CN106580730A - Silicone oil-free transparent shampoo adopting cereal amino acid salts as surfactant, and production method thereof - Google Patents
Silicone oil-free transparent shampoo adopting cereal amino acid salts as surfactant, and production method thereof Download PDFInfo
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- CN106580730A CN106580730A CN201611141069.1A CN201611141069A CN106580730A CN 106580730 A CN106580730 A CN 106580730A CN 201611141069 A CN201611141069 A CN 201611141069A CN 106580730 A CN106580730 A CN 106580730A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
- A61K8/645—Proteins of vegetable origin; Derivatives or degradation products thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/732—Starch; Amylose; Amylopectin; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/26—Optical properties
- A61K2800/262—Transparent; Translucent
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/34—Free of silicones
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/48—Thickener, Thickening system
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
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Abstract
The invention discloses a silicone oil-free transparent shampoo adopting cereal amino acid salts as a surfactant. The silicone oil-free transparent shampoo comprises, by weight, 10-40 parts of the cereal amino acid salts, 1-10 parts of a cosurfactant, 0.1-1.5 parts of a conditioner, 0.1-1.0 part of a pH regulator, and the balance of deionized water. The invention also discloses a production method of the silicone oil-free transparent shampoo adopting cereal amino acid salts as a surfactant. The surfactant in the invention is an amino acid surfactant, and completely substitutes a chemically-synthesized sulfate surfactant, and has the advantages of mild components, low irritation, and improvement of the safety of the above product; and the shampoo has the characteristics of rich foams, environmental protection, transparency and no silicone oil.
Description
Technical field
The invention belongs to field of daily chemicals, it is specially a kind of with corn amino acid salts as primary surfactant without silicon
Transparent shampoo of oil and preparation method thereof.
Background technology
Now, with the continuous improvement of people's know-how, everybody puts forward higher requirement to daily washing product.It is high
Shield was washed from the beginning of 2014 in end, seemingly became " favorite " of enterprise and media overnight.Enter one with " without silicone oil " concept
Step is propagandized hotly, even more high-end shampoo is lifted to a unprecedented height.Along with high price, consumer also carries one after another
The demand of oneself is gone out：Transparent, gentle, non-stimulated, hair is submissiveer etc..
Surfactant is content highest active matter in shampoo, and its addition species directly affects shampoo when in use
Whether there is zest.The use of gentle surfactant is the technical foundation without silicone oil shampoo, by improving gentle surface
The content of activating agent or only using gentle surfactant improving the mildness of shampoo.However, current washing on the market
Shampoo widely uses synthetic surfactant as primary surfactant, wherein representative is that (lauryl alcohol gathers AES
Ether sulfuric ester salt), K12A (lauryl sulfate ester ammonium salt), CAB (cocamido propyl betaine) etc..These surfactants are all
Synthesized by industrial chemicals after chemical reaction, not only zest is big but also causes severe contamination to environment, fully meets not
Requirement of the consumer for high-end shampoo characteristic.For these problems, people always search for solution.
The content of the invention
It is an object of the invention to provide it is a kind of with corn amino acid salts as primary surfactant without the transparent shampoo of silicone oil,
With amino acid type surfactant as primary surfactant, the use of sulfated surfactant is substituted completely, with foam
It is abundant, mild low-stimulation, the transparent advantage without silicone oil.
It is a further object of the present invention to provide above-mentioned a kind of saturating without silicone oil with corn amino acid salts as primary surfactant
The preparation method of bright shampoo.
In order to realize the object of the invention, following technical scheme is present invention employs：One kind is based on corn amino acid salts
Surfactant without the transparent shampoo of silicone oil, include the component of following weight portion：
Further, the corn amino acid salts are that cocos nucifera oil acyl hydrolyzes avenin potassium and Disodium N-Coco acy-L-Glutamate, and
Both weight ratios are 2-10:1.
