CN105616292B

CN105616292B - Tea Saponin shampoo containing Chinese medical extract and preparation method thereof

Info

Publication number: CN105616292B
Application number: CN201610079343.0A
Authority: CN
Inventors: 李海涛; 赵其秀; 陈卫卫
Original assignee: Nine Shanghai (shanghai) Biological Science And Technology Co Ltd
Current assignee: Nine Shanghai (shanghai) Biological Science And Technology Co Ltd
Priority date: 2016-02-03
Filing date: 2016-02-03
Publication date: 2019-03-12
Anticipated expiration: 2036-02-03
Also published as: CN105616292A

Abstract

The invention discloses a kind of Tea Saponin shampoo and preparation method thereof containing Chinese medical extract, substance including following weight ratio: Semen Sesami Nigrum extract 0.1-1%, ginkgo biloba p.e 0.2-1%, surfactant 20.15-24.1%, silicone emulsion 1.8-1.9%, cation guar gum 0.35-0.4%, NaCl 0.35-0.4%, EDTA 0.05-0.15%, magnesium stearate 0.05-0.15%, propylene glycol 1.45-1.5%, ethyl-para-hydroxybenzoate 0.05-0.15%, deionized water surplus.The present invention is by ginkgo biloba p.e, Semen Sesami Nigrum extract and surfactant system are added in shampoo, scientific matching, the effect of each active constituent can not only preferably be played, it can also act synergistically, so that effect doubles, it can rapidly permeate into scalp, diastole scalp capillary, promote absorption of nutrient ingredients, consolidate root of hair, inhibit trichomadesis, promote hair regeneration, reach Anti-hair loss, anti-dandruff and itching-relieving, hair care, the purpose of hair care, hair and fur suitable for various characteristics, without allergic reaction after use, it has no toxic side effect, and it is quick, generating and nourishing hair effect is good.

Description

Tea Saponin shampoo containing Chinese medical extract and preparation method thereof

Technical field

The present invention relates to a kind of shampoo and preparation method thereof containing Chinese medical extract, it is specific to contain traditional Chinese medicine extraction to be a kind of Tea Saponin shampoo of object and preparation method thereof.

Background technique

Through the ages, hair not only plays an important role in the instrument appearance of people, while from the perspective of Chinese medicine, It is the important indicator of human health status.However, the quickening of modern life rhythm and the increase of life stress are so that alopecia, hair The disease incidence of withered and yellow equal hairs disease is also higher and higher, brings more and more puzzlements to the life of modern.Hair quality is bad Or the unhealthy emotions such as alopecia not only influences beauty, and the generation at heart of patient can also be made to feel oneself inferior, depression, thus to work, life and Social activity etc. causes the influence differed in size.Therefore, the research and development of anti-hair loss products more and more by world's medicine with The attention of cosmetics circle.

Alopecia can be divided into alopecia seborrheica, sending alopecia early, alopecia areata, whole alopecia, general alopecia and postpartum alopecia etc. by its symptom.But It is alopecia no matter what type, the main reason is that causing hair follicle nutritional deficiency due to blood circulation disorder, causes to send out Silk is malnutritive, trophic disturbance, can not provide enough nutrition to hair follicle, cause hair follicle that can not take the photograph to live hair admittedly, finally lead Cause epilation.

The shampoo prevented hair loss at present be also it is dazzling, it is of all shapes and colors, but effect is not ideal, give user Bring very big pain.Wherein, most products be all by various chemically synthesized surfactants and chemically synthesized fungicide, The composition such as pearling agent, essence.Excessive surfactant is used for a long time, the excessive degreasing of scalp can be caused, harmful substance remains, into And scalp root of hair is caused to expand, irritation itch, repiece scurf are generated, so that alopecia, baldness and hair quality damage be further aggravated.

Summary of the invention

Goal of the invention: the purpose of the invention is to providing a kind of safety, efficiently, what is be more beneficial to health contains The Tea Saponin shampoo of medicament extract.

Technical solution: the Tea Saponin shampoo of the present invention containing Chinese medical extract, the substance including following weight ratio:

In order to further solve the above problems, the surfactant includes nonionic surface active agent, it is described it is non-from Subtype surfactant includes 6501 1.8-1.9% and Tea Saponin 3-6.5%.

