CN102716044B - Low-stimulation hair-cleaning compound - Google Patents
Low-stimulation hair-cleaning compound Download PDFInfo
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- CN102716044B CN102716044B CN 201210225173 CN201210225173A CN102716044B CN 102716044 B CN102716044 B CN 102716044B CN 201210225173 CN201210225173 CN 201210225173 CN 201210225173 A CN201210225173 A CN 201210225173A CN 102716044 B CN102716044 B CN 102716044B
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Abstract
The invention belongs to the field of daily chemical products and specifically relates to a low-stimulation hair-cleaning compound. The low-stimulation hair-cleaning compound contains 5.0-40.0% of surface active agents, 0.5-2% of wetting agents, 0.05-0.1% of chelating agents, 0.1-0.6% of preservatives, 0.2-0.8% of thickening agents, 0.05-0.1% of anti-sensitization agents, less than or equal to 1% of essences, and the balance of water. The surface active agents are selected from at least one of cocamidopropyl betaine, alkyl glycoside, sodium lauroyl sarcosine and polyoxyethylene (80) triol laurate. The low-stimulation hair-cleaning compound does not contain the traditional strong-stimulation surface active agents; the new amino acid surface active agents and the amphoteric surface active agents are adopted; and the low-stimulation hair-cleaning compound is a hair-cleaning compound which has the advantages that the foaming property is excellent, the cleaning capacity is moderate, the excessive degreasing is avoided, the hair is free from being dry and unsmooth, and the hair-cleaning compound does not contain any cation and silicone oil, is deposition-free, does not generate residues and is mild and stimulation-free.
Description
Technical field
The invention belongs to household chemicals field, be specifically related to a kind of low stimulation hair-washing composition prescription.
Background technology
The application of surfactant in the system that contacts with human body such as medicine, food, cosmetics and personal hygiene article more and more widely, along with human living standard's raising, people more and more pay close attention to all kinds of toxic and side effects inputs that contact surfactant in the prescription with human body.At different purposes, the emphasis that surfactant is paid close attention to mainly concentrates on aspects such as the zest to mucosa, sensitization, toxicity, heritability, carcinogenecity, teratogenecity and the hemolytic to skin, the property digested and assimilated, biological degradability, Market of Chinese Shampoo is that personal care market develops the earliest one of the fastest market.Market competition, production firm faces more pressure, needs constantly to release new product and promotion method to increase the market competitiveness.Because be to develop market faster, so consumer has more sophisticated consumption habit relatively, the consumption demand sectionalization that more becomes.The present invention is a kind of hair-washing composition of low irritant, use new amino acid surfactant and amphoteric surfactant, it is a kind of good foam performance that has, appropriateness cleaning washability is arranged, excessively defat and cause hair dry and astringent does not contain any cation and silicone oil, does not have deposition, can not produce residue, gentle inirritative hair-washing composition.
Summary of the invention
The technical problem to be solved in the present invention provides a kind of hair washing combination formula of low irritant, solved the difficult problem that present shampoo occurs: " the surfactant zest big ", " foam performance is poor ", " degreasing power is crossed strong and is caused the hair dry and astringent "; " various conditioning agent deposits serious ", " contain the dioxanes carcinogen " etc. problem.
The present invention is for solving the problems of the technologies described above, at first abandoned polyoxyethylene lauryl ether sodium sulfate, the surfactant of traditional strong and stimulating such as sodium lauryl sulphate, but use new amino acid surfactant and amphoteric surfactant, and the collocation of the choose reasonable by host, formed the prescription of following low stimulation hair-washing composition:
A kind of hair washing combination formula prescription of low irritant, form by following component by weight percentage:
The surfactant of 5.0-40%;
The wetting agent of 0.5-2%;
The chelating agen of 0.05-0.1%;
The 0.05-0.1% anti-sensitizer;
The 0.1-0.5% antiseptic;
The 0.2-0.8% thickening agent;
≤ 1% essence;
Surplus is a water;
Described surfactant is selected from cocamido propyl betaine, alkyl polyglucoside, sodium lauroyl sarcosine, at least a in polyoxyethylene (80) the sorbic alcohol laurate.Owing to used new amino acid surfactant and amphoteric surfactant, guaranteed that the present invention not only has good foam performance, appropriateness cleaning washability is arranged, and not excessively defat and cause hair dry and astringent, and owing to do not contain any cation and silicone oil, therefore not having deposition, can not produce residue, is the inirritative hair-washing composition of a gentleness.
