CN101857824B - Detergent using sodium alcohol ether carboxylate as main raw material - Google Patents
Detergent using sodium alcohol ether carboxylate as main raw material Download PDFInfo
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- CN101857824B CN101857824B CN2010101534741A CN201010153474A CN101857824B CN 101857824 B CN101857824 B CN 101857824B CN 2010101534741 A CN2010101534741 A CN 2010101534741A CN 201010153474 A CN201010153474 A CN 201010153474A CN 101857824 B CN101857824 B CN 101857824B
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Abstract
The invention provides a detergent using sodium alcohol ether carboxylate as a main raw material. The detergent mainly comprises sodium fatty alcohol polyoxyethylene ether carboxylate and 1,2-benzisothiazolin-3-one. Through reasonable compatibility of the sodium alcohol ether carboxylate, a penetrating agent, an emulsifying agent and a dispersing agent, the detergent can quickly seep into dirt to swell the dirt, so that the dirt is easy to strip off and break away and is completely removed and good cleaning effect is achieved; and the detergent is environmental-friendly and has no toxicity or irritation to a human body.
Description
Technical field
The invention belongs to the detergent composition field, particularly a kind of is the washing composition of main raw material with the sodium alcohol ether carboxylate.
Background technology
Ether alcohol sulfate is widely used in the washing composition as traditional surfactant; But in use there are some defectives in it: if any the pungency certain to skin; Slightly not enough at aspect of performances such as surface tension, wetting, emulsification, soil removabilitys, can not reach good effect.
The alkyl ethoxylated carboxylate salt is that the collection of one type of excellent performance is gentle, safety, and multi-functional novel green tensio-active agent, the development in the world of ether carboxylate tensio-active agent has become flourishing gesture, and its good application performance is generally acknowledged by the world.Alcohol ether carboxylate is compared with ether alcohol sulfate, owing to the difference of terminal hydrophilic group, has avoided the defective of ether alcohol sulfate.Therefore, can think that alcohol ether carboxylate is a kind of than the better tensio-active agent of ether alcohol sulfate performance, be the ideal substitute of ether alcohol sulfate.H.Haussmann synthesized the sodium alcohol ether carboxylate that textile industry is used first with alcohol ether, sodium Metal 99.5 and sodium chloroacetate in 1934, so far the history in existing more than 70 year.The eighties, the property of alcohol ether carboxylate is familiar with gradually and is gained universal acceptance, and alcohol ether carboxylate gets into brand-new developing period in developed country.
Alcohol ether carboxylate develops starting at home than later, and is current, though China is domestic product for trial sale arranged, and the kind and the output of alcohol ether carboxylate are less, and Application Areas is extensive inadequately, still is in the starting stage; Domestic many advantageous property understanding to alcohol ether carboxylate are not very abundant, along with the rise of green chemical industry, and environmental problem, the focusization of ecological protection problem, the biological degradability of alcohol ether carboxylate, mildness etc. are just understood by people gradually.Therefore need carry out seriation research in all kinds of detergent application situation to alcohol ether carboxylate, develop gentleness, efficient, environmental protection, green serial articles for washing.
Summary of the invention
The purpose of this invention is to provide a kind of is the washing composition of main raw material with the sodium alcohol ether carboxylate, and this washing is concentrated and contained aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium, 1,2-benzisothiazole-3-ketone; The present invention can thoroughly remove spot, reaches good clean effect; And environmentally friendly, non-stimulated to human non-toxic.
The objective of the invention is to realize through following technical scheme:
A kind of is the washing composition of main raw material with the sodium alcohol ether carboxylate, contains aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium, 1 in this washing composition, 2-benzisothiazole-3-ketone, aliphatic alcohol polyethenoxy (9) ether, essence, deionized water; The weight ratio of each component is in this washing composition:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 2.0 ~ 8.0
1,2-benzisothiazole-3-ketone 0.1
Aliphatic alcohol polyethenoxy (9) ether 1.0 ~ 5.0
Essence 0.2 ~ 0.3
Deionized water 80～99.
The present invention can be used as leather cleaning agent and uses; According to the examining report of national light industry makeup articles for washing quality examination Beijing Station, submitted sample of the present invention detects according to Q/HDLSH 030-2009 " leather cleaning agent " company standard, the project conformance with standard requirement of examining.
The objective of the invention is to realize through following another technical scheme:
A kind of is the preparation method of the washing composition of main raw material with the sodium alcohol ether carboxylate, contains aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium, 1 in this washing composition, 2-benzisothiazole-3-ketone, aliphatic alcohol polyethenoxy (9) ether, essence, deionized water; The weight ratio of each component is in this washing composition:; The weight ratio of each component is in this washing composition:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 2.0～8.0
1,2-benzisothiazole-3-ketone 0.1
Aliphatic alcohol polyethenoxy (9) ether 1.0～5.0
Essence 0.2～0.3
Deionized water 80～99;
This preparing method's steps in sequence is following:
A. get 70%～85% of described deionized water weight in the said ratio and be heated to 40～50 ℃,, obtain mixed solution A to wherein adding described aliphatic alcohol polyethenoxy (9) ether, aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium by the preparation weight ratio successively;
B. after treating that described solution A temperature is reduced to 35 ℃～45 ℃, add describedly 1 successively by the preparation weight ratio, remaining described deionized water obtains mixing solutions B in 2-benzisothiazole-3-ketone, essence, the said ratio;
C. described mixing solutions B is left standstill, obtaining described is the washing composition of main raw material with the sodium alcohol ether carboxylate.
