CN108685734A - A kind of no sulfate is without the low mild plant herbal shampoo of stimulation of silicon - Google Patents
A kind of no sulfate is without the low mild plant herbal shampoo of stimulation of silicon Download PDFInfo
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- CN108685734A CN108685734A CN201810904431.9A CN201810904431A CN108685734A CN 108685734 A CN108685734 A CN 108685734A CN 201810904431 A CN201810904431 A CN 201810904431A CN 108685734 A CN108685734 A CN 108685734A
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- sulfate
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/34—Free of silicones
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- Health & Medical Sciences (AREA)
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- General Health & Medical Sciences (AREA)
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Abstract
The invention discloses a kind of no sulfate without the low mild plant herbal shampoo of stimulation of silicon, and the weight percent of component is anion surfactant:5%~50%, amphoteric surfactant:2%~30%, viscosity and remy hair conditioning agent:0.2~12%, chelating agent:0.02~0.4%, plant extraction liquid:0.2%~10%, cation opsonizing agent:0.1~0.5%, surplus is deionized water.The present invention is by no silicone oil without sulfate and natural origin object group blending, solve not degradable silicone oil and sulfate stimulation and bioxin risk, the problems such as being solved simultaneously without silicon shampoo using the smooth reduction of rear hair and dullness, it is less stimulated compared to conventional products in the market, milder, to play hair care hair care and other effects.
Description
Technical field
The present invention relates to daily chemicals field, specifically a kind of no sulfate is without the low mild plant herbal shampoo of stimulation of silicon.
Background technology
Shampoo in Chinese market at present be mostly sulfate table live and silicone oil addition product, using sulfate table live it is low at
This easily thickening and strong foaming abundancy of dirt-removing power and silicone oil can come that decontamination is easy to hair carry, submissive glossy feeling after doing.
The shampoo lived containing silicone oil and sulfate table, which is used for a long time, in this simultaneously can lead to hair heavy feeling, the hair with the later stage
Feel withered, it is greasy, and silicone oil is not degradable, can lead to environmental pollution.Moreover, sulfate table live body system may bring by-product into
Bioxin increases the great difficult problem that potential risk , bioxin is also daily use chemicals product in the industry in recent years.Furthermore sulfate table work pair
Skin irritatin is relatively large.
Invention content
The invention aims to solve above-mentioned technical problem, it is foster without the low mild plant of stimulation of silicon to provide a kind of no sulfate
Hair-care shampoo, the present invention is by no silicone oil without sulfate and natural origin object group blending, and solution silicone oil is not degradable and sulfate pierces
Swash and bioxin risk, while solving to compare in the market using the smooth reduction of rear hair and the problems such as dullness without silicon shampoo
Conventional products less stimulate, milder, to play hair care hair care and other effects.
Technical solution is used by the present invention solves the technical problem:A kind of no sulfate is without the low mild plant of stimulation of silicon
The weight percent of herbal shampoo, component is,
Anion surfactant:5%~50%,
Amphoteric surfactant:2%~30%,
Viscosity and remy hair conditioning agent:0.2~12%,
Chelating agent:0.02~0.4%,
Plant extraction liquid:0.2%~10%,
Cation opsonizing agent:0.1~0.5%,
Surplus is deionized water.
Further, the components also include PH conditioning agents, essence, pigment, moisturizer and preservatives.
Preferably, the anion surfactant is amino acid anion surfactant.
Specifically, the anion surfactant is:The counties sodium lauroyl sarcosine , Yue Juan sodium sarcosinate, nutmeg flesh
Propylhomoserin sodium, sodium lauroyl glutamate, sodium cocoyl glutamate, cocounut oil Sodium Glycinate, cocounut oil acyl alanine potassium or laureth
The one or more of sulfosuccinic ester disodium.Amino acid anion surfactant has outstanding blistering low with to skin
Irritation, and dirt-removing power is excellent.
Specifically, the amphoteric surfactant is:Lauroylamidopropyl betaine, cocounut oil both sexes guanidine-acetic acid sodium, bay
The one or more of acyl both sexes guanidine-acetic acid sodium, cocoamphoacetate or lauroyl both sexes base diethyl acid disodium.Both sexes
Surfactant acts synergistically with anion surfactant, and anion surfactant, which plays, increases foam and reduction anion
Stimulation caused by surfactant high-foaming.
