CN109401869A - Liquid cleansing composition and its preparation method and application - Google Patents
Liquid cleansing composition and its preparation method and application Download PDFInfo
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- CN109401869A CN109401869A CN201811329653.9A CN201811329653A CN109401869A CN 109401869 A CN109401869 A CN 109401869A CN 201811329653 A CN201811329653 A CN 201811329653A CN 109401869 A CN109401869 A CN 109401869A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
- A61K8/645—Proteins of vegetable origin; Derivatives or degradation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/08—Anti-ageing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/08—Liquid soap, e.g. for dispensers; capsuled
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Abstract
The present invention relates to a kind of liquid cleansing compositions, based on parts by weight, the raw material including following parts by weight: 3.0-15.0 parts of natural oil；18.0-27.0 parts of fatty acid；6.0-8.0 parts of potassium hydroxide；0.2-3.0 parts of nonionic surfactant；0.1-3.0 parts of brown sugar；Cocounut oil acyl hydrolyzes 1.0-5.0 parts of avenin potassium；50.0-60.0 parts of water；The nonionic surfactant is the composition of PEG/PPG-80/20 copolymer, PEG-32 and PEG-6.Aforesaid liquid skin cleansing composition viscosity is low, convenient for taking, is added in cleaning class product, is easy to rinse, not will cause dry, tight body-sensing, can form foam abundant, even if using in hard water, nor affect on its foam volume.
Description
Technical field
The present invention relates to daily chemical product technical fields, more particularly to liquid cleansing composition and preparation method thereof and answer
With.
Background technique
Traditional soap grease and sodium hydroxide reaction are prepared, and grease primary raw material is the animals such as butter, lard
Grease tanning neutralizes again, and traditional soapmaking method is called " soap boiling ", that is, the time reacted is very long, and is difficult industrialized batch
Amount production.Lye used in traditional soapmaking is sodium hydroxide, and dosage excessively must just can guarantee that grease is converted to soap, therefore its
PH is in 11-12, and alkalinity is stronger, and skin is relatively dry after washing, big for skin irritation.
With the change of social demand, consumer thirsts for the product of mild health, big in order to solve traditional soap base irritation
The problem of, it is more popular using natural oil handmade soap at present, because its cold process soap enters the characteristic of soap, that is, use natural oil and alkali
Liquid neutralizes, and in the case where not heating, is prepared into handmade soap by long-term purifying, such way remains in natural oil
All multi-nutrients have preferable nourishing effect for skin.But when using slow fat saponification reaction time, purifying completely
Between it is long, be difficult to volume production, cannot achieve industrialized demand, because can only deposit in solid form using fat saponification at handmade soap
, and it is current wash shield product form multiplicity, such as: face cleaning rub this, bubble, mildy wash, face cleaning cream etc., handmade soap form list
One and easy pollution is taken repeatedly, be unable to satisfy the diversified demand of cleaning product.
It is easier to the liquid soap taken in order to promote speed and the acquisition of saponification, daily cosmetics factory prepares soap lye at present
It is mainly saponified by fatty acid and lye, the fatty acid and alkaline reaction crossed using only oil and fat refining can not just retain grease
In natural component, can not be using the multiple efficacies such as natural oil nourishings, moisturizing, therefore major part product can be only applied to clothing
The cleaning such as object, tableware；And the difficulty for directly preparing soap lye using grease participation reaction production is very big, there are the viscous of soap lye reaction
It spends too big, it is difficult to stir, product final viscosity is unstable, and it is existing that not easy enough muddiness of precipitation crystallization, transparency etc. is easy under low temperature
As, and free alkali etc. is difficult to control, and irritation is caused to increase.Meanwhile the time of preparation is relatively long, energy consumption compares
Greatly, and complex process, product batches stability are difficult to ensure.
Summary of the invention
Based on this, the present invention provides a kind of liquid cleansing composition, has a good nourishing effect to skin, foaming abundancy,
It is easy to thicken, rinses.Simultaneously after saponification, pH is lower, and it is tight not will cause skin after washing.
