CN106929178A - A kind of acid scouring agent and preparation method thereof - Google Patents
A kind of acid scouring agent and preparation method thereof Download PDFInfo
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- CN106929178A CN106929178A CN201710143781.3A CN201710143781A CN106929178A CN 106929178 A CN106929178 A CN 106929178A CN 201710143781 A CN201710143781 A CN 201710143781A CN 106929178 A CN106929178 A CN 106929178A
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2082—Polycarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/06—After-treatment with organic compounds containing nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/10—After-treatment with compounds containing metal
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/30—Sulfonation products derived from lignin
Abstract
The present invention relates to dyeing assistant field, there is provided a kind of acid scouring agent and preparation method thereof, the soaping agent water consumption that solves prior art is big, containing APEO is high, nonbiodegradability defect.Component A and B component including separating packaging, the component A include each raw material of following weight portion:15~20 parts of acrylic acid, 20~30 parts of maleic acid, 15~20 parts of pyrrolidones, 5~10 parts of sodium lignin sulfonate, 5~10 parts of docosyl sodium sulphate, 200~300 parts of deionized water, 15~20 parts of N cocoyl L glutamic acid, 10~20 parts of soapberry extract;The B component is:10~30 parts of Microencapsulated Slow alkalescent auxiliary agent.
Description
Technical field
The present invention relates to dyeing assistant field, more particularly to a kind of acid scouring agent and preparation method thereof.
Background technology
Dyeing is the important composition one's duty of textile industry, is again the industry that energy consumption is higher, quantity of wastewater effluent is larger.Print
Dye industry is carried out energy-saving and emission-reduction and is worked, and except researching and developing efficient, water saving, energy-saving equipment, develops simultaneously popularization and application energy-conservation, the reality economized on water
It is most effective method at this stage using the dye material of efficient, environmentally friendly, water saving, energy-conservation with outside new technology, and less investment,
Instant effect.Typically using reactive dye, such dyestuff has the advantages that chromatogram is complete bright in colour to cellulose dyeing, but
Can be hydrolyzed while upper dye set, hydrolised dye absorption forms loose colour on fiber, has a strong impact on the color fastness of product, because
Soaping after this reactive dyeing is extremely important.The soaping agent of production mostly used the compound of surfactant in the past, such as
Patent publication No. be described in CN1834216A " a kind of textile printing and dyeing is soaped with high-efficiency environment friendly soaping agent composite and its preparation side
Method ".Being typically contained in these surfactants has the APES (abbreviation APEO) of potential hazard to environment,
Or to environmentally undesirable phosphate (salt).APEO is larger to the toxicity of aquatic organism, biological degradability is slow, swash with similar female
The effect of element, can the normal hormone secretion of harmful to human, i.e., described " female effect ".America and Europe is on textile and clothing
APEO carried out strict restriction:It is required that must not exceed 30ppm.Therefore the APEO contents on textile have caused each processing factory
The great attention of business, requires that various auxiliary agents are free of APEO one after another.Phosphate (salt) class surfactant can then greatly improve sewage
Chemical oxygen consumption (COC) (COD), after particularly Taihu Lake Blue Algae Event occurs, country is carried out sternly to the COD value of printing and dyeing mill's sewage discharge
Lattice are controlled.Therefore the developing direction of soaping agent is that biological degradability is good without APEO, without " phosphorus ".Polymer copolymerization in recent years
The anti-staining detergent that thing type soaping agent has certain research and development, such as Wang Xiangrong, Pu Zongyao et al. research (is disclosed see patent
Number CN101314922A, CN101531956A), the polymer copolymerization that such soaping agent is used is sodium-salt type, and this is as neutrality
Or alkalescent, do not possess the ability for neutralizing residual alkali on cloth cover.Cellulose fibre is after reactive dyeing according to such washing
Agent is soaped, must also by washing-cross (vinegar) acid-wash-soap-(heat) washing-wash-excessively soft etc. operation, one ton of fabric
For rear road soap washing water consumption two up to more than 70 tons.
The content of the invention
Therefore, for above content, the present invention provides a kind of acid scouring agent and preparation method thereof, solves prior art
Soaping agent water consumption is big, containing APEO is high, nonbiodegradability defect.
