JPH01152199A - Detergent composition for hard water - Google Patents

Abstract

PURPOSE:To obtain the present composition having excellent (persistent) foaming ability and detergency even in hard water, by mixing a polyoxyethylene alkyl ether sulfonate, an alkylamine oxide, a fatty acid amide alkyl betaine. CONSTITUTION:0.1-90.0wt.% polyoxyethylene alkyl ether sulfonate (A) of formula I (wherein R is 8-20C straight-chain or branched alkyl or alkenyl; n is 1-30; X is Na, K, NH3, monoethanolamine, diethanolamine or triethanolamine) [e.g., a sodium polyoxyethylene (15 E.O.) alkyl (12-14C) ether sulfonate] is mixed with 0.1-99.8wt.% alkylamine oxide (B) of formula II (wherein R1 is R; R2 is CH3 or hydroxyethyl) (e.g., lauryldimethylamine oxide) and 0.1-99.8wt.% fatty acid amide alkyl betaine (C) of formula III (wherein n is 1-8) (e.g., a coconut oil fatty acid amide propyl betaine).

Description

Detailed Description of the Invention (Field of Industrial Application) The present invention relates to a cleaning composition for hard water, and its purpose is to foam the same level as normal soft water even in so-called hard water such as hot springs, seawater, and mineral water. The purpose of the present invention is to provide a detergent composition for hard water that has excellent cleaning power, detergency, and foaming retention.

(Conventional technology) Conventionally, there are no cleaning agents that can be effectively used for hard water.

Metal ions and metal salts in hard water work to increase surface tension, or chemically and physically combine with detergents, lowering surfactant power, and furthermore, they become insoluble and precipitate. This is because it works in a similar manner.

By the way, the cleaning ability of a detergent, not only in hard water but also in soft water, is determined by its foaming power (foaming height) and foaming maintenance power (time).
, the suspending power of fats and oils, the fineness of foam, and the property of not forming scum must be fully satisfied.

However, for hard water, especially hard water with high concentrations of metal ions such as hot springs and seawater, and hard water saturated with metal ions such as Dead Sea water, the cleaning agents that currently exist and can be used are There is no such thing as satisfying all of the conditions.

In fact, some detergents for hard water contain metal chelating agents such as metapolyphosphoric acid.

These phosphoric acid-based detergents are not desirable as they cause excessive nutrient enrichment of the water quality, and their cleaning efficacy is also limited. As mentioned above, this cleaning agent could not be used in hard water such as seawater with a high concentration of metal ions.

Therefore, it can be said that there are currently no suitable hot spring detergents, seawater detergents, etc.

(Problem to be solved) Therefore, in light of the above-mentioned conventional circumstances, the inventors have determined that the foaming power, foaming sustaining power, oil and fat suspending power, ease of rinsing, fineness of foam, and conditions under which scum is not generated. We set out to develop a hard water detergent with excellent performance.

(Means for solving the invention) That is, the present invention provides that the polyoxyethylene alkyl ether sulfonate represented by the following formula (1) is
．． 0 wt%, 0.1 to 99.8 wt% of the alkylamine oxide represented by the following formula (2), and 0.1 to 99.8 wt% of the fatty acid amide alkyl betaine represented by the following formula (3).
By providing a hard water detergent composition in which each of the above-mentioned detergent compositions contains t%, we succeeded in creating a hard water detergent composition that has all the characteristics of the above detergent.

R-(OCHzCHz)n-5O3-X
...' (1) (However, in the formula, R is a linear or branched alkyl group or alkenyl group of C8 to C!, and n is 1 to
An integer of 30, X is sodium, potassium, ammonia,
Indicates monoethanolamine, jetanolamine, or triethanolamine. ) R, -N→0...(2) (However, in the formula, R represents a C8 to C2° linear or branched alkyl group or alkenyl group, or R2 represents a methyl group or a hydroxyethyl group, respectively. )? H. (However, in the formula, R is a C8 to C2° straight-chain or branched alkyl group or alkenyl group, and n is an integer of 1 to 8.) (Structure of the Invention) The structure of this invention will be explained in detail below. do.

The polyoxyethylene alkyl ether sulfonate (formula (1) below) preferably used in this invention may be one or a mixture of one or more of the substances listed below.

A specific example when X is sodium.

Polyoxyethylene (1-30 EO) Avocado oil Sodium alkyl ether sulfonate, Polyoxyethylene (1-30 EO) Almond oil Sodium alkyl ether sulfonate, Polyoxyethylene (1-3080)
Fur seal oil alkyl ether sulfonate sodium,
Polyoxyethylene (1~30EO) Sodium Hypericum oil alkyl ether sulfonate, Polyoxyethylene (1~30EO) Sodium oricaoyl alkyl ether sulfonate, Polyoxyethylene (1~30E
O) Sodium olive oil alkyl ether sulfonate,
Polyoxyethylene (1-3011!0) Sodium cocoa butter alkyl ether sulfonate, polyoxyethylene (1-30EO) Sodium carrot oil alkyl ether sulfonate, polyoxyethylene (1-3020)
Calope oil sodium alkyl ether sulfonate, polyoxyethylene (1-30 EO) liver oil sodium alkyl ether sulfonate, polyoxyethylene (1-3
0 EO) Cucumber oil sodium alkyl ether sulfonate, polyoxyethylene (1-30 EO) Sodium tallow alkyl ether sulfonate, polyoxyethylene (1-30 EO) Strong liver oil sodium alkyl ether sulfonate, polyoxyethylene (1-30 EO)
Kyonin oil sodium alkyl ether sulfonate,
Polyoxyethylene (1~30EO) Hydrogenated oil Sodium alkyl ether sulfonate, Polyoxyethylene (1~30EO)
~30 EO) Synthetic cocoa butter sodium alkyl ether sulfonate, polyoxyethylene (1~30 EO) Sesame oil sodium alkyl ether sulfonate, polyoxyethylene (1~30 EO) Wheat germ oil sodium alkyl ether sulfonate, polyoxyethylene (1~30 EO) 30
EO) Sodium rice bran oil alkyl ether sulfonate, polyoxyethylene (1-30 EO) Rice germ oil sodium alkyl ether sulfonate, polyoxyethylene (1-30 EO) Sodium sasanqua oil alkyl ether sulfonate, polyoxyethylene (1-30 EO)
) Sodium safflower oil alkyl ether sulfonate, polyoxyethylene (1-30 EO) Sodium alkyl ether sulfonate, polyoxyethylene (1-30 EO) Sodium safflower oil alkyl ether sulfonate, polyoxyethylene (1-30 EO)
Hydrogenated cocoa butter alkyl ether sulfonate sodium, polyoxyethylene (1-30 EO) hydrogenated liver oil sodium alkyl ether sulfonate, polyoxyethylene (1-30 EO) soybean oil sodium alkyl ether sulfonate, polyoxyethylene (1-30 EO) ) Turtle oil sodium alkyl ether sulfonate, polyoxyethylene (1-30 EO) Tea seed oil sodium alkyl ether sulfonate, polyoxyethylene (1-30 EO)
EO) Sodium camellia oil alkyl ether sulfonate, polyoxyethylene (1-30 EO)) Sodium corn oil alkyl ether sulfonate, polyoxyethylene (1-30 EO) Sodium rapeseed oil alkyl ether sulfonate, polyoxyethylene (1-30 EO)
O) Sodium milk fat alkyl ether sulfonate, polyoxyethylene (1-301 EO) sodium persic oil alkyl ether sulfonate, polyoxyethylene (1-30 EO) sodium palm oil alkyl ether sulfonate, polyoxyethylene (1-30 EO) bean nuts Sodium oil alkyl ether sulfonate, polyoxyethylene (1 to 30 EO) Sodium castor oil alkyl ether sulfonate, polyoxyethylene (1 to 30 EO)
~30 EO) Sunflower oil sodium alkyl ether sulfonate, polyoxyethylene (1~30 EO) Grape oil sodium alkyl ether sulfonate, polyoxyethylene (1~30 EO) Piper oil sodium alkyl ether sulfonate, polyoxyethylene (1~30 EO)
EO) Marmot oil sodium alkyl ether sulfonate, polyoxyethylene (1-30T!0) Mink oil sodium alkyl ether sulfonate, polyoxyethylene (1-30EO) Cottonseed oil sodium alkyl ether sulfonate, polyoxyethylene (1-30E
O) Sodium pomegranate alkyl ether sulfonate,
Polyoxyethylene (1 to 30 EO) Sodium Coco Alkyl Ether Sulfonate, Polyoxyethylene (1 to 30 EO)
~30EO) Sodium egg yolk oil alkyl ether sulfonate, polyoxyethylene (1~30EO) Sodium nonyl ether sulfonate, polyoxyethylene (1~30EO)
30EO) Sodium nonenyl ether sulfonate, polyoxyethylene (1~30t!O) Sodium decyl ether sulfonate, polyoxyethylene (1~30E
O) Sodium decenyl ether sulfonate, polyoxyethylene (1-30 EO) Sodium undecyl ether sulfonate, polyoxyethylene (1-30 EO)
Sodium randecylenyl ether sulfonate, polyoxyethylene (1-30EO) Sodium dodecyl ether sulfonate, polyoxyethylene (1-30E
O) Sodium dodecenyl ether sulfonate, polyoxyethylene (1-3011:0)) Sodium lysosyl ether sulfonate, polyoxyethylene (
) Sodium lysocenyl ether sulfonate, polyoxyethylene (1-30 EO) sodium tetradecyl ether sulfonate, polyoxyethylene (1-30 EO) sodium tetradecenyl ether sulfonate, polyoxyethylene (1-30 EO) ) Sodium pentadecyl ether sulfonate, polyoxyethylene (1-30 EO) Sodium pentadecenyl ether sulfonate, polyoxyethylene (1-30 EO
) Sodium hexadecyl ether sulfonate, polyoxyethylene (1-301!O) Sodium hexadecenyl ether sulfonate, polyoxyethylene (1-3
0EO) sodium heptadecyl ether sulfonate,
Polyoxyethylene (1~30EO) Sodium octadecyl ether sulfonate, polyoxyethylene (1~30EO)
30EO) sodium octadecenyl ether sulfonate, polyoxyethylene (1-30EO) sodium octadecenyl ether sulfonate, polyoxyethylene (1-30EO) sodium octadecenyl ether sulfonate, polyoxyethylene (1-301
! 0) Sodium octadecatetraenyl ether sulfonate, polyoxyethylene (1-30 EO) sodium nonadecyl ether sulfonate, polyoxyethylene (1-3080) sodium eicosyl ether sulfonate, polyoxyethylene (1-30 EO) eico Sodium satetraenyl ether sulfonate, polyoxyethylene (1-30 EO) Sodium eicosapentaenyl ether sulfonate, polyoxyethylene (1-3 EO)
0EO) sodium heneicosyl ether sulfonate, etc.

A specific example when X is potassium.

