CN109629271A - A kind of anti-staining soaping agent and preparation method thereof - Google Patents
A kind of anti-staining soaping agent and preparation method thereof Download PDFInfo
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- CN109629271A CN109629271A CN201811567287.0A CN201811567287A CN109629271A CN 109629271 A CN109629271 A CN 109629271A CN 201811567287 A CN201811567287 A CN 201811567287A CN 109629271 A CN109629271 A CN 109629271A
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- staining
- soaping agent
- staining soaping
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/10—After-treatment with compounds containing metal
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/06—After-treatment with organic compounds containing nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/08—After-treatment with organic compounds macromolecular
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
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Abstract
The present invention relates to a kind of anti-staining soaping agents, it as mass fraction include: 3-7% isomeric alcohol polyethenoxy ether, 10-20% poly-epoxy succinic acid, 0.1-3% polyvinylpyrrolidone, 0.5-2% aluminum magnesium silicate, 20-30% zeolite powder, 1-2% ethoxylated alkyl sulfate, 1-4% fatty acid distribution of coconut oil diglycollic amide；0.1-1% defoaming agent, surplus are water.The invention further relates to a kind of preparation methods of anti-staining soaping agent.The anti-staining soaping agent can be effectively prevented the staining of dyestuff, improve the washing effect of fabric and the anti-staining effect of white background PRINTED FABRIC.
Description
Technical field
The present invention relates to textile auxiliary fields, and in particular to a kind of anti-staining soaping agent and preparation method thereof.
Background technique
Fabric is washed, after carrying out dyeing or stamp to remove cloth cover loose colour.A large amount of dye is had in the process
Material, slurry and alkaline agent, enter in water lotion from fabric, it is easy to carry out staining to fabric.Especially stamp class product is same
It can generate and cut marks because returning staining in water-washing process, thus to fabric simultaneously containing the dyestuff of different colours on one piece of fabric
Quality causes very big influence.
Anti-staining soaping agent is suspended by dispersion, and complexing makes dyestuff is no longer counter to be stained on fabric, to reach
Improve the purpose of soaping fastness and anti-staining.Conventional method mainly debugs soaping method using the test of multiple hand sample dyeing and constantly
And kind solves the problems, such as the staining of dyestuff.But time-consuming for debugging process, and stable product quality is poor, there is apparent office
It is sex-limited.
Current existing anti-staining soaping agent type is more, and researcher has carried out many researchs to such technology.Such as CN
107151929 A disclose a kind of stamp anti-staining soaping agent, are grouped as by each group of following parts by weight: 20-45 parts of ammonium stearate,
25-35 parts of polyoxyethylene, 10-20 parts of Dodecyl Polyoxyethylene Ether, 1-5 parts of sorbierite, 0.1-2 parts of methylisothiazolinone, water
12-25 parts.105625061 A of CN discloses a kind of anti-staining saponification agent of anionic dye, by 200-250 parts of fatty amine polyoxy second
Alkene ether, 20-25 parts of benzyl chlorides, 10-20 parts of sodium secondary alkyl sulfonate, 18-20 parts of fatty alcohol polyoxyethylene ether, 2-5 parts of sodium hydroxides,
It is formed with 680-750 parts of water.103642600 A of CN discloses a kind of anti-staining soaping agent for printing of an activated dye, by following raw material system
At: 20-60 parts of aliphatic amine polyoxyethylene ethers of parts by weight, 1-3 parts of alkylating agents, 0.1-2 parts of stabilizers, 30-70 parts of water and 2-
10 parts of polyvinylpyrrolidones.
Although anti-dyestuff staining soaping agent is many kinds of, existing anti-staining soaping agent is in actual production and use process
In it is restricted more, anti-staining effect is poor.
Summary of the invention
In view of the above-mentioned deficiencies in the prior art, it is an object of the present invention to provide a kind of anti-staining soaping agent, can effectively mention
High anti-staining effect.