The objective of the invention is to realize through following another technical scheme:
A kind of is the washing composition of main raw material with the sodium alcohol ether carboxylate; Contain aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium, 1 in this washing composition, 2-benzisothiazole-3-ketone, aliphatic alcohol polyethenoxy (9) ether, polyoxyethylenated alcohol sodium sulfate, aliphatic alcohol polyethenoxy (7) ether, essence, deionized water; The weight ratio of each component is in this washing composition:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 3.0～25.0
1,2-benzisothiazole-3-ketone 0.1
Aliphatic alcohol polyethenoxy (9) ether 1.0～10.0
Polyoxyethylenated alcohol sodium sulfate 3.0～8.0
Aliphatic alcohol polyethenoxy (7) ether 3.0～20.0
Essence 0.1～0.3
Deionized water 25～90.
The present invention can be used as collar cleaner and uses; Examining report according to national light industry makeup articles for washing quality examination Beijing Station; Submitted sample of the present invention is according to QB/T1224-2007 " dress material washes agent by liquid " (the preparatory Destain liquid of clothing A level) and GB/T 13171-2004 " washing powder " (WL; Total phosphorus pentoxide content) standard detection, the project conformance with standard requirement of examining.
The objective of the invention is to realize through following another technical scheme:
A kind of is the preparation method of the washing composition of main raw material with the sodium alcohol ether carboxylate; Contain aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium, 1 in this washing composition, 2-benzisothiazole-3-ketone, aliphatic alcohol polyethenoxy (9) ether, polyoxyethylenated alcohol sodium sulfate, aliphatic alcohol polyethenoxy (7) ether, essence, deionized water; The weight ratio of each component is in this washing composition:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 3.0～25.0
1,2-benzisothiazole-3-ketone 0.1
Aliphatic alcohol polyethenoxy (9) ether 1.0～10.0
Polyoxyethylenated alcohol sodium sulfate 3.0～8.0
Aliphatic alcohol polyethenoxy (7) ether 3.0～20.0
Essence 0.1～0.3
Deionized water 25～90;
This preparing method's steps in sequence is following:
A. get 70%～85% of described deionized water weight in the said ratio and be heated to 60～80 ℃; To wherein adding described polyoxyethylenated alcohol sodium sulfate, aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (9) ether, aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium by the preparation weight ratio successively, obtain mixed solution A;
B. after treating that described solution A temperature is reduced to 35 ℃～45 ℃, add describedly 1 successively by the preparation weight ratio, remaining described deionized water obtains mixing solutions B in 2-benzisothiazole-3-ketone, essence, the said ratio;
C. described mixing solutions B is left standstill, obtaining described is the washing composition of main raw material with the sodium alcohol ether carboxylate.
The objective of the invention is to realize through following another technical scheme:
A kind of is the washing composition of main raw material with the sodium alcohol ether carboxylate; Contain aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium, 1 in this washing composition, 2-benzisothiazole-3-ketone, polyoxyethylenated alcohol sodium sulfate, aliphatic alcohol polyethenoxy polyoxypropylene (9) ether, fatty acid alkyl amide, absolute ethyl alcohol, essence, deionized water; The weight ratio of each component is in this washing composition:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 8.0～20.0
1,2-benzisothiazole-3-ketone 0.1
Polyoxyethylenated alcohol sodium sulfate 30.0～40.0
Aliphatic alcohol polyethenoxy polyoxypropylene (9) ether 18.0～28.0
Fatty acid alkyl amide 3.0～6.5
Absolute ethyl alcohol 4.0～9.0
Essence 0.1～0.3
Deionized water 10～40.
The present invention can be used as the concentrated fabric washing composition and uses; Examining report according to national light industry makeup articles for washing quality examination Beijing Station; Submitted sample of the present invention is according to Q/HDLSH045-2008 " highly enriched dress material washes agent by liquid " [highly enriched washing liquid (I)] standard detection, the project conformance with standard requirement of examining.
The objective of the invention is to realize through following another technical scheme:
A kind of is the preparation method of the washing composition of main raw material with the sodium alcohol ether carboxylate; It is characterized in that: contain aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium, 1 in this washing composition, 2-benzisothiazole-3-ketone, polyoxyethylenated alcohol sodium sulfate, aliphatic alcohol polyethenoxy polyoxypropylene (9) ether, fatty acid alkyl amide, absolute ethyl alcohol, essence, deionized water; The weight ratio of each component is in this washing composition:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 8～20
1,2-benzisothiazole-3-ketone 0.1
Polyoxyethylenated alcohol sodium sulfate 30～40
Aliphatic alcohol polyethenoxy polyoxypropylene (9) ether 18～28
Fatty acid alkyl amide 3.0～6.5
Absolute ethyl alcohol 4～9
Essence 0.1～0.3
Deionized water 10～40;
This preparing method's steps in sequence is following:
A. get 70%～85% of described deionized water weight in the said ratio and be heated to 60～80 ℃; To wherein adding described polyoxyethylenated alcohol sodium sulfate, aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium, aliphatic alcohol polyethenoxy (9) ether, fatty acid alkyl amide by the preparation weight ratio successively, obtain mixed solution A;
B. after treating that described solution A temperature is reduced to 35 ℃～45 ℃, add described absolute ethyl alcohol, 1 by the preparation weight ratio successively, remaining described deionized water obtains mixing solutions B in 2-benzisothiazole-3-ketone, essence, the said ratio;
C. described mixing solutions B is left standstill, obtaining described is the washing composition of main raw material with the sodium alcohol ether carboxylate.
The objective of the invention is to realize through following another technical scheme:
A kind of is the washing composition of main raw material with the sodium alcohol ether carboxylate; Contain aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium, 1 in this washing composition, 2-benzisothiazole-3-ketone, polyoxyethylenated alcohol sodium sulfate, cocamidopropyl propyl amide ammonium oxide, fatty acid alkyl amide, alkyl-glucoside, the two stearates of polyethylene glycol 6000, Hydrocerol A, sodium-chlor, essence, deionized water; The weight ratio of each component is in this washing composition:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 8.0～15.0
1,2-benzisothiazole-3-ketone 0.1
Polyoxyethylenated alcohol sodium sulfate 13.0～17.0
Cocamidopropyl propyl amide ammonium oxide 4.0～6.0
Fatty acid alkyl amide 0.5～5.0
Alkyl-glucoside 2.0～6.0
The two stearates 0.02～0.2 of polyethylene glycol 6000
Hydrocerol A 0.2～0.5
Sodium-chlor 1.0～3.0
Essence 0.1～0.3
Deionized water 40～75.
