CN107523426A - A kind of stability concentrates the natural dish washing detergent of APG and preparation method - Google Patents
A kind of stability concentrates the natural dish washing detergent of APG and preparation method Download PDFInfo
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- CN107523426A CN107523426A CN201710705379.XA CN201710705379A CN107523426A CN 107523426 A CN107523426 A CN 107523426A CN 201710705379 A CN201710705379 A CN 201710705379A CN 107523426 A CN107523426 A CN 107523426A
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/1213—Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
Abstract
The present invention relates to the production field of domestic chemical products, there is provided a kind of stability concentrates the natural dish washing detergent of APG and preparation method, is made up of the raw material including following parts by weight：30 ~ 45 parts of starch, 10 ~ 15 parts of fatty alcohol, 2 ~ 10 parts of acid source, 3 ~ 30 parts of silicon particle, 2 ~ 15 parts of rose of Sharon extract solution, 50 ~ 80 parts of water, appropriate alpha amylase；By the way that Starch Fraction hydrolysis to be arrived to the polysaccharide for short chain, the more glucosides of synthesis of alkyl again, complete starch microparticles and nano-silicon micelle composition absorption carrier is not hydrolyzed present in system, APG is adsorbed to form hyperconcetration, and when in use carried APG to tableware surface adhesion friction increase clean effect；Rose of Sharon extract is further compounded, APG is maintained weakly alkaline environment, prevents its hydrolysis, and have certain inhibitory action to staphylococcus aureus, typhoid bacillus, Escherichia coli by careless glucoside therein, isovitexin, saponin.
Description
Technical field
The present invention relates to the production field of domestic chemical products, and APG day is concentrated more particularly to a kind of stability
Right dish washing detergent and preparation method.
Background technology
With our people's living standard step up and enhancing to health consciousness, China's house detergent disappear
The amount of expense is increasing, shows very big development prospect.Predicted according to research, the coming years, Chinese daily-use chemical industry articles for use will be held
Continuous steady-state growth, compound growth rate are maintained at 13.4% or so, and overall market can reach more than 2,000 hundred million yuan.Obtain employment large enterprise 300
More families.
As the development of society and the raising of the level of consumption, people are also increasing to the demand of detergent.Domestic consumption
Person gets used to the solid detergent based on washing powder and laundry soap always, and in recent years, increasing of the liquid detergent to be exceedingly fast
Long speed is changing the Distribution Pattern of detergent market.Liquid detergent compared with solid detergent, it is easy to use, dissolving it is fast
Speed, cold washing effect is good, system it is alkaline it is low, more gentle to fabric and skin, be adapted to mechanization washing process, while also have
There is formula spirit.The developing direction of detergent is at present：To green safe, multifunctional direction development；Research and design novel surface is lived
Property agent molecule structure effective catalyst；Improve the use of natural reproducible raw material；Greenization preparation and clean manufacturing；Develop low
Stimulation, hard water resistance, low-temperature resistance and the high value added product with the multiple functions such as submissive, nursing, antibacterial, color protection, pure and fresh.
Primary concern is that the price and quality of product, a measured product of matter is such as when consumer buys dish washing detergent
Fruit price is relatively low, i.e. if the ratio of performance to price of product is preferable, then is easier to win the favor of consumer.And consumer couple
The sensation when evaluation of dishwashing detergent product quality is washed based on them, it is clean level during such as product dishwashing, viscous
Degree, to several important indexs such as the mildness of hand skin, fragrance.Although viscosity index therein does not reflect product decontamination
Ability it is fine or not, but a suitable product of viscosity uses more convenient, is also less susceptible to leak during transport；Simultaneously viscosity compared with
High product, consumer also may feel that the effective ingredient of product is more, and dirt-removing power is stronger.
Dish washing detergent all contacts with people daily as kitchen daily chemical product.With the progressively enhancing of people's environmental consciousness,
The developing direction of dish washing detergent will be using environment-friendly and green health as the main direction of development.Except requiring strong detergency ability, also
Must possess harmless, sterilizing, easily degraded, requirement free from environmental pollution.
