CN111991261A - Mild oil control shampoo composition suitable for sensitive scalp and preparation method thereof - Google Patents
Mild oil control shampoo composition suitable for sensitive scalp and preparation method thereof Download PDFInfo
- Publication number
- CN111991261A CN111991261A CN202010849481.9A CN202010849481A CN111991261A CN 111991261 A CN111991261 A CN 111991261A CN 202010849481 A CN202010849481 A CN 202010849481A CN 111991261 A CN111991261 A CN 111991261A
- Authority
- CN
- China
- Prior art keywords
- oil control
- shampoo
- shampoo composition
- tea
- mild
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/63—Steroids; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/88—Polyamides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9789—Magnoliopsida [dicotyledons]
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/008—Preparations for oily hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Biotechnology (AREA)
- Botany (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a mild oil control shampoo composition suitable for sensitive scalp and a preparation method thereof, wherein the mild oil control shampoo composition comprises, by mass, 6-10% of tea saponin, 2-5% of coco-glucoside, 1-4% of cocamidopropyl betaine, 1-5% of sodium lauroyl sarcosinate, 0.5-1.5% of a conditioner, 0.5-1.5% of a fatting agent, 0.5-2.0% of an auxiliary oil control additive, 0.5-2.0% of a cuticle softener, 1.5-2% of a thickener and the balance of water. The tea saponin is simultaneously used as a main surfactant and a main oil control component of the shampoo, a multi-target oil control way is formed through reasonable compounding, the oil control effect of the shampoo is enhanced, the mildness of the shampoo is improved, the shampoo is suitable for people with sensitive scalp, and the irritation to the scalp is reduced while the good combing property of the hair is maintained.
Description
Technical Field
The invention belongs to the technical field of daily chemicals, and particularly relates to a mild oil control shampoo composition suitable for sensitive scalp and a preparation method thereof.
Background
The oil control function of the shampoo is one of the important demands of consumers, the scalp sebum secretion of partial crowds is too vigorous, the attractive appearance of hair is affected, and the hair and the scalp are easily damaged due to too frequent hair washing. In addition, the exuberant sebum secretion may cause excessive proliferation of microorganisms such as malassezia and propionibacterium acnes on the scalp. The microorganisms not only cause dandruff, but also decompose sebum to generate free fatty acid and other metabolites, so that scalp generates inflammatory reaction, scalp itching, stimulation, sensitivity and other series problems are caused, scalp barrier function is damaged, and seborrheic dermatitis, alopecia and the like are generated in severe cases.
At present, a plurality of oil control shampoos exist in the market, and the formula characteristics can be divided into three types: (1) the conventional shampoo taking lauryl ether sulfate (AES for short) as a main cleaning component is added with a certain amount of strong acids (such as salicylic acid, tartaric acid and the like), the strong acid components can peel off the cuticle of the scalp, dredge pores and avoid sebum secretion imbalance and inflammatory reaction caused by accumulation of grease in the pores, but the shampoo has strong acidity, has a stimulation effect on the scalp, is not suitable for people with sensitive scalp, and is often sensitive to the scalp of people with vigorous sebum; (2) the shampoo which takes the synthetic surfactant (usually amino acid surfactant) with good mildness as the main cleaning component has moderate degreasing power, avoids the sebum rebound phenomenon caused by excessive sebum washing, scalp lipid dissolution and scalp barrier function damage brought by the surfactant with over-strong cleaning power, but the synthetic surfactant generally has no other biological activity and can not effectively solve the problem that part of people have active sebaceous glands; (3) the shampoo prepared by adding various plant extracts and Chinese herbal medicine extracts into the conventional shampoo (such as the conventional shampoo taking AES as a main cleaning component), but the additive is not considered to be synergistic with other components, the oil control principle is not clear, sebum secretion is difficult to be reduced fundamentally, and the actual effect is not good (or is not reported). (4) The conventional cationic conditioner or silicone compound conditioner has obvious scalp irritation, such as polyquaternium-10, guar gum cationic conditioner (such as guar gum hydroxypropyl trimethyl ammonium amide), polyquaternium-39, etc. In conclusion, the existing oil control shampoo has the problem that the scalp sebum secretion is vigorous due to various different mechanisms, cannot be suitable for wider crowds, and particularly lacks an ideal mild oil control shampoo for crowds with sensitive scalp.
Disclosure of Invention
This section is for the purpose of summarizing some aspects of embodiments of the invention and to briefly introduce some preferred embodiments. In this section, as well as in the abstract and the title of the invention of this application, simplifications or omissions may be made to avoid obscuring the purpose of the section, the abstract and the title, and such simplifications or omissions are not intended to limit the scope of the invention.
As one aspect of the present invention, the present invention provides a mild oil control shampoo composition suitable for use on sensitive scalp.
In order to solve the technical problems, the invention provides the following technical scheme: a mild oil control shampoo composition suitable for sensitive scalp: the oil-soluble tea saponin comprises, by mass, 6-9% of tea saponin, 2-5% of coco-oil glucoside, 1-4% of cocamidopropyl betaine, 1-5% of sodium lauroyl sarcosinate, 0.5-1.5% of a conditioner, 0.5-1.5% of a fatting agent, 0.5-2.0% of an auxiliary oil control additive, 0.5-2.0% of a cuticle softener, 1.5-2% of a thickener and the balance of water.
As a preferred embodiment of the mild oil control shampoo composition suitable for sensitive scalp according to the present invention: the content of the tea saponin is 7-8%; the content of the coco glucoside is 3-4%; the content of the cocamidopropyl betaine is 2-3%; the content of the sodium lauroyl sarcosinate is 2-3%.
As a preferred embodiment of the mild oil control shampoo composition suitable for sensitive scalp according to the present invention: the conditioner consists of 0.5-0.6% of tea bran polysaccharide, 0.4-0.6% of sodium polyaspartate and 0.3-0.4% of inulin; the tea bran polysaccharide has the molecular weight of 5000-10000 Da.
As a preferred embodiment of the mild oil control shampoo composition suitable for sensitive scalp according to the present invention: the molecular weight of the polyaspartic acid sodium is 3000-5000.
As a preferred embodiment of the mild oil control shampoo composition suitable for sensitive scalp according to the present invention: the fat-liquoring agent consists of 0.4-0.5% of tea tree oil and 0.4-0.6% of turmeric oil.
As a preferred embodiment of the mild oil control shampoo composition suitable for sensitive scalp according to the present invention: the auxiliary oil control additive consists of 0.3% of zinc pyrrolidone carboxylate, 0.8-1.0% of eucalyptus leaf extract and 0.5-0.7% of folium artemisiae argyi extract.