Further, the corn amino acid salts are cocos nucifera oil acyl hydrolysis avenin potassium and Disodium N-Coco acy-L-Glutamate weight
Than for 4-6:1.
Further, the cosurfactant is cocamido propyl betaine, last of the ten Heavenly stems glucose glucosides, cocos nucifera oil acyl hydroxyl second
One or more combination in any in sulphonic acid ester sodium, LAA.
Further, the conditioner is Polyquaternium-10, guar hydroxypropyltrimonium chloride, the smooth octanoic acid of Pyrusussuriensiss
One or more combination in any in ester, hydrolysed corn starch.
Further, the pH adjusting agent is citric acid-sodium citrate buffer solution.
Further, the shampoo can also include other optional components, such as thickening agent, chelating agen, essence, preservative
Deng the conventional composition of shampoo, but any siliceous material in shampoo of the present invention, is not contained.
Further, the shampoo is transparent shampoo.
Further, the viscosity of the shampoo is 3000-8000cP.
Further, the pH value of the shampoo is 5.0-7.0.
The step that a kind of preparation method without the transparent shampoo of silicone oil with corn amino acid salts as primary surfactant includes
It is rapid as follows：
(1) raw material is weighed by above-mentioned formula；
(2) above-mentioned deionized water, corn amino acid salts, cosurfactant, conditioner input emulsifying pot are heated to
80 DEG C, it is uniformly mixed so as to be completely dissolved；
(3) cooling to 40 DEG C adds citric acid-sodium citrate buffer solution that pH value is adjusted to 5.0-7.0, stirs；
(4) evacuation, stirs, and cools to 37 DEG C of dischargings.
Compared with prior art, the invention has the beneficial effects as follows：
1) solve the defect that amino acid type surfactant is difficult thickening：Avenin potassium and coconut palm are hydrolyzed with cocos nucifera oil acyl
Oleoyl disodium glutamate can form from thickened systems then auxiliary with other surfaces activating agent (such as cocamido propyl betaine) compounding
Help other thickening agents that system can be made to reach suitable denseness, it is ensured that system stability；
2) it is strong using cocos nucifera oil acyl hydrolysis avenin potassium foaming power, abundant foam is provided for system；
3) by adding Polyquaternium-10, guar hydroxypropyltrimonium chloride, the smooth caprylate of Pyrusussuriensiss, hydrolysed corn
The conditioners such as starch, it is not only good to hair hair conditioning, it is also equipped with the advantages of repairing damaged hair；
4) it is transparent shampoo.
Specific embodiment
Below by way of specific embodiment come the present invention is further illustrated, but these embodiments simply to illustrate that,
It is not limitation of the present invention.Unless stated otherwise, the content described in embodiment is mass percentage content.Method of testing is joined
Examine：PH value method according to specified in GB GB/T 13531.1-2008 is determined；Foaming power is according to GB GB/T 13173-
2008 are determined using Roche foam meter；Viscosity is determined at 25 DEG C with BROOKFIELD LVDV-C types viscometers；Hair setting
Can test is carried out using DIA-STRON MTT175 types testers；The experimental technique of unreceipted actual conditions, generally according to routine
Condition, or manufacturer's recommendations condition carries out.
The shampoo of embodiment 1-2 and comparative example 1-2
The shampoo formula of embodiment 1-2 and comparative example 1-2 is see the table below shown in 1.
1 comparative example 1-2 of table and embodiment 1-2
The shampoo of embodiment 3-6
The shampoo formula of embodiment 3-6 is shown in Table 2.
2 embodiment 3-6 of table
The step of preparation method of above-mentioned shampoo includes is as follows：
(1) raw material is weighed by above-mentioned formula；
(2) above-mentioned deionized water, corn amino acid salts, cosurfactant, conditioner input emulsifying pot are heated to
80 DEG C, it is uniformly mixed so as to be completely dissolved；
(3) cooling to 40 DEG C adds citric acid-sodium citrate buffer solution that pH value is adjusted to 6.5, stirs；
(4) evacuation, stirs, and cools to 37 DEG C of dischargings.