The surfactant commonly used in the surfactant meal wash agent of obvious traditional chemical synthesis has the horizontal acid of linear alkylbenzene (LAB)
Salt (LAS), alpha-alkene sulfonate (AOS), fatty alcohol polyoxyethylene ether sulfate (AES), secondary alkyl sulfonate (SAS), fat
Alcohol sulfate (FAS), AEO (AEO), alkanolamide etc. are difficult to meet to require.In recent years, green surface was lived
Property agent APG (APG) has obtained preferable development as tableware Xian Di agent.Although such product is if formula is reasonable
Decontamination is also preferable, but due to being limited by used surfactant kind, the ratio of performance to price of formula is not so good；1 makes
Used time is not gentle enough, has stimulation to hand skin, and dry sensation is also easy to produce after washing；After 2 products are thickened with thickener, viscosity with temperature
Change greatly, when temperature rise, viscosity decline it is larger；3 are limited by the preservative kind added in addition, and product is in the shelf-life
Content easy bacteria-developing, it have impact on the quality of product.But the efficiency of existing green surfactant APG (APG) is relatively low,
Unstable under sour environment, uniting often needs to be formed with traditional chemical synthetic surfactant (such as LAS, AS, AES, SAS) compatibility
Alkaline environment uses.This defect limits the application of the more glycosides in alkyl Portugal (APG).Therefore, efficient APG is developed
(APG) dish washing detergent is the development key of dish washing detergent instantly.
The content of the invention
For existing dish washing detergent using green surfactant APG (APG) efficiency is low, sour environment is easy
The defects of polysaccharide that hydrolyze, contains hand easy to stick, the present invention proposes a kind of stability concentration natural dish washing detergent of APG,
So that not hydrolyzing complete starch microparticles and nano-silicon micelle composition absorption carrier present in system, APG is adsorbed
Hyperconcetration is formed, and when in use carries APG to tableware surface adhesion friction increase clean effect.
To solve the above problems, the present invention uses following technical scheme：
A kind of stability concentrates the natural dish washing detergent of APG, it is characterised in that by the raw material for including following parts by weight
It is made：30 ~ 45 parts of starch, 10 ~ 15 parts of fatty alcohol, 2 ~ 10 parts of acid source, 3 ~ 30 parts of silicon particle, 2 ~ 15 parts of rose of Sharon extract solution, water 50 ~
80 parts, appropriate alpha-amylase；
The described stability concentration natural dish washing detergent of APG, is that Starch Fraction is hydrolyzed to the washing prepared after sugar
Agent, comprise the following steps：
（1）Xiang Shuizhong adds fatty alcohol, acid source, opens and stirs and vacuumize decompression, is heated to 105 ~ 125 DEG C, then adds and forms sediment
Powder and alpha-amylase, continue 30 ~ 90min of reaction, obtain connecting the APG of starch；
（2）To step（1）Mixed system in add silicon particle and rose of Sharon extract solution, after being well mixed, obtain stability concentration
The natural dish washing detergent of APG.
The present invention is being synthesized by the way that Starch Fraction hydrolysis to be arrived to polysaccharide or monose for short chain, then the more glucosides of synthesis of alkyl
During add nano-silicon micelle, in post synthesis the phase add rose of Sharon extract solution, it is more so as to obtain the strong dirt-removing alkyl of hyperconcetration
Glucoside natural dish washing detergent.Its significant advantage is not hydrolyze complete starch microparticles and nano-silicon micelle present in system
Absorption carrier is formed, APG is adsorbed to form hyperconcetration, and when in use carry APG to tableware table
Face adhesion friction increase clean effect；Rose of Sharon extract is further compounded, careless glucoside therein, isovitexin, saponin are more by alkyl
Glucosides maintains weakly alkaline environment, prevents its hydrolysis, and have certain suppression to staphylococcus aureus, typhoid bacillus, Escherichia coli
Make and use.