As a preferred embodiment of the mild oil control shampoo composition suitable for sensitive scalp according to the present invention: the cuticle softener consists of 0.5-0.6% of citric acid and 0.3-0.4% of lactic acid; the thickener was 1.75% pentaerythritol tetrastearate.
As a preferred embodiment of the mild oil control shampoo composition suitable for sensitive scalp according to the present invention: also comprises 0.1 percent of disodium ethylene diamine tetraacetate and essence.
As another aspect of the present invention, the present invention provides a method for preparing the mild oil control shampoo composition suitable for sensitive scalp, which comprises the following steps: adding deionized water into a main pot, adding tea bran polysaccharide, sodium polyaspartate, inulin and disodium ethylene diamine tetraacetate serving as composite conditioners, quickly stirring to enable the composite conditioners to be swelled and fully dissolved, adding tea saponin, coco glucoside, cocamidopropyl betaine, sodium lauroyl sarcosinate and pentaerythritol tetrastearate, heating to 75 ℃, and keeping stirring until the tea saponin, the coco glucoside, the coco amidopropyl betaine, the sodium lauroyl sarcosinate and the pentaerythritol tetrastearate are completely dissolved; then cooling to 55 ℃ while stirring, slowly adding the tea tree oil, the curcuma oil, the zinc pyrrolidone carboxylate, the eucalyptus leaf extract and the folium artemisiae argyi extract into the main pot, controlling the stirring speed at 45 revolutions per minute, stirring for 30 minutes and cooling; cooling to 45 deg.C, adding sodium benzoate, citric acid, lactic acid and essence, stirring for 30 min, cooling to below 35 deg.C, and discharging.
As a preferred embodiment of the preparation method of the mild oil control shampoo composition suitable for sensitive scalp, the preparation method comprises the following steps: the extraction method of the tea saponin comprises the following steps: taking degreased oil tea bran, wherein the material-liquid ratio is 1: 8. extracting at 70 deg.C for 3 hr, filtering the extractive solution, separating, evaporating to concentrate to 20% of original volume, concentrating to obtain concentrated solution: the volume ratio of ethanol is 1: 4, adding 95% ethanol, stirring, centrifugally separating to obtain an ethanol extract, and drying to obtain a crude product of the tea saponin; further purifying the crude product of the tea saponin by using AB-8 type macroporous resin, and eluting by using 80% ethanol solution to obtain the purified tea saponin with the purity of more than 90%.
The invention has the beneficial effects that: the tea saponin is simultaneously used as a main surfactant and a main oil control component of the shampoo, and a multi-target-point oil control way is formed by compounding various other mild surfactants, namely coco-glucoside, cocamidopropyl betaine and sodium lauroyl sarcosinate, and reasonably compounding and optimizing the composition of the eucalyptus extract and the folium artemisiae argyi extract which are used as auxiliary oil control additives and the tea saponin, so that the oil control effect of the shampoo is enhanced, the mildness of the shampoo is improved, the shampoo is suitable for scalp sensitive people, and the scalp sensitivity is improved; in addition, while maintaining good hair combing properties, the preferred combination conditioners suitable for this system avoid the accumulation of cationic conditioners commonly used in the prior art on the hair and the irritation of the scalp of sensitive people over extended periods of time.
Drawings
In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the drawings needed to be used in the description of the embodiments will be briefly introduced below, and it is obvious that the drawings in the following description are only some embodiments of the present invention, and it is obvious for those skilled in the art to obtain other drawings based on these drawings without inventive exercise. Wherein:
fig. 1 is a micrograph of the scalp sensitivity state before and after the volunteer uses the shampoo of example 1 of the present invention.
Fig. 2 is a micrograph of oil accumulation in scalp pores before and after applying shampoo of example 1 of the present invention to volunteers.
Detailed Description
In order to make the aforementioned objects, features and advantages of the present invention comprehensible, embodiments accompanied with examples are described in detail below.
In the following description, numerous specific details are set forth in order to provide a thorough understanding of the present invention, but the present invention may be practiced in other ways than those specifically described and will be readily apparent to those of ordinary skill in the art without departing from the spirit of the present invention, and therefore the present invention is not limited to the specific embodiments disclosed below.
Furthermore, reference herein to "one embodiment" or "an embodiment" means that a particular feature, structure, or characteristic described in connection with the embodiment is included in at least one implementation of the invention. The appearances of the phrase "in one embodiment" in various places in the specification are not necessarily all referring to the same embodiment, nor are separate or alternative embodiments mutually exclusive of other embodiments.
Example 1:
the mild oil control shampoo composition suitable for sensitive scalp comprises the following components in percentage by mass (g: mL): 8% of tea saponin, 3% of coco glucoside, 2% of cocamidopropyl betaine, 2% of sodium lauroyl sarcosinate, 0.5% of tea bran polysaccharide (5000-10000 Da), 0.4% of sodium polyaspartate (molecular weight is 3000-5000 Da), 0.3% of inulin, 0.4% of tea tree oil, 0.4% of turmeric oil, 0.6% of citric acid, 0.3% of lactic acid, 0.3% of zinc pyrrolidone carboxylate, 0.8% of eucalyptus leaf extract (obtained by performing ethanol extraction on eucalyptus leaf powder at a material-liquid ratio of 1: 10 and 60 ℃ and then drying), 0.5% of folium artemisiae argyi extract (obtained by performing ethanol extraction on folium artemisiae argyi powder at a material-liquid ratio of 1: 10 and 70 ℃ and then drying), 1.75% of pentaerythritol tetrastearate, 0.3% of sodium benzoate, 0.1% of disodium ethylenediamine tetraacetate, a proper amount of essence, and the balance of water, wherein the pH value of the shampoo is about 4.6.
The preparation method of the shampoo comprises the following steps: adding deionized water into a main pot, adding a compound conditioner (tea bran polysaccharide, sodium polyaspartate and inulin) and disodium ethylene diamine tetraacetate, rapidly stirring to swell and fully dissolve the conditioner, adding a surfactant (tea saponin, coco glucoside, cocamidopropyl betaine and sodium lauroyl sarcosinate) and pentaerythritol tetrastearate, heating to 75 ℃, and keeping stirring until the mixture is completely dissolved; then cooling to 55 ℃ while stirring, slowly adding the tea tree oil, the curcuma oil, the zinc pyrrolidone carboxylate, the eucalyptus leaf extract and the folium artemisiae argyi extract into the main pot, controlling the stirring speed at 45 revolutions per minute, stirring for 30 minutes and cooling; when the temperature is reduced to 45 ℃, adding sodium benzoate, citric acid, lactic acid and essence, continuing stirring for 30 minutes, and discharging when the temperature is reduced to below 35 ℃.
