CN106420423A - Silicone-free amino acid/fibroin shampoo and preparation method thereof - Google Patents
Silicone-free amino acid/fibroin shampoo and preparation method thereof Download PDFInfo
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- CN106420423A CN106420423A CN201611015344.5A CN201611015344A CN106420423A CN 106420423 A CN106420423 A CN 106420423A CN 201611015344 A CN201611015344 A CN 201611015344A CN 106420423 A CN106420423 A CN 106420423A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/736—Chitin; Chitosan; Derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/925—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of animal origin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/002—Preparations for repairing the hair, e.g. hair cure
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/34—Free of silicones
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
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Abstract
The invention relates to a silicone-free amino acid/fibroin shampoo which comprises the following components in percentage by weight: 8-15% of cocamidopropyl betaine, 4-9% of coconut oil acetal amide, 3-8% of amino acid foaming agent, 3-7% of disodium sulfosuccinate, 0.5-2% of lanolin, 0.3-1.5% of cationic cellulose JR-400, 1-3% of amino acid plant moisturizer, 1-3% of chitosan silk fibroin, 1-4% of polyquaternary amine salt-47, 1-3% of polyquaternary amine salt-22, 0.05-0.1% of methyl isothiazolinone, 0.2-0.4% of citric acid, 0.5-1.5% of essence and the balance of water. The invention also relates to a preparation method of the shampoo. By effectively combining the amino-acid-component-rich raw materials and plant surfactants, the shampoo has stable performance, and supplements required nutrients for hair.
Description
Technical field
The present invention relates to one kind no silicoamino-acid fibroin shampoo and preparation method thereof.
Background technology
The shampoo for circulating on the market at present is substantially containing silicon compound, such as polydimethylsiloxane, amido silicon oil
Deng.Silicone oil is a kind of water-fast lubricant, and the hair washing water energy of the silicate-containing oil chemical composition moment in hair washing forms protecting film,
Play the submissive effect of moisturizing water lock and hair.But it is due to having water-fast characteristic, with increasing for effect number of times, insoluble
Accumulate between hair hair scale piece in the silicone oil of water, smooth illusion is caused, a large amount of silicone oil can cause closed head fur hole, hair
And then withered impaired, serious meeting causes the sequela of alopecia.
In the case that people increasingly focus on health, for how making hair scalp reduce injury, need in fundamentally pin
Enemy shows effect in maintenance reparation.And aminoacid is the fundamental unit of protein, it is each that human body includes that the nutrition needed for hair be unable to do without
Aminoacid is planted, and with this understanding, is developed a kind of no silicon matter and the strong of people's hair is more beneficial for rich in aminophenol nutrient
Health.
Content of the invention
It is an object of the invention to provide one kind no silicoamino-acid fibroin shampoo and preparation method thereof, prepared
Shampoo does not contain silicone oil, will not damaged scalp pore, hair, also there is excellent conditioning nursing, cleaning, hair care function, with
Overcome weak point of the prior art.
The object of the present invention is achieved like this:
A kind of no silicoamino-acid fibroin shampoo, by weight percentage, each constituent content is:
Cocamido propyl betaine 8%-15%,
Coconut oil diethanol amide 4%-9%,
Aminoacid foaming agent 3%-8%,
Sulfo group tiger amber acid monoester disodium 3%-7%,
Lanoline 0.5%-2%,
Cationic cellulose JR-400,0.3%-1.5%,
Aminoacid plant moisturizing agent 1%-2%,
Chitosan/silk fibroin 1%-3%,
Polyquaternary ammonium salt -47,1%-3%,
Merquat 280,1%-3%,
Methylisothiazolinone 0.05%-0.1%,
Citric acid 0.2-0.4,
Essence 0.5%-1.5%,
Balance of water.
By weight percentage, each constituent content is the shampoo:
Cocamido propyl betaine 12%,
Coconut oil diethanol amide 6%,
Aminoacid foaming agent 6%,
Sulfo group tiger amber acid monoester disodium 5%,
Lanoline 1%,
Cationic cellulose JR-400,0.3%,
Aminoacid plant moisturizing agent 1%,
Chitosan/silk fibroin 1.5%,
Polyquaternary ammonium salt -47,2%,
Merquat 280,1%,
Methylisothiazolinone 0.1%,
Citric acid 0.2-0.4,
Essence 0.5%-1.5%,
Balance of water.
