CN105002022A - Low-temperature deoiling scouring agent and preparation method thereof - Google Patents
Low-temperature deoiling scouring agent and preparation method thereof Download PDFInfo
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- CN105002022A CN105002022A CN201510440689.4A CN201510440689A CN105002022A CN 105002022 A CN105002022 A CN 105002022A CN 201510440689 A CN201510440689 A CN 201510440689A CN 105002022 A CN105002022 A CN 105002022A
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- polyoxyethylene ether
- scouring agent
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- deoiling
- alcohol
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Abstract
The invention discloses a low-temperature deoiling scouring agent. The low-temperature deoiling scouring agent comprises, by weight friction, 10-20% of fatty alcohol-polyoxyethylene ether (EO9), 10-20% of fatty amine alcohol-polyoxyethylene ether (EO15), 5-10% of Isomeric ten alcohol-polyoxyethylene ether (EO5), 5-15% of secondary alcohol-polyoxyethylene ether (EO9), 3-6% of solubilizer, and the allowance is deionized water. The invention further discloses a preparation method for the low-temperature deoiling scouring agent. The low-temperature deoiling scouring agent is applied to the pretreatment processes of refining, deoiling, detergent washing and the like, the deoiling problem of fabric (especially the fabric containing spandex) in the process of pretreatment is solved, and oil stain and impurities in the fabric are guaranteed to be removed effectively. The functions of dispersing, emulsifying and wetting are achieved, the permeability is good, the form is little, and detergency is strong.
Description
Technical field
The present invention relates to a kind of textile auxiliary, a kind of low temperature deoils scouring agent and preparation method thereof specifically.
Background technology
In fabric finishing process, often can encounter cloth cover greasy dirt, contamination, look stain, look flower, silicone oil spot etc., cause quality product to reduce, what have even cannot repair.Therefore, all need before textile dyeing, stamp through certain scouring process, to remove impurity on cloth cover and greasy dirt, this scouring process is commonly referred to concise.Deoil scouring agent, also claims oil removing scouring agent, have infiltration, emulsification, washing, dispersion, wetting function all kinds of of concise middle interpolation.The scouring agent that deoils to go up to the sky right impurity, pollutant and weave the auxiliary agent of slurry with chemistry and each kind fabric such as physical method removal cotton, hair, fiber crops, silk and synthon.In textile industry, deoil scouring agent, the concept of narrow sense mostly, mainly refer to all kinds of negatively charged ion, nonionogenic tenside and suitable additive, through the method for certain proportioning obtain a kind of based on cleaning function, have the synergistic compounds such as infiltration, emulsification, dispersion, complexing concurrently.
In numerous fabric, because spandex is a kind of spandex fiber, itself have very strong adhesive capacity, oil absorbency is strong, and the synthon oiliness that the finish that resultant yarn process adds is more general is stronger.The finish that on spandex thread, easily attachment is more, not easily removes, and spandex is thermo-labile, not chlorine-resistant drift, thermo-labile concentrated base, easily sustain damage.Therefore, in pretreatment process, efficient degreasing is carried out to the fabric containing spandex, comparatively difficulty.
Along with the development of textile technology, having good elastic spandex is extensively made an addition in various fabric, because traditional oil removing scouring agent more considers the impurity of common spinning and woven finish and weaving process, have ignored the emulsion dispersion needs to the special finish of spandex yarn, indifferent for deoiling of spandex, easily cause the remnants of spandex oil agent in dyeing course, therefore, have impact on the effect of deoiling to fabric largely.The process relying on high temperature easily damages spandex, thus affects its performance.In addition, traditional scouring agent effect of deoiling is single, thus affects pre-treatment effect.
Summary of the invention
The invention provides a kind of low temperature to deoil scouring agent and preparation method thereof, its object is to solve fabric (especially containing spandex fabric) the oil removing problem in pretreatment process.
