CN104434581A - Mild surfactant system and application thereof in toiletries - Google Patents
Mild surfactant system and application thereof in toiletries Download PDFInfo
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- CN104434581A CN104434581A CN201410784007.7A CN201410784007A CN104434581A CN 104434581 A CN104434581 A CN 104434581A CN 201410784007 A CN201410784007 A CN 201410784007A CN 104434581 A CN104434581 A CN 104434581A
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Abstract
The invention discloses a mild surfactant system and an application thereof in toiletries. The surfactant system comprises the following components: 3-5% of N-fatty acyl protein hydrolysate substance, 7-10% of N-fatty acyl protein hydrolysate salt substance, 5-10% of alkyl glucoside, 5-10% of alkyl amidopropyl betaine, 2-5% of betaine and 0.15-0.3% of preservative. The mild surfactant system is prepared in the following manner: dissolving the alkyl glucoside in water, adding the N-fatty acyl protein hydrolysate substance, N-fatty acyl protein hydrolysate salt substance and the alkyl amidopropyl betaine, maintaining the temperature at 65-85 DEG C until the components are dissolved, adding the betaine and the preservative after the solution is cooled, and filtering to obtain the mild surfactant system. The surfactant system is reasonable in match, remarkable in synergistic effect and very low in irritation and is suitable for infant formula systems; moreover, the surfactant system is convenient and flexible to use, is easy to thicken and can be used as a main surfactant or a cosurfactant.
Description
Technical field
The present invention relates to household chemicals technical field, be specifically related to a kind of surfactant system of gentleness and the application in bath article thereof.
Background technology
Surfactant is one of most basic material of cosmetics and personal care articles, adds in personal care articles and with human body and directly or indirectly contacts, finally enter nature with the form of formula.The events such as along with the raising of people's living standard, people drop into increasing concern to the toxic and side effects of various surfactants gradually, and the such as diox occurred especially is in recent years residual, Determination of Residual Acrylamide, nitrosamine are residual accelerate this process.
Surfactant contacts by different way with human body different parts, relates to the aspects such as the zest to mucosa, the sensitization to skin, toxicity, heritability, carcinogenecity, teratogenecity and hemolytic, the property digested and assimilated, biological degradability.Typically, in bath article, people more pay close attention to the biological degradability of surfactant to the zest of skin and surfactant itself.
The concept such as " environmentally friendly ", " green, natural ", " renewable plant origin " is through in the development & application of surfactant at present, so solve safety and the mildness of surfactant, the safest, the gentleest the most effective goods are again provided to become the challenge of this specialty research personage to consumer.Except the surfactant of development of new, by existing surfactant optimum organization to reach Synergistic be also research emphasis.
Summary of the invention
Primary and foremost purpose of the present invention is to overcome the deficiencies in the prior art, a kind of surfactant system of gentleness is provided, it both can use as primary surfactant, and performance is gentle, can improve again the zest of traditional primary surfactant as cosurfactant.
Another object of the present invention is to the preparation method of the surfactant system that described gentleness is provided.
Another object of the present invention is to provide the application of the surfactant system of described gentleness in bath article.