In order to further solve the above problems, the surfactant includes anionic surfactant, the anion Surfactant includes AES 8.3-8.4%, K12-Na 2.7-2.8% and MES 1.45-1.5%.

In order to further solve the above problems, the surfactant includes zwitterionic surfactant, the both sexes Ionic surface active agent includes CAB 1.45-1.5%.

In order to further solve the above problems, the surfactant includes cationic surfactant, the cation Surfactant includes LAO 1.45-1.5%.

Surfactant uses the system of a variety of surfactant compounds.By the system foam of these surfactant compounds It is abundant, it can moderately clean, degreasing power is not strong, and will not stimulate scalp.The Tea Saponin wherein added, it is a kind of function admirable Natural nonionic surface active agent has good emulsification, foaming, dispersion, infiltration, lubrication isoreactivity effect；With other tables Face activating agent is used in compounding, and system dirt-removing power is remarkably reinforced.In addition, Tea Saponin also has antibacterial anti-inflammatory, anti-dandruff and itching-relieving and washes Hair hair care multiple activities.Tea Saponin is added in shampoo, not only can be reduced the use of synthetic surfactant, but also will not weaken The dirt-removing power of shampoo, moreover it is possible to which anti-dandruff and itching-relieving protects scalp, hairy root nourishing.

In order to further solve the above problems, comprising the following steps:

(1) deionized water is added in stirring container, heats up 80-85 DEG C, AES and K12-Na is added, stirring makes its mixing Uniformly, MES, EDTA, 6501, cation guar gum and silicone emulsion are then added, continues stirring to being completely dissolved；

(2) it is cooled to 70-78 DEG C, Tea Saponin, CAB, LAO and propylene glycol is added, stirs evenly；Semen sesami nigrum is added later Extract and ginkgo biloba p.e, stir evenly；

(3) cool down 40-50 DEG C, magnesium stearate, NaCl, ethyl-para-hydroxybenzoate and deionized water be added, continues to stir, Make its dilution fusion to get.

In order to further solve the above problems, the Semen Sesami Nigrum extract is made by following methods: Semen sesami nigrum is rushed with water It cleans, is later 30-60% ethyl alcohol circumfluence distillation 0.5-3h under the conditions of 60-70 DEG C with concentration, the dosage of ethyl alcohol is black sesame Residue is abandoned in 45-65 times of numb quality, filtering, depressurize under conditions of being 0.1MPa in 50-60 DEG C and pressure by filtrate dense Contracting, obtains Semen Sesami Nigrum extract.

The Semen Sesami Nigrum extract that this method obtains can promote tyrosinase to express, and the synthetic quantity of melanin is improved, So that hair becomes more pitch-black glossy；In addition to this, white hair also can become again pitch-black, play the work of black hair profit hair With.

In order to further solve the above problems, the ginkgo biloba p.e is made by following methods: ginkgo leaf is cleaned, 55-75 DEG C of drying crushed 20 meshes later, obtain ginkgo leaf fragment；Then it repeats ginkgo leaf fragment under the conditions of 70 DEG C With 70% ethanol solution circumfluence distillation 5-8 times, the dosage of 70% ethanol solution is 4-8 times of Ginkgo Leaf weight, later The filtrate extracted every time is merged, residue is abandoned in filtering, depressurize under conditions of being 0.1MPa in 55 DEG C and pressure by filtrate dense Contracting, ethyl alcohol recycling, obtains ginkgo biloba p.e.

It is rich in flavone compound in ginkgo biloba p.e, there is anti-oxidant, removing superfluous free radical, expansion blood in vivo Pipe increases blood volume, improves the effect of cerebral artery and blood flow of the tip, while having and promoting hair raw.Ginkgo is added in shampoo After leaf extract, effective component acts on scalp surface, makes scalp surface relaxation, so as to make the tip blood capillary of papilla The effect of flow of pipe increases, and generates Anti-hair loss.

