CN107375053A

CN107375053A - A kind of ginseng and Chinese angelica root is without silicone oil shampoo and preparation method thereof

Info

Publication number: CN107375053A
Application number: CN201710461490.9A
Authority: CN
Inventors: 曾万祥; 覃敢为; 陈海; 陈健; 黄娜
Original assignee: Individual
Current assignee: Individual
Priority date: 2017-06-16
Filing date: 2017-06-16
Publication date: 2017-11-24

Abstract

The invention provides a kind of ginseng and Chinese angelica root without silicone oil shampoo, includes the preparing raw material of following weight percentage：The mixture 5~10% of ginseng extract and angelica extract and tax fat agent 1~5%；The tax fat agent is at least one of monoolein, the Octyl Ethers of PPG 3, the propylene glycol oleates of PEG 55 and the glyceryl cocoates of PEG 7.Present invention also offers a kind of preparation method of ginseng and Chinese angelica root without silicone oil shampoo.Ginseng and Chinese angelica root of the present invention without silicone oil shampoo can effectively cleaning and nourishing hair and scalp, make hair salubrious elegant submissive, be not in after hair washing scalp it is difficult ventilative, greasy thick and heavy phenomenon, natural on-off cycles of hair growth can be promoted with strong root of hair again simultaneously, reduce alopecia, slow down the generation of white hair.

Description

A kind of ginseng and Chinese angelica root is without silicone oil shampoo and preparation method thereof

Technical field

The present invention relates to a kind of shampoo, and in particular to a kind of ginseng and Chinese angelica root is without silicone oil shampoo and preparation method thereof.

Background technology

Shampoo refers to a kind of hair products with functions such as cleaning, anti-dandruff, treatment oil.With living standards of the people Improve, to the quality requirement of shampoo also more and more higher, particularly plus the environmental pollution being on the rise, the fungi on scalp is got over Come more, cause the various symptom of scalp, as dandruff is excessive, hair dries up, alopecia etc..At present, many natural materials have Good hair-washing hair-care performance, have been used to wash during hair care applies some make up.In the case where modern cosmetics return to the trend of the Nature, people It is highly desirable have a kind of to human hair and scalp safety, and the hair care of washing for having certain effect applies some make up, therefore, will be natural Material elite stoste is combined with modern chemical industry technology, and it will be natural hair-washing hair-care cosmetics from now on to develop natural hair washing shield cosmetics The direction of development.

In order that hair is submissive in traditional shampoo, add the highly viscous silicon compound of some HMWs serve as it is smooth Agent, they can be adsorbed in each hair surface, form very smooth film.The silicon compound commonly used at present in shampoo has poly- Dimethyl siloxane, amido silicon oil, cyclomethicone etc., in hair-washing hair-care, these silicon-containing compounds can be between hair scale piece Gap fill up, people can be allowed to think that hair sense of touch is very smooth, but because silicone oil has characteristic not soluble in water, be wrapped in head Silicon on hair and scalp is less susceptible to be cleaned, and enrichment so year in year out, silicone oil can adsorb the meeting on hair Cause that hair is thicker, hair weight becomes weight, reduce the electrostatic interaction of hair, hair gradually lost elasticity, produced disconnected hair, scalp Clogging of pores, cause scalp oxygen flow insufficient, papilla may gradual atrophy, scalp just start to occur it is withered and yellow, itch, or even alopecia Phenomenon, and long-term use of siliceous oils product can be covered by silicone oil because of hair, and the real nutrition subsequently nursed cannot be introduced into And hair quality is set to be deteriorated.In addition these organosilicons are not only not soluble in water but also do not dissolve in any surfactant, and environment is discharged into after hair washing It is difficult to it is biodegradable, easily cause environmental pollution.

In addition, the use of preservative is extremely common in washing product, but excessive or inappropriate preservative can make table Chrotoplast developmental immaturity, it is loosely organized, so that epidermis is thinning, easily declined by environmental stimuli, phylactic power defensive power, can damaging cells DNA, make skin follow the string gradually, easily produce relaxation, microgroove, and the Skin Cell damaged by preservative then can continuous defect Breeding, makes skin quality worse and worse.So traditional preservatives use harm to cause existing washing product to be badly in need of finding natural anticorrosion Agent is seted out to no added preservative direction.