The present invention can be used as the fruit-vegetable type liquid detergent and uses; Wash the examining report at articles for use quality supervision and test center (Taiyuan) according to country; Submitted sample of the present invention is according to GB9985-2000 and " the hand washing third quarter in 2009 is with dish washing detergent state control sampling observation scheme " standard detection, the project conformance with standard requirement of examining.
The objective of the invention is to realize through following another technical scheme:
A kind of is the preparation method of the washing composition of main raw material with the sodium alcohol ether carboxylate; Contain aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium, 1 in this washing composition, 2-benzisothiazole-3-ketone, polyoxyethylenated alcohol sodium sulfate, cocamidopropyl propyl amide ammonium oxide, fatty acid alkyl amide, alkyl-glucoside, the two stearates of polyethylene glycol 6000, Hydrocerol A, sodium-chlor, essence, deionized water; The weight ratio of each component is in this washing composition:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 8.0～15.0
1,2-benzisothiazole-3-ketone 0.1
Polyoxyethylenated alcohol sodium sulfate 13.0～17.0
Cocamidopropyl propyl amide ammonium oxide 4.0～6.0
Fatty acid alkyl amide 0.5～5.0
Alkyl-glucoside 2.0～6.0
The two stearates 0.02～0.2 of polyethylene glycol 6000
Hydrocerol A 0.2～0.5
Sodium-chlor 1.0～3.0
Essence 0.1～0.3
Deionized water 40～75;
This preparing method's steps in sequence is following:
A. get 70%～85% of described deionized water weight in the said ratio and be heated to 60～80 ℃, obtain mixed solution A to wherein adding described polyoxyethylenated alcohol sodium sulfate, aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium, cocamidopropyl propyl amide ammonium oxide, fatty acid alkyl amide, alkyl-glucoside, the two stearates of polyethylene glycol 6000 by the preparation weight ratio successively;
B. after treating that described solution A temperature is reduced to 35 ℃～45 ℃, add described sodium-chlor, 1 by the preparation weight ratio successively, 2-benzisothiazole-3-ketone, essence, Hydrocerol A stir, and obtain mixing solutions B;
C. described mixing solutions B is left standstill, obtaining described is the washing composition of main raw material with the sodium alcohol ether carboxylate.
Compared with present technology the present invention has the following advantages:
The present invention selects sodium alcohol ether carboxylate and permeate agent, emulsifying agent, dispersion agent reasonable compatibility for use, and is can rapid permeability inner to spot, makes the spot swelling, is easy to peel off, break away from, and thoroughly removes spot, reaches good clean effect.The present invention is environmentally friendly, and non-stimulated to human non-toxic.
Embodiment
Embodiment 1:
A kind of is the washing composition of main raw material with the sodium alcohol ether carboxylate, contains aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium, 1 in this washing composition, 2-benzisothiazole-3-ketone, aliphatic alcohol polyethenoxy (9) ether, essence, deionized water; The weight ratio of each component is in this washing composition:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 2.0～8.0
1,2-benzisothiazole-3-ketone 0.1
Aliphatic alcohol polyethenoxy (9) ether 1.0～5.0
Essence 0.2～0.3
Deionized water 80～99.
The used weight unit of present embodiment is a kilogram, also can be gram;
Each component described in the present embodiment for being technical grade;
Each component described in the present embodiment is the conventional products of selling on the market;
In the present embodiment, described with the sodium alcohol ether carboxylate be each component in the washing composition of main raw material can be in the ratio range that provides flexible combination, do not enumerate one by one at this.
The washing composition of present embodiment can use by leather cleaning agent.
Aliphatic alcohol polyethenoxy in the present embodiment (9) ether, aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium is composite to have good wetting, foaming, dispersion, emulsifying capacity; The soil removability that the system of giving is good can effectively be removed dirts such as greasy dirt that leather is infected with, dish stain.
The adding of aliphatic alcohol polyethenoxy in the present embodiment (9) ether carboxylic acid sodium has reduced the pungency of system, can be in cleaning curing leather, make the leather after the cleaning soft, bright and clean, and to human temperature and, the low stimulation.
Each component environment-friendly high-efficiency is environmentally friendly in the present embodiment.
According to the examining report of national light industry makeup articles for washing quality examination Beijing Station, the submitted sample of present embodiment detects according to Q/HDLSH 030-2009 " leather cleaning agent " company standard, the project conformance with standard requirement of examining.
Embodiment 2:
Present embodiment is the preferred version on embodiment 1 basis, and the quality of raw materials used (component) is identical with embodiment 1, and described is that the weight ratio of each component is in the washing composition of main raw material with the sodium alcohol ether carboxylate:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 5.0
1,2-benzisothiazole-3-ketone 0.1
Aliphatic alcohol polyethenoxy (9) ether 1.0
Essence 0.2
Deionized water 93.7.
The used weight unit of present embodiment is a kilogram, also can be gram.
Embodiment 3:
Present embodiment is the preferred version on embodiment 1 basis, and the quality of raw materials used (component) is identical with embodiment 1, and described is that the weight ratio of each component is in the washing composition of main raw material with the sodium alcohol ether carboxylate:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 8.0
1,2-benzisothiazole-3-ketone 0.1
Aliphatic alcohol polyethenoxy (9) ether 2.0
Essence 0.2
Deionized water 89.7.