The specific technical proposal is:
A kind of liquid cleansing composition, based on parts by weight, the raw material including following parts by weight:
The nonionic surfactant is the composition of PEG/PPG-80/20 copolymer, PEG-32 and PEG-6.
The liquid cleansing composition in one of the embodiments, the raw material including following parts by weight:
The liquid cleansing composition in one of the embodiments, the raw material including following parts by weight:
The weight ratio of the PEG/PPG-80/20 copolymer, PEG-32 and PEG-6 in one of the embodiments, are as follows:
(5-10):(2-3):1。
The number-average molecular weight of the PEG/PPG-80/20 copolymer is 14000-16000 in one of the embodiments,.
The natural oil is in coconut oil, olive oil, camellia oil and rose hip oil in one of the embodiments,
It is one or more of.
In one of the embodiments, the fatty acid in lauric acid, myristic acid, palmitinic acid and stearic acid extremely
It is two kinds few.
The present invention also provides the preparation methods of aforesaid liquid skin cleansing composition.
Specific technical solution are as follows:
A kind of preparation method of liquid cleansing composition, comprising the following steps:
The natural oil, fatty acid, part water and nonionic surfactant are mixed, are heated to 50-65 DEG C, stirring
It is completely dissolved, keeps the temperature to it, keep vacuum degree -0.05~0.2Mpa, obtain mixture；
The potassium hydroxide is mixed with part water, being configured to concentration is 35-45% potassium hydroxide solution, by the hydrogen-oxygen
Change potassium solution to be slowly added drop-wise in the mixture, in vacuum degree -0.05~0.2Mpa, temperature is homogeneous point at 50-65 DEG C
It is dissipated to mixing completely, adds the cocounut oil acyl hydrolysis avenin potassium and brown sugar, stirring obtains supernatant liquid to dissolving, cools down
To 20-25 DEG C, discharging to get；
The revolving speed of the dispersion is 1000-8000rpm.
The present invention also provides a kind of shower creams.
The specific scheme is that
A kind of shower cream, based on parts by weight, including following raw material:
20-55 parts of liquid cleansing composition；3.5-6.5 parts of cocounut oil both sexes sodium acetate；0.1-10 parts of polyalcohol；Inorganic salts
0.1-2.0 parts；0.5-2.5 parts of pearling agent；5.0-25.0 parts of amphoteric surfactant；0.5-5.0 parts of amino acid surfactant；
0.01-0.1 parts of high molecular polymer；0.01-0.20 parts of acid-base modifier；0.05-0.5 parts of preservative；Cocounut oil acyl diethanol amine
0-3.0 parts；Disodium ethylene diamine tetraacetate 0.05-0.1；0.1-1 parts of essence；Appropriate amount of water.
The polyalcohol is selected from glycerol, 1,2 propylene glycol, 1,3 butanediols and 1,3 propylene glycol in one of the embodiments,
One or more；And/or
The inorganic salts are selected from the one or more of sodium chloride, potassium chloride and sodium citrate；And/or
The pearling agent is selected from the one or more of glycol distearate and ethylene glycol monostearate；And/or
The zwitterionic surfactant is selected from Cocoamidopropyl betaine, cocamidopropyl propyl amide hydroxy sulfo lycine
One or more；And/or
The amino acid surfactant is selected from sodium lauroyl sarcosine, cocoyl sarcosine sodium, myristoyl-N-methylaminoacetic acid
Sodium, lauroyl Sodium Glycinate, lauroyl glycine potassium, methyl lauroyl sodium taurocholate and sodium methyl cocoyl taurate
It is one or more of；And/or
The high molecular polymer is selected from the one or more of PEG-14M, PEG-7M and PEG-90M；And/or
The acid-base modifier is selected from the one or more of citric acid, potassium hydroxide, sodium hydroxide；And/or
The preservative is selected from methylparaben, the one or more of propylben and Phenoxyethanol.
The present invention also provides the preparation methods of above-mentioned shower cream.
