CN101390816A - Formulation of tea saponin shampoo and production technique thereof - Google Patents
Formulation of tea saponin shampoo and production technique thereof Download PDFInfo
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- CN101390816A CN101390816A CNA2008101435058A CN200810143505A CN101390816A CN 101390816 A CN101390816 A CN 101390816A CN A2008101435058 A CNA2008101435058 A CN A2008101435058A CN 200810143505 A CN200810143505 A CN 200810143505A CN 101390816 A CN101390816 A CN 101390816A
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Abstract
The invention relates to a formulation and production process of tea saponin shampoo made of pure natural ecological compositions as active additive. Refined tea saponin, lauryl alcohol polyoxyethylene alkyl ether sodium sulfate, fatty acid alkanolamide, dodecyl dimethyl betain, poly cellulose quaternary ammonium salt, glycol monostearate, kayhon-GG, essence and deionized water are mixed in an emulsifying tank, processed with ultrasonic processing and adjusted on PH value and emulsion viscosity, so as to obtain the shampoo. The formulation and production process of tea saponin shampoo have the advantages of high comprehensive utilization rate, low production cost, green ecological and environmental protection, having the effects of hair washing, hair care, sterilization, relieving itching and anti-dandruff, and having no stimulation effect on human skin, ensuring the hair to have luster and elasticity after frequent use.
Description
Technical field
The present invention relates to a kind of shampoo in the cosmetic field, being specifically related to a kind of is the prescription and the production technology of the tea saponin shampoo of active additive making with the pure natural ecological composition.
Background technology
Liu Tong hair washing product brand is various in the market, and it is bigger that its class also differs, and some low grade products majorities all are to be made up of the antibacterial of the surfactant of various chemosynthesis and chemosynthesis, pearling agent, essence etc.If select surfactant improper, that use is excessive for use, can cause harmful substance to remain in scalp to the excessive defat of scalp, and then cause that the scalp root of hair expands, produce the zest pruritus, the repiece scurf, thus cause alopecia, alopecia and hair quality damage.
In recent years, the psychology that people pursue green cosmetics, back to nature strengthens day by day, and the cosmetic product of therefore seeking natural product with no side effects and be active additive and cosmetic material becomes fine chemicals industry one big focus.On February 27th, 2008, it contained tea saponin just to disclose " anti-dandruff shampoo of common camellia seed " (publication number CN 101129310A) of Guangdong New Earth Bio-Science ﹠ Technology Co., Ltd in the Chinese invention patent application documents; Polyoxyethylenated alcohol sodium sulfate; Ammonium lauryl sulfate; 16 carbon/18 carbon fatty alcohols; Guar gum; Polyquaternary ammonium salt-10; Fatty acid alkanol amides; Cocamidopropyl betaine; Pearl Concentrate; Triumphant pine; Essence; GMT; Totally 13 kinds of compositions of TAB-2 forms with the deionized water allotment.Though the surfactant that this prescription uses is a pure natural ecological composition tea saponin, but for thickening, that is added contains the conditioner GMT that is made by the emulsified body of high viscosity dimethyl siloxane, silicone grease, cause shampoo emulsion suspension stability variation, so that have to use emulsion suspension stabilizer TAB-2.Cause complex process, the properties of product variation.
Summary of the invention
Technical problem to be solved by this invention overcomes the deficiencies in the prior art exactly, a kind of prescription and production technology of tea saponin shampoo are provided, the present invention produces the tea cake behind natural Camellia expressed oil and extracts tea saponin, replace the chemosynthesis emulsion adjuvant with the emulsifying of ultrasound wave physical external force, has the comprehensive utilization ratio height, low production cost, the Product Green ecological, environmental protective that is obtained has effect that washing hair care sterilization, antipruritic, anti-dandruff; Human body skin is had no stimulation, often use hair pitch-black glossy, high resilience.
Technical scheme of the present invention is:
A kind of prescription of tea saponin shampoo, the percetage by weight ratio that contains refined theasapogenin is 9～20%; Deionized water 50～60% and surplus auxiliary agent; It is characterized in that: the percetage by weight ratio of described surplus auxiliary agent is: polyoxyethylene lauryl ether sodium sulfate 7～16%; Fatty acid alkanol amides 2～7%; Dodecyldimethylammonium hydroxide inner salt 2～7%; Poly-cellulose quaternary ammonium salt 1～3%; Ethylene glycol monostearate 1～3%; Citric acid 1～3%; Sal 1～3%; Triumphant pine-GG0.01～1%; Essence 0.19～1%.
The present invention carries out successively according to following production craft step: (1) extracts the tea saponin concentrated solution earlier from the tea oilseedsand cake after low-temperature cold pressing removes oils and fats, with the concentrated solution spraying drying powder-forming, promptly get refined theasapogenin; (2) the percent ratio is got 50～60 parts of deionized waters adding emulsion tanks by weight, is warmed to 80～85 ℃; (3) with 9～20 parts of refined theasapogenins, 7～16 parts of polyoxyethylene lauryl ether sodium sulfate, 2～7 parts of fatty acid alkanol amides, 2～7 parts of dodecyldimethylammonium hydroxide inner salts, 1～3 part of poly-cellulose quaternary ammonium salt adds emulsion tank together, mixes and stirs 15～20 minutes; Adjust temperature constant then at 80 ℃, in emulsion tank, the luffing vibrating arm in the ultrasonic instrument is immersed in the mixed emulsion, the control frequency of ultrasonic is 30～40KHz, mixed emulsion is carried out ultrasonic Treatment, ultrasonic treatment time is 5～40 minutes, the foam for the treatment of the emulsion surface all nebulizes, and emulsifying is finished; (4) emulsion with (3) step gained is cooled to 30 ℃, adds 1～3 part of ethylene glycol monostearate, 0.01～1 part of triumphant pine-GG, and 0.19～1 part of essence slowly stirs homogenizing 2～5 minutes; After continuing to be cooled to 25 ℃, adding 1～3 part of citric acid, is 6.5～6.9 with pH value; Add 1～3 portion of Sal again and transfer emulsion viscosity to 0.3～0.5Pa.s; Emulsion goes out jar, leaves standstill froth breaking naturally and promptly gets shampoo in 12 hours.
The above-mentioned triumphant pine-GG chemical name of the present invention is dimethyl four isothiazoline triketones.
The effect that the present invention adds poly-cellulose quaternary ammonium salt is to strengthen hair soft and antistatic effect.
Compared with prior art, the present invention has following beneficial effect: the tea saponin raw material that adopts of the present invention is carried the tea oilseedsand cake that the oil back is produced from natural Camellia low-temperature cold pressing, be the by-product that our company produces the Oleum Camelliae operation, therefrom extract tea saponin, improved the comprehensive utilization of Camellia; Tea saponin belongs to the pentacyclic triterpenoid saponin compounds, is a kind of nonionic surfactant, has stronger foaming, emulsifying, dispersion, humidification, and the influence that changed by water hardness.Particularly the present invention uses in the tea oilseedsand cake after low-temperature cold pressing removes oils and fats and extracts tea saponin, also contain active ingredients such as tocopherol, Squalene, sterol in the tea saponin, have fragrance, antiinflammatory, sterilization, antipruritic, analgesia, physiologically active such as anticancer, the various skin pruritus there is inhibitory action, no side effects.Tea saponin is used for articles for washing, and foam is many, lasting, strong detergency, has hair washing, hair care dual-use function, uses back hair gloss, feel and combing etc. good, and non-stimulated and irritated to skin.The present invention does not use conditioner GMT, mixed emulsion is only carried out ultrasonic Treatment, resulting good emulsion stability, properties of product are superior, both reduced the use amount of chemosynthesis medicament, satisfied people and pursued green cosmetics, return psychological need natural, ecological natural, production cost also significantly reduces simultaneously.After testing, tea saponin shampoo working substance 25 of the present invention, heat-resisting, cold-resistant conformance with standard, pH value 6.5～6.9, foam (40 ℃) 140 meets national QB/T1974-2004 standard.
The specific embodiment
Below in conjunction with embodiment, the invention will be further described:
Embodiment 1
A kind of prescription of tea saponin shampoo, the percetage by weight ratio that contains refined theasapogenin is 17%; Deionized water 55%; Polyoxyethylene lauryl ether sodium sulfate 7%; Fatty acid alkanol amides 7%; Dodecyldimethylammonium hydroxide inner salt 5%; Poly-cellulose quaternary ammonium salt 2%; Ethylene glycol monostearate 2.1%; Citric acid 1%; Sal 3%; Triumphant pine-GG0.05%; Essence 0.85%.
Present embodiment carries out successively according to following production craft step: (1) extracts the tea saponin concentrated solution earlier from the tea oilseedsand cake after low-temperature cold pressing removes oils and fats, with the concentrated solution spraying drying powder-forming, promptly get refined theasapogenin; (2) the percent ratio is removed ionized water adding emulsion tank by weight, is warmed to 80～85 ℃; (3) the above-mentioned again ratio of percent is by weight got refined theasapogenin, polyoxyethylene lauryl ether sodium sulfate, and fatty acid alkanol amides, dodecyldimethylammonium hydroxide inner salt, poly-cellulose quaternary ammonium salt adds emulsion tank together, mixes and stirs 15～20 minutes; Adjust temperature constant then at 80 ℃, in emulsion tank, the luffing vibrating arm in the ultrasonic instrument is immersed in the mixed emulsion, the control frequency of ultrasonic is 30～40KHz, mixed emulsion is carried out ultrasonic Treatment, ultrasonic treatment time is 5～40 minutes, the foam for the treatment of the emulsion surface all nebulizes, and emulsifying is finished; (4) emulsion with (3) step gained is cooled to 30 ℃, adds the ethylene glycol monostearate of above-mentioned percetage by weight than quantity, triumphant pine-GG, and essence slowly stirs homogenizing 2～5 minutes; After continuing to be cooled to 25 ℃, adding citric acid, is 6.5～6.9 with pH value; Add Sal again and transfer emulsion viscosity to 0.3～0.5Pa.s; Emulsion goes out jar, leaves standstill froth breaking naturally and promptly gets shampoo in 12 hours.
Embodiment 2
A kind of prescription of tea saponin shampoo, the percetage by weight ratio that contains refined theasapogenin is 20%; Deionized water 50%; Polyoxyethylene lauryl ether sodium sulfate 16%; Fatty acid alkanol amides 1.8%; Dodecyldimethylammonium hydroxide inner salt 7%; Poly-cellulose quaternary ammonium salt 1%; Ethylene glycol monostearate 1%; Citric acid 2%; Sal 1%; Triumphant pine-GG0.01%; Essence 0.19%.
The present embodiment production craft step is with embodiment 1.
Embodiment 3
A kind of prescription of tea saponin shampoo, the percetage by weight ratio that contains refined theasapogenin is 9%; Deionized water 60%; Polyoxyethylene lauryl ether sodium sulfate 14%; Fatty acid alkanol amides 2%; Dodecyldimethylammonium hydroxide inner salt 2%; Poly-cellulose quaternary ammonium salt 3%; Ethylene glycol monostearate 3%; Citric acid 3%; Sal 2%; Triumphant pine-GG1%; Essence 1%.
The present embodiment production craft step is with embodiment 1.
Claims (2)
1, a kind of prescription of tea saponin shampoo, the percetage by weight ratio that contains refined theasapogenin is 9～20%; Deionized water 50～60% and surplus auxiliary agent; It is characterized in that: the percetage by weight ratio of described surplus auxiliary agent is: polyoxyethylene lauryl ether sodium sulfate 7～16%; Fatty acid alkanol amides 2～7%; Dodecyldimethylammonium hydroxide inner salt 2～7%; Poly-cellulose quaternary ammonium salt 1～3%; Ethylene glycol monostearate 1～3%; Citric acid 1～3%; Sal 1～3%; Triumphant pine-GG0.01～1%; Essence 0.19～1%.
2, a kind of production technology of tea saponin shampoo is characterized in that processing step carries out successively according to following:
(1) from the tea oilseedsand cake after low-temperature cold pressing removes oils and fats, extracts the tea saponin concentrated solution earlier,, promptly get refined theasapogenin the concentrated solution spraying drying powder-forming;
(2) the percent ratio is got 50～60 parts of deionized waters adding emulsion tanks by weight, is warmed to 80～85 ℃;
(3) with 9～20 parts of refined theasapogenins, 7～16 parts of polyoxyethylene lauryl ether sodium sulfate, 2～7 parts of fatty acid alkanol amides, 2～7 parts of dodecyldimethylammonium hydroxide inner salts, 1～3 part of poly-cellulose quaternary ammonium salt adds emulsion tank together, mixes and stirs 15～20 minutes; Adjust temperature constant then at 80 ℃, in emulsion tank, the luffing vibrating arm in the ultrasonic instrument is immersed in the mixed emulsion, the control frequency of ultrasonic is 30～40KHz, mixed emulsion is carried out ultrasonic Treatment, ultrasonic treatment time is 5～40 minutes, the foam for the treatment of the emulsion surface all nebulizes, and emulsifying is finished;
(4) emulsion with (3) step gained is cooled to 30 ℃, adds 1～3 part of ethylene glycol monostearate, 0.01～1 part of triumphant pine-GG, and 0.19～1 part of essence slowly stirs homogenizing 2～5 minutes; After continuing to be cooled to 25 ℃, adding 1～3 part of citric acid, is 6.5～6.9 with pH value; Add 1～3 portion of Sal again and transfer emulsion viscosity to 0.3～0.5Pa.s; Emulsion goes out jar, leaves standstill froth breaking naturally and promptly gets shampoo in 12 hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CNB2008101435058A CN100569214C (en) | 2008-11-06 | 2008-11-06 | Tea saponin shampoo and production technology |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2008101435058A CN100569214C (en) | 2008-11-06 | 2008-11-06 | Tea saponin shampoo and production technology |
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| CN101390816A true CN101390816A (en) | 2009-03-25 |
| CN100569214C CN100569214C (en) | 2009-12-16 |
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| CNB2008101435058A Expired - Fee Related CN100569214C (en) | 2008-11-06 | 2008-11-06 | Tea saponin shampoo and production technology |
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| CN102293719A (en) * | 2011-09-05 | 2011-12-28 | 郴州邦尔泰苏仙油脂有限公司 | Sanitizer |
| CN102319190A (en) * | 2011-01-18 | 2012-01-18 | 朱绍华 | Pure plant hair dyeing method for blackening white hairs and shampoos used before dyeing |
| CN102626377A (en) * | 2011-12-14 | 2012-08-08 | 李海祥 | Tea bran hair washing powder |
| CN102836088A (en) * | 2012-09-12 | 2012-12-26 | 杭州小青生物科技有限公司 | Cleansing cream containing tea saponin and preparation method thereof |
| CN103006504A (en) * | 2012-11-27 | 2013-04-03 | 北京凝翠轩生物科技有限公司 | Multi-effect natural plant hair shampoo |
| CN103385831A (en) * | 2013-07-19 | 2013-11-13 | 泉州市新益日用化妆品有限公司 | Novel oil tea shampoo and preparation method thereof |
| CN103462851A (en) * | 2013-09-26 | 2013-12-25 | 陈理敬 | Head wind removing shampoo formula |
| CN103520036A (en) * | 2013-10-12 | 2014-01-22 | 湖南金浩茶油股份有限公司 | Hair-loss-preventing shampoo |
| CN103550072A (en) * | 2013-11-13 | 2014-02-05 | 长沙昊瑞生物科技有限公司 | Method for utilizing waste water generated in the technology for extracting tea seed oil through aqueous phase, and formula of liquid shampoo |
| CN104013559A (en) * | 2014-06-28 | 2014-09-03 | 管天球 | Anti-scurf shampoo containing tea saponin |
| CN105616292A (en) * | 2016-02-03 | 2016-06-01 | 九沪（上海）生物科技有限公司 | Tea saponin shampoo containing traditional Chinese medicine extracts and preparation method thereof |
| CN105616204A (en) * | 2016-01-25 | 2016-06-01 | 柳州三农科技有限公司 | Antidandruff and gentle shampoo |
| CN105902450A (en) * | 2016-06-20 | 2016-08-31 | 合肥丰瑞隆生物科技有限公司 | Itching relieving shampoo and preparation method thereof |
| CN105919894A (en) * | 2016-06-20 | 2016-09-07 | 合肥丰瑞隆生物科技有限公司 | Biological environment-friendly liquid shampoo and preparing method thereof |