The used weight unit of present embodiment is a kilogram, also can be gram.
Embodiment 4:
Present embodiment is the preferred version on embodiment 1 basis, and the quality of raw materials used (component) is identical with embodiment 1, and described is that the weight ratio of each component is in the washing composition of main raw material with the sodium alcohol ether carboxylate:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 6.0
1,2-benzisothiazole-3-ketone 0.1
Aliphatic alcohol polyethenoxy (9) ether 3.8
Essence 0.25
Deionized water 89.85.
The used weight unit of present embodiment is a kilogram, also can be gram.
Embodiment 5:
Present embodiment is the preferred version on embodiment 1 basis, and the quality of raw materials used (component) is identical with embodiment 1, and described is that the weight ratio of each component is in the washing composition of main raw material with the sodium alcohol ether carboxylate:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 2.0
1,2-benzisothiazole-3-ketone 0.1
Aliphatic alcohol polyethenoxy (9) ether 5.0
Essence 0.3
Deionized water 93.6.
The used weight unit of present embodiment is a kilogram, also can be gram.
Embodiment 6:
Present embodiment is the preparation method of embodiment 1～5.
A kind of is the preparation method of the washing composition of main raw material with the sodium alcohol ether carboxylate; It is characterized in that: contain aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium, 1 in this washing composition, 2-benzisothiazole-3-ketone, aliphatic alcohol polyethenoxy (9) ether, essence, deionized water; The weight ratio of each component is in this washing composition:; The weight ratio of each component is in this washing composition:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 2.0～8.0
1,2-benzisothiazole-3-ketone 0.1
Aliphatic alcohol polyethenoxy (9) ether 1.0～5.0
Essence 0.2～0.3
Deionized water 80～99;
This preparing method's steps in sequence is following:
A. get 70%～85% of described deionized water weight in the said ratio and be heated to 40～50 ℃; Be preferably 45 ℃ to wherein adding described aliphatic alcohol polyethenoxy (9) ether, aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium by the preparation weight ratio successively, obtain mixed solution A; This mixed solution A is formulated in changing the material still, need stir successively when adding described each component;
B. treat that described solution A temperature reduces to 35 ℃～45 ℃, be preferably 40 ℃ after, add describedly 1 successively by the preparation weight ratio, remaining described deionized water obtains mixing solutions B in 2-benzisothiazole-3-ketone, essence, the said ratio; When preparing this mixing solutions B, need stir successively when adding described each component;
C. described mixing solutions B was left standstill 30 ~ 40 minutes, be lower than 35 ℃ until described mixing solutions B temperature, promptly getting described is the washing composition of main raw material with the sodium alcohol ether carboxylate; Carry out can again.
In above-mentioned process for preparation, should note entire operation clean environment health, dustproof.
The equipment that adopts in the present embodiment is conventional equipment, all can on market, buy to obtain.
Embodiment 7:
A kind of is the washing composition of main raw material with the sodium alcohol ether carboxylate; Contain aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium, 1 in this washing composition, 2-benzisothiazole-3-ketone, aliphatic alcohol polyethenoxy (9) ether, polyoxyethylenated alcohol sodium sulfate, aliphatic alcohol polyethenoxy (7) ether, essence, deionized water; The weight ratio of each component is in this washing composition:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 3.0～25.0
1,2-benzisothiazole-3-ketone 0.1
Aliphatic alcohol polyethenoxy (9) ether 1.0～10.0
Polyoxyethylenated alcohol sodium sulfate 3.0～8.0
Aliphatic alcohol polyethenoxy (7) ether 3.0～20.0
Essence 0.1～0.3
Deionized water 25～90.
The used weight unit of present embodiment is a kilogram, also can be gram;
Each component described in the present embodiment for being technical grade;
Each component described in the present embodiment is the conventional products of selling on the market;
In the present embodiment, described with the sodium alcohol ether carboxylate be each component in the washing composition of main raw material can be in the ratio range that provides flexible combination, do not enumerate one by one at this.
The washing composition of present embodiment can be used as collar cleaner and uses.
Polyoxyethylenated alcohol sodium sulfate in the present embodiment, aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (9) ether be composite to have good wetting, foaming, dispersion, emulsifying capacity, the soil removability that the system of giving is good; Can effectively remove heavy dirts such as greasy dirt that clothing is infected with, sweat stain.
The adding of aliphatic alcohol polyethenoxy in the present embodiment (9) ether carboxylic acid sodium has kept good perviousness, detersive power, compatibleness and the solvability of system, has overcome that fatty alcohol polyethenoxy ether class tensio-active agent degreasing power is strong, foam is low, the weakness bigger to skin irritation.
Each component environment-friendly high-efficiency is environmentally friendly in the present embodiment.
Examining report according to national light industry makeup articles for washing quality examination Beijing Station; The submitted sample of present embodiment is according to QB/T1224-2007 " dress material washes agent by liquid " (the preparatory Destain liquid of clothing A level) and GB/T 13171-2004 " washing powder " (WL; Total phosphorus pentoxide content) standard detection, the project conformance with standard requirement of examining.
Embodiment 8:
Present embodiment is the preferred version on embodiment 7 bases, and the quality of raw materials used (component) is identical with embodiment 1, and described is that the weight ratio of each component is in the washing composition of main raw material with the sodium alcohol ether carboxylate:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 3.0
1,2-benzisothiazole-3-ketone 0.1
Aliphatic alcohol polyethenoxy (9) ether 1.0
Polyoxyethylenated alcohol sodium sulfate 3.0
Aliphatic alcohol polyethenoxy (7) ether 20.0
Essence 0.1
Deionized water 72.8.
The used weight unit of present embodiment is a kilogram, also can be gram.
