CN103505375B - Liquid detergent composition - Google Patents
Liquid detergent composition Download PDFInfo
- Publication number
- CN103505375B CN103505375B CN201310244129.2A CN201310244129A CN103505375B CN 103505375 B CN103505375 B CN 103505375B CN 201310244129 A CN201310244129 A CN 201310244129A CN 103505375 B CN103505375 B CN 103505375B
- Authority
- CN
- China
- Prior art keywords
- composition
- mass
- salt
- content
- liquid detergent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention provides a kind of liquid detergent composition, it can realize and take into account the good good alveolar substance of quality is fine and smooth, foam is good to the close property of skin and foam is on skin ductility, in washing, foam can be throughout each corner of skin, and carrys out soft good use feeling to the skin tape after washing.The liquid detergent composition of the present invention contains following component（A）With（B）：（A）N acyl glutamic acids or its salt with the acyl group that carbon number is 8~18；With（B）N acylaspartic acids or its salt with the acyl group that carbon number is 8~18, and contain（C）Amphoteric surfactant, composition（A）And composition（B）Content add up to more than 2 mass % below 18 mass %, composition（C）Content be below 2.5 mass %, in composition（A）And composition（B）Content it is total in N stearyls glutamic acid or its salt and the content of N stearyls aspartic acid or its salt it is total（S）Shared ratio is with mass ratio（（S）/[（A）+（B）]）It is calculated as less than 0.1, also, composition（B）Content relative to composition（A）And composition（B）Content total mass ratio（（B）/[（A）+（B）]）For less than more than 0.3 0.6.
Description
Technical field
The present invention relates to liquid detergent composition.
Background technology
The detergent composition used in the washing of the skin of body washes etc. requires to skin irritation in recent years
It is low and with good alveolar substance, use feeling etc..N- acyl amino hydrochlorates are the low anion surfactants of skin irritation,
Compared with other anion surfactants such as soap, alkyl sulfate salt or laureth sulfate, bubble
Matter or use feeling have room for improvement, also develop the detergent combination of the N- acyl amino hydrochlorates described in various uses so far
Thing.
For example, in patent document 1, by being made N- acyl acidic amino acids or its salt and alkene sulfonic acid or its salt simultaneously
Composition, the improvement of foaming characteristic or washing performance can be sought, in patent document 2, by and use Krafft's point（Krafft
Point）High other anion surfactants, it can obtain making alveolar substance creaminess and bringing with elastic force and after washing
The composition of salubrious moist feeling.
In addition, in the composition of patent document 3, in order to improve alveolar substance or low-temperature stability etc., in N- acyl aminos
In hydrochlorate and with the amphoteric surfactant of specified quantitative and the PEG of specified molecular weight.Further, in patent document 4, with N-
Acyl glutamate is as main component, in patent document 5, with specific ratio and use described N- acyl glutamates and
Other surfactants, the composition that foamability improves or alveolar substance is smooth can be respectively obtained.
Prior art literature
Patent document
Patent document 1：Japanese Unexamined Patent Publication 1-272697 publications
Patent document 2：Japanese Unexamined Patent Publication 2006-183039 publications
Patent document 3：Japanese Unexamined Patent Publication 2009-120546 publications
Patent document 4：Japanese Unexamined Patent Publication 2005-306752 publications
Patent document 5：Japanese Unexamined Patent Publication 6-108090 publications
The content of the invention
The present invention provides a kind of liquid detergent composition, wherein, contain following component（A）With（B）：
（A）N- acyl glutamic acids or its salt with the acyl group that carbon number is 8~18；And
（B）N- acylaspartic acids or its salt with the acyl group that carbon number is 8~18；
（C）Amphoteric surfactant,
Composition（A）And composition（B）Content add up to more than 2 mass % below 18 mass %, composition（C）Content be
Below 2.5 mass %,
In composition（A）And composition（B）Content it is total in N- stearyls glutamic acid or its salt and N- stearyls
The content of aspartic acid or its salt adds up to（S）Shared ratio, with mass ratio（（S）/[（A）+（B）]）It is calculated as less than 0.1, and
And
Composition（B）Content relative to composition（A）And composition（B）Content total mass ratio（（B）/[（A）+
（B）]）For less than more than 0.3 0.6.
Embodiment
In recent years, it is desirable to have the detergent of high performance alveolar substance can be played by having, and have close sense of the foam to skin,
And ductility of the foam on skin is good and can be throughout the alveolar substance in each corner of skin, can be with as by foam bag
Dermal sensation after sense of touch as wrapping up in is washed and washed is soft and bring good use feeling.
If however, as described in Patent Document 1 and with N- acyl acidic amino acids or its salt and alkene sulfonic acid, to skin
It is irritating reduce it is insufficient, in addition, if as documents 2 and with N- acyl acidic amino acids or its salt and Kerafyrm
High anion surfactant is selected, even if foam creaminess can be made to improve elastic force, and salubrious moist feeling can be assigned, but
It is to leave technical problem in the use feeling still after alveolar substance and flushing.And then if as documents 3, even if being used in combination
Amphoteric surfactant and specific PEG, excellent effect can be played in terms of foaming characteristic, also having can not realize with high property
The worry of good use feeling after the alveolar substance of energy or flushing.In addition, even if composition as described in patent document 4~5, bubble
Ductility or foam of the foam on skin are also possible to make after damage is rinsed in addition to the alveolar substances such as the close property of skin deficiency
With sense.
Therefore, present invention offer, which can be realized, takes into account quality exquisiteness, and foam is good to the close property of skin and foam exists
The good alveolar substance of ductility on skin, in washing, foam can be throughout each corner of skin, and to the skin after washing
Skin brings the liquid detergent composition of soft good use feeling.
Here, from the viewpoint of excitant of the present inventor from reduction to skin, in order to develop containing N- acylamino acids
Or its salt, and have both the detergent composition of excellent alveolar substance and good use feeling and carry out various researchs, as a result find
By containing specific 2 kinds of N- acylamino acids or its salt with specific ratio with specific measure, the quality of foam can be obtained
Exquisiteness, there is the good alveolar substance of close sense and ductility to skin, and soft good of the skin after being washed
The liquid detergent composition of good use feeling.
By the present invention, the excitant to skin can not only be reduced, moreover it is possible to bring froth texture exquisiteness and foam is to skin
The close sense of skin is good, the good alveolar substance of ductility of the foam on skin, and therefore, foam can be fully throughout each of skin during washing
Individual corner, and skin after washing is soft and can assign salubrious moist feeling, can bring good use feeling.Here, wash
Skin afterwards is soft and refers to that the surface of skin refreshing moistening and skin is smooth with salubrious moist feeling, when contacting skin
The soft sense of touch containing moisture can be actually perceived.
Hereinafter, the present invention is described in detail for pin.