Comparative example 3-5
Comparative example 3-5 shampoo is the commercial shampoos of purchase, and nearly 5 years of this three sections of shampoos are in China's hair washing market for water pin
The volume ranking of selling is always held at top ten.
1 erythrocyte hemolysis of test example are tested
Erythrocyte hemolysis method of testing：Replace rabbit using erythrocyte hemolysis experiment (Red blood cell test RBC)
Eye irritation experiment carries out eye irritation assessment to shampoo mildness, and ultimate principle is by determining chemicals to cell membrane
Damage (haemolysis) and infringement (hemoglobin degeneration) degree to hemoglobin to evaluate the eye irritation of tested material.Lead in the world
RBC is tested into the eye irritation research for chemicals such as cosmetic product and raw materials.Therefore the present invention is molten by erythrocyte
Blood experimental technique is determining the mildness of formula, and is contrasted, and evaluates product mildness.Calculate and cause 50% at 410nm
The blood that A values ratio under tested material weight concentration (HC50, mg/L) and 575,540nm wavelength when erythrocyte occurs haemolysis is worth to
Lactoferrin denaturation rate (DI), and calculate the ratio L/D (L50/DI) of 2 variables.
3 foam height of table and L/D ratios
| Test sample | Foam height (mm) | L/D ratios | Zest is evaluated |
| Embodiment 1 | 123 | 13.98 | Microstimulation |
| Embodiment 2 | 120 | 5.24 | Slight stimulation |
| Comparative example 1 | 150 | 4.12 | Slight stimulation |
| Comparative example 2 | 65 | 14.70 | Microstimulation |
| Embodiment 3 | 121 | 9.52 | Slight stimulation |
| Embodiment 4 | 133 | 12.62 | Microstimulation |
| Embodiment 5 | 130 | 8.86 | Slight stimulation |
| Embodiment 6 | 128 | 9.01 | Slight stimulation |
| Comparative example 3 | 175 | 0.70 | Moderate zest |
| Comparative example 4 | 150 | 0.52 | Moderate zest |
| Comparative example 5 | 145 | 4.39 | Slight stimulation |
Test result shows that the zest of embodiment 1-6 in the present invention is well below commercial three sections of shampoo comparative examples
3-5's, the composition for further relating to embodiment is more gentle, safe.Surveyed according to foam height of embodiment 1-6 with comparative example 1-2
Examination data, erythrocyte hemolysis test L/D ratio contrasts, find the proportion of master meter work composition in present invention：Cocos nucifera oil acyl
The weight ratio of hydrolysis avenin potassium and Disodium N-Coco acy-L-Glutamate is 2-10：1.By above-mentioned experiment, it may be determined that most ratio of greater inequality
Example scope be：It is 4-6 that cocos nucifera oil acyl hydrolyzes avenin potassium and the weight ratio of Disodium N-Coco acy-L-Glutamate：1.
2 Hair setting power of test example is tested
By 3 as shown by data of table, in embodiment 1-6, embodiment 4 is in terms of foam height and zest two in general for most
Good formula, therefore select embodiment 4 and carry out Hair setting power test with comparative example 5, as a result as shown in table 4.
4. Hair setting performance comparison of table is tested
By upper table data display, relative to blank sample (only with originally washing), had one's hair wash using 4 formula shampoo of embodiment
Afterwards, wet can be obviously improved with hair drying comb rationality.This lifting can mutually be equal to city's comparative example 5, or even manage in hair drying comb
In terms of performance boost, embodiment 4 is also slightly better than comparative example 5.
3 crowd's test evaluation of test example：
For the performance for further contrasting shampoo, choosing each 15 of 22-55 year men and women volunteer of age carries out Blind Test.