In the present invention, the proportioning of each material is an important factor for influenceing detergent performance, in order to improve the washing of detergent
Effect and stability, it is preferred that the stability concentrates the natural dish washing detergent of APG, by including following parts by weight
Raw material is made：25 ~ 32 parts of starch, 12 ~ 16 parts of fatty alcohol, 3 ~ 8 parts of acid source, 12 ~ 25 parts of silicon particle, 6 ~ 12 parts of rose of Sharon extract solution,
60 ~ 75 parts of water, alpha-amylase 0.01-0.05 parts.
In the present invention, the fatty alcohol is C8-C18 fatty alcohol.
The pH value of solution is adjusted in the present invention by acid source, the present invention does not have special requirement to it, can be this area
Strong acid or weak acid known to technical staff, for example, the acid source can be at least one in sulfuric acid, hydrochloric acid, phosphoric acid, nitric acid
Kind.
The present invention can not only adsorb APG, it is more to improve alkyl by loading APG in Silica Surface
Concentration and stability of the glucosides in system, it is preferred that the particle diameter of the silicon particle is 50 ~ 300nm.
Also include following raw material：At least one of emulsifying agent, inorganic salts, chelating agent.
The emulsifying agent is coconut acid diethanolamide, cocinic acid formicester diglycollic amide, cocinic acid monoethanol
Acid amides, lauric monoisopropanolamide, Stearic acid diethanolamine salt, stearic acid methyl ester diglycollic amide, stearic acid monoethanol acyl
At least one of amine, oleic acid diethyl amide, oleic acid formicester diglycollic amide, myristic acid single ethanol amide.
The inorganic salts be sodium sulphate, potassium sulfate, sodium chloride, potassium chloride, magnesium sulfate, magnesium chloride, in calcium chloride at least
It is a kind of.
The chelating agent is at least one of citric acid, tartaric acid.
A kind of natural dish washing detergent of stability concentration APG of the present invention and preparation method, with prior art phase
Than, its protrude the characteristics of and excellent effect be：
The present invention is added by the way that Starch Fraction hydrolysis to be arrived to the polysaccharide for short chain, then the more glucosides of synthesis of alkyl in building-up process
Nano-silicon micelle, phase addition rose of Sharon extract solution, naturally eats so as to obtain the strong dirt-removing APG of hyperconcetration in post synthesis
Has detergent.Its significant advantage is not hydrolyze complete starch microparticles and nano-silicon micelle composition absorption present in system to carry
Body, APG is adsorbed to form hyperconcetration, and when in use carried APG to tableware surface adhesion friction
Increase clean effect；Rose of Sharon extract is further compounded, careless glucoside therein, isovitexin, saponin maintain APG
Weakly alkaline environment, its hydrolysis is prevented, and have certain inhibitory action to staphylococcus aureus, typhoid bacillus, Escherichia coli.
Embodiment
Below by way of embodiment, the present invention is described in further detail, but this should not be interpreted as to the present invention
Scope be only limitted to following example.In the case where not departing from above method thought of the present invention, according to ordinary skill
The various replacements or change that knowledge and customary means are made, should be included in the scope of the present invention.
Embodiment 1
A kind of stability concentrates the natural dish washing detergent of APG, it is characterised in that by the raw material for including following parts by weight
It is made：30 parts of starch, C8 50 parts of 5 parts of 3 parts of 2 parts of 10 parts of fatty alcohol, sulfuric acid, silicon particle, rose of Sharon extract solution, water, alpha-amylase
0.03 part；
The described stability concentration natural dish washing detergent of APG, is that Starch Fraction is hydrolyzed to the washing prepared after sugar
Agent, comprise the following steps：
（1）Xiang Shuizhong adds fatty alcohol, acid source, opens and stirs and vacuumize decompression, is heated to 105 ~ 125 DEG C, then adds and forms sediment
Powder and alpha-amylase, continue to react 30min, obtain connecting the APG of starch；
（2）To step（1）Mixed system in add silicon particle and rose of Sharon extract solution, after being well mixed, obtain stability concentration
The natural dish washing detergent of APG.