Technical solution provided by the present invention are as follows:
A kind of anti-staining soaping agent includes: as mass fraction
Anti-staining soaping agent in the present invention selects suitable raw material composition and raw material proportioning, passes through mutual association
Same-action has excellent chelating, dispersion and emulsifying capacity.It can be effectively prevented the staining of dyestuff when soaping, improve fabric
Washing effect and white background PRINTED FABRIC anti-staining effect.The anti-staining soaping agent can be used for reactive dyeing or stamp produces
Product soap during anti-return staining, it can also be used to modified polyester fiber is stained with anti-return in cotton fiber blended fabric dyeing course
Color.
Wherein, poly-epoxy succinic acid is a kind of without phosphorus, non-nitrogen environmental type water-soluble polymer.With good resistance
Dirty dispersion performance effectively inhibits intergranular reunion.In addition, poly-epoxy succinic acid can reduce Ca in water2+、Mg2+、Cu2+、Fe2+
Influence of the equal metal ions to fabric quality, has protective effect to fiber, is remarkably improved whiteness, eliminate macula lutea phenomenon.
Aluminum magnesium silicate is that a kind of specific surface area is very big, and the very flourishing substance of micropore system can be used as adsorbent,
As thickener.
Polyvinylpyrrolidone has anti-dirt reprecipitation performance, and washing ability can be enhanced.
Ethoxylated alkyl sulfate has excellent decontamination, emulsification, foam performance and hard water resistance performance, and character is mild,
Biological degradability is good.
Fatty acid distribution of coconut oil diglycollic amide has good thickening, foam enhancing and foam stability energy, has good emulsification, decontamination
Ability.There are good compatibility and synergistic effect with other surfactants.
Heretofore described isomeric alcohol polyethenoxy ether is selected from heterogeneous ten alcohol polyoxyethylene ether, isomerous tridecanol polyoxyethylene
One or both of ether.
Preferably, the isomeric alcohol polyethenoxy ether is selected from one of XP-50, XP-70, TO-7, TO-10 or more
Kind.
Heretofore described zeolite powder is 4A zeolite.The adsorption ability of 4A zeolite is strong, is ideal adsorbent.This hair
The adsorption function of function and strength is mainly washed in bright using its environmentally friendly helping.
Heretofore described defoaming agent is silicon ether-ether class defoaming agent.The antifoaming speed of silicon ether-ether class defoaming agent is fast, and disappear foam inhibition
It has excellent performance, and high temperature resistant.The DS-DEFOMER 4090 that silicon ether-ether class defoaming agent can be contained for Nanjing moral.
As one of preferred, described anti-reactive dye staining soaping agent, include: as mass fraction
As one of preferred, described anti-reactive dye staining soaping agent, include: as mass fraction
Further preferably, the anti-reactive dye staining soaping agent includes: as mass fraction
The present invention also provides a kind of preparation methods of anti-staining soaping agent, comprising:
1) 40-45 DEG C of temperature is controlled, bottom water is added in a kettle, sequentially adds isomeric alcohol polyethenoxy ether while stirring
And poly-epoxy succinic acid, it adds and is sufficiently stirred, make it completely dissolved；
2) continue that polyvinylpyrrolidone is added while stirring, add and stir, make it completely dissolved；
3) it then proceedes to stirring and sequentially adds defoaming agent, aluminum magnesium silicate, zeolite powder, ethoxylated alkyl sulfate and cocounut oil
Fatty diglycollic amide stirs evenly, and is diluted with water according to required content to obtain the final product.
Compared with the existing technology, the beneficial effects of the present invention are embodied in:
(1) anti-staining soaping agent provided by the present invention can improve textile wet-milling product quality and improve dye shade
Reproducibility, and be widely used.
(2) loose colour that anti-staining soaping agent provided by the present invention can effectively on hydrolaced fabrics, improves fabric dry and wet
Crock fastness, time, the energy, water consume and sewage expense can be saved by soaping for reactive dye.During soaping, it effectively prevent
The reactive dye for being easy to staining are above contaminated on secondary color calico again.
