CN103498337B - A kind of application of environment-friendly type scouring agent - Google Patents
A kind of application of environment-friendly type scouring agent Download PDFInfo
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- CN103498337B CN103498337B CN201310424656.1A CN201310424656A CN103498337B CN 103498337 B CN103498337 B CN 103498337B CN 201310424656 A CN201310424656 A CN 201310424656A CN 103498337 B CN103498337 B CN 103498337B
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Abstract
The invention belongs to fabric used additives technical field, particularly a kind of application of environment-friendly type scouring agent. Described scouring agent weight portion is composed as follows: alcohol ether glucoside 2-50 part, and APG 2-50 part, water 20-60 part, is formulated as the aqueous solution of 0.1-5g/L when use. Raw material type of the present invention is few, and is the non-ionic surface active agent of easily biological-degradable, also has advantages such as strong infiltration, high capillary effect in conjunction with rear; In fabric pretreatment technique, can effectively strengthen washing, improve capillary effect, in cold batching process and boiling, be better than like product.
Description
Technical field
The invention belongs to fabric used additives technical field, particularly a kind of application of environment-friendly type scouring agent.
Background technology
Remove all kinds of textiles heavens such as cotton, hair, fiber crops, silk and synthetic fibers with chemistry and physical methodSo impurity, pollutant and the technical process of weaving slurry are called concise. Thereby, broadly say, conciseThe chemical substances such as acid, alkali, oxidant, reducing agent and the various surfactants of adding in process can be namedDo scouring agent. But in textile industry, generally mentioning scouring agent, is the concept of narrow sense mostly, is mainlyRefer to each anionoid, non-ionic surface active agent and suitable additive, through the method for certain proportioningObtain a kind of taking cleaning function as main, to have infiltration, emulsification, dispersion, complexing etc. concurrently synergistic multipleJoin thing. According to the classification in textile industry, cotton, fiber crops, silk, hair, staple fibre, synthetic fabricsDifference, component and the proportioning of scouring agent are also not quite similar. But basis is nothing more than alkaline agent, bleeding agent, breastAgent, washing agent, dispersant, complexing of metal ion agent and suitable neutral salt. But make a general survey of current essencePractice agent, substantially all exists pollute greatly, the defect such as the low and difficult degradation of capillary effect.
Summary of the invention
The object of this invention is to provide a kind of application of environment-friendly type refining agent, can overcome current scouring agent and polluteThe defects such as greatly, capillary effect is low, degraded is difficult.
For solving the problems of the technologies described above, the technical solution used in the present invention is as follows:
An application for environment-friendly type scouring agent, described scouring agent weight portion is composed as follows: alcohol ether glucoside 5-35Part, APG 5-35 part, water 30-90 part, three's sum is 100 parts; When use, be formulated as 0.1-5.0g/LThe aqueous solution.
Preferably, the weight portion of described scouring agent consists of: alcohol ether glucoside 5-10 part, APG 5-10Part, water 80-90 part.
Or the weight portion of described scouring agent consists of: alcohol ether glucoside 10-15 part, APG 10-15Part, water 70-80 part.
Again or, the weight portion of described scouring agent consists of: alcohol ether glucoside 15-25 part, APG 15-25Part, water 50-70 part.
Preferred, described scouring agent is formulated as the solution of 0.5-1.5g/L while use.
While preparing described scouring agent, the component of getting corresponding weight portion mixes and then is water-soluble.
Scouring agent of the present invention is particularly suitable for cotton, fiber crops and blend fabric thereof.
Described alcohol ether glucoside structural formula is as follows:
Alcohol ether glucoside (AlkylEthoxyPolyglycosides is called for short AEG) is the glucosides of fatty alcohol etherProduct, claims again alcohol ether glucoside. Alcohol ether glucoside AEG belongs to the performance of APG APG and fatty alcohol ether AEOnImproved products is, application widely novel, multi-functional green activity higher than APG cost performanceMaterial.
Raw material A PG and AEG can directly buy commercially available product, and AEG also can be with reference to ZL200410064576.0Be prepared.