Object of the present invention is achieved through the following technical solutions: a kind of surfactant system of gentleness, comprises following component by mass percentage: N-fatty acyl group hydrolyzed protein class material 3 ~ 5%, N-fatty acyl group hydrolyzed protein salts substances 7 ~ 10%, alkyl-glucoside 5 ~ 10%, alkylamide propyl-betaine 5 ~ 10%, betanin 2 ~ 5%, antiseptic 0.15 ~ 0.3%;
The surfactant system of described gentleness also comprises water, and water is surplus;
Described N-fatty acyl group hydrolyzed protein class material is preferably one in cocoyl hydrolyzed soybean protein, cocoyl hydrolytic collagen, cocoyl hydrolysis of keratin, palmityl hydrolytic collagen and palmityl hydrolyzed wheat protein or at least two kinds;
Described N-fatty acyl group hydrolyzed protein salts substances is preferably one in cocos nucifera oil acyl hydrolysis avenin potassium, cocos nucifera oil acyl hydrolyzed wheat protein sodium, cocos nucifera oil acyl hydrolyzed soybean protein potassium, cocos nucifera oil acyl hydrolyzed soybean protein sodium, cocoyl hydrolytic collagen TEA salt, cocos nucifera oil acyl hydrolytic collagen potassium, palmityl hydrolyzed wheat protein potassium, lauroyl hydrolyzed soybean protein potassium, lauroyl hydrolytic collagen TEA salt, lauroyl hydrolytic collagen potassium and lauroyl hydrolytic collagen sodium or at least two kinds;
Described alkyl-glucoside is preferably one in lauryl glucoside, Coco-Glucoside, myristyl glucoside, octyl glucoside, octyl group/decyl glucoside, C12-18 alkyl androstanediol, C12-20 alkyl androstanediol, C8-14 alkyl androstanediol and Xylitol-based glucoside or at least two kinds;
Described alkylamide propyl-betaine is preferably cocamido propyl betaine, lauroylamidopropyl betaine, myristamide CAB, palmitamide CAB, palm-kernel oil amido propyl betaine, oleamide CAB, isostearoyl amine CAB, dodecanamide propyl hydroxy sulfo lycine, cocamidopropyl propyl amide hydroxyl sulfo betaine, cocos nucifera oil acyl/oleamide CAB, one in Semen Tritici aestivi germ oil amido propyl betaine and endecatylene amido propyl betaine or at least two kinds,
Described betanin, chemical name is trimethyl glycine, derives from the rhizome extract of natural Radix Betae;
Described antiseptic is preferably one in Kazon, 1,3-diformazan methylol dimethyl hydantion (DMDMH), sodium benzoate, methyl parahydroxybenzoate, propyl p-hydroxybenzoate and phenoxyethanol or at least two kinds;
Described N-fatty acyl group hydrolyzed protein class material, N-fatty acyl group hydrolyzed protein salts substances, alkyl-glucoside, alkylamide propyl-betaine, betanin, antiseptic are all commercial cosmetic products contain level product.
The preparation method of the surfactant system of described gentleness, comprises following steps:
(1) alkyl-glucoside is added to the water, is stirred to and dissolves completely;
(2) N-fatty acyl group hydrolyzed protein class material, N-fatty acyl group hydrolyzed protein salts substances and alkylamide propyl-betaine is added, in 65 ~ 85 DEG C of insulated and stirred to clear;
(3) add betanin and antiseptic after cooling, filter and obtain gentle surfactant system;
Wherein, the consumption of each raw material is by mass percentage, as follows: N-fatty acyl group hydrolyzed protein class material 3 ~ 5%, N-fatty acyl group hydrolyzed protein salts substances 7 ~ 10%, alkyl-glucoside 5 ~ 10%, alkylamide propyl-betaine 5 ~ 10%, betanin 2 ~ 5%, antiseptic 0.15 ~ 0.3%;
Described water is surplus;
Water described in step (1) is preferably the water of 65 ~ 85 DEG C;
The time of the stirring described in step (2) is preferably 1 ~ 1.5h;
The temperature of the cooling described in step (3) is preferably less than 50 DEG C; Be more preferably 20 ~ 40 DEG C.
The surfactant system of described gentleness may be used in bath article, in the formula of especially baby bath articles for use.
The present invention has following advantage and effect relative to prior art:
(1) N-fatty acyl group hydrolyzed protein or its esters material are the sensu lato amino acid surfactants of a class, and the application at present in bath article is reported to some extent, but not extensive, use mainly as cosurfactant.Its shortcoming in formula is stablize not on the one hand, is not easily thickening on the other hand, needs the extra thickening agent that supplements to carry out thickening.Inventor finds in formulating, the compositions that specific N-fatty acyl group hydrolyzed protein and its esters and alkyl-glucoside, alkylamide propyl-betaine, betanin etc. obtain after compound in certain proportion has good serviceability, can use as primary surfactant, stable in formula, easy thickening; The zest of compositions itself is extremely low, after being other high irritating surfactant compounds, significantly can reduce the zest of high irritating surfactant, is a kind of excellent bath article raw material.