The content of the invention

A kind of ginseng and Chinese angelica root is provided and washed without silicone oil it is an object of the invention to overcome the shortcomings of the prior art part Shampoo and preparation method thereof.

To achieve the above object, the technical scheme taken of the present invention is：A kind of ginseng and Chinese angelica root without silicone oil shampoo, comprising with The preparing raw material of lower weight percentage：The mixture 5~10% of ginseng extract and angelica extract and tax fat agent 1~5%； The tax fat agent is in monoolein, PPG-3 Octyl Ethers, PEG-55 propylene glycol oleates and PEG-7 glyceryl cocoates At least one.

Ginseng possesses the good reputation of " kings of hundred grass " since ancient times, is more described as that " life is mended in enriching yin, and righting is solid by oriental medicine circle Originally superfine product ".Ginseng contains a variety of saponins and polysaccharide constituents, and the leachate of ginseng can be by skin slow-absorbing, do not have to skin Any pessimal stimulation, capillary of skin can be expanded, promote skin blood circulation, increase skin-nourishing, adjust the water of skin Oil balance, prevents skin dehydration, hardening, corrugation, adheres to using the product containing ginseng for a long time, can strengthen skin elasticity, make cell Obtain newborn.Ginseng active material also has the reducing property for suppressing melanin simultaneously, makes skin pure white smooth.Its beauty effect It is the superfine product improved looks with innumerable.In shampoo field, the addition of ginseng can have good hair care educate hair, Anticreep and the effect for suppressing dandruff, ginseng essential ingredient can make the telangiectasis on head, improve the nutrition condition of hair, can The tensile strength and extensibility of hair are improved, makes hair more compliant, is easy to comb.Also having prevents with reducing alopecia and breaking Hair, promote natural on-off cycles of hair growth development, repair the effect of damaged hair.In addition, ginseng extract has preferably to dermatitis, fungal infection Therapeutic effect, add ginseng, ginseng extract etc., can not only make hair more compliant, reduce dandruff, while prevent hair Come off, promote the growth of new hair, the effect of can reach head beauty.

Radix Angelicae Sinensis has anti anoxia；Adjust body's immunity, anticancer；Improve looks；Replenishing and activating blood；Antibacterial, anti-artery is hard Change and other effects.Wherein cosmetology effect mainly has three, is hair care, anti-wrinkle respectively, except spot.Radix Angelicae Sinensis contains substantial amounts of volatilization A variety of organic principles such as oil, vitamin, organic acid and trace element, experimental study show that it can expand peripheral vascular, reduce Vascular resistence, increase circulating liquid measure etc..Tyrosinase in human body can produce the melanin for causing freckle, blackspot, age mark, Its activity is higher, then the appearance of senile plaque expelling is more early, and quantity is also more.The aqueous solution of Radix Angelicae Sinensis suppresses the work(of tyrosinase activity Can be very strong, thus the formation of melanin can be suppressed, the pigmented dermatosis such as treatment chloasma, freckle are produced effects well, had anti- Aging and beautification function, helping to make one the youth resides.Radix Angelicae Sinensis is added in cosmetic cream, content in freckle cream, there is skin nutrition, is prevented The effect such as only pachylosis, preventing and treating acne, chloasma, freckle, and it is without any side effects.Because Radix Angelicae Sinensis contains vitamin A, dimension Raw plain B₁₂, the nutrient such as vitamin E and essential amino acid, natural on-off cycles of hair growth can be promoted by shampoo adding Radix Angelicae Sinensis, can be with The nutrition of scalp is supplemented, hair growth, makes hair soft shinny, is easy to comb.The present invention shares ginseng and Chinese angelica root, can increase head The nutrition of hair and increase hair toughness, reduce alopecia and delay the generation of white hair.

