CN109010137A - A kind of salubrious humidity-preserving type is without silicone oil shampoo - Google Patents
A kind of salubrious humidity-preserving type is without silicone oil shampoo Download PDFInfo
- Publication number
- CN109010137A CN109010137A CN201811160323.1A CN201811160323A CN109010137A CN 109010137 A CN109010137 A CN 109010137A CN 201811160323 A CN201811160323 A CN 201811160323A CN 109010137 A CN109010137 A CN 109010137A
- Authority
- CN
- China
- Prior art keywords
- salubrious
- shampoo
- humidity
- oil
- silicone oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/064—Water-in-oil emulsions, e.g. Water-in-silicone emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/002—Preparations for repairing the hair, e.g. hair cure
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/34—Free of silicones
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Chemical & Material Sciences (AREA)
- Emergency Medicine (AREA)
- Dermatology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dispersion Chemistry (AREA)
- Cosmetics (AREA)
Abstract
The invention belongs to daily cosmetics fields, and in particular to a kind of salubrious humidity-preserving type is without silicone oil shampoo.A kind of salubrious humidity-preserving type is without silicone oil shampoo, which is characterized in that by mass percentage, raw material composition includes: propylene glycol 0.1-2%；Cation opsonizing agent 0.05-0.5%；Cocounut oil acid methyl single ethanol amide 0.5-3%；Disodium ethylene diamine tetraacetate 0.05-0.2%；Citric acid 0.05-0.5%；Sodium citrate 0.05-2%；Anionic surfactant 10-25%；Gel water-in-oil emulsion composition 0.1-3%；PEG-7 cocounut oil acid glyceride 2-5%；Zwitterionic surfactant 1-9%；Essence 0.05-1%；Cithrol 0.1-1%；Inorganic salts thickener 0.1-2%；Alkyl glycosides 1-5%；Preservative 0.0001-0.1%；Pigment 0.0001-0.01%；Water 41-84%.The compound system that the collaborations such as cation opsonizing agent, cocounut oil acid methyl single ethanol amide, anionic surfactant form in shampoo of the present invention, enhance the stability of shampoo, the viscosity for not destroying system has the effect of that scalp, hair are nourished in salubrious moisturizing, safety.
Description
Technical field
The invention belongs to daily cosmetics fields, and in particular to a kind of salubrious humidity-preserving type is without silicone oil shampoo.
Background technique
Shampoo also known as shampoo, be a kind of collection Surfactants solution, oily matter solubilising, dispersion suspend, high score
The complex system that sub- colloidal solution is integrated.The major function of shampoo is cleaning hair and scalp, and is beaten for the maintenance of hair
Lower basis.With the development of technology, also increasingly increase the effect of shampoo, nowadays have evolved into degreasing, anti-dandruff, taste
The product of the multiple functions such as profit, hair care, anticreep, hair tonic.Now, while people pursue conditioning effect, shampoo is also required
Adverse effect will not be generated to scalp, hair and human health.And the conditioning ingredients in most of shampoo have skin
Certain irritation, and smooth feel is brought to moisten hair, usually using silicone oil conditioner.It is used for a long time siliceous
The shampoo of oil, silicone oil easily adsorb and are deposited on scalp, are difficult to rinse on hair, make that hair is greasy, it is short-tempered to dry up or even is easy to draw
Play dandruff problem.
In view of the above problems, the present invention provides a kind of salubrious humidity-preserving types without silicone oil shampoo, wherein using air permeable humidity retaining
Gel water-in-oil emulsion composition replace silicone oil to be attached on hair, fill up and repair impaired hair scale piece.Meanwhile it having one's hair wash
The compound system that each group is grouped as in water, enhances the low-temperature stability of shampoo, does not destroy the viscosity of system, reaches health and washes
Shield, salubrious moisturizing, the safe effect for nourishing scalp, hair.