(2) N-fatty acyl group hydrolyzed protein or its esters material are gentle weak anionic surfactant, and zest is low, and foam performance is superior; Alkyl-glucoside is gentle non-ionic surface active agent, and alkylamide propyl-betaine is gentle amphoteric surfactant, and trimethyl glycine has excellent moisture-keeping function.After composite, the mildness of system improves further; Foaming and the steady bubble of system improve further.
(3) surfactant system provided by the invention is easy to use, flexible, easy thickening, is applicable to transparent or opaque system, can uses as primary surfactant, prepare the formula of not containing sulfate or oxirane; Also can use as cosurfactant, in low cost formula.
(4) this surfactant system zest is extremely low, is applicable to baby formula system.
Accompanying drawing explanation
Fig. 1 is that stimulation design sketch falls in the collaborative of gentle surfactant system prepared by embodiment 1.
Detailed description of the invention
Below in conjunction with embodiment and accompanying drawing, the present invention is described in further detail, but embodiments of the present invention are not limited thereto.
Embodiment 1
5 mass parts lauryl glucoside are added in 77.85 mass parts, 65 DEG C of water, be stirred to and dissolve completely.Then 3 mass parts cocoyl hydrolyzed soybean protein, 7 mass parts cocos nucifera oil acyl hydrolyzed soybean protein potassium and 5 mass parts cocamido propyl betaine are added, 65 DEG C of insulated and stirred 0.5h, solution clear.Then be cooled to room temperature, add 2 mass parts betanins and 0.15 mass parts Kazon, filter the surfactant system that namely discharging obtains 100 mass parts gentlenesses.
Embodiment 2
10 mass parts octyl group/decyl glucoside are added in 59.7 mass parts, 85 DEG C of water, is stirred to and dissolves completely.Then 5 mass parts cocoyl hydrolytic collagens, 10 mass parts cocoyl hydrolytic collagen TEA salt and 10 mass parts palmitamide CAB are added, 85 DEG C of insulated and stirred 1h, solution clear.Then be cooled to room temperature, add 5 mass parts betanins and 0.3 mass parts DMDMH, filter the surfactant system that namely discharging obtains 100 mass parts gentlenesses.
Embodiment 3
4 mass parts myristyl glucosides and 4 mass parts C12-18 alkyl androstanediol are added in 68.8 mass parts, 75 DEG C of water, is stirred to and dissolves completely.Then 2 mass parts palmityl hydrolyzed wheat proteins, 2 mass parts cocoyl hydrolysis of keratin, 4 mass parts palmityl hydrolyzed wheat protein potassium, 4 mass parts cocos nucifera oil acyl hydrolyzed wheat protein sodium and 8 mass parts cocamidopropyl propyl amide hydroxyl sulfo betaines are added; 75 DEG C of insulated and stirred 0.8h, solution clear.Then be cooled to room temperature, add 3 mass parts betanins, 0.1 mass parts methyl parahydroxybenzoate and 0.1 mass parts DMDMH, filter the surfactant system that namely discharging obtains 100 mass parts gentlenesses.
Embodiment 4
6 mass parts C8-14 alkyl androstanediol are added in 72.25 mass parts, 70 DEG C of water, be stirred to and dissolve completely.Then 3 mass parts palmityl hydrolytic collagens, 10 mass parts lauroyl hydrolytic collagen sodium, 2 mass parts lauroylamidopropyl betaines and 4 mass parts Semen Tritici aestivi germ oil amido propyl betaines are added, 70 DEG C of insulated and stirred 1h, solution clear.Then be cooled to room temperature, add 2.5 mass parts betanins and 0.25 mass parts Kazon, filter the surfactant system that namely discharging obtains 100 mass parts gentlenesses.