Raw material type of the present invention is few, and two kinds of main component APG and AEG are environment-friendly type non-ionic surfaceActivating agent, easily biological-degradable; After both combinations, not only still there is environmental protection, easily degraded, also simultaneouslyThere is the advantages such as strong infiltration, high capillary effect. In fabric pretreatment technique, can effectively strengthen washing, improve capillary effect,In cold batching process and boiling, be better than like product.
Compared with prior art, tool has the following advantages in the present invention:
Raw material type of the present invention is few, and is the non-ionic surface active agent of easily biological-degradable, goes back in conjunction with rearThere is the advantages such as strong infiltration, high capillary effect; In fabric pretreatment technique, can effectively strengthen washing, improve capillary effect,In cold batching process and boiling, be better than like product.
Detailed description of the invention
With specific embodiment, technical scheme of the present invention is described below, but protection scope of the present invention is not limited toThis:
Embodiment 1
A kind of environment-friendly type scouring agent, described scouring agent weight portion is composed as follows: 10 parts of alcohol ether glucosides, alkyl10 parts, glucosides, 80 parts, water.
Get 10 parts of alcohol ether glucosides, 10 parts of APGs, 80 parts of even mixing of water obtain described scouring agent.
Embodiment 2
A kind of environment-friendly type scouring agent, described scouring agent weight portion is composed as follows: 15 parts of alcohol ether glucosides, alkyl15 parts, glucosides, 70 parts, water.
Get 15 parts of alcohol ether glucosides, 15 parts of APGs, 70 parts of even mixing of water obtain described scouring agent.
Embodiment 3
A kind of environment-friendly type scouring agent, described scouring agent weight portion is composed as follows: 25 parts of alcohol ether glucosides, alkyl25 parts, glucosides, 50 parts, water.
Get 25 parts of alcohol ether glucosides, 25 parts of APGs, 50 parts of even mixing of water obtain described scouring agent.
Table 1 is knitted after being formulated as capillary effect after the respective concentration aqueous solution and wherethrough reason for embodiment 1-3 scouring agentThe whiteness data of thing, compare with OEP-98, and capillary effect is high, and whiteness is high.
Table 1
In table 1, capillary effect method for measuring is as follows: by the sample after concise, (cotton grey cloth boils 30minRear flatiron is smooth) be cut into the cloth of warp-wise 30cm, broadwise 5cm, using along broadwise from 1cm place, one endPencil is made parallel lines, and fixes a short glass bar that nearly weighs 3g at this end along broadwise and make heavy burden, willThe sample other end is fixed on a crossbearer and makes its vertical hanging with shelf, and the dichromic acid of 5g/L is immersed in lower endPotassium solution, makes liquid level just in time align with pencil line. Measuring potassium bichromate solution in 30min rises along warp-wiseHeight, represent with cm. Numerical value is larger, shows that scouring result is better.
When measuring brightness, on ZBD-1 type whiteness instrument, measure. Concrete operations are as follows: sample is built up on request8 layers, keep direction of warp and weft to get 5 point measurements consistent at the different parts of sample, get that it is averageValue. Reading is larger, shows that whiteness is better.
Table 2 is penetration, alkali resistance and the emulsifying ability data of embodiment 1 product.
Table 2
| Project | Concentration | Result |
| Penetration | 5g/L | 5s |
| Alkali resistance | 230g/L | |
| Emulsifying ability | Solid content 0.15% | ＞5min |
Wherein, penetration is measured according to standard HG/T2575-94;
Alkali resistance assay method is as follows: get mass concentration and be 2% scouring agent solution 100ml, add hydrogen-oxygenChange sodium solid, and stir. In the time there is muddiness in solution, weigh solution, calculate the NaOH quality addingM. Accurately take again (M-1) g sodium hydrate solid, be slowly added to mass concentration and be 2% scouring agent 100In mL solution, if be still transparent after scouring agent solution left standstill 2h, without separating out, coacervation, this 2%The alkaline-resisting amount of scouring agent is (10M-10) g/L.
Emulsifying ability assay method is as follows: preparation is equivalent to the scouring agent aqueous solution of solid content 0.15%. Get40mL sample solution and 40ml atoleine (HG/T2892), in iodine value bottle, fluctuate five times,Park one minute, then fluctuate five times, emulsion is poured in the graduated cylinder of 100mL, open immediately stopwatch,Record emulsion lower floor and separate the needed time of 10mL water.