The extraction method of the tea saponin comprises the following steps: taking degreased oil tea bran, wherein the material-liquid ratio is 1: 8. extracting at 70 deg.C for 3 hr, filtering the extractive solution, separating, evaporating to concentrate to 20% of original volume, concentrating to obtain concentrated solution: the volume ratio of ethanol is 1: 4, adding 95% ethanol, stirring, centrifugally separating to obtain an ethanol extract, and drying to obtain a crude product of the tea saponin; further purifying the crude product by AB-8 type macroporous resin, and eluting with 80% ethanol solution to obtain purified tea saponin with purity of more than 90%.
The extraction and purification method of the tea bran polysaccharide comprises the following steps:
(1) taking degreased oil tea bran powder, adding 85% ethanol, and mixing the materials in a material-liquid ratio of 1: 7. refluxing at 60 deg.C for 2 hr, filtering, and drying the residue to obtain tea saponin-removed tea bran powder;
(2) mixing tea saponin-removed tea bran powder with distilled water, and mixing the mixture in a material-liquid ratio of 1: 7. extracting at 70 deg.C for 3 hr, centrifuging the extractive solution, collecting supernatant, and concentrating the supernatant to 20% of original volume by evaporation under reduced pressure;
(3) regulating the pH of the concentrated extract obtained in the step (2) to 4.5 by using dilute hydrochloric acid at room temperature, standing for 12 hours, and centrifuging to remove precipitates;
(4) preparing an ammonium sulfate/polyethylene glycol (PEG)2000 two-aqueous phase extraction system, wherein the mass fraction of ammonium sulfate is 15%, and the mass fraction of PEG2000 is 12%; extracting the extracting solution obtained in the step (3) for 50min by using the extracting system under the conditions of ultrasonic assistance, ultrasonic power of 200W and room temperature (20-30 ℃); and (4) after extraction is finished and the mixture is fully kept stand, taking the lower phase. The yield of the tea bran polysaccharide is measured to be 15.3%; the protein removal rate was 96%.
(5) Concentrating tea bran polysaccharide, dialyzing, desalting, purifying by DEAE cellulose column chromatography, and purifying with 0.05 mol.L-1Eluting with NaCl solution, collecting eluent, and concentrating to obtain the tea bran polysaccharide with the molecular weight of 5000-10000 Da.
Propionibacterium acnes lipase activity assay: the Propionibacterium acnes lipase activity was determined spectrophotometrically at 412nm after treating lipase with a 2% tea bran polysaccharide solution and reacting for 30 minutes using the lipase activity colorimetric assay kit II (England ). The experimental result shows that the lipase activity of the propionibacterium acnes is reduced by 28 percent. If the distilled water is used for elution, the obtained tea bran polysaccharide component has no obvious effect of reducing the activity of the acne propionibacterium lipase.
20 volunteers (volunteers who have relatively oily scalp and are screened out by a sebum test) are selected, and the average sebum secretion of the volunteers is reduced by 38% (P <0.005, with a significant difference) according to the scalp sebum secretion test result (increasing or decreasing percentage compared with 0 day) before and after 21 days by using the shampoo prepared in the embodiment.
Skin irritation test:
the skin irritation of the chemical is judged by detecting the cell activity through an MTT method, a PBS solution is used as a negative control, a 5% SLS aqueous solution of a typical skin irritant is used as a positive control, and in the embodiment, the cell survival rate is 81% which shows that the shampoo prepared by the invention has no skin irritation.
The maximum combing force of the prepared shampoo wet combing is measured to be 2.30N, and the maximum combing force of the dry combing is measured to be 0.35N.
The foam height was 148mm as measured by the foamability test.
Typical micrographs of scalp states (including scalp redness and pore grease accumulation) of volunteers before and after applying the shampoo of the invention are shown in fig. 1-2. The result shows that the accumulation amount of pore grease is obviously reduced after the volunteers use the shampoo, and the red (sensitive) condition of the scalp is improved.
According to the invention, the tea saponin is simultaneously used as a main surfactant and a main oil control agent of the shampoo, and is compounded with various other mild surfactants, namely coco glucoside, cocamidopropyl betaine and sodium lauroyl sarcosine, so that the problems of foam richness, stability, thickening difficulty and the like existing in the case of singly using the tea saponin are solved, the mildness of the shampoo is improved, the shampoo is suitable for scalp sensitive people, and the improvement effect on scalp sensitivity is achieved; by adding the eucalyptus extract, the folium artemisiae argyi extract and other auxiliary oil control components and the tea saponin for reasonable compounding and composition optimization, the oil control effect of the shampoo is enhanced. In addition, the conditioning agent (the composition of the tea bran polysaccharide, the sodium polyaspartate and the inulin) is adopted, so that the accumulation on the hair and the irritation on the scalp caused by the conventional single use of a cationic conditioning agent are avoided while the good combing property of the hair is ensured. Most of the prior shampoos adopt organosilicon compounds as a conditioning agent, or a sufficient amount of cationic conditioning agent is added, so that the mode easily generates an accumulation effect on hair, brings a heavy feeling, and is deposited on scalp to influence air permeability and generate scalp irritation. The invention discovers that when the tea bran polysaccharide is combined with the sodium polyaspartate with medium molecular weight and the inulin and the proportion is adopted, good combing property can be obtained under the condition that a conventional cationic conditioner is not added and an organic silicon conditioner is not needed, and heavy feeling, greasy feeling and irritating feeling caused by deposition of the cationic conditioner and the organic silicon conditioner on hair/scalp are avoided.
The preferable fat-endowing agent is a composition of tea tree oil and turmeric oil, and when the oily raw materials are mixed according to the proportion, the oily raw materials can be matched with each other and have synergistic effect with tea saponin and tea bran polysaccharide, so that the fat-endowing agent has the functions of improving anti-inflammatory and antibacterial effects and avoids the stimulation of excessive sebum secretion by microorganisms or inflammatory reaction. In addition, the above fat-imparting agent has an effect of improving the combing property. Meanwhile, the active ingredient zinc pyrrolidone carboxylate with the 5 alpha-reductase inhibition effect is added to be matched with the tea saponin and the tea bran polysaccharide, and meanwhile, the eucalyptus extract and the folium artemisiae argyi extract can synergistically enhance the inhibition effect on the 5 alpha-reductase activity, so that a multi-target oil control way is formed, and the oil control effect of the shampoo is enhanced.