The present invention uses PPG-3 Octyl Ethers, 12~13 carbon alcohol lactates, PEG-55 propylene glycol oleates and PEG-7 glycerine At least one of cocounut oil acid esters substitute traditional silicone oil as fat agent is assigned, because traditional silicone oil does not dissolve in surfactant body In system, long-term use of easily absorption on hair and not easy cleaning, hair is set gradually to lose elasticity, produce disconnected hair, scalp for a long time Clogging of pores, cause scalp oxygen flow insufficient, papilla may gradual atrophy, scalp just start to occur it is withered and yellow, itch, or even alopecia Phenomenon, every kind of tax fat agent of the present invention is completely soluble in the surfactant system of shampoo, and their knot Lubricant component in structure and skin is all more approximate, therefore correct leatherware has extraordinary nourish to lubricate, after can washing hair Salubrious submissive non-greasy, obvious heavy feeling, softening hair and the gloss for increasing hair are not had.Ginseng extract and Radix Angelicae Sinensis carry The mixture for taking thing and the cooperation according to the above ratio for assigning fat agent are added so that shampoo of the present invention can not only be cleaned effectively While hair scalp, blood circulation can be effectively facilitated, nutrient is provided to scalp, disconnected hair, fork hair is repaired, improves hair quality, hair quality It is shiny black submissive, moreover it is possible to make scalp more healthy, hair increases, and reduces dandruff.

It is highly preferred that the tax fat agent be monoolein, PPG-3 Octyl Ethers, PEG-55 propylene glycol oleates and The mixture of PEG-7 glyceryl cocoates；The monoolein, PPG-3 Octyl Ethers, PEG-55 propylene glycol oleates and The weight ratio of PEG-7 glyceryl cocoates is：Monoolein：PPG-3 Octyl Ethers：PEG-55 propylene glycol oleates：PEG-7 Glyceryl cocoate=1~10:1~10:1~10:1~10.

Drawn through inventor's test of many times, when tax fat agent of the invention uses said ratio, to the submissive and scalp of hair Nourishes effect it is preferable.

Preferably, in the mixture of the ginseng extract and angelica extract, ginseng extract and the Radix Angelicae Sinensis extraction The weight ratio of thing is：Ginseng extract：Angelica extract=1~5:1.Drawn through inventor's test of many times, ginseng extract and When angelica extract uses said ratio, the nutrition of abundance can be provided for scalp, effectively mitigates the hair that alopecia slows down white hair It is raw.

It is highly preferred that in the mixture of the ginseng extract and angelica extract, the ginseng extract and Radix Angelicae Sinensis carry The weight ratio for taking thing is：Ginseng extract：Angelica extract=3:1.Drawn through inventor's test of many times, when ginseng extract and The weight ratio of angelica extract is 3:When 1, the mixed liquor of ginseng extract and angelica extract is scalp and the battalion of hair offer Support the most comprehensively, after the shampoo of the long-term use of ginseng extract containing the proportioning and angelica extract mixture, alopecia and The phenomenon of white hair mitigates significantly.

Preferably, shampoo also includes following preparing raw material：It is surfactant, cation opsonizing agent, hair conditioner, anti- Rotten agent substitute and thickener；In preparing raw material of the ginseng and Chinese angelica root without silicone oil shampoo, the surfactant is in raw material In weight percentage be 22~48%, the weight percentage of the cation opsonizing agent in the feed be 0.1~ 1.5%, the weight percentage of the hair conditioner in the feed is 0.2~4%, the weight of the preservative in the feed Percentage composition is 0.01~0.5%, and the weight percentage of the thickener in the feed is 0.1~10%.Each component uses Said ratio, obtained shampoo have preferable cleannes and moisten degree.

Preferably, the antiseptic substitute is decoyl hydroximic acid, parahydroxyacet-ophenone, glycerine octanoic acid fat and butanediol Mixture.