Low temperature deoils scouring agent, its composition and massfraction as follows:
Fatty alcohol-polyoxyethylene ether (EO9) 10 ~ 20%;
Aliphatic amine polyoxyethylene ether (EO15) 10 ~ 20%;
Isomery ten polyoxyethylenated alcohol (EO5) 5 ~ 10%;
Secondary alcohol Soxylat A 25-7 (EO9) 5 ~ 15%;
Solubilizing agent (butyl glycol ether, ethanol or Virahol) 3 ~ 6%;
Surplus is deionized water.
Above-mentioned low temperature deoils the preparation method of scouring agent, the steps include: the aliphatic amine polyoxyethylene ether of 10 ~ 20 weight parts (EO15) fully to mix with the solubilizing agent (butyl glycol ether, ethanol or Virahol) of 3 ~ 6 weight parts, stirs; Add the secondary alcohol Soxylat A 25-7 (EO9) of the fatty alcohol-polyoxyethylene ether (EO9) of 10 ~ 20 weight parts and isomery ten polyoxyethylenated alcohol (EO5) of 5 ~ 10 weight parts and 5 ~ 15 weight parts successively; Finally add the deionized water weighed in proportion, and stir, discharging.
The present invention adopts nonionogenic tenside and solubilizing agent is composite forms.
Wherein, fatty alcohol-polyoxyethylene ether (EO9) is a kind of nonionogenic tenside, and the ehter bond in molecule is not easily destroyed by acid, alkali, so stability is higher, better water-soluble, electrolyte-resistant, is easy to biological degradation; The compatibleness of fatty alcohol-polyoxyethylene ether and other tensio-active agents is good, and insensitive to hard water, and cold washing performance is good.
Aliphatic amine polyoxyethylene ether (EO15) is a kind of special nonionogenic tenside, there is no cloud point, therefore there is wide temperature range of application, particularly can be good at affine in cold weather conditions with fiber, demonstrate excellent washing and return contamination performance with anti-, and water hardness has no significant effect its washability; The aliphatic amine polyoxyethylene ether of high EO number has excellent wetting ability, so have good soil removability to hydrophilic fiber (as: cotton fibre).
Isomery ten polyoxyethylenated alcohol (EO5) is a kind of low EO number Soxylat A 25-7, its HLB value (hydrophile-lipophile balance value) is about 12, close with the HLB value of spandex thread finish, according to similar dissolve mutually theory, this composition is used for deoiling in scouring agent, be particularly conducive to the oil removing containing spandex thread, thus promote scouring agent for containing spandex fabric specific aim.
Secondary alcohol Soxylat A 25-7 (EO9) is extremely strong emulsifying power, seepage force and dispersion force, excellent infiltration, emulsifying agent, wetting and detergent, can with other kinds negatively charged ion, nonionic, the composite use of cats product, there is outstanding synergistic effect, the use consumption of auxiliary agent can be greatly reduced, reach good cost performance, and have extremely strong seepage force, may penetrate into the inside of fiber, thus obtain more satisfied soft feel and refining whiteness.
Meanwhile, be added with butyl glycol ether, ethanol or Virahol as solubilizing agent, on the one hand, contribute to the combination with finish, strengthen deoiling effect, on the other hand, solubilizing agent can promote fatty alcohol-polyoxyethylene ether dissolving power at normal temperatures, is convenient to the use of product.
Between above composition by synergy, greatly can promote oil removing, the soil removability of the scouring agent that deoils, can well emulsion dispersion greasy dirt and remove various impurity.Can be used for the fabric of various fabric, that especially washs for difficulty contains spandex fabric and spun rayon piece goods, has better oil removing scavenging effect than traditional scouring agent that deoils.And above each composition is environment-friendly type raw material, without high-risk material, meets the requirement of environmental protection.
The low temperature of the present invention scouring agent that deoils is applicable in the pretreatment procedures such as refining, oil removing, washing, can use, and it is concise to realize low temperature under neutral and solutions of weak acidity.Meanwhile, there is dispersion, emulsification, wetting effect, good penetrability, foam be low, strong detergency.Especially pointed to the fabric containing spandex fibre, deoil effective.If cooperate with soda ash, can be used for the refining of pure cotton fabric, and have destarch concurrently, brighten, prevent dyestuff from condensing, guarantee the even unique function such as gorgeous of dyeing.
