cleaning agent field, be specifically related to a kind of cleaning agent with medicated clothing increasing New function and preparation method thereof.
Background technology
Organic silicone oil product develops quickly at home in recent years, and siliceous surfactant is as the novel surfactant that organosilicon new material grows up. Organic silicone oil surfactant, except the performance with conventional surfactants, also has a higher surface activity, easy spread, physiological, weatherability and the feature such as high temperature resistant. At present, it is applied primarily in the several respects such as polyurethane foam industry, textile industry and personal care products, also has for medicated clothing soft finishing agent aspect, increase new nursing aspect but without applying it to medicated clothing.
The medicated clothing of people's dress is constantly using and in washing process, can become more and more older, particularly the medicated clothing of fugitive color, and several times, color relation seems and turns white in washing, sends out dirt. The nursing agent of New function is increased in the market but without a clothes fabric that is specifically designed to. Therefore, in order to solve COLOR FASTNESS PROBLEM in clothes fabric cleaning process, it is necessary for developing a kind of cleaning agent with medicated clothing increasing New function.
Summary of the invention
It is an object of the invention to provide a kind of cleaning agent with medicated clothing increasing New function and preparation method thereof, described cleaning agent not only dirt-removing power is strong, and faded dark clothes fabric color can be made to recover true qualities. The present invention passes through the organic silicone oil interaction to fabric fibre surface, fiber is formed very firmly oriented adsorption effect, utilize dye migration technology, make the dye migration within fabric fibre, thus faded dark clothes fabric color is recovered true qualities.
It is an object of the invention to be achieved through the following technical solutions:
A kind of cleaning agent with medicated clothing increasing New function, the raw material of described cleaning agent include aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (9) ether, short-chain branch type aliphatic alcohol polyethenoxy (8) ether, alkyl-glucoside, lauryl amidopropyl betaine, excellent Si Te-1, RC smooth agent, citric acid, 1,2-benzisothiazole-3-ketone, essence and deionized water, the ratio of weight and number of each raw material described is:
Aliphatic alcohol polyethenoxy (7) ether 1 ~ 5
Aliphatic alcohol polyethenoxy (9) ether 5 ~ 10
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether 0.5 ~ 3
Alkyl-glucoside 10 ~ 15
Lauryl amidopropyl betaine 10 ~ 20
Excellent Si Te-12 ~ 6
RC smooth agent 1 ~ 2
Citric acid 0.05 ~ 0.2
BIT 0.5 ~ 1
Essence 0.3 ~ 0.5
Deionized water 40 ~ 70.
It is another object of the present invention to by another technical scheme following realization:
A kind of have the preparation method that medicated clothing increases the cleaning agent of New function, the raw material of described cleaning agent include aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (9) ether, short-chain branch type aliphatic alcohol polyethenoxy (8) ether, alkyl-glucoside, lauryl amidopropyl betaine, excellent Si Te-1, RC smooth agent, citric acid, 1,2-benzisothiazole-3-ketone, essence and deionized water, the ratio of weight and number of each raw material described is:
Aliphatic alcohol polyethenoxy (7) ether 1 ~ 5
Aliphatic alcohol polyethenoxy (9) ether 5 ~ 10
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether 0.5 ~ 3
Alkyl-glucoside 10 ~ 15
Lauryl amidopropyl betaine 10 ~ 20
Excellent Si Te-12 ~ 6
RC smooth agent 1 ~ 2
Citric acid 0.05 ~ 0.2
BIT 0.5 ~ 1
Essence 0.3 ~ 0.5
Deionized water 40 ~ 70;
Described preparation method comprises the following steps:
1) 40% ~ 50% in described deionized water is taken according to above-mentioned ratio of weight and number, add in material still, heating is to 50 DEG C~60 DEG C, then described aliphatic alcohol polyethenoxy (9) ether, aliphatic alcohol polyethenoxy (7) ether, short-chain branch type aliphatic alcohol polyethenoxy (8) ether, alkyl-glucoside, lauryl amidopropyl betaine are added according to above-mentioned ratio of weight and number respectively, stirring, to being completely dissolved, obtains mixed liquor A;
2) adding described excellent Si Te-1, RC smooth agent according to above-mentioned ratio of weight and number in described mixed liquor A, stirring, to being completely dissolved, obtains mixed liquid B;
3) when above-mentioned mixed liquid B is cooled to 35 DEG C ~ 45 DEG C, add described BIT, essence and remaining deionized water according to above-mentioned ratio of weight and number, stir, obtain mixed liquor C;
4) by the mixed liquor C that obtains in above-mentioned citric acid to step 3), regulate its pH value to 6 ~ 6.5, filter after stirring, namely obtain the described medicated clothing that has and increase the cleaning agent of New function.
The present invention compared with prior art has the advantages that
1, cleaning agent of the present invention can make faded dark clothes fabric color recover true qualities. By the organic silicone oil interaction to fabric fibre surface, fiber is formed very firmly oriented adsorption effect, utilizes dye migration technology, make the dye migration within fabric fibre, thus faded dark clothes fabric color is recovered true qualities;