The cocamido propyl betaine concentration is 35wt%.
The coconut oil diethanol amide concentration is 95wt%.
The aminoacid foaming agent concentration is 30wt%.
Two na concn of sulfo group tiger amber acid monoester is 30wt%.
The lanoline, aminoacid plant moisturizing agent, chitosan/silk fibroin, polyquaternary ammonium salt -47, Merquat 280, sun
Ion fiber element JR-400 is smooth conditioner;The cocamido propyl betaine, coconut oil diethanol amide, aminoacid rise
Infusion, sulfo group tiger amber acid monoester disodium are surfactant;The Methylisothiazolinone is preservative.
The pH value of the shampoo is 6.5-7.5.
A kind of preparation method of no silicoamino-acid fibroin shampoo, comprises the following steps:
(1)The water in component is taken, adds lanoline, cationic cellulose JR-400 and aminoacid plant moisturizing agent, stirring and dissolving;
(2)Add chitosan/silk fibroin, Merquat 280, polyquaternary ammonium salt -47, cocamido propyl betaine, Cortex cocois radiciss
Oily diglycollic amide, aminoacid foaming agent, sulfo group tiger amber acid monoester disodium, citric acid and appropriate essence, stir.
Beneficial effects of the present invention are as follows:
The shampoo of the present invention is effectively combined with animal and plant type surfactant by the raw material rich in amino acid composition, performance
Stable, foam exquisiteness, desired nutritional is supplemented to impaired, fragile hair quality.Its abundant amino acid nutrient can go deep into skin, make skin
More healthy with hair follicle.The present invention adopts the conditioner without silicone oil component, is effectively improved oils and fatss on the scared squama of hair follicle fall
Accumulation, take leave of hair washing rear enclosed scalp pore, make nutrients help more cross absorbed by hair follicle.
Specific embodiment
With reference to embodiment, the invention will be further described.
A kind of no silicoamino-acid fibroin shampoo, by weight percentage, each constituent content is:
Cocamido propyl betaine 8%-15%,
Coconut oil diethanol amide 4%-9%,
Aminoacid foaming agent 3%-8%,
Sulfo group tiger amber acid monoester disodium 3%-7%,
Lanoline 0.5%-2%,
Cationic cellulose JR-400,0.3%-1.5%,
Aminoacid plant moisturizing agent 1%-2%,
Chitosan/silk fibroin 1%-3%,
Polyquaternary ammonium salt -47,1%-3%,
Merquat 280,1%-3%,
Methylisothiazolinone 0.05%-0.1%,
Citric acid 0.2-0.4,
Essence 0.5%-1.5%,
Balance of water.
Further, the cocamido propyl betaine concentration is 35wt%, the cocoanut oil diethan olamide concentration
For 95wt%, it is 30wt% that the aminoacid foaming agent concentration is 30wt%, described two na concn of sulfo group tiger amber acid monoester.
The citric acid is used for adjusting the pH value of shampoo, and the suitable pH value of shampoo is 6.5-7.5.
Wherein:Lanoline, lanoline has permeability, may penetrate into deep skin during use, supplements human skin
Required fatty acid, collagen protein, maintain skin and hair oils and fatss balance, can mitigate the dry sensation of scalp, improve hair follicle and be good for
Health situation, improves the cardability of hair, repairs damaged hair.
Aminoacid plant moisturizing agent, chemical entitled trimethyl glycine, is a kind of natural structure material, and amphoteric ion type is protected
Wet composition, can improve rapidly the moisture content retentivity of skin and scalp, activated cell vigor, have outstanding natural moisture preserving effect to hair
Really, make hair bright, the lubrication sense of hair, damage of the hair after hair caring is repaired, with good moisturizing, antistatic property.
Chitosan/silk fibroin, a kind of chitose fibroin albumen with plant and animal material, rich in more than ten kinds of needed by human body amino
Acid, wherein Glycine (gly), alanine (ala) and serine (ser) are more, can prevent hair from being undermined bifurcated, make hair weight
Existing health, moistens submissive, with excellent dry cardability, is effectively improved wet cardability.