Summary of the invention
Above-mentioned technical purpose of the invention has the technical scheme that
A kind of salubrious humidity-preserving type is without silicone oil shampoo, and by mass percentage, raw material composition includes:
Propylene glycol 0.1-2%；Cation opsonizing agent 0.05-0.5%；Cocounut oil acid methyl single ethanol amide 0.5-3%；Second two
Amine tetraacethyl disodium 0.05-0.2%；Citric acid 0.05-0.5%；Sodium citrate 0.05-2%；Anionic surfactant 10-
25%；Gel water-in-oil emulsion composition 0.1-3%；PEG-7 cocounut oil acid glyceride 2-5%；Amphoteric ion surface-active
Agent 1-9%；Essence 0.05-1%；Cithrol 0.1-1%；Inorganic salts thickener 0.1-2%；Alkyl glycosides 1-
5%；Preservative 0.0001-0.1%；Pigment 0.0001-0.01%；Water 41-84%.
Preferably, a kind of salubrious humidity-preserving type is without silicone oil shampoo, and by mass percentage, raw material composition includes:
Propylene glycol 0.1-2%；Guar hydroxypropyltrimonium ammonium chloride 0.05-0.5%；Cocounut oil acid methyl single ethanol amide
0.5-3%；Disodium ethylene diamine tetraacetate 0.05-0.2%；Citric acid 0.05-0.5%；Sodium citrate 0.05-2%；Dodecyl
Sodium sulphate 0.5-5%；Sodium sulfate of polyethenoxy ether of fatty alcohol 10-20%；；Gel water-in-oil emulsion composition 0.1-3%；
PEG-7 cocounut oil acid glyceride 2-5%；Cocoamidopropyl betaine 1-9%；Menthol 0.05-1%；PEG-6000 distearyl
Acid esters 0.1-1%；Sodium chloride 0.1-2%；APG0810 alkyl glycosides 1-5%；Kathon CG 0.0001-0.1%；Lemon yellow 0.0001-
0.01%；Brilliant blue 0.0001-0.01%；Water 45-80%.
It is further preferred that a kind of salubrious humidity-preserving type is without silicone oil shampoo, by mass percentage, by following components group
At:
Propylene glycol 0.5%；Guar hydroxypropyltrimonium ammonium chloride 0.15%；Cocounut oil acid methyl single ethanol amide 1%；Second
Edetate disodium 0.1%；Citric acid 0.15%；Sodium citrate 1.25%；Lauryl sodium sulfate 1%；Fatty alcohol polyoxy
Ethylene ether sodium sulfate 14%；Gel water-in-oil emulsion composition 1%；PEG-7 cocounut oil acid glyceride 2%；Coconut oleoyl amine third
Base glycine betaine 3.33%；Essence 0.1%；PEG-6000 distearate 0.6%；APG0810 alkyl glycosides 1.5%；Sodium chloride
0.5%；Kathon CG 0.04%；Lemon yellow 0.0004%；Brilliant blue 0.0004%；Surplus is water.
Preferably, the gel water-in-oil emulsion composition is trimethylolpropane tris caprylate, saualane, Ci A
The composition of dry tree benevolence oil, polyglycereol -2 three isostearates and water, by mass percentage, raw material composition includes 60-
80% trimethylolpropane tris caprylate；The saualane of 1-10%；The thorn A Gan tree benevolence oil of 1-10%；Gathering for 1-10% is sweet
Oily -2 three isostearates；The water of 1-10%.
It is further preferred that the gel water-in-oil emulsion composition is prepared by following methods:
(1) by the trimethylolpropane tris caprylate of 60-80%, the thorn A Gan tree benevolence of the saualane of 1-10%, 1-10%
Oil is added in oily phase pot, stirs evenly, obtains mixed liquor A；(2) three isostearate of the polyglycereol -2 of 1-10% is added and is mixed
Where liquid A in oily phase pot, stirs evenly, obtain oil-phase solution；(3) water of 1-10% is slowly pumped into above-mentioned oil-phase solution,
It stirs at low speed and a kind of gel water-in-oil emulsion composition is prepared.
Preferably, the cation opsonizing agent is guar hydroxypropyltrimonium ammonium chloride, Polyquaternium-10 and polyquaternary amine
One of salt -7 is a variety of.
