CN103805368A - Color-protective laundry detergent - Google Patents
Color-protective laundry detergent Download PDFInfo
- Publication number
- CN103805368A CN103805368A CN201410072010.6A CN201410072010A CN103805368A CN 103805368 A CN103805368 A CN 103805368A CN 201410072010 A CN201410072010 A CN 201410072010A CN 103805368 A CN103805368 A CN 103805368A
- Authority
- CN
- China
- Prior art keywords
- washing liquid
- parts
- color
- agent
- thickening material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003599 detergent Substances 0.000 title abstract 3
- 238000005406 washing Methods 0.000 claims abstract description 21
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 9
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical group C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000004094 surface-active agent Substances 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 claims description 20
- 230000008719 thickening Effects 0.000 claims description 19
- 239000007788 liquid Substances 0.000 claims description 17
- 239000003223 protective agent Substances 0.000 claims description 17
- -1 sodium alkyl benzene Chemical class 0.000 claims description 10
- 239000012752 auxiliary agent Substances 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- PMPJQLCPEQFEJW-HPKCLRQXSA-L disodium;2-[(e)-2-[4-[4-[(e)-2-(2-sulfonatophenyl)ethenyl]phenyl]phenyl]ethenyl]benzenesulfonate Chemical group [Na+].[Na+].[O-]S(=O)(=O)C1=CC=CC=C1\C=C\C1=CC=C(C=2C=CC(\C=C\C=3C(=CC=CC=3)S([O-])(=O)=O)=CC=2)C=C1 PMPJQLCPEQFEJW-HPKCLRQXSA-L 0.000 claims description 6
- MGIYRDNGCNKGJU-UHFFFAOYSA-N isothiazolinone Chemical compound O=C1C=CSN1 MGIYRDNGCNKGJU-UHFFFAOYSA-N 0.000 claims description 6
- 239000000049 pigment Substances 0.000 claims description 6
- 229940077388 benzenesulfonate Drugs 0.000 claims description 4
- 235000010418 carrageenan Nutrition 0.000 claims description 4
- 229920001525 carrageenan Polymers 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- 229930182470 glycoside Natural products 0.000 claims description 4
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 4
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 230000002087 whitening effect Effects 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 150000004665 fatty acids Chemical class 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 239000011591 potassium Substances 0.000 claims description 3
- 239000000344 soap Substances 0.000 claims description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 3
- 235000011152 sodium sulphate Nutrition 0.000 claims description 3
- 235000010493 xanthan gum Nutrition 0.000 claims description 3
- 239000000230 xanthan gum Substances 0.000 claims description 3
- 229920001285 xanthan gum Polymers 0.000 claims description 3
- 229940082509 xanthan gum Drugs 0.000 claims description 3
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 2
- 150000001450 anions Chemical class 0.000 claims description 2
- 235000010413 sodium alginate Nutrition 0.000 claims description 2
- 239000000661 sodium alginate Substances 0.000 claims description 2
- 229940005550 sodium alginate Drugs 0.000 claims description 2
- 239000003643 water by type Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 20
- 239000008367 deionised water Substances 0.000 abstract description 10
- 229910021641 deionized water Inorganic materials 0.000 abstract description 10
- 239000004744 fabric Substances 0.000 abstract description 7
- 239000000834 fixative Substances 0.000 abstract 3
- 239000000654 additive Substances 0.000 abstract 1
- 238000004140 cleaning Methods 0.000 abstract 1
- 239000002736 nonionic surfactant Substances 0.000 abstract 1
- 239000002562 thickening agent Substances 0.000 abstract 1
- 229920006163 vinyl copolymer Polymers 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 30
- 239000013543 active substance Substances 0.000 description 14
- 239000000975 dye Substances 0.000 description 12
- 238000002360 preparation method Methods 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000005012 migration Effects 0.000 description 3
- 238000013508 migration Methods 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 2
- 230000000536 complexating effect Effects 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention discloses a color-protective laundry detergent which comprises the following components in parts by weight: 0.5-6 parts of color fixative, 6-31 parts of anionic surfactant, 12-43 parts of nonionic surfactant, 0.06-1 part of thickening agent and other additives, and 40-60 parts of deionized water, wherein the color fixative is 1-vinyl pyrrolidone or a 1-vinyl copolymer. As the surfactant and the color fixative are compounded to enhance the efficacy, the color-protective laundry detergent disclosed by the invention can be used for cleaning fabrics as well as lowering or reducing appearance and color losses caused in a washing process.