Concrete scheme is as follows:
A kind of preparation method of shower cream, comprising the following steps:
Each raw material is weighed by above-mentioned parts by weight；
The disodium ethylene diamine tetraacetate and inorganic salts are added in Xiang Shuizhong, and water temperature is 25-45 DEG C, and stirring is obtained to dissolving
Bright solution A；
Be added into the clear solution A liquid cleansing composition, cocounut oil both sexes sodium acetate, polyalcohol, pearling agent,
Amphoteric surfactant, amino acid surfactant, high molecular polymer and preservative are warming up to 50-60 DEG C, stir to molten
Solution, obtains solution B；
Acid-base modifier is added into the solution B, is cooled to 45-55 DEG C, adds cocounut oil acyl diethanol amine, stirs,
It is cooled to 40-45 DEG C again, essence is added, stirring obtains shower cream.
The present invention also provides a kind of facial cleansers.
The specific scheme is that
A kind of facial cleanser, based on parts by weight, including following raw material:
15-50 parts of liquid cleansing composition；0.1-2.0 parts of inorganic salts；1.0-5.0 parts of polyalcohol；Pearling agent 0.5-3.0
Part；5.0-18.0 parts of zwitterionic surfactant, 0.1-5.0 parts of cationic surfactant；Amino acid surfactant
0.5-5.0 parts；1.0-5.0 parts of suspending agent；3.0-8.0 parts of thickening stabilizing agent；0.01-0.1 parts of high molecular polymer；Preservative
0.05-0.5 parts；Disodium ethylene diamine tetraacetate 0.05-0.15；0.1-1.0 parts of essence；Appropriate amount of water.
In a wherein embodiment, the polyalcohol is selected from glycerol, 1,2 propylene glycol, 1,3 butanediols and 1, and 3 the third two
The one or more of alcohol；And/or
The inorganic salts are selected from the one or more of sodium chloride, potassium chloride and sodium citrate；And/or
The pearling agent is selected from the one or more of glycol distearate and ethylene glycol monostearate；And/or
The zwitterionic surfactant is selected from Cocoamidopropyl betaine, cocamidopropyl propyl amide hydroxy sulfo lycine
One or more；And/or
The cationic surfactant is selected from polyquaternium -7& polyquaternium -43；And/or
The amino acid surfactant is selected from sodium lauroyl sarcosine, methyl lauroyl sodium taurocholate, methyl cocoyl
The one or more of acyl taurines sodium and cocounut oil acyl hydrolysis avenin potassium；And/or
The suspending agent is selected from polyacrylate analog copolymer；And/or
The thickening stabilizing agent is selected from cornstarch & laruyl alcohol sulfosuccinate disodium；And/or
The high molecular polymer is selected from the one or more of PEG-14M, PEG-7M and PEG-90M；And/or
The preservative is selected from methylparaben, the one or more of propylben and Phenoxyethanol.
Compared with existing scheme, the invention has the following advantages:
(1) viscosity of the aforesaid liquid skin cleansing composition at 25 DEG C is 10.0-50.0mpa.s, pH 9.0-10.2, is clear
Clear bright low-viscosity (mobile) liquid soap.Its using natural oil, fatty acid as primary raw material, using by PEG/PPG-80/20 copolymer,
The nonionic surfactant of PEG-32 and PEG-6 composition is equipped with cocounut oil acyl hydrolysis avenin potassium and brown sugar, anti-by being saponified
It should be prepared, save all multi-nutrients such as polyunsaturated fatty acid, squalene, the glycerol in natural oil, Neng Gou
While cleaning skin surface smut, moisturizing, anti-oxidant, anti-inflammatory and other effects are played, low ph value not will cause dry skin, tight
It is taut, it can get and good wash rear skin sense.The environmentally protective easy degradation of raw material is free of harmful specified risk material.
