CN109381363A - A kind of amino acid shampoo and preparation method thereof - Google Patents
A kind of amino acid shampoo and preparation method thereof Download PDFInfo
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- CN109381363A CN109381363A CN201811567694.1A CN201811567694A CN109381363A CN 109381363 A CN109381363 A CN 109381363A CN 201811567694 A CN201811567694 A CN 201811567694A CN 109381363 A CN109381363 A CN 109381363A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A61K8/602—Glycosides, e.g. rutin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/002—Preparations for repairing the hair, e.g. hair cure
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/006—Antidandruff preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
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Abstract
The invention discloses a kind of amino acid shampoos comprising following weight percentage components: C14-16 alkene sulfonic acid sodium 2%~30%, Plantacare 818 1%~10%, coconut oleoyl amine MEA 0.1%~5%, sodium methyl cocoyl taurate 1%~20%, sodium lauroyl sarcosine solution 1%~30% and Cocoamidopropyl betaine 1%~30%.The present invention is studied by a large amount of creative experiments, raw material in amino acid shampoo is selected and formula is optimized, the Blowing agent composition of above-mentioned formula is arranged in pairs or groups with certain proportion and is used, make shampoo obtained that not only there is good cleaning dirt-removing power, it is mild non-stimulated, there are soft effect, and the moderate viscosity of shampoo to hair, foaming abundancy, exquisiteness and stabilization persistently, are easy to rinse well.
Description
Technical field
The present invention relates to daily chemical product technical fields more particularly to a kind of amino acid shampoo and preparation method thereof.
Background technique
The a part of hair as body structure, plays an important role in our daily life.Firstly, hair pair
Scalp has direct protective effect, and external force to scalp can work as a buffer, and reduces damage, protects head.Clinically, by
In the presence of hair, in addition to hair dye, foreign object can not directly contact scalp, avoid and the contact of dust, bacterium, therefore scalp
The generation of portion's contact dermatitis is few compared with other positions.At the same time, hair has very important Aesthetic Function, with unique
Important social mentality's function.Hair is the sign of blood condition is thought in Chinese medicine, the growth of kidney storing essence, Hua Fa, hair relies on essence and blood
It supplements nutrition, dense glossy hair represents health, can give people fine image, the shape of hair and the difference of state, to people's
Impression is different, and healthy and beautiful healthy hair makes people more self-confident in human communication.Same various hair follicle diseases, as alopecia,
Bad mentals, the serious persons such as few hair, dandruff etc. can allow people's generation to be felt oneself inferior, anxiety even influence social activity, therefore in daily life
Have in work the nursing for paying attention to hair.
Shampoo also known as shampoo are a kind of hair washing makeup articless for washing, belong to personal care market develop earliest and
One of most fast product.The development of shampoo has very long history, and people clean hair using soap before the 1930s, later
It comes out by the liquid shampoo of base-material of surfactant, the hard water resistance property of product and mildness are greatly improved.With life
The fast development of horizontal raising and science and technology, people to the security requirement of the surfactant of shampoo also increasingly
It is high.Amino acid surfactant is the mild surfactant of a protein species, have low irritant, hypotoxicity, mildness,
Good biodegradability properties and to preferable compatibility of human body etc., meet every demand of consumer, increasingly cause people's
Pay attention to.At home, to the research starting of amino acid type surfactant than later and relatively backward, amino acid type surfactant
When applied in cleaning class product, often there are problems that thickening is difficult can not even be thickened so as to cause being difficult to apply.Cause
This, utility ratio of the amino acid type surfactant at home in hair product is not also very high.Currently, all big enterprises pass through addition
Various high molecular polymer type thickeners are solved, but the foam characteristic of amino acid surfactant is suppressed,
To limit application of the amino acid surfactant in hair product.
Summary of the invention
It is an object of the invention to solve above-mentioned shortcoming and defect existing in the prior art, a kind of amino acid hair washing is provided
Water and preparation method thereof.Amino acid shampoo moderate viscosity of the invention, foaming abundancy is mild non-stimulated, cleaning and anti-dandruff effect
Fruit is good, solves the difficult technical problem of existing amino acid hair product thickening.