The utility model has the advantages that ginkgo biloba p.e, Semen Sesami Nigrum extract and surfactant system are added to hair washing by the present invention In water, scientific matching, the effect of can not only preferably playing each active constituent, moreover it is possible to it acts synergistically, so that effect doubles, it can Scalp is rapidly permeated into, diastole scalp capillary promotes absorption of nutrient ingredients, consolidates root of hair, inhibits trichomadesis, promotes hair Regeneration, reaches the purpose of Anti-hair loss, anti-dandruff and itching-relieving, hair care, hair care, suitable for the hair and fur of various characteristics, nothing after use Allergic reaction has no toxic side effect, and quick, and generating and nourishing hair effect is good.Hair amount is used for a long time to increase, root of hair is solid, hair It is pitch-black glossy, high resilience.Preparation process is simple to operate, is suitable for large-scale production.

Specific embodiment

In order to deepen the understanding of the present invention, the present invention will be described in further detail with reference to the examples below, these implementations Example for explaining only the invention, is not intended to limit the scope of the present invention..

Embodiment 1

Tea Saponin shampoo containing Chinese medical extract is by the material composition of following percentage:

Semen Sesami Nigrum extract 0.55%

Ginkgo biloba p.e 0.6%

AES 8.38%

K12-Na 2.75%

MES 1.48%

6501 1.86%

Tea Saponin 5%

CAB 1.48%

LAO 1.48%

Silicone emulsion 1.86%

Cation guar gum 0.37%

Nacl 0.37%

EDTA 0.1%

Magnesium stearate 0.1%

Propylene glycol 1.48%

Ethyl-para-hydroxybenzoate 0.1%

Deionized water surplus.

The preparation method of Semen Sesami Nigrum extract: Semen sesami nigrum is rinsed with water completely, is later 50% ethyl alcohol in 65 with concentration Circumfluence distillation 1h under the conditions of DEG C, the dosage of 50% ethyl alcohol are 50 times of Semen sesami nigrum quality, and filtering abandons residue, by filtrate in 55 DEG C and pressure be 0.1MPa under conditions of be concentrated under reduced pressure, ethyl alcohol recycling, obtain Semen Sesami Nigrum extract.

The preparation method of ginkgo biloba p.e: ginkgo leaf is cleaned, and 60 DEG C of dryings crushed 20 meshes later, obtain silver Apricot leaf fragment；Then it repeats ginkgo leaf fragment under the conditions of 70 DEG C with 70% ethanol solution circumfluence distillation 6 times, 70% ethyl alcohol The dosage of solution is 6 times of Ginkgo Leaf weight, later merges the filtrate extracted every time, and residue is abandoned in filtering, by filtrate in 55 DEG C and pressure are concentrated under reduced pressure under conditions of being 0.1MPa, and ethyl alcohol recycling obtains ginkgo biloba p.e.

The method of the above-mentioned Tea Saponin shampoo containing Chinese medical extract, method includes the following steps:

(1) deionized water of 3/4 total amount is added in stirring container, is warming up to 85 DEG C, AES and K12-Na is added, sufficiently Stirring is uniformly mixed it, then adds MES, EDTA, 6501, cation guar gum and silicone emulsion, continues stirring extremely It is completely dissolved；

(2) temperature is down to 75 DEG C, and Tea Saponin, CAB, LAO and propylene glycol is added, stirs evenly；It sequentially adds later black Seed of Sesamum indicum L. extract and ginkgo biloba p.e, stir evenly；

(3) temperature is down to 45 DEG C, and going for magnesium stearate, Nacl, ethyl-para-hydroxybenzoate and remaining 1/4 total amount is added Ionized water then proceedes to stir, and after so that it is sufficiently diluted fusion, obtains the Tea Saponin shampoo containing Chinese medical extract.

Embodiment 2

Tea Saponin shampoo containing Chinese medical extract is by following material composition:

Semen Sesami Nigrum extract 0.1%

Ginkgo biloba p.e 0.2%

AES 8.3%

K12-Na 2.7%

MES 1.45%

6501 1.8%

Tea Saponin 3%

CAB 1.45%

LAO 1.45%

Silicone emulsion 1.8%

Cation guar gum 0.35%

NaCl 0.35%

EDTA 0.05%

Magnesium stearate 0.05%

Propylene glycol 1.45%

Ethyl-para-hydroxybenzoate 0.05%

Ion water surplus.