(2) nonionic surfactant, the cocounut oil acyl water being made of PEG/PPG-80/20 copolymer, PEG-32 and PEG-6
Solve avenin potassium and brown sugar can solubilized grease soap, assist dissolution and the dispersion soap group of grease soap, promote natural oil soap energy
Enough reactions rapidly.And the nonionic table mixture living with natural component can be effectively reduced irritation.Meanwhile adding Gu Fahong
Sugar reduces the stimulation to skin, moreover it is possible to save microelement, amino acid etc., enhancing moisturizes the skin, moisturizing is antipruritic, strengthens skin knot
The effect of structure and skin elasticity.
(3) present composition can keep supernatant liquid state in the case where adding high level natural oil,
The concentration of clean skin effective component reaches 35%-45% or so (concentration of the clean skin effective component of common soap lye is 20-30%), adds
It is added in cleaning class product, there is better clean skin effect, and be easier to thicken.
(4) fluid present invention skin cleansing composition controls reaction condition during the preparation process, accelerates reaction rate, so that naturally
Grease conversion ratio is higher, and controls temperature, save the nutrition such as squalene, amount of grease in natural oil in unsaponifiable matter at
Point, enhance the effect of nourishing moisturizing moisturizing, by specific formula rate and technology controlling and process, is easy stirring point in saponification process
It dissipates, and final products are clear weak solution, are easy to add use, facilitate the application of downstream Management of Cosmetics Enterprises.
(5) the liquid cleansing composition of the present invention using specific components is matched as raw material and other surfaces activating agent and auxiliary agent
It closes, the skin cleaning types daily chemical products such as facial cleanser, shower cream can be prepared.The cleaning class product can form foam abundant, and steep
Foam is stablized, even if using in hard water, nor affects on its foam volume, is easy to rinse, does not have the skin sense not washed clean.And
All more stable within the scope of high and low temperature, holding composition is that liquid condition is easy to take even if under low temperature, also not precipitating crystal
With.
Specific embodiment
Liquid cleansing composition of the invention and its preparation method and application is made below in conjunction with specific embodiment further
Detailed description.
It is raw materials used in the specific embodiment of the invention, if can be derived from commercially available without specified otherwise, wherein
PEG/PPG-80/20 copolymer is purchased from Shanghai Hong Du Fine Chemical Co., Ltd, number-average molecular weight 15000.
PEG-32 is purchased from DOW Chemical.
PEG-6 is purchased from DOW Chemical.
Cocoamidopropyl betaine, trade name: CAB-35 is purchased from Guangzhou Startec Science and Technology Co., Ltd.；
Glycol distearate, trade name: EGDS is purchased from Rhodia；
Cocounut oil both sexes sodium acetate, trade name: HONDU SN30 is purchased from Shanghai Hong Du Fine Chemical Co., Ltd；
Sodium lauroyl sarcosine, trade name: LS-30 is bestowed by heaven new material Co., Ltd purchased from Guangzhou；
Cocounut oil acyl diethanol amine, trade name: 6501, it is purchased from Guangzhou good friend Co., Ltd；
Cornstarch & laruyl alcohol sulfosuccinate disodium, trade name: HC-10PLUS, purchased from the macro degree fining in Guangzhou
Work Co., Ltd；
Methyl lauroyl sodium taurocholate, trade name: HONDU LT-40, content are 50~60%, are purchased from the macro degree in Shanghai
Fine Chemical Co., Ltd；
Acrylic acid esters co-polymer, trade name: Carbopol Aqua SF-1, it is limited purchased from the weighing apparatus Trade Development of Guangzhou million
Company；
Polyquaternium -43 polyquaternium -7&, trade name: Supcare 627, it is limited purchased from the macro degree fine chemistry industry in Shanghai
Company.
Embodiment 1-6
Table 1 is the formula of the liquid cleansing composition of embodiment 1-6.
The preparation method of the liquid cleansing composition of embodiment 1-6 is as follows:
Raw material needed for weighing each embodiment by parts by weight shown in table 1.