Polyoxyethylene (1-30EO) Avocado oil Potassium alkyl ether sulfonate, Polyoxyethylene (
1-30 EO) Potassium aluminum alkyl ether sulfonate, polyoxyethylene (1-30 EO) Potassium seal oil alkyl ether sulfonate, polyoxyethylene (1-30 EO) Potassium hypericum oil alkyl ether sulfonate, polyoxyethylene (1-30 EO)
-30 EO) Potassium orica oil alkyl ether sulfonate, polyoxyethylene (1-30 EO) Potassium olive oil alkyl ether sulfonate, polyoxyethylene (1-30 EO) Potassium cocoa butter alkyl ether sulfonate, polyoxyethylene (1-30 EO) )
Potassium carot oil alkyl ether sulfonate, polyoxyethylene (1-30HO) Potassium carob oil alkyl ether sulfonate, polyoxyethylene (1-30HO)
30EO) Potassium liver oil alkyl ether sulfonate,
Polyoxyethylene (1-30 EO) potassium cucumber alkyl ether sulfonate, polyoxyethylene (1-30 EO) potassium tallow alkyl ether sulfonate, polyoxyethylene (1-30 EO) strong liver oil potassium alkyl ether sulfonate, polyoxyethylene (1 to 30 EO) Potassium kyonin oil alkyl ether sulfonate, polyoxyethylene (1 to 30 EO
) Hydrogenated oil Potassium alkyl ether sulfonate, polyoxyethylene (1-30EO) Synthetic cocoa butter Potassium alkyl ether sulfonate, Polyoxyethylene (1-30EO)
30 EO) Potassium sesame oil alkyl ether sulfonate, polyoxyethylene (1~30 HO") Wheat germ oil potassium alkyl ether sulfonate, polyoxyethylene (1~30 EO) Potassium rice bran oil alkyl ether sulfonate, polyoxyethylene (1~30 EO") ) Potassium rice germ oil alkyl ether sulfonate, polyoxyethylene (1 to 30 EO) Potassium sasanquat oil alkyl ether sulfonate, polyoxyethylene (1 to 3
0 EO) Potassium safflower oil alkyl ether sulfonate, polyoxyethylene (1-30 EO) Potassium shea alkyl ether sulfonate, polyoxyethylene (1-30 EO) Potassium safflower oil alkyl ether sulfonate, polyoxyethylene (1-30 EO) 30EO
) Potassium hydrogenated cocoa butter alkyl ether sulfonate, polyoxyethylene (1-30 EO) Potassium hydrogenated cod liver oil alkyl ether sulfonate, polyoxyethylene (1-30 EO) Potassium soybean oil alkyl ether sulfonate, polyoxyethylene (1 ~30EO) Turtle oil potassium alkyl ether sulfonate, polyoxyethylene (1~30EO) Tea-based potassium alkyl ether sulfonate, polyoxyethylene (1~3011!O
) Potassium camellia oil alkyl ether sulfonate, polyoxyethylene (1-30Eo) Corn oil potassium alkyl ether sulfonate, polyoxyethylene (
1-30 EO) rapeseed oil potassium alkyl ether sulfonate, polyoxyethylene (1-3011!O) milk fat potassium alkyl ether sulfonate, polyoxyethylene (1-30 EO) persic oil potassium alkyl ether sulfonate, polyoxyethylene (1-301!O) 30EO)
Potassium palm oil alkyl ether sulfonate, polyoxyethylene (1 to 30 EO) Potassium peanut oil alkyl ether sulfonate, polyoxyethylene (1 to 30 EO)
30 EO) Potassium castor oil alkyl ether sulfonate, polyoxyethylene (1-301 EO) Potassium sunflower oil alkyl ether sulfonate, polyoxyethylene (1-30 EO) Potassium grape oil alkyl ether sulfonate, polyoxyethylene (1-30 EO) Potassium marmot oil alkyl ether sulfonate, polyoxyethylene (1-30EO) Marmot oil alkyl ether 2 Potassium tylsulfonate, polyoxyethylene (
1-30 EO) Potassium mink oil alkyl ether sulfonate, polyoxyethylene (1-30 EO) Potassium cottonseed oil alkyl ether sulfonate, polyoxyethylene (1-30 EO) Potassium alkyl ether sulfonate, polyoxyethylene (1-30 EO) )
Potassium coconut oil alkyl ether sulfonate, polyoxyethylene (1-30EO)Egg yolk oil potassium alkyl ether sulfonate, polyoxyethylene (1-30EO
) Potassium nonenyl ether sulfonate, polyoxyethylene (1 to 30 EO) Potassium nonenyl ether sulfonate, polyoxyethylene (1 to 30 EO) Potassium decyl ether sulfonate, polyoxyethylene (1 to 3
0EO) Potassium decenyl ether sulfonate, polyoxyethylene (1-30EO) Potassium undecyl ether sulfonate, polyoxyethylene (1-301!O
) Potassium randecylenyl ether sulfonate, polyoxyethylene (1-30 EO) Potassium dodecyl ether sulfonate, polyoxyethylene (1-30 EO)
Potassium dodecenyl ether sulfonate, polyoxyethylene (1-30 EO) Potassium tridecyl ether sulfonate, polyoxyethylene (1-30 EO)
) Potassium lysocenyl ether sulfonate, polyoxyethylene (1-30 EO) potassium tetradecyl ether sulfonate, polyoxyethylene (1-30 EO) potassium tetradecenyl ether sulfonate, polyoxyethylene (1-30 EO) pentadecyl ether Potassium sulfonate, polyoxyethylene (1-30 EO) potassium pentadecenyl ether sulfonate, polyoxyethylene (1-30 EO) potassium hexadecyl ether sulfonate, polyoxyethylene (1-3010) hexadecenyl ether sulfonic acid Potassium, polyoxyethylene (1-30 EO) potassium heptadecyl ether sulfonate, polyoxyethylene (1-30 EO) potassium octadecyl ether sulfonate, polyoxyethylene (1-30 EO) potassium octadecenyl ether sulfonate, polyoxyethylene (1-30 EO) Potassium octadecagenyl ether sulfonate, polyoxyethylene (1-30 EO) Potassium octadecatrienyl ether sulfonate, polyoxyethylene (1-30 EO)
30EO) potassium octadecatetraenyl ether sulfonate, polyoxyethylene (1-3QEO) potassium nonadecyl ether sulfonate, polyoxyethylene (1-30EO) potassium eicosyl ether sulfonate, polyoxyethylene (1-30EO) eico Potassium satetraenyl ether sulfonate, polyoxyethylene (1 to 30 EO) Potassium eicosabentaenyl ether sulfonate, polyoxyethylene (1 to 30 EO
) Potassium heneicosyl ether sulfonate, etc.

A specific example when X is ammonium.

Polyoxyethylene (1-3080) Avocado oil ammonium alkyl ether sulfonate, polyoxyethylene (1-30EO) Almond oil ammonium alkyl ether sulfonate, polyoxyethylene (1-30E
O) Ammonium fur alkyl ether sulfonate, polyoxyethylene (1-30 EO) Ammonium hypericum oil alkyl ether sulfonate, polyoxyethylene (1-30 EO) ammonium orica oil alkyl ether sulfonate, polyoxyethylene (
1-30 EO) ammonium olive oil alkyl ether sulfonate, polyoxyethylene (1-30 EO) ammonium cocoa butter alkyl ether sulfonate, polyoxyethylene (1-30 f!0) ammonium carrot oil alkyl ether sulfonate, polyoxyethylene (
1-30 BO) Ammonium Calope Oil Alkyl Ether Sulfonate, Polyoxyethylene (1-30 EO) Ammonium Liver Oil Alkyl Ether Sulfonate, Polyoxyethylene (1-30 EO) Ammonium Cucumber Oil Alkyl Ether Sulfonate, Polyoxyethylene (1-30 EO) ) Beef tallow alkyl ether sulfonate ammonium, polyoxyethylene (1-30EO) '!
Ammonium cod liver oil alkyl ether sulfonate, polyoxyethylene (1-30EO) Ammonium cod liver oil alkyl ether sulfonate, polyoxyethylene (
1-30 EO) Hydrogenated oil ammonium alkyl ether sulfonate, polyoxyethylene (1-30 EO) synthetic cocoa butter ammonium alkyl ether sulfonate, polyoxyethylene (1-30 EO) sesame oil ammonium alkyl ether sulfonate, polyoxyethylene (1-30 EO)
30 EO) Wheat germ oil ammonium alkyl ether sulfonate, polyoxyethylene (1-30 EO) rice bran oil ammonium alkyl ether sulfonate, polyoxyethylene (1-30 EO) rice germ oil ammonium alkyl ether sulfonate, polyoxyethylene (1
~30 EO) Ammonium sasanqua oil alkyl ether sulfonate, Polyoxyethylene (1~30 EO) Ammonium safflower oil alkyl ether sulfonate, Polyoxyethylene (1~3080) Ammonium shea alkyl ether sulfonate, Polyoxyethylene (
1-30EO) Ammonium juzdama oil alkyl ether sulfonate, polyoxyethylene (1-3080)
Hydrogenated cocoa butter alkyl ether sulfonate ammonium, polyoxyethylene (1-30 EO) hydrogenated liver oil ammonium alkyl ether sulfonate, polyoxyethylene (1-3020) soybean oil alkyl ether sulfonate ammonium, polyoxyethylene (1-30 EO)
) Turtle oil ammonium alkyl ether sulfonate, polyoxyethylene (1-30 EO) tea-based ammonium alkyl ether sulfonate, polyoxyethylene (1-30 EO) camellia oil ammonium alkyl ether sulfonate, polyoxyethylene (1-30 EO)
) Corn oil ammonium alkyl ether sulfonate, polyoxyethylene (1-30 EO) Rapeseed oil ammonium alkyl ether sulfonate, polyoxyethylene (1-30 EO) Milk fat alkyl ether sulfonate ammonium, polyoxyethylene (1-30 EO)
Ammonium persic oil alkyl ether sulfonate, polyoxyethylene (1 to 30 EO) Ammonium palm oil alkyl ether sulfonate, polyoxyethylene (1 to 30 EO) Bean oil ammonium alkyl ether sulfonate, polyoxyethylene (1 to 3
Ammonium castor oil alkyl ether sulfonate, polyoxyethylene (1-30 EO) Ammonium sunflower oil alkyl ether sulfonate, polyoxyethylene (1-30 EO) Ammonium grape oil alkyl ether sulfonate, polyoxyethylene (1-30 EO)
30 EO) Ammonium marmot oil alkyl ether sulfonate, polyoxyethylene (1-30 EO) Ammonium marmot oil alkyl ether sulfonate, polyoxyethylene (1-30 EO) Mink oil ammonium alkyl ether sulfonate, polyoxyethylene (
1-30 EO) ammonium cottonseed oil alkyl ether sulfonate, polyoxyethylene (1-30 EO) ammonium black alkyl ether sulfonate, polyoxyethylene (1-30 EO) ammonium coconut oil alkyl ether sulfonate, polyoxyethylene (1-30 EO)
EO) Egg yolk oil ammonium alkyl ether sulfonate, polyoxyethylene (1-30EO) ammonium nonyl ether sulfonate, polyoxyethylene (1-3
0EO) ammonium nonenyl ether sulfonate, polyoxyethylene (1~30EO) ammonium decyl ether sulfonate, polyoxyethylene (1~30E
O) Ammonium decenyl ether sulfonate, polyoxyethylene (1-30EO) Ammonium undecyl ether sulfonate, polyoxyethylene (1-30E
O) ammonium randecylenyl ether sulfonate,
Polyoxyethylene (1 to 30 EO) Ammonium dodecyl ether sulfonate, polyoxyethylene (1
-30 EO) Ammonium dodecenyl ether sulfonate, polyoxyethylene (1-30 EO)) Ammonium lysosyl ether sulfonate, polyoxyethylene (1-30 EO)) Ammonium lysocenyl ether sulfonate, polyoxyethylene (1-30 EO)
O) Ammonium tetradecyl ether sulfonate, polyoxyethylene (1 to 30 EO) Ammonium tetradecenyl ether sulfonate, polyoxyethylene (1 to 30 EO)
~30 EO) ammonium pentadecyl ether sulfonate, polyoxyethylene (1~3° EO) ammonium pentadecenyl ether sulfonate, polyoxyethylene (1~30 EO) ammonium hexadecyl ether sulfonate, polyoxyethylene (1~30 EO) ) Ammonium hexadecenyl ether sulfonate, polyoxyethylene (1-30 EO) Ammonium heptadecyl ether sulfonate, polyoxyethylene (1-30 EO)
EO) ammonium octadecyl ether sulfonate,
Polyoxyethylene (1-30EO) Ammonium Octadecenyl Ether Sulfonate, Polyoxyethylene (
1-30 EO) ammonium octadecagenyl ether sulfonate, polyoxyethylene (1-30 EO) ammonium octadecatrienyl ether sulfonate,
Polyoxyethylene (1-30 EO) ammonium octadecatetraenyl ether sulfonate, polyoxyethylene (1-30 EO) ammonium nonadecyl ether sulfonate, polyoxyethylene (1-30 EO) ammonium eicosyl ether sulfonate, polyoxyethylene (1-30 EO) Ammonium eicosatetraenyl ether sulfonate, polyoxyethylene (1-30 EO)
30EO) ammonium eicosapentaenyl ether sulfonate, polyoxyethylene (1-30EO) ammonium eicosyl ether sulfonate, and the like.

Specific example when X is monoethanolamine.