It is further preferred that the cation opsonizing agent is guar hydroxypropyltrimonium ammonium chloride.
Preferably, the anionic surfactant is lauryl sodium sulfate, ammonium lauryl sulfate, fatty alcohol polyoxy
One of ethylene ether sodium sulfate, alpha-olefin sodium sulfonate, fatty alcohol polyoxyethylene ether ammonium sulfate and lauric acid sodium taurocholate are more
Kind.
It is further preferred that the anionic surfactant is lauryl sodium sulfate, fatty alcohol polyoxyethylene ether sulphur
The weight ratio of the composition of sour sodium, the lauryl sodium sulfate and sodium sulfate of polyethenoxy ether of fatty alcohol is 1:14-16.
Preferably, the inorganic salts thickener is sodium chloride.
Preferably, the cithrol is PEG-6000 distearate.
Preferably, the alkyl glycosides is APG-0810 alkyl glycosides, APG-1220 alkyl glycosides, APG-0814 alkyl sugar
One of glycosides is a variety of.
It is further preferred that the alkyl glycosides is APG-0810 alkyl glycosides.
Preferably, the zwitterionic surfactant is Cocoamidopropyl betaine, dodecyl dimethyl beet
One of alkali and palmitamide propyl betaine are a variety of.
It is further preferred that the zwitterionic surfactant is Cocoamidopropyl betaine.
Preferably, the preservative is one of Kathon CG, sodium benzoate, Phenoxyethanol, paraben esters or a variety of.
It is further preferred that the preservative is Kathon CG.
Preferably, the pigment is one of brilliant blue, lemon yellow or a variety of.
It is further preferred that the pigment is brilliant blue, the composition in lemon yellow, sunset yellow, the brilliant blue and lemon yellow
Weight ratio be 1:1.
The present invention also provides a kind of preparation method of the salubrious humidity-preserving type without silicone oil shampoo, the preparation method include with
Lower step:
(1) cation opsonizing agent and citric acid are added to the water, homogeneous is transparent to solution, is warming up to 70-80 DEG C, is mixed
Close solution A；
(2) under 70-80 DEG C and stirring condition, by disodium ethylene diamine tetraacetate, sodium citrate, cithrol,
Anionic surfactant, cocounut oil acid methyl single ethanol amide are added in mixed solution A, obtain mixed solution B；
(3) PEG-7 cocounut oil acid glyceride and gel water-in-oil emulsion composition are mixed, obtains mixed solution C；
(4) zwitterionic surfactant, alkyl glycosides and mixed solution C are added in mixed solution B, at 70-80 DEG C
Lower stirring keeps the temperature 30min, obtains mixed solution D；
(5) solution D to be mixed is cooled to 25-45 DEG C, and propylene glycol, essence, citric acid, preservative, pigment, sodium chloride are added
Enter and mixed in mixed solution D, stirred evenly, the salubrious humidity-preserving type is made without silicone oil shampoo.
Compared with prior art, the beneficial effects of the present invention are:
It joined the gel water-in-oil emulsion composition quite similar with scalp sebum structure in inventive formulation, show
Writing to reduce stimulates caused by scalp, improves safety.The gel water-in-oil emulsion composition of air permeable humidity retaining replaces silicone oil
It is attached on hair, fills up and repair impaired hair scale piece.Meanwhile cation opsonizing agent, cocounut oil acid methyl monoethanol in shampoo
The compound system of the collaborations such as amide, anionic surfactant composition, enhances the low-temperature stability of shampoo, does not destroy system
Viscosity, achieved the effect that salubrious moisturizing, safety nourish scalp, hair.
Specific embodiment
Embodiment of the present invention is described in detail below in conjunction with specific embodiment, the embodiment provided is only
Reach illustration purpose, can not be interpreted as limitation of the invention.Constituent content in following embodiments, such as without special theory
It is bright, it is mass percent.