Described wetting agent is a glycerol.Wetting agent can improve foamy wettability, gives the good feel of consumer.
Described chelating agen is EDTA-2NA.Chelating agen mainly is in order to reduce the dissociated ion concentration in water quality and the raw material.
Described anti-sensitizer is a bisabolol.
Described antiseptic is selected from methyl parahydroxybenzoate, propyl p-hydroxybenzoate, and at least a in the dihydroxymethyl dimethyl hydantoin is used to prevent growth of microorganism.
Described thickening agent is an ethylene glycol distearate, and thickening agent has also played the effect of suspending agent simultaneously.
The present invention has following beneficial effect compared to existing technology:
The hair-washing composition of low irritant of the present invention does not contain polyoxyethylene lauryl ether sodium sulfate, the surfactant of traditional strong and stimulating such as sodium lauryl sulphate, but select good new amino acid surfactant and the amphoteric surfactant of natural low stimulation foaminess for use, therefore good foam performance is not only arranged, appropriateness cleaning washability is arranged, and not excessively defat and cause hair dry and astringent, and owing to do not contain any cation and silicone oil, therefore there is not deposition, can not produce residue, in addition, prescription does not contain the dioxanes carcinogen yet, is the inirritative hair-washing composition of a gentleness.
The specific embodiment
Preparation method of the present invention is conventional hybrid technology, does not elaborate at this.The present invention uses in the hair washing mode of routine, mainly comprises following step:
(1) after the use clear water drenches hair earlier;
(2) use new cream shampoo product of the present invention to spread upon equably on the hair, gently rubbed hair one minute;
(3) water is rinsed the foam on the hair well.
Suggestion is used every day, make first watch clearly, more moist, more healthy.
For the ease of it will be appreciated by those skilled in the art that the present invention will be further described below in conjunction with the zest test.Embodiment only is a preferred implementation of the present invention, is not limitation of the invention.
1, the evaluation of mildness of the present invention(1) tests the zest of estimating the embodiment of the invention 1 sample with the Draize lagophthalmos.Test method is for to be subjected to test solution to act on the cornea of white rabbit 0.1mL, certain hour is observed results of stimulation at interval, and tests in contrast with certain commercially available shampoo A, certain commercially available shampoo B, polyoxyethylene lauryl ether sodium sulfate (10% solution), sodium lauryl sulphate (10% solution).Result of the test sees Table 1.
Table 1 Draize lagophthalmos result of the test.
Sample | Total stimulation index | The Draize lagophthalmos is tested total stimulation index |
Embodiment 1 | 0~0.5 | <5 |
Commercially available shampoo A | 0.6~1.9? | <10 |
Commercially available shampoo B | 2.0~5.9 | <20 |
Polyoxyethylene lauryl ether sodium sulfate (10% solution) | / | >50 |
Sodium lauryl sulphate (10% solution) | / | >50 |
(2) with of the comparison of lagophthalmos mucosa to the tolerance level of several surfactants and the embodiment of the invention 1 sample stimulus.
(
Annotate: the high more system that shows of maximum concentration that tolerance stimulates is gentle more).
2, the embodiment of the invention 1 is at foam performance, washability and degreasing power, and the contrast test of hair compliance aspect and other commercially available shampoo sees the following form.
Name of product | Bubble high (mm) | Washability (calico whiteness d/o) | Degreasing power (oils and fats dissolution rate %) | Compliance (reducing coefficient of friction %) |
Commercially available shampoo 1 | 110 | 20 | 70 | 60 |
Commercially available shampoo 2 | 105 | 15 | 65 | 75 |
Commercially available shampoo 3 | 120 | 25 | 75 | 63 |
Commercially available shampoo 4 | 115 | 18 | 60 | 70 |
Embodiment 1 | 125 | 20 | 55 | 80 |
As seen from the above table, the present invention compares with the commercially available shampoo of several moneys, and good foam performance is arranged, and appropriateness cleaning washability is arranged, not excessively defat and cause hair dry and astringent.