The liquid detergent composition of the present invention contains（A）N- acyl group paddy ammonia with the acyl group that carbon number is 8~18
Acid or its salt.By containing the composition（A）N- acyl glutamic acids or its salt, good foaming characteristic can be kept, and can
Realize the high foam of fine and smooth close sense of the creaminess to skin of quality.Composition（A）In carbon number be 8~18 acyl group from
From the viewpoint of realizing good foaming characteristic and high alveolar substance, preferably carbon number is 8~16, more preferably 12~16, excellent
Choosing is from the saturation either acyl group of the aliphatic acid of undersaturated straight chain or side chain or fatty acid mixed.As such
Aliphatic acid, octanoic acid, capric acid, laurate, myristic acid, palmitic acid, stearic acid, oleic acid can be enumerated；Or coco-nut oil fatty acid,
Fatty acid mixed of palm kernel fatty acid etc. etc..In these aliphatic acid, from the viewpoint of foaming characteristic, alveolar substance or storage stability
Set out, preferably laurate, myristic acid, palmitic acid, oleic acid, coco-nut oil fatty acid, palm kernel fatty acid, further preferably
For laurate, myristic acid, coco-nut oil fatty acid, palm kernel fatty acid, more preferably coco-nut oil fatty acid.It is above-mentioned（A）
N- acyl glutamic acids or its salt can be used alone, and can also combine two or more use.
Above-mentioned（A）N- acyl glutamic acids or its salt as acid in the case where coordinating, in order to ensure foaming characteristic or alveolar substance,
Desired pH can be neutralized to alkali to use.As alkali, sodium hydroxide, potassium hydroxide, MEA, three second can be used
Hydramine, diethanol amine, ammonia, lysine, arginine, histidine, sodium acetate, potassium acetate, AMP（2- amino-2-methyls -1- third
Alcohol）, the common alkali, preferably sodium hydroxide, potassium hydroxide, arginine such as TRIS.Wherein,
From foaming characteristic either alveolar substance, skin irritation or from the viewpoint of obtaining easiness, preferably using sodium hydroxide, hydroxide
Potassium, arginine are modulated to form sodium salt, sylvite, arginine salt as alkali, further preferably use sodium hydroxide or hydrogen-oxygen
Change potassium as alkali to modulate to form sodium salt or sylvite.On the other hand, can also coordinate（A）N- acyl glutamic acids or its salt institute
Salt obtained from all or part for the carboxyl having is neutralized with alkali in advance.As salt obtained from the neutralization, from foaming
Property either alveolar substance, skin irritation or obtain easiness from the viewpoint of, be preferably selected from sodium salt, sylvite, ammonium salt, monoethanolamine
Salt, basic amino acid（Lysine, arginine, histidine）Salt in salt, more preferably selected from sodium salt, sylvite, arginine
Salt in salt, particularly preferably use sodium salt and sylvite.Alternatively, it is also possible to the additional hydroxide using above-mentioned record as needed
The common various alkali such as sodium, potassium hydroxide, triethanolamine, ammonia, lysine, arginine, histidine are to adjust detergent composition
PH to final desired value.In addition, in the case of any, or the pH of regulation detergent composition and enter one
Step is additional to use the common various acid such as hydrochloric acid, sulfuric acid, phosphoric acid, acetic acid, citric acid, malic acid, lactic acid, fumaric acid, butanedioic acid.
The liquid detergent composition of the present invention contains（B）N- acyl group asparagus ferns with the acyl group that carbon number is 8~18
Propylhomoserin or its salt.By containing the composition（B）N- acylaspartic acids or its salt, foaming characteristic is good, can suppress to rinse
The discomfort of middle creak creak sense etc., by with composition（A）And use can strengthen the slickness of foam, make foam in skin
Ductility on skin is good, and the quality of foam is fine and smooth, obtains foam and is close to the sense of touch of skin, and the skin after washing is soft
It is soft, the sense of touch clearly moistened is assigned, obtains good use feeling.
Composition（B）In carbon number be 8~18 acyl group from the viewpoint of good foaming characteristic and high alveolar substance is realized,
Preferably carbon number is 8~16 acyl group, and more preferably carbon number is 12~16 acyl group, and preferably coming from has
The acyl group of the aliphatic acid or fatty acid mixed of saturation or undersaturated straight or branched, more preferably from straight chain saturated fat
The acyl group of fat acid.As such aliphatic acid, can enumerate octanoic acid, capric acid, laurate, myristic acid, palmitic acid, stearic acid,
Fatty acid mixed of oleic acid or coco-nut oil fatty acid, palm kernel fatty acid etc. etc..In these aliphatic acid, from foaming characteristic, bubble
From the viewpoint of matter or storage stability, preferably laurate, myristic acid, palmitic acid, oleic acid, coco-nut oil fatty acid, palm fibre
Palmitic acid kernel oil and fat fat acid, more preferably laurate, myristic acid, coco-nut oil fatty acid, palm kernel fatty acid, particularly preferably
For laurate.It is above-mentioned（B）N- acylaspartic acids or its salt can be used alone, and can also combine two or more use.
（B）N- acylaspartic acids or its salt, can in order to ensure foaming characteristic or alveolar substance in the case where coordinating as acid
Used with being neutralized to desired pH with alkali.As alkali, sodium hydroxide, potassium hydroxide, MEA, three ethanol can be used
Amine, diethanol amine, ammonia, lysine, arginine, histidine, sodium acetate, potassium acetate, AMP（2-amino-2-methyl-1-propanol）、
The common alkali such as 2- amino -2- methylol -1,3- propane diols.Wherein, either alveolar substance, skin irritation or obtained from foaming characteristic
From the viewpoint of easiness, preferably sodium salt, sylvite, arginine are modulated into as alkali using sodium hydroxide, potassium hydroxide, arginine
Salt, further preferably modulated using sodium hydroxide, potassium hydroxide, arginine as alkali to form sodium salt, sylvite, arginine
Salt.On the other hand, can also coordinate（B）The all or part of carboxyl is advance possessed by N- acylaspartic acids or its salt
Salt obtained from being neutralized with alkali.As salt obtained from the neutralization, either alveolar substance, skin irritation or held from foaming characteristic
From the viewpoint of easy property, sodium salt, sylvite, ammonium salt, ethanolamine salt, basic amino acid are preferably selected from（Lysine, arginine, group ammonia
Acid）Salt in salt, more preferably sodium salt, sylvite, arginine salt, particularly preferably using sodium salt.Furthermore it is possible to chase after as needed
Add common each using the sodium hydroxide of above-mentioned record, potassium hydroxide, triethanolamine, ammonia, lysine, arginine, histidine etc.
Kind alkali is so that the pH of detergent composition turns into final desired value.In addition, in the case of any, in order to adjust detergent
The pH of composition, can also further add using hydrochloric acid, sulfuric acid, phosphoric acid, acetic acid, citric acid, malic acid, lactic acid, fumaric acid,
The common various acid such as butanedioic acid.
From improving foaming characteristic and also improve the soft sense of touch of the skin after washing, and improve the slickness of foam and
From the viewpoint of ductility on skin is excellent, in the liquid detergent composition of the present invention,（A）N- acyl glutamic acids or
Its salt and（B）The content of N- acylaspartic acids or its salt is added up to more than 2 mass % below 18 mass %, preferably 2.5 matter
More than % is measured, more preferably more than 3 mass %, preferably below 15 mass %, more preferably below 10 mass %, further
Preferably below 7 mass %.Composition（A）And composition（B）Content add up to 2~18 mass %, preferably 2~15 mass %, more
Add preferably 2.5~10 mass %, be still more preferably 3~7 mass %.From such a viewpoint, composition（A）Content it is excellent
Elect as more than 1.5 mass % below 17 mass %, more preferably more than 2 mass %, preferably below 14 mass %, further preferably
For below 10 mass %, and it is still more preferably below 6 mass % more preferably below 9 mass %.In addition, from same
Viewpoint is set out, composition（B）Content be preferably more than 1 mass % below 15 mass %, more preferably more than 1.2 mass %, more
Add preferably below 10 mass %, be still more preferably below 8 mass %, more more preferably below 5 mass %.
Composition（A）And composition（B）From the viewpoint and alveolar substance of foaming characteristic improve, wash after skin it is soft feel excellent
Viewpoint and from the viewpoint of ensuring storage stability under low temperature, composition（A）And composition（B）In, acyl group is stearyl
N- stearyls glutamic acid or its salt and the content of N- stearyls aspartic acid or its salt it is total（S）In composition（A）With
Composition（B）Content it is total in shared ratio, with mass ratio（（S）/[（A）+（B）]）Less than 0.1 is calculated as, further preferably
For less than 0.07, more preferably less than 0.05.
The fine and smooth close sense having to skin of quality of the liquid detergent composition of the present invention from foam, prolongs to skin
Malleability is good, and foam can be throughout each corner of skin, and the skin after washing is soft, assigns the sight of the sense of touch clearly moistened
Point sets out, composition（B）Content relative to the composition（A）And composition（B）Content total mass ratio（（B）/[（A）+
（B）]）For less than more than 0.3 0.6, more preferably more than 0.35, more preferably more than 0.37, it is more preferably
Less than 0.55, more preferably less than 0.5.In addition, mass ratio（（B）/[（A）+（B）]）For 0.3~0.6, more preferably
0.35~0.55, more preferably 0.37~0.5.
The liquid detergent composition of the present invention, alveolar substance is improved from further, improves slickness of the foam on skin
Viewpoint is set out, and is preferably further contained（C）Amphoteric surfactant.By containing composition（C）, composition（A）And composition（B）Can be with
Exist with specific mass ratio, further improve slickness and ductility of the foam on skin, foam is easily over to skin
Each corner, also improve wash after skin soft use feeling.
As described（C）Amphoteric surfactant, specifically, such as alkyl carboxyl glycine betaine, alkyl can be enumerated
Sulfobetaines, alkyl hydroxy glycine betaine, alkylamidoalkyl hydroxyl sulfo betaine, alkylamidoalkyl amine type glycine betaine, alkyl
Imidazoline type glycine betaine etc..As（C）Amphoteric surfactant, from the viewpoint of the use feeling from alveolar substance and after washing, preferably
Alkylamidopropyl betaine, alkyl hydroxy sulfobetaines with the alkyl that carbon number is 8~14, it is more preferably
Alkyl hydroxy sulfobetaines, wherein it is preferred that coco-nut oil fatty acid hydroxyl sulfo betaine, lauryl hydroxyl sulfo betaine, meat
Myristyl hydroxyl sulfo betaine, more preferably lauryl hydroxyl sulfo betaine.These can be used alone, and also may be used
To combine two or more use.
Contain（C）Content in the case of amphoteric surfactant, from cunning when improving alveolar substance and use feeling, suppression flushing
It is more than 0.5 mass % preferably in the liquid detergent composition of the present invention from the viewpoint of greasy, more preferably 0.8 matter
More than % is measured, more preferably more than 1 mass %, preferably below 7 mass %, more preferably below 5 mass %, is more preferably
Below 2.5 mass %.
In the liquid detergent composition of the present invention, from the soft sense of touch and salubrious moistening for improving the skin after washing
Sense, from the viewpoint of further improving use feeling, preferably further contain（D）Sugar alcohol.As described（D）Sugar alcohol, tool
For body, for example, can enumerate maltitol, mannitol, D-sorbite, inositol, antierythrite, xylitol, lactitol, also
Ative starch syrup.These can be used alone, and can also combine two or more use.Wherein, after effectively improving and washing
From the viewpoint of the soft sense of touch of skin and salubrious moist feeling, preferably maltitol, antierythrite, D-sorbite, further
From the viewpoint of salubrious moist feeling is improved, preferably maltitol.
Containing（D）Content in the case of sugar alcohol, from the soft sense of touch and salubrious moistening for improving the skin after washing
It is more than 0.5 mass % preferably in the liquid detergent composition of the present invention from the viewpoint of sense, more preferably 1 matter
More than % is measured, it is more excellent more preferably below 15 mass % preferably below 20 mass % more preferably more than 2 mass %
Elect as below 10 mass %.
The liquid detergent composition of the present invention is preferably to be formed using water as medium to dissolve or disperse mentioned component
Liquid form.As water, from the viewpoint of never being had an impact to storage-stable, distilled water, ion exchange can be used
Water.The content of the water, in addition to the water of cooperation, in addition to the water contained in other compositions.Water（Moisture）Content except
Mentioned component（A）、（B）Outside, the composition as needed to contain can also be passed through（C）Or composition（D）, in addition to use
The regulation of sense etc. and the amount of other additives for adding etc. and change, discharge or foaming characteristic from by container, keep good
It is preferably 40 in the liquid detergent composition of the present invention from the viewpoint of alveolar substance well, use feeling and storage-stable
More than quality %, more preferably more than 50 mass %, more preferably more than 55 mass %, preferably below 95 mass %, more
Add preferably below 80 mass %, be the surplus of other compositions more preferably below 75 mass %.
From the viewpoint of excitant from the viewpoint and reduction for obtaining good foaming characteristic to skin, liquid of the invention is washed
The pH for washing agent composition is preferably the scope of pH5~8, more preferably pH5.3~7.5, particularly preferably pH5.6~6.5.
In the region of such faintly acid~alkalescent or faintly acid~neutrality, it is possible to give full play to excellent alveolar substance and good
Use feeling.In addition, in order to which pH is adjusted to desired value, can add as needed using sodium hydroxide, potassium hydroxide,
The common various alkali of triethanolamine, ammonia etc.；Or hydrochloric acid, sulfuric acid, phosphoric acid, acetic acid, citric acid, malic acid, lactic acid, rich horse
The common various acid such as acid, butanedioic acid.Described pH refers in principle by liquid detergent composition keeping in 25 DEG C of constant temperature
In groove, pH measuring electrodes are impregnated in undiluted liquid detergent composition 3 minutes and determined obtained value.
Further, liquid detergent composition of the invention, it can also not hinder the present invention's outside mentioned component
Contain the composition that uses in common liquid detergent composition in the range of effect, for example, glycerine, 1,3-BDO, the third two
The polyalcohol or polyalcohols of alcohol, polyethylene glycol, DPG etc.；The polysaccharide from plant of guar gum etc., xanthans etc.
The cellulose family of polysaccharide, hydroxypropyl cellulose, carboxymethyl cellulose from microorganism etc., intramolecular have polyoxyethylene chain
Ester either ether compound, acrylate copolymer or acrylic acid/methacrylate copolymers etc. carboxy vinyl polymer
The tackifier of class etc., alkyl poly glucoside, polyoxyethylene alkyl ether, polyoxyalkene sorbitan fatty acid ester etc. it is non-from
Sub- surfactant；The composition of alkyl sulfate or its salt, polyoxyethylene alkyl ether sulfuric ester or its salt etc.（A）And composition（B）
Anion surfactant in addition；The colouring agent of dyestuff etc.；Inorganic salts；Plant extract species；Preservative；Chelating agent；Dimension
Raw plain agent；Anti-inflammatory agent；Spices；Ultra-violet absorber；Antioxidant；Bactericide etc..
On the other hand, in the liquid detergent composition of the present invention, after ensuring to the low irritant of skin and washing
Skin soft sense of touch and the high use feeling of salubrious moist feeling from the viewpoint of, preferably reduce containing for aliphatic acid or its salt
Amount.As described aliphatic acid or its salt, such as aliphatic acid or its alkali metal that average carbon atom number is 8~20 can be enumerated
Salt, as described aliphatic acid, such as laurate, myristic acid, palmitic acid, stearic acid, behenic acid, different tristearin can be enumerated
Acid, oleic acid, leukotrienes, linoleic acid, epoxide stearic acid, undecenoic acid, lanolin fatty acid, coco-nut oil fatty acid etc..It is above-mentioned
The content of aliphatic acid or its salt, it is preferably below 1.5 mass % in the liquid detergent composition of the present invention, further preferably
It is still more preferably below 0.1 mass %, more further preferably more preferably below 0.5 mass % for below 1 mass %
For below 0.01 mass %, inevitably mixed situation is further removed in addition, is not preferably contained.
In addition, in the liquid detergent composition of the present invention, after reducing to the excitant of skin, not damaging and wash
From the viewpoint of the soft sense of touch of skin and the high use feeling of salubrious moist feeling, preferred component（A）And composition（B）Choosing in addition
From the content of alkyl sulfate or other anion surfactants of its salt and polyoxyethylene alkyl ether sulfuric ester or its salt
Total preferably compare composition（A）And composition（B）Content it is total small, the present invention liquid detergent composition in be preferably
Below 7 mass %, more preferably below 4 mass %, more preferably below 1 mass %, more preferably 0.3 mass % with
Under.In addition, in the liquid detergent composition of the present invention, even if the content of above-mentioned other anion surfactants is 0.1
Below quality %, good foaming characteristic and alveolar substance can also be further obtained for below 0.01 mass %.
Viscosity of the liquid detergent composition at 25 DEG C of the present invention, from the viewpoint of the discharge from by container,
Preferably 1~100000mPas, more preferably 1~10000mPas, more preferably 4~4000mPas.This hair
In the case that bright liquid detergent composition is installed in non-pneumatic bubbling container, liquid detergent composition is at 25 DEG C
Viscosity, from the viewpoint of being spued with good foam state, preferably 1~30mPas, more preferably 2~
20mPas, more preferably 3~15mPas.
The viscosity of the liquid detergent composition of the present invention can be by using Brookfield type viscosimeters at 25 DEG C（East
Machine industry, TVB-10M）Measure.Viscosity be less than 100mPas in the case of, using rotor No.1, rotating speed as 60r/min be bar
Part；It is 60r/min as condition using rotor No.2, rotating speed in the case where 100mPas is less than 500mPas；
It is 30r/min as condition using rotor No.2, rotating speed in the case that 500mPas is less than 1000mPas；
It is 30r/min as condition using rotor No.3, rotating speed in the case that 1000mPas is less than 4000mPas；
It is 12r/min as condition using rotor No.3, rotating speed in the case that 4000mPas is less than 10000mPas；
It is 30r/min as condition using rotor No.4, rotating speed in the case that 10000mPas is less than 20000mPas；
In the case that 20000mPas is less than 50000mPas, using rotor No.4, rotating speed 12r/min as condition；
In the case that 50000mPas is less than 100000mPas, using rotor No.4, rotating speed be 6r/min as condition, from rotation
Viscosity is determined after starting 60 seconds so as to obtain.
The liquid detergent composition of the present invention, can be manufactured by using above-mentioned each composition according to common method.Separately
Outside, described liquid detergent composition, preferably as skin washing be used for use, more preferably as hand soaps, cleanser,
Bath soap uses.
The present invention liquid detergent composition can for by common skin washing methods come in washed skin
Use.As washing methods, have the method washed by hand, using made of the chemical fibre of cotton or nylon etc. sponge, towel, cook a meal
The method that broom etc. is washed, from the viewpoint for reducing the stimulation to skin and the foaming properties and use feeling that effectively play product of the present invention
From the viewpoint of, preferably used in the method for directly being taken and being washed by hand with hand.Wherein, more preferably for by liquid
Detergent composition is in advance with sponge or towel, bubbler（Bubbling container）Deng foaming, the foam is taken come washed skin with hand
Middle use.From the viewpoint of simplicity, more preferably using bubbler（Bubbling container）Foaming spues in advance, holds as foaming
Device, such as non-pneumatic type foam discharge container can be enumerated.In addition, the liquid detergent composition of the present invention is due to low irritant
And alveolar substance, foaming characteristic are good, the soft sense of touch of the skin after being washed, thus be suitable for selected from sensitive skin,
The washing of dry skin, mixing skin, Oily and the skin in the thin infant's skin of cuticula, it is more preferably suitable
Together in the washing of the skin in sensitive skin, dry skin and infant's skin.Here, the sensitive skin in the present invention
Skin refers to that nerve fibre is extended in epidermis and immediately below cuticula, it will readily recognize that the hyperesthesia state of sensory stimuli
Skin.Specifically, refer to due to sensory nerve allergy and for a little outside stimulus（Temperature, humidity, dust, metamorphosis
React original etc.）Also easily impacted, use or outside stimulus by cosmetics, produce it is that burning, continuous pin is pricked, itch
The skin of the sensory stimuli of gargalesthesia.In addition, infant refers to infants and young, baby refers to after birth 0 day to discontented one-year-old
Child, child refer to more than the 1 years old child to before going to school, in the present invention the more preferably child of less than 5 years old.
Composition（A）Or composition（B）N- acylamino acids or its salt, if compared with fatty acid soaps have in foam
The property that creaminess etc. is somewhat short of, but be filled in by aforesaid liquid detergent composition in non-pneumatic bubbling container
In the case of discharge, mentioned component（A）With（B）Mutually worked for specific content and specific ratio, obtain the quality of foam
Exquisiteness, the good alveolar substance of ductility of the foam on skin, the skin after washing can be easily soft.Bubble as non-pneumatic type
Foam discharge container, as long as the container to be spued as foam can be mixed with air, it is possible to use is any number of, for example, can arrange
Lift by pressing pump head, the cylinder of air chamber and the cylinder of liquid detergent composition are pressurized, air and liquid detergent group
Compound is mixed into the pump bubbling container of foam-like discharge；Or can be with the body of the container of crimp by extruding
Point, the extruding bubbling container that container is deformed and spued, preferably on the discharge stream of the liquid detergent composition of these containers
The membrane filtering device of screen cloth etc. is set.Specifically, Yoshino Kogyosho Co., Ltd's manufacture, big and processed tank manufacture can be enumerated
Bubbling container etc..In addition, for example, it is also possible to using in Japanese Unexamined Patent Publication 7-315463, Japanese Unexamined Patent Publication 8-230961 and
Bubbling container described in Japanese Unexamined Patent Publication 2005-193972 publications etc..
On the embodiment of the invention described above, following liquid detergent composition is further disclosed.
[1] a kind of liquid detergent composition, wherein,
Contain following component（A）With（B）：
（A）N- acyl glutamic acids or its salt with the acyl group that carbon number is 8~18；With
（B）N- acylaspartic acids or its salt with the acyl group that carbon number is 8~18,
And contain（C）Amphoteric surfactant,
Composition（A）And composition（B）Content add up to more than 2 mass % below 18 mass %, composition（C）Content be
Below 2.5 mass %,
In composition（A）And composition（B）Content it is total in N- stearyls glutamic acid or its salt and N- stearyls
The content of aspartic acid or its salt adds up to（S）Shared ratio, with mass ratio（（S）/[（A）+（B）]）It is calculated as less than 0.1, and
And
Composition（B）Content relative to composition（A）And composition（B）Content total mass ratio（（B）/[（A）+
（B）]）For less than more than 0.3 0.6.
[2] a kind of liquid detergent composition, wherein,
Contain following component（A）With（B）：
（A）N- acyl glutamic acids or its salt with the acyl group that carbon number is 8~16；With
（B）N- acylaspartic acids or its salt with the acyl group that carbon number is 8~16,
And contain（C）Amphoteric surfactant,
Composition（A）And composition（B）Content add up to more than 2 mass % below 18 mass %, composition（C）Content be
Below 2.5 mass %,
Composition（B）Content relative to composition（A）And composition（B）Content total mass ratio（（B）/[（A）+
（B）]）For less than more than 0.3 0.6.
[3] liquid detergent composition described in [1] or [2] as described above, wherein, in composition（A）And composition（B）Content
It is total in N- stearyls glutamic acid or its salt and the content of N- stearyls aspartic acid or its salt it is total（S）It is shared
Ratio, with mass ratio（（S）/[（A）+（B）]）It is calculated as less than 0.1, more preferably less than 0.07, more preferably 0.05
Below.
[4] liquid detergent composition any one of [1]~[3] as described above, wherein, composition（A）And composition（B）
Content add up to more than 2 mass % below 18 mass %, preferably more than 2.5 mass %, more preferably more than 3 mass %,
Preferably below 15 mass %, more preferably below 10 mass %, more preferably below 7 mass %.
[5] liquid detergent composition any one of [1]~[4] as described above, wherein, composition（B）Content phase
For composition（A）And composition（B）Content total mass ratio（（B）/[（A）+（B）]）For less than more than 0.3 0.6, preferably
For more than 0.35, more preferably more than 0.37, preferably less than 0.55, more preferably less than 0.5.
[6] liquid detergent composition any one of [1]~[5] as described above, wherein, composition（A）It is possessed
The carbon number of acyl group is 8~18, preferably 8~16, more preferably 12~16.
[7] liquid detergent composition any one of [1]~[6] as described above, wherein, composition（A）For selected from N-
1 kind or 2 kinds in lauroyl glutamate, N- myristoyls glutamic acid, N- cocoyls glutamic acid and their salt
More than.
[8] liquid detergent composition any one of [1]~[7] as described above, wherein, composition（A）Content be
Below the mass % of more than 1.5 mass % 17, preferably more than 2 mass %, preferably below 14 mass %, more preferably 9 mass %
Hereinafter, more preferably below 6 mass %.
[9] liquid detergent composition any one of [1]~[8] as described above, wherein, composition（B）It is possessed
The carbon number of acyl group is 8~18, preferably 8~16, more preferably 12~16.
[10] liquid detergent composition any one of [1]~[9] as described above, wherein, composition（B）For N- bays
Acylaspartic acid or its salt.
[11] liquid detergent composition any one of [1]~[10] as described above, wherein, composition（B）Content
For below the mass % of more than 1 mass % 15, preferably more than 1.2 mass %, preferably below 10 mass %, more preferably 8 mass %
Hereinafter, it is still more preferably below 5 mass %.
[12] liquid detergent composition any one of [1]~[11] as described above, wherein, composition（C）Content
Preferably more than 0.5 mass %, more preferably more than 0.8 mass %, more preferably more than 1 mass %.
[13] liquid detergent composition described in [12] as described above, wherein, composition（C）For selected from coco-nut oil fatty acid hydroxyl
1 kind or 2 kinds in base sulfobetaines, lauryl hydroxyl sulfo betaine and myristyl hydroxyl sulfo betaine with
On, preferably lauryl hydroxyl sulfo betaine.
[14] liquid detergent composition any one of [1]~[13] as described above, wherein, further contain（D）
Below the mass % of more than the mass % of sugar alcohol 0.5 20.
[15] liquid detergent composition described in [14] as described above, wherein, composition（D）For selected from maltitol, red moss
1 kind in sugar alcohol, D-sorbite or two or more.
[16] liquid detergent composition described in [14] or [15] as described above, wherein, composition（D）Content be 0.5 matter
Below the mass % of more than % 20 are measured, preferably more than 1 mass %, more preferably more than 2 mass %, preferably below 15 mass %,
More preferably below 10 mass %.
[17] liquid detergent composition any one of [1]~[16] as described above, wherein, aliphatic acid or its salt
Content is below 1.5 mass %, more preferably below 1 mass %, more preferably below 0.5 mass %, still more preferably
For below 0.1 mass %, especially preferably below 0.01 mass %.
[18] liquid detergent composition any one of [1]~[17] as described above, wherein, composition（A）And composition
（B）In addition be selected from alkyl sulfate or its salt and other anionic surfaces of polyoxyethylene alkyl ether sulfuric ester or its salt
The total of the content of activating agent is less than composition（A）And composition（B）Content it is total, it is further excellent preferably below 7 mass %
Elect as below 4 mass %, be still more preferably below 0.3 mass %, more further preferably more preferably below 1 mass %
For below 0.01 mass %.
[19] liquid detergent composition any one of [1]~[18] as described above, wherein, the content of water is 40 matter
Measure below the mass % of more than % 95, preferably more than 50 mass %, more preferably more than 55 mass %, preferably 80 mass % with
Under, more preferably below 75 mass %.
[20] liquid detergent composition any one of [1]~[19] as described above, wherein, pH is 5~8, enters one
Step is preferably 5.3~7.5, more preferably 5.6~6.5.
[21] liquid detergent composition any one of [1]~[20] as described above, wherein, the viscosity at 25 DEG C
For 1~30mPas, preferably 2~20mPas, more preferably 3~15mPas.
[22] a kind of liquid detergent composition, it is the liquid detergent any one of by above-mentioned [1]~[21]
Composition is filled in what is formed in non-pneumatic bubbling container.
[23] a kind of skin cleaning composition, wherein, contain following component（A）With（B）：
（A）N- acyl glutamic acids or its salt with the acyl group that carbon number is 8~18；With
（B）N- acylaspartic acids or its salt with the acyl group that carbon number is 8~18,
Composition（A）And composition（B）Content add up to more than 2 mass % below 15 mass %,
In composition（A）And composition（B）Content it is total in N- stearyls glutamic acid or its salt and N- stearyls
The content of aspartic acid or its salt adds up to（S）Shared ratio, with mass ratio（（S）/[（A）+（B）]）It is calculated as less than 0.1, and
And
Composition（B）Content relative to composition（A）And composition（B）Content total mass ratio（（B）/[（A）+
（B）]）For less than more than 0.3 0.6,
Composition（A）Content be below the mass % of more than 1.5 mass % 6.