Embodiment 1-6
Embodiment 1-3 is according to a kind of salubrious humidity-preserving type provided by the invention without silicone oil shampoo, and contained component includes melon
That glue hydroxypropyl-trimethyl ammonium chloride, propylene glycol, cocounut oil acid methyl single ethanol amide (CMMEA), disodium ethylene diamine tetraacetate
(EDTA-2Na), citric acid, sodium citrate, lauryl sodium sulfate (K12), sodium sulfate of polyethenoxy ether of fatty alcohol (AES), solidifying
Gluey water-in-oil type emulsion compositions, PEG-7 cocounut oil acid glyceride (HE), Cocoamidopropyl betaine (CAB), essence are (thin
Lotus alcohol), PEG-6000 distearate, APG-0810 alkyl glycosides, sodium chloride, Kathon CG, lemon yellow, brilliant blue, water.
Embodiment 4-6 is the shampoo prepared according to inventive formulation, and contained component includes guar hydroxypropyltrimonium
Ammonium chloride, Polyquaternium-10, propylene glycol, CMMEA, EDTA-2Na, citric acid, sodium citrate, K12, ammonium lauryl sulfate
(K12A), laureth ammonium sulfate (AESA), alpha-olefin sodium sulfonate, gel water-in-oil emulsion composition, HE, CAB, ten
Dialkyl dimethyl glycine betaine, menthol, PEG-6000 distearate, APG-0810 alkyl glycosides, sodium chloride, Kathon CG, lemon
Lemon Huang, brilliant blue, water.
Comparative example 7-9
Component contained by comparative example 7-9 includes guar hydroxypropyltrimonium ammonium chloride, propylene glycol, cation flocculation guarantor
Wet conditioner (QZ-1001), coconut oil fatty acid monoethanolamide (CMEA), cocounut oil acid methyl single ethanol amide (CMMEA), second
Edetate disodium (EDTA-2Na), citric acid, sodium citrate, lauryl sodium sulfate (K12), fatty alcohol polyoxyethylene ether
Sodium sulphate (AES), gel water-in-oil emulsion composition, PEG-7 cocounut oil acid glyceride (HE), Cocoamidopropyl betaine
(CAB), essence (menthol), PEG-6000 distearate, APG-0810 alkyl glycosides, sodium chloride, Kathon CG, lemon yellow, bright
Blue, water.
Cation flocculation moisture-regulating agent (QZ-1001) is that our company is commercially available by polyquaternium -49, pyrrolidones carboxylic
The compound that sour sodium, sodium lactate, sodium citrate, glutamic acid, water compound.
Comparative example 7, the difference with 1-6 of the embodiment of the present invention are, increase 2% QZ-1001.
Comparative example 8, the difference with 1-6 of the embodiment of the present invention are, guar gum is substituted using 2% QZ-1001
Hydroxypropyl-trimethyl ammonium chloride.
Comparative example 9, the difference with 1-6 of the embodiment of the present invention are, CMMEA is substituted for CMEA.
A kind of preparation of gel water-in-oil emulsion composition
A kind of gel water-in-oil emulsion composition, constitutive material are as follows: 70% trimethylolpropane tris octanoic acid
Ester；5% saualane；5% thorn A Gan tree benevolence oil；10% three isostearate of polyglycereol -2；10% water.
The gel water-in-oil emulsion composition, is prepared by following methods:
(1) weigh 70% trimethylolpropane tris caprylate, 5% saualane, 5% thorn A Gan tree benevolence oil, be put into
In oily phase pot, stirs evenly, obtain mixed liquor A；(2) three isostearate of polyglycereol -2 for weighing certain proportion 10%, which is added, to be mixed
Where closing liquid A in oily phase pot, stirs evenly, obtain oil-phase solution；(3) 10% water is slowly pumped into above-mentioned oil-phase solution
In, it stirs at low speed, a kind of gel water-in-oil emulsion composition is prepared.
Component information contained by embodiment 1-3 is as shown in table 1, and component information contained by embodiment 4-6 is as shown in table 2, real
It is as shown in table 3 to apply component information contained by a 7-9.