(3) anti-staining soaping agent provided by the present invention, technique is very simple, and raw material is easy to get, environmentally protective, at low cost,
The stability for the anti-staining soaping agent being prepared is good.
Specific embodiment
Below by specific embodiment, present invention will be explained in further detail.
Embodiment 1
Raw material is as follows as mass fraction:
Complex process is as follows:
(1) 40-45 DEG C of temperature is controlled, 54.7% bottom water is added in a kettle, sequentially adds XP-50, XP- while stirring
70 and poly-epoxy succinic acid (PESA), it adds and is sufficiently stirred, make it completely dissolved.
(2) it is slowly added into polyvinylpyrrolidone PVP-K30 while stirring, adds and stirs, makes it completely
Dissolution.
(3) continue stirring and sequentially add silicon ether-ether class defoaming agent, aluminum magnesium silicate, 4A zeolite, ethoxylated alkyl sulfate
With fatty acid distribution of coconut oil diglycollic amide, after mixing evenly to get anti-staining soaping agent.
Embodiment 2
The complex process of anti-staining soaping agent includes: as mass fraction with embodiment 1
Embodiment 3
The complex process of anti-staining soaping agent includes: as mass fraction with embodiment 1
Embodiment 4
The complex process of anti-staining soaping agent includes: as mass fraction with embodiment 1
Embodiment 5
The complex process of anti-staining soaping agent includes: as mass fraction with embodiment 1
Comparative example 1
Commercially available common anti-staining soaping agent main component are as follows: polyvinylpyrrolidone 15%, horse propylene copolymer 25%, isomery
Tridecanol polyoxyethylene ether 9%, peroxidase 1% and water 50%.
Comparative example 2
Commercially available common anti-staining soaping agent main component are as follows: alkyl halide ammonium salt 5%, polyvinylpyrrolidone 25%, rouge
Fat amine polyoxyethylene ether 12%, alkyl phenol and ethylene oxide condensate 15% and water 43%.
Performance test
To soap effect and the anti-staining effect of Examples 1 to 5, comparative example 1~2 and blank control (soaping agent is not added)
Two main performance index compare test.
The dyestuff of this test is active red 3BF 100%.Dyeing: bath of dye liquor ratio is 1:50, dye dosage 2%
(owf).Water temperature rises to 30 DEG C and sequentially adds dyestuff, anhydrous sodium sulphate 50g/L, enters dye after mixing evenly, 60 DEG C are risen to after 10min, protect
Warm 10min adds soda ash 15s/L, 60 DEG C of constant temperature fixation 90min.
Test method: stained clot-h is put into cold water washing, then 50 DEG C of hot water wash 10min again, prepare 2g/L soaping agent
It soaps liquid, stained clot-h and stickers lining cloth is put into the liquid of soaping simultaneously and soaped, 95 DEG C of 30min that soap then will dyeing
Cloth and stickers lining cloth take out, then with 60 DEG C of hot water wash 10min, are finally rinsed with cold water, dry it at 60 DEG C, test the dyeing
The colorfastness to rubbing of cloth, and the staining depth of stickers lining cloth is observed, to judge releasing fastness.
Soap effective evaluation method: colorfastness to rubbing test method is carried out referring to GB/T3920, if colorfastness to rubbing grade
It is higher, then show that the effect of soaping of soaping agent is better.The K/S value of fabric is lower after soaping, and liquid absorbance of soaping is bigger, shows soap
The effect of lotion is better.
Releasing fastness assessment method: the staining depth of observation stickers lining cloth shows soaping agent if releasing festness ratings are higher
Anti- staining effect it is better.
The results are shown in Table 1 for performance test:
Table 1 is embodiment 1-5 and the properties of comparative example 1~2 compare
According to table 1 as can be seen that anti-staining soaping agent effect of the invention is better than commercially available soaping agent, especially embodiment
3 soap effect and anti-staining effect has good application value than more prominent.