Description
Technical field
The invention belongs to daily-use chemical industry technical field, be specifically related to one and protect look washing liquid.
Background technology
Because the main raw material of washing liquid is AES and AEO9, due to its very strong emulsification and seepage force, cause that dye molecule is de-to be lost, make people in the time of the dark clothing of washing usually for fade with colour contamination worries endlessly.Current washing industry adopts colour protecting agent and tensio-active agent to arrange in pairs or groups to strengthen the colour-preserving function of washing liquid more, colour protecting agent has non-ionic type and cationic 2 classes, non-ionic type colour protecting agent is mainly by forming film at fabric face, can reduce the de-mistake of dye molecule on colored fabric, and white fabrics is infected with the amount of material, this fixation and anti-colour contamination performance to clothing has better effect.Cationic colour protecting agent by with the complexing of anionic dyestuff, thereby the absorption fastness of dye molecule on colored fabric is increased, also can in complex solution, take off mistake dye molecule, thereby increase fixation and the anti-dye migration performance of the water-insoluble raising washing liquid of dye molecule.Other also have part inorganic salts laking agent, also can improve the degree of fixation of dyestuff, have the chromatic effect of protecting.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of more washing liquid of fixation of look that protects.
Technical scheme provided by the invention is to provide one and protects look washing liquid, comprises the component of following weight part: 0.5～6 part of colour protecting agent, 6～31 parts of anion surfactants, 12～43 parts of nonionogenic tensides, thickening material and 0.06～1 part of other auxiliary agent, 40～60 parts of deionized waters;
Described colour protecting agent is 1-vinyl pyrrolidone or 1-ethylenic copolymer; Colour protecting agent of the present invention has the ability with the efficient complexing of tensio-active agent, the complex compound poorly water-soluble forming on colored fabric, avoid being disperseed by tensio-active agent institute solubilising, reduce the mechanical eluting rate of dyestuff, in addition, due to the de-complex compound poorly water-soluble that loses dye molecule and colour protecting agent formation in solution, cause precipitation, reduce dye migration to the probability on other fabrics, simultaneously colour protecting agent distinctive with the low adsorptive power of vegetable fibre, effectively reduce the colour contamination phenomenon of similar positively charged ion colour protecting agent, there is good anti-dye migration effect.
Described anion surfactant is sodium alkyl benzene sulfonate, fatty acid potassium soap or polyoxyethylenated alcohol sodium sulfate;
Described nonionogenic tenside is alkyl glycoside, fatty alcohol-polyoxyethylene ether.
Above-mentioned thickening material is Xylo-Mucine, sodium alginate, xanthan gum or carrageenin.
Other above-mentioned auxiliary agents are selected from one or more in whitening agent, sanitas, pigment and essence.
Foregoing preservatives is isothiazolinone.
Above-mentioned whitening agent is fluorescent brightener CBS-X.
Preparation method:
1) removing 30～40% of ionized water total amount joins in stirring tank, be heated to 70～80 ℃, successively add while stirring anion surfactant, nonionogenic tenside and colour protecting agent, after dissolving, stir 0.5～1h and make it to mix, obtain tensio-active agent stoste;
2) remove ionized water total amount 30～40% and join in stirring tank, be heated to 50～60 ℃, add while stirring thickening material, continue stirring until solution homogeneous transparent, obtain thickening material stoste;
3) tensio-active agent stoste and thickening material stoste are mixed, supply the deionized water of surplus, add other auxiliary agents, after all dissolving, then regulate pH to 6.0～8.0, be and protect look washing liquid.
Compared with prior art, the present invention has following beneficial effect:
1) the present invention, by compound to tensio-active agent and laking agent, synergy, can reduce or reduce the outward appearance and the colour loss that produce due to washing process in clean textile.
2) the present invention is take the anion surfactant with good decontamination, emulsification and foaming power as main, and composite with nonionogenic tenside gentle, low stimulation, soil removability is strong, is easy to rinsing, and it is neutral that pH value is, and gentleness is non-stimulated, does not hinder hand.
Embodiment
The present invention is further elaborated for following specific embodiment, but not as a limitation of the invention.