In addition, the low temperature of the present invention scouring agent that deoils also is the desirable auxiliary agent of terylene, polyamide fibre and BLENDED FABRIC scouring and dyeing technique thereof; For the cotton low-temperature refining of people, refining dye can be realized with bath, obtain excellent capillary effect and whiteness, obtain desirable dyeing behavior; For the knitting refining of cotton, fiber can be given with desirable whiteness, fluffy feel, greatly improve refining, bleaching effect, improve dyeing, printing performance further.
Embodiment
The present invention is further described with specific embodiment:
Embodiment one
Low temperature deoils scouring agent, its composition and massfraction as follows:
Fatty alcohol-polyoxyethylene ether (EO9) 20%;
Aliphatic amine polyoxyethylene ether (EO15) 10%;
Isomery ten polyoxyethylenated alcohol (EO5) 5%;
Secondary alcohol Soxylat A 25-7 (EO9) 15%;
Butyl glycol ether 6%;
Deionized water 44%.
Above-mentioned low temperature deoils the preparation method of scouring agent, the steps include: the aliphatic amine polyoxyethylene ether of 10 weight parts (EO15) fully to mix with the butyl glycol ether of 6 weight parts, stirs; Add the secondary alcohol Soxylat A 25-7 (EO9) of the fatty alcohol-polyoxyethylene ether (EO9) of 20 weight parts and isomery ten polyoxyethylenated alcohol (EO5) of 5 weight parts and 15 weight parts successively; Finally add the deionized water of 44 weight parts, and stir, discharging.
Embodiment two
Low temperature deoils scouring agent, its composition and massfraction as follows:
Fatty alcohol-polyoxyethylene ether (EO9) 15%;
Aliphatic amine polyoxyethylene ether (EO15) 15%;
Isomery ten polyoxyethylenated alcohol (EO5) 8%;
Secondary alcohol Soxylat A 25-7 (EO9) 10%;
Ethanol 5%;
Deionized water 47%.
Above-mentioned low temperature deoils the preparation method of scouring agent, the steps include: the aliphatic amine polyoxyethylene ether of 15 weight parts (EO15) fully to mix with the ethanol of 5 weight parts, stirs; Add the secondary alcohol Soxylat A 25-7 (EO9) of the fatty alcohol-polyoxyethylene ether (EO9) of 15 weight parts and isomery ten polyoxyethylenated alcohol (EO5) of 8 weight parts and 10 weight parts successively; Finally add the deionized water of 47 weight parts, and stir, discharging.
Embodiment three
Low temperature deoils scouring agent, its composition and massfraction as follows:
Fatty alcohol-polyoxyethylene ether (EO9) 10%;
Aliphatic amine polyoxyethylene ether (EO15) 20%;
Isomery ten polyoxyethylenated alcohol (EO5) 10%;
Secondary alcohol Soxylat A 25-7 (EO9) 7%;
Virahol 8%;
Deionized water 45%.
Above-mentioned low temperature deoils the preparation method of scouring agent, the steps include: the aliphatic amine polyoxyethylene ether of 20 weight parts (EO15) fully to mix with the Virahol of 8 weight parts, stirs; Add the secondary alcohol Soxylat A 25-7 (EO9) of the fatty alcohol-polyoxyethylene ether (EO9) of 10 weight parts and isomery ten polyoxyethylenated alcohol (EO5) of 10 weight parts and 7 weight parts successively; Finally add the deionized water of 45 weight parts, and stir, discharging.
Low temperature described in embodiment one, two, three deoils the outward appearance of scouring agent for yellow translucent to transparent liquid, and have nonionic, the pH value of its 1% aqueous solution is 7.0-7.5.
The deoil application of scouring agent of described low temperature mainly contains following several:
1) for generally going stupid dirt;
Suggestion consumption 0.5 ~ 3%(OWF), 40 DEG C ~ 80 DEG C, 20 minutes.
2) bleaching-bathing is practiced for chemical & blended fabric;
As auxiliary scouring agent, suggestion consumption 0.5 ~ 2%(OWF), with dyeing with bathing.
