CN102293719B - Sanitizer - Google Patents
Sanitizer Download PDFInfo
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- CN102293719B CN102293719B CN201110260257A CN201110260257A CN102293719B CN 102293719 B CN102293719 B CN 102293719B CN 201110260257 A CN201110260257 A CN 201110260257A CN 201110260257 A CN201110260257 A CN 201110260257A CN 102293719 B CN102293719 B CN 102293719B
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- CN
- China
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- percent
- essence
- tea saponin
- citric acid
- deionized water
- Prior art date
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Abstract
The invention relates to a sanitizer and belongs to the field of daily use chemical detergents. The sanitizer is particularly prepared by mixing the following raw materials in percentage by weight: 5 to 20 percent of tea saponin crystal, 6 to 15 percent of fatty alcohol polyoxyethylene ether sodium sulfate (AES), 1 to 5 percent of 6501, 0.1 to 0.3 percent of citric acid, 1 to 6 percent of cellulose acetate butyrate-35 (CAB-35), 1 to 3 percent of alpha-olefin sulfonate (AOS), 0.1 to 0.4 percent of ethylene diamine tetraacetic acid (EDTA-2Na), 0.1 to 0.3 percent of Kathon, 0.3 to 0.5 percent of essence, 1 to 3 percent of sodium chloride and 60 to 70 percent of deionized water. The sanitizer can be used for washing hands to remove stain, can sterilize and prevent hand diseases, makes skin soft and comfortable, has faint scent, and does not pollute the environment.
Description
Technical field
The invention belongs to the daily-use chemical industry detergent applications, be specifically related to a kind of handwashing liquid.
Background technology
Current, known handwashing liquid or liquid detergent contain detergent alkylate semi-annular jade pendant acids band benzene ring compound.In washing process, with contact skin with remain on the skin, be unsafe to application on human skin, the person of chapping is particularly arranged on hand, these chemical substances are infiltrated human body through breach on hand, play bad effect.Benzene ring compound is not subject to microbial decomposition in environment, washing, rinsing liquid are discharged to sewer and also can cause pollution to a certain degree to environment.
Summary of the invention
Based on the problems referred to above, technical problem to be solved by this invention is to provide a kind of handwashing liquid, uses the present invention in the decontamination of washing one's hands, can antibacterial, and control hands disease makes that skin is soft, comfortable, abnormal smells from the patient delicate fragrance, and environment is not polluted.
Technical scheme of the present invention can reach through following measure:
A kind of handwashing liquid, process by following raw materials by weight percent component mediation: tea saponin crystal 5～20, AES 6～15; 6,501 1～5, citric acid 0.1～0.3, CAB-35 1～6; AOS 1～3, and EDTA-2Na 0.1～0.4, and triumphant loose 0.1～0.3; Essence 0.3～0.5, NaCl 1～3, deionized water 60～70; Its manufacturing process is: with deionized water and NaCl modulation buffer, buffer adds tea saponin crystal, stirring and dissolving in the time of 80～90 ℃ earlier; Add AES, 6501, citric acid, CAB-35, AOS, EDTA-2Na, Kai Song and essence more successively, restir becomes latex solution; Be cooled to room temperature and get detergent; Through packing, after the check, the finished product warehouse-in.
Tea saponin crystal of the present invention is a kind of pure natural glucoside composition that from the seed of plant of theaceae, extracts, and is a kind of of Saponin.It is by aglucon (C
30H
50O
6), a kind of pentacyclic triterpene Saponin of constituting of sugared body and organic acid basic structure, molecular formula is C
57H
90O
26, molecular weight 1191.28.
It is instant that the tea saponin crystal is met water, and the solution of tea saponin crystal allotment is a kind of natural nonionic surfactant, has emulsifying efficiently, disperse, and foaming, surface activitys such as moistening, the pharmacological testing proof has antiinflammatory, analgesic activity.Be widely used on the production industries such as wool spinning, knitting, daily-use chemical industry, medicine, can be used as emulsifying agent, foaming agent, also can make detergent; But the present invention is a purpose to clean decontamination mainly, and it is to diesel oil, machine oil; Flue dust mixes the strong detergency of heavy dirt, and is non-stimulated to skin, do not have irritated reaction.China Hunan, Sichuan-band peasant works as detergent with tea cake for a long time and uses, and can eliminate some inflammation on hand.