Comparative example 1: do not add N-fatty acyl group hydrolyzed protein class material and N-fatty acyl group hydrolyzed protein salts substances in embodiment 1 surfactant system
5 mass parts lauryl glucoside are added in 87.85 mass parts, 65 DEG C of water, be stirred to and dissolve completely.Then 5 mass parts cocamido propyl betaine are added, 65 DEG C of insulated and stirred 0.5h, solution clear.Then be cooled to room temperature, add 2 mass parts betanins and 0.15 mass parts Kazon, filter discharging and namely obtain 100 mass of surface surfactant system.
Comparative example 2: do not add N-fatty acyl group hydrolyzed protein class material and N-fatty acyl group hydrolyzed protein salts substances in embodiment 2 surfactant system
10 mass parts octyl group/decyl glucoside are added in 74.7 mass parts, 85 DEG C of water, is stirred to and dissolves completely.Then 10 mass parts palmitamide CAB are added, 85 DEG C of insulated and stirred 1h, solution clear.Then be cooled to room temperature, add 5 mass parts betanins and 0.3 mass parts DMDMH, filter discharging and namely obtain 100 mass of surface surfactant system.
Comparative example 3: not containing alkyl-glucoside in embodiment 2 surfactant system
5 mass parts cocoyl hydrolytic collagens, 10 mass parts cocoyl hydrolytic collagen TEA salt and 10 mass parts palmitamide CAB are added in 69.7 mass parts, 85 DEG C of water, is stirred to and dissolves completely, 85 DEG C of insulated and stirred 1h, solution clear.Then be cooled to room temperature, add 5 mass parts betanins and 0.3 mass parts DMDMH, filter discharging and namely obtain 100 mass of surface surfactant system.
Comparative example 4: not containing alkylamide propyl-betaine in embodiment 3 surfactant system
4 mass parts myristyl glucosides and 4 mass parts C12-18 alkyl androstanediol are added in 76.8 mass parts, 75 DEG C of water, is stirred to and dissolves completely.Then 2 mass parts palmityl hydrolyzed wheat proteins, 2 mass parts cocoyl hydrolysis of keratin, 4 mass parts palmityl hydrolyzed wheat protein potassium, 4 mass parts cocos nucifera oil acyl hydrolyzed wheat protein sodium are added, 75 DEG C of insulated and stirred 0.8h, solution clear.Then be cooled to room temperature, add 3 mass parts betanins, 0.1 mass parts methyl parahydroxybenzoate and 0.1 mass parts DMDMH, filter discharging and namely obtain 100 mass of surface surfactant system.
The application of Application Example in bath article
(1) formula following (mass parts) of transparent bath foam:
One 20 parts, ricinoleic acid amide hydroxypropyltrimonium chloride 0.5 part, sodium cocoyl methyl sodium taurocholate 3 parts, cocoyl Glycine sodium 2 parts, citric acid 0.12 part, antiseptic (Euxyl K 100) 0.1 part, 73.28 parts, water in the surfactant system of glycerol 1 part, embodiment 1 ~ 4 and comparative example 1 ~ 4 preparation.
Preparation method:
A kind of, ricinoleic acid amide hydroxypropyltrimonium chloride, sodium cocoyl methyl sodium taurocholate, cocoyl Glycine sodium in the surfactant system prepare glycerol, embodiment 1 ~ 4 and comparative example 1 ~ 4 add stirring and dissolving in the water of 75 ~ 85 DEG C successively; until transparent; be cooled to room temperature; add citric acid, K-100; discharging, obtains transparent bath foam.
According to the order of embodiment 1 ~ 4 and comparative example 1 ~ 4, formula of bath cream numbering is respectively formula 1, formula 2, formula 3, formula 4, comparative formula 1, comparative formula 2, comparative formula 3, comparative formula 4.