To realize its purpose, the technical scheme adopted by the invention is as follows:
A kind of amino acid shampoo comprising following weight percentage components: C14-16 alkene sulfonic acid sodium 2%~
30%, Plantacare 818 1%~10%, coconut oleoyl amine MEA 0.1%~5%, sodium methyl cocoyl taurate 1%~
20%, sodium lauroyl sarcosine solution 1%~30% and Cocoamidopropyl betaine 1%~30%.
C14-16 alkene sulfonic acid sodium has the ability of excellent wetting, decontamination, emulsification and blistering, and foam is stablized, easily
It is dissolved in water, hard water resistance property is good, also has good biological degradability, mild to skin, compatibility is good, keeps the foam of product rich
It is rich, fine and smooth, it is easy to rinse.The trade name AOS for the C14-16 alkene sulfonic acid sodium that the present invention uses, manufacturer are in Zhejiang
Gently.
Plantacare 818 has good foaming capacity and skin-friendliness, and property is mild, and biodegradable, foam is thin
It is greasy, the irritation of pungent can be reduced, there is good thickening effect.The trade name for the Plantacare 818 that the present invention uses
For Plantacare 2000UP, manufacturer is BASF.
Coconut oleoyl amine MEA have excellent thickening property and foam stability, irritation is low, clean ability it is good, also have compared with
Good moisturizing and opsonizing capacity.The trade name Comperlan 100C for the coconut oleoyl amine MEA that the present invention uses, manufacturer are
Corning.
Sodium methyl cocoyl taurate (also known as sodium cocoyl methyl sodium taurocholate) is a kind of anionic surfactant,
With excellent washing, wetting, emulsification and soft ability, foaming abundancy, exquisiteness, stabilization.Its also have good detergency and
Emulsifiability, resistance to hard water, resistance to acid and alkali is good with the conformability of yin, yang, nonionic and other amphoteric surfactantes, green peace
Complete and easily biological-degradable, property is mild, structure containing hydrophilic amino acid, very small to skin irritation, and hair can be assigned after use
Soft feeling is easy to rinse, without soapy feeling.The trade name for the sodium methyl cocoyl taurate that the present invention uses
Pureact WS Conc, manufacturer Lu Borun.
Sodium lauroyl sarcosine has superior foaminess, and foam is fine and smooth, lasting, also has preferable antibiotic and sterilizing
Property, decontamination and antistatic effect, and low toxicity, low irritant and moisture-retaining capacity, biological degradability be good, and no pollution to the environment is matched
5 property are good, can other anionic surfactants and when nonionic surfactant compatibility, its various function can be enhanced, after washing not
The excessive degreasing of meeting, skin sense are good.The INCI of the sodium lauroyl sarcosine solution entitled " water (and) sodium lauroyl sarcosine ",
In sodium lauroyl sarcosine content be 30%, trade name Ucefactant LS-30N, manufacturer be Guangzhou star industry
Science and Technology Ltd..
Cocoamidopropyl betaine has excellent dissolubility, compatibility, foaminess and thickening property and good anti-
Water hardness tolerance, antistatic property and biological degradability, also have low irritant and bactericidal properties, and compatible use can significantly improve washing class and produce
Softness, conditioning and the low-temperature stability of product.The trade name Ucefactant for the Cocoamidopropyl betaine that the present invention uses
CAB, manufacturer are Guangzhou Xing Ye Science and Technology Ltd..
The present invention is studied by a large amount of creative experiments, in amino acid shampoo raw material selection and formula carried out it is excellent
Change, the Blowing agent composition of above-mentioned formula is arranged in pairs or groups with the proportion of inventive formulation and is used, there is shampoo obtained not only good
Good cleaning dirt-removing power, it is mild non-stimulated, there are soft effect, and the moderate viscosity of shampoo, foaming abundancy, exquisiteness to hair
And stablize persistently, it is easy to rinse well.
Preferably, the amino acid shampoo includes following weight percentage components: C14-16 alkene sulfonic acid sodium 15%,
Plantacare 818 8%, coconut oleoyl amine MEA 1%, sodium methyl cocoyl taurate 10%, sodium lauroyl sarcosine solution 8%
And Cocoamidopropyl betaine 20%.At this point, the foam of amino acid shampoo is in terms of richness, fine and smooth sense and stability
Effect is best.
