CN102631295A - Multifunctional foam liquid soap containing glucoside and derivatives of glucoside, and preparation method thereof - Google Patents

Multifunctional foam liquid soap containing glucoside and derivatives of glucoside, and preparation method thereof Download PDF

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Publication number
CN102631295A
CN102631295A CN2012100886155A CN201210088615A CN102631295A CN 102631295 A CN102631295 A CN 102631295A CN 2012100886155 A CN2012100886155 A CN 2012100886155A CN 201210088615 A CN201210088615 A CN 201210088615A CN 102631295 A CN102631295 A CN 102631295A
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Prior art keywords
citrate
alcohol ether
glucoside
multifunctional foam
handwashing liquid
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CN2012100886155A
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CN102631295B (en
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白亮
杨秀全
张军
周媛
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China Daily Chemical Industry Research Institute
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China Daily Chemical Industry Research Institute
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Abstract

The invention relates to a multifunctional foam liquid soap containing glucoside and derivatives of glucoside, which comprises the following raw materials by weight percent: 6.0-9.0% of citrate, 1.0-3.0% of alkyl glycoside or alcohol ether glycoside, 0.5-1.5% of coconut oil monoethanolamide (CMEA), 0.1-1.0% of bacteriacide, 0-0.4% of essence, 0-0.001% of pigment and the balance of deionized water. The multifunctional foam liquid soap has the advantages of being non-toxic and harmless to the skin.