Polyquaternary ammonium salt -47, are a kind of quaternary ammonium salt polymers of multi-component copolymer, with significant antistatic, lubricate,
The function of submissive and sterilization, makes hair shinny, submissive easily thin, with excellent lubricity and silk smooth felling.Improving the dry of hair,
With excellent anti-winding ability in wet rationality.
Merquat 280, with remarkable dry and wet cardability, can allow hair sense of touch silk typically soft in using effect, with
When there is excellent moistening effect.
Cationic cellulose JR-400, the affinity for having maximum to hair and skin, mitigate thorn of the detergent to skin
Swash, hair end bifurcated slightly is repaired, submissive, the smooth and antistatic behaviour of hair quality is improved, and its compatibility is good, to hair-washing hair-care
Product has good thickening power.
A kind of preparation method of no silicoamino-acid fibroin shampoo, comprises the following steps:
(1)The water in component is taken, adds lanoline, cationic cellulose JR-400 and aminoacid plant moisturizing agent, stirring and dissolving;
(2)Add chitosan/silk fibroin, Merquat 280, polyquaternary ammonium salt -47, cocamido propyl betaine, Oleum Cocois
Diglycollic amide, aminoacid foaming agent, sulfo group tiger amber acid monoester disodium, citric acid and appropriate essence, stir.
As preferred embodiment, this no silicoamino-acid fibroin shampoo, by weight percentage, each constituent content
For:
Cocamido propyl betaine 12%,
Coconut oil diethanol amide 6%,
Aminoacid foaming agent 6%,
Sulfo group tiger amber acid monoester disodium 5%,
Lanoline 1%,
Cationic cellulose JR-400,0.3%,
Aminoacid plant moisturizing agent 1%,
Chitosan/silk fibroin 1.5%,
Polyquaternary ammonium salt -47,2%,
Merquat 280,1%,
Methylisothiazolinone 0.1%,
Citric acid 0.2-0.4,
Essence 0.5%-1.5%,
Balance of water.
As preferred embodiment, the preparation method of this no silicoamino-acid fibroin shampoo,
(1)Take the water in component(Preferably use ultrafiltration water), add lanoline 1%, cationic cellulose JR-400,0.3% and ammonia
Base acid plant moisturizing agent 1%, stirring and dissolving;
(2)Add chitosan/silk fibroin 1.5%, Merquat 280,1%, polyquaternary ammonium salt -47,2%, cocamidopropyl propyl amide sweet
Dish alkali 12%, coconut oil diethanol amide 6%, aminoacid foaming agent 6%, sulfo group tiger amber acid monoester disodium 5%, add essence and fit
Amount, is eventually adding citric acid and pH value is adjusted between 6.5-7.5, stir and can be prepared by.
The above, be only the preferable case study on implementation of the present invention, not the technical scope of the present invention imposed any restrictions, therefore all
It is the trickle amendment that above example is made according to the technical spirit of the present invention, replaces effect identical component and all still fall within this
In the range of the technical scheme of invention.
Claims (9)
1. one kind no silicoamino-acid fibroin shampoo, it is characterised in that by weight percentage, each constituent content is:
Cocamido propyl betaine 8%-15%,
Coconut oil diethanol amide 4%-9%,
Aminoacid foaming agent 3%-8%,
Sulfo group tiger amber acid monoester disodium 3%-7%,
Lanoline 0.5%-2%,
Cationic cellulose JR-400,0.3%-1.5%,
Aminoacid plant moisturizing agent 1%-2%,
Chitosan/silk fibroin 1%-3%,
Polyquaternary ammonium salt -47,1%-3%,
Merquat 280,1%-3%,
Methylisothiazolinone 0.05%-0.1%,
Citric acid 0.2-0.4,
Essence 0.5%-1.5%,
Balance of water.
2. no silicoamino-acid fibroin shampoo according to claim 1, the shampoo by weight percentage, each group
Point content is:
Cocamido propyl betaine 12%,
Coconut oil diethanol amide 6%,
Aminoacid foaming agent 6%,
Sulfo group tiger amber acid monoester disodium 5%,
Lanoline 1%,
Cationic cellulose JR-400,0.3%,
Aminoacid plant moisturizing agent 1%,
Chitosan/silk fibroin 1.5%,
Polyquaternary ammonium salt -47,2%,
Merquat 280,1%,
Methylisothiazolinone 0.1%,
Citric acid 0.2-0.4,
Essence 0.5%-1.5%,
Balance of water.
