CN104224575B - It is a kind of transparent without silicone oil hair-washing composition and preparation method thereof - Google Patents
It is a kind of transparent without silicone oil hair-washing composition and preparation method thereof Download PDFInfo
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Abstract
The invention provides one kind is transparent without silicone oil hair-washing composition, it is characterised in that consists of the following components in percentage by weight：Anion surfactant 5~15%, amphoteric surfactant 10~20%, nonionic surfactant 0.5~6%, amino acid type surfactant 0~5%, NMF 1~5%, cation opsonizing agent 0.2~2%, water-soluble grease 0.05~1% nurses one's health nursing compositions 0.05~1%, essence 0.1~1%, preservative 0.02~0.5%, pH adjusting agent 0.05~1%, water surplus.The present invention provide it is transparent there is excellent conditioning performance and foaming properties without silicone oil hair-washing composition, it is with low cost.
Description
Technical field
The invention belongs to household chemicals field, and in particular to a kind of transparent without silicone oil hair-washing composition, and this is transparent without silicone oil
The preparation method of hair-washing composition.
Background technology
So far, the shampoo with good conditioning performance of commercial type, mostly silicate-containing oil (polysiloxanes
Product) shampoo.Because silicone oil can smooth hair scale piece, the friction of hair is reduced, so that hair is smooth, be easy to comb
Reason.Although silicone oil is applied to there can be good conditioning performance to hair in shampoo, there is a kind of viewpoint to think：Due to silicone oil
With water insoluble characteristic, if excess deposition is on scalp, be likely to result in hair follicle blocking, influence scalp and hair it is strong
Health, and then result even in the generation of the phenomenons such as scalp inflammation, alopecia, hair loss.Although such a viewpoint not yet obtains theoretical confirmation,
But from the perspective of consumer, the people for accepting such a viewpoint is to occupy certain ratio.In order to cater to disappearing for this groups of people
Take demand, and also to realize strategic structural of the shampoo on technological layer, develop without silicone oil conditioner shampoo, be to have
Important realistic meaning.And some beat the hair washing product of " scalp care " concept, silicone oil is much also free from.From in recent years
Market manifestation sees that no silicone oil shampoo is really also increasingly by the attention and concern of manufacturer and consumer, the species sum of product
Amount is also in rising trend always.But, shampoo how is ensured in the case of not silicate-containing oil, still with good hair conditioning
Can, it is a technological difficulties in current hair washing product exploitation.
Transparent type shampoo, the product with single cleaning function is all intended only as all the time and by consumer cognition,
Preferable conditioning functions can not be provided simultaneously with.Because much having the raw material of conditioning performance, such as cationic polymer or oil
Fat, after being added in shampoo, can influence the transparency of product.So enabling to be added to has conditioning in transparent type shampoo
The raw material type of performance is reduced.So, the original in transparent type shampoo with good conditioning performance can be added to by how preferably going out
Material, is the challenge that many hair washing product developers are faced.
That has sold on the market at present is domestic and international transparent without silicone oil shampoo, most of all to there is certain technological deficiency,
Mainly there are following several situations：First, conditioning performance is not good enough, the desired level of consumer is not reached；Second, foam is inadequate
Abundant, foam number does not reach the Standard of transparent type shampoo；Third, product cost is too high, certain is caused to production firm
Financial burden.
The content of the invention
It is an object of the invention to the technical problem to be solved for more than, there is provided a kind of conditioning performance and foaming properties are excellent
Different, with low cost is transparent without silicone oil hair-washing composition.
It is a further object to provide the above-mentioned transparent preparation method without silicone oil hair-washing composition.
Therefore, the invention provides one kind is transparent without silicone oil hair-washing composition, it is characterised in that by following percentage by weight
Component composition：Anion surfactant 5~15%, amphoteric surfactant 10~20%, nonionic surfactant 0.5
~6%, amino acid type surfactant 0~5%, NMF 1~5%, cation opsonizing agent 0.2~2%, water-soluble grease
0.05~1%, conditioning nursing compositions 0.05~1%, essence 0.1~1%, preservative 0.02~0.5%, pH adjusting agent 0.05~
1%, water surplus.