Embodiment 9:
Present embodiment is the preferred version on embodiment 7 bases, and the quality of raw materials used (component) is identical with embodiment 1, and described is that the weight ratio of each component is in the washing composition of main raw material with the sodium alcohol ether carboxylate:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 25.0
1,2-benzisothiazole-3-ketone 0.1
Aliphatic alcohol polyethenoxy (9) ether 6.0
Polyoxyethylenated alcohol sodium sulfate 4.5
Aliphatic alcohol polyethenoxy (7) ether 9.0
Essence 0.25
Deionized water 55.15.
The used weight unit of present embodiment is a kilogram, also can be gram.
Embodiment 10:
Present embodiment is the preferred version on embodiment 7 bases, and the quality of raw materials used (component) is identical with embodiment 1, and described is that the weight ratio of each component is in the washing composition of main raw material with the sodium alcohol ether carboxylate:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 9
1,2-benzisothiazole-3-ketone 0.1
Aliphatic alcohol polyethenoxy (9) ether 3.0
Polyoxyethylenated alcohol sodium sulfate 5.0
Aliphatic alcohol polyethenoxy (7) ether 16.0
Essence 0.3
Deionized water 66.6.
The used weight unit of present embodiment is a kilogram, also can be gram.
Embodiment 11:
Present embodiment is the preferred version on embodiment 7 bases, and the quality of raw materials used (component) is identical with embodiment 1, and described is that the weight ratio of each component is in the washing composition of main raw material with the sodium alcohol ether carboxylate:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 18.0
1,2-benzisothiazole-3-ketone 0.1
Aliphatic alcohol polyethenoxy (9) ether 10.0
Polyoxyethylenated alcohol sodium sulfate 8.0
Aliphatic alcohol polyethenoxy (7) ether 3.0
Essence 0.3
Deionized water 60.6.
The used weight unit of present embodiment is a kilogram, also can be gram.
Embodiment 12:
Present embodiment is the preparation method of embodiment 7～11.
A kind of is the preparation method of the washing composition of main raw material with the sodium alcohol ether carboxylate; Contain aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium, 1 in this washing composition, 2-benzisothiazole-3-ketone, aliphatic alcohol polyethenoxy (9) ether, polyoxyethylenated alcohol sodium sulfate, aliphatic alcohol polyethenoxy (7) ether, essence, deionized water; The weight ratio of each component is in this washing composition:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 3.0～25.0
1,2-benzisothiazole-3-ketone 0.1
Aliphatic alcohol polyethenoxy (9) ether 1.0～10.0
Polyoxyethylenated alcohol sodium sulfate 3.0～8.0
Aliphatic alcohol polyethenoxy (7) ether 3.0～20.0
Essence 0.1～0.3
Deionized water 25～90;
This preparing method's steps in sequence is following:
A. get 70%～85% of described deionized water weight in the said ratio and be heated to 60～80 ℃; Be preferably 70 ℃; To wherein adding described polyoxyethylenated alcohol sodium sulfate, aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (9) ether, aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium by the preparation weight ratio successively, obtain mixed solution A; This mixed solution A is formulated in changing the material still, need stir successively when adding described each component;
B. treat that described solution A temperature reduces to 35 ℃～45 ℃, be preferably 40 ℃ after, add describedly 1 successively by the preparation weight ratio, remaining described deionized water obtains mixing solutions B in 2-benzisothiazole-3-ketone, essence, the said ratio; When preparing this mixing solutions B, need stir successively when adding described each component;
C. described mixing solutions B was left standstill 60 ~ 70 minutes, be lower than 35 ℃ until described mixing solutions B temperature, promptly getting described is the washing composition of main raw material with the sodium alcohol ether carboxylate; Carry out can again.
In above-mentioned process for preparation, should note entire operation clean environment health, dustproof.
The equipment that adopts in the present embodiment is conventional equipment, all can on market, buy to obtain.
Embodiment 13:
A kind of is the washing composition of main raw material with the sodium alcohol ether carboxylate; Contain aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium, 1 in this washing composition, 2-benzisothiazole-3-ketone, polyoxyethylenated alcohol sodium sulfate, aliphatic alcohol polyethenoxy polyoxypropylene (9) ether, fatty acid alkyl amide, absolute ethyl alcohol, essence, deionized water; The weight ratio of each component is in this washing composition:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 8～20
1,2-benzisothiazole-3-ketone 0.1
Polyoxyethylenated alcohol sodium sulfate 30～40
Aliphatic alcohol polyethenoxy polyoxypropylene (9) ether 18～28
Fatty acid alkyl amide 3.0～6.5
Absolute ethyl alcohol 4～9
Essence 0.1～0.3
Deionized water 10～40.
The used weight unit of present embodiment is a kilogram, also can be gram;
Each component described in the present embodiment for being technical grade;
Each component described in the present embodiment is the conventional products of selling on the market;
In the present embodiment, described with the sodium alcohol ether carboxylate be each component in the washing composition of main raw material can be in the ratio range that provides flexible combination, do not enumerate one by one at this.
The washing composition of present embodiment can be used as the concentrated fabric washing composition and uses.
Present embodiment adopts and concentrates prescription, and dilution is used, and practices thrift packing cost and transportation cost, and is energy-saving and cost-reducing.
Polyoxyethylenated alcohol sodium sulfate in the present embodiment, aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium, aliphatic alcohol polyethenoxy (9) ether, fatty acid alkyl amide be composite to have good wetting, foaming, dispersion, emulsifying capacity, the soil removability that the system of giving is good; Can effectively remove dirts such as sweat stain that clothing is infected with, greasy dirt, dish juice.
The adding of aliphatic alcohol polyethenoxy in the present embodiment (9) ether carboxylic acid sodium has kept good perviousness, detersive power, compatibleness and the solvability of system, has overcome that fatty alcohol polyethenoxy ether class tensio-active agent degreasing power is strong, foam is low, the weakness bigger to skin irritation.
