CN107988795A - A kind of environment-friendly multipurpose scouring agent and preparation method thereof - Google Patents
A kind of environment-friendly multipurpose scouring agent and preparation method thereof Download PDFInfo
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- CN107988795A CN107988795A CN201610949554.5A CN201610949554A CN107988795A CN 107988795 A CN107988795 A CN 107988795A CN 201610949554 A CN201610949554 A CN 201610949554A CN 107988795 A CN107988795 A CN 107988795A
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- fatty alcohol
- ether
- polyoxyethylene ether
- alcohol polyoxyethylene
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/368—Hydroxyalkylamines; Derivatives thereof, e.g. Kritchevsky bases
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
- D06M13/17—Polyoxyalkyleneglycol ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of environment-friendly multipurpose scouring agent and preparation method thereof.Consisting of:5 10% C12‑C14Fatty alcohol polyoxyethylene ether, 5 10% C8‑C10Fatty alcohol polyoxyethylene ether, 5 10% alkylamide, 5 10% sodium alkyl sulfonate, 10 15% amino alcohol, 10 15% C16‑C18Fatty alcohol polyoxyethylene ether, 10 15% C12‑C14Fatty alcohol polyoxyethylene polyoxypropylene ether, 15 50% water;Wherein, the aggregate number of polyoxyethylene ether is respectively 67,56,9 10,67, and the aggregate number of polyethenoxy ether is 23.The scouring agent of the present invention is not only permeated, emulsified, washing effect is good, and low bubble property and scattered anti-deposition are functional and environmentally protective.The scouring agent can be not only used for interval impregnation technology and continuous padding process, and move back one bath process of scouring and bleaching available for cold pad--batch.
Description
Technical field
The invention belongs to auxiliary chemicals technical field, is related to a kind of environment-friendly multipurpose scouring agent and preparation method thereof.
Background technology
It is required for before textile dyeing, stamp by certain scouring process, to remove the impurity and greasy dirt on cloth cover.
With chemically and physically method remove natural impurity on all kinds of textiles such as cotton, hair, fiber crops, silk and synthetic fibers, pollutant with
And weaving slurry technical process be called it is concise.And there is infiltration, emulsification, washing, scattered, wetting in all kinds of of concise middle addition
The auxiliary chemicals of function, are just called scouring agent.
Thus, inventionbroadly, acid, alkali, oxidant, reducing agent and various surfactants for being added in refinery practice etc.
Chemical substance can be called scouring agent.But in textile printing and dyeing industry, scouring agent is generally mentioned, it is the general of narrow sense mostly
Read, be primarily referred to as each anionoid, nonionic surfactant and appropriate additive, the method by certain proportioning obtains
To a kind of compound based on cleaning function, having the synergistic effect such as infiltration, emulsification, scattered, complexing concurrently.
Currently on the market in common textile printing and dyeing scouring agent, contain material influential on environment, such as alkane mostly
Base phenol polyoxyethylene ether(APEO), nonylphenol polyoxyethylenes ether(NPEO), neopelex(ABS), phosphate
Class chemicals, therefore, using the surfactant of environment-friendly type structure come to give replacement be the task of top priority.But it is not simple
With the material of environment-friendly type come compound refining agent can, it needs by longer time groping of being formulated and adjusts
Whole, more important is the test for carrying out application performance, a suitable formula is found out, to meet the concise needs of textile.
The content of the invention
It is an object of the present invention to overcome the deficiencies of the prior art and provide a kind of environmental-friendly, low efficient environment-friendly type of bubble
Multipurpose scouring agent and preparation method thereof.
The purpose of the present invention is what is be achieved through the following technical solutions:
A kind of environment-friendly multipurpose scouring agent of the present invention, it is formed by seven kinds of surfactants and water compounding, consisting of:
The C of 5-10%12-C14The C of fatty alcohol polyoxyethylene ether, 5-10%8-C10Fatty alcohol polyoxyethylene ether, the alkylamide of 5-10%, 5-
10% sodium alkyl sulfonate, the amino alcohol of 10-15%, the C of 10-15%16-C18The C of fatty alcohol polyoxyethylene ether, 10-15%12-C14Fat
Fat alcohol polyoxyethylene poly-oxygen propylene aether, and the water of 15-50%.