Preferably, it is provided by the present invention transparent without silicone oil hair-washing composition, consist of the following components in percentage by weight：
Anion surfactant 8~10%, amphoteric surfactant 14~16%, nonionic surfactant 1~3%, amino acid
Type surfactant 0~1.5%, NMF 2~3%, cation opsonizing agent 0.5~1.2%, water-soluble grease 0.1~
0.3%, conditioning nursing compositions 0.1~0.3%, essence 0.2~0.4%, preservative 0.1%, pH adjusting agent 0.28~0.43%,
Water surplus.
In the transparent hair-washing composition without silicone oil of the present invention, described anion surfactant is preferably fatty alcohol
In polyethers sodium sulfovinate, poly alkyl alcohol ether sulfuric ester ammonium, fatty alcohol sulfate sodium, fatty alcohol sulfate ammonium it is one or two kinds of with
On mixture, more preferably laureth sodium sulfovinate.Anion surfactant laureth sodium sulfovinate application
The cost of composition can be reduced in the transparent hair-washing composition without silicone oil, and improves the foaming properties and washing performance of composition
Energy.
In the transparent hair-washing composition without silicone oil of the present invention, described amphoteric surfactant is preferably coconut oleoyl amine
In CAB, LAA, cocamidopropyl propyl amide hydroxy sulfo lycine, cocamidopropyl propyl amide amine oxide
The mixing of one or more kinds of mixtures, more preferably Cocoamidopropyl betaine and LAA
Thing.Cocoamidopropyl betaine and LAA are applied in the transparent hair-washing composition without silicone oil, can be dropped
The excitant of low composition, the foam state for improving composition, and show good conditioning performance.
In the transparent hair-washing composition without silicone oil of the present invention, described nonionic surfactant is preferably cocounut oil acyl
One or two kinds of mixtures in amine, APG, more preferably APG.APG, APG for short is by can be again
The natural fat alcohol and glucose synthesis of production-goods source, have the characteristic of conventional nonionic and anion surfactant concurrently, be safety
The surfactant of green.Applied in composition, the degreasing power with good dissolubility, mildness, to skin irritatin
Small, nontoxic, easy rinsing can also reduce the excitant of the other activating agents compounded with it.
In the transparent hair-washing composition without silicone oil of the present invention, described amino acid type surfactant is preferably bay
Acylsarcosine sodium, potassium lauroyl sarcosine, sodium lauroyl glutamate, lauroyl glutamate potassium, sodium cocoyl glycinate, cocounut oil acyl
One or more kinds of mixtures in glycine potassium, sodium methyl cocoyl taurate, more preferably Hamposyl L
Sodium.Sodium lauroyl sarcosine is applied in the transparent hair-washing composition without silicone oil, can improve scourability, the foaminess of composition
Can (make foam fine and smooth, persistently), conditioning performance, and the excitant of composition can be reduced.
In the transparent hair-washing composition without silicone oil of the present invention, described NMF is preferably glycerine, propane diols, fourth two
One or more kinds of mixtures in alcohol, more preferably glycerine.
In the transparent hair-washing composition without silicone oil of the present invention, described cation opsonizing agent is preferably guar gum hydroxypropyl
Base trimethyl ammonium chloride, polyquaternium -6, Polyquaternium-10, polyquaternium -53, myristamide propyl group PG- dimethylammonium chlorides
Ammonium phosphate (EverquatTMMP one or more kinds of mixtures in), more preferably Polyquaternium-10 and
EverquatTMMP mixture.EverquatTMMP is applied in the transparent hair-washing composition without silicone oil have following feature：
(1) coconut is originated, and bionic phospholipid structure, cationic characteristic has high affinity, tack with skin and hair, makes skin
It is more easy to absorb with hair, and with good mildness；(2) good hair conditioner, can assign hair submissive glossy spy
Property；(3) good thickening property, the viscosity to AES/AESA systems is obviously improved effect；(4) spumescence of composition is not influenceed
Energy；(5) there is good aqueous solubility, can make composition that good transparency is presented.