3) concise for people cotton;
Low temperature scouring agent concentration of deoiling is 0.5 ~ 1g/l, at 40 DEG C concise 20 minutes.Without the need to discharge opeing, directly add dyestuff, enter dyeing.
4) concise for cotton textiles;
Low temperature scouring agent concentration of deoiling is 0.5 ~ 1g/l, and adding soda ash concentration is 2g/l, at 90 DEG C concise 20 minutes.Discharge opeing is cleaned, and enters dyeing.
Above are only the specific embodiment of the present invention, but design concept of the present invention is not limited thereto, all changes utilizing this design the present invention to be carried out to unsubstantiality, all should belong to the behavior of invading scope.
Claims (3)
1. low temperature deoils scouring agent, its composition and massfraction as follows:
Fatty alcohol-polyoxyethylene ether (EO9) 10 ~ 20%;
Aliphatic amine polyoxyethylene ether (EO15) 10 ~ 20%;
Isomery ten polyoxyethylenated alcohol (EO5) 5 ~ 10%;
Secondary alcohol Soxylat A 25-7 (EO9) 5 ~ 15%;
Solubilizing agent 3 ~ 6%;
Surplus is deionized water.
2. low temperature deoils scouring agent as claimed in claim 1, it is characterized in that: described solubilizing agent is butyl glycol ether, ethanol or Virahol.
3. low temperature deoils the preparation method of scouring agent as claimed in claim 1 or 2, the steps include: the aliphatic amine polyoxyethylene ether of 10 ~ 20 weight parts (EO15) fully to mix with the solubilizing agent of 3 ~ 6 weight parts, stirs; Add the secondary alcohol Soxylat A 25-7 (EO9) of the fatty alcohol-polyoxyethylene ether (EO9) of 10 ~ 20 weight parts and isomery ten polyoxyethylenated alcohol (EO5) of 5 ~ 10 weight parts and 5 ~ 15 weight parts successively; Finally add the deionized water weighed in proportion, and stir, discharging.
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| CN201510440689.4A CN105002022A (en) | 2015-07-24 | 2015-07-24 | Low-temperature deoiling scouring agent and preparation method thereof |
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| CN201510440689.4A CN105002022A (en) | 2015-07-24 | 2015-07-24 | Low-temperature deoiling scouring agent and preparation method thereof |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106087407A (en) * | 2016-06-15 | 2016-11-09 | 晋江市南星印染材料有限公司 | A kind of textile highly effective oil remover |
| CN107541949A (en) * | 2016-06-29 | 2018-01-05 | 苏州联胜化学有限公司 | A kind of environment-friendly low-temperature scouring agent |
| CN107794763A (en) * | 2017-11-13 | 2018-03-13 | 东莞市古川纺织助剂有限公司 | A kind of fabric degreaser |
| CN108978188A (en) * | 2018-07-18 | 2018-12-11 | 珠海华大浩宏化工有限公司 | A kind of low temperature scouring agent and preparation method thereof |
| CN110564517A (en) * | 2019-09-09 | 2019-12-13 | 苏州联胜化学有限公司 | low-foam oil-removing scouring agent and preparation method and use method thereof |
| CN111101374A (en) * | 2018-10-29 | 2020-05-05 | 葛江波 | Environment-friendly multipurpose oil-removing scouring agent and preparation method thereof |
| CN111321590A (en) * | 2020-04-10 | 2020-06-23 | 江门市润祥纺织科技有限公司 | Non-ionic high-efficiency low-foam oil-removing refining agent and application thereof |
| CN111749034A (en) * | 2020-07-03 | 2020-10-09 | 绍兴海成化工有限公司 | Multifunctional emulsifier and application thereof |
| CN114806738A (en) * | 2022-05-18 | 2022-07-29 | 盛虹石化集团上海新材料有限公司 | Animal fiber cleaning agent composition suitable for low-temperature use and preparation method and application thereof |