Example 2:
the mild oil control shampoo composition suitable for sensitive scalp comprises the following components in percentage by mass: 7% of tea saponin, 4% of coco glucoside, 3% of cocamidopropyl betaine, 2% of sodium lauroyl sarcosinate, 0.5% of tea bran polysaccharide, 0.6% of sodium polyaspartate (molecular weight is 3000-5000), 0.3% of inulin, 0.5% of tea tree oil, 0.6% of turmeric oil, 0.6% of citric acid, 0.3% of lactic acid, 0.3% of zinc pyrrolidone carboxylate, 1.0% of eucalyptus leaf extract, 0.7% of folium artemisiae argyi extract, 1.50% of pentaerythritol tetrastearate, 0.3% of sodium benzoate, 0.1% of disodium ethylenediamine tetraacetic acid, a proper amount of essence and the balance of water, wherein the pH value of the shampoo is about 4.6.
Shampoo was prepared in the same manner as in example 1.
Testing results (percentage of increase or decrease compared to day 0) of scalp sebum secretion test before and after 21 days of 20 volunteers using the shampoo prepared in this example showed that average sebum secretion of the volunteers decreased by 34%.
Example 3:
the mild oil control shampoo composition suitable for sensitive scalp comprises the following components in percentage by mass (g: mL): 9% of tea saponin, 2% of coco glucoside, 3% of cocamidopropyl betaine, 2% of sodium lauroyl sarcosinate, 0.5% of tea bran polysaccharide (5000-10000 Da), 0.5% of sodium polyaspartate (molecular weight is 3000-5000 Da), 0.2% of inulin, 0.4% of tea tree oil, 0.6% of turmeric oil, 0.5% of citric acid, 0.4% of lactic acid, 0.3% of zinc pyrrolidone carboxylate, 0.6% of eucalyptus leaf extract (obtained by performing ethanol extraction on eucalyptus leaf powder at a material-liquid ratio of 1: 10 and 60 ℃ and then drying), 0.8% of folium artemisiae argyi extract (obtained by performing ethanol extraction on folium artemisiae argyi powder at a material-liquid ratio of 1: 10 and 70 ℃ and then drying), 1.75% of pentaerythritol tetrastearate, 0.3% of sodium benzoate, 0.1% of disodium ethylenediamine tetraacetate, a proper amount of essence, and the balance of water, wherein the pH value of the shampoo is about 4.6.
Comparative example 1:
the shampoo composition comprises the following components in percentage by mass: 8% of sodium laureth sulfate (AES), 3% of coco glucoside, 2% of cocamidopropyl betaine, 2% of sodium lauroyl sarcosinate, 0.4% of sodium polyaspartate (molecular weight is 3000-5000), 0.3% of Jerusalem artichoke inulin, 0.4% of tea tree oil, 0.4% of turmeric oil, 0.6% of citric acid, 0.3% of lactic acid, 0.3% of zinc pyrrolidone carboxylate, 0.8% of eucalyptus leaf extract, 0.5% of folium artemisiae argyi extract, 1.75% of pentaerythritol tetrastearate, 0.3% of sodium benzoate, 0.1% of disodium ethylene diamine tetraacetate, a proper amount of essence and the balance of water.
The preparation principle of the shampoo is the same as that of the example 1.
Test results (percentage of increase or decrease compared to day 0) of scalp sebum secretion test before and after 21 days using the shampoo prepared in this example were obtained in 20 volunteers, and the average sebum secretion of the volunteers was increased by 5%. The sodium laureth sulfate (AES) is used as a main surfactant and the tea saponin is not added, so that the oil control performance is poor.
Skin irritation test: the skin irritation of the chemical is judged by detecting the activity of the recombinant human epidermal model cells through an MTT method, the cell survival rate is measured to be 35% by taking a PBS solution as a negative control and taking a 5% SLS aqueous solution of a typical skin irritant as a positive control, and the fact that the shampoo prepared by taking AES as a main surfactant has certain skin irritation is shown.
Comparative example 2:
the shampoo composition comprises the following components in percentage by mass: 8% of tea saponin, 3% of sodium laureth sulfate, 2% of sodium cocoyl glutamate, 2% of sodium methyl cocoyl taurate, 0.5% of tea bran polysaccharide, 0.4% of sodium polyaspartate (molecular weight is 3000-5000), 0.3% of inulin, 0.4% of tea tree oil, 0.4% of turmeric oil, 0.6% of citric acid, 0.3% of lactic acid, 0.3% of zinc pyrrolidone carboxylate, 0.8% of eucalyptus leaf extract, 0.5% of folium artemisiae argyi extract, 1.75% of pentaerythritol tetrastearate, 0.3% of sodium benzoate, 0.1% of disodium ethylenediamine tetraacetic acid, a proper amount of essence and the balance of water.
The preparation principle of the shampoo is the same as that of the example 1.
Testing results (percentage of increase or decrease compared to day 0) of scalp sebum secretion test before and after 21 days of 20 volunteers using the shampoo prepared in this example, the average sebum secretion of the volunteers was decreased by 21%.
Skin irritation test: the skin irritation of the chemical is judged by detecting the cell activity by an MTT method, the cell survival rate is measured to be 48% by taking a PBS solution as a negative control and taking a 5% SLS aqueous solution of a typical skin irritant as a positive control, and the prepared shampoo has slight skin irritation.
Comparative example 3:
the shampoo composition comprises the following components in percentage by mass: 8% of tea saponin, 3% of coco glucoside, 2% of cocamidopropyl betaine, 2% of sodium lauroyl sarcosinate, 0.7% of polyquaternium-10, 0.4% of tea tree oil, 0.4% of curcuma oil, 0.6% of citric acid, 0.3% of lactic acid, 0.3% of zinc pyrrolidone carboxylate, 0.8% of eucalyptus leaf extract, 0.5% of folium artemisiae argyi extract, 1.75% of pentaerythritol tetrastearate, 0.3% of sodium benzoate, 0.1% of disodium ethylenediamine tetraacetic acid, a proper amount of essence and the balance of water.
The preparation principle of the shampoo is the same as that of the example 1.
The maximum combing force of the prepared shampoo wet combing is measured to be 2.25N, and the maximum combing force of the dry combing is measured to be 0.33N.