Natural oil, fatty acid, part water, PEG/PPG-80/20 copolymer, PEG-32 and PEG-6 are mixed, are heated to
50-65 DEG C, stirring is completely dissolved to it becomes weak solution, keeps vacuum degree -0.05~0.2Mpa；
Potassium hydroxide and part water are mixedly configured into the potassium hydroxide solution that concentration is 40%, are slowly added dropwise step by step
Into the mixture of preceding step, and keep vacuum degree in 0.2Mpa, temperature is 60 DEG C, configures condensation reflux unit, opens simultaneously
Fast separating device is opened, holding dispersion rotary speed is 3000rpm, and cocounut oil acyl is added and hydrolyzes avenin potassium, brown sugar, stirs to molten
Solution, until material is thoroughly mixed, it is ensured that without conglomeration in reaction process.Heat preservation, until liquid level clarification is still；It is passed through 0-5 DEG C of condensation
Water, cooling to 20-25 DEG C can discharge.
Table 1
Embodiment 1 and comparative example 1-4
Table 2 is the formula of the liquid cleansing composition of embodiment 1 and comparative example 1~4.
The performance test of embodiment 1-6 and comparative example 1-4
Test 1 basic physicochemical property test.
Wherein, the test method of viscosity are as follows: composition is kept the temperature at 25 DEG C in advance, is rotated using NDJ-5S/NDJ-8S
Digital Viscometer measures.
Test result is as shown in table 3.
Table 3
As shown in Table 3, the liquid cleansing composition of embodiment 1-6 preparation, is all the transparent aqueous solution of clear low viscous,
When as basic cleaning material, facilitate extraction, and can be applied in transparent, opaque product, can be made liquid
The product of the various states such as body, paste, emulsion form.It is easy to stir evenly in process of production, from feeding intake, to be reacted to liquid complete
Clear process only needs 1~2 hour.
Comparative example 1 is by palmitinic acid instead of olive oil, and the viscosity of composition is very high, and Material is uneven.2 nothing of comparative example
Method is prepared into clear liquid composition, and the time for needing to grow very much could make composition clear.Comparative example 3 combines
Object viscosity is higher, and soap group is more, and taking more time can just be completely dissolved, and 4 transparency of comparative example decline, composition viscosity omits
Height, more soap group, taking more time can just be completely dissolved.
4 ' of 1 ' of embodiment, 4 ' of embodiment-embodiment, 6 ' and 1 ' of comparative example-comparative example
The composition of embodiment 1,4-6 and comparative example 1-4 is prepared into shower cream, respectively corresponds as 1 ' of embodiment, implement
4 ' of 4 ' of example-embodiment, 6 ' and 1 ' of comparative example-comparative example, formula are as shown in table 4.
Shower cream the preparation method is as follows:
Raw material needed for weighing each embodiment and comparative example by parts by weight shown in table 4.
Disodium ethylene diamine tetraacetate and sodium chloride is added in Xiang Shuizhong, and water temperature is 25 DEG C, and stirring obtains clear solution A to dissolving；
Corresponding liquid cleansing composition, cocounut oil both sexes sodium acetate, 1,2 propylene glycol, ethylene glycol are added into clear solution A
Distearate, Cocoamidopropyl betaine, sodium lauroyl sarcosine, PEG-14M and methylparaben, propylben,
It is warming up to 50-60 DEG C, stirring obtains solution B to dissolving；
Aqueous citric acid solution is added into solution B, is cooled to 45 DEG C, adds cocounut oil acyl diethanol amine, stirs, then cool down
To 40 DEG C, essence is added, stirring obtains shower cream.
Table 4
1 ' ' of embodiment
1 ' ' of embodiment provides a kind of facial cleanser, and table 5 is the formula of the facial cleanser of 1 ' ' of embodiment.Table 5
2 viscosity test of test case
Comfortable use feeling is an important factor for embodying cleaning class value of the product and the product ratings.Wherein clean class
The viscosity index and the packaging material of product, use feeling of product are closely related.Viscosity can properly be brought for consumer and more preferably use body
Sense.
The product of 1 ' of testing example, 1 ' ' of 4 ' of embodiment-embodiment, 6 ', 1 ' of comparative example-comparative example, 4 ' and embodiment glue
Degree, method particularly includes: each shower cream and facial cleanser are kept the temperature at 25 DEG C in advance, it is viscous using NDJ-5S/NDJ-8S rotary digital
Degree meter measures.