Polyoxyethylene (1-30 EO) Avocado oil Alkyl ether sulfonic acid monoethanolamine, Polyoxyethylene (1-30 EO) Almond oil Alkyl ether sulfonic acid monoethanolamine, Polyoxyethylene (1-30 EO) Osotose oil Alkyl ether sulfonic acid Monoethanolamine, polyoxyethylene (
1-30EO) Hypericum oil alkyl ether sulfonic acid monoethanolamine, polyoxyethylene (1-30EO)
30EO) oricaoyl alkyl ether sulfonic acid monoethanolamine, polyoxyethylene (1-30E
O) Olive oil alkyl ether sulfonic acid monoethanolamine, polyoxyethylene (1-30EO) cocoa butter alkyl ether sulfonic acid monoethanolamine,
Polyoxyethylene (1-30 EO) Power Loft Oil Alkyl Ether Sulfonic Acid Monoethanolamine, Polyoxyethylene (1-30 EO) Carlope Oil Alkyl Ether Sulfonic Acid Monoethanolamine, Polyoxyethylene (1-30 EO) Liver Oil Alkyl Ether Sulfonic Acid Monoethanolamine, polyoxyethylene (1-30E
O) Cucumber oil alkyl ether sulfonic acid monoethanolamine, polyoxyethylene (1 to 30 EO
) Beef tallow alkyl ether sulfonic acid monoethanolamine, polyoxyethylene (1-30 EO) strong liver oil alkyl ether sulfonic acid monoethanolamine, polyoxyethylene (1-30 EO) kyonin oil alkyl ether sulfonic acid monoethanolamine, polyoxyethylene ( 1-30 EO) Hydrogenated oil alkyl ether sulfonic acid monoethanolamine, polyoxyethylene (1-3
0EO) Synthetic cocoa butter alkyl ether sulfonic acid monoethanolamine, polyoxyethylene (1-30EO
) Sesame oil alkyl ether sulfonic acid monoethanolamine, polyoxyethylene (1-30EO) Wheat germ oil alkyl ether sulfonic acid monoethanolamine, polyoxyethylene (1-30 EO) rice bran oil alkyl ether sulfonic acid monoethanolamine, polyoxyethylene (1-30 EO) Rice germ oil alkyl ether sulfonic acid monoethanolamine, polyoxyethylene (1-30 EO) Sazanka oil alkyl ether sulfonic acid monoethanolamine, polyoxyethylene (1-3
0EO) Safflower oil alkyl ether sulfonic acid monoethanolamine, polyoxyethylene (1-30EO
) Shea demonstration alkyl ether sulfonate monoethanolamine, polyoxyethylene (1-30 EO) juzdama oil alkyl ether sulfonate monoethanolamine, polyoxyethylene (1-30 EO) hydrogenated cocoa butter alkyl ether sulfonate monoethanolamine,
Polyoxyethylene (1-30 EO) Hydrogenated Liver Oil Alkyl Ether Sulfonic Acid Monoethanolamine, Polyoxyethylene (1-30 EO) Soybean Oil Alkyl Ether Sulfonic Acid Monoethanolamine, Polyoxyethylene (1
~30EO) Turtle oil alkyl ether sulfonic acid monoethanolamine, polyoxyethylene (1~30E
O) Tea-based alkyl ether sulfonic acid monoethanolamine, polyoxyethylene (1-30 EO) Camellia oil alkyl ether sulfonic acid monoethanol amine, polyoxyethylene (1-30 EO)) Corn oil alkyl ether sulfonic acid monoethanol amine, poly Oxyethylene (1-30 EO) Rapeseed oil alkyl ether sulfonic acid monoethanolamine, polyoxyethylene (1-3080) Milk fat alkyl ether sulfonic acid monoethanolamine, polyoxyethylene (1-30
EO) Persic oil alkyl ether sulfonic acid monoethanolamine, polyoxyethylene (1-30 EO)
Palm oil alkyl ether sulfonic acid monoethanolamine, polyoxyethylene (1-30EO) peanut oil alkyl ether sulfonic acid monoethanolamine,
Polyoxyethylene (1-30 EO) Castor Oil Alkyl Ether Sulfonic Acid Monoethanolamine, Polyoxyethylene (1-30 EO) Sunflower Oil Alkyl Ether Sulfonic Acid Monoethanolamine, Polyoxyethylene (1-30 EO) Grape Oil Alkyl Ether Sulfonic Acid Monoethanolamine, polyoxyethylene (1-3
0EO) Piper oil alkyl ether sulfonic acid monoethanolamine, polyoxyethylene (1-30 EO) Marmot oil alkyl ether sulfonic acid monoethanolamine, polyoxyethylene (1-30 EO) Mink oil alkyl ether sulfonic acid monoethanolamine, polyoxy Ethylene (1~30f!O) Cottonseed oil alkyl ether sulfonic acid monoethanolamine, Polyoxyethylene (1~30EO) Japanese wax alkyl ether sulfonic acid monoethanolamine, Polyoxyethylene (1~3011:0) Coconut oil alkyl ether sulfone Acid monoethanolamine, polyoxyethylene (1-3
0 EO) Egg yolk oil alkyl ether sulfonic acid monoethanolamine, polyoxyethylene (1-30 EO) nonyl ether sulfonic acid monoethanol amine, polyoxyethylene (1-30 EO) nonenyl ether sulfonic acid monoethanol amine, polyoxyethylene (1 ~3
0EO) decyl ether sulfonic acid monoethanolamine, polyoxyethylene (1-30 EO) decenyl ether sulfonic acid monoethanolamine, polyoxyethylene (1-30 EO) undecyl ether sulfonic acid monoethanolamine, polyoxyethylene (1-30 EO) 301
1! O) Randecylenyl ether sulfonic acid monoethanolamine, polyoxyethylene (1 to 30 EO)
Dodecyl ether sulfonic acid monoethanolamine, polyoxyethylene (1 to 30 EO) Dodecenyl ether sulfonic acid monoethanolamine, polyoxyethylene (1 to 30 EO) ) Lysosyl ether sulfonic acid monoethanolamine, polyoxyethylene (1 to 30 EO) 3
0EO)) Lysocenyl ether sulfonic acid monoethanolamine, polyoxyethylene (1-30EO) tetradecyl ether sulfonic acid monoethanolamine,
Polyoxyethylene (1 to 30 EO) Tetradecenyl ether sulfonic acid monoethanolamine, Polyoxyethylene (1 to 30 EO) Pentadecyl ether sulfonic acid monoethanolamine, Polyoxyethylene (1 to 3
0EO) pentadecenyl ether sulfonic acid monoethanolamine, polyoxyethylene (1-30EQ) hexadecyl ether sulfonic acid monoethanolamine, polyoxyethylene (1-301!0) hexadecenyl ether sulfonic acid monoethanolamine, Polyoxyethylene (1-30 EO) Heptadecyl ether sulfonic acid monoethanolamine, polyoxyethylene (1-3
0EO) octadecyl ether sulfonic acid monoethanolamine, polyoxyethylene (1-30 EO) octadecenyl ether sulfonic acid monoethanolamine, polyoxyethylene (1-30 EO) octadecagenyl ether sulfonic acid monoethanolamine, polyoxyethylene ( 1-30EO) octadecatrienyl ether sulfonic acid monoethanolamine, polyoxyethylene (1-30 EO) octadecatetraenyl ether sulfonic acid monoethanolamine, polyoxyethylene (
1-30EQ) Nonadecyl ether sulfonic acid monoethanolamine, polyoxyethylene (1-30 EO) eicosyl ether sulfonic acid monoethanolamine, polyoxyethylene (1-30 EO) eicosatetraenyl ether sulfonic acid monoethanolamine, poly Oxyethylene (1 to 30 EO) eicosabentaenyl ether sulfonic acid monoethanolamine, polyoxyethylene (1 to 30 EO) eicosyl ether sulfonic acid monoethanolamine, and the like.

A specific example when X is jetanolamine.

Polyoxyethylene (1-30 EO) Avocado oil Alkyl ether sulfonic acid jetanolamine, Polyoxyethylene (1-30 EO) Almond oil Alkyl ether sulfonic acid Jetanolamine, Polyoxyethylene (1-30 EO) Osotose oil Alkyl ether sulfonic acid Jetanolamine, polyoxyethylene (1-3
0EO) Hypericum oil alkyl ether sulfonic acid jetanolamine, polyoxyethylene (1-30EO
) Olive oil alkyl ether sulfonate jetanolamine, polyoxyethylene (1-30 EO) olive oil alkyl ether sulfonate jetanolamine, polyoxyethylene (1-30 EO) cocoa butter alkyl ether sulfonate jetanolamine, polyoxy Ethylene (1-3080) Carrot oil alkyl ether sulfonic acid jetanolamine, polyoxyethylene (1-3080)
30EO) Carob oil alkyl ether sulfonate jetanolamine, polyoxyethylene (1-30EO)
Cod liver oil alkyl ether sulfonic acid jetanolamine,
Polyoxyethylene (1-30 EO) Cucumber oil alkyl ether sulfonate jetanolamine, polyoxyethylene (1-30 EO) beef tallow alkyl ether sulfonate jetanolamine, polyoxyethylene (
1-30EO) Strong liver oil alkyl ether sulfonic acid jetanolamine, polyoxyethylene (1-30EO)
Cocoa butter alkyl ether sulfonate jetanolamine, polyoxyethylene (1-30 EO) hydrogenated oil alkyl ether sulfonate jetanolamine, polyoxyethylene (1-30 EO) synthetic cocoa butter alkyl ether sulfonate jetanolamine, polyoxyethylene (1-30 EO) Sesame oil alkyl ether sulfonic acid jetanolamine, polyoxyethylene (1-30
F'0) Wheat germ oil alkyl ether sulfonate jetanolamine, polyoxyethylene (1-30 EO) rice bran oil alkyl ether sulfonate jetanolamine, polyoxyethylene (1-30 EO) rice germ oil alkyl ether sulfonate jetanol Amine, polyoxyethylene (1-30 EO) sasanqua oil alkyl ether sulfonate jetanolamine, polyoxyethylene (1-30 EO) safflower oil alkyl ether sulfonate jetanolamine, polyoxyethylene (1-30 EO)
30 EO) shear demonstration alkyl ether sulfonic acid jetanolamine, polyoxyethylene (1-30 EO) juzda oil alkyl ether sulfonic acid jetanolamine, polyoxyethylene (1-30 EO) hydrogenated cocoa butter alkyl ether sulfonic acid jetanolamine, Polyoxyethylene (1-30 EO) hydrogenated cod liver oil alkyl ether sulfonate jetanolamine, polyoxyethylene (1-30 EO) soybean oil alkyl ether sulfonate jetanolamine, polyoxyethylene (1-30 EO)
30EO) Turtle oil alkyl ether sulfonic acid jetanolamine, polyoxyethylene (1-30EO)
Tetanolamine alkyl ether sulfonate, polyoxyethylene (1-30 EO) Camellia oil jetanolamine alkyl ether sulfonate, polyoxyethylene (1-30 EO)) Jetanolamine alkyl ether sulfonate, polyoxyethylene (1 to 30 EO) rapeseed oil alkyl ether sulfonic acid jetanolamine, polyoxyethylene (1 to 3
0EO) Milk fat alkyl ether sulfonate jetanolamine, polyoxyethylene (1-3011:O) persic oil alkyl ether sulfonate jetanolamine, polyoxyethylene (1-30EO) palm oil alkyl ether sulfonate diethanolamine, polyoxyethylene (1-30 EO) Bean oil alkyl ether sulfonic acid jetanolamine, polyoxyethylene (1-30 EO) Castor oil alkyl ether sulfonic acid jetanolamine, polyoxyethylene (1-30 EO)
EO) sunflower oil alkyl ether sulfonate jetanolamine, polyoxyethylene (1-30EO) grape oil alkyl ether sulfonate jetanolamine,
Polyoxyethylene (1 to 30 EO) Piper oil alkyl ether sulfonic acid jetanolamine, polyoxyethylene (1 to 30 EO) Marmoso oil alkyl ether sulfonic acid jetanolamine, polyoxyethylene (
1-30 EO) Mink oil alkyl ether sulfonic acid jetanolamine, polyoxyethylene (1-30
EO) Mnn extracted oil alkyl ether sulfonic acid jetanolamine polyoxyethylene (1-30EO) Japanese black alkyl ether sulfonic acid jetanolamine,
Polyoxyethylene (1-30 EO) Coconut oil alkyl ether sulfonate jetanolamine, polyoxyethylene (1-30 EO) Egg yolk oil alkyl ether sulfonate jetanolamine, polyoxyethylene (1-30
EO) nonyl ether sulfonic acid jetanolamine,
Polyoxyethylene (1-30EO) nonenyl ether sulfonic acid jetanolamine, polyoxyethylene (
1-30 EO) Decyl ether sulfonic acid jetanolamine, polyoxyethylene (1-30 EO) Decenyl ether sulfonic acid jetanolamine, polyoxyethylene (1-30 EO) Undecyl ether sulfonic acid jetanolamine, polyoxyethylene ( 1~3Q
EO) Landecylenyl ether sulfonic acid jetanolamine, polyoxyethylene (1 to 30 EO) Dodecyl ether sulfonic acid jetanolamine, polyoxyethylene (1 to 30 EO) Dodecenyl ether sulfonic acid jetanolamine, polyoxyethylene ( 1
~30EO)) Lysosyl ether sulfonic acid jetanolamine, polyoxyethylene (1~30EO)
Tridecenyl ether sulfonate jetanolamine, polyoxyethylene (1-30 EO) tetradecyl ether sulfonate jetanolamine, polyoxyethylene (1-30 EO) tetradecenyl ether sulfonate jetanolamine, polyoxyethylene (1-30 EO) 30
EO) pentadecyl ether sulfonate jetanolamine, polyoxyethylene (1-30 EO) pentadecenyl ether sulfonate jetanolamine, polyoxyethylene (1-30 EO) hexadecyl ether sulfonate jetanolamine, polyoxyethylene ( 1~
30 EO) hexadecenyl ether sulfonic acid jetanolamine, polyoxyethylene (1-30 EO) heptadecyl ether sulfonic acid jetanolamine, polyoxyethylene (1-30 EO) octadecyl ether sulfonic acid jetanolamine, polyoxyethylene (
1-30EO) Octadecenyl ether sulfonic acid jetanolamine, polyoxyethylene (1-30EO)
Octadecagenyl ether sulfonate jetanolamine, polyoxyethylene (1-30 EO) octadecatrienyl ether sulfonate jetanolamine, polyoxyethylene (1-30 EO) octadecatetraenyl ether sulfonate jetanolamine, polyoxy Ethylene (1-30 EO) nonadecyl ether sulfonic acid jetanolamine, polyoxyethylene (1-3
0 EO) eicosyl ether sulfonate jetanolamine, polyoxyethylene (1-30 EO) eicosatetraenyl ether sulfonate jetanolamine, polyoxyethylene (1-30 EO) eicosapentaenyl ether sulfonate jetanolamine, poly Oxyethylene (1 to 30 EO) heneicosyl ether sulfonic acid jetanolamine and the like.