Claims (8)
1. a kind of anti-staining soaping agent, which is characterized in that include: as mass fraction
2. anti-staining soaping agent according to claim 1, which is characterized in that the isomeric alcohol polyethenoxy ether is selected from isomery
One or both of ten alcohol polyoxyethylene ether, isomerous tridecanol polyoxyethylene ether.
3. anti-staining soaping agent according to claim 1, which is characterized in that the isomeric alcohol polyethenoxy ether is selected from XP-
50, one of XP-70, TO-7, TO-10 or a variety of.
4. anti-staining soaping agent according to claim 1, which is characterized in that the zeolite powder is 4A zeolite.
5. anti-staining soaping agent according to claim 1, which is characterized in that the defoaming agent is silicon ether-ether class defoaming agent.
6. anti-staining soaping agent according to claim 1, which is characterized in that include: as mass fraction
7. anti-staining soaping agent according to claim 1, which is characterized in that include: as mass fraction
8. a kind of preparation method of anti-staining soaping agent characterized by comprising
1) 40-45 DEG C of temperature is controlled, bottom water is added in a kettle, sequentially add isomeric alcohol polyethenoxy ether while stirring and is gathered
Epoxysuccinic acid is added and is sufficiently stirred, and is made it completely dissolved；
2) continue that polyvinylpyrrolidone is added while stirring, add and stir, make it completely dissolved；
3) it then proceedes to stirring and sequentially adds defoaming agent, aluminum magnesium silicate, zeolite powder, ethoxylated alkyl sulfate and coconut oil fat
Sour diglycollic amide, stirs evenly, and is diluted with water according to required content to obtain the final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811567287.0A CN109629271A (en) | 2018-12-20 | 2018-12-20 | A kind of anti-staining soaping agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811567287.0A CN109629271A (en) | 2018-12-20 | 2018-12-20 | A kind of anti-staining soaping agent and preparation method thereof |
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| CN109629271A true CN109629271A (en) | 2019-04-16 |
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| CN201811567287.0A Pending CN109629271A (en) | 2018-12-20 | 2018-12-20 | A kind of anti-staining soaping agent and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111118936A (en) * | 2020-01-03 | 2020-05-08 | 湖南金全立生物科技股份有限公司 | Multifunctional green environment-friendly dye-proofing agent and preparation method thereof |
| CN112695549A (en) * | 2020-12-28 | 2021-04-23 | 浙江震东新材料有限公司 | Low-temperature soaping agent for printing of reactive dye and preparation method thereof |
| CN114645475A (en) * | 2022-03-25 | 2022-06-21 | 广州市德鹏新材料科技有限公司 | Dye-resistant agent for washing jean fabric and preparation method thereof |
| CN115679725A (en) * | 2022-11-18 | 2023-02-03 | 浙江红利集团有限公司 | Low-temperature soaping agent and soaping process for dyed fabric |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111118936A (en) * | 2020-01-03 | 2020-05-08 | 湖南金全立生物科技股份有限公司 | Multifunctional green environment-friendly dye-proofing agent and preparation method thereof |
| CN112695549A (en) * | 2020-12-28 | 2021-04-23 | 浙江震东新材料有限公司 | Low-temperature soaping agent for printing of reactive dye and preparation method thereof |
| CN112695549B (en) * | 2020-12-28 | 2022-07-29 | 浙江震东新材料有限公司 | Low-temperature soaping agent for reactive dye printing and preparation method thereof |
| CN114645475A (en) * | 2022-03-25 | 2022-06-21 | 广州市德鹏新材料科技有限公司 | Dye-resistant agent for washing jean fabric and preparation method thereof |
| CN114645475B (en) * | 2022-03-25 | 2024-01-26 | 广州市德鹏新材料科技有限公司 | Dyeing resist for jean fabric washing and preparation method thereof |
| CN115679725A (en) * | 2022-11-18 | 2023-02-03 | 浙江红利集团有限公司 | Low-temperature soaping agent and soaping process for dyed fabric |
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Application publication date: 20190416 |