Description

Contain multifunctional foam handwashing liquid of glucosides and derivant thereof and preparation method thereof
Technical field
The invention belongs to a kind of handwashing liquid and preparation method thereof, be specifically related to a kind of multifunctional foam handwashing liquid that contains glucosides and derivant thereof and preparation method thereof.
Background technology
Handwashing liquid is a kind of hand cleaning product that occurs in recent years.It is compared with traditional fancy soap, soap, has avoided solidss such as fancy soap, soap to become easily infected by on hand dirt and the defective of antibacterial, has reduced the probability of cross infection.Yet part handwashing liquid prescription has the sordid sensation of flushing because the surfactant improper use remains on the skin after the use easily, makes that skin is dry to be sent out puckery, and skin is damaged.In addition, the multiclass active matter that traditional handwashing liquid prescription generally uses all contains poisonous harmfulness impurity, and for example ether alcohol sulfate AES contains that diox, alkanolamide 6501 contain nitrosamine, alkyl betaine contains chloroethene acids carcinogen etc.
Summary of the invention
The objective of the invention is to a kind of nontoxicly, do not contain multifunctional foam handwashing liquid of glucosides and derivant thereof and preparation method thereof what skin had an injury.
The present invention realizes through following technology:
A kind of multifunctional foam handwashing liquid, the percentage by weight of its raw material consists of:
Citrate 6.0-9.0%
Alkyl polyglucoside or alcohol ether glucoside 1.0-3.0%
Coconut oil single ethanol amide (CMEA) 0.5-1.5%
Antibacterial 0.1-1.0%
Essence 0-0.4%
Pigment 0-0.001%
The deionized water surplus
Citrate is fatty alcohol ether citrate, alkyl polyglucoside citrate, alcohol ether glucoside citrate etc. in the foregoing invention, is the chemical compound with following general formula:
In the formula: R 1For carbon number is 8～18 alkyl, m is O or 1.2～1.8, and n is 0～9, and m and n are not 0 simultaneously.
Wherein: m is O, n be 1～9 o'clock be the fatty alcohol ether citrate;
M is 1.2～1.8, n be 1～9 o'clock be the alcohol ether glucoside citrate;
M is 1.2～1.8, n be 0 o'clock be the alkyl polyglucoside citrate.
Alkyl polyglucoside or alcohol ether glucoside are the chemical compounds with following general formula in the foregoing invention:
In the formula: R 2For carbon number is 8～18 alkyl, m is 1.2～1.8, and n is 0～9.
Wherein: n be 0 o'clock be the alkyl polyglucoside of different carbon numbers, n be not 0 o'clock be C 12～14Alcohol ether glucoside.
Antibacterial is poly hexamethylene biguanide, dodine etc. in the foregoing invention.
A kind of multifunctional foam handwashing liquid, method for preparing is following:
Raw material is formed by its percentage by weight; 70-80% addingization material still with citrate and deionized water gross weight; Stir and to add NaOH down to be neutralized to PH be 6.0-7.0, add alkyl polyglucoside or alcohol ether glucoside and CMEA down at 70-80 ℃ again, stir and treat that said raw material all is cooled to 30-40 ℃ after the dissolving; Add antibacterial, pigment, essence and surplus deionized water again, obtain said multifunctional foam handwashing liquid after stirring.
The present invention compared with prior art has following advantage:
1, the multifunctional foam of the present invention fluid power deep-pollution-removing of washing one's hands, feel is soft and moist, and foam is fine and smooth, is prone to flushing.Used green active matter is a polyol, has the effect of skin-moisturizing, skin, can prevent that skin from cracking from dryness, and sterilization component can effectively prevent bacteria breed.
2, multifunctional foam handwashing liquid prescription of the present invention is raw materials used all nontoxic, non-stimulated, to human body safety, environmental friendliness.
The specific embodiment
Below in conjunction with specific embodiment the present invention is done to further describe, these embodiment only are used to the present invention is described and are not used in restriction scope of the present invention.
Embodiment 1
Raw material weight percentage ratio component is:
C 12～14Fatty alcohol ether citrate (EO=3) 6.0%
C 12～14Alkyl polyglucoside (degree of polymerization DP=1.8) 2.5%
CMEA 2.0%
Poly hexamethylene biguanide 0.1%
Essence 0.2%
Pigment 0.0004%
The deionized water surplus
Method for preparing:
Raw material is by its percentage by weight, with C 12～1470% addingization material still of fatty alcohol ether citrate (EO=3) and deionized water gross weight stirs and to add NaOH down to be neutralized to PH be 6.2, adds C down at 73 ℃ again 12～14Alkyl polyglucoside (degree of polymerization DP=1.8) and CMEA stir and treat that said raw material all is cooled to 30 ℃ after the dissolving, add poly hexamethylene biguanide, pigment, essence and surplus deionized water again, obtain said multifunctional foam handwashing liquid after stirring.