To reach above-mentioned purpose, the present invention is achieved by the following technical solutions:A kind of acid scouring agent, including separate
The component A and B component of packaging, the component A include each raw material of following weight portion:
15~20 parts of acrylic acid
20~30 parts of maleic acid
15~20 parts of pyrrolidones
5~10 parts of sodium lignin sulfonate
5~10 parts of docosyl sodium sulphate
200~300 parts of deionized water
N- cocoyls -15~20 parts of Pidolidone
10~20 parts of soapberry extract;
The B component is:
10~30 parts of Microencapsulated Slow alkalescent auxiliary agent.
Further improving is:The Microencapsulated Slow alkalescent auxiliary agent by:Solid potassium hydroxide particle, calcium chloride are water-soluble
Liquid is 0.1~0.2 by weight:1 composition.
Further improving is:The particle diameter of the solid potassium hydroxide particle is 50~200 microns.
Further improving is:The component A includes each raw material of following weight portion:
17~20 parts of acrylic acid
25~30 parts of maleic acid
17~20 parts of pyrrolidones
7~10 parts of sodium lignin sulfonate
7~10 parts of docosyl sodium sulphate
250~300 parts of deionized water
N- cocoyls -17~20 parts of Pidolidone
15~20 parts of soapberry extract.
Further improving is:The Microencapsulated Slow alkalescent auxiliary agent is 20~30 parts.
A kind of preparation method of acid scouring agent, including component A and B component preparation, the preparation method of the component A
For:10 parts of acrylic acid, 20~30 parts of maleic acid, 15~20 parts of pyrrolidones, deionized water 200~300 are added in a kettle.
Part, 80~85 DEG C are to slowly warm up to, the temperature is kept, then it is slowly added dropwise 5~10 parts of sodium lignin sulfonate, docosyl sulphur
5~10 parts of sour sodium, N- cocoyls -15~20 parts of Pidolidone, 10~20 parts of soapberry extract and remaining acrylic acid,
After completion of dropping, 3~4h is incubated at 80~85 DEG C, is cooled to room temperature.
Further improving is:The preparation method of the B component is:Solid potassium hydroxide particle is hanged in nitrogen atmosphere
Float in fluid bed, calcium chloride water is sprayed at the top of fluid bed, be then dried, be cooled to room temperature, that is, obtain micro- glue
Capsule alkalescent auxiliary agent.
By using preceding solution, the beneficial effects of the invention are as follows:Acid scouring agent of the invention, contains in component
Pyrrolidones, pyrrolidones contains lactam structure, can be with the organo-functional group in dye molecule, such as hydroxyl, amino, carboxyl knot
Close, improve the binding ability of soap agent molecule and dye molecule, effectively prevent hydrolised dye from returning and be stained with above dye thing, greatly improve
The releasing performance of acid scouring agent.Further, since the aobvious stronger acidity of soaping agent, can with dyeing after remain in alkali on cloth
Property material neutralized, can effectively remove loose colour, docosyl sodium sulphate is nonionic surfactant, sodium lignin sulfonate
It is anion surfactant, nonionic surfactant is compounded with anion surfactant, with preferably coordination
Effect, and docosyl sodium sulphate is all very stable to weak acid, alkali, hard water, this is that traditional dodecyl sodium sulfate does not have
Standby, using above-mentioned compound surfactant, with preferably absorption loose colour ability and biological degradability.
Specific embodiment
Describe embodiments of the present invention in detail below with reference to specific embodiment, how skill is applied to the present invention whereby
Art means solve technical problem, and reach the implementation process of technique effect and can fully understand and implement according to this.
If not specializing, the conventional hand that the technological means employed in embodiment is well known to those skilled in the art
Section, the reagent and product for being used also are available commercial.The source of agents useful for same, trade name and it is necessary to list it
Constituent person, indicates when occurring first.
Embodiment one
A kind of acid scouring agent, including the component A and B component of packaging are separated, the component A includes each of following weight portion
Raw material:
15 parts of acrylic acid
20 parts of maleic acid
15 parts of pyrrolidones
5 parts of sodium lignin sulfonate
5 parts of docosyl sodium sulphate
200 parts of deionized water
N- cocoyls -15 parts of Pidolidone
10 parts of soapberry extract;
The B component is:
1.2 parts of solid potassium hydroxide particle
Calcium chloride water is by weight for 8.8 parts.