Specifically, the viscosity and remy hair conditioning agent are:PEG-7 olive oil carboxylic acid sodiums, glycerol caprylate decylate, poly- season
Ammonium salt -67, coconut oil fatty acid monoethanolamide CMEA, PPG-3 Octyl Ether, PEG-120 methyl dioleates, PEG-
The one or more of 120 methyl, three grease acid or PEG-120 methyls trioleate/1,3-PD.Viscosity
With remy hair conditioning agent have high viscosity thickening effect, and with anion surfactant, amphoteric surfactant compatibility, reduce
The stimulation of surfactant system, and it is soft to assign hair, moistening effect so that the soft and smooth and moisture feeling of the plentiful sense of hair.
Further, glycerol caprylate decylate also has both the function of moisturizer.
Specifically, the cation opsonizing agent is:Polyquaternium-10, Polyquaternium-67 or melon glue hydroxypropyl trimethylammonium
The one or more of ammonium chloride.The cation opsonizing agent reduces the stimulation of surfactant.
Specifically, the preferred Radix Glycyrrhizae of the plant extraction liquid, moutan bark, folium artemisiae argyi, kuh-seng, rough gentian, one kind of chamomile or
Two or more combination extracting solutions.The plant extraction liquid have can slow down skin allergy, Lavender Extract itch, also anti-inflammatory work
With.
Further, Polyquaternium-67 can not only be used for viscosity and remy hair conditioning agent, can also be used as cation opsonizing agent addition
Into the present invention.Polyquaternium-10 and Polyquaternium-67 are used according to conditioning degree demand, Polyquaternium-10 is more slim and graceful,
Polyquaternium-67 is then more dense.
The PH conditioning agents are citric acid.
The moisturizer is glycerine and glycerol caprylate decylate.Glycerol caprylate decylate can not only be used for viscosity and remy hair
Conditioning agent also can be used as moisturizer, and there is glycerol caprylate decylate moisturizing to assign fat effect, also abundant foam.
Compared with prior art, there is following good effect:
1, invention removes silicone oil and sulfate surfactant, reduce the hair heavy feeling caused by silicone oil, keep away
Exempt from scalp itch caused by the withered rear scalp of hair is closed, inflammation, play the problems such as dandruff.And remove the work of sulfate surface
Property agent system Zhong bioxin, skin allergy problem caused by avoiding irritation overweight.
2, anion surfactant of the invention uses mild non-stimulated, viscosity and the remy hair of amino acid surfactant
Conditioning agent uses polyquaternium, glycerol caprylate/decylate and PEG-120 methyl dioleates, helps nourish hair.
The two collocation synergistic effect can lack smooth technical problem for hair after removal silicone oil, and the present invention is irritating in reduction
Meanwhile supplement conditioning captacula, make its have the submissive silk of natural health cunning, while plant extracts have it is antipruritic anti-inflammatory, send out
Silk hair care hair care effect in washing shield.
With reference to embodiment, the invention will be further described.
Specific implementation mode
Embodiment one
Embodiment one without sulfate without the mild plant herbal shampoo of the low stimulation of silicon, including following configured with weight percent
Raw material be prepared with the conventional method for preparing shampoo:
Moutan bark/folium artemisiae argyi/kuh-seng compound extracted solution purchase is antipruritic multiple in releiving for the Shanghai bio tech ltd Zhi Ying
Square LG type products, moutan bark/folium artemisiae argyi/kuh-seng compound extracted solution and one identical product of embodiment of following embodiments.
Embodiment two
Embodiment two without sulfate without the mild plant herbal shampoo of the low stimulation of silicon, including following configured with weight percent
Raw material be prepared with the conventional method for preparing shampoo:
Embodiment three
Embodiment three without sulfate without the mild plant herbal shampoo of the low stimulation of silicon, including following configured with weight percent
Raw material be prepared with the conventional method for preparing shampoo:
Example IV
Example IV without sulfate without the mild plant herbal shampoo of the low stimulation of silicon, including following configured with weight percent
Raw material be prepared with the conventional method for preparing shampoo:
Radix Glycyrrhizae/the rough gentian/Chinese medicine of the chamomile compound extracted solution purchase in the Shanghai bio tech ltd Zhi Ying is gone
Consider compound HK type products to be worth doing.Radix Glycyrrhizae/rough gentian/chamomile compound extracted solution of following embodiments and example IV identical product.