Preferably, the amino acid shampoo further includes following weight percentage components: piroctone olamine salt
0.01%~1% and myristamide propyl pg dimonium chloride phosphoesterase 30 .05%~2%.
Piroctone olamine salt has good debris removing effect, anti-dandruff and itching-relieving mechanism good to the inhibitory effect of fungi
It is the external channel by sterilizing and antioxidation fundamentally blocks dandruff to generate, so that dandruff, stopping head itching are effectively eradicated,
Rather than dandruff is temporarily eliminated from presentation by modes such as degreasings.The trade name for the piroctone olamine salt that the present invention uses
For Octopirox, manufacturer is Switzerland's Clariant (CLARIANT).
Myristamide propyl pg dimonium chloride phosphate has good conditioning performance, and property is mild, in this hair
In bright formula, synergistic function can be generated with piroctone olamine salt, the debris removing for enhancing piroctone olamine salt stops
Itch effect.The trade name Arlasilk PTM for the myristamide propyl pg dimonium chloride phosphate that the present invention uses,
Manufacturer is that standing grain is big.
Preferably, the matter of the piroctone olamine salt and myristamide propyl pg dimonium chloride phosphate
The ratio between amount are as follows: piroctone olamine salt: myristamide propyl pg dimonium chloride phosphate=1:1.At this point, pyrrole sieve
The synergistic effect that gram ketone ethanolamine salt and myristamide propyl pg dimonium chloride phosphate generate is most obvious, shampoo
Debris removing effect it is best.
Preferably, the amino acid shampoo further includes following weight percentage components: hydrolysed corn starch solution
0.01%~2%.The INCI of the hydrolysed corn starch solution entitled " hydrolysed corn starch (and) water ", hydrolysis therein are beautiful
Rice starch content is 72%, trade name TETRUP-L (maltotetraose), and manufacturer is Japan Hayashibara.It is described
The skin that hydrolysed corn starch solution occurs scratchiness to dry skin or often has improvement, can increase the moisture of cuticula
Content.
Preferably, the amino acid shampoo further includes following weight percentage components: polyquaternium -70.1%~
5% and Polyquaternium-10 0.01%~1%.
Polyquaternium -7 (Chinese nickname: two propylene ammonium chloride of dimethyl-acrylamide copolymer) can be used for enhancing yin from
The compatibility and transparency of sublist surfactant system, this copolymer with high adsorptivity are particularly suitable for improving hair care
The dry and wet characteristic of product and the texture of hair products can enable hair keep soft and water profit, moisturizing in use
Property it is high, reduce skin tight feeling.The trade name MerquatTM 550Polymer for the polyquaternium -7 that the present invention uses, production
Producer is Lu Borun.
Polyquaternium-10 is a kind of with superior water-soluble and adsorption capacity cationic cellulose polymer, can be with yin
Ion, cation, nonionic and zwitterionic surfactant are compatible, and irritation is low, and unique cationic properties can repair
Impaired hair protein matrix keeps hair to moisten, and assigns the superior carding property of hair and glossy smooth feeling.The present invention
The trade name JR-400 of the Polyquaternium-10 used, manufacturer are Dow Chemical.
Preferably, it counts in mass ratio, the polyquaternium -7: Polyquaternium-10=5:1.The present invention is found through experiments that,
Polyquaternium -7 and Polyquaternium-10 with the proportion and used time, the shampoo of inventive formulation in maintenance hair jag and change
Effect on kind damaged hair is more preferable.
Preferably, the amino acid shampoo further includes following weight percentage components: PEG-60 almond glyceride
0.01%~2% and moisturizing assign rouge agent 0.01%~3%；It is cocoyl glucoside and glyceryl oleate that rouge agent is assigned in the moisturizing
Mixture.
PEG-60 almond glyceride is a kind of modified vegetable oil suitable for all kinds of care products, is mainly characterized by make
For water-soluble emollient ester and solubilizer, meanwhile, anionic surfactant and zwitterionic surfactant can be dramatically increased
Mildness.The trade name Crovol A70 for the PEG-60 almond glyceride that the present invention uses, manufacturer are that standing grain is big.