The adding of aliphatic alcohol polyethenoxy in the present embodiment (9) ether carboxylic acid sodium, absolute ethyl alcohol has improved the water-soluble of system, and system is dissolved in the water rapidly, is user-friendly to;
Each component environment-friendly high-efficiency is environmentally friendly in the present embodiment.
Examining report according to national light industry makeup articles for washing quality examination Beijing Station; The submitted sample of present embodiment is according to Q/HDLSH045-2008 " highly enriched dress material washes agent by liquid " [highly enriched washing liquid (I)] standard detection, the project conformance with standard requirement of examining.
Embodiment 14:
Present embodiment is the preferred version on embodiment 13 bases, and the quality of raw materials used (component) is identical with embodiment 1, and described is that the weight ratio of each component is in the washing composition of main raw material with the sodium alcohol ether carboxylate:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 15
1,2-benzisothiazole-3-ketone 0.1
Polyoxyethylenated alcohol sodium sulfate 30
Aliphatic alcohol polyethenoxy polyoxypropylene (9) ether 28
Fatty acid alkyl amide 6.5
Absolute ethyl alcohol 6
Essence 0.1
Deionized water 14.3.
The used weight unit of present embodiment is a kilogram, also can be gram.
Embodiment 15:
Present embodiment is the preferred version on embodiment 13 bases, and the quality of raw materials used (component) is identical with embodiment 1, and described is that the weight ratio of each component is in the washing composition of main raw material with the sodium alcohol ether carboxylate:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 20
1,2-benzisothiazole-3-ketone 0.1
Polyoxyethylenated alcohol sodium sulfate 35
Aliphatic alcohol polyethenoxy polyoxypropylene (9) ether 22
Fatty acid alkyl amide 5.0
Absolute ethyl alcohol 4
Essence 0.25
Deionized water 13.65.
The used weight unit of present embodiment is a kilogram, also can be gram.
Embodiment 16:
Present embodiment is the preferred version on embodiment 13 bases, and the quality of raw materials used (component) is identical with embodiment 1, and described is that the weight ratio of each component is in the washing composition of main raw material with the sodium alcohol ether carboxylate:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 12
1,2-benzisothiazole-3-ketone 0.1
Polyoxyethylenated alcohol sodium sulfate 38
Aliphatic alcohol polyethenoxy polyoxypropylene (9) ether 18
Fatty acid alkyl amide 3.0
Absolute ethyl alcohol 8
Essence 0.3
Deionized water 20.6.
The used weight unit of present embodiment is a kilogram, also can be gram.
Embodiment 17:
Present embodiment is the preferred version on embodiment 13 bases, and the quality of raw materials used (component) is identical with embodiment 1, and described is that the weight ratio of each component is in the washing composition of main raw material with the sodium alcohol ether carboxylate:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 8
1,2-benzisothiazole-3-ketone 0.1
Polyoxyethylenated alcohol sodium sulfate 40
Aliphatic alcohol polyethenoxy polyoxypropylene (9) ether 26
Fatty acid alkyl amide 4.5
Absolute ethyl alcohol 9
Essence 0.3
Deionized water 12.1.
The used weight unit of present embodiment is a kilogram, also can be gram.
Embodiment 18:
Present embodiment is the preparation method of embodiment 13～17.
A kind of is the preparation method of the washing composition of main raw material with the sodium alcohol ether carboxylate; Contain aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium, 1 in this washing composition, 2-benzisothiazole-3-ketone, polyoxyethylenated alcohol sodium sulfate, aliphatic alcohol polyethenoxy polyoxypropylene (9) ether, fatty acid alkyl amide, absolute ethyl alcohol, essence, deionized water; The weight ratio of each component is in this washing composition:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 8～20
1,2-benzisothiazole-3-ketone 0.1
Polyoxyethylenated alcohol sodium sulfate 30～40
Aliphatic alcohol polyethenoxy polyoxypropylene (9) ether 18～28
Fatty acid alkyl amide 3.0～6.5
Absolute ethyl alcohol 4～9
Essence 0.1～0.3
Deionized water 10～40;
This preparing method's steps in sequence is following:
A. get 70%～85% of described deionized water weight in the said ratio and be heated to 60～80 ℃; Be preferably 70 ℃; To wherein adding described polyoxyethylenated alcohol sodium sulfate, aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium, aliphatic alcohol polyethenoxy (9) ether, fatty acid alkyl amide by the preparation weight ratio successively, obtain mixed solution A; This mixed solution A is formulated in changing the material still, need stir successively when adding described each component;
B. treat that described solution A temperature reduces to 35 ℃～45 ℃, be preferably 40 ℃ after, add described absolute ethyl alcohol, 1 by the preparation weight ratio successively, remaining described deionized water obtains mixing solutions B in 2-benzisothiazole-3-ketone, essence, the said ratio; When preparing this mixing solutions B, need stir successively when adding described each component;
C. described mixing solutions B was left standstill 100 ~ 120 minutes, be lower than 35 ℃ until described mixing solutions B temperature, promptly getting described is the washing composition of main raw material with the sodium alcohol ether carboxylate; Carry out can again.
In above-mentioned process for preparation, should note entire operation clean environment health, dustproof.
The equipment that adopts in the present embodiment is conventional equipment, all can on market, buy to obtain.