Wherein, the fatty alcohol is natural fatty alcohol;The C12-C14In fatty alcohol polyoxyethylene ether, polyoxyethylene ether
Aggregate number is 6-7;The C8-C10In fatty alcohol polyoxyethylene ether, the aggregate number of polyoxyethylene ether is 5-6;The C16-C18Fat
In fat alcohol polyoxyethylene ether, the aggregate number of polyoxyethylene ether is 9-10;The C12-C14Fatty alcohol polyoxyethylene polyoxypropylene ether
In, the aggregate number of polyoxyethylene ether is 6-7, and the aggregate number of polyethenoxy ether is 2-3.
Specifically, the molecular formula of above-mentioned seven kinds of surfactants is:
C12-C14Fatty alcohol polyoxyethylene ether:RO(C2H4O)nH, R=C12-14, n=6-7.
C8-C10Fatty alcohol polyoxyethylene ether:RO(C2H4O)nH, R=C8-10, n=5-6.
Alkylamide:RCONH2R=C18
Sodium alkyl sulfonate:RSO3Na R=C12-14
Amino alcohol:NH2C2H4OH or NH (C2H4OH)2
C16-C18Fatty alcohol polyoxyethylene ether:RO(C2H4O)nH, R=C16-18, n=9-10.
C12-C14Fatty alcohol polyoxyethylene polyoxypropylene ether:RO(C2H4O)n(C3H6O)mH, R=C12-14, n=6-7, m=2-3.
Specifically, the effect of above-mentioned each component is as follows:
The C12-C14Fatty alcohol polyoxyethylene ether, has good osmosis and washing effect.
The C8-C10Fatty alcohol polyoxyethylene ether, has good wetting action and osmotic effect.
The alkylamide, has good washing and foam stabilization effect.
The sodium alkyl sulfonate, has good emulsification and scourability.
The amino alcohol, has the function of good removing greasy dirt, can also adjust pH value.
The C16-C18Fatty alcohol polyoxyethylene ether, has excellent emulsification and disperses anti-deposition effect.
The C12-C14Fatty alcohol polyoxyethylene polyoxypropylene ether, in addition to scourability is excellent, also with low bubble, suds
Function.
The preparation method of environment-friendly multipurpose scouring agent of the present invention is as follows:Water and alkyl sulphur are first added in reaction kettle
Sour sodium is allowed to dissolve, and then sequentially adds C12-C14Fatty alcohol polyoxyethylene ether, C8-C10Fatty alcohol polyoxyethylene ether, C16-C18Fat
Fat alcohol polyoxyethylene ether, C12-C14Fatty alcohol polyoxyethylene polyoxypropylene ether, alkylamide, are eventually adding amino alcohol and adjust pH
Value, stirs 30-60 minutes at 50-60 DEG C of temperature, to obtain the final product.
Beneficial effects of the present invention:
The scouring agent of the present invention is formed by the surfactant compound of above-mentioned seven kinds of environment-friendly types, of the invention by above-mentioned seven
The surfactant compound of kind environment-friendly type together, has synergistic function;Obtained scouring agent is compounded, is not only had good
Infiltration, emulsification, scattered, washing effect, also there is low bubble, foam stabilizing, and with good scattered anti-deposition properties, it is most heavy
What is wanted is to human body and environmentally friendly, is a kind of environmental type auxiliary agent.