Comparative example 4:
the shampoo composition comprises the following components in percentage by mass: 8% of tea saponin, 3% of coco glucoside, 2% of cocamidopropyl betaine, 2% of sodium lauroyl sarcosinate, 0.5% of tea bran polysaccharide, 0.4% of sodium polyaspartate (molecular weight is 3000-5000), 0.3% of inulin, 0.4% of tea tree oil, 0.4% of turmeric oil, 0.6% of citric acid, 0.3% of lactic acid, 1.6% of folium artemisiae argyi extract, 1.75% of pentaerythritol tetrastearate, 0.3% of sodium benzoate, 0.1% of disodium edetate, a proper amount of essence and the balance of water.
The preparation principle of the shampoo is the same as that of the example 1.
Testing results (percentage of increase or decrease compared to day 0) of scalp sebum secretion test before and after 21 days in 20 volunteers using the shampoo prepared in this example, mean sebum secretion of volunteers decreased by 24% (P < 0.01).
Comparative example 5:
the shampoo composition comprises the following components in percentage by mass: 8% of tea saponin, 5% of coco glucoside, 1% of cocamidopropyl betaine, 1% of sodium lauroyl sarcosinate, 0.5% of tea bran polysaccharide, 0.4% of sodium polyaspartate (molecular weight is 3000-5000), 0.3% of inulin, 0.4% of tea tree oil, 0.4% of turmeric oil, 0.6% of citric acid, 0.3% of lactic acid, 0.3% of zinc pyrrolidone carboxylate, 0.8% of eucalyptus leaf extract, 0.5% of folium artemisiae argyi extract, 1.75% of pentaerythritol tetrastearate, 0.3% of sodium benzoate, 0.1% of disodium ethylenediamine tetraacetic acid, a proper amount of essence and the balance of water.
The preparation principle of the shampoo is the same as that of the example 1.
The foam height was 120mm as measured by the foamability test.
Comparative example 6:
the shampoo composition comprises the following components in percentage by mass: 5% of sodium laureth sulfate, 3% of tea saponin, 3% of coco glucoside, 2% of cocamidopropyl betaine, 2% of sodium lauroyl sarcosinate, 0.5% of tea bran polysaccharide, 0.4% of sodium polyaspartate (molecular weight is 3000-5000), 0.3% of Jerusalem artichoke inulin, 0.4% of tea tree oil, 0.4% of curcuma oil, 0.6% of citric acid, 0.3% of lactic acid, 0.3% of zinc pyrrolidone carboxylate, 0.8% of eucalyptus leaf extract, 0.5% of folium artemisiae argyi extract, 1.75% of pentaerythritol tetrastearate, 0.3% of sodium benzoate, 0.1% of disodium ethylenediamine tetraacetic acid, a proper amount of essence and the balance of water, wherein the pH value of the shampoo is about 4.6.
The preparation principle of the shampoo is the same as that of the example 1.
Testing results (percentage of increase or decrease compared to day 0) of scalp sebum secretion test before and after 21 days for 20 volunteers using the shampoo prepared in this example, the average sebum secretion of the volunteers decreased by 12%.
Comparative example 7:
the shampoo composition comprises the following components in percentage by mass: the shampoo comprises the components of, by weight, 3% of coco glucoside, 2% of cocamidopropyl betaine, 10% of sodium lauroyl sarcosinate, 0.5% of tea bran polysaccharide, 0.4% of sodium polyaspartate (molecular weight is 3000-5000), 0.3% of inulin, 0.4% of tea tree oil, 0.4% of curcuma oil, 0.6% of citric acid, 0.3% of lactic acid, 0.3% of zinc pyrrolidone carboxylate, 0.8% of eucalyptus leaf extract, 0.5% of folium artemisiae argyi extract, 1.75% of pentaerythritol tetrastearate, 0.3% of sodium benzoate, 0.1% of disodium ethylenediamine tetraacetic acid, a proper amount of essence, and the balance of water, wherein the pH value of the shampoo is about 4.65.
The preparation principle of the shampoo is the same as that of the example 1.
Testing results (percentage of increase or decrease compared to day 0) of scalp sebum secretion test before and after 21 days for 20 volunteers using the shampoo prepared in this example, the average sebum secretion of the volunteers decreased by 18% (P < 0.05).
Comparative example 8:
the shampoo composition comprises the following components in percentage by mass: 8% of tea saponin, 3% of coco glucoside, 2% of cocamidopropyl betaine, 2% of sodium lauroyl sarcosinate, 0.4% of tea tree oil, 0.4% of curcuma oil, 0.6% of salicylic acid, 0.3% of fruit acid, 0.3% of zinc pyrrolidone carboxylate, 0.8% of eucalyptus leaf extract, 0.5% of folium artemisiae argyi extract, 1.75% of pentaerythritol tetrastearate, 0.3% of sodium benzoate, 0.1% of disodium ethylene diamine tetraacetate, a proper amount of essence and the balance of water, wherein the pH value of the shampoo is about 4.5.
The preparation principle of the shampoo is the same as that of the example 1.
The maximum combing force of the prepared shampoo wet combing force is 2.76N, and the maximum combing force of the dry combing force is 0.52N.
Comparative example 9:
the shampoo composition comprises the following components in percentage by mass (g: mL): 12% of tea saponin, 3% of coco glucoside, 2% of cocamidopropyl betaine, 2% of sodium lauroyl sarcosinate, 0.5% of tea bran polysaccharide, 0.4% of sodium polyaspartate (molecular weight is 3000-5000), 0.3% of inulin, 0.4% of tea tree oil, 0.4% of turmeric oil, 0.6% of citric acid, 0.3% of lactic acid, 0.3% of zinc pyrrolidone carboxylate, 0.8% of folium eucalypti extract (obtained by performing ethanol extraction on folium eucalypti powder at the conditions of material-liquid ratio of 1: 10 and 60 ℃ and then drying), 0.5% of folium artemisiae argyi extract (obtained by performing ethanol extraction on folium artemisiae argyi powder at the conditions of material-liquid ratio of 1: 10 and 70 ℃ and then drying), 1.75% of pentaerythritol tetrastearate, 0.3% of sodium benzoate, 0.1% of disodium ethylenediamine tetraacetate, a proper amount of essence, and the balance of water, wherein the pH value of the shampoo is about 4.5. The preparation principle of the shampoo is the same as that of the example 1.
The foam height was found to be 131mm by the foamability test.
Experimental results show that a certain amount of skin irritation is generated when the tea saponin is excessively added, the synergistic effect of other surface activity and oil control agents is covered, and the oil control and combing performance is reduced.