2, cleaning agent stability of the present invention, good water solubility, plant, excellent Si Te-1 and RC smooth agent can be protected to have soft clothes fabric and anlistatig effect;
3, cleaning agent of the present invention is owing to the addition of aliphatic alcohol polyethenoxy (9) ether, aliphatic alcohol polyethenoxy (7) ether, can improve the dirt-removing power of described cleaning agent; Short-chain branch type aliphatic alcohol polyethenoxy (8) ether can improve the penetrating power of product, thus increasing dirt-removing power;
4, cleaning agent of the present invention is environmentally friendly, nontoxic non-stimulated, and decontamination, increasing newly once complete, thus economizing on resources, improve cleaning efficiency;
5, cleaning agent of the present invention reaches the requirement of national sector standard QB1224.
Detailed description of the invention
Embodiment 1
A kind of have the preparation method that medicated clothing increases the cleaning agent of New function, the raw material of described cleaning agent include aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (9) ether, short-chain branch type aliphatic alcohol polyethenoxy (8) ether, alkyl-glucoside, lauryl amidopropyl betaine, excellent Si Te-1, RC smooth agent, citric acid, 1,2-benzisothiazole-3-ketone, essence and deionized water, the ratio of weight and number of each raw material described is:
Aliphatic alcohol polyethenoxy (7) ether 1 ~ 5
Aliphatic alcohol polyethenoxy (9) ether 5 ~ 10
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether 0.5 ~ 3
Alkyl-glucoside 10 ~ 15
Lauryl amidopropyl betaine 10 ~ 20
Excellent Si Te-12 ~ 6
RC smooth agent 1 ~ 2
Citric acid 0.05 ~ 0.2
BIT 0.5 ~ 1
Essence 0.3 ~ 0.5
Deionized water 40 ~ 70;
Further, described essence is lavandula angustifolia essence, rose essence or moonlight essence.
Described preparation method comprises the following steps:
1) 40% ~ 50% in described deionized water is taken according to above-mentioned ratio of weight and number, add in material still, heating is to 50 DEG C~60 DEG C, then described aliphatic alcohol polyethenoxy (9) ether, aliphatic alcohol polyethenoxy (7) ether, short-chain branch type aliphatic alcohol polyethenoxy (8) ether, alkyl-glucoside, lauryl amidopropyl betaine are added according to above-mentioned ratio of weight and number respectively, stirring, to being completely dissolved, obtains mixed liquor A;
2) adding described excellent Si Te-1, RC smooth agent according to above-mentioned ratio of weight and number in described mixed liquor A, stirring, to being completely dissolved, obtains mixed liquid B;
3) when above-mentioned mixed liquid B is cooled to 35 DEG C ~ 45 DEG C, add described BIT, essence and remaining deionized water according to above-mentioned ratio of weight and number, stir, obtain mixed liquor C;
4) by the mixed liquor C that obtains in above-mentioned citric acid to step 3), regulate its pH value to 6 ~ 6.5, filter after stirring, namely obtain the described medicated clothing that has and increase the cleaning agent of New function.
Unit of weight used by the present embodiment is kilogram, it is also possible to for gram;
Essence described in the present embodiment is food stage, and other each raw materials are technical grade;
Each component described in the present embodiment be on market sell conventional products; Wherein, excellent Si Te-1 is purchased from Beijing Zhong Fang Chemical Co., Ltd., and RC smooth agent is purchased from Inner Mongol Hong science, industry and trade Co., Ltd.
In the present embodiment, each raw material in described Footgear deodorizer can in the ratio range provided flexible combination, do not enumerate one by one at this.
Embodiment 2
The present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the ratio of weight and number of each raw material described is:
Aliphatic alcohol polyethenoxy (7) ether 2
Aliphatic alcohol polyethenoxy (9) ether 8
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether 3
Alkyl-glucoside 10
Lauryl amidopropyl betaine 15
Excellent Si Te-16
RC smooth agent 1
Citric acid 0.1
BIT 0.6
Lavandula angustifolia essence 0.3
Deionized water 54.
Unit of weight used by the present embodiment is kilogram, it is also possible to for gram.
Described preparation method comprises the following steps:
1) 50% in described deionized water is taken according to above-mentioned ratio of weight and number, add in material still, heating is to 55 DEG C, then described aliphatic alcohol polyethenoxy (9) ether, aliphatic alcohol polyethenoxy (7) ether, short-chain branch type aliphatic alcohol polyethenoxy (8) ether, alkyl-glucoside, lauryl amidopropyl betaine are added according to above-mentioned ratio of weight and number respectively, stirring, to being completely dissolved, obtains mixed liquor A;
2) adding described excellent Si Te-1, RC smooth agent according to above-mentioned ratio of weight and number in described mixed liquor A, stirring, to being completely dissolved, obtains mixed liquid B;
3) when above-mentioned mixed liquid B is cooled to 40 DEG C, add described BIT, essence and remaining deionized water according to above-mentioned ratio of weight and number, stir, obtain mixed liquor C;
4) by the mixed liquor C that obtains in above-mentioned citric acid to step 3), regulate its pH value to 6.5, filter after stirring, namely obtain the described medicated clothing that has and increase the cleaning agent of New function.
Cleaning agent described in the present embodiment reaches the requirement of national sector standard QB1224.