In the transparent hair-washing composition without silicone oil of the present invention, described water-soluble grease is preferably
HydramolTMPGPD esters (HydramolTMPGPD Ester, INCI titles：PEG/PPG-8/3 Diisostearate).
HydramolTMPGPD esters are applied in the transparent hair-washing composition without silicone oil composition can be made to have good conditioning performance,
And have substantially no effect on the foaming properties and transparency of composition.
In the transparent hair-washing composition without silicone oil of the present invention, described conditioning nursing compositions are preferably D-pantothenyl aleohol, dimension
One or more kinds of mixtures in raw element E, hydrolyzed wheat protein, keratin, more preferably D-pantothenyl aleohol.
In the transparent hair-washing composition without silicone oil of the present invention, described preservative can be safety commonly used in the art
Preservative, preferably methylisothiazolinone (and) methylchloroisothiazandnone, DMDMH, Phenoxyethanol, EUXYI
One or more kinds of mixtures in K100, more preferably preservative are EUXYI K100.
In the transparent hair-washing composition without silicone oil of the present invention, described pH adjusting agent can be peace commonly used in the art
One or more kinds of mixtures in full pH adjusting agent, preferably triethanolamine, NaOH, citric acid, hydrochloric acid, more
The preferably mixture of triethanolamine and citric acid.
Present invention also offers the transparent preparation method without silicone oil hair-washing composition, its step is as follows：
1) appropriate water is weighed, is added in agitated kettle, under slow stirring, anion surfactant is added, together
When begin to warm up heating；
2) temperature rises to 80~85 DEG C, is kept stirring for 15 minutes or so to dissolving completely, then adds amophoteric surface active
Agent, nonionic surfactant, start cooling after stirring；
3) 75 DEG C are cooled to, amino acid type surfactant, cation opsonizing agent is added, stirs；
4) 60 DEG C are cooled to, NMF is added, and stir；
5) 50 DEG C are cooled to, water-soluble grease, conditioning nursing compositions, preservative, essence is added, stirs, Ran Houyong
PH adjusting agent adjusts pH value；
6) less than 40 DEG C are cooled to, stops stirring, discharging.
By physical and chemical index and performance test, sensory evaluation test, as a result prove that the present invention is provided transparent washes without silicone oil
Hair composition has excellent conditioning performance, foaming properties and other performance, and indivedual formulas are approached on conditioning performance, reached
It has been even more than the shampoo of part silicate-containing oil.Compared with the market largely similar hair washing product, the transparent nothing that the present invention is provided
Silicone oil hair-washing composition has more preferable conditioning performance, more rich foam, along with relatively low formulation cost so that the present invention
Achieve technological innovation and breakthrough very big in hair washing product field.
Embodiment
The following is the transparent non-limiting example without silicone oil hair-washing composition of the present invention.These embodiments are provided only
It is that for illustrative purposes, limitation of the invention can not be interpreted as, because not departing from the spirit and scope of the present invention
On the basis of, the present invention can reasonably be changed and modifications.
Embodiment 1-5
Transparent 5 specific embodiments without silicone oil hair-washing composition provided by the present invention are listed in table 1.Wherein implement
Example 1-3 recipe ingredient is identical, and embodiment 4-5 recipe ingredient is identical, and the former is than latter increasing a kind of component (lauroyl flesh
Propylhomoserin sodium).In listed component, myristamide propyl group pg dimonium chloride phosphate (EverquatTMMP it is) middle lion chemistry
Company produces, and Polyquaternium-10 (JR 400) produces for Dow Chemical company, Hydramol PGPD esters
(HydramolTMPGPD Ester) produced for the extraordinary chemical industry (Shanghai) Co., Ltd. of Lu Borun, EUXYI K100 are Germany Shu Mei
Company produces.Listed numeral is the percentage by weight of component in the embodiment of table 1.
Table 1
Embodiment 1-3 hair-washing composition is prepared in accordance with the following steps：
1) appropriate water is weighed, is added in agitated kettle, under slow stirring, laureth sodium sulfovinate is added,
Start simultaneously at heat temperature raising；
2) temperature rises to 80~85 DEG C, is kept stirring for 15 minutes or so to dissolving completely, then adds cocamidopropyl propyl amide
Glycine betaine, LAA, APG, start cooling after stirring；
3) be cooled to 75 DEG C, add sodium lauroyl sarcosine, myristamide propyl group pg dimonium chloride phosphate,
Polyquaternium-10 (is pre-mixed uniformly) with a small amount of water, triethanolamine, is stirred；
4) 60 DEG C are cooled to, glycerine is added, and stir；
5) 50 DEG C are cooled to, Hydramol PGPD esters, D-pantothenyl aleohol, EUXYI K100, essence is added, stirs, so
Lemon acid for adjusting pH value is used afterwards；
6) less than 40 DEG C are cooled to, stops stirring, discharging.
Embodiment 4-5 hair-washing composition is prepared in accordance with the following steps：
1) appropriate water is weighed, is added in agitated kettle, under slow stirring, laureth sodium sulfovinate is added,
Start simultaneously at heat temperature raising；
2) temperature rises to 80~85 DEG C, is kept stirring for 15 minutes or so to dissolving completely, then adds cocamidopropyl propyl amide
Glycine betaine, LAA, APG, start cooling after stirring；
3) 75 DEG C are cooled to, myristamide propyl group pg dimonium chloride phosphate, Polyquaternium-10 is added (with lacking
The water of amount, triethanolamine are pre-mixed uniformly), stir；
4) 60 DEG C are cooled to, glycerine is added, and stir；
5) 50 DEG C are cooled to, Hydramol PGPD esters, D-pantothenyl aleohol, EUXYI K100, essence is added, stirs, so
Lemon acid for adjusting pH value is used afterwards；
6) less than 40 DEG C are cooled to, stops stirring, discharging.
Physical and chemical index and performance test
Physical and chemical index and performance test are carried out to embodiment 1-5 and reference examples 1-5, according to the indices in table 2, table 3
Tested.Selected reference examples are commercially available domestic and international famous brand name product, and wherein reference examples 1-3 is that transparent type is fragrant without silicone oil
Ripple, reference examples 4-5 is nontransparent type silicate-containing oil shampoo.Key instrument equipment used：PH meter, BROOKFIELD DV-C digital displays glue
Degree meter, Roche foam meter combs force tester.
Table 2
In table 2 it can be seen from every test data embodiment 1-5 (especially embodiment 1-3) foaming properties and comb
Reason power performance has more excellent performance.The foam height of all embodiments is all considerably beyond the GB of transparent type shampoo
Standard (GB/T 29679-2013 shampoos, hair cream, foam height >=100).From embodiment 1 to the carding force of embodiment 5
Can successively be tapered off trend, be primarily due to following raw material ratio shared in embodiment and gradually decreased：Lauroyl both sexes
Guanidine-acetic acid sodium, APG, sodium lauroyl sarcosine, myristamide propyl group pg dimonium chloride phosphate,
HydramolTMPGPD esters, D-pantothenyl aleohol.This shows that these raw materials can influence the hair conditioning of hair-washing composition to a certain extent
Energy.
Every test data in contrast table 2, table 3, it can be seen that embodiment 1-3 foaming properties and carding force performance are whole
More than reference examples 1-3.Wherein, embodiment 1-2 dry, wet carding force reduction ratio has been over what is behaved oneself best in reference examples
4-5.This foaming properties for showing most of embodiment and carding force performance have exceeded the same type hair washing product in reference examples, individual
Other embodiment has been over the silicate-containing oil shampoo in reference examples in carding force performance.In conjunction with the low of embodiment 1-5 formulas
Cost advantage, it was demonstrated that technical scheme provided by the present invention has reached expected purpose, the innovation realized on technological layer is dashed forward
It is broken.
Sensory evaluation is tested
In order to preferably prove it is provided by the present invention it is transparent there is excellent effect without silicone oil hair-washing composition, choose real
Apply example 2,3 and reference examples 1,2,5 carry out further investigation on probation and sensory evaluation test.Embodiment is as follows：Choose on probation
The people of crowd 50, age distribution is 20-60 Sui.Wherein male's number is 20 people, and women number is 30 people.To embodiment 2,3 and right
1,2,5 sample carries out sensory evaluation test as usual, and each sampling 2 weeks is given a mark according to the indices in table 4.