The INCI entitled " cocoyl glucoside (and) glyceryl oleate " of rouge agent, trade name are assigned in the moisturizing
Lamesoft PO 65, manufacturer are BASF.The moisturizing, which is assigned rouge agent and played in inventive formulation, keeps hair moisturizing clear
Refreshing effect.
Preferably, the amino acid shampoo also comprises the following components: pH adjusting agent, thickener and preservative.Preferably,
The pH adjusting agent includes at least one of sodium citrate, citric acid.Preferably, the thickener includes PEG-150 season penta
Tetrol tetrastearate.Preferably, the preservative includes sodium benzoate, Phenoxyethanol, at least one in Sensiva SC50
Kind.It is highly preferred that the preservative includes the mixture of sodium benzoate and Phenoxyethanol and Sensiva SC50.Preferably, it presses
Mass ratio meter, the sodium benzoate: mixture=1:1 of Phenoxyethanol and Sensiva SC50.The Phenoxyethanol and ethyl
The INCI of the mixture of hexyl glycerol entitled " Phenoxyethanol (and) Sensiva SC50 ", trade name Euxyl PE9010,
Manufacturer is Germany Shu Mei.
Preferably, the amino acid shampoo by forming following weight percentage components: C14-16 alkene sulfonic acid sodium 2%
~30%, Plantacare 818 1%~10%, coconut oleoyl amine MEA 0.1%~5%, sodium methyl cocoyl taurate 1%~
20%, sodium lauroyl sarcosine solution 1%~30%, Cocoamidopropyl betaine 1%~30%, piroctone olamine salt
0.01%~1%, myristamide propyl pg dimonium chloride phosphoesterase 30 .05%~2%, hydrolysed corn starch solution
0.01%~2%, polyquaternium -7 0.1%~5%, Polyquaternium-10 0.01%~1%, PEG-60 almond glyceride
0.01%~2%, moisturizing assign rouge agent 0.01%~3%, EDETATE SODIUM 0.01%~0.5%, sodium citrate 0.05%~1%,
Citric acid 0.01%~1%, PEG-150 pentaerythritol tetrastearate 0.05%~2%, sodium benzoate 0.1%~1%, benzene
The mixture 0.01%~1% of oxyethanol and Sensiva SC50, essence 0.1%~2% and water surplus.
Preferably, the amino acid shampoo is grouped as by the group of following weight ratio: C14-16 alkene sulfonic acid sodium 15%, the last of the ten Heavenly stems
Base glucoside 8%, coconut oleoyl amine MEA 1%, sodium methyl cocoyl taurate 10%, sodium lauroyl sarcosine solution 8%, coconut palm
Oleamide propyl betaine 20%, piroctone olamine salt 0.3%, myristamide propyl pg dimonium chloride phosphoric acid
Ester 0.3%, hydrolysed corn starch solution 0.3%, polyquaternium -7 2%, Polyquaternium-10 0.4%, PEG-60 almond glycerol
Rouge agent 1%, EDETATE SODIUM 0.1%, sodium citrate 0.4%, citric acid 0.3%, PEG-150 pentaerythrite are assigned in ester 0.5%, moisturizing
Tetrastearate 0.3%, sodium benzoate 0.5%, the mixture 0.5% of Phenoxyethanol and Sensiva SC50, essence 0.5% and
Water surplus.
Preferably, the preparation method of the amino acid shampoo, includes the following steps:
(1) EDETATE SODIUM and part water are added in emulsion pot, are heated to 85~90 DEG C；
(2) by Polyquaternium-10 surplus water dispersion, sodium citrate is then added, is added immediately after mixing evenly above-mentioned
In emulsion pot；
(3) by C14-16 alkene sulfonic acid sodium, Plantacare 818, coconut oleoyl amine MEA, sodium methyl cocoyl taurate, the moon
Osmanthus acylsarcosine sodium solution, PEG-150 pentaerythritol tetrastearate, piroctone olamine salt, PEG-60 almond glyceride
It assigns rouge agent with moisturizing to be added in above-mentioned emulsion pot, stirring keeps the temperature 10~20min to being completely dissolved, then defoaming cooling；
(4) when being cooled to 40~50 DEG C, hydrolysed corn starch solution, Cocoamidopropyl betaine, myristoyl is added
Amine propyl pg dimonium chloride phosphate and polyquaternium -7, stir evenly, citric acid are then added, stir evenly；
(5) it is eventually adding the mixture and essence of sodium benzoate, Phenoxyethanol and Sensiva SC50, is stirred evenly,
The amino acid shampoo is made.