Everyone uses 4 shampoo of embodiment and 5 shampoo of comparative example five days (once a day) of continuous hair washing respectively, is then investigated, is adjusted
The fruit that comes to an end is listed in table 5.
5 shampoo sensory testing of table evaluates
| Optionies | Outward appearance | Foam | Smoothness during bath | Wet comb smoothness | Dry comb smoothness | Scalp is felt |
| Embodiment 4 is more excellent | 9 | 6 | 3 | 4 | 10 | 13 |
| Comparative example 5 is more excellent | 7 | 9 | 2 | 5 | 7 | 5 |
| Both are the same | 14 | 15 | 25 | 21 | 13 | 12 |
As a result show, embodiment 4 is suitable with comparative example 5 in " smoothness during bath " and " wet smoothness " project；" bubble
In terms of foam ", comparative example 5 is slightly excellent；" outward appearance ", " dry comb smoothness " and " scalp sensation " embodiment 4 are slightly excellent.Especially, embodiment 4
Comparative example 5 is substantially better than in " scalp impression " project, shows that the shampoo of the present invention is adopting amino acid type surfactant
In the case of reduce zest of the shampoo to scalp, so as to improve scalp impression.
Above the specific embodiment of the present invention is described in detail, but which has been intended only as example, the present invention has not been limited
It is formed on particular embodiments described above.To those skilled in the art, any equivalent modifications carried out by the present invention and
Replacement is also all among scope of the invention.Therefore, the impartial conversion made without departing from the spirit and scope of the invention and
Modification, should all cover within the scope of the invention.
Claims (8)
1. with corn amino acid salts as primary surfactant without the transparent shampoo of silicone oil, it is characterised in that：Include following heavy
The component of amount part：
2. it is according to claim 1 with corn amino acid salts as primary surfactant without the transparent shampoo of silicone oil, which is special
Levy and be：The corn amino acid salts are that cocos nucifera oil acyl hydrolyzes avenin potassium and Disodium N-Coco acy-L-Glutamate, and corn aminoacid
Salt is 2-10 for the weight ratio that cocos nucifera oil acyl hydrolyzes avenin potassium and Disodium N-Coco acy-L-Glutamate:1.
3. it is according to claim 1 with corn amino acid salts as primary surfactant without the transparent shampoo of silicone oil, which is special
Levy and be：The cosurfactant be cocamido propyl betaine, last of the ten Heavenly stems glucose glucosides, cocos nucifera oil acyl isethionic acid ester sodium,
One or more combination in any in LAA.
4. it is according to claim 1 with corn amino acid salts as primary surfactant without the transparent shampoo of silicone oil, which is special
Levy and be：The conditioner is Polyquaternium-10, guar hydroxypropyltrimonium chloride, the smooth caprylate of Pyrusussuriensiss, hydrolysed corn
One or more combination in any in starch.
5. it is according to claim 1 with corn amino acid salts as primary surfactant without the transparent shampoo of silicone oil, which is special
Levy and be：The pH adjusting agent is citric acid-sodium citrate buffer solution.
6. it is according to claim 1 with corn amino acid salts as primary surfactant without the transparent shampoo of silicone oil, which is special
Levy and be：Viscosity is 3000-8000cP.
7. it is according to claim 1 with corn amino acid salts as primary surfactant without the transparent shampoo of silicone oil, which is special
Levy and be：PH value is 5.0-7.0.