Embodiment 2
Raw material weight percentage ratio component is:
C 8～10Alkyl polyglucoside citrate (DP=1.2) 7.0%
C 16～18Alkyl polyglucoside (DP=1.2) 2.0%
CMEA 1.2%
Poly hexamethylene biguanide 0.5%
Essence 0.3%
Pigment 0.0006%
The deionized water surplus
Method for preparing:
Raw material is by its percentage by weight, with C 8～1080% addingization material still of alkyl polyglucoside citrate (DP=1.2) and deionized water gross weight stirs and to add NaOH down to be neutralized to PH be 7.0, adds C down at 70 ℃ again 16～18Alkyl polyglucoside (DP=1.2) and CMEA stir and treat that said raw material all is cooled to 35 ℃ after the dissolving, add poly hexamethylene biguanide, pigment, essence and surplus deionized water again, obtain said multifunctional foam handwashing liquid after stirring.
Embodiment 3
Raw material weight percentage ratio component is:
C 16～18Alcohol ether glucoside citrate (EO=6, DP=1.8) 9.0%
C 12～14Alcohol ether glucoside (EO=9, DP=1.8) 1.0%
CMEA 0.5%
Dodine 0.7%
Essence 0.1%
Pigment 0.001%
The deionized water surplus
Method for preparing:
Raw material is by its percentage by weight, with C 16～18(EO=6 DP=1.8) with 73% addingizations material still of deionized water gross weight, stirs and adds NaOH down to be neutralized to PH be 6.0, again adding C under 80 ℃ the alcohol ether glucoside citrate 12～14(EO=9 DP=1.8) and CMEA, stirs and treats that said raw material all is cooled to 40 ℃ after the dissolving alcohol ether glucoside, adds dodine, pigment, essence and surplus deionized water again, obtains said multifunctional foam handwashing liquid after stirring.
Embodiment 4
Raw material weight percentage ratio component is:
C 16～18Alkyl polyglucoside citrate (DP=1.8) 8.0%
C 8～10Alkyl polyglucoside (DP=1.4) 1.0%
CMEA 1.0%
Poly hexamethylene biguanide 0.3%
Essence 0.4%
Pigment 0.0008%
The deionized water surplus
Method for preparing:
Raw material is by its percentage by weight, with C 16～1877% addingization material still of alkyl polyglucoside citrate (DP=1.8) and deionized water gross weight stirs and to add NaOH down to be neutralized to PH be 6.6, adds C down at 76 ℃ again 8～10Alkyl polyglucoside (DP=1.4) and CMEA stir and treat that said raw material all is cooled to 36 ℃ after the dissolving, add poly hexamethylene biguanide, pigment, essence and surplus deionized water again, obtain said multifunctional foam handwashing liquid after stirring.
Embodiment 5
Raw material weight percentage ratio component is:
C 12～14Alcohol ether glucoside citrate (EO=9, DP=1.4) 8.0%
C 16～18Alkyl polyglucoside (DP=1.3) 1.5%
CMEA 0.8%
Dodine 0.6%
Essence 0.2%
Pigment 0.001%
The deionized water surplus
Method for preparing:
Raw material is by its percentage by weight, with C 12～14(EO=9 DP=1.4) with 78% addingizations material still of deionized water gross weight, stirs and adds NaOH down to be neutralized to PH be 6.4, again adding C under 77 ℃ the alcohol ether glucoside citrate 16～18Alkyl polyglucoside (DP=1.3) and CMEA stir and treat that said raw material all is cooled to 34 ℃ after the dissolving, add dodine, pigment, essence and surplus deionized water again, obtain said multifunctional foam handwashing liquid after stirring.
Embodiment 6
Raw material weight percentage ratio component is:
C 8～10Fatty alcohol ether citrate (EO=9) 6.0%
C 12～14Alcohol ether glucoside (EO=3, DP=1.2) 2.5%
CMEA 1.2%
Dodine 0.5%
Essence 0.1%
Pigment 0.007%
The deionized water surplus
Method for preparing:
Raw material is by its percentage by weight, with C 8～1073% addingization material still of fatty alcohol ether citrate (EO=9) and deionized water gross weight stirs and to add NaOH down to be neutralized to PH be 6.4, adds C down at 76 ℃ again 12～14(EO=3 DP=1.2) and CMEA, stirs and treats that said raw material all is cooled to 38 ℃ after the dissolving alcohol ether glucoside, adds dodine, pigment, essence and surplus deionized water again, obtains said multifunctional foam handwashing liquid after stirring.
Embodiment 7
Raw material weight percentage ratio component is:
C 8～10Alcohol ether glucoside citrate (EO=1, DP=1.2) 9.0%
C 12～14Alcohol ether glucoside (EO=6, DP=1.4) 1.0%
CMEA 1.2%
Poly hexamethylene biguanide 0.7%
Essence 0.3%
Pigment 0.004%
The deionized water surplus
Method for preparing:
Raw material is by its percentage by weight, with C 8～10(EO=1 DP=1.2) with 80% addingizations material still of deionized water gross weight, stirs and adds NaOH down to be neutralized to PH be 6.1, again adding C under 70 ℃ the alcohol ether glucoside citrate 12～14(EO=6 DP=1.4) and CMEA, stirs and treats that said raw material all is cooled to 40 ℃ after the dissolving alcohol ether glucoside, adds poly hexamethylene biguanide, pigment, essence and surplus deionized water again, obtains said multifunctional foam handwashing liquid after stirring.

Claims (5)

1. multifunctional foam handwashing liquid that contains glucosides and derivant thereof is characterized in that the percentage by weight of its raw material consists of:
Citrate 6.0-9.0%
Alkyl polyglucoside or alcohol ether glucoside 1.0-3.0%
Coconut oil single ethanol amide 0.5-1.5%
Antibacterial 0.1-1.0%
Essence 0-0.4%
Pigment 0-0.001%
The deionized water surplus.
2. a kind of multifunctional foam handwashing liquid that contains glucosides and derivant thereof as claimed in claim 1 is characterized in that described citrate is the chemical compound with following general formula:
In the formula: R 1For carbon number is 8～18 alkyl, m is O or 1.2～1.8, and n is 0～9, and m and n are not 0 simultaneously;
Wherein: m is O, n be 1～9 o'clock be the fatty alcohol ether citrate;
M is 1.2～1.8, n be 1～9 o'clock be the alcohol ether glucoside citrate;
M is 1.2～1.8, n be 0 o'clock be the alkyl polyglucoside citrate.
3. a kind of multifunctional foam handwashing liquid that contains glucosides and derivant thereof as claimed in claim 1 is characterized in that described alkyl polyglucoside or alcohol ether glucoside are the chemical compounds with following general formula:
Figure 231634DEST_PATH_IMAGE002
In the formula: R 2For carbon number is 8～18 alkyl, m is 1.2～1.8, and n is 0～9;
Wherein: n be 0 o'clock be the alkyl polyglucoside of different carbon numbers, n be not 0 o'clock be C 12～14Alcohol ether glucoside.
4. a kind of multifunctional foam handwashing liquid that contains glucosides and derivant thereof as claimed in claim 1 is characterized in that described antibacterial is poly hexamethylene biguanide or dodine.
5. like each described a kind of method for preparing that contains the multifunctional foam handwashing liquid of glucosides and derivant thereof of claim 1-4, it is characterized in that comprising the steps:
Raw material is formed by its percentage by weight; 70-80% addingization material still with citrate and deionized water gross weight; Stir and to add NaOH down to be neutralized to PH be 6.0-7.0, add alkyl polyglucoside or alcohol ether glucoside and CMEA down at 70-80 ℃ again, stir and treat that said raw material all is cooled to 30-40 ℃ after the dissolving; Add antibacterial, pigment, essence and surplus deionized water again, obtain said multifunctional foam handwashing liquid after stirring.
CN 201210088615 2012-03-30 2012-03-30 Multifunctional foam liquid soap containing glucoside and derivatives of glucoside, and preparation method thereof Expired - Fee Related CN102631295B (en)

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Cited By (15)

* Cited by examiner, † Cited by third party
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CN103271834A (en) * 2013-06-18 2013-09-04 中国日用化学工业研究院 Non-irritant pollution-free moisturizing pearly lustre bath foam and preparation method thereof
CN103301029A (en) * 2013-06-18 2013-09-18 中国日用化学工业研究院 Facial cleanser capable of balancing oil and moisturizing skin, and preparation method thereof
CN103498336A (en) * 2013-09-17 2014-01-08 安阳博奥生物新合成有限公司 Environment-friendly scouring agent
CN103498337A (en) * 2013-09-17 2014-01-08 安阳博奥生物新合成有限公司 Application of environment-friendly scouring agent
CN103553981A (en) * 2013-11-05 2014-02-05 中国日用化学工业研究院 Sodium fatty acyl oxyisopropyl sulfonate as well as synthetic method and application thereof
CN103705418A (en) * 2013-12-20 2014-04-09 青岛琴诚医药技术有限公司 Liquid soap
CN104194968A (en) * 2014-09-19 2014-12-10 江苏万淇生物科技有限公司 Washing product containing AEG (Alkyl Ethoxy Polyglycosides) for hand washing dishes
CN104323925A (en) * 2014-09-29 2015-02-04 江苏万淇生物科技有限公司 Bath lotion being green, environmental-protective and gentle and containing glucoside derivative
CN104434556A (en) * 2014-11-11 2015-03-25 上海万淇生物科技有限公司 Hand sanitizer containing glucoside and derivatives of glucoside
CN106265350A (en) * 2016-09-22 2017-01-04 长兴净安环保科技有限公司 A kind of bacteriostatic hand sanitizer and preparation method thereof
CN106309281A (en) * 2016-09-22 2017-01-11 长兴净安环保科技有限公司 Anti-bacteria foam hand sanitizer and preparation method thereof
CN106554856A (en) * 2016-10-14 2017-04-05 无锡市华诚印染剂厂 A kind of good water soluble detergent of biochemical degradation degree
CN108938468A (en) * 2018-08-29 2018-12-07 陕西为康食品科技股份有限公司 A kind of Chinese prickly ash hand cleanser and preparation method thereof
CN109157435A (en) * 2018-09-28 2019-01-08 陕西为康食品科技股份有限公司 A kind of sterilization, the bacteriostatic hand sanitizer of Chinese prickly ash and Mongollian Thyme Herb essential oil
CN109199934A (en) * 2018-11-27 2019-01-15 微普安全科技（徐州）股份有限公司 A kind of foam liquid soap and preparation method thereof