The test method comprises the following steps:
oil control performance: the scalp sebum secretion test results (percentage of increase or decrease compared to day 0) were tested in 20 volunteers before and after 21 days using the shampoo prepared in each example. The volunteers need to sit still for 20min in a room with constant temperature of (20 +/-1) DEG C and constant humidity of 50 percent, and then scalp grease test is carried out. The scalp grease test is based on the principle of a grease test photometer and is a method for testing skin grease
The two ends of an adhesive tape strip used in the method are folded and fixed on a grease probe, the probe is pressed and contacted with a scalp to-be-tested part for 30s in a constant-temperature and constant-humidity environment, the transparency of the test adhesive tape is changed by grease on the scalp, a light transmittance distribution curve on the adhesive tape can be tested by a photoelectric tube in an instrument, the peak value of the light transmittance distribution curve represents the content of the grease on the scalp, and three parallel data are taken to obtain an average value.
Skin irritation test: EpiSkinTMRecombinant human epidermis model: the culture plate with skin tissue was placed at 37. + -. 1 ℃ and 5. + -. 1% CO2And (3) culturing for 24 hours in an incubator with 95% relative humidity. Each sample was run in parallel with 3 tissue models, each tissue was given 10. mu.L of sample fluid, 10. mu.L of PBS negative, 10. mu.L of 5% SLS positive, and the tissue was rinsed with 25mL of PBS by pipetting with a continuous sample gun after 15min exposure at room temperature. Will cultivateThe plates were continued to be cultured in the incubator for 42 h. Take 0.3 mg. mL-1The model was placed in a 12-well plate, and 2mL of MTT solution was added to each well, and the solution was incubated in an incubator for 3 hours. After the culture is finished, the epidermal tissue sample block is taken down by a puncher, turned over, transferred to a centrifugal microtube, added with 0.5mL of acid isopropanol, shaken and uniformly mixed on a vortex machine, and kept standing overnight at room temperature in a dark place. For each tissue, 2 aliquots of 200 μ L of the solution were pipetted in parallel into a 96-well plate and the MTT assay results were analyzed using acidic isopropanol as a blank and reading the optical density values at a wavelength of 570 nm. If the survival rate of the epidermal tissue is less than or equal to 50% of that of the control group, the sample is irritant; if the survival rate of epidermal tissue is greater than 50% of that of the control group, the sample is non-irritant.
And (3) testing the foamability: measurements were made according to GB/T7462-94. 2g of a sample was placed in a 800mL beaker, and 80g of standard hard water (hardness: 0.342g/L in terms of calcium carbonate) and 718g of deionized water were added thereto, and the temperature was raised to 40 ℃ while opening a constant temperature water bath so that the temperature of the water was stabilized at 40 ℃. The inner wall of the test tube was rinsed 3 times with deionized water and the solution to be tested in that order. The piston is in a closed state, 50mL of liquid to be tested is carefully removed, the liquid level is aligned with 50mL of scale marks of the testing tube, and foam is avoided. A pipette is used to aspirate 200mL of the test solution and the pipette is placed in the holder so that the cross section of the pipette and the test tube is at 90 °. The pipette piston is rapidly in a completely opened state, and the liquid to be measured is ensured to vertically and naturally flow down. And immediately reading the instantaneous foam height when the liquid to be detected is completely discharged.
Half-head test: the half-head test was performed on 20 volunteers, and 20 volunteers were each subjected to sensory evaluation using shampoos prepared in different embodiments, and the half-head test was performed by simultaneously washing two shampoos in the left and right half-heads during hair washing, and simultaneously feeling different feelings during and after hair washing. The experimental result is an integer.
Table 1: half-head test evaluation index
Table 2: evaluation score results of five shampoos
| Evaluation index | Example 1 | Comparative example 1 | Comparative example 3 | Comparative example 8 | Comparative example 9 |
| Without heaviness | 5 | 3 | 4 | 5 | 5 |
| No itching or irritation | 5 | 3 | 2 | 2 | 4 |
| Smooth feeling during hair drying | 4 | 4 | 4 | 3 | 3 |
| Has no greasy feeling | 5 | 2 | 3 | 4 | 3 |
It should be noted that the above-mentioned embodiments are only for illustrating the technical solutions of the present invention and not for limiting, and although the present invention has been described in detail with reference to the preferred embodiments, it should be understood by those skilled in the art that modifications or equivalent substitutions may be made on the technical solutions of the present invention without departing from the spirit and scope of the technical solutions of the present invention, which should be covered by the claims of the present invention.
Claims (10)
1. A mild oil control shampoo composition suitable for sensitive scalp is characterized in that: the oil-soluble tea saponin comprises, by mass, 6-9% of tea saponin, 2-5% of coco-oil glucoside, 1-4% of cocamidopropyl betaine, 1-5% of sodium lauroyl sarcosinate, 0.5-1.5% of a conditioner, 0.5-1.5% of a fatting agent, 0.5-2.0% of an auxiliary oil control additive, 0.5-2.0% of a cuticle softener, 1.5-2% of a thickener and the balance of water.
2. A mild oil control shampoo composition suitable for application to sensitive scalp according to claim 1 wherein: the content of the tea saponin is 7-8%; the content of the coco glucoside is 3-4%; the content of the cocamidopropyl betaine is 2-3%; the content of the sodium lauroyl sarcosinate is 2-3%.
3. A mild oil control shampoo composition suitable for application to sensitive scalp according to claim 1 or claim 2 wherein: the conditioner consists of 0.5-0.6% of tea bran polysaccharide, 0.4-0.6% of sodium polyaspartate and 0.3-0.4% of inulin; the tea bran polysaccharide has the molecular weight of 5000-10000 Da.
4. A mild oil control shampoo composition suitable for application to sensitive scalp according to claim 3 wherein: the molecular weight of the polyaspartic acid sodium is 3000-5000.
5. A mild oil control shampoo composition suitable for application to sensitive scalp according to claim 1 or claim 2 wherein: the fat-liquoring agent consists of 0.4-0.5% of tea tree oil and 0.4-0.6% of turmeric oil.
6. A mild oil control shampoo composition suitable for application to sensitive scalp according to claim 1 or claim 2 wherein: the auxiliary oil control additive consists of 0.3% of zinc pyrrolidone carboxylate, 0.8-1.0% of eucalyptus leaf extract and 0.5-0.7% of folium artemisiae argyi extract.
