CN103498336B - A kind of environment-friendly type scouring agent - Google Patents
A kind of environment-friendly type scouring agent Download PDFInfo
- Publication number
- CN103498336B CN103498336B CN201310424659.5A CN201310424659A CN103498336B CN 103498336 B CN103498336 B CN 103498336B CN 201310424659 A CN201310424659 A CN 201310424659A CN 103498336 B CN103498336 B CN 103498336B
- Authority
- CN
- China
- Prior art keywords
- scouring agent
- environment
- agent
- friendly type
- alcohol ether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention belongs to fabric used additives technical field, particularly a kind of environment-friendly type scouring agent. Described scouring agent weight portion is composed as follows: alcohol ether glucoside 2-50 part, APG 2-50 part, water 20-60 part. Raw material type of the present invention is few, and is the non-ionic surface active agent of easily biological-degradable, also has advantages such as strong infiltration, high capillary effect in conjunction with rear; In fabric pretreatment technique, can effectively strengthen washing, improve capillary effect, in cold batching process and boiling, be better than like product.
Description
Technical field
The invention belongs to fabric used additives technical field, particularly a kind of environment-friendly type scouring agent.
Background technology
Remove all kinds of textiles heavens such as cotton, hair, fiber crops, silk and synthetic fibers with chemistry and physical methodSo impurity, pollutant and the technical process of weaving slurry are called concise. Thereby, broadly say, conciseThe chemical substances such as acid, alkali, oxidant, reducing agent and the various surfactants of adding in process can be namedDo scouring agent. But in textile industry, generally mentioning scouring agent, is the concept of narrow sense mostly, is mainlyRefer to each anionoid, non-ionic surface active agent and suitable additive, through the method for certain proportioningObtain a kind of taking cleaning function as main, to have infiltration, emulsification, dispersion, complexing etc. concurrently synergistic multipleJoin thing. According to the classification in textile industry, cotton, fiber crops, silk, hair, staple fibre, synthetic fabricsDifference, component and the proportioning of scouring agent are also not quite similar. But basis is nothing more than alkaline agent, bleeding agent, breastAgent, washing agent, dispersant, complexing of metal ion agent and suitable neutral salt. But make a general survey of current essencePractice agent, substantially all exists pollute greatly, the defect such as the low and difficult degradation of capillary effect.
Summary of the invention
The object of this invention is to provide a kind of environment-friendly type refining agent, can overcome current scouring agent and pollute large, hairImitate the defects such as low, degraded is difficult.
For solving the problems of the technologies described above, the technical solution used in the present invention is as follows:
A kind of environment-friendly type scouring agent, described scouring agent weight portion is composed as follows: alcohol ether glucoside 5-35 part, alkaneBase glucosides 5-35 part, water 30-90 part, three's sum is 100 parts.
Preferably, the weight portion of described scouring agent consists of: alcohol ether glucoside 5-10 part, APG 5-10Part, water 80-90 part.
Or the weight portion of described scouring agent consists of: alcohol ether glucoside 10-15 part, APG 10-15Part, water 70-80 part.
Again or, the weight portion of described scouring agent consists of: alcohol ether glucoside 15-25 part, APG 15-25Part, water 50-70 part.
While preparing described scouring agent, the component of getting corresponding weight portion mixes.
When use, the aqueous solution that generally described scouring agent is formulated as to 0.5-1.5g/L uses.
Scouring agent of the present invention is particularly suitable for cotton, fiber crops and blend fabric thereof.
Described alcohol ether glucoside structural formula is as follows:
Alcohol ether glucoside (AlkylEthoxyPolyglycosides is called for short AEG) is the glucosides of fatty alcohol etherProduct, claims again alcohol ether glucoside. Alcohol ether glucoside AEG belongs to the performance of APG APG and fatty alcohol ether AEOnImproved products is, application widely novel, multi-functional green activity higher than APG cost performanceMaterial.
Raw material A PG and AEG can directly buy commercially available product, and AEG also can be with reference to ZL200410064576.0Be prepared.
Raw material type of the present invention is few, and two kinds of main component APG and AEG are environment-friendly type non-ionic surfaceActivating agent, easily biological-degradable; After both combinations, not only still there is environmental protection, easily degraded, also simultaneouslyThere is the advantages such as strong infiltration, high capillary effect. In fabric pretreatment technique, can effectively strengthen washing, improve capillary effect,In cold batching process and boiling, be better than like product.
Compared with prior art, tool has the following advantages in the present invention:
Raw material type of the present invention is few, and is the non-ionic surface active agent of easily biological-degradable, goes back in conjunction with rearThere is the advantages such as strong infiltration, high capillary effect; In fabric pretreatment technique, can effectively strengthen washing, improve capillary effect,In cold batching process and boiling, be better than like product.
Detailed description of the invention
With specific embodiment, technical scheme of the present invention is described below, but protection scope of the present invention is not limited toThis:
Embodiment 1
A kind of environment-friendly type scouring agent, described scouring agent weight portion is composed as follows: 10 parts of alcohol ether glucosides, alkyl10 parts, glucosides, 80 parts, water.
Get 10 parts of alcohol ether glucosides, 10 parts of APGs, 80 parts of even mixing of water obtain described scouring agent.
Embodiment 2
A kind of environment-friendly type scouring agent, described scouring agent weight portion is composed as follows: 15 parts of alcohol ether glucosides, alkyl15 parts, glucosides, 70 parts, water.
Get 15 parts of alcohol ether glucosides, 15 parts of APGs, 70 parts of even mixing of water obtain described scouring agent.
Embodiment 3
A kind of environment-friendly type scouring agent, described scouring agent weight portion is composed as follows: 25 parts of alcohol ether glucosides, alkyl25 parts, glucosides, 50 parts, water.
Get 25 parts of alcohol ether glucosides, 25 parts of APGs, 50 parts of even mixing of water obtain described scouring agent.
Table 1 is knitted after being formulated as capillary effect after the respective concentration aqueous solution and wherethrough reason for embodiment 1-3 scouring agentThe whiteness data of thing, compare with OEP-98, and capillary effect is high, and whiteness is high.
Table 1
In table 1, capillary effect method for measuring is as follows: by the sample after concise, (cotton grey cloth boils 30minRear flatiron is smooth) be cut into the cloth of warp-wise 30cm, broadwise 5cm, using along broadwise from 1cm place, one endPencil is made parallel lines, and fixes a short glass bar that nearly weighs 3g at this end along broadwise and make heavy burden, willThe sample other end is fixed on a crossbearer and makes its vertical hanging with shelf, and the dichromic acid of 5g/L is immersed in lower endPotassium solution, makes liquid level just in time align with pencil line. Measuring potassium bichromate solution in 30min rises along warp-wiseHeight, represent with cm. Numerical value is larger, shows that scouring result is better.
When measuring brightness, on ZBD-1 type whiteness instrument, measure. Concrete operations are as follows: sample is built up on request8 layers, keep direction of warp and weft to get 5 point measurements consistent at the different parts of sample, get that it is averageValue. Reading is larger, shows that whiteness is better.
Table 2 is penetration, alkali resistance and the emulsifying ability data of embodiment 1 product.
Table 2
| Project | Concentration | Result |
| Penetration | 5g/L | 5s |
| Alkali resistance | 230g/L | |
| Emulsifying ability | Solid content 0.15% | ＞5min |
Wherein, penetration is measured according to standard HG/T2575-94;
Alkali resistance assay method is as follows: get mass concentration and be 2% scouring agent solution 100ml, add hydrogen-oxygenChange sodium solid, and stir. In the time there is muddiness in solution, weigh solution, calculate the NaOH quality addingM. Accurately take again (M-1) g sodium hydrate solid, be slowly added to mass concentration and be 2% scouring agent 100In mL solution, if be still transparent after scouring agent solution left standstill 2h, without separating out, coacervation, this 2%The alkaline-resisting amount of scouring agent is (10M-10) g/L.
Emulsifying ability assay method is as follows: preparation is equivalent to the scouring agent aqueous solution of solid content 0.15%. Get40mL sample solution and 40ml atoleine (HG/T2892), in iodine value bottle, fluctuate five times,Park one minute, then fluctuate five times, emulsion is poured in the graduated cylinder of 100mL, open immediately stopwatch,Record emulsion lower floor and separate the needed time of 10mL water.
Claims (4)
1. an environment-friendly type scouring agent, is characterized in that, described scouring agent weight portion is composed as follows: alcohol ether sugarGlycosides 5-35 part, APG 5-35 part, water 30-90 part, three's summation is 100 parts.
2. environment-friendly type scouring agent as claimed in claim 1, is characterized in that, the weight portion of described scouring agentConsist of: alcohol ether glucoside 5-10 part, APG 5-10 part, water 80-90 part.
3. environment-friendly type scouring agent as claimed in claim 1, is characterized in that, the weight portion of described scouring agentConsist of: alcohol ether glucoside 10-15 part, APG 10-15 part, water 70-80 part.
4. environment-friendly type scouring agent as claimed in claim 1, is characterized in that, the weight portion of described scouring agentConsist of: alcohol ether glucoside 15-25 part, APG 15-25 part, water 50-70 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310424659.5A CN103498336B (en) | 2013-09-17 | 2013-09-17 | A kind of environment-friendly type scouring agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310424659.5A CN103498336B (en) | 2013-09-17 | 2013-09-17 | A kind of environment-friendly type scouring agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103498336A CN103498336A (en) | 2014-01-08 |
| CN103498336B true CN103498336B (en) | 2016-05-04 |
Family
ID=49863587
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310424659.5A Expired - Fee Related CN103498336B (en) | 2013-09-17 | 2013-09-17 | A kind of environment-friendly type scouring agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103498336B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105274829A (en) * | 2015-11-20 | 2016-01-27 | 常熟市梦迪安家饰用品有限公司 | Alkali-resistant environment-friendly scouring agent |
| CN105525509B (en) * | 2016-02-02 | 2018-04-06 | 山东黄河三角洲纺织科技研究院有限公司 | A kind of low alkali scouring agent for bafta rope form continuous scouring |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101440572A (en) * | 2008-12-29 | 2009-05-27 | 邵国标 | Environment protection type alkaliproof refining agent and preparation thereof |
| CN102618398A (en) * | 2012-02-15 | 2012-08-01 | 中国日用化学工业研究院 | Concentrated fabric liquid detergent containing fatty acid methyl ester sulfonate and preparation method of concentrated fabric liquid detergent |
| CN102631295A (en) * | 2012-03-30 | 2012-08-15 | 中国日用化学工业研究院 | Multifunctional foam liquid soap containing glucoside and derivatives of glucoside, and preparation method thereof |
| CN102704267A (en) * | 2012-04-05 | 2012-10-03 | 苏州百氏高化工有限公司 | Catalytic preparation method of environment-friendly alkaliproof refining agent |
-
2013
- 2013-09-17 CN CN201310424659.5A patent/CN103498336B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101440572A (en) * | 2008-12-29 | 2009-05-27 | 邵国标 | Environment protection type alkaliproof refining agent and preparation thereof |
| CN102618398A (en) * | 2012-02-15 | 2012-08-01 | 中国日用化学工业研究院 | Concentrated fabric liquid detergent containing fatty acid methyl ester sulfonate and preparation method of concentrated fabric liquid detergent |
| CN102631295A (en) * | 2012-03-30 | 2012-08-15 | 中国日用化学工业研究院 | Multifunctional foam liquid soap containing glucoside and derivatives of glucoside, and preparation method thereof |
| CN102704267A (en) * | 2012-04-05 | 2012-10-03 | 苏州百氏高化工有限公司 | Catalytic preparation method of environment-friendly alkaliproof refining agent |
Non-Patent Citations (1)
| Title |
|---|
| 醇醚糖苷微乳液相行为的研究;张远军 等;《精细化工》;20090430;第26卷(第3期);第230-234页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103498336A (en) | 2014-01-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103498337B (en) | A kind of application of environment-friendly type scouring agent | |
| CN101914848B (en) | Pre-treatment auxiliary agent for cotton knitted fabrics, preparation method and application thereof | |
| CN104532556B (en) | High-alkali-resistance type textile scouring agent and preparation method thereof | |
| JP5455483B2 (en) | Cleaning composition | |
| DE19839776B4 (en) | Detergent composition for fibers | |
| CN105803799B (en) | A kind of rope form pre-treating technology based on low alkali scouring agent | |
| CN107460728B (en) | High-efficiency low-foam refining agent and preparation method thereof | |
| CN103498336B (en) | A kind of environment-friendly type scouring agent | |
| CN105040423A (en) | Alkali-resisting spinning refining agent and preparation method thereof | |
| CN110079402A (en) | Compound alkaline foam cleaning agent of a kind of environment-friendly type and preparation method thereof | |
| EP2726186B1 (en) | Branched alkoxylate surfactant composition | |
| CN105176141A (en) | Activated dark blue to black dye compositioncombination and dye product | |
| DE2552353B2 (en) | LIQUID AQUATIC DETERGENT COMPOSITION | |
| DE102013218614A1 (en) | Detergent containing ether carboxylates | |
| CN105525509A (en) | Low-alkaline scouring agent for continuous rope scouring of cotton fabrics | |
| CN109797551A (en) | A kind of environmentally-friendly alkali resistant scouring agent and preparation method thereof | |
| CN106398903B (en) | A kind of hand-wash laundry liquid easily rinsed and preparation method thereof | |
| CN102888313B (en) | Infant laundry detergent | |
| DE2304060C3 (en) | Liquid detergent and cleaning agent compositions | |
| CN107988795A (en) | A kind of environment-friendly multipurpose scouring agent and preparation method thereof | |
| CN105001672A (en) | Orange disperse dye composition, disperse dye, and preparation method and uses of disperse dye | |
| JP2014141631A (en) | Liquid detergent composition for clothing | |
| CN108865486B (en) | Collar cleaner and preparation method thereof | |
| CN103334323A (en) | Wetting agent for textile fibers and preparation method thereof | |
| JP5694176B2 (en) | Nonionic surfactant and surfactant composition containing the same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160504 Termination date: 20180917 |