| CN115807340A (en) * | 2022-12-26 | 2023-03-17 | 绍兴海成化工有限公司 | Low-temperature scouring agent and preparation method and application thereof |
| WO2023178580A1 (en) * | 2022-03-24 | 2023-09-28 | Ecolab Usa Inc. | Laundry emulsifier with surfactant and solvent |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101440572A (en) * | 2008-12-29 | 2009-05-27 | 邵国标 | Environment protection type alkaliproof refining agent and preparation thereof |
| CN102953278A (en) * | 2011-08-24 | 2013-03-06 | 冯祥茂 | Production process of textile fiber color modifier |
| CN103498337A (en) * | 2013-09-17 | 2014-01-08 | 安阳博奥生物新合成有限公司 | Application of environment-friendly scouring agent |
| CN104480718A (en) * | 2014-12-22 | 2015-04-01 | 晋江市南星印染材料有限公司 | Novel low-temperature refining agent for artificial cotton |
-
2015
- 2015-07-24 CN CN201510440689.4A patent/CN105002022A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101440572A (en) * | 2008-12-29 | 2009-05-27 | 邵国标 | Environment protection type alkaliproof refining agent and preparation thereof |
| CN102953278A (en) * | 2011-08-24 | 2013-03-06 | 冯祥茂 | Production process of textile fiber color modifier |
| CN103498337A (en) * | 2013-09-17 | 2014-01-08 | 安阳博奥生物新合成有限公司 | Application of environment-friendly scouring agent |
| CN104480718A (en) * | 2014-12-22 | 2015-04-01 | 晋江市南星印染材料有限公司 | Novel low-temperature refining agent for artificial cotton |
Non-Patent Citations (1)
| Title |
|---|
| 徐谷仓: "《染整织物短流程前处理》", 30 September 1999, 中国纺织出版社 * |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106087407A (en) * | 2016-06-15 | 2016-11-09 | 晋江市南星印染材料有限公司 | A kind of textile highly effective oil remover |
| CN106087407B (en) * | 2016-06-15 | 2017-03-22 | 晋江市南星印染材料有限公司 | High-efficiency oil removal agent for textile |
| CN107541949A (en) * | 2016-06-29 | 2018-01-05 | 苏州联胜化学有限公司 | A kind of environment-friendly low-temperature scouring agent |
| CN107794763A (en) * | 2017-11-13 | 2018-03-13 | 东莞市古川纺织助剂有限公司 | A kind of fabric degreaser |
| CN108978188A (en) * | 2018-07-18 | 2018-12-11 | 珠海华大浩宏化工有限公司 | A kind of low temperature scouring agent and preparation method thereof |
| CN111101374A (en) * | 2018-10-29 | 2020-05-05 | 葛江波 | Environment-friendly multipurpose oil-removing scouring agent and preparation method thereof |
| CN110564517A (en) * | 2019-09-09 | 2019-12-13 | 苏州联胜化学有限公司 | low-foam oil-removing scouring agent and preparation method and use method thereof |
| CN111321590A (en) * | 2020-04-10 | 2020-06-23 | 江门市润祥纺织科技有限公司 | Non-ionic high-efficiency low-foam oil-removing refining agent and application thereof |
| CN111749034A (en) * | 2020-07-03 | 2020-10-09 | 绍兴海成化工有限公司 | Multifunctional emulsifier and application thereof |
| WO2023178580A1 (en) * | 2022-03-24 | 2023-09-28 | Ecolab Usa Inc. | Laundry emulsifier with surfactant and solvent |
| CN114806738A (en) * | 2022-05-18 | 2022-07-29 | 盛虹石化集团上海新材料有限公司 | Animal fiber cleaning agent composition suitable for low-temperature use and preparation method and application thereof |
| CN114806738B (en) * | 2022-05-18 | 2023-08-01 | 盛虹石化集团上海新材料有限公司 | Animal fiber cleaning agent composition suitable for low-temperature use as well as preparation method and application thereof |
| CN115807340A (en) * | 2022-12-26 | 2023-03-17 | 绍兴海成化工有限公司 | Low-temperature scouring agent and preparation method and application thereof |
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Application publication date: 20151028 |