The particle diameter of the solid potassium hydroxide particle is 50 microns.
A kind of preparation method of acid scouring agent, including component A and B component preparation, the preparation method of the component A
For:10 parts of acrylic acid, 20 parts of maleic acid, 15 parts of pyrrolidones, 200 parts of deionized water are added in a kettle., are to slowly warm up to
80 DEG C, the temperature is kept, be then slowly added dropwise 5 parts of sodium lignin sulfonate, 5 parts of docosyl sodium sulphate, N- cocoyls-L-
15 parts of glutamic acid, 10 parts of soapberry extract and remaining acrylic acid, after completion of dropping, are incubated 3h, then cool down at 80 DEG C
To room temperature.
The preparation method of the B component is:Solid potassium hydroxide particle is suspended in fluid bed in nitrogen atmosphere,
Fluid bed top sprays into calcium chloride water, is then dried, and is cooled to room temperature, that is, obtain microcapsules alkalescent auxiliary agent.
Embodiment two
A kind of acid scouring agent, including the component A and B component of packaging are separated, the component A includes each of following weight portion
Raw material:
17 parts of acrylic acid
25 parts of maleic acid
17 parts of pyrrolidones
7 parts of sodium lignin sulfonate
7 parts of docosyl sodium sulphate
250 parts of deionized water
N- cocoyls -17 parts of Pidolidone
15 parts of soapberry extract.
4 parts of solid potassium hydroxide particle
16 parts of calcium chloride water;
The particle diameter of the solid potassium hydroxide particle is 100 microns.
A kind of preparation method of acid scouring agent, including component A and B component preparation, the preparation method of the component A
For:10 parts of acrylic acid, 25 parts of maleic acid, 17 parts of pyrrolidones, 250 parts of deionized water are added in a kettle., are to slowly warm up to
83 DEG C, the temperature is kept, be then slowly added dropwise 7 parts of sodium lignin sulfonate, 7 parts of docosyl sodium sulphate, N- cocoyls-L-
17 parts of glutamic acid, 15 parts of soapberry extract and remaining acrylic acid, after completion of dropping, are incubated 3h, then cool down at 83 DEG C
To room temperature.
The preparation method of the B component is:Solid potassium hydroxide particle is suspended in fluid bed in nitrogen atmosphere,
Fluid bed top sprays into calcium chloride water, is then dried, and is cooled to room temperature, that is, obtain microcapsules alkalescent auxiliary agent.
Embodiment three
A kind of acid scouring agent, including the component A and B component of packaging are separated, the component A includes each of following weight portion
Raw material:
20 parts of acrylic acid
30 parts of maleic acid
20 parts of pyrrolidones
10 parts of sodium lignin sulfonate
10 parts of docosyl sodium sulphate
300 parts of deionized water
N- cocoyls -20 parts of Pidolidone
20 parts of soapberry extract;
The B component is:
5 parts of solid potassium hydroxide particle
25 parts of calcium chloride water
The particle diameter of the solid potassium hydroxide particle is 200 microns.
A kind of preparation method of acid scouring agent, including component A and B component preparation, the preparation method of the component A
For:10 parts of acrylic acid, 30 parts of maleic acid, 20 parts of pyrrolidones, 300 parts of deionized water are added in a kettle., are to slowly warm up to
85 DEG C, keep the temperature, be then slowly added dropwise 10 parts of sodium lignin sulfonate, 10 parts of docosyl sodium sulphate, N- cocoyls-
20 parts of Pidolidone, 20 parts of soapberry extract and remaining acrylic acid, after completion of dropping, are incubated 4h at 85 DEG C, then cold
But to room temperature.
The preparation method of the B component is:Solid potassium hydroxide particle is suspended in fluid bed in nitrogen atmosphere,
Fluid bed top sprays into calcium chloride water, is then dried, and is cooled to room temperature, that is, obtain microcapsules alkalescent auxiliary agent.