Embodiment 19:
A kind of is the washing composition of main raw material with the sodium alcohol ether carboxylate; Contain aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium, 1 in this washing composition, 2-benzisothiazole-3-ketone, polyoxyethylenated alcohol sodium sulfate, cocamidopropyl propyl amide ammonium oxide, fatty acid alkyl amide, alkyl-glucoside, the two stearates of polyethylene glycol 6000, Hydrocerol A, sodium-chlor, essence, deionized water; The weight ratio of each component is in this washing composition:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 8.0～15.0
1,2-benzisothiazole-3-ketone 0.1
Polyoxyethylenated alcohol sodium sulfate 13.0～17.0
Cocamidopropyl propyl amide ammonium oxide 4.0～6.0
Fatty acid alkyl amide 0.5～5.0
Alkyl-glucoside 2.0～6.0
The two stearates 0.02～0.2 of polyethylene glycol 6000
Hydrocerol A 0.2～0.5
Sodium-chlor 1.0～3.0
Essence 0.1～0.3
Deionized water 40～75.
The used weight unit of present embodiment is a kilogram, also can be gram;
Each component described in the present embodiment for being technical grade;
Each component described in the present embodiment is the conventional products of selling on the market;
In the present embodiment, described with the sodium alcohol ether carboxylate be each component in the washing composition of main raw material can be in the ratio range that provides flexible combination, do not enumerate one by one at this.
The washing composition of present embodiment can be used as vegetables and fruits type liquid detergent and uses.
Polyoxyethylenated alcohol sodium sulfate in the present embodiment, aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium, cocamidopropyl propyl amide ammonium oxide, fatty acid alkyl amide, APG be composite to have good wetting, dispersion, emulsification, foaming power, the emulsification that the system of giving is good, soil removability; So the washing composition of present embodiment can effectively be removed the remains of pesticide on greasy dirt, dish juice and vegetable and fruit surface on the tableware.
The adding of aliphatic alcohol polyethenoxy in the present embodiment (9) ether carboxylic acid sodium has kept good perviousness, detersive power, compatibleness and the solvability of system; Overcome that fatty alcohol polyethenoxy ether class tensio-active agent degreasing power is strong, foam is low, the weakness bigger to skin irritation, cleaning is not hindered hand.
Each component environment-friendly high-efficiency is environmentally friendly in the present embodiment.
Wash the examining report at articles for use quality supervision and test center (Taiyuan) according to country; The submitted sample of present embodiment is according to GB9985-2000 and " the hand washing third quarter in 2009 is with dish washing detergent state control sampling observation scheme " standard detection, the project conformance with standard requirement of examining.
Embodiment 20:
Present embodiment is the preferred version on embodiment 13 bases, and the quality of raw materials used (component) is identical with embodiment 1, and described is that the weight ratio of each component is in the washing composition of main raw material with the sodium alcohol ether carboxylate:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 10.0
1,2-benzisothiazole-3-ketone 0.1
Polyoxyethylenated alcohol sodium sulfate 13.5
Cocamidopropyl propyl amide ammonium oxide 5.0
Fatty acid alkyl amide 5.0
Alkyl-glucoside 6.0
The two stearates 0.15 of polyethylene glycol 6000
Hydrocerol A 0.35
Sodium-chlor 2.0
Essence 0.2
Deionized water 57.7.
The used weight unit of present embodiment is a kilogram, also can be gram.
Embodiment 21:
Present embodiment is the preferred version on embodiment 13 bases, and the quality of raw materials used (component) is identical with embodiment 1, and described is that the weight ratio of each component is in the washing composition of main raw material with the sodium alcohol ether carboxylate:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 15
1,2-benzisothiazole-3-ketone 0.1
Polyoxyethylenated alcohol sodium sulfate 13.0
Cocamidopropyl propyl amide ammonium oxide 4.0
Fatty acid alkyl amide 3.0
Alkyl-glucoside 2.0
The two stearates 0.2 of polyethylene glycol 6000
Hydrocerol A 0.2
Sodium-chlor 1.5
Essence 0.1
Deionized water 60.9.
The used weight unit of present embodiment is a kilogram, also can be gram.
Embodiment 22:
Present embodiment is the preferred version on embodiment 13 bases, and the quality of raw materials used (component) is identical with embodiment 1, and described is that the weight ratio of each component is in the washing composition of main raw material with the sodium alcohol ether carboxylate:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 8
1,2-benzisothiazole-3-ketone 0.1
Polyoxyethylenated alcohol sodium sulfate 14.0
Cocamidopropyl propyl amide ammonium oxide 6.0
Fatty acid alkyl amide 2.5
Alkyl-glucoside 4.0
The two stearates 0.2 of polyethylene glycol 6000
Hydrocerol A 0.5
Sodium-chlor 1.0
Essence 0.25
Deionized water 63.45.
The used weight unit of present embodiment is a kilogram, also can be gram.
Embodiment 23:
Present embodiment is the preferred version on embodiment 13 bases, and the quality of raw materials used (component) is identical with embodiment 1, and described is that the weight ratio of each component is in the washing composition of main raw material with the sodium alcohol ether carboxylate:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 12
1,2-benzisothiazole-3-ketone 0.1
Polyoxyethylenated alcohol sodium sulfate 17.0
Cocamidopropyl propyl amide ammonium oxide 4.0
Fatty acid alkyl amide 0.5
Alkyl-glucoside 3.0
The two stearates 0.05 of polyethylene glycol 6000
Hydrocerol A 0.3
Sodium-chlor 3.0
Essence 0.3
Deionized water 59.75.
The used weight unit of present embodiment is a kilogram, also can be gram.
Embodiment 24:
Present embodiment is the preparation method of embodiment 19～23.