7. A mild oil control shampoo composition suitable for application to sensitive scalp according to claim 1 or claim 2 wherein: the cuticle softener consists of 0.5-0.6% of citric acid and 0.3-0.4% of lactic acid; the thickening agent is 1.25-2.0% of pentaerythritol tetrastearate.
8. A mild oil control shampoo composition suitable for application to sensitive scalp according to claim 1 or claim 2 wherein: also comprises 0.1 percent of disodium ethylene diamine tetraacetate and essence.
9. A method of preparing a mild oil control shampoo composition for sensitive scalp according to claim 8 wherein: adding deionized water into a main pot, adding tea bran polysaccharide, sodium polyaspartate, inulin and ethylene diamine tetraacetic acid serving as composite conditioners, quickly stirring to enable the composite conditioners to be swelled and fully dissolved, adding tea saponin, coco glucoside, cocamidopropyl betaine, sodium lauroyl sarcosinate and pentaerythritol tetrastearate, heating to 70-75 ℃, and keeping stirring until the mixture is completely dissolved; then cooling to 50-55 ℃ while stirring, slowly adding the tea tree oil, the turmeric oil, the zinc pyrrolidone carboxylate, the eucalyptus leaf extract and the folium artemisiae argyi extract into the main pot, controlling the stirring speed at 40-50 revolutions per minute, stirring for 30-40 minutes, and cooling; and (3) cooling to 40-50 ℃, adding sodium benzoate, citric acid, lactic acid and essence, continuously stirring for 30-40 minutes, and discharging when the temperature is reduced to below 35 ℃.
10. A method of preparing a mild oil control shampoo composition for sensitive scalp according to claim 9 wherein: the extraction method of the tea saponin comprises the following steps: taking degreased oil tea bran, wherein the material-liquid ratio is 1: 7-8, extracting for 2-3 h at the temperature of 60-70 ℃, filtering and separating an extracting solution, evaporating and concentrating to obtain 20-30% of the original volume, and mixing the concentrated solution: the volume ratio of ethanol is 1: adding 85-95% ethanol under 4-5 conditions, stirring, performing centrifugal separation to obtain an ethanol extract, and drying to obtain a crude product of tea saponin; further purifying the crude product of the tea saponin by using AB-8 type macroporous resin, and eluting by using 80% ethanol solution to obtain the purified tea saponin with the purity of more than 90%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010849481.9A CN111991261B (en) | 2020-08-21 | 2020-08-21 | Mild oil control shampoo composition suitable for sensitive scalp and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010849481.9A CN111991261B (en) | 2020-08-21 | 2020-08-21 | Mild oil control shampoo composition suitable for sensitive scalp and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN111991261A true CN111991261A (en) | 2020-11-27 |
| CN111991261B CN111991261B (en) | 2021-10-08 |
Family
ID=73473633
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010849481.9A Active CN111991261B (en) | 2020-08-21 | 2020-08-21 | Mild oil control shampoo composition suitable for sensitive scalp and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111991261B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115475126A (en) * | 2022-09-21 | 2022-12-16 | 广州德谷个人护理用品有限公司 | Composition with oil control and relieving effects and application thereof |
| CN115919677A (en) * | 2022-11-15 | 2023-04-07 | 广州德谷个人护理用品有限公司 | Hair washing and caring composition for slowing hair fading after hair dyeing and application thereof |
| CN116035955A (en) * | 2022-12-28 | 2023-05-02 | 寒霜籽(上海)生物科技有限公司 | Quick-absorption skin-care hair-care dual-purpose oil based on camellia seed oil |
| CN116492259A (en) * | 2023-05-11 | 2023-07-28 | 广州希海生物科技有限公司 | Mild plant surfactant and application thereof in shampoo |
Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060286062A1 (en) * | 2005-06-06 | 2006-12-21 | Schep Raymond A | Completely natural plant based shampoo and body wash devoid of synthetic ingredients |
| CN102716044A (en) * | 2012-07-03 | 2012-10-10 | 澳宝化妆品（惠州）有限公司 | Low-stimulation hair-cleaning compound |
| CN102993329A (en) * | 2012-12-31 | 2013-03-27 | 广西师范大学 | Method for comprehensively extracting saponin, polysaccharides and polyphenol from camellia oleifera abel defatted cakes |
| US20130130329A1 (en) * | 2009-06-10 | 2013-05-23 | Heng-Jui Hsu | Method for extracting substances from soapberry fruit and its seeds |
| CN103349621A (en) * | 2013-07-15 | 2013-10-16 | 澳宝化妆品（惠州）有限公司 | Washing and protecting combination low in excitation and good in flexibility |
| CN104921989A (en) * | 2015-06-12 | 2015-09-23 | 广州环亚化妆品科技有限公司 | Liquid shampoo without silicon oil and with hair caring effect and preparation method thereof |
| CN107375028A (en) * | 2017-07-31 | 2017-11-24 | 广州道明研究院有限公司 | A kind of non-stimulated no silicon shampoo and preparation method thereof |
| CN108096173A (en) * | 2017-12-28 | 2018-06-01 | 广州蜜妆生物科技有限公司 | Mild amino acid shampoo of a kind of green and preparation method thereof |
| CN108904392A (en) * | 2018-09-18 | 2018-11-30 | 广西壮族自治区农业科学院农产品加工研究所 | A kind of Tea Saponin shampoo and preparation method thereof |
| CN109381363A (en) * | 2018-12-20 | 2019-02-26 | 广州艾蓓生物科技有限公司 | A kind of amino acid shampoo and preparation method thereof |
| CN109806213A (en) * | 2019-04-01 | 2019-05-28 | 贵州阿斯科科技开发有限公司 | A kind of Chinese medicinal plant desquamation compositions, botanical hair shampoo and preparation method thereof |
| CN111214414A (en) * | 2019-12-30 | 2020-06-02 | 周健 | Shampoo containing tea bran and preparation method thereof |
| CN111419762A (en) * | 2020-06-02 | 2020-07-17 | 广州德谷个人护理用品有限公司 | Tea bran silicone oil-free shampoo and preparation method thereof |
-
2020
- 2020-08-21 CN CN202010849481.9A patent/CN111991261B/en active Active
Patent Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060286062A1 (en) * | 2005-06-06 | 2006-12-21 | Schep Raymond A | Completely natural plant based shampoo and body wash devoid of synthetic ingredients |