Compared with prior art, the beneficial effects of the present invention are: the present invention to the raw material selection of amino acid shampoo and
Formula is optimized, and has the energy of excellent dandruff-removing itching-relieve and cleaning decontamination with amino acid shampoo made from inventive formulation
Power, and property is mild, to no skin irritation, moderate viscosity, foaming abundancy, exquisiteness and stabilization persistently, are easy to rinse well, make
It is good to the repairing effect of damaged hair without glutinous soapy feeling with rear imparting hair soft, moisturizing and salubrious feeling.
Specific embodiment
To better illustrate the object, technical solutions and advantages of the present invention, the present invention passes through the following example furtherly
It is bright.It should be understood that the embodiment of the present invention is merely to illustrate technical effect of the invention, protection model and is not intended to limit the present invention
It encloses.In embodiment, method therefor is conventional method unless otherwise instructed.
Embodiment
Examples 1 to 10 is the embodiment of amino acid shampoo of the present invention, and formula is shown in Table 1.
In embodiment: the trade name AOS of C14-16 alkene sulfonic acid sodium, manufacturer are light in Zhejiang.Plantacare 818
Trade name Plantacare 2000UP, manufacturer is BASF.The trade name Comperlan of coconut oleoyl amine MEA
100C, manufacturer are Corning.The trade name Pureact WS Conc of sodium methyl cocoyl taurate, manufacturer are
Lu Borun.The trade name Ucefactant LS-30N of sodium lauroyl sarcosine solution, manufacturer are that star industry science and technology in Guangzhou has
Limit company.The trade name Ucefactant CAB of Cocoamidopropyl betaine, manufacturer are that star industry science and technology in Guangzhou is limited
Company.The trade name Octopirox of piroctone olamine salt, manufacturer are Switzerland's Clariant (CLARIANT).Pork and beans
The trade name Arlasilk PTM of cool amido propyl pg dimonium chloride phosphate, manufacturer are that standing grain is big.Hydrolysed corn
The trade name TETRUP-L (maltotetraose) of starch solution, manufacturer are Japan Hayashibara.The quotient of polyquaternium -7
The name of an article is MerquatTM 550Polymer, manufacturer Lu Borun.The trade name JR-400 of Polyquaternium-10, production
Producer is Dow Chemical.The trade name Crovol A70 of PEG-60 almond glyceride, manufacturer are that standing grain is big.Cocoyl
Glucoside (and) the trade name Lamesoft PO 65 of glyceryl oleate, manufacturer is BASF.Phenoxyethanol (and) second
The trade name Euxyl PE9010 of base hexyl glycerol, manufacturer are Germany Shu Mei.
The amino acid shampoo formula (weight percent, %) of 1 Examples 1 to 10 of table
The preparation method of the amino acid shampoo of Examples 1 to 10, includes the following steps:
(1) EDETATE SODIUM and part water are added in emulsion pot, are heated to 85 DEG C；
(2) by Polyquaternium-10 surplus water dispersion, sodium citrate is then added, is added immediately after mixing evenly above-mentioned
In emulsion pot；
(3) by C14-16 alkene sulfonic acid sodium, Plantacare 818, coconut oleoyl amine MEA, sodium methyl cocoyl taurate, the moon
Osmanthus acylsarcosine sodium solution, PEG-150 pentaerythritol tetrastearate, piroctone olamine salt, PEG-60 almond glyceride
And cocoyl glucoside (and) glyceryl oleate is added in above-mentioned emulsion pot, stirring keeps the temperature 15min, then disappears to being completely dissolved
Bubble cooling；
(4) when being cooled to 45 DEG C, hydrolysed corn starch solution, Cocoamidopropyl betaine, myristamide third is added
Base pg dimonium chloride phosphate and polyquaternium -7, stir evenly, citric acid are then added, stir evenly；
(5) be eventually adding sodium benzoate, Phenoxyethanol (and) Sensiva SC50 and essence, stir evenly, institute be made
State amino acid shampoo.