The present invention scouring agent be it is a kind of formed by the surfactant compound of environment-friendly type, for handling cellulose fibre
And its pre-treatment auxiliary agent of yarn fabric, suitable for the deoiling of cotton fabric, desizing, boiling-off and bleaching process, can moisten quick and completely
Wet fabric, and impurity is removed, it is a kind of good infiltration, washing, removal of impurities auxiliary agent.The product has good infiltration, emulsification, divides
The comprehensive performances such as scattered, washing.The product is concise at the uniform velocity, removal of impurities is good, has after use to the capillary effect and whiteness of fiber and carries greatly very much
It is high.Damage of the product to fiber is small, is had a good guarantee using the longitude and latitude strength of rear fiber.In addition, the scouring agent of the present invention
Interval impregnation technology and continuous padding process are cannot be only used for, and can also be used for cold pad--batch and move back one bath process of scouring and bleaching.Therefore, it is
A kind of multiduty scouring agent of environment-friendly type.
Embodiment
The present invention is further illustrated with reference to embodiments.
Embodiment 1
A kind of environment-friendly multipurpose scouring agent of the present invention, it is formed by seven kinds of surfactants and water compounding, consisting of:
5% C12-C14Fatty alcohol polyoxyethylene ether, 5% C8-C10Fatty alcohol polyoxyethylene ether, 5% alkylamide, 5% alkyl sulphur
Sour sodium, 10% amino alcohol, 10% C16-C18Fatty alcohol polyoxyethylene ether, 10% C12-C14Aliphatic alcohol polyethenoxy polyoxypropylene
Ether, and 50% water;Wherein, the fatty alcohol is natural fatty alcohol;The C12-C14In fatty alcohol polyoxyethylene ether, polyoxy
The aggregate number of vinethene is 6-7;The C8-C10In fatty alcohol polyoxyethylene ether, the aggregate number of polyoxyethylene ether is 5-6;It is described
C16-C18In fatty alcohol polyoxyethylene ether, the aggregate number of polyoxyethylene ether is 9-10;The C12-C14Aliphatic alcohol polyethenoxy polyoxy
In propylene ether, the aggregate number of polyoxyethylene ether is 6-7, and the aggregate number of polyethenoxy ether is 2-3.
The preparation method of above-mentioned environment-friendly multipurpose scouring agent:First water is added in reaction kettle and sodium alkyl sulfonate is allowed to molten
Solution, then sequentially adds C12-C14Fatty alcohol polyoxyethylene ether, C8-C10Fatty alcohol polyoxyethylene ether, C16-C18Fatty alcohol polyoxy second
Alkene ether, C12-C14Fatty alcohol polyoxyethylene polyoxypropylene ether, alkylamide, are eventually adding amino alcohol and adjust pH value, in temperature 50
Stir 60 minutes at DEG C, to obtain the final product.
Embodiment 2
A kind of environment-friendly multipurpose scouring agent of the present invention, it is formed by seven kinds of surfactants and water compounding, consisting of:
10% C12-C14Fatty alcohol polyoxyethylene ether, 10% C8-C10Fatty alcohol polyoxyethylene ether, 10% alkylamide, 10% alkane
Base sodium sulfonate, 15% amino alcohol, 15% C16-C18Fatty alcohol polyoxyethylene ether, 15% C12-C14Aliphatic alcohol polyethenoxy polyoxy
Propylene ether, and 15% water;Wherein, the fatty alcohol is natural fatty alcohol;The C12-C14In fatty alcohol polyoxyethylene ether,
The aggregate number of polyoxyethylene ether is 6-7;The C8-C10In fatty alcohol polyoxyethylene ether, the aggregate number of polyoxyethylene ether is 5-6;
The C16-C18In fatty alcohol polyoxyethylene ether, the aggregate number of polyoxyethylene ether is 9-10;The C12-C14Aliphatic alcohol polyethenoxy
In polyethenoxy ether, the aggregate number of polyoxyethylene ether is 6-7, and the aggregate number of polyethenoxy ether is 2-3.
The preparation method of above-mentioned environment-friendly multipurpose scouring agent:First water is added in reaction kettle and sodium alkyl sulfonate is allowed to molten
Solution, then sequentially adds C12-C14Fatty alcohol polyoxyethylene ether, C8-C10Fatty alcohol polyoxyethylene ether, C16-C18Fatty alcohol polyoxy second
Alkene ether, C12-C14Fatty alcohol polyoxyethylene polyoxypropylene ether, alkylamide, are eventually adding amino alcohol and adjust pH value, in temperature 60
Stir 30 minutes at DEG C, to obtain the final product.
