CN101440572A - Environment protection type alkaliproof refining agent and preparation thereof - Google Patents
Environment protection type alkaliproof refining agent and preparation thereof Download PDFInfo
- Publication number
- CN101440572A CN101440572A CNA2008101635478A CN200810163547A CN101440572A CN 101440572 A CN101440572 A CN 101440572A CN A2008101635478 A CNA2008101635478 A CN A2008101635478A CN 200810163547 A CN200810163547 A CN 200810163547A CN 101440572 A CN101440572 A CN 101440572A
- Authority
- CN
- China
- Prior art keywords
- refining agent
- polyoxyethylene ether
- alcohol polyoxyethylene
- environment protection
- protection type
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000007670 refining Methods 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 25
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 17
- -1 alkyl glycoside Chemical class 0.000 claims abstract description 15
- 229930182470 glycoside Natural products 0.000 claims abstract description 13
- 239000000203 mixture Substances 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 26
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 26
- 150000002191 fatty alcohols Chemical class 0.000 claims description 11
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 239000012467 final product Substances 0.000 claims description 4
- 238000004043 dyeing Methods 0.000 abstract description 9
- 239000003513 alkali Substances 0.000 abstract description 5
- 239000012752 auxiliary agent Substances 0.000 abstract description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 8
- 238000000034 method Methods 0.000 abstract 2
- 238000009991 scouring Methods 0.000 description 9
- 230000007613 environmental effect Effects 0.000 description 8
- 239000000047 product Substances 0.000 description 6
- 238000007639 printing Methods 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 208000031320 Teratogenesis Diseases 0.000 description 3
- 230000000711 cancerogenic effect Effects 0.000 description 3
- 231100000315 carcinogenic Toxicity 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- DPJRMOMPQZCRJU-UHFFFAOYSA-M thiamine hydrochloride Chemical compound Cl.[Cl-].CC1=C(CCO)SC=[N+]1CC1=CN=C(C)N=C1N DPJRMOMPQZCRJU-UHFFFAOYSA-M 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 235000016936 Dendrocalamus strictus Nutrition 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000001684 chronic effect Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000005556 hormone Substances 0.000 description 1
- 229940088597 hormone Drugs 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003305 oil spill Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 210000000952 spleen Anatomy 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Abstract
The invention relates to an environment friendly type alkali resistant refining agent and a method for preparing the same. The refining agent comprises the following components in mass percentage: 10 to 25 percent of alkyl glycoside, 10 to 40 percent of isomerized alcohol polyethenoxy ether with molecular weight of between 360 and 460, 2 to 15 percent of natural fat alcohol polyethenoxy ether, and the balance being water. The preparation method comprises the following steps: 1, the isomerized alcohol polyethenoxy ether is added in the alkyl glycoside and evenly mixed; and 2, the mixing solution obtained at the step 1 is added with water solution of the natural fat alcohol polyethenoxy ether and evenly mixed. The invention has the characteristics of convenient composition, simple process, good product stability and the like, and can meet the needs of the Chinese dyeing industry on green environment friendly dyeing auxiliary agent, and greatly improve the development of the Chinese weaving-dyeing industry.
Description
Technical field
The present invention relates to a kind of printing and dyeing assistant, especially relate to a kind of environment protection type alkaliproof refining agent and preparation method thereof.
Background technology
Expansion along with development of science and technology and international trade, people's environmental consciousness is also progressively being strengthened, external weaving market is more and more high to the requirement of green textiles, the promulgation of ISO14000 and Oeko TEX standard100 impels dyeing exploitation green product, mainly is security and biological degradability as its supporting printing and dyeing assistant to the influence of environment.Security comprises toxicity, teratogenesis, carcinogenic etc., the European Community points out that biodegradable environment-friendly type surfactant must have 90% average biological degradability and 80% initial biological degradability, and the part material such as the polyoxyethylene nonylphenol ether of the scouring agent of domestic production at present, neopelex, sodium phosphate trimer, urea, disodium ethylene diamine tetraacetates etc. have been listed non-environmental protection ProductName list in and are disabled, also begin constantly to appear on the market with stylish environment-friendly type scouring agent.Because polyoxyethylene nonylphenol ether (APEO) has the wetting of excellence, infiltration, emulsification, dispersion, solubilising and cleaning function, it is preferred raw materials as scouring agent, but because carcinogenic, the teratogenesis of APEO and cause variability and caused both at home and abroad forbidding to this product, neopelex has chronic symptons such as damaging and causes that spleen dwindles to liver after skin absorbs, and teratogenesis and carcinogenic.For biological degradability is minimum with non-ionic surface active agent APEO, only is 0-9%, and his low EO metabolin is toxic to aquatic organism, and final metabolin alkyl phenol is an environmental hormone, and Europe bans use of the eighties in 20th century.