The percentage of weight formula of the amino acid shampoo of comparative example 1~5 is as shown in table 2.
The amino acid shampoo formula (weight percent, %) of 2 comparative example 1~5 of table
The amino acid shampoo of preparation method reference above-described embodiment 1~10 of the amino acid shampoo of comparative example 1~5
Preparation method.
One, shampoo safety evaluatio (patch test)
Patch test (patch test) be prepared according to the property of tested material the immersion liquid of debita spissitudo, solution, ointment or
The original is affixed on skin as reagent in a suitable approach, observes whether body generates hypersensitivity to it after a certain period of time,
Patch test is the main method for being clinically used for IV type hypersensitivity of detection at present.
Test method: volunteer of 50 ages of random selection at 20~40 years old, selected volunteer is without skin allergy history.It will
Volunteer is randomly divided into 10 groups, and every group of 5 people carry out patch test using the amino acid shampoo of Examples 1 to 10 respectively.
Suitable quantity of water is added in the amino acid shampoo of Examples 1 to 10 respectively, is configured to the test solution of same concentrations, then
1cm is soaked with test solution2Then 4 thickness gauzes of size apply the gauze soaked in the forearm side in the wrong of volunteer, thereon with slightly larger
Cellophane cover covering, surrounding fixed with adhesive plaster, remove gauze (48h can induce local skin and react) after 48h, and
According to the performance interpretation result of local skin.Test result is feminine gender, then without allergic phenomena；Test result is the positive, then generates
Irritative response (erythematous response disappears quickly after irritative response removal spot examination object) or allergic reaction (allergic reaction then table
It is now wellability erythema, papule etc.).
It is observed that the recipient site of all volunteers is without there is irritative response and allergic reaction, test result is equal
Show as feminine gender.Show that amino acid shampoo of the invention is non-stimulated to skin safe.
Two, debris removing measure of merit
Horse traction color Salmonella is one of an important factor for forming dandruff, the growing state of horse traction color Salmonella and dandruff it is more
There is directly related property less.Therefore, it is to inhibit the growth of horse traction color Salmonella that mesh, which has most effective anti-dandruff method,.
The preparation of sample board: taking Xinhua's No.1 qualitative filter paper, diameter 5mm circular filter paper piece is broken into punch, through pressure
Steam sterilizing takes the coupons dried after sterilization treatment several, dips a little implementation 1~10 and comparative example respectively with aseptic nipper
1~2 amino acid shampoo is as far as possible smeared coupons uniform in coupons.
The preparation of plate: the activated not plump chlosma of sugar (being purchased from Wuhan University's Culture Collection Center) is configured to
106Cfu/mL~107The bacteria suspension of cfu/mL takes bacteria suspension 0.3mL to be applied to the Leeming&Notman culture medium flat plate of 12cm
On.After above-mentioned plate containing bacterium is placed 10min, flat plate cover is opened in aseptic superclean bench, (about with sterile wind drying plate
20min)。
The measurement of fungistatic effect: 4 coupons are placed in each plate, 1 negative control is (without test hair washing water sample
Product) print, totally 5.After being placed with, with the light pressure-like piece of aseptic nipper, it is made to be close to planar surface.Plate is covered, 32 DEG C of perseverances are set
It is inverted culture 7 days in warm incubator, antibacterial diameter is recorded with vernier caliper measurement.Evaluation criterion: inhibition zone diameter >=20mm
When, it is determined as that debris removing effect is obvious；When 20mm > inhibition zone diameter >=15mm, it is determined as that debris removing effect is general；Inhibition zone diameter
When < 15mm, it is determined as no debris removing effect.Test result is as shown in table 3.
Table 3
Table 3 the result shows that, the amino acid shampoo of the embodiment of the present invention all has apparent debris removing effect.Adding on an equal basis
In the case where dosage, piroctone olamine salt: when myristamide propyl pg dimonium chloride phosphate=1:1, hair washing
The debris removing effect of water is best.With the increase of piroctone olamine salt additive amount, the debris removing effect of shampoo improves, but works as it
When additive amount is more than 0.3%, the debris removing effect of shampoo can be gradually reduced again, therefore, when the addition of piroctone olamine salt
When amount is 0.3%, the debris removing effect of the shampoo of inventive formulation is best.