Standards of grading：Total score is 10 points, 1 point to be worst, 10 points are best, and score value is higher, and to represent effect better.Finally to this 50 people's
Marking is averaged, and (each numerical value i.e. in table 4 represents this 50 crowds on probation and beaten the every numerical value for just obtaining in table 4
The average value of fraction).
Table 4
The evaluation score that embodiment 2,3 is obtained it can be seen from the sensory evaluation data in table 4 is all very high, shows examination
It is all very satisfied to the trial effect of the two embodiments with crowd.The score value of all evaluation indexes is all compared in embodiment 2,3
1,2 is high as usual, illustrates that the trial effect of the two embodiments has exceeded selected domestic and international same type hair washing product.Embodiment
The score value of all evaluation indexes is higher than reference examples 5 in 2, illustrates that the trial effect of separate embodiment exceedes selected silicate-containing oil
Shampoo.And in foam, smoothness, pliability, cardability these indexs, the advantage of embodiment is more obvious.This is further
It is reasonable and effective to demonstrate technical scheme provided by the present invention.
Claims (3)
1. it is a kind of transparent without silicone oil hair-washing composition, it is characterised in that to consist of the following components in percentage by weight：Anion table
Face activating agent 8 ~ 10%, amphoteric surfactant 14 ~ 16%, nonionic surfactant 1 ~ 3%, amino acid type surfactant 0 ~
1.5%, NMF 1~5%, cation opsonizing agent 0.5 ~ 1.2%, water-soluble grease 0.1 ~ 0.3%, conditioning nursing compositions 0.05~
1%, essence 0.1~1%, preservative 0.02~0.5%, pH adjusting agent 0.05~1%, water surplus；
Wherein, described anion surfactant is poly alkyl alcohol ether sodium sulfovinate, poly alkyl alcohol ether sulfuric ester ammonium, fatty alcohol
One or more kinds of mixtures in sodium sulfovinate, fatty alcohol sulfate ammonium；
Described amphoteric surfactant is Cocoamidopropyl betaine and LAA；
Described nonionic surfactant is APG；
Described amino acid type surfactant is sodium lauroyl sarcosine, potassium lauroyl sarcosine, sodium lauroyl glutamate, the moon
One or two in osmanthus acyl potassium glutamate, sodium cocoyl glycinate, cocounut oil acyl glycine potassium, sodium methyl cocoyl taurate
Mixture above；
Described cation opsonizing agent is Polyquaternium-10 and myristamide propyl group pg dimonium chloride phosphate；
Described conditioning nursing compositions are the one or more in D-pantothenyl aleohol, vitamin E, hydrolyzed wheat protein, keratin
Mixture；
Described water-soluble grease is PEG/PPG-8/3 diisopstearates.
2. it is according to claim 1 transparent without silicone oil hair-washing composition, it is characterised in that：Described NMF be glycerine,
One or more kinds of mixtures in propane diols, butanediol.
3. the transparent preparation method without silicone oil hair-washing composition described in claim 1 or 2, it is characterised in that step is as follows：
（1）Add water in agitated kettle, under slow stirring, add anion surfactant, start simultaneously at heating and rise
Temperature；
（2）Temperature rises to 80~85 DEG C, be kept stirring for 15 minutes it is complete to dissolving, then add amphoteric surfactant, it is non-from
Sub- surfactant, starts cooling after stirring；
（3）75 DEG C are cooled to, amino acid type surfactant, cation opsonizing agent is added, stirs；
（4）60 DEG C are cooled to, NMF is added, and stir；
（5）50 DEG C are cooled to, water-soluble grease, conditioning nursing compositions, preservative, essence is added, stirs, then adjusted with pH
Save agent regulation pH value；
（6）Less than 40 DEG C are cooled to, stops stirring, discharging.
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| CN103315932B (en) * | 2013-06-05 | 2014-11-12 | 片仔癀（上海）生物科技研发有限公司 | Itching-relieving body wash and preparation method thereof |
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