(2) formula following (mass parts) of shampoo:
One 20 parts, ricinoleic acid amide hydroxypropyltrimonium chloride 1 part, polyquaternary ammonium salt-390.5 parts, polysorbate-200.2 parts, citric acid 0.15 part, antiseptic (Euxyl K 100) 0.1 part, 60.55 parts, water in the surfactant system of sodium laureth sulfate 2.5 parts, C12-15 Pareth-2 phosphate ester 15 parts, embodiment 1 ~ 4 and comparative example 1 ~ 4 preparation.
Preparation method:
One in the surfactant system prepare sodium laureth sulfate, C12-15 Pareth-2 phosphate ester, embodiment 1 ~ 4 and comparative example 1 ~ 4, ricinoleic acid amide hydroxypropyltrimonium chloride, polyquaternary ammonium salt-39, polysorbate-20 add stirring and dissolving in 75 ~ 85 DEG C of water successively, until transparent, be cooled to room temperature, add citric acid, K-100, discharging, obtains transparent hair shampoo.
According to the order of embodiment 1 ~ 4 and comparative example 1 ~ 4, shampoo formula numbering is respectively formula 5, formula 6, formula 7, formula 8, comparative formula 5, comparative formula 6, comparative formula 7, comparative formula 8.
(3) performance test
1. zest test, adopt Red Blood Corpuscle test (RBC test, erythrocyte haemolysis value) characterize, test with fresh Sanguis Bovis seu Bubali erythrocyte (from animal science institute of Agricultural University Of South China), with SDS (sodium lauryl sulphate) for reference, the experimental technique of RBC operates with reference to such as Publication about Document: Li Yang, Dong Yinmao, Meng Hong, wish an ancient unit of weight .7 kind Chinese herbal medicine extract antiallergic effect and zest research [J]. Chinese experimental pharmacology of Chinese medical formulae magazine, 2013,19 (4): 191-194.Result is as shown in table 1.
Table 1 haemolysis pH-value determination pH result (%)
As can be seen from Table 1, embodiment and the surfactant system erythrocyte haemolysis value prepared by comparative example all much little compared with SDS, but the gentle surfactant system prepared by embodiment is owing to arranging in pairs or groups rationally, comparatively comparative example is lower to make erythrocyte hemolysis value.
2. stimulation index measures: adopt zein method, zein (zein) is almost completely water insoluble, but after its and surfactant interact, water solublity increase; Than weak zest surfactant, there is the trend more easily making zein dissolve compared with the surfactant of strong and stimulating.Therefore according to the situation of change of nitrogen content before and after Action of Surfactant in aqueous solution, the dissolubility after zein and Action of Surfactant can be determined, and the nitrogen content in the zein dissolved is directly proportional to the skin irritation that surfactant causes, the irritating size of surfactant can be judged thus.Zein method measures stimulation index and operates with reference to such as Publication about Document: Dong Yinmao, this knows sail, Peng Jinluan. by the zest [J] of zein test surfaces activating agent. and daily chemical industry, 2002,32 (5): 59-61.Zein value is greater than the surfactant of N 4g/L for " strong and stimulating ", and this type of surfactant makes zein solubilising power stronger; Zein value is " low stimulation " at the surfactant of N 2 ~ 4g/L; Be less than the surfactant of N 2g/L for " non-stimulated ".
Detecting sample arranges as follows: the surfactant system of 0.3% (w/w) SDS, 0.3% (w/w) SDS+0.75% (w/w) embodiment 1 preparation, the surfactant system of 0.3% (w/w) SDS+1.5% (w/w) embodiment 1 preparation.
As shown in Figure 1, as can be seen from Figure 1, the surfactant system of the gentleness prepared by embodiment 1 has the irritating effect of collaborative reduction surfactant to experimental result, and the embodiment 1 of 1.50% can make the SDS almost nonirritant of 0.30%.