Method by the test of GB/T3921-2008 textile color stability, measuring different colours, the color fastness to washing that different fabrics repeatedly wash with this cleaning agent, with the various fabric of this detergent washing 1 ~ 10 time, measuring the color fastness of fabric after every time washing respectively, variable color all reaches 5 grades.
Embodiment 3
The present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the ratio of weight and number of each raw material described is:
Aliphatic alcohol polyethenoxy (7) ether 3
Aliphatic alcohol polyethenoxy (9) ether 8
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether 1
Alkyl-glucoside 12
Lauryl amidopropyl betaine 13
Excellent Si Te-14
RC smooth agent 1
Citric acid 0.15
BIT 0.6
Moonlight essence 0.3
Deionized water 56.95.
Unit of weight used by the present embodiment is kilogram, it is also possible to for gram.
The preparation method detailed in Example 1 of the present embodiment.
Cleaning agent described in the present embodiment reaches the requirement of national sector standard QB1224.
Method by the test of GB/T3921-2008 textile color stability, measuring different colours, the color fastness to washing that different fabrics repeatedly wash with this cleaning agent, with the various fabric of this detergent washing 1 ~ 10 time, measuring the color fastness of fabric after every time washing respectively, variable color all reaches 5 grades.
Embodiment 4
The present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the ratio of weight and number of each raw material described is:
Aliphatic alcohol polyethenoxy (7) ether 5
Aliphatic alcohol polyethenoxy (9) ether 5
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether 2
Alkyl-glucoside 15
Lauryl amidopropyl betaine 13
Excellent Si Te-14
RC smooth agent 1.5
Citric acid 0.2
BIT 0.6
Rose essence 0.3
Deionized water 53.4.
Unit of weight used by the present embodiment is kilogram, it is also possible to for gram.
The preparation method detailed in Example 1 of the present embodiment.
Cleaning agent described in the present embodiment reaches the requirement of national sector standard QB1224.
Method by the test of GB/T3921-2008 textile color stability, measuring different colours, the color fastness to washing that different fabrics repeatedly wash with this cleaning agent, with the various fabric of this detergent washing 1 ~ 10 time, measuring the color fastness of fabric after every time washing respectively, variable color all reaches 5 grades.
Embodiment 5
The present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the ratio of weight and number of each raw material described is:
Aliphatic alcohol polyethenoxy (7) ether 3
Aliphatic alcohol polyethenoxy (9) ether 8
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether 1
Alkyl-glucoside 15
Lauryl amidopropyl betaine 16
Excellent Si Te-14
RC smooth agent 2
Citric acid 0.2
BIT 0.6
Lavandula angustifolia essence 0.3
Deionized water 49.9.
Unit of weight used by the present embodiment is kilogram, it is also possible to for gram.
The preparation method detailed in Example 1 of the present embodiment.
Cleaning agent described in the present embodiment reaches the requirement of national sector standard QB1224.
Method by the test of GB/T3921-2008 textile color stability, measuring different colours, the color fastness to washing that different fabrics repeatedly wash with this cleaning agent, with the various fabric of this detergent washing 1 ~ 10 time, measuring the color fastness of fabric after every time washing respectively, variable color all reaches 5 grades.
Embodiment 6
The present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the ratio of weight and number of each raw material described is:
Aliphatic alcohol polyethenoxy (7) ether 5
Aliphatic alcohol polyethenoxy (9) ether 7
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether 0.5
Alkyl-glucoside 14
Lauryl amidopropyl betaine 15
Excellent Si Te-14
RC smooth agent 2
Citric acid 0.18
BIT 0.6
Rose essence 0.3
Deionized water 51.42.
Unit of weight used by the present embodiment is kilogram, it is also possible to for gram.
The preparation method detailed in Example 1 of the present embodiment.
Cleaning agent described in the present embodiment reaches the requirement of national sector standard QB1224.
Method by the test of GB/T3921-2008 textile color stability, measuring different colours, the color fastness to washing that different fabrics repeatedly wash with this cleaning agent, with the various fabric of this detergent washing 1 ~ 10 time, measuring the color fastness of fabric after every time washing respectively, variable color all reaches 5 grades.
Embodiment 7
The present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the ratio of weight and number of each raw material described is:
Aliphatic alcohol polyethenoxy (7) ether 1
Aliphatic alcohol polyethenoxy (9) ether 10
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether 2
Alkyl-glucoside 12
Lauryl amidopropyl betaine 17
Excellent Si Te-14
RC smooth agent 1.5
Citric acid 0.15
BIT 0.6
Moonlight essence 0.3
Deionized water 51.45.
Unit of weight used by the present embodiment is kilogram, it is also possible to for gram.
The preparation method detailed in Example 1 of the present embodiment.
Cleaning agent described in the present embodiment reaches the requirement of national sector standard QB1224.
Method by the test of GB/T3921-2008 textile color stability, measuring different colours, the color fastness to washing that different fabrics repeatedly wash with this cleaning agent, with the various fabric of this detergent washing 1 ~ 10 time, measuring the color fastness of fabric after every time washing respectively, variable color all reaches 5 grades.