Three, using effect is tested
Female volunteers of 130 ages at 20~40 years old are randomly selected, are divided into 13 groups, number group 1~groups 13.Group 1
~groups 13 volunteer uses the shampoo of Examples 1 to 10 and comparative example 3~5 respectively, and after continuous use 3 times, feedback is used
Effect, and shampoo is evaluated according to assessment item, other hair products are forbidden to use during test.Count each group aspiration
Person chooses the number of each option of assessment item, as a result as shown in table 4 and table 5.
4 shampoo using effect of table statistics
5 shampoo using effect of table statistics
Table 4 and table 5 the result shows that, nearly all obtained using the volunteer of the amino acid shampoo of Examples 1 to 10
Preferable also to illustrate that amino acid shampoo of the invention has preferable cleaning dynamics using feeling, dandruff-removing itching-relieve effect is good, bubble
The abundant exquisiteness of foam, is easy to rinse well, can increase the compliance of hair after washing, mild non-stimulated.And due to comparative example 3~5
In shampoo, the proportion of foaming agent is changed, and leads to spatter property, easy washability, foaming abundancy degree and the temperature of shampoo
It is all greatly affected with property etc..Illustrate, C14-16 alkene sulfonic acid sodium, Plantacare 818, coconut oleoyl amine MEA, methyl cocoyl ox
Sodium sulfonate, sodium lauroyl sarcosine solution and Cocoamidopropyl betaine these types component are arranged in pairs or groups with the proportion of inventive formulation
In use, shampoo not only has good cleaning dirt-removing power, and it is mild non-stimulated, there are soft effect, and shampoo to hair
Moderate viscosity, foaming abundancy, exquisiteness and stablize persistently, be easy to rinse well.
In summary test result, the present invention is using the formula of embodiment 1 as optimization formula.
Finally, it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention rather than protects to the present invention
The limitation of range is protected, although the invention is described in detail with reference to the preferred embodiments, those skilled in the art should
Understand, it can be with modification or equivalent replacement of the technical solution of the present invention are made, without departing from the essence of technical solution of the present invention
And range.
Claims (10)
1. a kind of amino acid shampoo, which is characterized in that including following weight percentage components: C14-16 alkene sulfonic acid sodium
2%~30%, Plantacare 818 1%~10%, coconut oleoyl amine MEA 0.1%~5%, sodium methyl cocoyl taurate 1%
~20%, sodium lauroyl sarcosine solution 1%~30% and Cocoamidopropyl betaine 1%~30%.
2. amino acid shampoo as described in claim 1, which is characterized in that the amino acid shampoo includes following weight hundred
Divide the component of ratio: C14-16 alkene sulfonic acid sodium 15%, Plantacare 818 8%, coconut oleoyl amine MEA 1%, methyl cocoyl ox
Sodium sulfonate 10%, sodium lauroyl sarcosine solution 8% and Cocoamidopropyl betaine 20%.
3. amino acid shampoo as described in claim 1, which is characterized in that the amino acid shampoo further includes following weight
The component of percentage: piroctone olamine salt 0.01%~1% and myristamide propyl pg dimonium chloride phosphate
0.05%~2%；
Preferably, the quality of the piroctone olamine salt and myristamide propyl pg dimonium chloride phosphate it
Than are as follows: piroctone olamine salt: myristamide propyl pg dimonium chloride phosphate=1:1.
4. amino acid shampoo as claimed in claim 3, which is characterized in that the amino acid shampoo further includes following weight
The component of percentage: hydrolysed corn starch solution 0.01%~2%.
5. amino acid shampoo as described in claim 1, which is characterized in that the amino acid shampoo further includes following weight
The component of percentage: polyquaternium -7 0.1%~5% and Polyquaternium-10 0.01%~1%.
6. amino acid shampoo as described in claim 1, which is characterized in that the amino acid shampoo further includes following weight
The component of percentage: rouge agent 0.01%~3% is assigned in PEG-60 almond glyceride 0.01%~2% and moisturizing；Rouge is assigned in the moisturizing
Agent is the mixture of cocoyl glucoside and glyceryl oleate.