In the present invention, each raw material of the component A is capable of achieving the purpose of the present invention in following parameter area:
15~20 parts of acrylic acid, 20~30 parts of maleic acid, 15~20 parts of pyrrolidones, 5~10 parts of sodium lignin sulfonate, two
5~10 parts of lauryl sodium sulfate, 200~300 parts of deionized water, N- cocoyls -15~20 parts of Pidolidone, soapberry are carried
Take 10~20 parts of liquid;The B component is:10~30 parts of Microencapsulated Slow alkalescent auxiliary agent.The Microencapsulated Slow alkalescent is helped
Agent by:Solid potassium hydroxide particle, calcium chloride water are 0.1~0.2 by weight:1 composition.The solid potassium hydroxide
The particle diameter of grain is 50~200 microns.The purpose of the present invention is capable of achieving in above parameter area.
Described above, only using the embodiment of this origination techniques content, any those skilled in the art are with this wound
Make done modification, change, all belong to the scope of the claims of this creation opinion, and be not limited to those disclosed embodiments.
Claims (7)
1. a kind of acid scouring agent, it is characterised in that component A and B component including separating packaging, the component A includes following
Each raw material of weight portion:
15~20 parts of acrylic acid
20~30 parts of maleic acid
15~20 parts of pyrrolidones
5~10 parts of sodium lignin sulfonate
5~10 parts of docosyl sodium sulphate
200~300 parts of deionized water
N- cocoyls -15~20 parts of Pidolidone
10~20 parts of soapberry extract;
The B component is:
10~30 parts of Microencapsulated Slow alkalescent auxiliary agent.
2. a kind of acid scouring agent according to claim 1, it is characterised in that:The Microencapsulated Slow alkalescent auxiliary agent
By:Solid potassium hydroxide particle, calcium chloride water are 0.1~0.2 by weight:1 composition.
3. a kind of acid scouring agent according to claim 2, it is characterised in that:The particle diameter of the solid potassium hydroxide particle
It is 50~200 microns.
4. a kind of acid scouring agent according to claim 1, it is characterised in that:The component A includes following weight portion
Each raw material:
17~20 parts of acrylic acid
25~30 parts of maleic acid
17~20 parts of pyrrolidones
7~10 parts of sodium lignin sulfonate
7~10 parts of docosyl sodium sulphate
250~300 parts of deionized water
N- cocoyls -17~20 parts of Pidolidone
15~20 parts of soapberry extract.
5. a kind of acid scouring agent according to claim 4, it is characterised in that:The Microencapsulated Slow alkalescent auxiliary agent is
20~30 parts.
6. a kind of preparation method of acid scouring agent, it is characterised in that:Preparation including component A and B component, the component A
Preparation method is:10 parts of acrylic acid, 20~30 parts of maleic acid, 15~20 parts of pyrrolidones, deionized water are added in a kettle.
200~300 parts, 80~85 DEG C are to slowly warm up to, keep the temperature, be then slowly added dropwise 5~10 parts of sodium lignin sulfonate, 20
5~10 parts of sodium dialkyl sulfate, N- cocoyls -15~20 parts of Pidolidone, 10~20 parts of soapberry extract and residue
Acrylic acid, after completion of dropping, at 80~85 DEG C be incubated 3~4h, be cooled to room temperature.
7. the preparation method of a kind of acid scouring agent according to claim 6, it is characterised in that:The preparation of the B component
Method is:Solid potassium hydroxide particle is suspended in fluid bed in nitrogen atmosphere, calcium chloride water is sprayed at the top of fluid bed
Solution, is then dried, and is cooled to room temperature, that is, obtain microcapsules alkalescent auxiliary agent.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110499218A (en) * | 2019-09-17 | 2019-11-26 | 黄河三角洲京博化工研究院有限公司 | A kind of efficient and environment-friendly type acid scouring agent and preparation method thereof |
CN114164053A (en) * | 2021-12-03 | 2022-03-11 | 广东三兴高新材料科技有限公司 | Acidic soaping agent |
CN114232365A (en) * | 2021-12-20 | 2022-03-25 | 广东三兴高新材料科技有限公司 | Method for preparing acidic soaping agent |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN110499218A (en) * | 2019-09-17 | 2019-11-26 | 黄河三角洲京博化工研究院有限公司 | A kind of efficient and environment-friendly type acid scouring agent and preparation method thereof |
CN114164053A (en) * | 2021-12-03 | 2022-03-11 | 广东三兴高新材料科技有限公司 | Acidic soaping agent |
CN114232365A (en) * | 2021-12-20 | 2022-03-25 | 广东三兴高新材料科技有限公司 | Method for preparing acidic soaping agent |
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Application publication date: 20170707 |