Embodiment 1
Formula: 1-vinyl pyrrolidone 0.5kg, sodium alkyl benzene sulfonate 6kg, alkyl glycoside 12kg, Xylo-Mucine and fluorescent brightener CBS-X, isothiazolinone, pigment and essence 0.06kg, deionized water 40kg;
Preparation method:
1) remove 30% of ionized water total amount and join in stirring tank, be heated to 70 ℃, successively add while stirring anion surfactant, nonionogenic tenside and colour protecting agent, after dissolving, stir 0.5～1h and make it to mix, obtain tensio-active agent stoste;
2) remove ionized water total amount 30% and join in stirring tank, be heated to 50 ℃, add while stirring thickening material, continue stirring until solution homogeneous transparent, obtain thickening material stoste;
3) tensio-active agent stoste and thickening material stoste are mixed, supply the deionized water of surplus, add other auxiliary agents, after all dissolving, then regulate pH to 6.0, be and protect look washing liquid.
Embodiment 2
Formula: 1-ethylenic copolymer 6kg, fatty acid potassium soap 31kg, fatty alcohol-polyoxyethylene ether 43kg, xanthan gum and fluorescent brightener CBS-X, isothiazolinone, pigment and essence 1kg, deionized water 60kg;
Preparation method:
1) remove 40% of ionized water total amount and join in stirring tank, be heated to 80 ℃, successively add while stirring anion surfactant, nonionogenic tenside and colour protecting agent, after dissolving, stir 1h and make it to mix, obtain tensio-active agent stoste;
2) remove ionized water total amount 40% and join in stirring tank, be heated to 60 ℃, add while stirring thickening material, continue stirring until solution homogeneous transparent, obtain thickening material stoste;
3) tensio-active agent stoste and thickening material stoste are mixed, supply the deionized water of surplus, add other auxiliary agents, after all dissolving, then regulate pH to 8.0, be and protect look washing liquid.
Embodiment 3
Formula: 1-vinyl pyrrolidone 3kg, polyoxyethylenated alcohol sodium sulfate 18kg, alkyl glycoside 23kg, carrageenin and fluorescent brightener CBS-X, isothiazolinone, pigment and essence 0.2kg, deionized water 50kg;
Preparation method:
1) remove 33% of ionized water total amount and join in stirring tank, be heated to 76 ℃, successively add while stirring anion surfactant, nonionogenic tenside and colour protecting agent, after dissolving, stir 0.75h and make it to mix, obtain tensio-active agent stoste;
2) remove ionized water total amount 33% and join in stirring tank, be heated to 55 ℃, add while stirring thickening material, continue stirring until solution homogeneous transparent, obtain thickening material stoste;
3) tensio-active agent stoste and thickening material stoste are mixed, supply the deionized water of surplus, add other auxiliary agents, after all dissolving, then regulate pH to 7.0, be and protect look washing liquid.
Embodiment 4
Formula: 1-ethylenic copolymer 6kg, sodium alkyl benzene sulfonate 6kg, fatty alcohol-polyoxyethylene ether 43kg, carrageenin and fluorescent brightener CBS-X, isothiazolinone, pigment and essence 0.06kg, deionized water 60kg;
Preparation method:
1) remove 30% of ionized water total amount and join in stirring tank, be heated to 80 ℃, successively add while stirring anion surfactant, nonionogenic tenside and colour protecting agent, after dissolving, stir 0.5h and make it to mix, obtain tensio-active agent stoste;
2) remove ionized water total amount 40% and join in stirring tank, be heated to 50 ℃, add while stirring thickening material, continue stirring until solution homogeneous transparent, obtain thickening material stoste;
3) tensio-active agent stoste and thickening material stoste are mixed, supply the deionized water of surplus, add other auxiliary agents, after all dissolving, then regulate pH to 8.0, be and protect look washing liquid.
Claims (5)
1. protect a look washing liquid, it is characterized in that: the component that comprises following weight part: 0.5～6 part of colour protecting agent, 6～31 parts of anion surfactants, 12～43 parts of nonionogenic tensides, thickening material and 0.06～1 part of other auxiliary agent, 40～60 parts of deionized waters;
Described colour protecting agent is 1-vinyl pyrrolidone or 1-ethylenic copolymer;
Described anion surfactant is sodium alkyl benzene sulfonate, fatty acid potassium soap or polyoxyethylenated alcohol sodium sulfate;
Described nonionogenic tenside is alkyl glycoside, fatty alcohol-polyoxyethylene ether.
2. the look washing liquid that protects according to claim 1, is characterized in that: described thickening material is Xylo-Mucine, sodium alginate, xanthan gum or carrageenin.
3. the look washing liquid that protects according to claim 1, is characterized in that: other described auxiliary agents are selected from one or more in whitening agent, sanitas, pigment and essence.