7. the amino acid shampoo as described in right wants 1, which is characterized in that the amino acid shampoo also comprises the following components:
PH adjusting agent, thickener and preservative；
Preferably, the pH adjusting agent includes at least one of sodium citrate, citric acid；
Preferably, the thickener includes PEG-150 pentaerythritol tetrastearate；
Preferably, the preservative includes at least one of sodium benzoate, Phenoxyethanol, Sensiva SC50；
It is highly preferred that the preservative includes the mixture of sodium benzoate and Phenoxyethanol and Sensiva SC50；
Preferably, it counts in mass ratio, the sodium benzoate: mixture=1:1 of Phenoxyethanol and Sensiva SC50.
8. amino acid shampoo as described in any one of claims 1 to 7, which is characterized in that the amino acid shampoo is by such as
The group of lower weight percent is grouped as: C14-16 alkene sulfonic acid sodium 2%~30%, Plantacare 818 1%~10%, coconut oleoyl amine
MEA 0.1%~5%, sodium methyl cocoyl taurate 1%~20%, sodium lauroyl sarcosine solution 1%~30%, cocounut oil
Amido propyl betaine 1%~30%, piroctone olamine salt 0.01%~1%, myristamide propyl PG- dimethyl chloride
Change ammonium phosphoesterase 30 .05%~2%, hydrolysed corn starch solution 0.01%~2%, polyquaternium -7 0.1%~5%, poly- season
Rouge agent 0.01%~3%, EDTA bis- are assigned in ammonium salt -10 0.01%~1%, PEG-60 almond glyceride 0.01%~2%, moisturizing
Sodium 0.01%~0.5%, sodium citrate 0.05%~1%, citric acid 0.01%~1%, four stearic acid of PEG-150 pentaerythrite
Ester 0.05%~2%, sodium benzoate 0.1%~1%, Phenoxyethanol and Sensiva SC50 mixture 0.01%~1%, fragrant
Essence 0.1%~2% and water surplus.
9. amino acid shampoo as claimed in claim 8, which is characterized in that the amino acid shampoo is by following weight ratio
Group is grouped as: C14-16 alkene sulfonic acid sodium 15%, Plantacare 818 8%, coconut oleoyl amine MEA 1%, methyl cocoyl ox sulphur
Sour sodium 10%, sodium lauroyl sarcosine solution 8%, Cocoamidopropyl betaine 20%, piroctone olamine salt 0.3%,
Myristamide propyl pg dimonium chloride phosphoesterase 30 .3%, hydrolysed corn starch solution 0.3%, polyquaternium -7
2%, rouge agent 1%, EDETATE SODIUM 0.1%, lemon are assigned in Polyquaternium-10 0.4%, PEG-60 almond glyceride 0.5%, moisturizing
Sour sodium 0.4%, citric acid 0.3%, PEG-150 pentaerythritol tetrastearate 0.3%, sodium benzoate 0.5%, Phenoxyethanol and
Mixture 0.5%, essence 0.5% and the water surplus of Sensiva SC50.
10. the preparation method of amino acid shampoo as claimed in claim 8 or 9, which comprises the steps of:
(1) EDETATE SODIUM and part water are added in emulsion pot, are heated to 85~90 DEG C；
(2) by Polyquaternium-10 surplus water dispersion, sodium citrate is then added, above-mentioned emulsification is added immediately after mixing evenly
In pot；
(3) by C14-16 alkene sulfonic acid sodium, Plantacare 818, coconut oleoyl amine MEA, sodium methyl cocoyl taurate, lauroyl
Sodium sarcosinate solution, PEG-150 pentaerythritol tetrastearate, piroctone olamine salt, PEG-60 almond glyceride and guarantor
Wet tax rouge agent is added in above-mentioned emulsion pot, and stirring keeps the temperature 10~20min to being completely dissolved, then defoaming cooling；
(4) when being cooled to 40~50 DEG C, hydrolysed corn starch solution, Cocoamidopropyl betaine, myristamide third is added
Base pg dimonium chloride phosphate and polyquaternium -7, stir evenly, citric acid are then added, stir evenly；
(5) it is eventually adding the mixture and essence of sodium benzoate, Phenoxyethanol and Sensiva SC50, is stirred evenly, is made
The amino acid shampoo.
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