Of the present invention 6501 is cocoanut fatty acid diethanolamides, belongs to non-ionic surface active agent, does not have cloud point.Character be faint yellow to amber thick liquid, soluble in water, have functions such as good foaming, steady bubble, infiltration decontamination, anti-hard water.Be to utilize it to have tangible dirt-removing power and the surface tension ability that reduces water in the present invention, can increase the osmosis of this prescription, it is superior to both independent results of use with after the crystalline aqueous solution of tea saponin cooperates to the dirty dirt-removing power of oiliness weight.
AES of the present invention, its chemical name is polyoxyethylenated alcohol sodium sulfate, molecular formula: RO (CH
2CH
2O) n-SO
3Na; Performance: soluble in water, have good decontamination, emulsifying, foam performance and anti-performance of hard water, gentle washing character can injured skin.Mainly being used in meal in household chemicals field and washing, is exactly common liquid detergent.MSDS (material safety appraisal report) according to AES shows that AES is nontoxic product.Be purpose mainly in the present invention with emulsifying, foaming.
Citric acid chemical name of the present invention: 3-hydroxyl-3-carboxyl 1,3-propanedicarboxylic acid; Molecular formula: C6H8O7 molecular weight: 192.14; Belong to a kind of of fruit acid, the faint scent of Fructus Citri Limoniae is arranged.Have good kill bacteria spore and the cuticular function of softening skin, evidence of the present invention, citric acid passes through emulsion process; Be dispersed in the handwashing liquid; Can get into human body through skin absorbs and can accelerate the cutin of skin and upgrade, the renewal of cutin help skin in melanic peeling off, the receipts of pore are thin; Make that skin is soft, comfortable, abnormal smells from the patient delicate fragrance, the colour of skin is pure and fresh, pure.
AOS of the present invention, another name alpha-olefin sodium sulfonate, AOS has good surface activity, and in the finite concentration scope, AOS can be with the surface tension of water from 72mN.m
-1Reduce to 30～40mN.m
-1About.The wetting power of AOS and foaminess are good, and resistance to hard water is strong; Its biodegradation rate and ultimate biodegradation degree are high, in natural environment, can degrade fully in 5-7 days and disappear, and do not pollute the environment.AOS has good clean effect to sebum dirt and oiliness and powdery dirt.In detergent of the present invention as active component.
CAB-35 chemical name of the present invention: cocamidopropyl propyl amide decil lactone; Chemical structural formula: RCONH (CH2) 3N (CH3) 2CH2COO; Molecular weight: 342.52, nontoxic, zest is little, and performance is gentle, and foam is fine and smooth, and is abundant, stable, has adjusting viscosity, and the flexibility that strengthens skin has bactericidal action.It is a kind of zwitterionic surfactant; Composite with AOS of the present invention, under pH5.5～6.5 conditions, can improve material body viscosity, thickening effect is obvious.
EDTA-2Na of the present invention, chemical name: disodiumedetate, English name: EDTA Disodium Salt is tasteless odorless or little salty white or milky crystallization or particulate powder.Water-soluble, be insoluble to ethanol, ether.Purposes: make heavy metal detoxification medicine, chelating agent, antioxidant synergist, stabilizing agent and softening agent etc.Conduct in the present invention
Chelating agentComponent.
Triumphant pine of the present invention, its active part is the isothiazolone compounds, can effectively suppress and go out except that mushroom and various microorganism.Be widely used in the products such as high-grade nutrient cosmetics such as shampoo of hair washing and conditioning, body lotion and various skin moistening, protective skin cream, cream, breast, lip pomade and handwashing liquid, dish detergent, tableware cleaning essence, hair dye, fur clothing glazing agent, softening agent, glue, external-applied ointment, pesticide.Play the bactericidal effect in the present invention.NaCl
Essence of the present invention plays the flavouring effect.
The main effect of NaCl of the present invention is the ionic strength of regulating above-mentioned latex solution.
1, the handwashing liquid of the present invention detergency test result that washes one's hands: by age divide teenager, the middle age, old three groups, every group of each 10 people of men and women's property, wherein 16 people have inflammation such as hand desquamation eczema.Select representative dirt to smear the palm of the hand, the back of the hand, the pollution time is that to receive half an hour and 1 hour the examination time continuously be 32 days; The average 2.5 times/people of test number (TN). day, the highest test number (TN) 104 times, minimum 48 times; Always tried detergency test result such as following table 1 per capita 60 times.
Table 1
Can know that by last table the present invention has very strong detergency to multiple dirt, skin is not only had allergy, stimulate phenomenon, on the contrary control hands disease had certain effect.
2, the present invention's decontamination and deodorant effect of washing one's hands: when human body is washed one's hands detergency test, observe when by kerosene smoke, paint, printing ink; Useless machine diesel oil is behind the severe contaminations such as bean curd with odor juice, with the decontamination of these article of 0.4-1.5 gram; The whole eluting of dirt; Can't smell the foreign odor of dirt, stay the delicate fragrance of detergent itself on hand, this is used the back by people surplus 600 and confirms.
3, the present invention's bactericidal effect in different time is seen table 2.
Table 2
4, in the process of washing one's hands, to the killing bacteria effect,, wash one's hands with product of the present invention to 100 people experiment, everyone 5 times, bacteriology checking result before and after washing one's hands, before washing one's hands: have bacterial growth rate to account for 64%, no bacterial growth rate accounts for 36%; After washing one's hands, whole asepsis growths.
5, this product toxicology test and other performance test: divide the toxic classification standard judgement of material by internationally recognized animal acute poisoning test LD50 value and the invention belongs to nontoxic level product.Prove that through holding toxicity test this product does not have overt toxicity.Photaesthesia is reacted also no significant difference, through the rabbit eye mask being tested equal vacuum response characteristic.The stability and the fire resistance test of product prove that this product has stability preferably.In addition, this product also has better frost resistance ,-15 ℃ deposit 10 days after, recover flowability after, clean effect is still constant.
Comprehensive the above, the present invention compared with prior art has the recipe design advanced person, can prevent and treat chapped skin, to hand desquamation, eczema inflammation on hand also has prevention and therapeutical effect, plays-the dual-purpose effect of thing.The tea saponin natural surfactant that main body prescription of the present invention uses is to have replaced in the prior art to be the composite component of the decontamination of main body with synthetic with part, and the present invention is nontoxic safe in utilization, and dirt-removing power is strong, can sterilize, and antibacterial, deodorizing has moist function to skin.
The specific embodiment
The following stated embodiment has specified the present invention.
Embodiment 1
Produce 100kg old people and use handwashing liquid; Material component mediation by following weight is processed: tea saponin crystal 5 kg, AES 15kg, 6501 1kg, citric acid 0.3 kg; CAB-35 2 kg, AOS 3 kg, EDTA-2Na 0.1 kg, triumphant loose 0.2 kg; Essence 0.4 kg, NaCl 3 kg, deionized water 70 kg; Its manufacturing process is: with deionized water and NaCl modulation buffer, buffer adds tea saponin crystal, stirring and dissolving in the time of 80～90 ℃ earlier; Add AES, 6501, citric acid, CAB-35, AOS, EDTA-2Na, Kai Song and essence more successively, restir becomes latex solution; Be cooled to room temperature and get detergent; Through packing, after the check, the finished product warehouse-in.
Embodiment 2
Produce the 100kg middle age and use handwashing liquid; Material component mediation by following weight is processed: tea saponin crystal 2 0kg, AES 6kg, 6501 5kg, citric acid 0.2 kg; CAB-35 1 kg, AOS 1 kg, EDTA-2Na 0.4 kg, triumphant loose 0.1 kg; Essence 0.3 kg, NaCl 1 kg, deionized water 65kg; Its manufacturing process is: with deionized water and NaCl modulation buffer, buffer adds tea saponin crystal, stirring and dissolving in the time of 80～90 ℃ earlier; Add AES, 6501, citric acid, CAB-35, AOS, EDTA-2Na, Kai Song and essence more successively, restir becomes latex solution; Be cooled to room temperature and get detergent; Through packing, after the check, the finished product warehouse-in.