Claims (8)

1. a cleaning agent with medicated clothing increasing New function, it is characterized in that, the raw material of described cleaning agent by aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (9) ether, short-chain branch type aliphatic alcohol polyethenoxy (8) ether, alkyl-glucoside, lauryl amidopropyl betaine, excellent Si Te-1, RC smooth agent, citric acid, 1,2-benzisothiazole-3-ketone, essence and deionized water composition, the ratio of weight and number of each raw material described is:
Aliphatic alcohol polyethenoxy (7) ether 1 ~ 5
Aliphatic alcohol polyethenoxy (9) ether 5 ~ 10
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether 0.5 ~ 3
Alkyl-glucoside 10 ~ 15
Lauryl amidopropyl betaine 10 ~ 20
Excellent Si Te-12 ~ 6
RC smooth agent 1 ~ 2
Citric acid 0.05 ~ 0.2
BIT 0.5 ~ 1
Essence 0.3 ~ 0.5
Deionized water 40 ~ 70;
Preparation method comprises the following steps:
1) 40% ~ 50% in described deionized water is taken according to above-mentioned ratio of weight and number, add in material still, heating is to 50 DEG C~60 DEG C, then described aliphatic alcohol polyethenoxy (9) ether, aliphatic alcohol polyethenoxy (7) ether, short-chain branch type aliphatic alcohol polyethenoxy (8) ether, alkyl-glucoside, lauryl amidopropyl betaine are added according to above-mentioned ratio of weight and number respectively, stirring, to being completely dissolved, obtains mixed liquor A;
2) adding described excellent Si Te-1, RC smooth agent according to above-mentioned ratio of weight and number in described mixed liquor A, stirring, to being completely dissolved, obtains mixed liquid B;
3) when above-mentioned mixed liquid B is cooled to 35 DEG C ~ 45 DEG C, add described BIT, essence and remaining deionized water according to above-mentioned ratio of weight and number, stir, obtain mixed liquor C;
4) above-mentioned citric acid is joined in the mixed liquor C obtained in step 3), regulate its pH value to 6 ~ 6.5, filter after stirring, namely obtain the described medicated clothing that has and increase the cleaning agent of New function.
2. the cleaning agent with medicated clothing increasing New function according to claim 1, it is characterised in that described essence is lavandula angustifolia essence or rose essence.
3. the cleaning agent with medicated clothing increasing New function according to claim 1, it is characterised in that the ratio of weight and number of each raw material described is:
Aliphatic alcohol polyethenoxy (7) ether 2
Aliphatic alcohol polyethenoxy (9) ether 8
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether 3
Alkyl-glucoside 10
Lauryl amidopropyl betaine 15
Excellent Si Te-16
RC smooth agent 1
Citric acid 0.1
BIT 0.6
Essence 0.3
Deionized water 54.
4. the cleaning agent with medicated clothing increasing New function according to claim 1, it is characterised in that the ratio of weight and number of each raw material described is:
Aliphatic alcohol polyethenoxy (7) ether 3
Aliphatic alcohol polyethenoxy (9) ether 8
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether 1
Alkyl-glucoside 12
Lauryl amidopropyl betaine 13
Excellent Si Te-14
RC smooth agent 1
Citric acid 0.15
BIT 0.6
Essence 0.3
Deionized water 56.95.
5. the cleaning agent with medicated clothing increasing New function according to claim 1, it is characterised in that the ratio of weight and number of each raw material described is:
Aliphatic alcohol polyethenoxy (7) ether 5
Aliphatic alcohol polyethenoxy (9) ether 5
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether 2
Alkyl-glucoside 15
Lauryl amidopropyl betaine 13
Excellent Si Te-14
RC smooth agent 1.5
Citric acid 0.2
BIT 0.6
Essence 0.3
Deionized water 53.4.
6. the cleaning agent with medicated clothing increasing New function according to claim 1, it is characterised in that the ratio of weight and number of each raw material described is:
Aliphatic alcohol polyethenoxy (7) ether 3
Aliphatic alcohol polyethenoxy (9) ether 8
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether 1
Alkyl-glucoside 15
Lauryl amidopropyl betaine 16
Excellent Si Te-14
RC smooth agent 2
Citric acid 0.2
BIT 0.6
Essence 0.3
Deionized water 49.9.
7. the cleaning agent with medicated clothing increasing New function according to claim 1, it is characterised in that the ratio of weight and number of each raw material described is:
Aliphatic alcohol polyethenoxy (7) ether 5
Aliphatic alcohol polyethenoxy (9) ether 7
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether 0.5
Alkyl-glucoside 14
Lauryl amidopropyl betaine 15
Excellent Si Te-14
RC smooth agent 2
Citric acid 0.18
BIT 0.6
Essence 0.3
Deionized water 51.42.
8. the cleaning agent with medicated clothing increasing New function according to claim 1, it is characterised in that the ratio of weight and number of each raw material described is:
Aliphatic alcohol polyethenoxy (7) ether 1
Aliphatic alcohol polyethenoxy (9) ether 10
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether 2
Alkyl-glucoside 12
Lauryl amidopropyl betaine 17
Excellent Si Te-14
RC smooth agent 1.5
Citric acid 0.15
BIT 0.6
Essence 0.3
Deionized water 51.45.
CN201310719917.2A 2013-12-24 2013-12-24 A kind of have medicated clothing cleaning agent increasing New function and preparation method thereof Active CN103725446B (en)