3. no silicoamino-acid fibroin shampoo according to claim 1, it is characterised in that the cocamidopropyl propyl amide is sweet
Dish alkali concn is 35wt%.
4. no silicoamino-acid fibroin shampoo according to claim 1, it is characterised in that the Oleum Cocois diethanol acyl
Amine concentration is 95wt%.
5. no silicoamino-acid fibroin shampoo according to claim 1, it is characterised in that the aminoacid foaming agent is dense
Spend for 30wt%.
6. no silicoamino-acid fibroin shampoo according to claim 1, it is characterised in that the sulfo group tiger amber acid monoester
Two na concns are 30wt%.
7. no silicoamino-acid fibroin shampoo according to claim 1, it is characterised in that the lanoline, aminoacid
Plant moisturizing agent, chitosan/silk fibroin, polyquaternary ammonium salt -47, Merquat 280, cationic cellulose JR-400 is smooth tune
Reason agent;The cocamido propyl betaine, coconut oil diethanol amide, aminoacid foaming agent, sulfo group tiger amber acid monoester disodium
For surfactant;The Methylisothiazolinone is preservative.
8. no silicoamino-acid fibroin shampoo according to claim 1, it is characterised in that the pH value of the shampoo is
6.5-7.5.
9. according to the preparation method of the mono- no silicoamino-acid fibroin shampoo of claim 1-8, it is characterised in that bag
Include following steps:
(1)The water in component is taken, adds lanoline, cationic cellulose JR-400 and aminoacid plant moisturizing agent, stirring and dissolving;
(2)Add chitosan/silk fibroin, Merquat 280, polyquaternary ammonium salt -47, cocamido propyl betaine, Oleum Cocois
Diglycollic amide, aminoacid foaming agent, sulfo group tiger amber acid monoester disodium, citric acid and appropriate essence, stir.
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CN201611015344.5A CN106420423A (en) | 2016-11-18 | 2016-11-18 | Silicone-free amino acid/fibroin shampoo and preparation method thereof |
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Cited By (5)
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CN107280994A (en) * | 2017-05-04 | 2017-10-24 | 上海章华保健化妆品有限公司 | One kind hydrolysis fibroin hair conditioner and preparation method thereof |
CN109602652A (en) * | 2018-12-10 | 2019-04-12 | 怀化五零三侗医药科技开发有限公司 | Hair care strengthen the hair composition, hair soap and preparation method thereof |
WO2019091682A1 (en) | 2017-11-10 | 2019-05-16 | Unilever N.V. | A hair care composition comprising silk fibroin |
WO2020104129A1 (en) | 2018-11-22 | 2020-05-28 | Beiersdorf Ag | A cosmetic cleansing composition |
CN111631999A (en) * | 2020-06-23 | 2020-09-08 | 余世明 | Formula and preparation method of skin-friendly environment-friendly shampoo |
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2016
- 2016-11-18 CN CN201611015344.5A patent/CN106420423A/en active Pending
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107280994A (en) * | 2017-05-04 | 2017-10-24 | 上海章华保健化妆品有限公司 | One kind hydrolysis fibroin hair conditioner and preparation method thereof |
WO2019091682A1 (en) | 2017-11-10 | 2019-05-16 | Unilever N.V. | A hair care composition comprising silk fibroin |
JP2021502354A (en) * | 2017-11-10 | 2021-01-28 | ユニリーバー・ナームローゼ・ベンノートシヤープ | Hair care composition containing silk fibroin |
JP7317822B2 (en) | 2017-11-10 | 2023-07-31 | ユニリーバー・アイピー・ホールディングス・ベスローテン・ヴェンノーツハップ | Hair care composition containing silk fibroin |
WO2020104129A1 (en) | 2018-11-22 | 2020-05-28 | Beiersdorf Ag | A cosmetic cleansing composition |
CN109602652A (en) * | 2018-12-10 | 2019-04-12 | 怀化五零三侗医药科技开发有限公司 | Hair care strengthen the hair composition, hair soap and preparation method thereof |
CN111631999A (en) * | 2020-06-23 | 2020-09-08 | 余世明 | Formula and preparation method of skin-friendly environment-friendly shampoo |
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Application publication date: 20170222 |