| US20130130329A1 (en) * | 2009-06-10 | 2013-05-23 | Heng-Jui Hsu | Method for extracting substances from soapberry fruit and its seeds |
| CN102716044A (en) * | 2012-07-03 | 2012-10-10 | 澳宝化妆品（惠州）有限公司 | Low-stimulation hair-cleaning compound |
| CN102993329A (en) * | 2012-12-31 | 2013-03-27 | 广西师范大学 | Method for comprehensively extracting saponin, polysaccharides and polyphenol from camellia oleifera abel defatted cakes |
| CN103349621A (en) * | 2013-07-15 | 2013-10-16 | 澳宝化妆品（惠州）有限公司 | Washing and protecting combination low in excitation and good in flexibility |
| CN104921989A (en) * | 2015-06-12 | 2015-09-23 | 广州环亚化妆品科技有限公司 | Liquid shampoo without silicon oil and with hair caring effect and preparation method thereof |
| CN107375028A (en) * | 2017-07-31 | 2017-11-24 | 广州道明研究院有限公司 | A kind of non-stimulated no silicon shampoo and preparation method thereof |
| CN108096173A (en) * | 2017-12-28 | 2018-06-01 | 广州蜜妆生物科技有限公司 | Mild amino acid shampoo of a kind of green and preparation method thereof |
| CN108904392A (en) * | 2018-09-18 | 2018-11-30 | 广西壮族自治区农业科学院农产品加工研究所 | A kind of Tea Saponin shampoo and preparation method thereof |
| CN109381363A (en) * | 2018-12-20 | 2019-02-26 | 广州艾蓓生物科技有限公司 | A kind of amino acid shampoo and preparation method thereof |
| CN109806213A (en) * | 2019-04-01 | 2019-05-28 | 贵州阿斯科科技开发有限公司 | A kind of Chinese medicinal plant desquamation compositions, botanical hair shampoo and preparation method thereof |
| CN111214414A (en) * | 2019-12-30 | 2020-06-02 | 周健 | Shampoo containing tea bran and preparation method thereof |
| CN111419762A (en) * | 2020-06-02 | 2020-07-17 | 广州德谷个人护理用品有限公司 | Tea bran silicone oil-free shampoo and preparation method thereof |
Non-Patent Citations (3)
| Title |
|---|
| FU, GUIMING等: ""Screening of tea saponin-degrading strain to degrade the residual tea saponin in tea seed cake"", 《PREPARATIVE BIOCHEMISTRY & BIOTECHNOLOGY》 * |
| 段新芳: "《中国林业循环经济发展研究》", 31 October 2016, 中国建材工业出版社 * |
| 陶莉 等: ""茶皂素有机硅季铵盐的合成及其在洗发香波中的应用"", 《日用化学工业》 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115475126A (en) * | 2022-09-21 | 2022-12-16 | 广州德谷个人护理用品有限公司 | Composition with oil control and relieving effects and application thereof |
| CN115475126B (en) * | 2022-09-21 | 2023-11-28 | 广州德谷个人护理用品有限公司 | Composition with oil control and relieving effects and application thereof |
| CN115919677A (en) * | 2022-11-15 | 2023-04-07 | 广州德谷个人护理用品有限公司 | Hair washing and caring composition for slowing hair fading after hair dyeing and application thereof |
| CN115919677B (en) * | 2022-11-15 | 2024-06-25 | 广州澳谷化妆品制造有限公司 | Hair washing and caring composition for relieving hair fading after dyeing and application thereof |
| CN116035955A (en) * | 2022-12-28 | 2023-05-02 | 寒霜籽(上海)生物科技有限公司 | Quick-absorption skin-care hair-care dual-purpose oil based on camellia seed oil |
| CN116035955B (en) * | 2022-12-28 | 2024-10-18 | 寒霜籽(上海)生物科技有限公司 | Quick-absorption skin-care hair-care dual-purpose oil based on camellia seed oil |
| CN116492259A (en) * | 2023-05-11 | 2023-07-28 | 广州希海生物科技有限公司 | Mild plant surfactant and application thereof in shampoo |
Also Published As
| Publication number | Publication date |
|---|---|
| CN111991261B (en) | 2021-10-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN111991261B (en) | Mild oil control shampoo composition suitable for sensitive scalp and preparation method thereof | |
| EP3261611B1 (en) | Composition comprising rhamnolipid and siloxane | |
| CN111991303B (en) | Plant extract composition with multi-target scalp oil control and dandruff removal effects, preparation method thereof and scalp care composition | |
| CN106309280B (en) | A kind of Ginger P.E and its preparation method and application | |
| CN110960434B (en) | Scalp care shampoo composition and preparation method thereof | |
| CN108125870B (en) | Scalp nourishing composition, preparation method and application thereof, and scalp nourishing shampoo | |
| CN111909284B (en) | Extraction and purification method of tea bran polysaccharide and scalp care composition containing tea bran polysaccharide | |
| CN109394624A (en) | A kind of plant-nursing composition and its preparation method and application | |
| CN112006954A (en) | Shampoo and preparation method thereof | |
| CN106236676B (en) | Plant composition with anti-aging effect and application thereof | |
| KR102029078B1 (en) | Novel oligosaccharide compounds and the cosmetic use thereof | |
| FR2957923A1 (en) | NOVEL HALYMENIA DURVILLEI EXTRACT, PROCESS FOR PREPARING SUCH EXTRACT AND COSMETIC USE THEREOF | |
| JP2000053533A (en) | Ceramide synthesis-promoting agent and cosmetic, quasi- drug and preparation for external use for skin containing the same ceramide synthesis-promoting agent | |
| CN117159403A (en) | Oil-control fluffy composition and preparation method and application thereof | |
| CN109908061B (en) | Anti-dandruff shampoo rich in foam and preparation method thereof | |
| CN106727255B (en) | Shampoo containing natural surfactant and preparation method thereof | |
| CN111920726B (en) | Multi-effect quick scalp itching relieving composition, preparation method thereof and shampoo composition | |
| CN112426391B (en) | Chitosan nourishing and skin moistening shower gel and preparation method thereof | |
| CN114306146A (en) | Shampoo containing combination of anti-dandruff and anti-hair loss active ingredients | |
| JP6521211B2 (en) | Activator containing cellobiose lipid as an active ingredient | |
| CN112022756A (en) | Shower gel containing ganoderma lucidum sporophore spore powder fermentation liquid and preparation method thereof | |
| CN105963218A (en) | Shower gel containing brassica extract | |
| CN111317704A (en) | Whitening skin care composition containing pearl extract and preparation method thereof | |
| CN111888295A (en) | Plant-source antioxidant bacteriostatic environment-friendly hand sanitizer and preparation method thereof | |
| CN110755347A (en) | Skin moistening humectant and preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |