CN109401869B

CN109401869B - Liquid skin cleaning composition and preparation method and application thereof

Info

Publication number: CN109401869B
Application number: CN201811329653.9A
Authority: CN
Inventors: 李韩林; 周姝; 李友勇
Original assignee: Guangzhou Hongdu Fine Chemical Co ltd
Current assignee: Guangzhou Hongdu Fine Chemical Co ltd
Priority date: 2018-11-09
Filing date: 2018-11-09
Publication date: 2020-09-29
Anticipated expiration: 2038-11-09
Also published as: CN109401869A

Abstract

The invention relates to a liquid skin-cleaning composition which comprises the following raw materials in parts by weight: 3.0-15.0 parts of natural oil; 18.0-27.0 parts of fatty acid; 6.0-8.0 parts of potassium hydroxide; 0.2-3.0 parts of nonionic surfactant; 0.1-3.0 parts of brown sugar; 1.0-5.0 parts of coconut acyl hydrolyzed oat protein potassium; 50.0-60.0 parts of water; the non-ionic surfactant is a composition of PEG/PPG-80/20 copolymer, PEG-32 and PEG-6. The liquid skin-cleaning composition has low viscosity, is convenient to take and use, is added into cleaning products, is easy to wash, does not cause dry and tight body feeling, can form rich foam, and does not influence the foam amount even if used in hard water.

Description

Liquid skin cleaning composition and preparation method and application thereof

Technical Field

The invention relates to the technical field of daily chemical articles, in particular to a liquid skin-cleaning composition and a preparation method and application thereof.

Background

The traditional soap is prepared by reacting grease with sodium hydroxide, the main raw material of the grease is animal grease such as beef tallow, lard and the like, which are decocted and neutralized, the traditional soap making method is called soap boiling, namely, the reaction time is long, and the industrialized batch production is difficult. The alkali liquor used in the traditional soap making is sodium hydroxide, and the grease can be ensured to be converted into the soap only by using excessive dosage, so that the pH value of the soap is 11-12, the soap is strong in alkalinity, and the skin is dry after washing, and has large skin irritation.

With the change of social demands, consumers desire mild and healthy products, and in order to solve the problem of great irritation of the traditional soap base, the handmade soap using natural oil is popular at present, and due to the characteristic that the handmade soap is added into the soap by cold making, namely the natural oil is neutralized with alkali liquor, and the handmade soap is prepared by long-term purification under the condition of not heating, so that a plurality of nutrient components in the natural oil are reserved, and the handmade soap has a good nourishing effect on skin. However, the saponification reaction time is slow, the purification time is long, the mass production is difficult, and the industrial demand cannot be realized because the manual soap obtained by using the oil and fat through saponification can only exist in a solid form, and the current washing and caring products have various forms, such as: the hand soap has single form and is easy to pollute after being repeatedly used, and the requirements of diversified washing products cannot be met.

In order to improve the saponification speed and obtain liquid soap which is easier to take, the soap liquid prepared by daily cosmetic factories is mainly prepared by saponifying fatty acid and alkali liquor, only fatty acid refined by grease is used for reacting with the alkali liquor, so that natural ingredients in the grease cannot be reserved, and various effects of nourishing, moisturizing and the like by using the natural grease cannot be utilized, so that most products can only be applied to cleaning of clothes, tableware and the like; the difficulty of directly using the grease to participate in the reaction to produce the soap solution is very high, the phenomena that the viscosity of the soap solution reaction is too high, the stirring is difficult, the final viscosity of the product is unstable, crystals are easy to separate out at low temperature, the transparency is not enough, the turbidity is easy to occur and the like exist, and the free alkali and the like are difficult to control, so that the irritation is increased. Meanwhile, the preparation time is relatively long, the energy consumption is relatively large, the process is complex, and the stability of the product batch is difficult to guarantee.

Disclosure of Invention

Based on the liquid skin-cleaning composition, the liquid skin-cleaning composition provided by the invention has a good nourishing effect on skin, is rich in foam, and is easy to thicken and wash. Meanwhile, after saponification reaction, the pH value is low, and the skin cannot be tense after washing.

The specific technical scheme is as follows:

the liquid skin cleaning composition comprises the following raw materials in parts by weight:

the non-ionic surfactant is a composition of PEG/PPG-80/20 copolymer, PEG-32 and PEG-6.

In one embodiment, the liquid skin-cleaning composition comprises the following raw materials in parts by weight:

in one embodiment, the weight ratio of the PEG/PPG-80/20 copolymer to PEG-32 to PEG-6 is: (5-10):(2-3):1.

In one embodiment, the PEG/PPG-80/20 copolymer has a number average molecular weight of 14000-16000.

In one embodiment, the natural oil is selected from one or more of coconut oil, olive oil, camellia oil and rosehip oil.

In one embodiment, the fatty acid is selected from at least two of lauric acid, myristic acid, palmitic acid, and stearic acid.

The invention also provides a preparation method of the liquid skin-cleaning composition.

The specific technical scheme is as follows:

a method for preparing a liquid skin cleansing composition comprising the steps of:

mixing the natural oil, the fatty acid, partial water and the nonionic surfactant, heating to 50-65 ℃, stirring until the natural oil, the fatty acid, the partial water and the nonionic surfactant are completely dissolved, keeping the temperature, and keeping the vacuum degree at-0.05-0.2 Mpa to obtain a mixture;

mixing the potassium hydroxide with part of water to prepare a 35-45% potassium hydroxide solution, slowly dripping the potassium hydroxide solution into the mixture, homogenizing and dispersing at 50-65 ℃ under the vacuum degree of-0.05-0.2 Mpa until the potassium hydroxide solution is completely mixed, adding the potassium cocoyl hydrolyzed oat protein and brown sugar, stirring until the potassium cocoyl hydrolyzed oat protein and the brown sugar are dissolved to obtain a clear liquid, cooling to 20-25 ℃, and discharging to obtain the finished product;

the rotation speed of the dispersion is 1000-.

The invention also provides the shower gel.

The specific scheme is as follows:

the shower gel comprises the following raw materials in parts by weight:

20-55 parts of liquid skin-cleaning composition; 3.5-6.5 parts of coconut oil amphoteric sodium acetate; 0.1-10 parts of polyhydric alcohol; 0.1-2.0 parts of inorganic salt; 0.5-2.5 parts of pearling agent; 5.0-25.0 parts of amphoteric surfactant; 0.5-5.0 parts of amino acid surfactant; 0.01-0.1 part of high molecular polymer; 0.01-0.20 part of acid-base regulator; 0.05-0.5 part of preservative; 0-3.0 parts of coconut diethanol amide; 0.05-0.1 of disodium ethylene diamine tetraacetate; 0.1-1 part of essence; and a proper amount of water.

In one embodiment, the polyhydric alcohol is one or more selected from glycerol, 1,2 propylene glycol, 1,3 butylene glycol and 1,3 propylene glycol; and/or

The inorganic salt is selected from one or more of sodium chloride, potassium chloride and sodium citrate; and/or

The pearling agent is selected from one or more of ethylene glycol distearate and ethylene glycol monostearate; and/or

The zwitterionic surfactant is selected from one or more of cocamidopropyl betaine and cocamidopropyl hydroxysulfobetaine; and/or

The amino acid surfactant is selected from one or more of sodium lauroyl sarcosinate, sodium cocoyl sarcosinate, sodium myristoyl sarcosinate, sodium lauroyl glycinate, potassium lauroyl glycinate, sodium methyl lauroyl taurate and sodium methyl cocoyl taurate; and/or

The high molecular polymer is selected from one or more of PEG-14M, PEG-7M and PEG-90M; and/or

The acid-base regulator is selected from one or more of citric acid, potassium hydroxide and sodium hydroxide; and/or

The preservative is selected from one or more of methyl paraben, propyl paraben and phenoxyethanol.

The invention also provides a preparation method of the shower gel.

The specific scheme is as follows:

a preparation method of the shower gel comprises the following steps:

weighing the raw materials in parts by weight;

adding the disodium ethylene diamine tetraacetate and the inorganic salt into water, wherein the water temperature is 25-45 ℃, and stirring until the disodium ethylene diamine tetraacetate and the inorganic salt are dissolved to obtain a transparent solution A;

adding the liquid skin-cleaning composition, coconut oil amphoteric sodium acetate, polyhydric alcohol, a pearling agent, an amphoteric surfactant, an amino acid surfactant, a high molecular polymer and a preservative into the transparent solution A, heating to 50-60 ℃, and stirring until the liquid skin-cleaning composition, the coconut oil amphoteric sodium acetate, the polyhydric alcohol, the pearling agent, the amphoteric surfactant, the amino acid surfactant, the high molecular polymer and the preservative are dissolved to obtain a solution B;

adding an acid-base regulator into the solution B, cooling to 45-55 ℃, adding the cocoyl diethanol amine, stirring, cooling to 40-45 ℃, adding the essence, and stirring to obtain the shower gel.

The invention also provides the facial cleanser.

The specific scheme is as follows:

the facial cleanser comprises the following raw materials in parts by weight:

15-50 parts of liquid skin-cleaning composition; 0.1-2.0 parts of inorganic salt; 1.0-5.0 parts of polyol; 0.5-3.0 parts of pearling agent; 5.0-18.0 parts of zwitterionic surfactant and 0.1-5.0 parts of cationic surfactant; 0.5-5.0 parts of amino acid surfactant; 1.0-5.0 parts of a suspending agent; 3.0-8.0 parts of thickening stabilizer; 0.01-0.1 part of high molecular polymer; 0.05-0.5 part of preservative; 0.05-0.15 parts of disodium ethylene diamine tetraacetate; 0.1-1.0 part of essence; and a proper amount of water.

In one embodiment, the polyhydric alcohol is selected from one or more of glycerol, 1,2 propylene glycol, 1,3 butylene glycol, and 1,3 propylene glycol; and/or

The cationic surfactant is selected from polyquaternium-7 & polyquaternium-43; and/or

The amino acid surfactant is selected from one or more of sodium lauroyl sarcosinate, sodium methyl lauroyl taurate, sodium methyl cocoyl taurate and potassium cocoyl hydrolyzed oat protein; and/or

The suspending agent is selected from polyacrylate copolymer; and/or

The thickening stabilizer is selected from disodium corn starch & lauryl alcohol sulfosuccinate; and/or

Compared with the prior art, the invention has the following beneficial effects:

(1) the liquid skin cleaning composition has viscosity of 10.0-50.0mpa.s at 25 deg.C, pH of 9.0-10.2, and is clear transparent liquid soap with low viscosity. The skin cleansing cream is prepared by taking natural grease and fatty acid as main raw materials, adopting a nonionic surfactant consisting of PEG/PPG-80/20 copolymer, PEG-32 and PEG-6, matching with coconut acyl hydrolyzed oat protein potassium and brown sugar, and performing saponification reaction, so that a plurality of nutrient components such as polyunsaturated fatty acid, squalene, glycerol and the like in the natural grease are preserved, the effects of moistening skin, resisting oxidation, resisting inflammation and the like can be achieved while dirt on the surface of the skin is cleaned, the skin is not dried and tense due to low pH value, and good skin feeling after washing can be obtained. The raw materials are green, environment-friendly and easy to degrade, and do not contain harmful risk substances.

(2) The nonionic surfactant consisting of PEG/PPG-80/20 copolymer, PEG-32 and PEG-6, potassium cocoyl hydrolyzed oat protein and brown sugar can solubilize the grease soap, assist the dissolution and dispersion of soap groups of the grease soap and promote the quick reaction of the natural grease soap. And the mixture of the nonionic surfactant and the natural ingredients can effectively reduce the irritation. Meanwhile, the addition of the brown sugar prepared by the ancient method can reduce the stimulation to the skin, also can preserve trace elements, amino acids and the like, and can enhance the effects of moistening the skin, moisturizing, relieving itching and strengthening the skin structure and skin elasticity.

(3) The composition can keep a clear liquid state under the condition of adding higher content of natural oil, the concentration of the skin-cleaning active ingredients of the composition reaches about 35-45% (the concentration of the skin-cleaning active ingredients of the common soap solution is 20-30%), and the composition has better skin-cleaning effect and is easier to thicken when being added into cleaning products.

(4) The liquid skin-cleaning composition disclosed by the invention has the advantages that the reaction conditions are controlled in the preparation process, the reaction rate is accelerated, the conversion rate of natural oil is higher, the temperature is controlled, the nutritional ingredients such as squalene and partial oil in unsaponifiable matters in the natural oil are stored, the effects of nourishing, moistening and moisturizing are enhanced, the liquid skin-cleaning composition is easy to stir and disperse in the saponification process through specific formula proportion and process control, the final product is a clear transparent dilute solution, is easy to add and use, and is convenient for application of downstream cosmetic enterprises.

(5) The liquid skin-cleaning composition with specific components is used as a raw material to be matched with other surfactants and auxiliaries, and skin-cleaning daily chemical products such as facial cleanser, shower gel and the like can be prepared. The cleaning product can form abundant foam, has stable foam, does not affect the foam amount even if used in hard water, is easy to wash, and does not have unclean skin feeling. And is stable in both high and low temperature ranges, the composition is kept in a liquid state, crystals are not precipitated even at low temperature, and the composition is easy to take.

Detailed Description

The liquid skin cleansing composition of the present invention, its preparation method and use are further described in detail with reference to the following examples.

The raw materials used in the embodiments of the present invention may be commercially available, unless otherwise specified, wherein,

the PEG/PPG-80/20 copolymer was obtained from Shanghai Macro Fine chemical Co., Ltd and had a number average molecular weight of 15000.

PEG-32 was purchased from Dow chemistry.

PEG-6 was purchased from Dow chemistry.

Cocamidopropyl betaine, under the trade name: CAB-35, available from Guangzhou Star science and technology, Inc.;

ethylene glycol distearate, trade name: EGDS, available from luodiya;

coconut oil amphoteric sodium acetate, trade name: HONDU SN30, available from shanghai macroscale fine chemicals, ltd;

sodium lauroyl sarcosinate, trade name: LS-30, available from Guangzhou Tiancinew materials, Inc.;

cocoyl diethanol amine, trade name: 6501, available from entacapone, guang, Inc.;

corn starch & disodium lauryl sulfosuccinate, trade name: HC-10PLUS, available from Guangzhou Macro Fine chemical Co., Ltd;

sodium methyl lauroyl taurate, trade name: HONDU LT-40 with the content of 50-60% is purchased from Shanghai Macro fine chemical company Limited;

acrylate copolymer, trade name: carbopol Aqua SF-1, available from Guangzhou Mega Scale trade development, Inc.;

polyquaternium-7 & polyquaternium-43, trade name: supcare 627 available from Shanghai, Macro, Fine chemical Co., Ltd.

Examples 1 to 6

Table 1 shows the formulations of the liquid skin cleansing compositions of examples 1-6.

The liquid skin cleansing compositions of examples 1-6 were prepared as follows:

the raw materials required in the examples were weighed in the parts by weight shown in Table 1.

Mixing natural oil, fatty acid, part of water, PEG/PPG-80/20 copolymer, PEG-32 and PEG-6, heating to 50-65 ℃, stirring until the mixture is completely dissolved to form a dilute solution, and keeping the vacuum degree at-0.05-0.2 Mpa;

mixing potassium hydroxide with part of water to prepare a potassium hydroxide solution with the concentration of 40%, slowly dripping the potassium hydroxide solution into the mixture obtained in the previous step in steps, keeping the vacuum degree at 0.2Mpa and the temperature at 60 ℃, preparing a condensation reflux device, simultaneously starting a rapid dispersion device, keeping the dispersion rotation speed at 3000rpm, adding the cocoyl hydrolyzed oat protein potassium and the brown sugar, stirring until the materials are completely mixed, and ensuring that no agglomeration exists in the reaction process. Preserving the temperature until the liquid level is clear and bubble-free; introducing 0-5 deg.C condensed water, cooling to 20-25 deg.C, and discharging.

TABLE 1

Example 1 and comparative examples 1 to 4

Table 2 shows the formulations of the liquid skin cleansing compositions of example 1 and comparative examples 1 to 4.

Performance testing of examples 1-6 and comparative examples 1-4

Test 1 basic physical and chemical properties.

The viscosity test method comprises the following steps: the composition was previously incubated at 25 ℃ and measured using an NDJ-5S/NDJ-8S rotary digital viscometer.

The test results are shown in table 3.

TABLE 3

As can be seen from Table 3, the liquid skin cleansing compositions prepared in examples 1 to 6, which are clear transparent aqueous solutions having low viscosity, are easy to extract when used as a base cleansing material, and can be applied to transparent and opaque products in various forms such as liquid, paste, emulsion, etc. The stirring is easy to be uniform in the production process, and the process from feeding reaction to complete clarification of liquid only needs 1-2 hours.

Comparative example 1 palmitic acid was used instead of olive oil, the viscosity of the composition was high and the body was not uniform. Comparative example 2 could not be prepared as a clear liquid composition and a very long time was required to make the composition clear and transparent. Comparative example 3 the composition had a higher viscosity and more soap mass and took longer to dissolve completely, and comparative example 4 had a lower transparency and the composition had a slightly higher viscosity and more soap mass and took longer to dissolve completely.

Example 1 ', example 4' -example 6 'and comparative example 1' -comparative example 4

The compositions of examples 1, 4-6 and comparative examples 1-4 were prepared as body washes, corresponding to example 1 ', example 4 ' -example 6 ' and comparative example 1 ' -comparative example 4 ', respectively, the formulations of which are shown in table 4.

The preparation method of the shower gel comprises the following steps:

the raw materials required for each example and comparative example were weighed in the parts by weight shown in Table 4.

Adding disodium ethylene diamine tetraacetate and sodium chloride into water at the temperature of 25 ℃, and stirring until the disodium ethylene diamine tetraacetate and the sodium chloride are dissolved to obtain a transparent solution A;

adding corresponding liquid skin cleaning composition, sodium cocoamphoacetate, 1, 2-propylene glycol, ethylene glycol distearate, cocamidopropyl betaine, sodium lauroyl sarcosinate, PEG-14M, methyl hydroxybenzoate and propyl hydroxybenzoate into the transparent solution A, heating to 50-60 deg.C, and stirring to dissolve to obtain solution B;

and adding a citric acid aqueous solution into the solution B, cooling to 45 ℃, adding the cocoyl diethanol amide, stirring, cooling to 40 ℃, adding the essence, and stirring to obtain the shower gel.

TABLE 4

Example 1

Example 1 'provides a facial cleanser, and table 5 shows the formula of the facial cleanser of example 1'. TABLE 5

Test example 2 viscosity test

Comfortable use feeling is an important factor for embodying the value of the cleaning product and the popularity of the product. Wherein, the viscosity index of the cleaning product is closely related to the packing material and the use feeling of the product. The proper viscosity brings better feeling of use for consumers.

The products of example 1 ', example 4' -example 6 ', comparative example 1' -comparative example 4 'and example 1' were tested for viscosity in the following way: each of the body wash and the face wash was previously kept warm at 25 ℃ and measured using an NDJ-5S/NDJ-8S rotational digital viscometer.

The test results are shown in table 6:

TABLE 6

The above experimental results show that the liquid skin cleansing compositions prepared in examples 1, 4 to 6 of the present invention can achieve an ideal viscosity when applied to a body wash and a face wash system, and are convenient for filling and consumers to take. The body wash prepared from the liquid skin-cleaning compositions prepared in comparative examples 1,2, 3 and 4 has too high viscosity, poor ductility, no uniform spreading, discontinuous state, extremely high filling difficulty and difficult taking.

Test example 4 stability test

Cleaning products are subject to temperature changes during transportation, storage, etc. Therefore, the cleaning products are required to have better high and low temperature stability.

The test method is as follows: the products of example 1 ', example 4' -example 6 ', comparative example 1' -comparative example 4 'and example 1' were taken and left to stand at 45 ℃ for 30 days and then at 0 to 5 ℃ for 15 days, and the high and low temperature resistances of the respective products were examined, and the results are shown in Table 7.

TABLE 7

The experimental results show that when the liquid skin-cleaning composition of the embodiments 1, 4-6 of the invention is applied to a body wash and a face wash system, the product does not have the phenomena of crystal precipitation and delamination under the condition of long-term storage at high temperature and low temperature, and the body wash product has good stability. In the process of high and low temperature resistance investigation, the shower gel prepared by the compositions in comparative examples 1-4 is easy to generate phenomena of layering, crystal precipitation and the like, so that the appearance and the use effect of the product are changed, and the adaptability of the product to temperature is poor.

Test example 5 foaming ability test

The foaming force tests were carried out on the products of example 1 ', example 4' -example 6 ', comparative example 1' -comparative example 4 'and example 1'. Test methods the foaming power was measured by reference to the Ross-Miles method, and the test was performed using deionized water. The test reads foam height immediately and 5 minutes after the test. The average test data are shown in table 8:

TABLE 8

The above experimental results show that the liquid skin cleansing compositions of examples 1, 4-6 of the present invention have high foaming power when applied to body wash and face wash systems. Moreover, the bath lotion of example 1 'and the facial cleanser of example 1' still exhibited good foaming power in hard water.

Test example 6 somatosensory test

The evaluation of the efficacy of the cleaning products mainly takes cleaning performance and body feeling as main points, wherein the richer the foam, the better the thickening performance, the less the tightening feeling and the easier the washing, the better the body feeling.

The test method comprises the following steps: 10 volunteers were randomly selected, each using 8 products of example 1 ', example 4' -example 6 ', comparative example 3', comparative example 4 'and example 1', using the same method.

Volunteers respectively score the foamability, the cleanability, the washability and the tightness of each body wash and facial cleanser according to the respective use body feeling, the score is full at 10 points, the higher the score is, the better the effect is, then, the average score of 10 persons to the same body wash is calculated, and the evaluation result is shown in table 9:

TABLE 9

The above experimental results show that the body wash of example 1 ', example 4' -example 6 ', and the facial cleanser of example 1' scored well on the cleansing power and the skin feel after washing, and in particular, the facial cleansers of example 1 'and example 1' were abundant in foam, easy to rinse, free from tightness, very mild, and low in irritation.

In comparative example 3 ', the replacement of potassium cocoyl hydrolyzed oat protein with sodium cocoyl glycinate resulted in insufficient foam richness and poor flushing performance as in example 1'. In comparative example 4', the absence of brown sugar resulted in tight drying after washing and a significant increase in irritation.

The technical features of the embodiments described above may be arbitrarily combined, and for the sake of brevity, all possible combinations of the technical features in the embodiments described above are not described, but should be considered as being within the scope of the present specification as long as there is no contradiction between the combinations of the technical features.

The above-mentioned embodiments only express several embodiments of the present invention, and the description thereof is more specific and detailed, but not construed as limiting the scope of the present invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention. Therefore, the protection scope of the present patent shall be subject to the appended claims.

Claims

1. The liquid skin cleaning composition is characterized by comprising the following raw materials in parts by weight:

2. The liquid skin-cleaning composition according to claim 1, which comprises the following raw materials in parts by weight:

3. the liquid skin cleansing composition according to claim 2, comprising the following raw materials in parts by weight:

4. the liquid skin cleansing composition according to any one of claims 1 to 3, wherein said PEG/PPG-80/20 copolymer, PEG-32 and PEG-6 are in a weight ratio of: (5-10):(2-3):1.

5. The liquid skin cleansing composition according to any one of claims 1 to 3, wherein said PEG/PPG-80/20 copolymer has a number average molecular weight of 14000-16000.

6. The liquid skin cleansing composition according to any one of claims 1 to 3, wherein said natural oil is selected from one or more of coconut oil, olive oil, camellia oil and rosehip oil.

7. The liquid skin cleansing composition according to any one of claims 1 to 3, wherein said fatty acid is selected from at least two of lauric acid, myristic acid, palmitic acid and stearic acid.

8. A process for preparing a liquid skin cleansing composition according to any one of claims 1 to 7 comprising the steps of:

the rotation speed of the dispersion is 1000-.

9. The shower gel is characterized by comprising the following raw materials in parts by weight:

20-55 parts of a liquid skin cleansing composition according to any one of claims 1-7; 3.5-6.5 parts of coconut oil amphoteric sodium acetate; 0.1-10 parts of polyhydric alcohol; 0.1-2.0 parts of inorganic salt; 0.5-2.5 parts of pearling agent; 5.0-25.0 parts of amphoteric surfactant; 0.5-5.0 parts of amino acid surfactant; 0.01-0.1 part of high molecular polymer; 0.01-0.20 part of acid-base regulator; 0.05-0.5 part of preservative; 0-3.0 parts of coconut diethanol amide; 0.05-0.1 of disodium ethylene diamine tetraacetate; 0.1-1 part of essence; and a proper amount of water.

10. The facial cleanser is characterized by comprising the following raw materials in parts by weight:

15-50 parts of a liquid skin cleansing composition according to any one of claims 1-7; 0.1-2.0 parts of inorganic salt; 1.0-5.0 parts of polyol; 0.5-3.0 parts of pearling agent; 5.0-18.0 parts of zwitterionic surfactant and 0.1-5.0 parts of cationic surfactant; 0.5-5.0 parts of amino acid surfactant; 1.0-5.0 parts of a suspending agent; 3.0-8.0 parts of thickening stabilizer; 0.01-0.1 part of high molecular polymer; 0.05-0.5 part of preservative; 0.05-0.15 parts of disodium ethylene diamine tetraacetate; 0.1-1.0 part of essence; and a proper amount of water.