4. the look washing liquid that protects according to claim 3, is characterized in that: described sanitas is isothiazolinone.
5. the look washing liquid that protects according to claim 3, is characterized in that: described whitening agent is fluorescent brightener CBS-X.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410072010.6A CN103805368A (en) | 2014-02-28 | 2014-02-28 | Color-protective laundry detergent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410072010.6A CN103805368A (en) | 2014-02-28 | 2014-02-28 | Color-protective laundry detergent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103805368A true CN103805368A (en) | 2014-05-21 |
Family
ID=50702760
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410072010.6A Pending CN103805368A (en) | 2014-02-28 | 2014-02-28 | Color-protective laundry detergent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103805368A (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103966033A (en) * | 2014-05-30 | 2014-08-06 | 于文 | Color-protecting laundry detergent and preparation method thereof |
| CN104629928A (en) * | 2015-03-10 | 2015-05-20 | 偃师然合生物材料有限公司 | Gentle and safe laundry detergent and preparation method thereof |
| CN105586165A (en) * | 2016-01-29 | 2016-05-18 | 广州康钰生物科技有限公司 | Laundry sheet with color protecting function and preparation method thereof |
| CN105907490A (en) * | 2016-05-17 | 2016-08-31 | 河南工程学院 | Acidic colour-protecting detergent composition |
| CN106675825A (en) * | 2016-12-24 | 2017-05-17 | 叶宗瑞 | Fabric washing agent having color protection function and preparation method thereof |
| CN107083284A (en) * | 2017-06-24 | 2017-08-22 | 徐同强 | A kind of liquid detergent |
| CN108130199A (en) * | 2017-12-25 | 2018-06-08 | 上海和黄白猫有限公司 | Efficient color protection liquid detergent and preparation method thereof |
| CN108505331A (en) * | 2018-04-04 | 2018-09-07 | 安徽恒益纺织科技有限公司 | A kind of inorganic agent for preventing children's pure cotton clothes from fading |
| CN108570358A (en) * | 2017-09-11 | 2018-09-25 | 无锡市科姆斯化工科技有限公司 | A kind of liquid detergent containing essential oil |
| CN108659980A (en) * | 2018-07-01 | 2018-10-16 | 田波 | A kind of without phosphorus color protection liquid detergent |
| CN109112007A (en) * | 2018-09-30 | 2019-01-01 | 北京洛娃日化有限公司 | A kind of liquid detergent and preparation method |
| CN109749875A (en) * | 2017-11-01 | 2019-05-14 | 鼎汉泰捷科技（武汉）有限公司 | A kind of novel liquid laundry detergent formula and preparation method |
| CN115368981A (en) * | 2022-09-21 | 2022-11-22 | 云南水星生物科技有限公司 | Biological color fixative and preparation method and application thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1167505A1 (en) * | 1999-05-12 | 2002-01-02 | National Starch and Chemical Investment Holding Corporation | Controlled release bleach thickening composition having enhanced viscosity stability at elevated temperatures |
| CN101798552A (en) * | 2010-05-07 | 2010-08-11 | 北京绿伞化学股份有限公司 | Fabric detergent with colour-preserving function and preparation method thereof |
| CN102304437A (en) * | 2011-08-03 | 2012-01-04 | 安徽师范大学 | High-efficiency liquid-phase washing agent with bleaching effect for colored fabric |
| CN102643724A (en) * | 2012-04-13 | 2012-08-22 | 江南大学 | Liquid laundry detergent containing tea saponin and method for preparing liquid laundry detergent |
| CN102643721A (en) * | 2012-03-30 | 2012-08-22 | 中国日用化学工业研究院 | Mild safe liquid laundry detergent and preparing method thereof |
-
2014
- 2014-02-28 CN CN201410072010.6A patent/CN103805368A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1167505A1 (en) * | 1999-05-12 | 2002-01-02 | National Starch and Chemical Investment Holding Corporation | Controlled release bleach thickening composition having enhanced viscosity stability at elevated temperatures |
| CN101798552A (en) * | 2010-05-07 | 2010-08-11 | 北京绿伞化学股份有限公司 | Fabric detergent with colour-preserving function and preparation method thereof |
| CN102304437A (en) * | 2011-08-03 | 2012-01-04 | 安徽师范大学 | High-efficiency liquid-phase washing agent with bleaching effect for colored fabric |
| CN102643721A (en) * | 2012-03-30 | 2012-08-22 | 中国日用化学工业研究院 | Mild safe liquid laundry detergent and preparing method thereof |