Test result is shown in Table 6:
Table 6
It is above-mentioned the experimental results showed that, by the embodiment of the present invention 1,4-6 prepare liquid cleansing composition be applied to shower cream
In mildy wash system, ideal viscosity can be reached, filling and consumer is facilitated to take.And prepared by comparative example 1,2,3,4
Liquid cleansing composition preparation shower cream, viscosity is too high, poor ductility, can not sprawl uniformly, state is discontinuous, filling difficulty
It spends high, and is not easy to take.
4 stability test of test case
Class product is cleaned durings transport, storage etc., temperature change can be encountered.It is therefore desirable to clean class product have compared with
Good high-low temperature resistant stability.
Test method is as follows: 1 ' of Example, 4 ' of embodiment-embodiment, 6 ', 1 ' of comparative example-comparative example, 4 ' and embodiment
The product of 1 ' ' is placed 30 days under 45 DEG C of temperature environments, under 0-5 DEG C of temperature environment, is placed 15 days, is investigated each product
High-low temperature resistant stability, the results are shown in Table 7.
Table 7
It is above-mentioned the experimental results showed that, the liquid cleansing composition of the embodiment of the present invention 1,4-6 is applied to shower cream and clean
In the cream system of face, there is not the phenomenon that precipitating crystal, being layered, shower cream in the case where high temperature, low temperature long-term preservation in product
Product stability is preferable.And the shower cream of the composition preparation in comparative example 1-4 is easy during high-low temperature resistant is investigated
There is phenomena such as layering, precipitate crystal, causes the appearance of product and using effect to change, adaptability of the product to temperature
It is poor.
The test of 5 foaming capacity of test case
The product of 1 ' of embodiment, 1 ' ' of 4 ' of embodiment-embodiment, 6 ', 1 ' of comparative example-comparative example, 4 ' and embodiment are sent out
Steep the test of power.Test method refers to Ross-Miles method, carries out the measurement of foaming power, and test uses deionized water.Test horse
5 minutes reading foam heights after upper reading foam height, test.Average test data such as table 8:
Table 8
It is above-mentioned the experimental results showed that, the liquid cleansing composition of the embodiment of the present invention 1,4-6 is applied to shower cream and clean
In the cream system of face, product foaming power is strong.Moreover, the facial cleanser of the 1 ' ' of shower cream and embodiment of 1 ' of embodiment and in hard water according to
So there is good foaming power.
The test of 6 body-sensing of test case
It cleans class product efficacy to evaluate mainly based on spatter property and body-sensing, wherein foam is abundanter, and thickening property is got over
Good, tight feeling is fewer, more Yi Chongxi, then body-sensing is better.
Test method: randomly selecting 10 volunteers, and each volunteer uses 1 ' of embodiment, 4 ' of embodiment-implementation
8 kinds of products of 6 ' of example, 1 ' ' of 3 ' of comparative example, 4 ' of comparative example and embodiment, application method are identical.
Volunteer is respectively foaming characteristic per a shower cream and facial cleanser, spatter property, easily using body-sensing according to respective
The marking of washability and tight property, 10 points of full marks, score more high effect is better, then, calculates 10 people to a shower cream
Average mark, evaluation result is as shown in table 9:
Table 9
It is above-mentioned the experimental results showed that, 1 ' of embodiment, the shower cream of 4 ' of embodiment-embodiment, 6 ', embodiment 1 ' ' wash one's face
Milk, preferably, the facial cleanser of 1 ' ' of especially 1 ' of embodiment and embodiment, foam is rich for scoring in the skin sense in cleaning force and after washing
Richness is easy to rinse, and does not have tight feeling, and as mild as a dove, irritation is low.
In 3 ' of comparative example, after cocounut oil acyl hydrolysis avenin potassium is replaced with sodium cocoyl glycinate, in use, foam is rich
Rich degree is inadequate, and bath property is not so good as 1 ' of embodiment.In 4 ' of comparative example, brown sugar is free of, it is tight to result in after washing drying, and irritation
It obviously increases.