Embodiment 2
A kind of stability concentrates the natural dish washing detergent of APG, it is characterised in that by the raw material for including following parts by weight
It is made：60 parts of 5 parts of 10 parts of 2 parts of 10 parts of fatty alcohol, hydrochloric acid, silicon particle, rose of Sharon extract solution, water, the alphalise starch of 45 parts of starch, C12
0.05 part of enzyme；
The described stability concentration natural dish washing detergent of APG, is that Starch Fraction is hydrolyzed to the washing prepared after sugar
Agent, comprise the following steps：
（1）Xiang Shuizhong adds fatty alcohol, acid source, opens and stirs and vacuumize decompression, is heated to 105 ~ 125 DEG C, then adds and forms sediment
Powder and alpha-amylase, continue to react 30min, obtain connecting the APG of starch；
（2）To step（1）Mixed system in add silicon particle and rose of Sharon extract solution, after being well mixed, obtain stability concentration
The natural dish washing detergent of APG.
Embodiment 3
A kind of stability concentrates the natural dish washing detergent of APG, it is characterised in that by the raw material for including following parts by weight
It is made：50 parts of 5 parts of 20 parts of 2 parts of 15 parts of fatty alcohol, nitric acid, silicon particle, rose of Sharon extract solution, water, the alphalise starch of 30 parts of starch, C10
0.01 part of enzyme；
The described stability concentration natural dish washing detergent of APG, is that Starch Fraction is hydrolyzed to the washing prepared after sugar
Agent, comprise the following steps：
（1）Xiang Shuizhong adds fatty alcohol, acid source, opens and stirs and vacuumize decompression, is heated to 105 ~ 125 DEG C, then adds and forms sediment
Powder and alpha-amylase, continue to react 45min, obtain connecting the APG of starch；
（2）To step（1）Mixed system in add silicon particle and rose of Sharon extract solution, after being well mixed, obtain stability concentration
The natural dish washing detergent of APG.
Embodiment 4
A kind of stability concentrates the natural dish washing detergent of APG, it is characterised in that by the raw material for including following parts by weight
It is made：80 parts of 15 parts of 15 parts of 2 parts of 10 parts of fatty alcohol, hydrochloric acid, silicon particle, rose of Sharon extract solution, water, the alphalise starch of 45 parts of starch, C8
0.01 part of enzyme；
The described stability concentration natural dish washing detergent of APG, is that Starch Fraction is hydrolyzed to the washing prepared after sugar
Agent, comprise the following steps：
（1）Xiang Shuizhong adds fatty alcohol, acid source, opens and stirs and vacuumize decompression, is heated to 105 ~ 125 DEG C, then adds and forms sediment
Powder and alpha-amylase, continue to react 60min, obtain connecting the APG of starch；
（2）To step（1）Mixed system in add silicon particle and rose of Sharon extract solution, after being well mixed, obtain stability concentration
The natural dish washing detergent of APG.
Embodiment 5
A kind of stability concentrates the natural dish washing detergent of APG, it is characterised in that by the raw material for including following parts by weight
It is made：80 parts of 12 parts of 30 parts of 3 parts of 15 parts of fatty alcohol, phosphoric acid, silicon particle, rose of Sharon extract solution, water, the alphalise starch of 35 parts of starch, C8
0.01 part of enzyme；
The described stability concentration natural dish washing detergent of APG, is that Starch Fraction is hydrolyzed to the washing prepared after sugar
Agent, comprise the following steps：
（1）Xiang Shuizhong adds fatty alcohol, acid source, opens and stirs and vacuumize decompression, is heated to 105 ~ 125 DEG C, then adds and forms sediment
Powder and alpha-amylase, continue to react 30min, obtain connecting the APG of starch；
（2）To step（1）Mixed system in add silicon particle and rose of Sharon extract solution, after being well mixed, obtain stability concentration
The natural dish washing detergent of APG.