Embodiment 3
Produce the 100kg teenager and use handwashing liquid; Material component mediation by following weight is processed: tea saponin crystal 8kg, AES 10kg, 6501 3kg, citric acid 0.2 kg; CAB-35 4kg, AOS 2kg, EDTA-2Na 0.2 kg, triumphant loose 0.3 kg; Essence 0.3 kg, NaCl 2 kg, deionized water 70kg; Its manufacturing process is: with deionized water and NaCl modulation buffer, buffer adds tea saponin crystal, stirring and dissolving in the time of 80～90 ℃ earlier; Add AES, 6501, citric acid, CAB-35, AOS, EDTA-2Na, Kai Song and essence more successively, restir becomes latex solution; Be cooled to room temperature and get detergent; Through packing, after the check, the finished product warehouse-in.
Embodiment 4
Produce the old and young general handwashing liquid of 100kg; Material component mediation by following weight is processed: tea saponin crystal 17kg, AES 8kg, 6501 4kg, citric acid 0.1 kg; CAB-35 6kg, AOS 2kg, EDTA-2Na 0.2 kg, triumphant loose 0.2 kg; Essence 0.5 kg, NaCl 2 kg, deionized water 60kg; Its manufacturing process is: with deionized water and NaCl modulation buffer, buffer adds tea saponin crystal, stirring and dissolving in the time of 80～90 ℃ earlier; Add AES, 6501, citric acid, CAB-35, AOS, EDTA-2Na, Kai Song and essence more successively, restir becomes latex solution; Be cooled to room temperature and get detergent; Through packing, after the check, the finished product warehouse-in.
Claims (1)
1. a handwashing liquid is characterized in that, is in harmonious proportion by following raw materials by weight percent component and processes: tea saponin crystal 5 %～20%, polyoxyethylenated alcohol sodium sulfate 6%～15%; Cocoanut fatty acid diethanolamide 1%～5%, citric acid 0.1%～0.3%, cocamidopropyl propyl amide decil lactone 1%～6%; Alpha-olefin sodium sulfonate 1%～3%, disodiumedetate 0.1%～0.4%, triumphant loose 0.1%～0.3%; Essence 0.3%～0.5%, NaCl 1%～3%, deionized water 60%～70%; Its manufacturing process is: with deionized water and NaCl modulation buffer, buffer adds tea saponin crystal, stirring and dissolving in the time of 80～90 ℃ earlier; Add polyoxyethylenated alcohol sodium sulfate, cocoanut fatty acid diethanolamide, citric acid, cocamidopropyl propyl amide decil lactone, alpha-olefin sodium sulfonate, disodiumedetate, Kai Song and essence more successively, restir becomes latex solution; Be cooled to room temperature and get detergent; Through packing, after the check, the finished product warehouse-in.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110260257A CN102293719B (en) | 2011-09-05 | 2011-09-05 | Sanitizer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110260257A CN102293719B (en) | 2011-09-05 | 2011-09-05 | Sanitizer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102293719A CN102293719A (en) | 2011-12-28 |
| CN102293719B true CN102293719B (en) | 2012-09-19 |
Family
ID=45354562
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110260257A Expired - Fee Related CN102293719B (en) | 2011-09-05 | 2011-09-05 | Sanitizer |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102293719B (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102766542A (en) * | 2012-07-09 | 2012-11-07 | 陈文志 | Detergent containing tea saponin |
| CN104644458A (en) * | 2014-06-10 | 2015-05-27 | 莫治玲 | Hand sanitizer |
| CN104083294A (en) * | 2014-07-25 | 2014-10-08 | 广西和桂集团有限公司 | Anti-bacterial hand-washing solution |
| CN105287249A (en) * | 2015-11-04 | 2016-02-03 | 成都百味坊贸易有限公司 | Hand sanitizer and preparation method thereof |
| CN109125171A (en) * | 2018-09-18 | 2019-01-04 | 广西壮族自治区农业科学院农产品加工研究所 | A kind of Tea Saponin hand cleanser and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101390816A (en) * | 2008-11-06 | 2009-03-25 | 郴州邦尔泰苏仙油脂有限公司 | Formulation of tea saponin shampoo and production technique thereof |
-
2011
- 2011-09-05 CN CN201110260257A patent/CN102293719B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101390816A (en) * | 2008-11-06 | 2009-03-25 | 郴州邦尔泰苏仙油脂有限公司 | Formulation of tea saponin shampoo and production technique thereof |
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|---|---|
| CN102293719A (en) | 2011-12-28 |
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Granted publication date: 20120919 Termination date: 20160905 |