The use of preservative is extremely common in washing product, but excessive or inappropriate preservative can make epidermal cell Developmental immaturity, it is loosely organized, so that epidermis is thinning, easily declined by environmental stimuli, phylactic power defensive power, meeting damaging cells DNA, make skin Skin follows the string gradually, easily produces relaxation, microgroove, and constantly defect can then be bred by the Skin Cell of preservative infringement, order Skin quality is worse and worse.The present invention uses antiseptic substitute --- HL-01, is decoyl hydroximic acid, parahydroxyacet-ophenone, caprylic The mixture of sour fat, butanediol, an unbounded quantity of requirement more effective to mould, and also excitant is low, and shampoo of the present invention In other raw materials compatibility it is preferable, be a kind of gentle preservative of efficient natural.In addition, antiseptic substitute of the present invention Also there is chelating Ca²⁺、Fe²⁺And Fe³⁺Effect, it is possible to reduce the concentration of metal ion, reduce traditional preservatives and give scalp band The infringement come.

Preferably, the hair conditioner is cocodimonium hydroxypropyl base hydrolyzed wheat keratin, hydrolytic collagen egg At least one of white and panthenol.

Cocodimonium hydroxypropyl base hydrolyzed wheat keratin is a kind of cation opsonizing agent of high activity, gently, nothing Stimulate, the elasticity of hair fiber can be increased, improve dry and wet comb performance, can provide nutrition to hair again, allow it that there is gloss And the sensation that silk is slided.Hydrolyzed Collagen can be the lac nutrition that hair supplement is lost in, and make hair healthy glossy.It is general Application of the alcohol in shampoo, shows as the moisture-keeping functions lasting to hair, and it can wrap up hair, has and moistens, moisturizing is suitable It is sliding, bifurcated is reduced, prevents hair to be damaged, increases the density of hair, improve the effect of the gloss of hair quality.

It is highly preferred that the hair conditioner is cocodimonium hydroxypropyl base hydrolyzed wheat keratin, hydrolytic collagen The mixture of albumen and panthenol；Cocodimonium hydroxypropyl base hydrolyzed wheat keratin, Hydrolyzed Collagen and the panthenol Weight ratio be：Cocodimonium hydroxypropyl base hydrolyzed wheat keratin：Hydrolyzed Collagen：Panthenol=1~3:1~3:1 ~3.

Cocodimonium hydroxypropyl base hydrolyzed wheat keratin, Hydrolyzed Collagen and panthenol coordinate according to the above ratio should With, nutrition can be provided for hair, it is non-stimulated to scalp, it is shampoo synergy of the present invention.

Preferably, the cation opsonizing agent is Polyquaternium-10, behenyl base trimethyl ammonium chloride, cation guar gum At least one of with polyquaternium -7.

It is highly preferred that the cation opsonizing agent is Polyquaternium-10, behenyl base trimethyl ammonium chloride, cation Guar The mixture of glue and polyquaternium -7；The Polyquaternium-10, behenyl base trimethyl ammonium chloride, cation guar gum and poly- season The weight ratio of ammonium salt -7 is：Polyquaternium-10：Behenyl base trimethyl ammonium chloride：Cation guar gum：Polyquaternium -7=1~ 3:1~3:1~3:1~3.

Cation opsonizing agent of the present invention selects the material non-stimulated to scalp, can effectively nourish scalp and moist head Hair.That hair is not submissive short-tempered after washing using the cationic conditioning agent of said ratio, to the moisturizing effect of scalp and hair compared with It is good.

Preferably, the surfactant be lauroyl both sexes base diethyl acid disodium, laruyl alcohol sulfosuccinate disodium, Tallow fatty acid sodium, laureth sodium sulfovinate, laruyl alcohol sodium sulfovinate, cocounut oil acyl methyl taurine sodium and cocamidopropyl propyl amide sweet tea At least one of dish alkali.

Surfactant used in the present invention is relatively mild surfactant, to hair and scalp cleannes compared with It is good, moreover it is possible to mitigate stimulation of the shampoo to scalp to a certain extent, reduce and hair is injured.