Specific example when X is triethanolamine.

Polyoxyethylene (1~30EO) Avocado oil alkyl ether sulfonic acid triethanolamine, Polyoxyethylene (1~30S!O) Almond oil alkyl ether sulfonic acid triethanolamine, Polyoxyethylene (1~30EO) Fur seal oil alkyl ether Triethanolamine sulfonate, polyoxyethylene (1 to 30 EO) Hypericum oil alkyl ether triethanolamine sulfonate, polyoxyethylene (1 to 30 EO)
~30EO) triethanolamine, polyoxyethylene (1~30EO)
EO) Olive oil alkyl ether sulfonate triethanolamine, polyoxyethylene (1-30 EO) cocoa butter alkyl ether sulfonate triethanolamine, polyoxyethylene (1-30 EO) carrot oil alkyl ether sulfonate triethanolamine, polyoxy Ethylene (1-30 EO) Calope oil alkyl ether sulfonic acid triethanolamine, polyoxyethylene (1-3 ogo) Liver td + alkyl ether sulfonic acid triethanolamine, polyoxyethylene (1
~30EO) Cucumber oil alkyl ether sulfonic acid triethanolamine, polyoxyethylene (1~
30EO) Beef tallow alkyl ether sulfonic acid triethanolamine, polyoxyethylene (1-30 EO) Strong liver oil alkyl ether sulfonic acid triethanolamine, polyoxyethylene (1-30 EO) Kyonin oil alkyl ether sulfonic acid triethanolamine, polyoxyethylene (1-30 EO) Hardened oil alkyl ether sulfonic acid triethanolamine, polyoxyethylene (1-30 EO) Synthetic cocoa butter alkyl ether sulfonic acid triethanolamine, polyoxyethylene (1
~30EO) Sesame oil alkyl ether sulfonic acid triethanolamine, polyoxyethylene (1~30EO)
Wheat germ oil alkyl ether sulfonate triethanolamine, polyoxyethylene (1-30EO) rice bran oil alkyl ether sulfonate triethanolamine,
Polyoxyethylene (1-30 EO) rice germ oil alkyl ether sulfonic acid triethanolamine, polyoxyethylene (1-30 EO) sasanquat oil alkyl ether sulfonic acid triethanolamine, polyoxyethylene (1-30 EO) safflower oil alkyl ether Triethanolamine sulfonate, polyoxyethylene (1
~3011!0) Shea practical alkyl ether sulfonic acid triethanolamine, polyoxyethylene (1~30
EO) Juzdama oil alkyl ether sulfonic acid triethanolamine, polyoxyethylene (1-3011!
0) Hydrogenated cocoa butter alkyl ether sulfonic acid triethanolamine, polyoxyethylene (1 to 30 EO
) Hydrogenated cod liver oil alkyl ether sulfonate triethanolamine, polyoxyethylene (1-30 EO) soybean oil alkyl ether sulfonate triethanolamine, polyoxyethylene (1-30 EO) tard oil alkyl ether sulfonate triethanolamine, polyoxy Ethylene (1-30 EO) tea-based alkyl ether sulfonic acid triethanolamine, polyoxyethylene (1-30 EO)
30EO) Camellia oil alkyl ether sulfonic acid triethanolamine, polyoxyethylene (1-30EO)
) Corn oil alkyl ether sulfonic acid triethanolamine, polyoxyethylene (1-30EO)
Rapeseed oil alkyl ether sulfonate triethanolamine, polyoxyethylene (1-30 EO) milk fat alkyl ether sulfonate triethanolamine, polyoxyethylene (1-30 EO) persic oil alkyl ether sulfonate triethanolamine, polyoxyethylene (1-30 EO) 30EO) Palm oil alkyl ether sulfonic acid triethanolamine, polyoxyethylene (1-3
0EO) Bean oil alkyl ether sulfonic acid triethanolamine, polyoxyethylene (1-30EO
) Castor oil alkyl ether sulfonate triethanolamine, polyoxyethylene (1-30 EO) Sunflower oil alkyl ether sulfonate triethanolamine, polyoxyethylene (1-30 EO) Grape oil alkyl ether sulfonate triethanolamine, polyoxyethylene (1-301!O) Marmot oil alkyl ether sulfonate triethanolamine, polyoxyethylene (1-301!0) Marmot oil alkyl ether sulfonate triethanolamine, polyoxyethylene (
1~30t! O) Mink oil alkyl ether sulfonic acid triethanolamine, polyoxyethylene (1-
30EO) Cottonseed oil alkyl ether sulfonate triethanolamine, polyoxyethylene (1-30EO) Japanese wax alkyl ether sulfonate triethanolamine, polyoxyethylene (1-30EO) coconut oil alkyl ether sulfonate triethanolamine, polyoxyethylene (1-30 EO) Egg yolk oil alkyl ether sulfonic acid triethanolamine, polyoxyethylene (
1 to 30 EO) nonyl ether sulfonic acid triethanolamine, polyoxyethylene (1 to 30 EO) nonenyl ether sulfonic acid triethanolamine, polyoxyethylene (1 to 30 EO) decyl ether sulfonic acid triethanolamine, polyoxyethylene (1 to 30 EO) ~30
EO) decenyl ether sulfonate triethanolamine, polyoxyethylene (1-30 EO) undecyl ether sulfonate triethanolamine, polyoxyethylene (1-30 uO) randecylenyl ether sulfonate triethanolamine, polyoxyethylene ( 1~
30EO) Dodecyl ether sulfonic acid triethanolamine, polyoxyethylene (1-30EO)
dodecenyl ether sulfonic acid triethanolamine,
Polyoxyethylene (1 to 30 EO)) Lysocyl ether sulfonic acid triethanolamine, Polyoxyethylene (1 to 30 EO)) Lysocenyl ether sulfonic acid triethanolamine, Polyoxyethylene (1
~3011!0) Tetradecyl ether sulfonic acid triethanolamine, polyoxyethylene (1~30EO
) Tetradecenyl ether sulfonic acid triethanolamine, polyoxyethylene (1-30 EO) pentadecyl ether sulfonic acid triethanolamine, polyoxyethylene (1-30 EO) pentadecenyl ether sulfonic acid triethanolamine, polyoxyethylene (
1-30EO) Hexadecyl ether sulfonic acid triethanolamine, polyoxyethylene (1-30EO)
Triethanolamine hexadecenyl ether sulfonate, polyoxyethylene (1-30EO) triethanolamine heptadecyl ether sulfonate, triethanolamine octadecyl ether sulfonate, polyoxyethylene (1-3QEO), triethanolamine octadecyl ether sulfonate, polyoxyethylene (1-30EO)
30 EO) octadecenyl ether sulfonic acid triethanolamine, polyoxyethylene (1 to 30 EO) octadecagenyl ether sulfonic acid triethanolamine, polyoxyethylene (1 to 30 EO) octadecatrienyl ether sulfonic acid triethanolamine,
Polyoxyethylene (1-30 EO) octadecatetraenyl ether sulfonic acid triethanolamine, polyoxyethylene (1-30 EO) nonadecyl ether sulfonic acid triethanolamine, polyoxyethylene (
1-30 EO) eicosyl ether sulfonic acid triethanolamine, polyoxyethylene (1-30 EO) eicosatetraenyl ether sulfonic acid triethanolamine, polyoxyethylene (1-30 EO) eicosapentaenyl ether sulfonic acid triethanolamine , polyoxyethylene (1 to 30 EO) heneicosyl ether sulfonic acid triethanolamine, and the like.

R-(OCHzGHz)n-5Oi-X
...(1) (However, in the formula, R is a linear or branched alkyl group or alkenyl group of Ca"Cz, and n is 1 to
An integer of 30, X is sodium, potassium, ammonia,
Indicates monoethanolamine, jetanolamine, or triethanolamine. ) In this invention, this polyoxyethylene alkyl ether sulfonate is mainly used to improve the foaming and rinsability of hard water, and its blending amount is 0.1 to 9.
Q, preferably 0 wt%.

The reason is that if it is less than 0.1 wt%, it will not improve the foaming and rinsing properties of hard water, and if it is more than 90.0 wt%, the detergency of hard water will deteriorate. This is because there is none.

The reason why linear or branched alkyl or alkenyl groups are made to have 8 to 20 carbon atoms is that those with less than 8 carbon atoms have weak lipophilic power, and conversely, those with more than 20 carbon atoms have poor lipophilic power. This is because although the polyoxyethylene alkyl ether sulfonate has a strong strength, its hydrophilicity deteriorates and its solubility in water decreases, and the viscosity of the polyoxyethylene alkyl ether sulfonate increases, making it difficult to handle, both of which are undesirable.

The reason why the degree of polymerization of polyoxyethylene is set to 1 to 30 is as follows.
In the absence of polyoxyethylene, skin irritation is observed, and when the degree of polymerization of polyoxyethylene exceeds 30, the hydrophilicity is strong but the lipophilicity is weak and the polyoxyethylene alkyl ether sulfonate This is because the cleaning power deteriorates, which is not preferable in either case.

Bases that make up the salt include sodium, potassium, ammonia, monoethanolamine, jetanolamine,
The reason for using triethanolamine is that when polyvalent bases such as calcium and magnesium are used, the solubility of polyoxyethylene alkyl ether sulfonate decreases.
When a monovalent base such as rubidium, cesium, or francium is used, it is not possible to prepare a raw material suitable for industrial production, which is not preferable in either case.

The alkylamine oxide used in this invention (the following formula (
2)) may be one or a mixture of two or more of the following substances.