| CN105919919A (en) * | 2016-06-20 | 2016-09-07 | 合肥丰瑞隆生物科技有限公司 | Hair growing and dandruff removing liquid shampoo and preparing method thereof |
| CN105943456A (en) * | 2016-06-20 | 2016-09-21 | 合肥丰瑞隆生物科技有限公司 | Tea saponin shampoo and preparation method thereof |
| US9474283B2 (en) | 2010-12-09 | 2016-10-25 | Y&B Mother's Choice Ltd. | Formulations comprising saponins and uses thereof |
| US10064881B2 (en) | 2010-12-09 | 2018-09-04 | Y&B Mother's Choice Ltd. | Natural formulations |
| US10117827B2 (en) | 2013-12-08 | 2018-11-06 | Y&B Mother's Choice Ltd. | Preparations for suppressing or attenuating ocular irritancy |
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- 2008-11-06 CN CNB2008101435058A patent/CN100569214C/en not_active Expired - Fee Related
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| US10434058B2 (en) | 2010-12-09 | 2019-10-08 | Y&B Mother's Choice Ltd. | Natural formulations |
| US10064881B2 (en) | 2010-12-09 | 2018-09-04 | Y&B Mother's Choice Ltd. | Natural formulations |
| US9474283B2 (en) | 2010-12-09 | 2016-10-25 | Y&B Mother's Choice Ltd. | Formulations comprising saponins and uses thereof |
| CN102319190A (en) * | 2011-01-18 | 2012-01-18 | 朱绍华 | Pure plant hair dyeing method for blackening white hairs and shampoos used before dyeing |
| CN102319190B (en) * | 2011-01-18 | 2013-09-11 | 朱绍华 | Pure plant hair dyeing method for blackening white hairs and shampoos used before dyeing |
| CN102293719A (en) * | 2011-09-05 | 2011-12-28 | 郴州邦尔泰苏仙油脂有限公司 | Sanitizer |
| CN102293719B (en) * | 2011-09-05 | 2012-09-19 | 郴州邦尔泰苏仙油脂有限公司 | Sanitizer |
| CN102626377A (en) * | 2011-12-14 | 2012-08-08 | 李海祥 | Tea bran hair washing powder |
| CN102836088A (en) * | 2012-09-12 | 2012-12-26 | 杭州小青生物科技有限公司 | Cleansing cream containing tea saponin and preparation method thereof |
| CN103006504B (en) * | 2012-11-27 | 2015-04-15 | 杜江 | Multi-effect natural plant hair shampoo |
| CN103006504A (en) * | 2012-11-27 | 2013-04-03 | 北京凝翠轩生物科技有限公司 | Multi-effect natural plant hair shampoo |
| CN103385831A (en) * | 2013-07-19 | 2013-11-13 | 泉州市新益日用化妆品有限公司 | Novel oil tea shampoo and preparation method thereof |
| CN103462851B (en) * | 2013-09-26 | 2016-04-06 | 陈理敬 | One is decaptitated wind shampoo |
| CN103462851A (en) * | 2013-09-26 | 2013-12-25 | 陈理敬 | Head wind removing shampoo formula |
| CN103520036A (en) * | 2013-10-12 | 2014-01-22 | 湖南金浩茶油股份有限公司 | Hair-loss-preventing shampoo |
| CN103550072A (en) * | 2013-11-13 | 2014-02-05 | 长沙昊瑞生物科技有限公司 | Method for utilizing waste water generated in the technology for extracting tea seed oil through aqueous phase, and formula of liquid shampoo |
| CN103550072B (en) * | 2013-11-13 | 2016-03-16 | 长沙昊瑞生物科技有限公司 | A kind of Application way of aqueous extraction Oleum Camelliae technique waste water and shampoo prescription |
| US10117827B2 (en) | 2013-12-08 | 2018-11-06 | Y&B Mother's Choice Ltd. | Preparations for suppressing or attenuating ocular irritancy |
| CN104013559A (en) * | 2014-06-28 | 2014-09-03 | 管天球 | Anti-scurf shampoo containing tea saponin |
| CN105616204A (en) * | 2016-01-25 | 2016-06-01 | 柳州三农科技有限公司 | Antidandruff and gentle shampoo |
| CN105616292B (en) * | 2016-02-03 | 2019-03-12 | 九沪（上海）生物科技有限公司 | Tea Saponin shampoo containing Chinese medical extract and preparation method thereof |
| CN105616292A (en) * | 2016-02-03 | 2016-06-01 | 九沪（上海）生物科技有限公司 | Tea saponin shampoo containing traditional Chinese medicine extracts and preparation method thereof |
| CN105943456A (en) * | 2016-06-20 | 2016-09-21 | 合肥丰瑞隆生物科技有限公司 | Tea saponin shampoo and preparation method thereof |
| CN105919919A (en) * | 2016-06-20 | 2016-09-07 | 合肥丰瑞隆生物科技有限公司 | Hair growing and dandruff removing liquid shampoo and preparing method thereof |
| CN105919894A (en) * | 2016-06-20 | 2016-09-07 | 合肥丰瑞隆生物科技有限公司 | Biological environment-friendly liquid shampoo and preparing method thereof |
| CN105902450A (en) * | 2016-06-20 | 2016-08-31 | 合肥丰瑞隆生物科技有限公司 | Itching relieving shampoo and preparation method thereof |
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