Comparative example 1
A kind of stability concentrates the natural dish washing detergent of APG, it is characterised in that by the raw material for including following parts by weight
It is made：80 parts of 12 parts of 3 parts of 15 parts of fatty alcohol, phosphoric acid, rose of Sharon extract solution, the water of 35 parts of monose, C8；
The described stability concentration natural dish washing detergent of APG, comprises the following steps：
（1）Xiang Shuizhong adds fatty alcohol, acid source, opens and stirs and vacuumize decompression, is heated to 105 ~ 125 DEG C, then adds single
Sugar, continue to react 30min, obtain APG；
（2）To step（1）Mixed system in add rose of Sharon extract solution, be well mixed after, obtain stability concentration alkyl polysaccharide
The natural dish washing detergent of glycosides.
Comparative example 2
A kind of stability concentrates the natural dish washing detergent of APG, it is characterised in that by the raw material for including following parts by weight
It is made：35 parts of starch, C8 80 parts of 30 parts of 3 parts of 15 parts of fatty alcohol, phosphoric acid, silicon particle, water, 0.01 part of alpha-amylase；
The described stability concentration natural dish washing detergent of APG, is that Starch Fraction is hydrolyzed to the washing prepared after sugar
Agent, comprise the following steps：
（1）Xiang Shuizhong adds fatty alcohol, acid source, opens and stirs and vacuumize decompression, is heated to 105 ~ 125 DEG C, then adds and forms sediment
Powder and alpha-amylase, continue to react 30min, obtain connecting the APG of starch；
（2）To step（1）Mixed system in add silicon particle, after being well mixed, obtain stability concentration APG day
Right dish washing detergent.
Performance test
1st, with reference to GB 9985-2000《Manual dishwashing detergent》The assay method measure dish washing detergent of Appendix B detergency
Cleaning effect and sterilizing ability.As a result it is as shown in table 1.
2nd, antibacterial test：
Anti-microbial property test is carried out to sample using plate count.
Carried out after sample is stored 6 months with the detergent of the dish washing detergent of embodiment 1 ~ 5, comparative example 1, comparative example 1
Clean contrast test.24h will be cultivated in 37 DEG C of incubators of tableware.The physiology containing 0.3% Tween-80 to be sterilized with 20 mL
Salt solution thoroughly cleans surface and obtains bacterium solution, and bacterium solution is diluted into 10 times and 100 times, takes undiluted, 10 times of dilution, dilution respectively
100 times of mL of bacterium solution 0.2 are coated uniformly on solid medium, and 24h, 7d are cultivated in 37 DEG C of cultures respectively, calculate the antibacterial of sample
Rate, experimental result are as shown in table 1（Detergency is reference with comparative example 1）.
Table 1
| Sample | Detergency | 24h antibiotic property（%） | 7d antibiotic property（%） |
| Embodiment 1 | 4.6 | 96.25 | 93.26 |
| Embodiment 2 | 4.3 | 94.32 | 91.25 |
| Embodiment 3 | 5.1 | 91.26 | 88.78 |
| Embodiment 4 | 4.1 | 88.16 | 85.69 |
| Embodiment 5 | 5.2 | 84.12 | 82.17 |
| Comparative example 1 | 1.0 | 64.66 | 62.31 |
| Comparative example 2 | 3.5 | 42.5 | 35.6 |
Claims (6)
1. a kind of stability concentrates the natural dish washing detergent of APG, it is characterised in that by the original for including following parts by weight
Material is made：30 ~ 45 parts of starch, 10 ~ 15 parts of fatty alcohol, 2 ~ 10 parts of acid source, 3 ~ 30 parts of silicon particle, 2 ~ 15 parts of rose of Sharon extract solution, water
50 ~ 80 parts, appropriate alpha-amylase；
The described stability concentration natural dish washing detergent of APG, is that Starch Fraction is hydrolyzed to the washing prepared after sugar
Agent, comprise the following steps：
（1）Xiang Shuizhong adds fatty alcohol, acid source, opens and stirs and vacuumize decompression, is heated to 105 ~ 125 DEG C, then adds and forms sediment
Powder and alpha-amylase, continue 30 ~ 90min of reaction, obtain connecting the APG of starch；
（2）To step（1）Mixed system in add silicon particle and rose of Sharon extract solution, after being well mixed, obtain stability concentration
The natural dish washing detergent of APG.