[24] a kind of skin cleaning composition, wherein, contain following component（A）With（B）：
（A）N- acyl glutamic acids or its salt with the acyl group that carbon number is 8~16；With
（B）N- acylaspartic acids or its salt with the acyl group that carbon number is 8~16,
Composition（A）And composition（B）Content add up to more than 2 mass % below 15 mass %,
Composition（B）Content relative to composition（A）And composition（B）Content total mass ratio（（B）/[（A）+
（B）]）For less than more than 0.3 0.6.
Composition（A）Content be below the mass % of more than 1.5 mass % 6.
[25] the skin cleaning composition described in [23] or [24] as described above, wherein, viscosity at 25 DEG C for 1~
30mPas, preferably 2~20mPas, more preferably 3~15mPas.
[26] liquid detergent composition any one of [1]~[22] or as described above [23]~[25] as described above
Any one of skin cleaning composition, wherein, liquid detergent composition or the skin cleaning composition
Preferably hand soaps, cleanser or bath soap.
[27] a kind of liquid detergent, it is the liquid detergent composition any one of by above-mentioned [1]~[22]
Or the skin cleaning composition any one of above-mentioned [23]~[25] is filled in what is formed in non-pneumatic bubbling container.
[28] appoint in the liquid detergent composition or above-mentioned [23]~[25] any one of above-mentioned [1]~[22]
Skin cleaning composition described in one is for manufacturing the purposes in skin detergent.
[29] appoint in the liquid detergent composition or above-mentioned [23]~[25] any one of above-mentioned [1]~[22]
Purposes of the skin cleaning composition in the washing for skin described in one.
[30] appoint in the liquid detergent composition or above-mentioned [23]~[25] any one of above-mentioned [1]~[22]
Skin cleaning composition described in one for selected from sensitive skin, dry skin, combination, Oily and
Purposes in the washing of skin in infant's skin.
[31] appoint in the liquid detergent composition or above-mentioned [23]~[25] any one of above-mentioned [1]~[22]
Skin cleaning composition described in one with hand for directly taking and washing by hand the purposes in washing skin.
[embodiment]
Hereinafter, it is specifically described based on embodiment for the present invention.In addition, each composition. in table unless stated otherwise
Content represents quality %.
[embodiment 1~12, comparative example 1~6]
According to the composition shown in table 1~5, each liquid detergent composition is manufactured according to common method, by the following method
Measure foam viscosity and pH simultaneously carry out each evaluation.As a result it is shown in table 1~5.
In addition, following raw materials is used when manufacturing each liquid detergent.
Sodium cocoyl glutamate：Trade name " Amisoft CS-11（F）, molecular weight 359 ", Ajincomoto Co., Inc
Sodium lauroyl glutamate：Trade name " Amisoft LS-11（F）" Ajincomoto Co., Inc
Stearyl sodium glutamate：Trade name " Amisoft HS-11P（F）" Ajincomoto Co., Inc
Lauroyl NaAsp liquid（25%）：Trade name " AminoFoamer FLDS-L " Asahi Kasei
Chemicals Corporation
Polyoxyethylene sorbitan monostearate：20EO additions mole, trade name " RHEODOL TW-S120V ",
Kao Corp
Lauryl hydroxyl sulfo betaine liquid（30%）：Trade name " AMPHITOL20HD ", Kao Corp
Glycerine：100%, trade name " concentrated glycerin ", Kao Corp
Macrogol 6000：Number-average molecular weight 8600, trade name " PEG#600 ", Japan Oil Co
2- hexyl glycidyl ethers：Kao Corp
Propane diols：Asahi Glass Co., Ltd
《The measure of viscosity》
The viscosity of liquid detergent composition is that Brookfield type viscosimeters are used at 25 DEG C（Eastern machine industry, TVB-
10M）.Rotor uses No.1 rotor, is rotated in the case where rotating speed is 60r/min, the viscosity after rotation starts 60 seconds is tried to achieve, as liquid
The viscosity of body detergent composition.Further, since only comparative example 6 generates sediment at 25 DEG C, therefore to be dissolved after manufacture
State is measured at 30 DEG C.
《PH measure》
Obtained liquid detergent composition 100mL is filled in beaker, regulation is to 25 DEG C in 25 DEG C of thermostat.
PH measuring electrodes are immersed in the sample for be adjusted to constant temperature 3 minutes, determine pH.Further, since only comparative example 6 is at 25 DEG C
Sediment is generated, therefore the state to be dissolved after manufacture determines at 30 DEG C.
《The evaluation of the sense of touch of skin after alveolar substance washing》
By each liquid detergent composition by 5 special evaluation group members by using following methods, respectively with 1~
5 points are evaluated.The summation score of evaluation result is shown in table 1~5.
Application method is in 25 DEG C, the room that relative humidity is 40%, by the liquid detergent composition shown in table 1~5
It is filled in following bottle, wherein, the bottle possesses the pump by being manufactured by pump head and the wild company of industrial institute of Ji that spues
Bubbling container（The mesh size for the membrane filtering device being arranged on discharge stream is 1 piece of 200 mesh and 1 piece of 305 mesh）, and in hand
Spue the component of pressing twice in the palm（The discharge-amount that pressing is 1 time is about 1ml, about 13cm3）, the foam of discharge is placed in advance use
It is water-moistened with the hands to spread apart on the face, then wash one's face.Afterwards, running water is used（25℃）Fully rinse, wiped with dry towel
Wipe.Further, since only comparative example 6 is immediately generated sediment at 25 DEG C, therefore, with lysed state after fabrication at 30 DEG C
It is lower directly to fill, spued and evaluated with foam-like.
<Feel that the skin smoothness of foam is good, ductility of the foam on skin is good>
5：Feel very much
4：Feel
3：Slightly feel
2：Substantially do not feel
1：Do not feel
<Feel that the quality of foam is fine and smooth, foam is close to skin>
5：Feel very much
4：Feel
3：Slightly feel
2：Substantially do not feel
1：Do not feel
<Feel the skin emolliency after washing and clearly moisten>
5：Feel very much
4：Feel
3：Slightly feel
2：Substantially do not feel
1：Do not feel
[table 1]
The content of * 1 stearyl sodium glutamate：2.5%
As shown in table 1, it is evaluated as：In the liquid detergent composition of embodiment, the skin after washing can obtain softness
Sense of touch, and clearly moisten, and in contrast, in comparative example, do not feel the soft, salubrious of the skin after washing substantially
The sense of touch of moistening.Additionally, it is believed that：In the liquid detergent composition of embodiment, the quality of foam is fine and smooth, and foam is the matter being close to
Measure good foam, and foam uniformly extended on skin with hand, feel to be wrapped up by foam and easily rinse, and with this phase
Instead, it is poor due to extending on skin although foam is fine and smooth in comparative example 1,2, therefore be difficult to rinse when washing by hand.Than
Compared with example 3,4, i.e., foam is extended on skin using hand, but the quality of foam is not fine and smooth, is thick foam, therefore confirm
Foam is bad to the close sense of skin, and the sense of touch wrapped up by foam is poor.
[table 2]
The content of * 1 stearyl sodium glutamate：2.5%
[table 3]
The content of * 1 stearyl sodium glutamate：2.5%
[table 4]
The content of * 1 stearyl sodium glutamate：2.5%
[table 5]
Claims (27)
1. a kind of liquid detergent composition, wherein,
Contain following component (A), (B) and (C)：
(A) there is the N- acyl glutamic acids or its salt of the acyl group that carbon number is 8~18；
(B) there is the N- acylaspartic acids or its salt of the acyl group that carbon number is 12~16；With
(C) the alkyl hydroxy sulfobetaines as amphoteric surfactant,
The content of composition (A) and composition (B) adds up to more than 2 mass % below 18 mass %, and the content of composition (C) is 0.5
Below the mass % of more than quality % 2.5,
In the total middle N- stearyls glutamic acid or its salt and N- stearyl asparagus ferns of the content of composition (A) and composition (B)
Ratio shared by total (S) of the content of propylhomoserin or its salt, less than 0.1 is calculated as with mass ratio (S)/[(A)+(B)], also,
Content as composition (B) is relative to composition (A) and total mass ratio of the content of composition (B), (B)/[(A)+(B)]
For less than more than 0.3 0.6,
Also, the viscosity at 25 DEG C is 1~30mPas.
2. a kind of liquid detergent composition, wherein,
Contain following component (A), (B) and (C)：
(A) there is the N- acyl glutamic acids or its salt of the acyl group that carbon number is 8~16；
(B) there is the N- acylaspartic acids or its salt of the acyl group that carbon number is 12~16；With
(C) the alkyl hydroxy sulfobetaines as amphoteric surfactant,
The content of composition (A) and composition (B) adds up to more than 2 mass % below 18 mass %, and the content of composition (C) is 0.5
Below the mass % of more than quality % 2.5, also,
Content as composition (B) is relative to composition (A) and total mass ratio of the content of composition (B), (B)/[(A)+(B)]
For less than more than 0.3 0.6,
Also, the viscosity at 25 DEG C is 1~30mPas.
3. liquid detergent composition as claimed in claim 1 or 2, wherein,
Composition (A) is selected from N- lauroyl glutamates or its salt, N- myristoyls glutamic acid or its salt and N- cocounut oil acyls
1 kind in base glutamic acid or its salt or two or more.
4. liquid detergent composition as claimed in claim 1 or 2, wherein,
Composition (B) is N- lauroyls aspartic acid or its salt.
5. liquid detergent composition as claimed in claim 1 or 2, wherein,
Content as composition (B) is relative to composition (A) and total mass ratio of the content of composition (B), (B)/[(A)+(B)]
For less than more than 0.35 0.55.
6. liquid detergent composition as claimed in claim 1 or 2, wherein,
Further contain below the mass % of more than the mass % of (D) sugar alcohol 0.5 20.
7. a kind of liquid detergent composition, wherein,
The liquid detergent composition is that the liquid detergent composition described in claim 1 or 2 is filled in into non-pneumatic to rise
Formed in bubble container.
8. liquid detergent composition as claimed in claim 1 or 2, wherein,
Content as composition (B) is relative to composition (A) and total mass ratio of the content of composition (B), (B)/[(A)+(B)]
For less than more than 0.37 0.5.
9. liquid detergent composition as claimed in claim 1 or 2, wherein,
The content of water is below the mass % of more than 55 mass % 80.
10. liquid detergent composition as claimed in claim 1 or 2, wherein,
Composition (C) is lauryl hydroxyl sulfo betaine.
11. liquid detergent composition as claimed in claim 1 or 2, wherein,
Composition (D) is maltitol.
12. liquid detergent composition as claimed in claim 1 or 2, wherein,
The content of aliphatic acid or its salt is below 0.1 mass %, or does not contain aliphatic acid or its salt.
13. liquid detergent composition as claimed in claim 1 or 2, wherein,
Alkyl sulfate or its salt and polyoxyethylene alkyl ether sulfuric ester or its salt are selected from beyond composition (A) and composition (B)
The contents of other anion surfactants add up to below 0.1 mass %, or do not contain composition (A) and composition (B)
In addition be selected from alkyl sulfate or its salt and other anion surface actives of polyoxyethylene alkyl ether sulfuric ester or its salt
Agent.
14. a kind of skin cleaning composition, wherein,
Contain following component (A) and (B)：
(A) there is the N- acyl glutamic acids or its salt of the acyl group that carbon number is 8~18；With
(B) there is the N- acylaspartic acids or its salt of the acyl group that carbon number is 12~16,
Further contain the alkyl hydroxy sulfobetaines of (C) as amphoteric surfactant,
The content of composition (A) and composition (B) adds up to more than 2 mass % below 15 mass %, (C) amphoteric surfactant
Content is below the mass % of more than 0.5 mass % 2.5,
In the total middle N- stearyls glutamic acid or its salt and N- stearyl asparagus ferns of the content of composition (A) and composition (B)
Ratio shared by total (S) of the content of propylhomoserin or its salt, less than 0.1 is calculated as with mass ratio (S)/[(A)+(B)],
Content as composition (B) is relative to composition (A) and total mass ratio of the content of composition (B), (B)/[(A)+(B)]
For less than more than 0.3 0.6, and
The content of composition (A) is below the mass % of more than 1.5 mass % 6,
Also, the viscosity at 25 DEG C is 1~30mPas.
15. a kind of skin cleaning composition, wherein,
Contain following component (A) and (B)：
(A) there is the N- acyl glutamic acids or its salt of the acyl group that carbon number is 8~16；With
(B) there is the N- acylaspartic acids or its salt of the acyl group that carbon number is 12~16,
Further contain the alkyl hydroxy sulfobetaines of (C) as amphoteric surfactant,
The content of composition (A) and composition (B) adds up to more than 2 mass % below 15 mass %, (C) amphoteric surfactant
Content is below the mass % of more than 0.5 mass % 2.5,
Content as composition (B) is relative to composition (A) and total mass ratio of the content of composition (B), (B)/[(A)+(B)]
For less than more than 0.3 0.6, and
The content of composition (A) is below the mass % of more than 1.5 mass % 6,
Also, the viscosity at 25 DEG C is 1~30mPas.
16. the skin cleaning composition as described in claims 14 or 15, wherein,
Composition (A) is selected from N- lauroyl glutamates or its salt, N- myristoyls glutamic acid or its salt and N- cocounut oil acyls
1 kind in base glutamic acid or its salt or two or more.
17. the skin cleaning composition as described in claims 14 or 15, wherein,
Composition (B) is N- lauroyls aspartic acid or its salt.
18. the skin cleaning composition as described in claims 14 or 15, wherein,
Content as composition (B) is relative to composition (A) and total mass ratio of the content of composition (B), (B)/[(A)+(B)]
For less than more than 0.35 0.55.
19. the skin cleaning composition as described in claims 14 or 15, wherein,
Further contain below the mass % of more than the mass % of (D) sugar alcohol 0.5 20.
20. a kind of skin cleaning composition, wherein,
The skin cleaning composition is that the skin cleaning composition described in claims 14 or 15 is filled in into non-pneumatic
Formed in bubbling container.
21. the skin cleaning composition as described in claims 14 or 15, wherein,
Content as composition (B) is relative to composition (A) and total mass ratio of the content of composition (B), (B)/[(A)+(B)]
For less than more than 0.37 0.5.