The component information table of 1 embodiment 1-3 of table
The component information table of 2 embodiment 4-6 of table
The component information table of 3 embodiment 7-9 of table
A kind of preparation of the salubrious humidity-preserving type without silicone oil shampoo
Salubrious humidity-preserving type in embodiment 1-6 is prepared by the following method without silicone oil shampoo:
(1) guar hydroxypropyltrimonium ammonium chloride/Polyquaternium-10, a small amount of citric acid are put into water, and homogeneous is formed
Transparency liquid is warming up to 75 DEG C, obtains mixed solution A；
(2) by EDTA-2Na, sodium citrate, PEG-6000 distearate, K12/K12A, AES/AESA/ alpha-olefin sulphur
Sour sodium, CMMEA are put into mixed solution A, and temperature is maintained at 75 DEG C, and stirring forms transparent clear solution, obtain mixed solution
B；
(3) HE and gel water-in-oil emulsion composition are mixed, obtains mixed solution C；
(4) by CAB/ dodecyldimethylammonium hydroxide inner salt, APG-0810 alkyl glycosides/APG-1220 alkyl glycosides and mixing
Solution C is added in mixed solution B, stirs at 75 DEG C, keeps the temperature 30min, obtains mixed solution D；
(5) solution D to be mixed is cooled to 45 DEG C hereinafter, propylene glycol is uniformly mixed with essence (menthol), with citric acid,
Kathon CG, lemon yellow mix in brilliant blue investment mixed solution D, and sodium chloride is added, stirs evenly, be made a kind of salubrious humidity-preserving type without
Silicone oil shampoo.
The preparation method of embodiment 7-9 shampoo is identical as embodiment 1-6, the cation added in comparative example 7-9
Moisture-regulating agent of flocculating is added in step (1).
Testing example 1: stability experiment
The stability test experiment condition of hair washing is respectively as follows: heat-resistant stability, and shampoo is placed at 40 DEG C for 24 hours, extensive
Whether there is or not laminations for observation after multiple room temperature；Shampoo is placed under 5 DEG C of refrigerating chamber for 24 hours, restores room temperature by cold resistance stability
After observe phenomenon.And be placed on shampoo under -10 DEG C of freezing chamber for 24 hours, phenomenon is observed after restoring room temperature, test result is such as
Shown in table 4.
The stability test result of 4 embodiment 1-9 of table
The QZ-1001 that can promote flocculation enhancing oil-control, but shampoo stablizing effect obtained are added in comparative example 7-8
Not as good as 1-6 of the embodiment of the present invention, easily occurs layering turbid phenomenon in low temperature.In comparative example 8 be added QZ-1001 instead of
Opaque state is presented in guar hydroxypropyltrimonium ammonium chloride, shampoo obtained, and system is very unstable.Comparative example 9
CMMEA is substituted for CMEA, obtained shampoo can only be able to maintain stabilization in a short time, be unfavorable for shampoo industrial production and reality
Long-term preservation in the application of border.
Testing example 2: applied experiments
(A is the siliceous shampoo of certain brand of market sale, certain product that B is market sale to the comparison of this product applied experiments
Board tea-seed oil is salubrious humidity-preserving type described in embodiment 2 in inventive formulation without silicon shampoo without silicone oil shampoo, C).
Test equipment: combing force tester.
Test sample: import topknot (30 ± 1cm of length, 10 ± 1g of weight).
Test method: first surveying the dry and wet carding force of blank topknot, after 2g hair washing water process hair, test hair washing water process
The dry and wet carding force of topknot afterwards, the relatively variation of front and back carding force.Flushing period 30s, resistance unit are newton, and test result is such as
Shown in table 5.
The test result contrast table of salubrious humidity-preserving type shampoo described in 5 commercial product of table and embodiment 2
Embodiment 1 and 3-6 retest embodiment 2 obtain contrast effect even more preferably similar with table 5, wherein
The wet carding force of embodiment 1 and 3-6 reduce 78.10%, 77.41%, 80.08%, 79.83%, 78.87% respectively；Dry comb
Reason power reduces 53.25%, 52.86%, 55.20%, 50.80%, 55.39% respectively.
In conclusion cation opsonizing agent, cocounut oil acid methyl single ethanol amide, anionic surface are living in shampoo of the present invention
Property components such as agent and its proportion collaboration, enhance the stability of shampoo, do not destroy the viscosity of system.It is added and scalp sebum knot
The quite similar gel water-in-oil emulsion composition of structure, significant decrease are stimulated caused by scalp, improve safety, are breathed freely
The gel water-in-oil emulsion composition of moisturizing can replace silicone oil to be attached on hair, fill up and repair impaired hair scale piece.It washes
Shampoo has foam abundant, can obviously reduce hair dry and wet combing resistance, there is salubrious moisturizing, safety to nourish head after use
The effect of skin, hair.
Claims (10)
1. a kind of salubrious humidity-preserving type is without silicone oil shampoo, which is characterized in that by mass percentage, raw material composition includes: third
Glycol 0.1-2%；Cation opsonizing agent 0.05-0.5%；Cocounut oil acid methyl single ethanol amide 0.5-3%；Ethylenediamine tetra-acetic acid two
Sodium 0.05-0.2%；Citric acid 0.05-0.5%；Sodium citrate 0.05-2%；Anionic surfactant 10-25%；Gel
Water-in-oil emulsion composition 0.1-3%；PEG-7 cocounut oil acid glyceride 2-5%；Zwitterionic surfactant 1-9%；Essence
0.05-1%；Cithrol 0.1-1%；Inorganic salts thickener 0.1-2%；Alkyl glycosides 1-5%；Preservative
0.0001-0.1%；Pigment 0.0001-0.01%；Water 41-84%.
2. a kind of salubrious humidity-preserving type as described in claim 1 is without silicone oil shampoo, which is characterized in that by mass percentage,
Its raw material composition includes: propylene glycol 0.1-2%；Guar hydroxypropyltrimonium ammonium chloride 0.05-0.5%；Cocounut oil acid methyl list
Glycollic amide 0.5-3%；Disodium ethylene diamine tetraacetate 0.05-0.2%；Citric acid 0.05-0.5%；Sodium citrate 0.05-2%；
Lauryl sodium sulfate 0.5-5%；Sodium sulfate of polyethenoxy ether of fatty alcohol 10-20%；；Gel water-in-oil emulsion composition
0.1-3%；PEG-7 cocounut oil acid glyceride 2-5%；Cocoamidopropyl betaine 1-9%；Menthol 0.05-1%；PEG-
6000 distearate 0.1-1%；Sodium chloride 0.1-2%；APG0810 alkyl glycosides 1-5%；Kathon CG 0.0001-0.1%；Lemon
Lemon Huang 0.0001-0.01%；Brilliant blue 0.0001-0.01%；Water 45-80%.
3. a kind of salubrious humidity-preserving type as claimed in claim 1 or 2 is without silicone oil shampoo, which is characterized in that the gel oil
Water-in type emulsion compositions are to prepare gained with the following method: by weight percentage, taking raw material: the three hydroxyl first of 60-80%
Three caprylate of base propane, the saualane of 1-10%, 1-10% thorn A Gan tree benevolence oil, -2 three isostearic acid of 1-10% polyglycereol
The water of ester, 1-10%；
Step 1): by the trimethylolpropane tris caprylate of 60-80%, the thorn A Gan tree benevolence of the saualane of 1-10%, 1-10%
Oil is added in oily phase pot, stirs evenly, obtains mixed liquor A；
Step 2): it where mixed liquor A is added in three isostearate of polyglycereol -2 of 1-10% in oily phase pot, stirs evenly, obtains
To oil-phase solution；
Step 3): the water of 1-10% is slowly pumped into above-mentioned oil-phase solution, stirs at low speed and the gel oil packet is prepared
Water emulsion composition.
4. a kind of salubrious humidity-preserving type as described in claim 1 is without silicone oil shampoo, which is characterized in that the cation opsonizing agent
For one of guar hydroxypropyltrimonium ammonium chloride, Polyquaternium-10 and polyquaternium -7 or a variety of.