2. stability according to claim 1 concentrates the natural dish washing detergent of APG, it is characterised in that by including
The raw material of following parts by weight is made：25 ~ 32 parts of starch, 12 ~ 16 parts of fatty alcohol, 3 ~ 8 parts of acid source, 12 ~ 25 parts of silicon particle, the rose of Sharon carry
Take 6 ~ 12 parts of liquid, 60 ~ 75 parts of water, alpha-amylase 0.01-0.05 parts.
3. stability according to claim 1 or 2 concentrates the natural dish washing detergent of APG, it is characterised in that institute
State the fatty alcohol that fatty alcohol is C8-18.
4. stability according to claim 1 or 2 concentrates the natural dish washing detergent of APG, it is characterised in that institute
Acid source is stated as at least one of sulfuric acid, hydrochloric acid, phosphoric acid, nitric acid.
5. stability according to claim 1 or 2 concentrates the natural dish washing detergent of APG, it is characterised in that institute
The particle diameter for stating silicon particle is 50 ~ 300nm.
6. stability according to claim 1 or 2 concentrates the natural dish washing detergent of APG, it is characterised in that also
Including following raw material：At least one of emulsifying agent, inorganic salts, chelating agent.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710705379.XA CN107523426A (en) | 2017-08-17 | 2017-08-17 | A kind of stability concentrates the natural dish washing detergent of APG and preparation method |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111939680A (en) * | 2020-08-14 | 2020-11-17 | 新乡市双诚环保设备有限公司 | Oil fume absorbent for construction machinery and preparation process thereof |
| CN113265304A (en) * | 2021-04-30 | 2021-08-17 | 湖北美拓日化科技有限公司 | Liquid detergent and preparation method thereof |
| CN115368978A (en) * | 2022-06-30 | 2022-11-22 | 纳爱斯浙江科技有限公司 | Concentrated detergent with high-power dilution and thickening performance and preparation method thereof |
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| JP2011225548A (en) * | 2010-03-30 | 2011-11-10 | Agc Si-Tech Co Ltd | Scrubbing agent for detergent composition and detergent composition |
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| CN107022430A (en) * | 2017-04-21 | 2017-08-08 | 程海权 | A kind of natural multiple-effect washes the dishes powder |
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| US20040248760A1 (en) * | 2001-03-03 | 2004-12-09 | Woodhead Peter Philip | Biocidal cleaning composition |
| CN101168761A (en) * | 2007-10-17 | 2008-04-30 | 山东轻工业学院 | Method for synthesizing alkyl polyglycoside catalyzed by amylase |
| JP2011225548A (en) * | 2010-03-30 | 2011-11-10 | Agc Si-Tech Co Ltd | Scrubbing agent for detergent composition and detergent composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111939680A (en) * | 2020-08-14 | 2020-11-17 | 新乡市双诚环保设备有限公司 | Oil fume absorbent for construction machinery and preparation process thereof |
| CN113265304A (en) * | 2021-04-30 | 2021-08-17 | 湖北美拓日化科技有限公司 | Liquid detergent and preparation method thereof |
| CN115368978A (en) * | 2022-06-30 | 2022-11-22 | 纳爱斯浙江科技有限公司 | Concentrated detergent with high-power dilution and thickening performance and preparation method thereof |
| CN115368978B (en) * | 2022-06-30 | 2023-09-12 | 纳爱斯浙江科技有限公司 | Concentrated detergent with high-power dilution and thickening performance and preparation method thereof |
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Application publication date: 20171229 |
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