Embodiment five
Embodiment five without sulfate without the mild plant herbal shampoo of the low stimulation of silicon, including following configured with weight percent
Raw material be prepared with the conventional method for preparing shampoo:
Both effectiveness evaluation and test
Comparative example one
The operating procedure of comparative example one:
1, it will expect that Hybrid Heating to 75 DEG C, stirs evenly spare in A;
2, the B of cold water dispersion is sequentially added, stirring is transparent to dissolving, and C is added;Cooling.
3, D is added in room temperature, stirs, both.
Comparative example two
The operating procedure of comparative example two:
1, it will expect that Hybrid Heating to 75 DEG C, stirs evenly spare in A;
2, the B of cold water dispersion is sequentially added, stirring is transparent to dissolving, and C is added;Cooling.
3, D is added in room temperature, stirs.
Test method
Foam height test method:It is tested using the test method of Roche (Ross--Miles) foamer meter, point
Initial foam height is not tested, and foam height and foam height after five minutes, are then averaged after 1 minute.It the results are shown in Table 1.
Mildness test method:(Red blood cell test RBC) method, this method are tested using erythrocyte hemolysis
It is one of Draize experiment alternatives, basic principle is to measure chemicals to the damage of cell membrane and therefore caused cell membrane
Infiltrative change evaluates the degree of injury of cell membrane, the damage by measuring the amount of the hemoglobin leaked out from red blood cell
The irritation for hindering degree and product has directly related property.In the world mainly by RBC experiments for cosmetic product and raw material etc.
The eye irritation of chemicals is studied.Therefore the present invention is by with the mildness of erythrocyte hemolysis determination of experimental method formula, and shape
In contrast with, test product mildness.Specific method is:The red cell suspension after chemicals effect is measured using spectrophotometry
Absorbance can calculate hemolysis rate and H50Value (even if the concentration value of the tested material of haemolysis occurs for 50% red blood cell).H50Be worth it is small,
Less amount of sample, which is added, can occur apparent haemolysis, show that sample stimulus is big, mildness is poor.H50Value is big, table
Bright sample stimulus is small, and mildness increases.It the results are shown in Table 1.
1 foam height of table and H50It is worth (mildness)
As seen from Table 1, in 152mm or more, embodiment two is even more the Roche foam height of the embodiment of the present invention one-five
Up to 163mm, and the Roche foam height of comparative example one and two is only in 143mm hereinafter, the foam height of the present invention is above pair
Ratio.
As seen from Table 1, the H of the embodiment of the present invention one-five50Value is up to 372 μ in 357 μ g/ml, the embodiment depth of the night
G/ml, and the H of comparative example one and two50Value is only in 343 μ g/ml hereinafter, the mildness of the present invention is superior to comparative example.
Sensitivity is evaluated and tested
The product of above-described embodiment one, embodiment two, embodiment three, comparative example one, comparative example two is subjected to contrast test,
Evaluation including glossiness, wet thin property, dry comb property and smoothness:
1, evaluation method:Detection takes volunteer on probation, is carried out by way of sensory evaluation.Volunteer is 18-20
One full year of life personnel, men and women is impartial, can independently be tested.It is divided into 5 groups of people, every group of 10 people.
2, glossiness is tested and assessed:By visual observation, glossy degree of the viewing head after so doing;
Wet comb property test and appraisal:In hair wet clean process, is combed by trying, experience the cardability of hair;
Dry comb property test and appraisal:After hair is naturally dry, is combed by trying, experience the cardability of hair;
Smoothness is tested and assessed:By comforting contact hair, the smoothness of hair is experienced;
Mildness is tested and assessed:It is washed by examination, a little foam is penetrated into canthus and periphery, experiences whether composition brings eyes
Irritation.
3,5 groups of personnel are corresponding at random uses a product.By to embodiment one, embodiment two, embodiment three, comparative example
One, the product of comparative example two carries out glossiness, wet thin property, dry comb property, smoothness marking, each total score is 10 points, best result 10
Point, it minimum point 1 point, makes even respectively.Evaluation cycle is 4 weeks.