5. a kind of salubrious humidity-preserving type as described in claim 1 is without silicone oil shampoo, which is characterized in that the anionic surface is living
Property agent be lauryl sodium sulfate, ammonium lauryl sulfate, sodium sulfate of polyethenoxy ether of fatty alcohol, alpha-olefin sodium sulfonate, fat
One of alcohol polyoxyethylene ether ammonium sulfate and lauric acid sodium taurocholate are a variety of.
6. a kind of salubrious humidity-preserving type as described in claim 1 is without silicone oil shampoo, which is characterized in that the amphoteric ion surface
Activating agent be one of Cocoamidopropyl betaine, dodecyldimethylammonium hydroxide inner salt and palmitamide propyl betaine or
It is a variety of.
7. a kind of salubrious humidity-preserving type as described in claim 1 is without silicone oil shampoo, which is characterized in that the preservative is card
One of pine, sodium benzoate, Phenoxyethanol, paraben esters are a variety of.
8. a kind of salubrious humidity-preserving type as described in claim 1 is without silicone oil shampoo, which is characterized in that the pigment be brilliant blue,
One of lemon yellow, sunset yellow are a variety of.
9. a kind of salubrious humidity-preserving type as described in claim 1 is without silicone oil shampoo, which is characterized in that the alkyl glycosides is
One of APG-0810 alkyl glycosides, APG-1220 alkyl glycosides, APG-0814 alkyl glycosides are a variety of.
10. a kind of prepare method of the salubrious humidity-preserving type without silicone oil shampoo using raw material described in claim 1, which is characterized in that
In the preparation method, ratio used in each raw material is as described in claim 1 comprising the steps of:
(1) cation opsonizing agent and citric acid are added to the water, homogeneous is transparent to solution, is warming up to 70-80 DEG C, obtains mixing molten
Liquid A；
(2) under 70-80 DEG C and stirring condition, by disodium ethylene diamine tetraacetate, sodium citrate, cithrol, yin from
Sub- surfactant, cocounut oil acid methyl single ethanol amide are added in mixed solution A, obtain mixed solution B；
(3) PEG-7 cocounut oil acid glyceride and gel water-in-oil emulsion composition are mixed, obtains mixed solution C；
(4) zwitterionic surfactant, alkyl glycosides and mixed solution C are added in mixed solution B, are stirred at 70-80 DEG C
It mixes, keeps the temperature 30min, obtain mixed solution D；
(5) solution D to be mixed is cooled to 25-45 DEG C, propylene glycol, essence, citric acid, preservative, pigment, sodium chloride is added mixed
It closes and is mixed in solution D, stir evenly, the salubrious humidity-preserving type is made without silicone oil shampoo.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811160323.1A CN109010137A (en) | 2018-09-30 | 2018-09-30 | A kind of salubrious humidity-preserving type is without silicone oil shampoo |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811160323.1A CN109010137A (en) | 2018-09-30 | 2018-09-30 | A kind of salubrious humidity-preserving type is without silicone oil shampoo |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109010137A true CN109010137A (en) | 2018-12-18 |
Family
ID=64615495
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811160323.1A Pending CN109010137A (en) | 2018-09-30 | 2018-09-30 | A kind of salubrious humidity-preserving type is without silicone oil shampoo |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109010137A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114288209A (en) * | 2021-10-25 | 2022-04-08 | 纳爱斯丽水日化有限公司 | Double-layer shampoo composition and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104921989A (en) * | 2015-06-12 | 2015-09-23 | 广州环亚化妆品科技有限公司 | Liquid shampoo without silicon oil and with hair caring effect and preparation method thereof |
| CN105726406A (en) * | 2016-03-24 | 2016-07-06 | 攀柔莎（江苏）生物科技股份有限公司 | Refreshing anti-dandruff shampoo without silicone oil |
| CN106580726A (en) * | 2016-11-11 | 2017-04-26 | 珠海伊斯佳科技股份有限公司 | Silicone-oil-free liquid shampoo containing amino acid and preparation method of silicone-oil-free liquid shampoo |