The environmental protection scouring agent that the external existing existing APEO of substituting is a raw material occurs, external Losin OCE as Switzerland RextiicororAG company, the Ecco HR-CO of U.S. Eas Tern company, Britain foretells the Lenotol HP Jet of inside door company, the Grese of U.S. Gresco company-oscour JNF, the Laventin CW of Germany Bayer company, the domestic consumption of these environment-friendly type scouring agents is huge, domestic recent some environmental protection scouring agents that occurred, but these homemade environmental protection scouring agents find that its alkali resistance is undesirable after the actual use of user---what have the oil spill phenomenon occurs in head tank uses, have capillary effect has appearred in semi-products tests or whiteness lags far behind imported product on product quality, country still needs and want a large amount of environmental protection scouring agents of import to satisfy user's needs every year.
Summary of the invention
The present invention mainly be solve that the existing refining agent alkali resistance of prior art is undesirable, raw material and accessory substance be to the technical problem of the adverse effect of environment etc.
Above-mentioned technical problem of the present invention is mainly solved by following technical proposals:
Described environment protection type alkaliproof refining agent, be made up of the component of following weight percentage: alkyl glycoside 10～25%, molecular weight are 360～460 isomery alcohol polyoxyethylene ether 10～40%, and natural fatty alcohol polyoxyethylene ether 2～15%, surplus are water.
Further, described environment protection type alkaliproof refining agent is made up of the component of following weight percentage: alkyl glycoside 20%, and isomery alcohol polyoxyethylene ether 30%, natural fatty alcohol polyoxyethylene ether 10%, surplus are water.
A kind of preparation method of above-mentioned environment protection type alkaliproof refining agent comprises:
(1) isomery alcohol polyoxyethylene ether is joined in the alkyl glycoside, mix;
(2) in the mixed liquor of step (1), add the aqueous solution of natural fatty alcohol polyoxyethylene ether, mix then and get final product.
The present invention adopts the anion surfactant APG to substitute the neopelex of being forbidden abroad, because of its final biological degradation rate can reach 99.3%, have good soil release characteristics, emulsibility and wettability, in 40% sodium hydroxide solution, do not produce muddiness, anti-inorganic salts performance is good, raw material as scouring agent can obviously improve the alkali resistance of auxiliary agent, and has good compound property, has good synergistic function with other surfactant compounds.
The present invention also adopts the isomery alcohol polyoxyethylene ether of narrow distribution to substitute the bigger APEO of toxicity, the isomery alcohol polyoxyethylene ether of narrow distribution all is better than APEO because of its emulsifying ability, washing force, the similar permeability to APEO of dispersion force and cloud point, so be desirable substitute.
The present invention adopts natural fatty alcohol-polyoxyethylene ether, be to utilize its good dispersiveness, emulsibility, permeability and good washability, reach and remove cured, as to improve dyestuff penetration performance purpose, and behind natural fatty alcohol-polyoxyethylene ether and other surfactant compounds, has obvious role in synergism equally.
Alkyl glycoside of the present invention, isomery alcohol polyoxyethylene ether, natural fatty alcohol polyoxyethylene ether all can obtain by commercial sources.
Characteristics such as the present invention has reasonable recipe, and technology is easy, product stability is good can satisfy the demand of domestic dyeing to the environmental protection printing and dyeing assistant, and the industry of China's textile printing and dyeing industry is promoted bigger impetus.
The specific embodiment
Below by embodiment, technical scheme of the present invention is described in further detail.
Embodiment 1:
A kind of environment protection type alkaliproof refining agent, be made up of the component of following weight percentage: alkyl glycoside 20%, molecular weight are 360～460 isomery alcohol polyoxyethylene ether 30%, natural fatty alcohol polyoxyethylene ether 10%, surplus 40% is a water.
A kind of preparation method of above-mentioned environment protection type alkaliproof refining agent comprises:
(1) isomery alcohol polyoxyethylene ether 30kg is joined among the alkyl glycoside 20kg, mix;
(2) in the mixed liquor of step (1), add the 40kg aqueous solution of natural fatty alcohol polyoxyethylene ether 10kg, mix then and get final product.
The environment protection type alkaliproof refining agent basic mechanical design feature index that makes is as follows:
Outward appearance: colourless liquid is nontoxic, tasteless
Proportion: 1.0kg/l
Solid content: 49%
Alkali resistance: 〉=200g/l
Penetrability :≤10s (10g/l)
Embodiment 2:
A kind of environment protection type alkaliproof refining agent, form by the component of following weight percentage:
Alkyl glycoside 15%, molecular weight are 360～460 isomery alcohol polyoxyethylene ether 20%, natural fatty alcohol polyoxyethylene ether 5%, and surplus 60% is a water.