Each technical characteristic of embodiment described above can be combined arbitrarily, for simplicity of description, not to above-mentioned reality
It applies all possible combination of each technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited
In contradiction, all should be considered as described in this specification.
The embodiments described above only express several embodiments of the present invention, and the description thereof is more specific and detailed, but simultaneously
Limitations on the scope of the patent of the present invention therefore cannot be interpreted as.It should be pointed out that for those of ordinary skill in the art
For, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to guarantor of the invention
Protect range.Therefore, the scope of protection of the patent of the invention shall be subject to the appended claims.
Claims (10)
1. a kind of liquid cleansing composition, which is characterized in that the raw material including following parts by weight:
The nonionic surfactant is the composition of PEG/PPG-80/20 copolymer, PEG-32 and PEG-6.
2. liquid cleansing composition according to claim 1, which is characterized in that the raw material including following parts by weight:
3. liquid cleansing composition according to claim 2, which is characterized in that the raw material including following parts by weight:
4. liquid cleansing composition according to claim 1-3, which is characterized in that the PEG/PPG-80/20
The weight ratio of copolymer, PEG-32 and PEG-6 are as follows: (5-10): (2-3): 1.
5. liquid cleansing composition according to claim 1-3, which is characterized in that the PEG/PPG-80/20
The number-average molecular weight of copolymer is 14000-16000.
6. liquid cleansing composition according to claim 1-3, which is characterized in that the natural oil is selected from coconut palm
One or more of seed oil, olive oil, camellia oil and rose hip oil.
7. liquid cleansing composition according to claim 1-3, which is characterized in that the fatty acid is selected from laurel
At least two in acid, myristic acid, palmitinic acid and stearic acid.
8. a kind of preparation method of the described in any item liquid cleansing compositions of claim 1-7, which is characterized in that including following
Step:
The natural oil, fatty acid, part water and nonionic surfactant are mixed, are heated to 50-65 DEG C, is stirred to it
It is completely dissolved, keeps the temperature, keep vacuum degree -0.05~0.2Mpa, obtain mixture；
The potassium hydroxide is mixed with part water, being configured to concentration is 35-45% potassium hydroxide solution, by the potassium hydroxide
Solution is slowly added drop-wise in the mixture, and in vacuum degree -0.05~0.2Mpa, temperature is at 50-65 DEG C, and homogenous disperse is extremely
Mixing completely, adds the cocounut oil acyl hydrolysis avenin potassium and brown sugar, and stirring obtains supernatant liquid, cool to 20- to dissolving
25 DEG C, discharging to get；
The revolving speed of the dispersion is 1000-8000rpm.
9. a kind of shower cream, which is characterized in that based on parts by weight, including following raw material:
20-55 parts of liquid cleansing composition；3.5-6.5 parts of cocounut oil both sexes sodium acetate；0.1-10 parts of polyalcohol；Inorganic salts 0.1-
2.0 part；0.5-2.5 parts of pearling agent；5.0-25.0 parts of amphoteric surfactant；0.5-5.0 parts of amino acid surfactant；High score
Sub- polymer 0.01-0.1 parts；0.01-0.20 parts of acid-base modifier；0.05-0.5 parts of preservative；Cocounut oil acyl diethanol amine 0-3.0
Part；Disodium ethylene diamine tetraacetate 0.05-0.1；0.1-1 parts of essence；Appropriate amount of water.