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Publication number Priority date Publication date Assignee Title
CN105733832A (en) * 2016-01-26 2016-07-06 池州汉诺威机电设备科技有限公司 Deoiling detergent and preparation method thereof
CN108978223B (en) * 2018-06-27 2020-12-11 北京福奈特洗衣服务有限公司 Clothing care agent and preparation method thereof
CN115651773A (en) * 2022-10-14 2023-01-31 丽友清洁科技(湖北)有限公司 Polyester fabric low-temperature degreasing agent and preparation method and preparation device thereof

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Publication number Priority date Publication date Assignee Title
CN101798552A (en) * 2010-05-07 2010-08-11 北京绿伞化学股份有限公司 Fabric detergent with colour-preserving function and preparation method thereof
CN101818105A (en) * 2010-05-17 2010-09-01 北京绿伞化学股份有限公司 Washing agent with stain removal and softening functions and preparation method thereof
CN102061227A (en) * 2011-01-24 2011-05-18 北京洛娃日化有限公司 Washing and protecting combined infant liquid detergent

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101798552A (en) * 2010-05-07 2010-08-11 北京绿伞化学股份有限公司 Fabric detergent with colour-preserving function and preparation method thereof
CN101818105A (en) * 2010-05-17 2010-09-01 北京绿伞化学股份有限公司 Washing agent with stain removal and softening functions and preparation method thereof
CN102061227A (en) * 2011-01-24 2011-05-18 北京洛娃日化有限公司 Washing and protecting combined infant liquid detergent

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Address after: 100094 block B, building 1, yard 2, Yongcheng North Road, Yongfeng Industrial base, Haidian District, Beijing

Patentee after: Beijing green umbrella Technology Co., Ltd

Address before: 100094 block B, building 1, yard 2, Yongcheng North Road, Yongfeng Science Park, Haidian District, Beijing

Patentee before: Beijing lvsan Chemical Co., Ltd