A kind of preparation method of above-mentioned environment protection type alkaliproof refining agent comprises:
(1) isomery alcohol polyoxyethylene ether 20kg is joined among the alkyl glycoside 15kg, mix;
(2) in the mixed liquor of step (1), add the 60kg aqueous solution of 5kg natural fatty alcohol polyoxyethylene ether, mix then and get final product.
At last, should be pointed out that above embodiment only is the more representational example of the present invention.Obviously, technical scheme of the present invention is not limited to the foregoing description, and many distortion can also be arranged.All distortion that those of ordinary skill in the art can directly derive or associate from content disclosed by the invention all should be thought protection scope of the present invention.
Claims (3)
1. environment protection type alkaliproof refining agent is characterized in that being made up of the component of following weight percentage: alkyl glycoside 10～25%, molecular weight are 360～460 isomery alcohol polyoxyethylene ether 10～40%, and natural fatty alcohol polyoxyethylene ether 2～15%, surplus are water.
2. according to the environment protection type alkaliproof refining agent of claim 1, it is characterized in that forming by the component of following weight percentage:
Alkyl glycoside 20%, isomery alcohol polyoxyethylene ether 30%, natural fatty alcohol polyoxyethylene ether 10%, surplus are water.
3. the preparation method of the described environment protection type alkaliproof refining agent of claim 1 is characterized in that comprising:
(1) isomery alcohol polyoxyethylene ether is joined in the alkyl glycoside, mix;
(2) in the mixed liquor of step (1), add the aqueous solution of natural fatty alcohol polyoxyethylene ether, mix then and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008101635478A CN101440572B (en) | 2008-12-29 | 2008-12-29 | Environment protection type alkaliproof refining agent and preparation thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008101635478A CN101440572B (en) | 2008-12-29 | 2008-12-29 | Environment protection type alkaliproof refining agent and preparation thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101440572A true CN101440572A (en) | 2009-05-27 |
| CN101440572B CN101440572B (en) | 2010-12-22 |
Family
ID=40725160
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2008101635478A Active CN101440572B (en) | 2008-12-29 | 2008-12-29 | Environment protection type alkaliproof refining agent and preparation thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101440572B (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102535156A (en) * | 2011-12-23 | 2012-07-04 | 北京光华纺织集团有限公司 | Refining agent for color cotton |
| CN103046331A (en) * | 2012-12-12 | 2013-04-17 | 常州大学 | High efficiency and low foam environment-friendly type scouring agent and preparation method thereof |
| CN103498337A (en) * | 2013-09-17 | 2014-01-08 | 安阳博奥生物新合成有限公司 | Application of environment-friendly scouring agent |
| CN103498336A (en) * | 2013-09-17 | 2014-01-08 | 安阳博奥生物新合成有限公司 | Environment-friendly scouring agent |
| CN104532556A (en) * | 2015-01-29 | 2015-04-22 | 偃师然合生物材料有限公司 | High-alkali-resistance type textile scouring agent and preparation method thereof |
| CN105002022A (en) * | 2015-07-24 | 2015-10-28 | 邦诺（福建）纺织实业有限责任公司 | Low-temperature deoiling scouring agent and preparation method thereof |
| CN105040423A (en) * | 2015-08-25 | 2015-11-11 | 无锡市长安曙光手套厂 | Alkali-resisting spinning refining agent and preparation method thereof |
| CN106702745A (en) * | 2016-12-16 | 2017-05-24 | 吴江市北厍盛源纺织品助剂厂 | Degreasing and low-fat fabric refining agent and preparation method thereof |
| CN110564517A (en) * | 2019-09-09 | 2019-12-13 | 苏州联胜化学有限公司 | low-foam oil-removing scouring agent and preparation method and use method thereof |
| CN111321599A (en) * | 2020-04-10 | 2020-06-23 | 江门市润祥纺织科技有限公司 | High-temperature-resistant alkali-resistant composite emulsifier for silicone oil emulsification and preparation method thereof |
| CN111910428A (en) * | 2020-07-09 | 2020-11-10 | 无锡联达化工有限公司 | Efficient multifunctional textile pretreatment auxiliary method |
| CN113564912A (en) * | 2021-07-28 | 2021-10-29 | 绍兴赫凡纺织科技有限公司 | Preparation method and application of efficient cold rolling batch refining agent |