10. a kind of facial cleanser, which is characterized in that based on parts by weight, including following raw material:
15-50 parts of liquid cleansing composition；0.1-2.0 parts of inorganic salts；1.0-5.0 parts of polyalcohol；0.5-3.0 parts of pearling agent；Two
5.0-18.0 parts of ionic surface active agent, 0.1-5.0 parts of cationic surfactant of property；Amino acid surfactant 0.5-5.0
Part；1.0-5.0 parts of suspending agent；3.0-8.0 parts of thickening stabilizing agent；0.01-0.1 parts of high molecular polymer；Preservative 0.05-0.5
Part；Disodium ethylene diamine tetraacetate 0.05-0.15；0.1-1.0 parts of essence；Appropriate amount of water.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109984953A (en) * | 2019-05-22 | 2019-07-09 | 宁波御坊堂生物科技有限公司 | A kind of protein peptides take a shower, clean skin gel and preparation method thereof |
| CN110731915A (en) * | 2019-11-25 | 2020-01-31 | 广州宏度精细化工有限公司 | Cleaning cosmetic composition, preparation method thereof and cosmetic |
| CN112342100A (en) * | 2020-09-23 | 2021-02-09 | 广东倾镜日化有限公司 | Formula and preparation method of high-efficiency antibacterial low-irritation handmade soap |
| CN113616553A (en) * | 2021-09-08 | 2021-11-09 | 上海新高姿化妆品有限公司 | Mild and moisture-stable soap-based cleansing cream and preparation method thereof |
| CN115569091A (en) * | 2021-06-21 | 2023-01-06 | 海南师范大学 | Millettia speciosa and noni enzyme facial cleanser |
| CN115813788A (en) * | 2022-12-26 | 2023-03-21 | 福建片仔癀化妆品有限公司 | Mild self-corrosion-resistant and foam-dense cleansing bubble liquid and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1999242A1 (en) * | 2006-03-28 | 2008-12-10 | Stepan Company | Water compatible emollient for cleansing products related applications |
| CN103301051A (en) * | 2012-03-07 | 2013-09-18 | 南京华狮化工有限公司 | Transparent beauty treatment soap composition |
| CN107854392A (en) * | 2017-10-31 | 2018-03-30 | 广州柏俐臣化妆品有限公司 | A kind of brown sugar mildy wash and preparation method thereof |
-
2018
- 2018-11-09 CN CN201811329653.9A patent/CN109401869B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1999242A1 (en) * | 2006-03-28 | 2008-12-10 | Stepan Company | Water compatible emollient for cleansing products related applications |
| CN103301051A (en) * | 2012-03-07 | 2013-09-18 | 南京华狮化工有限公司 | Transparent beauty treatment soap composition |
| CN107854392A (en) * | 2017-10-31 | 2018-03-30 | 广州柏俐臣化妆品有限公司 | A kind of brown sugar mildy wash and preparation method thereof |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109984953A (en) * | 2019-05-22 | 2019-07-09 | 宁波御坊堂生物科技有限公司 | A kind of protein peptides take a shower, clean skin gel and preparation method thereof |
| CN109984953B (en) * | 2019-05-22 | 2022-08-19 | 宁波御坊堂生物科技有限公司 | Protein peptide gel for bath and skin cleaning and preparation method thereof |
| CN110731915A (en) * | 2019-11-25 | 2020-01-31 | 广州宏度精细化工有限公司 | Cleaning cosmetic composition, preparation method thereof and cosmetic |
| CN112342100A (en) * | 2020-09-23 | 2021-02-09 | 广东倾镜日化有限公司 | Formula and preparation method of high-efficiency antibacterial low-irritation handmade soap |
| CN115569091A (en) * | 2021-06-21 | 2023-01-06 | 海南师范大学 | Millettia speciosa and noni enzyme facial cleanser |
| CN115569091B (en) * | 2021-06-21 | 2024-03-26 | 海南师范大学 | Millettia speciosa and noni enzyme facial cleanser |
| CN113616553A (en) * | 2021-09-08 | 2021-11-09 | 上海新高姿化妆品有限公司 | Mild and moisture-stable soap-based cleansing cream and preparation method thereof |
| CN113616553B (en) * | 2021-09-08 | 2023-02-10 | 上海新高姿化妆品有限公司 | Mild and moisture-stable soap-based cleansing cream and preparation method thereof |
| CN115813788A (en) * | 2022-12-26 | 2023-03-21 | 福建片仔癀化妆品有限公司 | Mild self-corrosion-resistant and foam-dense cleansing bubble liquid and preparation method thereof |
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