2. formulation stability test:
Sensory testing: the character of perusal product, sees if there is exception;
Heat resistant test: electro-heating standing-temperature cultivator 24h sample being put into (40 ± 1) DEG C, observes phenomenons such as whether having thinning, variable color, layering and firmness change, with the heat resistance of judgement sample after recovering room temperature;
Low temperature resistant test: sample is put into (-5 ~-10) DEG C ± electric refrigerator 24h of 1 DEG C, observes phenomenons such as whether having thinning, variable color, layering and firmness change, with the cold tolerance of judgement sample after recovering room temperature;
Centrifugal test: sample is placed in centrifuge, with the speed test 30min of (2000 ~ 4000) r/min, observes the separation of sample, point layer status.
Result is as shown in table 2 and table 3.
Table 2 formula of bath cream stability test result
Table 3 shampoo formula stability test result
As can be seen from table 2 and 3 result, the formula 1 ~ 8 containing the gentle surfactant system prepared by the present invention is all stable; And in comparative formula, there are the factors of instability in heat stability or freeze-stable.
Above-described embodiment is the present invention's preferably embodiment; but embodiments of the present invention are not restricted to the described embodiments; change, the modification done under other any does not deviate from spirit of the present invention and principle, substitute, combine, simplify; all should be the substitute mode of equivalence, be included within protection scope of the present invention.
Claims (10)
1. a gentle surfactant system, is characterized in that: comprise following component by mass percentage: N-fatty acyl group hydrolyzed protein class material 3 ~ 5%, N-fatty acyl group hydrolyzed protein salts substances 7 ~ 10%, alkyl-glucoside 5 ~ 10%, alkylamide propyl-betaine 5 ~ 10%, betanin 2 ~ 5%, antiseptic 0.15 ~ 0.3%.
2. the surfactant system of gentleness according to claim 1, is characterized in that: also comprise water, and water is surplus.
3. the surfactant system of gentleness according to claim 1, is characterized in that: described N-fatty acyl group hydrolyzed protein class material is one in cocoyl hydrolyzed soybean protein, cocoyl hydrolytic collagen, cocoyl hydrolysis of keratin, palmityl hydrolytic collagen and palmityl hydrolyzed wheat protein or at least two kinds.
4. the surfactant system of gentleness according to claim 1, is characterized in that: described N-fatty acyl group hydrolyzed protein salts substances is one in cocos nucifera oil acyl hydrolysis avenin potassium, cocos nucifera oil acyl hydrolyzed wheat protein sodium, cocos nucifera oil acyl hydrolyzed soybean protein potassium, cocos nucifera oil acyl hydrolyzed soybean protein sodium, cocoyl hydrolytic collagen TEA salt, cocos nucifera oil acyl hydrolytic collagen potassium, palmityl hydrolyzed wheat protein potassium, lauroyl hydrolyzed soybean protein potassium, lauroyl hydrolytic collagen TEA salt, lauroyl hydrolytic collagen potassium and lauroyl hydrolytic collagen sodium or at least two kinds.
5. the surfactant system of gentleness according to claim 1, is characterized in that: described alkyl-glucoside is one in lauryl glucoside, Coco-Glucoside, myristyl glucoside, octyl glucoside, octyl group/decyl glucoside, C12-18 alkyl androstanediol, C12-20 alkyl androstanediol, C8-14 alkyl androstanediol and Xylitol-based glucoside or at least two kinds.
6. the surfactant system of gentleness according to claim 1, it is characterized in that: described alkylamide propyl-betaine is cocamido propyl betaine, lauroylamidopropyl betaine, myristamide CAB, palmitamide CAB, palm-kernel oil amido propyl betaine, oleamide CAB, isostearoyl amine CAB, dodecanamide propyl hydroxy sulfo lycine, cocamidopropyl propyl amide hydroxyl sulfo betaine, cocos nucifera oil acyl/oleamide CAB, one in Semen Tritici aestivi germ oil amido propyl betaine and endecatylene amido propyl betaine or at least two kinds.
7. the surfactant system of gentleness according to claim 1, it is characterized in that: described antiseptic is one in Kazon, 1,3-diformazan methylol dimethyl hydantion, sodium benzoate, methyl parahydroxybenzoate, propyl p-hydroxybenzoate and phenoxyethanol or at least two kinds.