A kind of is the preparation method of the washing composition of main raw material with the sodium alcohol ether carboxylate; Contain aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium, 1 in this washing composition, 2-benzisothiazole-3-ketone, polyoxyethylenated alcohol sodium sulfate, cocamidopropyl propyl amide ammonium oxide, fatty acid alkyl amide, alkyl-glucoside, the two stearates of polyethylene glycol 6000, Hydrocerol A, sodium-chlor, essence, deionized water; The weight ratio of each component is in this washing composition:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 8.0～15.0
1,2-benzisothiazole-3-ketone 0.1
Polyoxyethylenated alcohol sodium sulfate 13.0～17.0
Cocamidopropyl propyl amide ammonium oxide 4.0～6.0
Fatty acid alkyl amide 0.5～5.0
Alkyl-glucoside 2.0～6.0
The two stearates 0.02～0.2 of polyethylene glycol 6000
Hydrocerol A 0.2～0.5
Sodium-chlor 1.0～3.0
Essence 0.1～0.3
Deionized water 40～75;
This preparing method's steps in sequence is following:
A. get 70%～85% of described deionized water weight in the said ratio and be heated to 60～80 ℃; Be preferably 70 ℃, obtain mixed solution A to wherein adding the two stearates of described polyoxyethylenated alcohol sodium sulfate, aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium, cocamidopropyl propyl amide ammonium oxide, fatty acid alkyl amide, alkyl-glucoside, polyethylene glycol 6000 by the preparation weight ratio successively; This mixed solution A is formulated in changing the material still, need stir successively when adding described each component;
B. after treating that described solution A temperature is reduced to 35 ℃～45 ℃, be preferably 40 ℃, add described sodium-chlor, 1 by the preparation weight ratio successively, 2-benzisothiazole-3-ketone, essence, Hydrocerol A stir, and obtain mixing solutions B; When preparing this mixing solutions B, need stir successively when adding described each component; The pH value of described solution B is 6.5～7.0;
C. described mixing solutions B was left standstill 100 ~ 120 minutes, be lower than 35 ℃ until described mixing solutions B temperature, promptly getting described is the washing composition of main raw material with the sodium alcohol ether carboxylate; Carry out can again.
In above-mentioned process for preparation, should note entire operation clean environment health, dustproof.
The equipment that adopts in the present embodiment is conventional equipment, all can on market, buy to obtain.
Claims (3)
1. one kind is the washing composition of main raw material with the sodium alcohol ether carboxylate; It is characterized in that: contain aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium, 1 in this washing composition, 2-benzisothiazole-3-ketone, polyoxyethylenated alcohol sodium sulfate, cocamidopropyl propyl amide amine oxide, fatty acid alkyl amide, alkyl-glucoside, the two stearates of polyethylene glycol 6000, Hydrocerol A, sodium-chlor, essence, deionized water; The weight ratio of each component is in this washing composition:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 8.0～15.0
1,2-benzisothiazole-3-ketone 0.1
Polyoxyethylenated alcohol sodium sulfate 13.0～17.0
Cocamidopropyl propyl amide amine oxide 4.0～6.0
Fatty acid alkyl amide 0.5～5.0
Alkyl-glucoside 2.0～6.0
The two stearates 0.02～0.2 of polyethylene glycol 6000
Hydrocerol A 0.2～0.5
Sodium-chlor 1.0～3.0
Essence 0.1～0.3
Deionized water 40～75.
2. according to claim 1 a kind of be the washing composition of main raw material with the sodium alcohol ether carboxylate, it is characterized in that: the weight ratio of each component is in this washing composition:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 10
1,2-benzisothiazole-3-ketone 0.1
Polyoxyethylenated alcohol sodium sulfate 13.5
Cocamidopropyl propyl amide amine oxide 5.0
Fatty acid alkyl amide 5.0
Alkyl-glucoside 6.0
The two stearates 0.15 of polyethylene glycol 6000
Hydrocerol A 0.35
Sodium-chlor 2.0
Essence 0.2
Deionized water 57.7.
3. according to claim 1 a kind of be the washing composition of main raw material with the sodium alcohol ether carboxylate, it is characterized in that: the weight ratio of each component is in this washing composition:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 12
1,2-benzisothiazole-3-ketone 0.1
Polyoxyethylenated alcohol sodium sulfate 17.0
Cocamidopropyl propyl amide amine oxide 4.0
Fatty acid alkyl amide 0.5
Alkyl-glucoside 3.0
The two stearates 0.05 of polyethylene glycol 6000
Hydrocerol A 0.3
Sodium-chlor 3.0
Essence 0.3
Deionized water 59.75.
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| CN108130223A (en) * | 2018-02-25 | 2018-06-08 | 杨倩倩 | A kind of ceramic tile cleaner and preparation method thereof |
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| CN102851125A (en) * | 2011-06-30 | 2013-01-02 | 达兴材料股份有限公司 | Washing agent and washing method of solar wafer |
| CN103194326B (en) * | 2013-04-28 | 2015-06-17 | 北京绿伞化学股份有限公司 | Disinfecting laundry detergent with compound cationic and anionic surfactant and preparation method of laundry detergent |
| CN104358148A (en) * | 2014-10-25 | 2015-02-18 | 合肥市安山涂层织物有限公司 | Cold-resistant flame-retardant leather penetrant and preparation method thereof |
| CN104358150A (en) * | 2014-10-29 | 2015-02-18 | 合肥市安山涂层织物有限公司 | Strong-alkali-resistant high-permeability penetrant for leather |
| CN104586645B (en) * | 2014-12-18 | 2017-10-10 | 广州市采奴化妆品有限公司 | The cleaning compositions of polyether carboxylation containing alkylol a kind of and the shampoo containing the cleaning compositions |
| CN106398896A (en) * | 2016-09-07 | 2017-02-15 | 马鞍山纽泽科技服务有限公司 | Efficient cleaning solution and preparation method thereof |
| CN108130214B (en) * | 2017-12-08 | 2020-09-01 | 武汉奥克特种化学有限公司 | Functional surfactant for cleaning and preparation method thereof |
| CN111286424A (en) * | 2018-12-06 | 2020-06-16 | 南风化工集团股份有限公司 | Super-concentrated detergent composition |
| CN111187681A (en) * | 2020-02-05 | 2020-05-22 | 长沙凯泽工程设计有限公司 | Hard water-resistant laundry detergent containing alcohol ether carboxylate |
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