The preparation method of Semen Sesami Nigrum extract: Semen sesami nigrum is rinsed with water completely, is later 30% ethyl alcohol in 60 with concentration Circumfluence distillation 3h under the conditions of DEG C, the dosage of 30% ethyl alcohol are 45 times of Semen sesami nigrum quality, and filtering abandons residue, by filtrate in 60 DEG C and pressure be 0.1MPa under conditions of be concentrated under reduced pressure, ethyl alcohol recycling, obtain Semen Sesami Nigrum extract.

The ginkgo biloba p.e is made by following methods: ginkgo leaf being cleaned, 55 DEG C of dryings crushed 20 mesh later Sieve, obtains ginkgo leaf fragment；Then repeat by ginkgo leaf fragment under the conditions of 70 DEG C with 70% ethanol solution circumfluence distillation 5 Secondary, the dosage of 70% ethanol solution is 4 times of Ginkgo Leaf weight, later merges the filtrate extracted every time, and filtering is abandoned residual Slag is concentrated under reduced pressure under conditions of being 0.1MPa in 55 DEG C and pressure by filtrate, and ethyl alcohol recycling obtains ginkgo biloba p.e.

(1) deionized water of 3/4 total amount is added in stirring container, is warming up to 80 DEG C, AES and K12-Na is added, sufficiently Stirring is uniformly mixed it, then adds MES, EDTA, 6501, cation guar gum and silicone emulsion, continues stirring extremely It is completely dissolved；

(2) temperature is down to 70 DEG C, and Tea Saponin, CAB, LAO and propylene glycol is added, stirs evenly；It sequentially adds later black Seed of Sesamum indicum L. extract and ginkgo biloba p.e, stir evenly；

(3) temperature is down to 50 DEG C, and going for magnesium stearate, Nacl, ethyl-para-hydroxybenzoate and remaining 1/4 total amount is added Ionized water then proceedes to stir, and after so that it is sufficiently diluted fusion, obtains the Tea Saponin shampoo containing Chinese medical extract.

Embodiment 3

The wherein mass percentage that each component uses are as follows:

Semen Sesami Nigrum extract 1%

Ginkgo biloba p.e 1%

AES 8.4%

K12-Na 2.8%

MES 1.5%

6501 1.9%

Tea Saponin 6.5%

CAB 1.5%

LAO 1.5%

Silicone emulsion 1.9%

Cation guar gum 0.4%

NaCl 0.4%

EDTA 0.15%

Magnesium stearate 0.15%

Propylene glycol 1.5%

Ethyl-para-hydroxybenzoate 0.15%

Deionized water surplus.

The preparation method of Semen Sesami Nigrum extract: Semen sesami nigrum is rinsed with water completely, is later 60% ethyl alcohol in 70 with concentration Circumfluence distillation 1h under the conditions of DEG C, the dosage of 60% ethyl alcohol are 65 times of Semen sesami nigrum quality, and filtering abandons residue, by 60 DEG C of filtrate It is concentrated under reduced pressure under conditions of being 0.1MPa with pressure, ethyl alcohol recycling obtains Semen Sesami Nigrum extract.

The preparation method of ginkgo biloba p.e: ginkgo leaf is cleaned, and 75 DEG C of dryings crushed 20 meshes later, obtain silver Apricot leaf fragment；Then it repeats ginkgo leaf fragment under the conditions of 70 DEG C with 70% ethanol solution circumfluence distillation 8 times, 70% ethyl alcohol The dosage of solution is 8 times of Ginkgo Leaf weight, later merges the filtrate extracted every time, and residue is abandoned in filtering, by filtrate in 55 DEG C and pressure are concentrated under reduced pressure under conditions of being 0.1MPa, and ethyl alcohol recycling obtains ginkgo biloba p.e.

(2) temperature is down to 78 DEG C, and Tea Saponin, CAB, LAO and propylene glycol is added, stirs evenly；It sequentially adds later black Seed of Sesamum indicum L. extract and ginkgo biloba p.e, stir evenly；

Embodiment 4

Tea Saponin shampoo is prepared through relevant physical and chemical inspection in above-described embodiment 1~3, is shown: noxious material Arsenic, lead, mercury are not detected；Excrement colibacillus group, pseudomonas aeruginosa and staphylococcus aureus are not detected；Total plate count < 10CFU/ml；Yeast and mold sum < 10CFU/ml.It is kept for 24 hours in (40 ± 1) DEG C, it is existing without layering after restoring to room temperature As；It is kept for 24 hours in (- 8 ± 2) DEG C, without lamination after restoring to room temperature；Foam (40 DEG C) >=80mm, substance content >= 10.0%, each index meets wanting for shampoo (GB/T29679-2013) and " cosmetics health specification " version specification in 2007 It asks.