| CN102643724A (en) * | 2012-04-13 | 2012-08-22 | 江南大学 | Liquid laundry detergent containing tea saponin and method for preparing liquid laundry detergent |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103966033A (en) * | 2014-05-30 | 2014-08-06 | 于文 | Color-protecting laundry detergent and preparation method thereof |
| CN104629928A (en) * | 2015-03-10 | 2015-05-20 | 偃师然合生物材料有限公司 | Gentle and safe laundry detergent and preparation method thereof |
| CN105586165A (en) * | 2016-01-29 | 2016-05-18 | 广州康钰生物科技有限公司 | Laundry sheet with color protecting function and preparation method thereof |
| CN105907490A (en) * | 2016-05-17 | 2016-08-31 | 河南工程学院 | Acidic colour-protecting detergent composition |
| CN106675825A (en) * | 2016-12-24 | 2017-05-17 | 叶宗瑞 | Fabric washing agent having color protection function and preparation method thereof |
| CN107083284A (en) * | 2017-06-24 | 2017-08-22 | 徐同强 | A kind of liquid detergent |
| CN108570358A (en) * | 2017-09-11 | 2018-09-25 | 无锡市科姆斯化工科技有限公司 | A kind of liquid detergent containing essential oil |
| CN109749875A (en) * | 2017-11-01 | 2019-05-14 | 鼎汉泰捷科技（武汉）有限公司 | A kind of novel liquid laundry detergent formula and preparation method |
| CN108130199A (en) * | 2017-12-25 | 2018-06-08 | 上海和黄白猫有限公司 | Efficient color protection liquid detergent and preparation method thereof |
| CN108505331A (en) * | 2018-04-04 | 2018-09-07 | 安徽恒益纺织科技有限公司 | A kind of inorganic agent for preventing children's pure cotton clothes from fading |
| CN108659980A (en) * | 2018-07-01 | 2018-10-16 | 田波 | A kind of without phosphorus color protection liquid detergent |
| CN109112007A (en) * | 2018-09-30 | 2019-01-01 | 北京洛娃日化有限公司 | A kind of liquid detergent and preparation method |
| CN115368981A (en) * | 2022-09-21 | 2022-11-22 | 云南水星生物科技有限公司 | Biological color fixative and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103805368A (en) | Color-protective laundry detergent | |
| CN102051277B (en) | Multifunctional bamboo vinegar laundry liquid | |
| CN102643724B (en) | A kind of laundry detergent containing tea saponin and preparation method thereof | |
| CN107955743B (en) | Efficient laundry detergent and preparation method thereof | |
| CN103849484A (en) | Bacteriostatic and anti-mite plant laundry detergent | |
| CN109112007A (en) | A kind of liquid detergent and preparation method | |
| CN103820240A (en) | Laundry detergent used for washing underwear | |
| CN105002022A (en) | Low-temperature deoiling scouring agent and preparation method thereof | |
| CN105239420A (en) | Cold pad batch dyeing method of non-pretreated cotton knitted fabric | |
| CN108130199A (en) | Efficient color protection liquid detergent and preparation method thereof | |
| CN107385976A (en) | A kind of high-performance environment-friendly resist printing ferment powder washed for cowboy's ferment and preparation method thereof | |
| CN111057624A (en) | Sterilization, color protection and color cross-linking prevention concentrated laundry detergent and preparation method thereof | |
| CN103233377A (en) | Staining back-preventive agent of jean clothes, and preparation method thereof | |
| CN102535156A (en) | Refining agent for color cotton | |
| CN104152291A (en) | Dye-resistant laundry detergent and preparation method thereof | |
| CN103046398A (en) | Printing process of silk-like terylene | |
| CN101161924A (en) | Indigo reduction deep dyeing promoter | |
| CN103103026A (en) | Anti-stain detergent of textile | |
| CN111534388A (en) | Low-foam easy-to-bleach sterilization laundry detergent and preparation method thereof | |
| CN103834494A (en) | Special laundry detergent for infants and young children | |
| CN104109590A (en) | Composite laccase soaping agent and cotton fabric finishing method using the same | |
| CN105001671A (en) | Compound brightening agent and washing agent composition containing compound brightening agent | |
| CN103820239A (en) | Mild safe laundry detergent | |
| CN104818614A (en) | Novel penetrating agent for textile pretreatment | |
| CN106929178A (en) | A kind of acid scouring agent and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20140521 |