| CN107997974A (en) * | 2017-12-04 | 2018-05-08 | 广州天赐高新材料股份有限公司 | Contain a kind of detergent composition of polyol |
| CN108553334A (en) * | 2018-07-19 | 2018-09-21 | 广州环亚化妆品科技有限公司 | A kind of hair care composition of the smooth not silicate-containing oil of maintenance and its application |
-
2018
- 2018-09-30 CN CN201811160323.1A patent/CN109010137A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104921989A (en) * | 2015-06-12 | 2015-09-23 | 广州环亚化妆品科技有限公司 | Liquid shampoo without silicon oil and with hair caring effect and preparation method thereof |
| CN105726406A (en) * | 2016-03-24 | 2016-07-06 | 攀柔莎（江苏）生物科技股份有限公司 | Refreshing anti-dandruff shampoo without silicone oil |
| CN106580726A (en) * | 2016-11-11 | 2017-04-26 | 珠海伊斯佳科技股份有限公司 | Silicone-oil-free liquid shampoo containing amino acid and preparation method of silicone-oil-free liquid shampoo |
| CN107997974A (en) * | 2017-12-04 | 2018-05-08 | 广州天赐高新材料股份有限公司 | Contain a kind of detergent composition of polyol |
| CN108553334A (en) * | 2018-07-19 | 2018-09-21 | 广州环亚化妆品科技有限公司 | A kind of hair care composition of the smooth not silicate-containing oil of maintenance and its application |
Non-Patent Citations (1)
| Title |
|---|
| 李仲华等: ""三羟甲基丙烷三辛酸酯/三癸酸酯在洗发香波中的应用"", 《中国洗涤用品工业》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114288209A (en) * | 2021-10-25 | 2022-04-08 | 纳爱斯丽水日化有限公司 | Double-layer shampoo composition and preparation method thereof |
| CN114288209B (en) * | 2021-10-25 | 2023-11-24 | 纳爱斯丽水日化有限公司 | Double-layer shampoo composition and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104224575B (en) | It is a kind of transparent without silicone oil hair-washing composition and preparation method thereof | |
| CN109498494A (en) | A kind of salubrious oil-control is without silicone oil shampoo and preparation method thereof | |
| KR20180109879A (en) | Clarified thickening cleansing composition and its application and manufacturing method | |
| EP0020706A1 (en) | Water soluble lecithin composition | |
| CN1988878A (en) | Mild, moisturizing sulfosuccinate cleansing compositions | |
| US20070232508A1 (en) | Cream-type skin cleansing composition | |
| CN110151578A (en) | A kind of clean face cream of amino acid skin-active and preparation method thereof of mild cleaning moisturizing | |
| CN104997661A (en) | Mild silicone-oil-free shampoo in cation system and preparing method thereof | |
| CN102552056B (en) | Shampoo composition | |
| CN102940585B (en) | Healthy shampoo taking natural source raw materials as main component | |
| CN108685734A (en) | A kind of no sulfate is without the low mild plant herbal shampoo of stimulation of silicon | |
| CN106361660A (en) | Sulfate-anionic-surfactant-free silicone-oil-free shampoo composition | |
| CN104257525A (en) | Oil-control shampoo and preparation method thereof | |
| CN108904311A (en) | A kind of no silicone oil shampoo | |
| CN109401869A (en) | Liquid cleansing composition and its preparation method and application | |
| CN105878128A (en) | Silicon-free transparent shampoo containing humectant and preparing method of silicon-free transparent shampoo | |
| CN106109275B (en) | A kind of foaming bath oil and preparation method thereof rich in vegetable oil | |
| CN104523450A (en) | Novel hair washing/caring/nourishing composition | |
| CN109288725A (en) | A kind of transparent amino acid pattern is without silicone oil shampoo | |
| CN109010137A (en) | A kind of salubrious humidity-preserving type is without silicone oil shampoo | |
| CN104684535B (en) | Foam improvement of soap containing compositions | |
| CN115645298B (en) | Personal care composition, preparation method and application | |
| CN114366693B (en) | Shampoo bath lotion for infants | |
| BR112018015326B1 (en) | Sulfate-free aqueous composition for personal hygiene and use of such compositions | |
| CN108852914A (en) | It is a kind of have effects that nourish repair without silicone oil shampoo |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181218 |