8. the arbitrary described system without the transparent shampoo of silicone oil with corn amino acid salts as primary surfactant of claim 1-7
Preparation Method, it is characterised in that：Including the step of it is as follows：
(1) raw material is weighed by above-mentioned formula；
(2) above-mentioned water, corn amino acid salts, cosurfactant, conditioner input emulsifying pot are heated to into 80 DEG C, stirring is mixed
Close uniform so as to be completely dissolved；
(3) cooling to 40 DEG C adds citric acid-sodium citrate buffer solution that pH value is adjusted to 5.0-7.0, stirs；
(4) evacuation, stirs, and cools to 37 DEG C of dischargings.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611141069.1A CN106580730A (en) | 2016-12-12 | 2016-12-12 | Silicone oil-free transparent shampoo adopting cereal amino acid salts as surfactant, and production method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611141069.1A CN106580730A (en) | 2016-12-12 | 2016-12-12 | Silicone oil-free transparent shampoo adopting cereal amino acid salts as surfactant, and production method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107802551A (en) * | 2017-12-08 | 2018-03-16 | 广州环亚化妆品科技有限公司 | A kind of shampoo and preparation method thereof |
| CN107898687A (en) * | 2017-12-04 | 2018-04-13 | 湖南金昌生物技术有限公司 | One kind is without silicone oil without natural tea seed shampoo of sulfate plant origin and preparation method thereof |
| CN108078796A (en) * | 2017-12-28 | 2018-05-29 | 珠海伊斯佳科技股份有限公司 | A kind of no silicone oil moistens submissive hair film and preparation method thereof |
| WO2020097982A1 (en) * | 2018-11-15 | 2020-05-22 | 广东轻工职业技术学院 | Essential oil composition for scalp care and use |
| CN116687778A (en) * | 2023-07-26 | 2023-09-05 | 广州海龟爸爸生物科技有限公司 | Mild, tear-free and eye-penetrating and non-irritating amino acid facial cleansing foam for children and preparation method thereof |
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| AU1033600A (en) * | 1998-12-10 | 2000-06-26 | Dhanuka, Vinodkumar Ramniranjan | Detergent bar composition |
| CN104224575A (en) * | 2014-09-12 | 2014-12-24 | 广州市天吻娇颜化妆品有限公司 | Transparent silicone-oil-free hairdressing composition and preparation method thereof |
| CN104434581A (en) * | 2014-12-16 | 2015-03-25 | 广州潮徽化工科技有限公司 | Mild surfactant system and application thereof in toiletries |
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2016
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| AU1033600A (en) * | 1998-12-10 | 2000-06-26 | Dhanuka, Vinodkumar Ramniranjan | Detergent bar composition |
| CN104224575A (en) * | 2014-09-12 | 2014-12-24 | 广州市天吻娇颜化妆品有限公司 | Transparent silicone-oil-free hairdressing composition and preparation method thereof |
| CN104434581A (en) * | 2014-12-16 | 2015-03-25 | 广州潮徽化工科技有限公司 | Mild surfactant system and application thereof in toiletries |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107898687A (en) * | 2017-12-04 | 2018-04-13 | 湖南金昌生物技术有限公司 | One kind is without silicone oil without natural tea seed shampoo of sulfate plant origin and preparation method thereof |
| CN107802551A (en) * | 2017-12-08 | 2018-03-16 | 广州环亚化妆品科技有限公司 | A kind of shampoo and preparation method thereof |
| CN113332191A (en) * | 2017-12-08 | 2021-09-03 | 广州环亚化妆品科技有限公司 | Shampoo and preparation method thereof |
| CN108078796A (en) * | 2017-12-28 | 2018-05-29 | 珠海伊斯佳科技股份有限公司 | A kind of no silicone oil moistens submissive hair film and preparation method thereof |
| WO2020097982A1 (en) * | 2018-11-15 | 2020-05-22 | 广东轻工职业技术学院 | Essential oil composition for scalp care and use |
| CN116687778A (en) * | 2023-07-26 | 2023-09-05 | 广州海龟爸爸生物科技有限公司 | Mild, tear-free and eye-penetrating and non-irritating amino acid facial cleansing foam for children and preparation method thereof |
| CN116687778B (en) * | 2023-07-26 | 2024-02-06 | 广州海龟爸爸生物科技有限公司 | Mild, tear-free and eye-penetrating and non-irritating amino acid facial cleansing foam for children and preparation method thereof |
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