4, evaluation result see the table below shown in 2:
As can be seen from Table 2, embodiment one, two and three is shown than comparative example one and two more superior glossiness, wet
Property, dry comb property and smoothness are dredged, the satisfaction of wherein embodiment one is highest.The present invention's is warm without the low stimulation of silicon without sulfate
It can efficiently and effectively achieve the purpose that glossiness, wet thin property, dry comb property and smoothness with plant herbal shampoo.And the present invention
Embodiment during examination is washed, do not have the phenomenon that Ocular irritation, show each raw material selected by the present invention and be good for safely
Health does not stimulate.
In summary:The present invention is answered without sulfate without low mild the alternative of plant herbal shampoo of stimulation of silicon extensively at present
For having silicone oil shampoo and without silicone oil shampoo, eliminate silicone oil and deposited on hair, causes the hair fuel-displaced and withered and yellowish hairs show
As efficiently solving the problems, such as biodegradation.
Foaming abundancy of the present invention, stabilization, product property milder, safer health, effective protection hair and scalp health,
Glossiness, wet thin property, dry comb property and the smoothness of product can be significantly improved simultaneously.
The invention is not limited in the above embodiments, if not departing from the present invention to the various changes or modifications of the present invention
Spirit and scope, if these modification and variations belong within the scope of the claim and equivalent technologies of the present invention, then this hair
It is bright to be also intended to include these modification and variations.
Claims (10)
1. a kind of no sulfate is without the low mild plant herbal shampoo of stimulation of silicon, it is characterised in that:The weight percent of its component is,
Surplus is deionized water.
2. as described in claim 1 without sulfate without the low mild plant herbal shampoo of stimulation of silicon, it is characterised in that:The component is also
Including PH conditioning agents, essence, pigment, moisturizer and/or preservative.
3. as described in claim 1 without sulfate without the low mild plant herbal shampoo of stimulation of silicon, it is characterised in that:The anion
Surfactant is amino acid anion surfactant.
4. as described in claim 1 without sulfate without the low mild plant herbal shampoo of stimulation of silicon, it is characterised in that:The anion
Surfactant is the counties sodium lauroyl sarcosine , Yue Juan sodium sarcosinate, nutmeg sodium sarcosinate, sodium lauroyl glutamate, cocounut oil
The one or two of acyl sodium glutamate, cocounut oil Sodium Glycinate, cocounut oil acyl alanine potassium or laureth sulfosuccinic ester disodium
More than.
5. as described in claim 1 without sulfate without the low mild plant herbal shampoo of stimulation of silicon, it is characterised in that:The both sexes table
Face activating agent is lauroylamidopropyl betaine, cocounut oil both sexes guanidine-acetic acid sodium, Sodium Lauroamphoacetate, cocounut oil acyl both sexes base
The one or more of acetic acid or lauroyl both sexes base diethyl acid disodium.
6. as described in claim 1 without sulfate without the low mild plant herbal shampoo of stimulation of silicon, it is characterised in that:The viscosity and
Remy hair conditioning agent is PEG-7 olive oil carboxylic acid sodiums, glycerol caprylate decylate, Polyquaternium-67, coco-nut oil fatty acid monoethanol
Amide CMEA, PPG-3 Octyl Ether, PEG-120 methyl dioleates, three grease of PEG-120 methyls acid or PEG-
The one or more of 120 methyl trioleates/1,3-PD.
7. as described in claim 1 without sulfate without the low mild plant herbal shampoo of stimulation of silicon, it is characterised in that:The cation
Conditioner is the one or more of Polyquaternium-10, Polyquaternium-67 or melon glue hydroxypropyl trimethylammonium ammonium chloride.
8. as described in claim 1 without sulfate without the low mild plant herbal shampoo of stimulation of silicon, it is characterised in that:The plant carries
It is Radix Glycyrrhizae, moutan bark, folium artemisiae argyi, kuh-seng, rough gentian, one or two kinds of combination of the above extracting solution of chamomile to take liquid.
9. as described in claim 1 without sulfate without the low mild plant herbal shampoo of stimulation of silicon, it is characterised in that:The PH is adjusted
Agent is citric acid.
10. as described in claim 1 without sulfate without the low mild plant herbal shampoo of stimulation of silicon, it is characterised in that:The moisturizing
Agent is glycerine and glycerol caprylate decylate.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810904431.9A CN108685734A (en) | 2018-08-09 | 2018-08-09 | A kind of no sulfate is without the low mild plant herbal shampoo of stimulation of silicon |
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| CN201810904431.9A CN108685734A (en) | 2018-08-09 | 2018-08-09 | A kind of no sulfate is without the low mild plant herbal shampoo of stimulation of silicon |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109481352A (en) * | 2018-12-10 | 2019-03-19 | 上海华银日用品有限公司 | It is a kind of with high conditioning performance without silicone oil without sulfate shampoo and preparation method thereof |
| CN109833226A (en) * | 2019-01-22 | 2019-06-04 | 广州积美国际贸易有限公司 | A kind of hair washing mousse mildly nourished |
| CN110664670A (en) * | 2019-10-24 | 2020-01-10 | 吴文育 | Mississian oil-releasing and oil-controlling shampoo |
| CN111759745A (en) * | 2020-07-30 | 2020-10-13 | 广州滨诺生物科技有限公司 | Dandruff-removing, itching-relieving, oil-controlling, anti-inflammatory and nourishing multi-effect shampoo |
| ES2789148A1 (en) * | 2019-04-23 | 2020-10-23 | Suavizantes Y Plastificantes Bituminosos S L | GRAPHENE-BASED COSMETIC COMPOSITION (Machine-translation by Google Translate, not legally binding) |
| CN112022741A (en) * | 2020-07-28 | 2020-12-04 | 名臣健康用品股份有限公司 | Mild low-stimulation hair washing mousse and preparation method thereof |
| CN112791041A (en) * | 2021-03-01 | 2021-05-14 | 李岳勿 | Plant shampoo and preparation method thereof |
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| WO2007104740A1 (en) * | 2006-03-13 | 2007-09-20 | Beiersdorf Ag | Silicon free hair cleaning emulsion |
| CN106580726A (en) * | 2016-11-11 | 2017-04-26 | 珠海伊斯佳科技股份有限公司 | Silicone-oil-free liquid shampoo containing amino acid and preparation method of silicone-oil-free liquid shampoo |
| CN108143671A (en) * | 2018-03-06 | 2018-06-12 | 石春妹 | A kind of shampoo for repairing hair |
| CN108283583A (en) * | 2018-03-27 | 2018-07-17 | 广州禾力生物科技有限公司 | A kind of no silicoamino-acid shampoo and preparation method thereof |
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| WO2007104740A1 (en) * | 2006-03-13 | 2007-09-20 | Beiersdorf Ag | Silicon free hair cleaning emulsion |
| CN106580726A (en) * | 2016-11-11 | 2017-04-26 | 珠海伊斯佳科技股份有限公司 | Silicone-oil-free liquid shampoo containing amino acid and preparation method of silicone-oil-free liquid shampoo |
| CN108143671A (en) * | 2018-03-06 | 2018-06-12 | 石春妹 | A kind of shampoo for repairing hair |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109481352A (en) * | 2018-12-10 | 2019-03-19 | 上海华银日用品有限公司 | It is a kind of with high conditioning performance without silicone oil without sulfate shampoo and preparation method thereof |
| CN109481352B (en) * | 2018-12-10 | 2021-07-16 | 上海蜂花日用品有限公司 | Silicone oil-free and sulfate-free shampoo with high conditioning performance and preparation method thereof |
| CN109833226A (en) * | 2019-01-22 | 2019-06-04 | 广州积美国际贸易有限公司 | A kind of hair washing mousse mildly nourished |
| ES2789148A1 (en) * | 2019-04-23 | 2020-10-23 | Suavizantes Y Plastificantes Bituminosos S L | GRAPHENE-BASED COSMETIC COMPOSITION (Machine-translation by Google Translate, not legally binding) |
| WO2020216975A1 (en) * | 2019-04-23 | 2020-10-29 | Suavizantes Y Plastificantes Bituminosos, S.L. | Graphene-based cosmetic composition |
| CN110664670A (en) * | 2019-10-24 | 2020-01-10 | 吴文育 | Mississian oil-releasing and oil-controlling shampoo |
| CN112022741A (en) * | 2020-07-28 | 2020-12-04 | 名臣健康用品股份有限公司 | Mild low-stimulation hair washing mousse and preparation method thereof |
| CN111759745A (en) * | 2020-07-30 | 2020-10-13 | 广州滨诺生物科技有限公司 | Dandruff-removing, itching-relieving, oil-controlling, anti-inflammatory and nourishing multi-effect shampoo |
| CN112791041A (en) * | 2021-03-01 | 2021-05-14 | 李岳勿 | Plant shampoo and preparation method thereof |
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Application publication date: 20181023 |