Embodiment 5

Tea Saponin shampoo is prepared through relevant toxicology test, through acute eye irritation in above-described embodiment 1~3 It tests (30s) to rinse, result is nonirritant；It is tested through acute skin irritation, it is nonirritant as the result is shown；Through skin light poison Property test, as the result is shown to have no skin phototoxicity；Through Skin allergy test, the results showed that have no that skin is abnormal anti- It answers.

Comparative example 1

A kind of shampoo, the mass percentage that each component uses are as follows: Semen Sesami Nigrum extract 1%, ginkgo biloba p.e 1%, AES 22.43%, silicone emulsion 1.9%, cation guar gum 0.4%, Nacl 0.4%, EDTA 0.15%, stearic acid Magnesium 0.15%, propylene glycol 1.5%, ethyl-para-hydroxybenzoate 0.15%, remaining be deionized water；

Method made from Semen Sesami Nigrum extract and ginkgo biloba p.e is same as Example 1.

The method of the above-mentioned shampoo containing Chinese medical extract, method includes the following steps:

(1) deionized water of 3/4 total amount is added in stirring container, is warming up to 85 DEG C, AES is added, is sufficiently stirred, makes it It is uniformly mixed, then adds EDTA, cation guar gum and silicone emulsion, continue stirring to being completely dissolved；

(2) temperature is down to 75 DEG C, and propylene glycol is added, stirs evenly；Semen Sesami Nigrum extract and ginkgo are sequentially added later Leaf extract stirs evenly；

(3) temperature is down to 45 DEG C, and going for magnesium stearate, Nacl, ethyl-para-hydroxybenzoate and remaining 1/4 total amount is added Ionized water then proceedes to stir, and after so that it is sufficiently diluted fusion, obtains shampoo.

Compared with the shampoo made from the embodiment 1, the emulsification degree that shampoo is made in comparative example 1 is low, foaming less, dispersion Difference, infiltration is poor, lubrication is low.

Comparative example 2

A kind of Tea Saponin shampoo containing Chinese medical extract, the mass percentage that each component uses are as follows: Semen sesami nigrum is extracted Object 1%, ginkgo biloba p.e 1%, AES 5%, Tea Saponin 17.43%, silicone emulsion 1.9%, cation guar gum 0.4%, Nacl0.4%, EDTA 0.15%, magnesium stearate 0.15%, propylene glycol 1.5%, ethyl-para-hydroxybenzoate 0.15%, remaining For deionized water；

(2) temperature is down to 75 DEG C, and Tea Saponin and propylene glycol is added, stirs evenly；Semen sesami nigrum extraction is sequentially added later Object and ginkgo biloba p.e, stir evenly；

Compared with the shampoo made from the embodiment 1, the emulsification degree that shampoo is made in comparative example 2 is low, dirt-removing power is too strong, Lubricate that low, hair is dry and astringent.

Comparative example 3

This comparative example carries out preparing shampoo using each component in the same manner as in Example 1 and its content proportion.

Preparation process is as follows: the deionized water of 3/4 total amount being added in stirring container, is warming up to 80 DEG C -85 DEG C, is added AES and K12-Na, is sufficiently stirred, and is uniformly mixed it, then adds MES, EDTA, 6501, Tea Saponin, CAB, LAO, sun Cationic guar and silicone emulsion, stirring, discovery are difficult to dissolve；Then temperature is down to 75 DEG C, and propylene glycol is added, stirs evenly； Semen Sesami Nigrum extract and ginkgo biloba p.e are sequentially added later, are stirred evenly；Temperature is down to 45 DEG C, be added magnesium stearate, The deionized water of Nacl, ethyl-para-hydroxybenzoate and remaining 1/4 total amount, then proceed to stir, and discovery can not dilute dissolution.