Specific example when R2 is a methyl group.

avocado oil alkyldimethylamine oxide, almond oil alkyldimethylamine oxide, fur oil alkyldimethylamine oxide, hypericum oil alkyldimethylamine oxide, orica oil alkyldimethylamine oxide, olive oil alkyldimethylamine oxide, cocoa butter alkyldimethylamine oxide,
Carrot oil alkyldimethylamine oxide, cocoa butter alkyldimethylamine oxide, cod liver oil alkyldimethylamine oxide, cucumber oil alkyldimethylamine oxide, beef tallow alkyldimethylamine oxide, strong cod liver oil alkyldimethylamine oxide, kung oil alkyldimethylamine oxide, hydrogenated oil alkyl Dimethylamine oxide, synthetic cocoa butter alkyldimethylamine oxide, sesame oil alkyldimethylamine oxide, wheat germ oil alkyldimethylamine oxide, rice bran oil alkyldimethylamine oxide, rice germ oil alkyldimethylamine oxide, sasanquat oil alkyldimethylamine oxide, safflower Oil Alkyl Dimethylamine Oxide, Shea Demonstration Alkyl Dimethylamine Oxide, Juzdama Oil Alkyl Dimethylamine Oxide,
Hydrogenated cocoa butter alkyldimethylamine oxide, hydrogenated cod liver oil alkyldimethylamine oxide, soybean oil alkyldimethylamine oxide, turdle oil alkyldimethylamine oxide, tea practice alkyldimethylamine oxide, camellia oil alkyldimethylamine oxide,
Corn oil alkyl dimethyl amine oxide, rapeseed oil alkyl dimethyl amine oxide, milk fat alkyl dimethyl amine oxide, persic oil alkyl dimethyl amine oxide, palm oil alkyl dimethyl amine oxide, bean oil alkyl dimethyl amine oxide, castor oil alkyl dimethyl amine oxide, sunflower oil alkyl Dimethylamine oxide, grape oil alkyldimethylamine oxide, pit viper oil alkyldimethylamine oxide, marmot oil alkyldimethylamine oxide, mink oil alkyldimethylamine oxide, cottonseed oil alkyldimethylamine oxide, Japanese alkyl dimethylamine oxide, coconut oil alkyl dimethylamine oxide oxide, egg yolk oil alkyl dimethyl amine oxide, nonyl dimethyl amine oxide, nonenyl dimethyl amine oxide, decyl dimethyl amine oxide, decenyl dimethyl amine oxide, undecyl dimethyl amine oxide, randecylenyl dimethyl amine oxide, dodecyl dimethyl amine oxide, Dodecenyldimethylamine oxide, tridecyldimethylamine oxide, tridecenyldimethylamine oxide, tetradecyldimethylamine oxide, tetradecenyldimethylamine oxide, pentadecyl ether sulfonic acid monoethanolamine, pentadecenyl dimethylamine oxide, hexadecyldimethylamine oxide, hexadecenyl dimethylamine oxide, heptadecyl dimethylamine oxide, octadecyl dimethylamine oxide, octadecenyl dimethylamine oxide, octadecadenyl dimethylamine oxide, ophtadetrienyl dimethylamine oxide , octadecatetraenyldimethylamine oxide, nonadecyldimethylamine oxide, eicosyldimethylamine oxide, eicosatetraenyldimethylamine oxide, eicosapentaenyldimethylamine oxide, heneicosyldimethylamine oxide, and the like.

Specific example when R2 is a hydroxyethyl group.

Avocado oil alkyldihydroxydiethylamine oxide, almond oil alkyldihydroxydiethylamine oxide, fur seal oil alkyldihydroxydiethylamine oxide, hypericum oil alkyldihydroxydiethylamine oxide, orica oil alkyldihydroxyethylamine oxide, olive oil alkyldihydroxydiethylamine oxide, cocoa butter alkyl Dihydroxydiethylamine oxide, carrot oil alkyldihydroxydiethylamine oxide, cocoa butter alkyldihydroxydiethylamine oxide, cod liver oil alkyldihydroxydiethylamine oxide, cucumber oil alkyldihydroxydiethylamine oxide, tallow alkyldihydroxydiethylamine oxide, strong liver oil alkyldihydroxydiethylamine oxide , Kyoto oil alkyldihydroxydiethylamine oxide, hydrogenated oil alkyldihydroxydiethylamine oxide, synthetic cocoa butter alkyldihydroxydiethylamine oxide, sesame oil alkyldihydroxydiethylamine oxide, wheat germ oil alkyldihydroxydiethylamine oxide, rice bran oil alkyldihydroxydiethylamine oxide, Rice germ oil alkyldihydroxydiethylamine oxide, sasanqua oil alkyldihydroxydiethylamine oxide, safflower oil alkyldihydroxydiethylamine oxide, shea jitsuji alkyldihydroxydiethylamine oxide, juzdama oil alkyldihydroxydiethylamine oxide, hydrogenated cocoa butter alkyldihydroxydiethylamine oxide, hydrogenated cod liver oil alkyldihydroxydiethylamine oxide, soybean oil alkyldihydroxydiethylamine oxide,
Turtle oil alkyldihydroxydiethylamine oxide, tea practice alkyldihydroxydiethylamine oxide,
camellia oil alkyldihydroxydiethylamine oxide,
Corn oil alkyldihydroxydiethylamine oxide, rapeseed oil alkyldihydroxydiethylamine oxide, milk fat alkyldihydroxydiethylamine oxide,
Persic oil alkyldihydroxydiethylamine oxide, palm oil alkyldihydroxydiethylamine oxide, bean oil alkyldihydroxydiethylamine oxide, castor oil alkyldihydroxydiethylamine oxide, sunflower oil alkyldihydroxydiethylamine oxide, grape oil alkyldihydroxydiethylamine oxide, viper oil Alkyldihydroxydiethylamine oxide, marmot oil alkyldihydroxydiethylamine oxide, mink oil alkyldihydroxydiethylamine oxide, cottonseed oil alkyldihydroxydiethylamine oxide, Japanese wax alkyldihydroxydiethylamine oxide, coconut oil alkyldihydroxydiethylamine oxide, egg yolk oil alkyldihydroxide diethylamine oxide, nonyldihydroxydiethylamine oxide, nonenyldihydroxydiethylamine oxide, decyl dihydroxydiethylamine oxide, decenyl dihydroxydiethylamine oxide, undecyl dihydroxydiethylamine oxide, randecylenyl dihydroxyethylamine oxide, dodecel dihydroxydiethylamine oxide, dodecenyldihydroxydiethylamine oxide,
Tridecyldihydroxydiethylamine oxide, tridecenyldihydroxydiethylamine oxide, tetradecyldihydroxyethylamine oxide, tetradecenyldihydroxydiethylamine oxide, pentadecyldihydroxyethylamine oxide, pentadecenyldihydroxydiethylamine oxide, hexadecyldihydroxydiethylamine oxide, hexadecyldihydroxyethylamine oxide Decenyldihydroxydiethylamine oxide, heptadecyldihydroxyethylamine oxide, octadecyldihydroxydiethylamine oxide, octadecenyldihydroxydiethylamine oxide, octadecagenyl dihydroxyethylamine oxide, octadecatrienyl dihydroxyethylamine oxide, octadecatetraenyl dihydroxyethylamine oxide , nonadecyl dihydroxyethylamine oxide, eicosyl dihydroxyethylamine oxide, eicosatetraenyl dihydroxyethylamine oxide, potassium eicosapentaenyl ether sulfonate, heneicosyl dihydroxyethylamine oxide, and the like.

R, -N→0...(2) (However, in the formula, R is a C8 to C2° linear or branched alkyl group or alkenyl group, and R2 is a methyl group or a hydroxyethyl group, respectively. ) In this invention,
This alkylamine oxide is mainly used to impart detergency to hard water, and its blending amount ranges from 0.1 to 99.
The content is preferably 8 wt%.

The reason is that if it is less than 0.1wtχ, it will not improve the detergency of hard water, and if it exceeds 99.8wt%, the detergency of hard water will be improved, but the texture of the foam will be adversely affected. This is because it will result in a loss of water, which is not desirable in either case.

The reason why R is a linear or branched alkyl group or alkenyl group having 8 to 20 carbon atoms is mainly as follows.

That is, those with less than 8 carbon atoms have weak lipophilic power, and conversely, those with more than 20 carbon atoms have strong lipophilic power, but the hydrophilic power deteriorates and the solubility of the alkylamine oxide in water decreases.
Moreover, the viscosity increases, which causes handling difficulties, which is not preferable in either case.

The fatty acid amide alkyl betaine (formula (3) below) used in this invention may be one or a mixture of two or more of the following substances.

A specific example when n=1.

Avocado oil fatty acid amide methyl betaine, almond oil fatty acid amide methyl betaine, fur seal oil fatty acid amide methyl betaine, Hypericum oil fatty acid amide methyl betaine, orica oil fatty acid amide methyl betaine,
Olip oil fatty acid amide methyl betaine, cocoa butter fatty acid amide methyl betaine, carrot oil fatty acid amide methyl betaine, cocoa butter fatty acid amide methyl betaine, liver oil fatty acid amide methyl betaine, cucumber oil fatty acid amide methyl betaine, beef tallow fatty acid amide methyl betaine, strong liver oil fatty acid Amidomethyl betaine, camphor oil fatty acid amide methyl betaine, hydrogenated oil fatty acid amide methyl betaine, synthetic cocoa butter fatty acid amide methyl betaine, sesame oil fatty acid amide methyl betaine, wheat germ oil fatty acid amide methyl betaine, rice bran oil fatty acid amide methyl betaine, rice germ oil fatty acid amidomethyl betaine,
Sasanqua oil fatty acid amide methyl betaine, safflower oil fatty acid amide methyl betaine, shea seed oil fatty acid amide methyl betaine, soybean oil fatty acid amide methyl betaine, hydrogenated cocoa butter fatty acid amide methyl betaine, hydrogenated liver oil fatty acid amide methyl betaine, soybean oil fatty acid Amidomethyl betaine, tartar oil fatty acid amidomethyl betaine, teaseed oil fatty acid amidomethyl betaine, camellia oil fatty acid amidomethyl betaine, corn oil fatty acid amidomethyl betaine, rapeseed oil fatty acid amidomethyl betaine, milk fat fatty acid amidomethyl betaine, persic oil fatty acid Amidomethyl betaine, palm oil fatty acid amide methyl betaine, bean oil fatty acid amide methyl betaine, castor oil fatty acid amide methyl betaine, castor oil fatty acid amide methyl betaine, grape oil fatty acid amide methyl betaine, pit viper oil fatty acid amide methyl betaine, marmot oil fatty acid amide Methyl betaine, mink oil fatty acid amide methyl betaine, cottonseed oil fatty acid amide methyl betaine, Japanese wax fatty acid amide methyl betaine, coconut oil fatty acid amide methyl betaine, egg yolk oil fatty acid amide methyl betaine, nonanoic acid amide methyl betaine, nonenoic acid amide methyl betaine, decanoic acid amidomethyl betaine,
Decenoic acid amidomethyl betaine, undecylic acid amidomethyl betaine, undecylenic acid amidomethyl betaine,
Dodecanoic acid amide methyl betaine, dodecenoic acid amide methyl betaine, tridecanoic acid amide methyl betaine, tridecenoic acid amide methyl betaine, tetradecanoic acid amide methyl betaine, tetradecenoic acid amide methyl betaine, pentadecanoic acid amide methyl betaine, pentadecenoic acid amide methyl betaine, hexadecanoic acid Amidomethyl betaine, hexadecenoic acid amide methyl betaine, heptadecanoic acid amide methyl betaine, octadecanoic acid amide methyl betaine, octadecene amide methyl betaine, octadecadienoic acid amide methyl betaine, octadecatrienoic acid amide methyl betaine, octadecatetraenoic acid amide Methyl betaine, nonadecanoic acid amide methyl betaine, eicosanoic acid amide methyl betaine,
Examples include eicosatetraenoic acid amide methyl betaine, eicosapene citrate amide methyl betaine, and heneicosanoic acid amide methyl betaine.

A specific example when n=2.

Avocado oil fatty acid amide ethyl betaine, almond oil fatty acid amide ethyl betaine, fur seal oil fatty acid amide ethyl betaine, Hypericum oil fatty acid amide ethyl betaine, orica oil fatty acid amide ethyl betaine,
Olive oil fatty acid amide ethyl betaine, cocoa butter fatty acid amide ethyl betaine, carrot oil fatty acid amide ethyl betaine, cocoa butter fatty acid amide ethyl betaine, liver oil fatty acid amide ethyl betaine, cucumber oil fatty acid amide ethyl betaine, beef tallow fatty acid amide ethyl betaine, strong liver oil fatty acid Amidoethylbetaine, quince oil fatty acid amideethylbetaine, hydrogenated oil fatty acid amideethylbetaine, synthetic cocoa butter fatty acid amideethylbetaine, sesame oil fatty acid amideethylbetaine, wheat germ oil fatty acid amideethylbetaine, rice bran oil fatty acid amideethylbetaine, rice Germ oil fatty acid amidoethyl betaine,
Sasanqua oil fatty acid amide ethyl betaine, safflower oil fatty acid amide ethyl betaine, shea seed oil fatty acid amide ethyl betaine, juzda bean oil fatty acid amide ethyl betaine, hydrogenated cocoa butter fatty acid amide ethyl betaine, hydrogenated liver oil fatty acid amide ethyl betaine, soybean oil fatty acid Amidoethyl betaine, tartar oil fatty acid amide ethyl betaine, tea seed oil fatty acid amide ethyl betaine, camellia oil fatty acid amide ethyl betaine, corn oil fatty acid amide ethyl betaine, rapeseed oil fatty acid amide ethyl betaine, milk fat fatty acid amide ethyl betaine, persic oil fatty acid amide ethyl betaine Betaine, palm oil fatty acid amide ethyl betaine, peanut oil fatty acid amide ethyl betaine,
Castor oil fatty acid amide ethyl betaine, castor oil fatty acid amide ethyl betaine, grape oil fatty acid amide ethyl betaine, pit viper oil fatty acid amide ethyl betaine, marmot oil fatty acid amide ethyl betaine, mink oil fatty acid amide ethyl betaine, cottonseed oil fatty acid amide ethyl betaine, Japanese black fatty acid Amidoethylbetaine, coconut oil fatty acid amideethylbetaine, egg yolk oil fatty acid amideethylbetaine, amideethylbetaine nonanoate, amideethylbetaine nonenoate, amideethylbetaine decanoate, amideethylbetaine decenoate, amideethylbetaine undecylate, undecylenic acid Amidoethylbetaine, Amidoethylbetaine dodecanoate, Amidoethylbetaine dodecenoate, Amidoethylbetaine tridecanoate, Amidoethylbetaine tridecanoate, Amidoethylbetaine tetradecanoate, Amidoethylbetaine tetradecenoate, Amidoethylbequin pentadecanoate, Pentadecenoic acid amide Ethyl betaine, hexadecanoic acid amide ethyl betaine, hexadecenoic acid amide ethyl betaine, heptadecanoic acid amide ethyl betaine, octadecanoic acid amide ethyl betaine, octadecenoic acid amide ethyl betaine, octadecadienoic acid amide ethyl betaine, octadecatrienoic acid amide ethyl betaine, octadecanoic acid amide ethyl betaine Examples include decatetraenoic acid amide ethyl betaine, nonadecano acid amide ethyl betaine, eicosanoic acid amide ethyl betaine, eicosatetraenoic acid amide ethyl betaine, eicosapentaenoic acid amide ethyl betaine, and heneicosanoic acid amide ethyl betaine.

A specific example when n=3.

Avocado oil fatty acid amidopropyl betaine, Almond oil fatty acid amidopropyl betaine, Fur seal oil fatty acid amidopropyl betaine, Hypericum perforatum oil fatty acid amidopropyl betaine, Orica oil fatty acid amidopropyl betaine, Oil fatty acid amidopropyl betaine, Cocoa butter fatty acid amidopropyl betaine, Carrot oil Fatty acid amidopropyl betaine, cocoa butter fatty acid amidopropyl betaine, cod liver oil fatty acid amidopropyl betaine, cucumber oil fatty acid amidopropyl betaine, beef tallow fatty acid amidopropyl betaine, strong liver oil fatty acid amidopropyl betaine, kyonin oil fatty acid amidopropyl betaine, hydrogenated oil fatty acid amidopropyl betaine Betaine, synthetic cocoa fat fatty acid amidopropyl betaine, sesame oil fatty acid amidopropyl betaine, wheat germ oil fatty acid amidopropyl betaine, rice bran oil fatty acid amidopropyl betaine, rice germ oil fatty acid amidopropyl betaine, sasanquat oil fatty acid amidopropyl betaine, safflower oil fatty acid amidopropyl betaine, shea oil fatty acid amidopropyl betaine, juzdama oil fatty acid amidopropyl betaine,
Hydrogenated cocoa butter fatty acid amidopropyl betaine, Hydrogenated liver oil fatty acid amidopropyl betaine, Soybean oil fatty acid amidopropyl betaine, Turtle oil fatty acid amidopropyl betaine, Tea seed oil fatty acid amidopropyl betaine, Camellia oil fatty acid amidopropyl betaine, Corn oil fatty acid amide Propyl betaine, rapeseed oil fatty acid amidopropyl betaine, milk fat fatty acid amidopropyl betaine, persic oil fatty acid amidopropyl betaine, palm oil fatty acid amidopropyl betaine, bean oil fatty acid amidopropyl betaine, castor oil fatty acid amidopropyl betaine, castor oil fatty acid amidopropyl betaine, Grape oil fatty acid amidopropyl betaine, pit viper oil fatty acid amidopropyl betaine, marmot oil fatty acid amidopropyl betaine, mink oil fatty acid amidopropyl betaine, cottonseed oil fatty acid amidopropyl betaine, Japanese blackberry fatty acid amidopropyl betaine, coconut oil fatty acid amidopropyl betaine, egg yolk oil Fatty acid amidopropyl betaine, nonanoic acid amidopropyl betaine, nonenoic acid amidopropyl betaine, decanoic acid amidopropyl betaine, decenoic acid amidopropyl betaine, undecylic acid amidopropyl betaine, undecylenic acid amidopropyl betaine,
Dodecanoic acid amide propyl betaine, dodecenoic acid amide propyl betaine, tridecanoic acid amide propyl betaine, tridecenoic acid amide propyl betaine, tetradecanoic acid amide propyl betaine, tetradecenoic acid amide propyl betaine, pentadecanoic acid amide propyl betaine, pentadecenoic acid amide propyl betaine, hexadecanoic acid Amidopropyl betaine, amidopropyl betaine hexadecenoate, amidopropyl betaine heptadecanoate, amidopropyl betaine octadecanoate, amidopropyl betaine octadecenoate, amidopropyl betaine octadecadienoate, amidopropyl betaine octadecatrienoate, amidopropyl octadecatetraenoic acid amide Propyl betaine, nonadecanoamide propyl betaine,
Examples thereof include eicosanoic acid amidopropyl betaine, eicosatetraenoic acid amidopropyl betaine, eicosapene citrate amidopropyl betaine, and heneicosanoic acid amidopropyl betaine.

A specific example when n=4.

Avocado oil fatty acid amide butyl betaine, almond oil fatty acid amide butyl betaine, fur seal oil fatty acid amide butyl betaine, Hypericum oil fatty acid amide butyl betaine, orica oil fatty acid amide butyl betaine,
Olip oil fatty acid amidobutyl betaine, cocoa butter fatty acid amidobutyl betaine, carot oil fatty acid amidobutyl betaine, carob oil fatty acid amidobutyl betaine, cod liver oil fatty acid amidobutyl betaine, cucumber oil fatty acid amidobutyl betaine, beef tallow fatty acid amidobutyl betaine, strong liver oil Fatty acid amide butyl betaine, ginseng oil fatty acid amide butyl betaine, hydrogenated oil fatty acid amide butyl betaine, synthetic cocoa butter fatty acid amide butyl betaine, sesame oil fatty acid amide butyl betaine, wheat germ oil fatty acid amide butyl betaine, rice bran oil fatty acid amide butyl betaine, rice germ Oil fatty acid amide butyl betaine, sasanqua oil fatty acid amide butyl betaine, safflower oil fatty acid amide butyl betaine, shea oil fatty acid amide butyl betaine, juzda oil fatty acid amide butyl betaine, hydrogenated cocoa butter fatty acid amide butyl betaine,
Hydrogenated cod liver oil fatty acid amide butyl betaine, soybean oil fatty acid amide butyl betaine, turdle oil fatty acid amide butyl betaine, teaseed oil fatty acid amide butyl betaine, camellia oil fatty acid amide butyl betaine, corn oil fatty acid amide butyl betaine, rapeseed oil fatty acid amide butyl betaine, Milk fat fatty acid amide butyl betaine, persic oil fatty acid amide butyl betaine, palm oil fatty acid amide butyl betaine, bean oil fatty acid amide butyl betaine, castor oil fatty acid amide butyl betaine, castor oil fatty acid amide butyl betaine, grape oil fatty acid amide butyl betaine, viper oil Fatty acid amide butyl betaine, marmot oil fatty acid amide butyl betaine, mink oil fatty acid amide butyl betaine, cottonseed oil fatty acid amide butyl betaine, Japanese wax fatty acid amide butyl betaine, coconut oil fatty acid amide butyl betaine, egg yolk oil fatty acid amide butyl betaine, nonanoic acid amide butyl betaine , amidobutyl betaine nonenoate, amidobutyl betaine decanoate,
Amidobutylbetaine decenoate, Amidobutylbetaine undecylate, Amidobutylbetaine undecylenate,
Dodecanoic acid amide butyl betaine, dodecenoic acid amide butyl betaine, tridecanoic acid amide butyl betaine, tridecenoic acid amide butyl betaine, tetradecanoic acid amide butyl betaine, tetradecenoic acid amide butyl betaine, pentadecanoic acid amide butyl betaine, pentadecenoic acid amide butyl betaine, hexadecanoic acid Amidobutylbetaine, amidobutylbetaine hexadecenoate, amidobutylbetaine heptadecanoate, amidobutylbetaine octadecanoate, amidobutylbetaine octadecenoate, amidobutylbetaine octadecadienoate, amidobutylbetaine octadecatrienoate, octadecatetraenoic acid Examples thereof include amidobutyl betaine, nonadecanoic acid amidobutyl betaine, eicosanoic acid amidobutyl betaine, eicosatetraenoic acid amidobutyl betaine, eicosapenic acid amidobutyl betaine, and heneicosanoic acid amidobutyl betaine.

A specific example when n=5.

Avocado oil fatty acid amide pentyl betaine, almond oil fatty acid amide pentyl betaine, fur seal oil fatty acid amide pentyl betaine, Hypericum perforatum oil fatty acid amide pentyl betaine, olive oil fatty acid amide pentyl betaine, olive oil fatty acid amide pentyl betaine, cocoa butter fatty acid amide pentyl betaine, Carrot oil fatty acid amide pentyl betaine, cocoa butter fatty acid amide pentyl betaine, cod liver oil fatty acid amide pentyl betaine, cucumber oil fatty acid amide pentyl betaine, beef tallow fatty acid amide pentyl betaine, strong liver oil fatty acid amide pentyl betaine, kyonin oil fatty acid amide pentyl betaine, hydrogenated oil fatty acid Amidopentylbetaine, synthetic cocoa butter fatty acid amidepentylbetaine, sesame oil fatty acid amidepentylbetaine, wheat germ oil fatty acid amidepentylbetaine, rice bran oil fatty acid amidepentylbetaine,
Rice germ oil fatty acid amide pentyl betaine, sasanqua oil fatty acid amide pentyl betaine, safflower oil fatty acid amide pentyl betaine, shea seed oil fatty acid amide pentyl betaine, juzda bean oil fatty acid amide pentyl betaine, hydrogenated cocoa butter fatty acid amide pentyl betaine, hydrogenated cod liver oil Fatty acid amide pentyl betaine, soybean oil fatty acid amide pentyl betaine, tartar oil fatty acid amide pentyl betaine, tea seed oil fatty acid amide pentyl betaine, camellia oil fatty acid amide pentyl betaine, corn oil fatty acid amide pentyl betaine, rapeseed oil fatty acid amide pentyl betaine, milk fat fatty acid amide pentyl betaine,
Persic oil fatty acid amide pentyl betaine, palm oil fatty acid amide pentyl betaine, bean oil fatty acid amide pentyl betaine, castor oil fatty acid amide pentyl betaine, castor oil fatty acid amide pentyl betaine, grape oil fatty acid amide pentyl betaine, viper oil fatty acid amide pentyl betaine, Marmont Oil fatty acid amide pentyl betaine, mink oil fatty acid amide pentyl betaine, cottonseed oil fatty acid amide pentyl betaine, Japanese wax fatty acid amide pentyl betaine, coconut oil fatty acid amide pentyl betaine, egg yolk oil fatty acid amide pentyl betaine,
Amidopentylbetaine nonanoate, Amidopentylbetaine nonenoate, Amidopentylbetaine decanoate, Amidopentylbetaine decenoate, Amidopentylbetaine undecylate, Amidopentylbetaine undecylenate, Amidopentylbetaine dodecanoate, Amidopentylbetaine dodecenoate, Tridecanoic acid Amidopentyl betaine, amidopentyl betaine tridecenoate, amidopentyl betaine tetradecanoate, amidopentyl betaine tetradecenoate, amidopentyl betaine pentadecanoate, amidopentyl betaine pentadecenoate, amidopentyl betaine hexadecanoate, amidopentyl betaine hexadecenoate, amidopentyl heptadecanoate Betaine, amide pentyl betaine octadecanoate, amide pentyl betaine octadecanoate, amide pentyl betaine octadecadienoate, amide pentyl betaine octadecatrienoate, amide pentyl betaine octadecatetraenoate, amide pentyl betaine nonadecanoate, amide pentyl betaine eicosanoate , eicosatetraenoic acid amide pentyl betaine, eicosapentaenoic acid amide pentyl betaine, heneicosanoic acid amide pentyl betaine, and the like.

A specific example when n=5.

Avocado oil fatty acid amidohexyl betaine, almond oil fatty acid amidohexyl betaine, fur seal oil fatty acid amidohexyl betaine, hypericum oil fatty acid amidohexyl betaine, orica oil fatty acid amidohexyl betaine, olive oil fatty acid amidohexyl betaine, cocoa butter fatty acid amidohexyl betaine, carot oil Fatty acid amidohexyl betaine, cocoa butter fatty acid amidohexyl betaine, cod liver oil fatty acid amidohexyl betaine, cucumber oil fatty acid amidohexyl betaine, beef tallow fatty acid amidohexyl betaine, strong liver oil fatty acid amidohexyl betaine, kyonin oil fatty acid amidohexyl betaine, hydrogenated oil fatty acid amidohexyl betaine Betaine, synthetic cocoa butter fatty acid amidohexylbetaine, sesame oil fatty acid amidohexylbetaine, wheat germ oil fatty acid amidohexylbetaine, rice bran oil fatty acid amidohexylbetaine,
Rice germ oil fatty acid amidohexyl betaine, sasanqua oil fatty acid amidohexyl betaine, safflower oil fatty acid amidohexyl betaine, shea seed oil fatty acid amidohexyl betaine, red bean oil fatty acid amidohexyl betaine, hydrogenated cocoa butter fatty acid amidohexyl betaine, hydrogenated liver oil Fatty acid amidohexylbetaine, soybean oil fatty acid amidohexylbetaine, turdle oil fatty acid amidohexylbetaine, teaseed oil fatty acid amidohexylbetaine, camellia oil fatty acid amidohexylbetaine, corn oil fatty acid amidohexylbetaine, rapeseed oil fatty acid amidohexylbetaine, milkfat fatty acid amide hexylbetaine,
Persic oil fatty acid amidohexyl betaine, palm oil fatty acid amidohexyl betaine, bean oil fatty acid amidohexyl betaine, castor oil fatty acid amidohexyl betaine, castor oil fatty acid amidohexyl betaine, grape oil fatty acid amidohexyl betaine, viper oil fatty acid amidohexyl betaine, marmot Oil fatty acid amidohexylbetaine, mink oil fatty acid amidohexylbetaine, cottonseed oil fatty acid amidohexylbetaine, Japanese wax fatty acid amidohexylbetaine, coconut oil fatty acid amidohexylbetaine, egg yolk oil fatty acid amidohexylbetaine,
Amidohexylbetaine nonanoate, Amidohexylbetaine nonenoate, Amidohexylbetaine decanoate, Amidohexylbetaine decenoate, Amidohexylbetaine undecylate, Amidohexylbetaine undecylenate, Amidohexylbetaine dodecanoate, Amidohexylbetaine dodecenoate, Tridecanoic acid Amidohexylbetaine, amidohexylbetaine tridecenoate, amidohexylbetaine tetradecanoate, amidohexylbetaine tetradecenoate, amidohexylbetaine pentadecanoate, amidohexylbetaine pentadecenoate, amidohexylbetaine hexadecanoate, amidohexylbetaine hexadecenoate, amidohexyl heptadecanoate Betaine, amidohexylbetaine octadecanoate, amidohexylbetaine octadecenoate, amidohexylbetaine octadecadienoate, amidohexylbetaine octadecatrienoate, amidohexylbetaine octadecatetraenoate, amidohexylbetaine nonadecanoate, amidohexylbetaine eicosanoate , eicosatetraenoic acid amidohexyl betaine, eicosapene citrate amidohexyl betaine, heneicosanoic acid amidohexyl betaine, and the like.

A specific example when n=7.

Avocado oil fatty acid amide heptyl betaine, almond oil fatty acid amide heptyl betaine, fur seal oil fatty acid amide heptyl betaine, hypericum oil fatty acid amide heptyl betaine, olive oil fatty acid amide heptyl betaine, olive oil fatty acid amide heptyl betaine, cocoa butter fatty acid amide heptyl betaine, Carrot oil fatty acid amide heptyl betaine, cocoa butter fatty acid amide heptyl betaine, cod liver oil fatty acid amide heptyl betaine, cucumber oil fatty acid amide heptyl betaine, beef tallow fatty acid amide heptyl betaine, strong liver oil fatty acid amide heptyl betaine, campan oil fatty acid amide heptyl betaine, hydrogenated oil fatty acid Amidoheptylbetaine, synthetic cocoa butter fatty acid amidoheptylbetaine, sesame oil fatty acid amidoheptylbetaine, wheat germ oil fatty acid amidoheptylbetaine, rice bran oil fatty acid amidoheptylbetaine,
Rice germ oil fatty acid amide heptyl betaine, sasanqua oil fatty acid amide heptyl betaine, safflower oil fatty acid amide heptyl betaine, shea seed oil fatty acid amide heptyl betaine, juzda bean oil fatty acid amide heptyl betaine, hydrogenated cocoa butter fatty acid amide heptyl betaine, hydrogenated liver oil Fatty acid amidoheptylbetaine, soybean oil fatty acid amidoheptylbetaine, turdle oil fatty acid amidoheptylbetaine, teaseed oil fatty acid amidoheptylbetaine, camellia oil fatty acid amidoheptylbetaine, corn oil fatty acid amidoheptylbetaine, rapeseed oil fatty acid 7-midoheptylbetaine, Milk fat fatty acid amide heptyl betaine, persic oil fatty acid amide heptyl betaine, palm oil fatty acid amide heptyl betaine, bean oil fatty acid amide heptyl betaine, castor oil fatty acid amide heptyl betaine, castor oil fatty acid amide heptyl betaine, grape oil fatty acid amide heptyl betaine, viper oil Fatty acid amide heptyl betaine, marmot oil fatty acid amide heptyl betaine, mink oil fatty acid amide heptyl betaine, cottonseed oil fatty acid amide heptyl betaine, Japanese wax fatty acid amide heptyl betaine, coconut oil fatty acid amide heptyl betaine, egg yolk oil fatty acid amide heptyl betaine, nonanoic acid amide heptyl betaine , amidoheptylbetaine nonenoate, amidoheptylbetaine decanoate,
Amidoheptylbetaine decenoate, Amidoheptylbetaine undecylate, Amidoheptylbetaine undecylenate, Amidoheptylbetaine dodecanoate, Amidoheptylbetaine dodecenoate, Amidoheptylbetaine tridecanoate, Amidoheptylbetaine tridecenoate, Amidoheptylbequin tetradecanoate, Tetradecene Acid amidoheptylbetaine, amidoheptylbetaine pentadecanoate, amidoheptylbetaine pentadecenoate, amidoheptylbetaine hexadecanoate, amidoheptylbetaine hexadecenoate, amidoheptylbetaine heptadecanoate, amidoheptylbetaine octadecanoate,
Amidoheptylbetaine octadecenoate, amidoheptylbetaine octadecadienate, amidoheptylbetaine octadecatrienoate, amidoheptylbetaine octadecatetraenoate, amidoheptylbetaine nonadecanoate, amidoheptylbetaine eicosanoate, amidoheptyl eicosatetraenoate Examples include betaine, eicosapene citrate amidoheptylbetaine, and heneicosanoate amidoheptylbetaine.

A specific example when n=8.

Avocado oil fatty acid amide octyl betaine, almond oil fatty acid amide octyl betaine, fur seal oil fatty acid amide octyl betaine, Hypericum oil fatty acid amide octyl betaine, orica oil fatty acid amide octyl betaine, olive oil fatty acid amide octyl betaine, cocoa butter fatty acid amide octyl betaine, carot Oil fatty acid amide octyl betaine, cocoa fat fatty acid amide octyl betaine, cod liver oil fatty acid amide octyl betaine, cucumber oil fatty acid amide octyl betaine, beef tallow fatty acid amide octyl betaine, strong liver oil fatty acid amide octyl betaine, kyonin oil fatty acid amide octyl betaine, hydrogenated oil fatty acid amide Octylbetaine, synthetic cocoa butter fatty acid amide octylbetaine, sesame oil fatty acid amide octylbetaine, wheat germ oil fatty acid amide octylbetaine, rice bran oil fatty acid amide octylbetaine,
Rice germ oil fatty acid amide octyl betaine, sasanqua oil fatty acid amide octyl betaine, safflower oil fatty acid amide octyl betaine, shea oil fatty acid amide octyl betaine, juzda bean oil fatty acid amide octyl betaine, hydrogenated cocoa butter fatty acid amide octyl betaine, hydrogenated liver oil Fatty acid amide octylbetaine, soybean oil fatty acid amide octylbetaine, turdle oil fatty acid amide octylbetaine, teaseed oil fatty acid amide octylbetaine, camellia oil fatty acid amide octylbetaine, corn oil fatty acid amide octylbetaine, rapeseed oil fatty acid amide octylbetaine, milk fat fatty acid amide octyl betaine,
Persic oil fatty acid amide octyl betaine, palm oil fatty acid amide octyl betaine, bean oil fatty acid amide octyl betaine, castor oil fatty acid amide octyl betaine, castor oil fatty acid amide octyl betaine, grape oil fatty acid amide octyl betaine, pit viper oil fatty acid amide octyl betaine, marmot Oil fatty acid amide octyl betaine, mink oil fatty acid amide octyl betaine, cottonseed oil fatty acid amide octyl betaine, Japanese wax fatty acid amide octyl betaine, coconut oil fatty acid amide octyl betaine, egg yolk oil fatty acid amide octyl betaine,
Nonanoic acid amide octyl betaine, nonenoic acid amide octyl betaine, decanoic acid amide octyl betaine, decenoic acid amide octyl betaine, undecylic acid amide octyl betaine, undecylenic acid amide octyl betaine, dodecanoic acid amide octyl betaine, dodecanoic acid amide octyl betaine, tridecanoic acid Amidooctylbetaine, tridecenoic acid amideoctylbetaine, tetradecanoic acid amideoctylbetaine, tetradecenoic acid amideoctylbetaine, pentadecanoic acid amideoctylbetaine, pentadecenoic acid amideoctylbetaine, hexadecanoic acid amideoctylbetaine, hexadecenoic acid amideoctylbetaine, heptadecanoic acid amideoctylbetaine Betaine, Octadecanoic acid amide octyl betaine, Octadecenoic acid amide octyl betaine, Octadecadienoic acid amide octyl betaine, Octadecatrienoic acid amide octyl betaine, Octadecatetraenoic acid amide octyl betaine, Nonadecanoic acid amide octyl betaine, Eicosanoic acid amide octyl betaine , eicosatetraenoic acid amide octyl betaine, eicosapene citrate amide octyl betaine, heneicosanoic acid amide octyl betaine, and the like.

OCH3 (However, in the formula, R is a C0 to CZO linear or branched alkyl group or alkenyl group, and n is an integer of 1 to 8.) In this invention, this fatty acid amide alkyl betaine is mainly used to improve the fineness of foaming in hard water. It is used to impart the following properties, and the amount thereof is preferably 0.1 to 99.8-t%.

The reason is that if it is less than 0.1wtχ, it will not improve the fineness of foaming of hard water, and if it is more than 99.8wt%, the ease of rinsing will be poor, which is not preferable in either case. It is.

The reason why linear or branched alkyl or alkenyl groups are made to have 8 to 20 carbon atoms is that those with less than 8 carbon atoms have weak lipophilic power, and conversely, those with more than 20 carbon atoms have poor lipophilic power. This is because, although the strength is strong, the hydrophilicity deteriorates and the solubility of the fatty acid amide alkyl betaine in water decreases, and the viscosity increases, making handling difficult, which is undesirable in either case.

The reason why n is limited to 1 to 8 is that when n is 0, the ability to improve the fineness of foaming deteriorates, and on the other hand, when n exceeds 8, the solubility in water decreases. This is because it is not desirable.

The hard water detergent composition according to the present invention having such a structure can be used as a solid detergent, hair shampoo, etc. by adding a small amount of perfume, coloring agent, preservative, etc. according to a conventional method, if necessary. When it comes to cleaning agents such as body shampoo, hot springs, seawater,
Even with so-called hard water such as mineral water, it has the same foaming power, foaming durability, oil and fat suspension power, ease of rinsing, and fineness of foam as ordinary soft water, and is excellent even under conditions where no scum is generated. It is a cleaning composition for hard water that has high performance, and in particular does not cause excessive nutrient enrichment of the water quality unlike conventional detergents containing metal chelating agents such as metapolyphosphoric acid, and its cleaning ability is similar to that of metal chelating agents such as metapolyphosphoric acid. Unlike chelating agents, the cleaning effect is not limited, and the cleaning agent can be used even in hard water with a high concentration of metal ions, such as hot springs and seawater.

The effects of this invention will be made clearer by showing Examples and Comparative Examples of this invention below.

Examples 1 to 15 A hard water cleaning composition having the following formulation was prepared.

Example 1 (χ) polyoxyethylene (15B, 0.) alkyl 33.4 (Ca
t~C++) Sodium ether sulfonate lauryl dimethylamine oxide 33.3 Coconut oil fatty acid amidopropyl betaine 33.3 Example 2
(χ) Polyoxyethylene (15E,
O,) Alkyl 90.0 (Cat~C□) Sodium ether sulfonate lauryl dimethylamine oxide 5.0 Coconut oil fatty acid amidopropyl betaine
5.0 Example 3 (χ) Polyoxyethylene (15E, O,) alkyl 80.
0 (Cag-Caa) Sodium Ethersulfonate Lauryl Dimethylamine Oxide 10.0 Coconut Oil Fatty Acid Amidopropyl Betaine io,.

Example 4 (χ) Polyoxyethylene (1511!, 0.) Alkyl 5.0 (C
+z~Cl4) Sodium ether sulfonate lauryl dimethylamine oxide 90.0 Coconut oil fatty acid amidopropyl betaine 5.0 Example 5
(χ) Polyoxyethylene (15H, O
,) Alkyl 50.0 (Cat-'-C+a) Sodium ether sulfonate Stearyldimethylamine oxide 20.0 Amidopropyl betaine laurate 30.0 Example 6
(χ) Polyoxyethylene (9E, O,) alkyl
50.0 (C+z~Cl4) Sodium ether sulfonate dihydroxyethyl laurylamine 10.0
Oxide capric acid amidopropyl betaine 40.0 Example 7 (χ) Polyoxyethylene (7E, O,) alkyl 40.0 (01□~
Cl4) Sodium ether sulfonate Beef tallow alkyl dimethylamine oxide 20.0 Capric acid amidopropyl betaine 40.0 Example 8
(χ) Polyoxyethylene (3E, 0.)
Alkyl 40.0 (C+t~C+a) Sodium ether sulfonate myristyldimethylamine oxide
10. O Balmitic acid amidopropyl betaine 5
0.0 Example 9 (χ) Polyoxyethylene (3B, 0.) Alkyl 30.0 (
Cat~C14) Sodium ether sulfonate palmityl dimethylamine oxide 20.0 Amidopropyl betaine myristate 50.0 Example 10 (
χ) Polyoxyethylene (9H,0,)alkyl 30.0
(C+z-C+t) Sodium ether sulfonate Coconut oil alkyl dimethylamine oxide 10.0 Amidopropyl betaine laurate 60.0 Example 11
(χ) Polyoxyethylene (3E, 0.) Alkyl 4.0 (
C+z～C□) Sodium ether sulfonate Coconut oil alkyl dimethylamine oxide 60 Lauric acid amidopropyl betaine 10.0 Coconut oil fatty acid diethanolamide 5.0 Fragrance
0.5 paraben
0.2 Purified water
74.3 Example 12(χ) Polyoxyethylene (3B, 0.) Alkyl 20.0
(C32-C34) Sodium ethersulfonate palmityldimethylamine oxide 20.0 Amidopropyl betaine myristate 60.0 Example 13
(χ) Polyoxyethylene (7E, O,) alkyl 20.0
(C+z~C+*) Sodium ethersulfonate myristyl dimethylamine oxide 10.0 Amidopropyl betaine palmitate 70.0 Example 14
(χ) Polyoxyethylene (9H,O,)alkyl 10.0
(C82-C34) Sodium ether sulfonate Beef tallow alkyldimethylamine oxide 30.0 Amidopropyl capric acid betaine 60.0 Example 15
(χ) Polyoxyethylene (7B, 0.) alkyl 10.0
(C12-CI4) Sodium ethersulfonate stearyldimethylamine oxide 20.0 Caprylic acid amidopropyl betaine 70.0 (Test method) (Preparation of standard solution) The following standard seawater salt and standard seawater were prepared.

Composition Axis) MgCh 3.807 NaC125,970 CaClt 1.17O NazSO41,31O NazCO30,130 MgSO3 1.658 KgSO40,863 MgBrz O,076 Total 34.984 The above composition was converted into standard sea salt. and add water to this te10
The mixture was brought to 100O and filtered to obtain standard seawater.

A mixed fat and oil described below was prepared.

Coconut oil 20.0 Liquid lanolin 6.0 Liquid paraffin 40.0 Oleyl alcohol 10.0 Castor oil 24.0 Total 100.0 (1. Carbide water foaming power test) 2 g of standard sea salt was placed in a test tube with a capacity of 10 m1. Tori standard seawater 5+sj! and 0.2g of the cleaning agent prepared in the example.
Add.

Place this in a shaking incubator and shake at 40°C for 1 hour.

Furthermore, after thoroughly shaking this with a touch mixer, the height of foam (IIIll) was measured.

(2. Liquid state test after carbide water foam retention test) The liquid state was measured and observed after the foam height was measured in the superhard water foaming power test.

The same liquid state as the liquid without detergent added...O lukewarm or cloudy liquid compared to the solution without detergent added...Δ Separation, precipitation, etc. occurred compared to the solution without detergent added... ×Measurement and observation results were divided into the above three categories and evaluated.

(3. Carbide water foam persistence test) After determining the liquid state of the above-mentioned superhard water foam breakage test, the foam height (m
m) was measured and a superhard water bubble persistence test was conducted.

(Left below) (Results of test Na3) Foam height (mm) Carbide bubble persistence rate = −−−−−−−−−−−−X 100 (χ) (Results of test Na3) Foaming power (mm) (4, Liquid state after carbide bubble persistence test) The liquid state was measured and observed after the carbide bubble persistence was measured in the above-mentioned superhard water bubble persistence test.

Same liquid state as the liquid without the addition of detergent ・−〇Low temperature or cloudy liquid compared to the liquid without the addition of the detergent −・△ Separation, precipitation, etc. occurred compared to the liquid without the addition of the detergent −× Results of measurement and observation The evaluation was divided into the above three categories.

(5, Foaming power test after adding oil and fat after carbide foam persistence test) After the liquid test after the carbide foam persistence test, the mixed oil and fat 0
．． Add 02g of 0.02g and place it in a shaking incubator at 4°C.
Shake for hours.

Further, this was thoroughly shaken with a touch mixer, and the height (mm) of the foam was measured.

(6, Sensory test Foaming) Ten men and women (5 each) (18 to 25 years old) were asked to wash their bodies in a bathtub heated to 35°C with the standard seawater, and compared with a detergent made of potassium laurate. The degree of foaming was then scored.

The evaluation was 3 points for very good lather, 2 points for good lather,
The total score was calculated, with 1 point being a slightly foamy point and 0 point being the same.

(7. Sensory test rinsing ease) Ten men and women (5 each) (18 to 25 years old) were asked to wash their bodies in a bathtub containing the standard seawater heated to 35°C. The degree of ease of rinsing was scored as compared to a detergent consisting only of detergents.

For the evaluation, the total score was determined as 3 points for very good, 2 points for good, 1 point for somewhat good, and 0 points for the same.

(8. Sensory test Texture evaluation) Ten men and women (5 each) (18 to 25 years old) were asked to wash their bodies with the detergent of the example in a bathtub containing the standard seawater heated to 35°C. The level of texture was scored and compared to when the subjects washed their bodies with tap water heated to 35°C using a detergent made only of potassium laurate.

For the evaluation, the total score was calculated as 3 points for very fine, 2 points for fine, 1 point for slightly fine, and 0 points for the same or less.

The results are summarized in Table 1.

Incidentally, as a comparative example, one having the following composition was used.

Comparative Example 1 (χ) Polyoxyethylene (15E, 0.) Alkyl 90.1 (
C02-C04) Sodium ether sulfonate Coconut oil alkyl dimethylamine oxide 1° Lauric acid amidopropyl betaine 1.0 Fragrance
0.5 paraben
0.2 Purified water
7.2 Comparative Example 2
(χ)Lauryldimethylamine oxide
100.0 Comparative Example 3 (
χ) Coconut oil fatty acid amidopropyl betai 7 100.0
Comparative example 4 (χ) Potassium laurate 100.0 Comparative example 5
(χ) Polyoxyethylene (15E, Oo) alkyl 50.0 (C, 2-C
IA) Sodium ether sulfonate lauryl dimethylamine oxide 50.0 Comparative Example 6
(χ) Polyoxyethylene (15E
, Oo) Alkyl 50.0 (CI!~C14) Sodium ether sulfonate Coco fatty acid amidopropyl betaine 50.0 Comparative example 7
(χ)Lauryldimethylamine oxide
50.0 Coconut oil fatty acid amidopropyl betaine 50.0
Comparative Example 8 (χ) Polyoxyethylene (15E, O,) alkyl 0.05 (C
+z~C+a) Sodium ether sulfonate lauryl dimethylamine oxide 29.95 Coconut oil fatty acid amidopropyl betaine 70.0 Comparative example 9
(χ) Polyoxyethylene (15B
,0. ) Alkyl 39.95 (CI2-C54) Sodium ether sulfonate lauryl dimethylamine oxide 0.05 Coconut oil fatty acid amidopropyl betaine 60.0 Comparative example 10 (χ) Polyoxyethylene (15E, O,) alkyl 49
．． 95 (C+z-C+4) Sodium ether sulfonate lauryl dimethylamine oxide 50.0 Coconut oil fatty acid amidopropyl betaine 0.05 The results of comparative examples are also summarized in Table 1.

(Hereinafter, blank spaces) Table 1 As is clear from the results shown above, the hard water detergent composition according to the present invention has excellent effects.

Claims (1)

[Claims] (1) 0.1 to 90.0 wt% of polyoxyethylene alkyl ether sulfonate represented by the following formula (1) and 0.1 wt% of the alkyl amine oxide represented by the following formula (2)
99.8 wt% and 0.1 to 99.8 wt% of fatty acid amide alkyl betaine represented by the following formula (3), respectively. R-(OCH_2CH_2)n-SO_3-X...(
1) (However, in the formula, R is a linear or branched alkyl group or alkenyl group of C_8 to C_2_0, n is an integer of 1 to 30, and X is sodium, potassium, ammonia, monoethanolamine, diethanolamine, triethanol amine) ▲Mathematical formulas, chemical formulas, tables, etc.▼...(2) (However, in the formula, R_1 is a C_8 to C_2_0 linear or branched alkyl group or alkenyl group, and R_2 is methyl. group or hydroxyethyl group.) ▲There are mathematical formulas, chemical formulas, tables, etc.▼・・・・・・(3), (However, in the formula, R is a C_8 to C_2_0 straight chain or branched alkyl group or alkenyl group. , n indicates an integer from 1 to 8.)