| CN113583762A (en) * | 2021-09-10 | 2021-11-02 | 湖南金裕环保科技有限公司 | High-alkali-resistant low-foam surfactant and preparation method thereof |
-
2008
- 2008-12-29 CN CN2008101635478A patent/CN101440572B/en active Active
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102535156A (en) * | 2011-12-23 | 2012-07-04 | 北京光华纺织集团有限公司 | Refining agent for color cotton |
| CN103046331B (en) * | 2012-12-12 | 2015-01-07 | 常州大学 | High efficiency and low foam environment-friendly type scouring agent and preparation method thereof |
| CN103046331A (en) * | 2012-12-12 | 2013-04-17 | 常州大学 | High efficiency and low foam environment-friendly type scouring agent and preparation method thereof |
| CN103498336B (en) * | 2013-09-17 | 2016-05-04 | 安阳博奥生物新合成有限公司 | A kind of environment-friendly type scouring agent |
| CN103498336A (en) * | 2013-09-17 | 2014-01-08 | 安阳博奥生物新合成有限公司 | Environment-friendly scouring agent |
| CN103498337A (en) * | 2013-09-17 | 2014-01-08 | 安阳博奥生物新合成有限公司 | Application of environment-friendly scouring agent |
| CN103498337B (en) * | 2013-09-17 | 2016-05-04 | 安阳博奥生物新合成有限公司 | A kind of application of environment-friendly type scouring agent |
| CN104532556A (en) * | 2015-01-29 | 2015-04-22 | 偃师然合生物材料有限公司 | High-alkali-resistance type textile scouring agent and preparation method thereof |
| CN105002022A (en) * | 2015-07-24 | 2015-10-28 | 邦诺（福建）纺织实业有限责任公司 | Low-temperature deoiling scouring agent and preparation method thereof |
| CN105040423A (en) * | 2015-08-25 | 2015-11-11 | 无锡市长安曙光手套厂 | Alkali-resisting spinning refining agent and preparation method thereof |
| CN106702745A (en) * | 2016-12-16 | 2017-05-24 | 吴江市北厍盛源纺织品助剂厂 | Degreasing and low-fat fabric refining agent and preparation method thereof |
| CN106702745B (en) * | 2016-12-16 | 2018-10-09 | 吴江市北厍盛源纺织品助剂厂 | One kind is deoiled low fat weaving refining agent and preparation method thereof |
| CN110564517A (en) * | 2019-09-09 | 2019-12-13 | 苏州联胜化学有限公司 | low-foam oil-removing scouring agent and preparation method and use method thereof |
| CN111321599A (en) * | 2020-04-10 | 2020-06-23 | 江门市润祥纺织科技有限公司 | High-temperature-resistant alkali-resistant composite emulsifier for silicone oil emulsification and preparation method thereof |
| CN111910428A (en) * | 2020-07-09 | 2020-11-10 | 无锡联达化工有限公司 | Efficient multifunctional textile pretreatment auxiliary method |
| CN113564912A (en) * | 2021-07-28 | 2021-10-29 | 绍兴赫凡纺织科技有限公司 | Preparation method and application of efficient cold rolling batch refining agent |
| CN113583762A (en) * | 2021-09-10 | 2021-11-02 | 湖南金裕环保科技有限公司 | High-alkali-resistant low-foam surfactant and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101440572B (en) | 2010-12-22 |
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| GR01 | Patent grant | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Shaoxing Guotai assistant factory Assignor: Shao Guobiao Contract record no.: 2011330000027 Denomination of invention: Environment protection type alkaliproof refining agent and preparation thereof Granted publication date: 20101222 License type: Exclusive License Open date: 20090527 Record date: 20110119 |
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Effective date of registration: 20180118 Address after: 312000 Changhe Road, Binhai New Town, Shaoxing, Shaoxing, Zhejiang Patentee after: ZHEJIANG JIEFA TECHNOLOGY Co.,Ltd. Address before: 312035 Zhejiang province Shaoxing city Gao Gao Bu Town North Industrial Zone, Shaoxing Guotai Auxiliaries Factory Patentee before: Shao Guobiao |
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| CP01 | Change in the name or title of a patent holder | ||
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Address after: 312000 No.15, Changhe Road, Binhai New Town, Shaoxing City, Zhejiang Province Patentee after: Zhejiang jiefa Technology Co.,Ltd. Address before: 312000 No.15, Changhe Road, Binhai New Town, Shaoxing City, Zhejiang Province Patentee before: ZHEJIANG JIEFA TECHNOLOGY Co.,Ltd. |
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Denomination of invention: An environment-friendly alkali resistant refining agent and its preparation method Effective date of registration: 20221010 Granted publication date: 20101222 Pledgee: China Guangfa Bank Co.,Ltd. Shaoxing Branch Pledgor: Zhejiang jiefa Technology Co.,Ltd. Registration number: Y2022980017885 |