Claims (4)
1. an application for environment-friendly type scouring agent, is characterized in that, described scouring agent weight portion is composed as follows: alcohol ether glucoside 5-35 part, and APG 5-35 part, water 30-90 part, three's summation is 100 parts;
When use, be formulated as the aqueous solution of 1.0-1.5g/L.
2. the application of environment-friendly type scouring agent as claimed in claim 1, is characterized in that, the weight portion of described scouring agent consists of: alcohol ether glucoside 5-10 part, APG 5-10 part, water 80-90 part.
3. the application of environment-friendly type scouring agent as claimed in claim 1, is characterized in that, the weight portion of described scouring agent consists of: alcohol ether glucoside 10-15 part, APG 10-15 part, water 70-80 part.
4. the application of environment-friendly type scouring agent as claimed in claim 1, is characterized in that, the weight portion of described scouring agent consists of: alcohol ether glucoside 15-25 part, APG 15-25 part, water 50-70 part.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310424656.1A CN103498337B (en) | 2013-09-17 | 2013-09-17 | A kind of application of environment-friendly type scouring agent |
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| CN201310424656.1A CN103498337B (en) | 2013-09-17 | 2013-09-17 | A kind of application of environment-friendly type scouring agent |
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| Publication Number | Publication Date |
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| CN103498337A CN103498337A (en) | 2014-01-08 |
| CN103498337B true CN103498337B (en) | 2016-05-04 |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105002022A (en) * | 2015-07-24 | 2015-10-28 | 邦诺（福建）纺织实业有限责任公司 | Low-temperature deoiling scouring agent and preparation method thereof |
| CN105525509B (en) * | 2016-02-02 | 2018-04-06 | 山东黄河三角洲纺织科技研究院有限公司 | A kind of low alkali scouring agent for bafta rope form continuous scouring |
| CN105714550B (en) * | 2016-02-29 | 2018-02-16 | 苏州印丝特纺织数码科技有限公司 | A kind of high-efficiency environment friendly bafta refining agent and preparation method thereof |
| CN110029401A (en) * | 2019-04-12 | 2019-07-19 | 苏州丝之源纺织科技有限公司 | A kind of low temperature degumming agent and its Degumming method for natural colorful silk |
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| CN101440572A (en) * | 2008-12-29 | 2009-05-27 | 邵国标 | Environment protection type alkaliproof refining agent and preparation thereof |
| CN102618398A (en) * | 2012-02-15 | 2012-08-01 | 中国日用化学工业研究院 | Concentrated fabric liquid detergent containing fatty acid methyl ester sulfonate and preparation method of concentrated fabric liquid detergent |
| CN102631295A (en) * | 2012-03-30 | 2012-08-15 | 中国日用化学工业研究院 | Multifunctional foam liquid soap containing glucoside and derivatives of glucoside, and preparation method thereof |
| CN102704267A (en) * | 2012-04-05 | 2012-10-03 | 苏州百氏高化工有限公司 | Catalytic preparation method of environment-friendly alkaliproof refining agent |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101440572A (en) * | 2008-12-29 | 2009-05-27 | 邵国标 | Environment protection type alkaliproof refining agent and preparation thereof |
| CN102618398A (en) * | 2012-02-15 | 2012-08-01 | 中国日用化学工业研究院 | Concentrated fabric liquid detergent containing fatty acid methyl ester sulfonate and preparation method of concentrated fabric liquid detergent |
| CN102631295A (en) * | 2012-03-30 | 2012-08-15 | 中国日用化学工业研究院 | Multifunctional foam liquid soap containing glucoside and derivatives of glucoside, and preparation method thereof |
| CN102704267A (en) * | 2012-04-05 | 2012-10-03 | 苏州百氏高化工有限公司 | Catalytic preparation method of environment-friendly alkaliproof refining agent |
Non-Patent Citations (1)
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| "烷基糖苷及其衍生物的技术进展";杨秀全等;《日用化学工业》;20120630;第42卷(第3期);第213-219页 * |
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