8. the preparation method of surfactant system gentle described in any one of claim 1 ~ 7, is characterized in that comprising following steps:
(1) alkyl-glucoside is added to the water, is stirred to and dissolves completely;
(2) N-fatty acyl group hydrolyzed protein class material, N-fatty acyl group hydrolyzed protein salts substances and alkylamide propyl-betaine is added, in 65 ~ 85 DEG C of insulated and stirred to clear;
(3) add betanin and antiseptic after cooling, filter and obtain gentle surfactant system;
Wherein, the consumption of each raw material is by mass percentage, as follows: N-fatty acyl group hydrolyzed protein class material 3 ~ 5%, N-fatty acyl group hydrolyzed protein salts substances 7 ~ 10%, alkyl-glucoside 5 ~ 10%, alkylamide propyl-betaine 5 ~ 10%, betanin 2 ~ 5%, antiseptic 0.15 ~ 0.3%.
9. surfactant system gentle described in any one of claim 1 ~ 8 is preparing the application in bath article.
10. surfactant system gentle is according to claim 9 preparing the application in bath article, it is characterized in that: described bath article is baby bath articles for use.
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105687056A (en) * | 2016-03-26 | 2016-06-22 | 华南理工大学 | Chinese traditional medicine shampoo suitably used by parturient and preparation method of Chinese traditional medicine shampoo |
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| CN106580730A (en) * | 2016-12-12 | 2017-04-26 | 广州环亚化妆品科技有限公司 | Silicone oil-free transparent shampoo adopting cereal amino acid salts as surfactant, and production method thereof |
| CN108324585A (en) * | 2018-03-26 | 2018-07-27 | 韩后化妆品股份有限公司 | A kind of clean skin class cosmetics |
| CN108685720A (en) * | 2018-07-25 | 2018-10-23 | 啵噜噜（广州）婴儿用品科技有限公司 | A kind of baby's shampoo used also as bath lotion |
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| CN115844764A (en) * | 2022-11-03 | 2023-03-28 | 山东九鑫生物工程有限公司 | Mild surfactant system and preparation method and application thereof |
| WO2024149652A1 (en) * | 2023-01-11 | 2024-07-18 | Basf Se | Blends of amidopropyl betaines derived from fatty acid mixtures comprising unsaturated fatty acids and alk(en)yl (poly)glycosides |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102824281A (en) * | 2012-09-17 | 2012-12-19 | 江苏隆力奇生物科技股份有限公司 | Skin cleaning foam and preparation method thereof |
| CN103263373A (en) * | 2013-05-28 | 2013-08-28 | 上海亚缇沐语生物科技有限公司 | Crocus sativus bath cream and preparation method thereof |
| US20140349902A1 (en) * | 2011-12-28 | 2014-11-27 | Evonik Industries Ag | Aqueous hair and skin cleaning compositions comprising biosurfactants |
-
2014
- 2014-12-16 CN CN201410784007.7A patent/CN104434581B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20140349902A1 (en) * | 2011-12-28 | 2014-11-27 | Evonik Industries Ag | Aqueous hair and skin cleaning compositions comprising biosurfactants |
| CN102824281A (en) * | 2012-09-17 | 2012-12-19 | 江苏隆力奇生物科技股份有限公司 | Skin cleaning foam and preparation method thereof |
| CN103263373A (en) * | 2013-05-28 | 2013-08-28 | 上海亚缇沐语生物科技有限公司 | Crocus sativus bath cream and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 杨倩燕等: "植物基脂氨基酸", 《日用化学品科学》 * |
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| CN105687056A (en) * | 2016-03-26 | 2016-06-22 | 华南理工大学 | Chinese traditional medicine shampoo suitably used by parturient and preparation method of Chinese traditional medicine shampoo |
| CN106580730A (en) * | 2016-12-12 | 2017-04-26 | 广州环亚化妆品科技有限公司 | Silicone oil-free transparent shampoo adopting cereal amino acid salts as surfactant, and production method thereof |
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