Claims (1)
1. one kind low stimulates hair-washing composition, it is characterized in that, is made up of following component by weight percentage:
The surfactant of 5.0-40%;
The wetting agent of 0.5-2%;
The chelating agen of 0.05-0.1%
The 0.05-0.1% anti-sensitizer
The 0.1-0.5% antiseptic;
The 0.2-0.8% thickening agent;
≤ 1% essence
Surplus is a water;
Described surfactant is selected from cocamido propyl betaine, alkyl polyglucoside, sodium lauroyl sarcosine, at least a in polyoxyethylene (80) sorbitan laurate;
Described wetting agent is a glycerol;
Described chelating agen is EDTA-2Na;
Described anti-sensitizer is a bisabolol;
Described antiseptic is selected from methyl parahydroxybenzoate, propyl p-hydroxybenzoate, at least a in the dihydroxymethyl dimethyl hydantoin;
Described thickening agent is an ethylene glycol distearate.
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CN 201210225173 CN102716044B (en) | 2012-07-03 | 2012-07-03 | Low-stimulation hair-cleaning compound |
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CN 201210225173 CN102716044B (en) | 2012-07-03 | 2012-07-03 | Low-stimulation hair-cleaning compound |
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CN102716044A CN102716044A (en) | 2012-10-10 |
CN102716044B true CN102716044B (en) | 2013-07-31 |
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Families Citing this family (15)
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CN102895151B (en) * | 2012-10-22 | 2014-04-16 | 广州立白企业集团有限公司 | Sulfate-free hair cleanser and preparation method thereof |
CN102940585B (en) * | 2012-11-29 | 2014-08-27 | 纳爱斯集团有限公司 | Healthy shampoo taking natural source raw materials as main component |
CN104095771B (en) * | 2013-04-12 | 2016-09-14 | 上海家化联合股份有限公司 | A kind of amino acid type surfactant is from thickener composition |
CN103349621A (en) * | 2013-07-15 | 2013-10-16 | 澳宝化妆品(惠州)有限公司 | Washing and protecting combination low in excitation and good in flexibility |
CN104257524A (en) * | 2014-09-19 | 2015-01-07 | 江苏万淇生物科技有限公司 | Shampoo containing alkyl ethoxy polyglycosides |
CN105616277A (en) * | 2015-12-31 | 2016-06-01 | 罗永强 | Shampoo with moisturizing and softening functions |
CN105616276A (en) * | 2015-12-31 | 2016-06-01 | 罗永强 | Dandruff removing moisturizing shampoo |
CN105853256A (en) * | 2016-04-07 | 2016-08-17 | 广东珍宝健康日用品科技有限公司 | Oil-control and moisturizing low-irritation shampoo composition |
CN105943466B (en) * | 2016-06-24 | 2019-04-02 | 中山爱护婴童健康科技研究有限公司 | A kind of baby child's shampoo used also as bath lotion |
CN106074215A (en) * | 2016-07-25 | 2016-11-09 | 深圳市美福源日用品有限公司 | A kind of plasticine bath shampoo |
CN106619162A (en) * | 2017-03-10 | 2017-05-10 | 九江天赐高新材料有限公司 | Mild cleaning composition |
CN108096173A (en) * | 2017-12-28 | 2018-06-01 | 广州蜜妆生物科技有限公司 | Mild amino acid shampoo of a kind of green and preparation method thereof |
CN108379148A (en) * | 2018-04-07 | 2018-08-10 | 广州市索柔生物科技有限公司 | Low stimulation cleaning compositions of one kind and preparation method thereof |
CN108434079B (en) * | 2018-06-01 | 2020-06-02 | 广州澳希亚实业有限公司 | Shampoo and bath foam composition for infants and children |
CN111991261B (en) * | 2020-08-21 | 2021-10-08 | 广州德谷个人护理用品有限公司 | Mild oil control shampoo composition suitable for sensitive scalp and preparation method thereof |
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CN102293721B (en) * | 2011-07-29 | 2013-08-21 | 拉芳家化股份有限公司 | Mild green environment-friendly hair shampoo |
CN102415971B (en) * | 2011-12-07 | 2013-02-13 | 广州青能健日用品有限公司 | Biological environment-friendly hair-darkening and hairloss-preventing shampoo and preparation method thereof |
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CN1366028A (en) * | 2000-08-18 | 2002-08-28 | 强生消费者公司 | Viscous, mild and effective cleaning composition |
CN1370516A (en) * | 2001-02-14 | 2002-09-25 | 上海白猫有限公司 | Nourishing and amending shampoo |
WO2011015857A2 (en) * | 2009-08-03 | 2011-02-10 | Innospec Limited | Composition |
CN101658475A (en) * | 2009-09-28 | 2010-03-03 | 杨保成 | Cleaning and moisturizing cosmetics of trichosanthes kirilowii maxim extract series and preparation method thereof |
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