100 triers are selected, two kinds of shampoos sold on the market (respectively VS Sassoon water profit anti-dandruff shampoo and Europe are used Lai Ya purifies oil-control shampoo) and the shampoo that is prepared of the embodiment of the present invention 1~3, every three days using primary, respectively Using 10 times, evaluation marking finally is carried out to each type shampoo, table 1 is the result after evaluation score is averaged.

1 trier of table is to the in-service evaluation after using the present embodiment 1~3 and existing market product

Conclusion: shampoo of the invention using when foaming abundancy, rich in herbaceous plant fragrance, clearly refresh oneself, to scalp and Skin of face does not have moderate excitement, dirt-removing power, dry comb, wet cardability fine, and continuous use back luminance submissive floats It escapes, is good to the repairing effect after hair dyeing or hair-waving, flexible.

And the shampoo of control group 1 using when there is no scent, to the irritating sense of scalp, dirt-removing power is too strong, hair Dry and astringent, tangled up and knotted, wet comb resistance is big, it is dry comb one's hair easy to produce static electricity, continuous use back hair shaft is withered, short-tempered, intensely dark.

The shampoo of control group 2 using when there is no scent, the only taste of natural flavor, scalp is not stimulated Sense, dirt-removing power is inadequate, does comb, wet comb resistance very greatly, second day hair starts greasy after wash my hair, and third day hair is There is stronger stink, hair quality fragility is easily broken after continuous use.

The above embodiments merely illustrate the technical concept and features of the present invention, and its object is to allow person skilled in the art Scholar cans understand the content of the present invention and implement it accordingly, and it is not intended to limit the scope of the present invention, it is all according to the present invention Equivalent change or modification made by Spirit Essence, should be covered by the protection scope of the present invention.

Claims

1. the Tea Saponin shampoo containing Chinese medical extract, it is characterised in that: the substance including following weight percent:

The surfactant includes nonionic surface active agent, anionic surfactant, zwitterionic surfactant It with cationic surfactant, calculates in percentage by weight, the nonionic surface active agent includes Tea Saponin 3-6.5% With 6501 1.8-1.9%, the anionic surfactant include AES 8.3-8.4%, K12 2.7-2.8% and MES1.45-1.5%, the zwitterionic surfactant include CAB 1.45-1.5%, the cationic surfactant packet Include LAO1.45-1.5%；

The Semen Sesami Nigrum extract is made by following methods: Semen sesami nigrum being rinsed with water only, is later 30-60% ethyl alcohol with concentration The circumfluence distillation 0.5-3h under the conditions of 60-70 DEG C, the dosage of ethyl alcohol are 45-65 times of Semen sesami nigrum quality, and residue is abandoned in filtering, It is concentrated under reduced pressure under conditions of being 0.1MPa in 50-60 DEG C and pressure by filtrate, obtains Semen Sesami Nigrum extract；

The ginkgo biloba p.e is made by following methods: ginkgo leaf cleaned, 55-75 DEG C of drying crushed 20 meshes later, Obtain ginkgo leaf fragment；Then it repeats to use ginkgo leaf fragment into concentration under the conditions of 70 DEG C to be 70% ethanol solution circumfluence distillation 5-8 times, concentration is that the dosage of 70% ethanol solution is 4-8 times of Ginkgo Leaf weight, later closes the filtrate extracted every time And filter, residue is abandoned, is concentrated under reduced pressure under conditions of being 0.1MPa in 55 DEG C and pressure by filtrate, ethyl alcohol recycling obtains ginkgo Leaf extract；

Wherein, the Tea Saponin shampoo containing Chinese medical extract is prepared by the following method to obtain:

(1) deionized water is added in stirring container, heats up 80-85 DEG C, AES and K12 is added, stirring is uniformly mixed it, so After add MES, EDTA, 6501, cation guar gum and silicone emulsion, continue stirring to being completely dissolved；

(2) it is cooled to 70-78 DEG C, Tea Saponin, CAB, LAO and propylene glycol is added, stirs evenly；Semen sesami nigrum extraction is added later Object and ginkgo biloba p.e, stir evenly；

(3) cool down 40-50 DEG C, magnesium stearate, NaCl, ethyl-para-hydroxybenzoate and deionized water is added, continues to stir, makes it Dilution fusion to get.