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CN101816625A (en) * 2010-05-17 2010-09-01 北京绿伞化学股份有限公司 Mild low-stimulation hand sanitizer and preparation method thereof
CN102138883A (en) * 2011-03-21 2011-08-03 吉林大学 Changbai Mountain ledum palustre bactericidal skin care hand washing lotion and preparation method thereof

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CN101381656A (en) * 2008-10-30 2009-03-11 九三粮油工业集团有限公司 Method for preparing soya bean lecithin hand cleanser
CN101816625A (en) * 2010-05-17 2010-09-01 北京绿伞化学股份有限公司 Mild low-stimulation hand sanitizer and preparation method thereof
CN102138883A (en) * 2011-03-21 2011-08-03 吉林大学 Changbai Mountain ledum palustre bactericidal skin care hand washing lotion and preparation method thereof

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103301029A (en) * 2013-06-18 2013-09-18 中国日用化学工业研究院 Facial cleanser capable of balancing oil and moisturizing skin, and preparation method thereof
CN103271834A (en) * 2013-06-18 2013-09-04 中国日用化学工业研究院 Non-irritant pollution-free moisturizing pearly lustre bath foam and preparation method thereof
CN103301029B (en) * 2013-06-18 2015-03-04 中国日用化学工业研究院 Facial cleanser capable of balancing oil and moisturizing skin, and preparation method thereof
CN103498337B (en) * 2013-09-17 2016-05-04 安阳博奥生物新合成有限公司 A kind of application of environment-friendly type scouring agent
CN103498336A (en) * 2013-09-17 2014-01-08 安阳博奥生物新合成有限公司 Environment-friendly scouring agent
CN103498337A (en) * 2013-09-17 2014-01-08 安阳博奥生物新合成有限公司 Application of environment-friendly scouring agent
CN103498336B (en) * 2013-09-17 2016-05-04 安阳博奥生物新合成有限公司 A kind of environment-friendly type scouring agent
CN103553981A (en) * 2013-11-05 2014-02-05 中国日用化学工业研究院 Sodium fatty acyl oxyisopropyl sulfonate as well as synthetic method and application thereof
CN103553981B (en) * 2013-11-05 2016-06-22 中国日用化学工业研究院 Fat acyl-oxygen sodium isopropyl xanthate and synthetic method and application
CN103705418A (en) * 2013-12-20 2014-04-09 青岛琴诚医药技术有限公司 Liquid soap
CN104194968A (en) * 2014-09-19 2014-12-10 江苏万淇生物科技有限公司 Washing product containing AEG (Alkyl Ethoxy Polyglycosides) for hand washing dishes
CN104323925A (en) * 2014-09-29 2015-02-04 江苏万淇生物科技有限公司 Bath lotion being green, environmental-protective and gentle and containing glucoside derivative
CN104434556A (en) * 2014-11-11 2015-03-25 上海万淇生物科技有限公司 Hand sanitizer containing glucoside and derivatives of glucoside
CN104434556B (en) * 2014-11-11 2017-10-03 江苏万淇生物科技有限公司 A kind of hand cleanser containing glucosides and its derivative
CN106265350A (en) * 2016-09-22 2017-01-04 长兴净安环保科技有限公司 A kind of bacteriostatic hand sanitizer and preparation method thereof
CN106309281A (en) * 2016-09-22 2017-01-11 长兴净安环保科技有限公司 Anti-bacteria foam hand sanitizer and preparation method thereof
CN106554856A (en) * 2016-10-14 2017-04-05 无锡市华诚印染剂厂 A kind of good water soluble detergent of biochemical degradation degree
CN108938468A (en) * 2018-08-29 2018-12-07 陕西为康食品科技股份有限公司 A kind of Chinese prickly ash hand cleanser and preparation method thereof
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