22. the skin cleaning composition as described in claims 14 or 15, wherein,
The content of water is below the mass % of more than 55 mass % 80.
23. the skin cleaning composition as described in claims 14 or 15, wherein,
Composition (D) is maltitol.
24. the skin cleaning composition as described in claims 14 or 15, wherein,
The content of aliphatic acid or its salt is below 0.1 mass %, or does not contain aliphatic acid or its salt.
25. the skin cleaning composition as described in claims 14 or 15, wherein,
Alkyl sulfate or its salt and polyoxyethylene alkyl ether sulfuric ester or its salt are selected from beyond composition (A) and composition (B)
The contents of other anion surfactants add up to below 0.1 mass %, or do not contain composition (A) and composition (B)
In addition be selected from alkyl sulfate or its salt and other anion surface actives of polyoxyethylene alkyl ether sulfuric ester or its salt
Agent.
26. purposes of the skin cleaning composition in the washing for skin any one of claim 14~25.
A kind of 27. skin cleaning composition for described in the claims 14 or 15 that is used as cleanser.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2012-141441 | 2012-06-22 | ||
| JP2012141441A JP5968692B2 (en) | 2012-06-22 | 2012-06-22 | Liquid detergent composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103505375A CN103505375A (en) | 2014-01-15 |
| CN103505375B true CN103505375B (en) | 2018-04-03 |
Family
ID=49889153
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310244129.2A Active CN103505375B (en) | 2012-06-22 | 2013-06-19 | Liquid detergent composition |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP5968692B2 (en) |
| CN (1) | CN103505375B (en) |
| TW (1) | TWI629999B (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6648760B2 (en) | 2015-07-09 | 2020-02-14 | 日油株式会社 | Hair shampoo composition |
| CN105541652A (en) * | 2015-12-17 | 2016-05-04 | 九江天赐高新材料有限公司 | Preparation method of cocoyl glutamate acid |
| KR102051789B1 (en) * | 2016-04-14 | 2019-12-04 | 아사히 가세이 파인켐 가부시키가이샤 | Cleaning composition and its manufacturing method |
| JP7045849B2 (en) * | 2016-12-28 | 2022-04-01 | 花王株式会社 | Skin cleanser article |
| CN110520103B (en) * | 2017-04-10 | 2023-04-04 | 花王株式会社 | Skin cleanser composition |
| JP7208107B2 (en) * | 2019-05-30 | 2023-01-18 | 株式会社ファンケル | powdered facial cleanser |
| JP7364502B2 (en) * | 2020-03-16 | 2023-10-18 | 株式会社マンダム | skin cleansing composition |
| KR20230147476A (en) * | 2022-04-14 | 2023-10-23 | 엘지전자 주식회사 | Detergent composition for wet cleaning |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59189197A (en) * | 1983-04-11 | 1984-10-26 | 味の素株式会社 | Detergent composition |
| JP2003055690A (en) * | 2001-08-21 | 2003-02-26 | Kanebo Ltd | Detergent composition |
| JP2006183039A (en) * | 2004-11-30 | 2006-07-13 | Lion Corp | Detergent composition contained in foamer container |
| JP2012102194A (en) * | 2010-11-08 | 2012-05-31 | Mikimoto Pharmaceut Co Ltd | Aqueous liquid detergent |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5023682B2 (en) * | 1971-11-19 | 1975-08-09 | ||
| JPS5590594A (en) * | 1978-12-28 | 1980-07-09 | Ajinomoto Kk | Novel detergent composition |
| US5000877A (en) * | 1988-08-12 | 1991-03-19 | Mitsubishi Petrochemical Co., Ltd. | Aqueous liquid detergent containing an N-acylaspartate and a betaine or imidazoline surfactant |
| JP2507546B2 (en) * | 1988-08-12 | 1996-06-12 | 三菱化学株式会社 | Liquid detergent composition |
| JP3441261B2 (en) * | 1994-09-20 | 2003-08-25 | 花王株式会社 | Aqueous liquid cleaner |
| DE10144264A1 (en) * | 2001-09-08 | 2003-03-27 | Cognis Deutschland Gmbh | Aqueous detergent formulation, useful in cosmetics, e.g. shampoo, hair lotion, foam bath or shower formulation, contains N-acylamino-acid and/or salt and polyol and/or polyol fatty acid ester |
| JP2005325204A (en) * | 2004-05-13 | 2005-11-24 | Asahi Kasei Chemicals Corp | Cleanser composition |
| JP5876744B2 (en) * | 2012-02-17 | 2016-03-02 | 株式会社コープクリーン | Body cleaning agent for foam discharge containers |
-
2012
- 2012-06-22 JP JP2012141441A patent/JP5968692B2/en active Active
-
2013
- 2013-06-19 CN CN201310244129.2A patent/CN103505375B/en active Active
- 2013-06-21 TW TW102122149A patent/TWI629999B/en active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59189197A (en) * | 1983-04-11 | 1984-10-26 | 味の素株式会社 | Detergent composition |
| JP2003055690A (en) * | 2001-08-21 | 2003-02-26 | Kanebo Ltd | Detergent composition |
| JP2006183039A (en) * | 2004-11-30 | 2006-07-13 | Lion Corp | Detergent composition contained in foamer container |
| JP2012102194A (en) * | 2010-11-08 | 2012-05-31 | Mikimoto Pharmaceut Co Ltd | Aqueous liquid detergent |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2014005230A (en) | 2014-01-16 |
| JP5968692B2 (en) | 2016-08-10 |
| TWI629999B (en) | 2018-07-21 |
| TW201410259A (en) | 2014-03-16 |
| CN103505375A (en) | 2014-01-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103505375B (en) | Liquid detergent composition | |
| JP5947121B2 (en) | Liquid cleaner in non-gas former container | |
| CN103301051B (en) | Transparent beauty treatment soap composition | |
| TWI488648B (en) | Foaming skin-cleansing agent | |
| CN109528523B (en) | Amino acid facial cleanser | |
| JP5328032B2 (en) | Cleaning composition | |
| CN103637941B (en) | Bath gel | |
| CN103202781A (en) | Cream body bath composition and application thereof | |
| CN109401869B (en) | Liquid skin cleaning composition and preparation method and application thereof | |
| TW200400052A (en) | Hair cleansing compositions | |
| JP5522828B2 (en) | Skin cleanser | |
| CN105476877A (en) | Facial cleanser | |
| CN109528505B (en) | Mild moisturizing and soothing skin-cleaning bubble composition | |
| CN113693956B (en) | Facial cleanser composition | |
| KR101168434B1 (en) | Detergent composition | |
| CN103637930B (en) | Aqueous scrubbing cleaning cosmetic product | |
| CN103509655B (en) | Non-pneumatic bubbling container fills liquid detergent | |
| WO2022127421A1 (en) | Cleaning composition | |
| CN112472630A (en) | Self-thickening composition of amino acid surfactants | |
| JP5946416B2 (en) | Skin cleansing cosmetics | |
| KR20170050414A (en) | Human body cleansing composition | |
| CN105919851A (en) | Whitening and bathing liquid containing towel gourd | |
| KR20110014915A (en) | Conditioning shampoo composition | |
| KR102601554B1 (en) | Hair cleansing composition having improved conditioning | |
| JP5654197B2 (en) | Shampoo composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |