CN104194968A - Washing product containing AEG (Alkyl Ethoxy Polyglycosides) for hand washing dishes - Google Patents
Washing product containing AEG (Alkyl Ethoxy Polyglycosides) for hand washing dishes Download PDFInfo
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- CN104194968A CN104194968A CN201410484801.XA CN201410484801A CN104194968A CN 104194968 A CN104194968 A CN 104194968A CN 201410484801 A CN201410484801 A CN 201410484801A CN 104194968 A CN104194968 A CN 104194968A
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- ether glucoside
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Abstract
The invention relates to a washing product containing AEG (Alkyl Ethoxy Polyglycosides) for hand washing dishes. The washing product comprises the following components in percentage by weight: 26.0-50.0% of AEG, 1.0-1.5% of dodecyl betain, 31.0-35.0% of cocamidopropylamine oxide, 1.0-4.0% of citric acid, 6.0-12.0% of a thickening product, and the balance of deionized water. According to the washing product provided by the invention, non-ionic surface active products and amphoteric surface active products are used in a combined manner, so that the product is environment-friendly, gentle and non-irritating to skin, and is suitable for hand washing; moreover, an application of AEG in industries is successfully realized, the expansion of the production scale is facilitated, and benefits are brought to the human society; furthermore, a cooling preparation production technology is adopted in a preparation process, thereby being capable of dissolving the surface active products without need of wasting heat energy to heat and lowering the production cost.
Description
Technical field
The invention belongs to articles for washing field, especially relate to a kind of hand dishwashing articles for use that contain alcohol ether glucoside.
Background technology
Dish washing detergent is that current family is used the widest daily article for washing.Enhancing along with people's environmental consciousness and health perception, surfactivity articles for use industrial expansion, washing article for dishware has been had to higher requirement and expectation, and the research that makes its formula is day by day to functional, the economy of product and to aspect development such as human safety and environmental safeties.The washing article for dishware of prior art generally be take anion surface activity articles for use Sodium dodecylbenzene sulfonate (LAS) and polyoxyethylenated alcohol sodium sulfate (AES) as main, for example the patent No. is that ZL201110413453.3, patentee are that Southern Yangtze University, patent name are a kind of Chinese patent of the washing article for dishware that contains N-fatty acyl group glutaminate, adopt anion surface activity articles for use Sodium dodecylbenzene sulfonate (LAS), be called for short file 1; And the patent No. is that ZL200910213873.X, patentee are that Chen Zheng, patent name are the Chinese patent of multi-component concentrated dish articles for washing simultaneously, adopted polyoxyethylenated alcohol sodium sulfate as surfactivity articles for use, be called for short file 2, this type of washing article for dishware has certain pungency to skin, and polyoxyethylenated alcohol sodium sulfate (AES) is not soluble in water, process for preparation needs heating, increases production cost.
The class specific function that alcohol ether glucoside AEGShi China has independent intellectual property right helps articles for use, belongs to the improved properties product of alkyl glycoside APG, than APG, has better low-temperature water-soluble, mildness, compatibility and resistance to hard water.AEG series products stable chemical nature, nontoxic, non-stimulated, to human body and environmental safety, be easy to biological degradation, good, the resistance to hard water of low-temperature water-soluble, have preserving moisture and protecting skin effect, be applied to, in formula, can significantly reduce the pungency of integral formulation, formula system is had to good tackify effect.The raw materials cost of AEG and product price be lower than APG, is that cost performance is higher, Application Areas novel, green multi-functional look surfactivity articles for use widely.But because it is still in development, to not grasping completely in its performance, more have no way of it to refer in the large-scale application aspect articles for washing.
Summary of the invention
The deficiency existing for above-mentioned file, the invention provides a kind ofly contain alcohol ether glucoside, washing effect is good, cost is low, safe and non-stimulating, and washing article for dishware that can large-scale commercial production.
For achieving the above object, the invention provides a kind of hand dishwashing articles for use that contain alcohol ether glucoside, by following composition by weight percentage composition calculate and to form:
Further, described alcohol ether glucoside is the compound with following general formula:
Wherein: R is that carbonatoms is the alkyl of 8-14, and m is 1.2-1.8, and n is 1-9.
Preferably, described thickening articles for use are sodium-chlor.
Further, described articles for washing is solid state, liquid, gel shape, paste, spumescence.
The preparation method of the hand dishwashing articles for use that contain alcohol ether glucoside as above: the alcohol ether glucoside of metering, empgen BB and cocamidopropyl propyl amide amine oxide are added in the deionized water of metering successively, stir, with appropriate lemon acid for adjusting pH to 6.5-7.5, further, can also add as required appropriate essence, anticorrosion articles for use, pigment etc., after stirring, add appropriate thickening articles for use to be adjusted to appropriate viscosity and obtain hand dishwashing articles for use of the present invention.
Beneficial effect of the present invention is: non-ionic surface active articles for use and amophoteric surface active articles for use are combined with, and product environmental protection, to the gentle nonirritant of skin, is applicable to hand washing; Successfully realized alcohol ether glucoside in industrial application, be conducive to expand the production application aspect cleaning product, society promotes the well-being of mankind simultaneously; Moreover the present invention adopts the cold production technique of joining in preparation process, do not need to expend heat energy heating for dissolving surfactivity articles for use, save production cost.
Embodiment
Below in conjunction with specific embodiment, the present invention is further explained.
Embodiment 1:
A kind of gentle hand dishwashing articles for use that contain alcohol ether glucoside described in the embodiment of the present invention, its components in weight percent:
Preparation method: the alcohol ether glucoside of metering, empgen BB and cocamidopropyl propyl amide amine oxide are added in the deionized water of metering successively, stir, with appropriate lemon acid for adjusting pH to 6.5-7.5, can also add again appropriate anticorrosion articles for use, essence, pigment if necessary, after stirring, add appropriate thickening articles for use to be adjusted to appropriate viscosity and obtain hand dishwashing articles for use of the present invention, wherein thickening articles for use are sodium chloride.
Embodiment 2
Gentle hand dishwashing articles for use that contain alcohol ether glucoside, its components in weight percent:
Preparation method is identical with embodiment 1.
Embodiment 3
Gentle hand dishwashing articles for use that contain alcohol ether glucoside, its components in weight percent:
Preparation method is identical with embodiment 1.
Embodiment 4
Gentle hand dishwashing articles for use that contain alcohol ether glucoside, its components in weight percent:
Preparation method is identical with embodiment 1.
In order further to prove effect of the present invention, 2 patents in background technology and the present invention are tested to contrast under the same conditions, wherein 4 of file 1 embodiment are called comparative example 1, comparative example 2, comparative example 3, comparative example 4, 11 embodiment of file 2 are called comparative example 5, comparative example 6, comparative example 7, comparative example 8, comparative example 9, comparative example 10, comparative example 11, comparative example 12, comparative example 13, comparative example 14, comparative example 15, 4 embodiment of the application are called embodiment 1, embodiment 2, embodiment 3, embodiment 4, specific experiment process is as follows:
Step 1: the configuration experiments such as the raw material of recording according to associated documents respectively, concentration need articles for washing;
Step 2: get respectively the articles for washing that 6ml configures, the water of putting into 3kg stirs;
Step 3: rub in solution and wash 10 times with special-purpose sponge respectively, observe height and the residence time of foam, concrete outcome is as shown in table 1:
From comparative example 1-4 and embodiment 1-4 contrast, can find out, the articles for washing foam height of file 1 is lower, from comparative example 5-15 and embodiment 1-4 contrast, can find out, although foam height and the application are similar, but overstand, that is to say and after washing tableware, be difficult for rinsing well, on tableware surface, easily leave spot, be not suitable as the articles for washing of tableware.
And observe the hand that is finished 3 kinds of articless for washing, discovery used the hand after the articles for washing described in file 2 rubescent, that is to say that its product has stronger pungency, and was not suitable for hand washing; And used the hand after the articles for washing described in file 1 slightly rubescent, illustrate that it has certain pungency; And the hand of using articles for washing of the present invention is not seen rubescent phenomenon, do not illustrate and come to harm, real being applicable to, hand-washes.
According to the method described in GB 9986-2000, the corresponding articles for washing of embodiment is tested subsequently, Example formulations indices all meets GB requirement.
Table 1 articles for washing washing effect synopsis
| ? | Foam height (mm) | The residence time (min) |
| Comparative example 1 | 85 | 5 |
| Comparative example 2 | 87 | 2 |
| Comparative example 3 | 79 | 4.5 |
| Comparative example 4 | 84 | 3 |
| Comparative example 5 | 110 | 20 |
| Comparative example 6 | 124 | 16 |
| Comparative example 7 | 131 | 14 |
| Comparative example 8 | 125 | 25 |
| Comparative example 9 | 153 | 20 |
| Comparative example 10 | 143 | 18 |
| Comparative example 11 | 138 | 23 |
| Comparative example 12 | 149 | 17 |
| Comparative example 13 | 151 | 23 |
| Comparative example 14 | 125 | 27 |
| Comparative example 15 | 126 | 29 |
| Embodiment 1 | 142 | 5 |
| Embodiment 2 | 150 | 4 |
| Embodiment 3 | 153 | 4 |
| Embodiment 4 | 148 | 6 |
Only as described above, be only preferred embodiment of the present invention, professional who are familiar with this art such as, and after understanding technique means of the present invention, natural energy, according to actual needs, is changed under instruction of the present invention.Therefore all equal variation and modifications of doing according to the present patent application the scope of the claims, all should still remain within the scope of the patent.
Claims (6)
1. hand dishwashing articles for use that contain alcohol ether glucoside, is characterized in that: by following composition by weight percentage composition calculate and to form:
2. hand dishwashing articles for use that contain alcohol ether glucoside according to claim 1, is characterized in that: described alcohol ether glucoside is the compound with following general formula:
Wherein: R is that carbonatoms is the alkyl of 8-14, and m is 1.2-1.8, and n is 1-9.
3. the hand dishwashing articles for use that contain alcohol ether glucoside according to claim 2, is characterized in that: described thickening articles for use are sodium-chlor.
4. hand dishwashing articles for use that contain alcohol ether glucoside according to claim 2, is characterized in that: described articles for washing is solid state, liquid, gel shape, paste, spumescence.
5. a method of preparing as above the hand dishwashing articles for use that contain alcohol ether glucoside described in claim arbitrarily, it is characterized in that comprising the steps: the alcohol ether glucoside of metering, empgen BB and cocamidopropyl propyl amide amine oxide are added in the deionized water of metering successively, stir, with appropriate lemon acid for adjusting pH, to 6.5-7.5, after stirring, add appropriate thickening articles for use to be adjusted to appropriate viscosity and obtain hand dishwashing articles for use of the present invention.
6. the application of alcohol ether glucoside in hand dishwashing articles for use.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410484801.XA CN104194968A (en) | 2014-09-19 | 2014-09-19 | Washing product containing AEG (Alkyl Ethoxy Polyglycosides) for hand washing dishes |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410484801.XA CN104194968A (en) | 2014-09-19 | 2014-09-19 | Washing product containing AEG (Alkyl Ethoxy Polyglycosides) for hand washing dishes |
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| CN104194968A true CN104194968A (en) | 2014-12-10 |
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| CN201410484801.XA Pending CN104194968A (en) | 2014-09-19 | 2014-09-19 | Washing product containing AEG (Alkyl Ethoxy Polyglycosides) for hand washing dishes |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106479727A (en) * | 2016-09-22 | 2017-03-08 | 长兴净安环保科技有限公司 | A kind of environment-friendly type imitates net Multifunctional detergent and preparation method thereof entirely |
| CN106479707A (en) * | 2016-09-22 | 2017-03-08 | 长兴净安环保科技有限公司 | A kind of oil cauldron cleaning agent of high-efficient greasy dirt removing and preparation method thereof |
| CN113637534A (en) * | 2021-08-13 | 2021-11-12 | 云南洗消佳医药科技有限公司 | Double-chain quaternary ammonium salt cleaning solution |
Citations (4)
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| CN1651129A (en) * | 2004-11-30 | 2005-08-10 | 中国日用化学工业研究院 | Surface active agent alcohol ether glucoside and its preparation method |
| CN102631295A (en) * | 2012-03-30 | 2012-08-15 | 中国日用化学工业研究院 | Multifunctional foam liquid soap containing glucoside and derivatives of glucoside, and preparation method thereof |
| CN103271834A (en) * | 2013-06-18 | 2013-09-04 | 中国日用化学工业研究院 | Non-irritant pollution-free moisturizing pearly lustre bath foam and preparation method thereof |
| CN103301029A (en) * | 2013-06-18 | 2013-09-18 | 中国日用化学工业研究院 | Facial cleanser capable of balancing oil and moisturizing skin, and preparation method thereof |
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2014
- 2014-09-19 CN CN201410484801.XA patent/CN104194968A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1651129A (en) * | 2004-11-30 | 2005-08-10 | 中国日用化学工业研究院 | Surface active agent alcohol ether glucoside and its preparation method |
| CN102631295A (en) * | 2012-03-30 | 2012-08-15 | 中国日用化学工业研究院 | Multifunctional foam liquid soap containing glucoside and derivatives of glucoside, and preparation method thereof |
| CN103271834A (en) * | 2013-06-18 | 2013-09-04 | 中国日用化学工业研究院 | Non-irritant pollution-free moisturizing pearly lustre bath foam and preparation method thereof |
| CN103301029A (en) * | 2013-06-18 | 2013-09-18 | 中国日用化学工业研究院 | Facial cleanser capable of balancing oil and moisturizing skin, and preparation method thereof |
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| 刘永强等: "《手洗餐具洗涤剂的现状与发展》", 《云南化工》, no. 4, 31 December 1999 (1999-12-31), pages 27 - 29 * |
| 张远军等: "《醇醚糖苷的制备及其复配性能研究》", 《化学研究与应用》, vol. 21, no. 8, 31 August 2009 (2009-08-31), pages 1108 - 1112 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106479727A (en) * | 2016-09-22 | 2017-03-08 | 长兴净安环保科技有限公司 | A kind of environment-friendly type imitates net Multifunctional detergent and preparation method thereof entirely |
| CN106479707A (en) * | 2016-09-22 | 2017-03-08 | 长兴净安环保科技有限公司 | A kind of oil cauldron cleaning agent of high-efficient greasy dirt removing and preparation method thereof |
| CN113637534A (en) * | 2021-08-13 | 2021-11-12 | 云南洗消佳医药科技有限公司 | Double-chain quaternary ammonium salt cleaning solution |
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