Embodiment 3
A kind of environment-friendly multipurpose scouring agent of the present invention, it is formed by seven kinds of surfactants and water compounding, consisting of:
8% C12-C14Fatty alcohol polyoxyethylene ether, 7% C8-C10Fatty alcohol polyoxyethylene ether, 8% alkylamide, 7% alkyl sulphur
Sour sodium, 12% amino alcohol, 13% C16-C18Fatty alcohol polyoxyethylene ether, 12% C12-C14Aliphatic alcohol polyethenoxy polyoxypropylene
Ether, and 33% water;Wherein, the fatty alcohol is natural fatty alcohol;The C12-C14In fatty alcohol polyoxyethylene ether, polyoxy
The aggregate number of vinethene is 6-7;The C8-C10In fatty alcohol polyoxyethylene ether, the aggregate number of polyoxyethylene ether is 5-6;It is described
C16-C18In fatty alcohol polyoxyethylene ether, the aggregate number of polyoxyethylene ether is 9-10;The C12-C14Aliphatic alcohol polyethenoxy polyoxy
In propylene ether, the aggregate number of polyoxyethylene ether is 6-7, and the aggregate number of polyethenoxy ether is 2-3.
The preparation method of above-mentioned environment-friendly multipurpose scouring agent:First water is added in reaction kettle and sodium alkyl sulfonate is allowed to molten
Solution, then sequentially adds C12-C14Fatty alcohol polyoxyethylene ether, C8-C10Fatty alcohol polyoxyethylene ether, C16-C18Fatty alcohol polyoxy second
Alkene ether, C12-C14Fatty alcohol polyoxyethylene polyoxypropylene ether, alkylamide, are eventually adding amino alcohol and adjust pH value, in temperature 55
Stir 45 minutes at DEG C, to obtain the final product.
The character for the environment-friendly multipurpose scouring agent product that above-described embodiment 1-3 is compounded is as follows:
Appearance:Light yellow viscous liquid
Acid-base property:1% aqueous solution is in alkalescence, pH 7~9.
Dissolubility:It is soluble easily in water, it can be diluted in any proportion with water.
Characteristic:There is high osmosis energy to cellulose fibre, and have good scattered and washing ability, hydrophily is high, has anti-
Precipitation.
It is ionic:Anion
Stability:It is alkaline-resisting, acidproof, high temperature resistant, electrolyte-resistant.Intolerant to strong acid.
Mixed property:Can be mixed with anion and nonionic surfactant.
The physicochemical property for the environment-friendly multipurpose scouring agent product that above-described embodiment 1-3 is compounded is as follows:
The product can be used for interval impregnation technology and continuous padding process, it can also be used to and cold pad--batch moves back one bath process of scouring and bleaching,
It is 3-8 g/l to recommend dosage.
Make the scouring agent used time in cold-pad-batch process, reference formulation and technique are as follows:
Technological process:Two leachings two are rolled(Pick-up 80%)→ sealing stack stand 24 it is small when → with 80 DEG C of hot water wash three times
→ being washed once with cold water → hot water wash for 15min → 80 DEG C of soaping → being washed with cold water → is dried
Application test the result shows that:The environment-friendly multipurpose scouring agent product that above-described embodiment 1-3 is compounded, has good
The comprehensive performances such as infiltration well, emulsification, scattered, washing.The product is concise at the uniform velocity, removal of impurities is good, after use to the capillary effect of fiber
All improve a lot with whiteness.Damage of the product to fiber is small, is had a good guarantee using the longitude and latitude strength of rear fiber.
It can be seen from the above that the present invention environment-friendly multipurpose scouring agent product, not only with good infiltration, emulsification, disperse,
Washing effect, also has the function of low bubble, foam stabilizing, and is a kind of multiduty green ring with good scattered anti-deposition properties
Guarantor's type auxiliary agent.
Claims (9)
1. a kind of environment-friendly multipurpose scouring agent, it is characterised in that it is formed by seven kinds of surfactants and water compounding, it is formed
For:The C of 5-10%12-C14The C of fatty alcohol polyoxyethylene ether, 5-10%8-C10The alkyl of fatty alcohol polyoxyethylene ether, 5-10%
Acid amides, the sodium alkyl sulfonate of 5-10%, the amino alcohol of 10-15%, the C of 10-15%16-C18Fatty alcohol polyoxyethylene ether, 10-
15% C12-C14Fatty alcohol polyoxyethylene polyoxypropylene ether, and the water of 15-50%.
2. environment-friendly multipurpose scouring agent as claimed in claim 1, it is characterised in that consisting of:5% C12-C14Fat
Alcohol polyoxyethylene ether, 5% C8-C10Fatty alcohol polyoxyethylene ether, 5% alkylamide, 5% sodium alkyl sulfonate, 10%
Amino alcohol, 10% C16-C18Fatty alcohol polyoxyethylene ether, 10% C12-C14Fatty alcohol polyoxyethylene polyoxypropylene ether, and
50% water.
3. environment-friendly multipurpose scouring agent as claimed in claim 1, it is characterised in that consisting of:10% C12-C14Fat
Alcohol polyoxyethylene ether, 10% C8-C10Fatty alcohol polyoxyethylene ether, 10% alkylamide, 10% sodium alkyl sulfonate, 15%
Amino alcohol, 15% C16-C18Fatty alcohol polyoxyethylene ether, 15% C12-C14Fatty alcohol polyoxyethylene polyoxypropylene ether, with
And 15% water.
4. the environment-friendly multipurpose scouring agent as described in claim 1,2 or 3, it is characterised in that the fatty alcohol is natural grease
Fat alcohol.
5. environment-friendly multipurpose scouring agent as claimed in claim 4, it is characterised in that the C12-C14Aliphatic alcohol polyethenoxy
In ether, the aggregate number of polyoxyethylene ether is 6-7.
6. environment-friendly multipurpose scouring agent as claimed in claim 4, it is characterised in that the C8-C10Aliphatic alcohol polyethenoxy
In ether, the aggregate number of polyoxyethylene ether is 5-6.
7. environment-friendly multipurpose scouring agent as claimed in claim 4, it is characterised in that the C16-C18Aliphatic alcohol polyethenoxy
In ether, the aggregate number of polyoxyethylene ether is 9-10.
8. environment-friendly multipurpose scouring agent as claimed in claim 4, it is characterised in that the C12-C14Aliphatic alcohol polyethenoxy
In polyethenoxy ether, the aggregate number of polyoxyethylene ether is 6-7, and the aggregate number of polyethenoxy ether is 2-3.
9. the preparation method of a kind of environment-friendly multipurpose scouring agent as described in claim 1-8 is any, it is characterised in that first exist
Water is added in reaction kettle and sodium alkyl sulfonate is allowed to dissolve, and then sequentially adds C12-C14Fatty alcohol polyoxyethylene ether, C8-C10Fat
Fat alcohol polyoxyethylene ether, C16-C18Fatty alcohol polyoxyethylene ether, C12-C14Fatty alcohol polyoxyethylene polyoxypropylene ether, alkylamide,
Be eventually adding amino alcohol and adjust pH value, stir 30-60 minutes at 50-60 DEG C of temperature, to obtain the final product.
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Cited By (2)
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CN108611863A (en) * | 2018-05-17 | 2018-10-02 | 苏州联胜化学有限公司 | A kind of without phosphorus nitrogen-free type scouring agent and its preparation and application |
CN109267393A (en) * | 2018-07-26 | 2019-01-25 | 浙江丝科院轻纺材料有限公司 | A kind of preparation method of the oil removing level dyeing compound emulsifying agent for dacron |
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Application publication date: 20180504 |