It is highly preferred that the surfactant is laureth sodium sulfovinate, laruyl alcohol sodium sulfovinate and cocounut oil acyl first The mixture of base sodium taurocholate；The laureth sodium sulfovinate, laruyl alcohol sodium sulfovinate and cocounut oil acyl methyl taurine sodium Weight ratio be：Laureth sodium sulfovinate：Laruyl alcohol sodium sulfovinate：Cocounut oil acyl methyl taurine sodium=3~5:2~3:1 ~2.

Drawn through inventor's test of many times, when surfactant is the proportioning of said components, foaming abundancy, to scalp and head The effect with deep layer cleaning of hair.

Preferably, the thickener is cocamidopropyl methyl betaine and coconut oleoyl amine MEA mixture；The cocounut oil Amide methyl glycine betaine and coconut oleoyl amine MEA weight ratio is：Cocamidopropyl methyl betaine：Coconut oleoyl amine MEA=1~ 3:0.5~2.

The ginseng and Chinese angelica root of the present invention is without silicone oil shampoo, in addition to said components clearly require, lossless of the invention In the range of effect, other adjunct ingredients, such as pH adjusting agent, essence etc. can be added or used to, those skilled in the art can Conventional content is selected according to conventional criteria.

Ginseng extract or angelica extract of the present invention can be made using following methods：Ginseng or Radix Angelicae Sinensis are ground To 60~80 mesh, 5~10 times of the Extraction solvent ethanol that weight is ginseng or Radix Angelicae Sinensis is added, is warming up to 40~60 DEG C, with super Sound wave 30~60min of ultrasound, ultrasonic power are 150~200W, filter to take filtrate, produce ginseng extract or angelica extract.

Ginseng extract or angelica extract use ultrasonic wave extraction, and extraction efficiency is high, and ultrasonic wave can make plant cell Broken wall or deformation are organized, makes extracts active ingredients more abundant, recovery rate raising more significant than traditional handicraft；Extraction time is short, processing Amount is big；Extracting temperature is low, has protective effect to the active ingredient in plant, can also save；It is few to extract impurity, active ingredient It is easily isolated, purifies；Extraction process operating cost is low, and overall economic efficiency is notable；And operation is simple, plant maintenance, guarantor It is convenient to support.The mixture of the ginseng extract and angelica extract is that ginseng extract and angelica extract are pressed into certain ratio Example is formed by directly mixing.

Another object of the present invention, which also resides in, provides a kind of preparation method of the above-mentioned ginseng and Chinese angelica root without silicone oil shampoo, including Following steps：

(1), surfactant is added in 80~85 DEG C of deionized water, is well mixed, adds cation opsonizing agent, It is well mixed, obtain component A；

(2) component A, is cooled to 40~45 DEG C, the mixture of ginseng extract and angelica extract is added thereto, assigns Fat agent and cation opsonizing agent, it is well mixed, obtains component B；

(3) component B, is cooled to less than 42 DEG C, adds hair conditioner, essence and antiseptic substitute thereto, is mixed Close uniformly, adjust pH value, add thickener, adjust to target viscosity, produce the ginseng and Chinese angelica root without silicone oil shampoo.

The shampoo character being prepared using the above method is stable, it is long-term place be not in bleed, layering, separation, The bad phenomenons such as precipitation, discoloration, peculiar smell, demulsification.

The beneficial effects of the present invention are：The invention provides a kind of ginseng and Chinese angelica root without silicone oil shampoo and its preparation side Method, ginseng and Chinese angelica root of the present invention assign fat agent to substitute traditional silicone oil without silicone oil shampoo using without silicone oil, are not in wash Scalp is difficult ventilative after hair, greasy thick and heavy phenomenon, still smooth but elegant salubrious after hair cleaning, also increases the light of hair Pool.Shampoo of the present invention, which uses, to be had increase scalp nutrition and hair toughness, promotes natural on-off cycles of hair growth, reduce alopecia, slow down The ginseng extract of white hair and the mixture of angelica extract and the tax fat agent without silicone oil are as raw material, with the use of non-stimulated The raw materials such as antiseptic substitute, hair conditioner, surfactant, reach the overall mildness for improving shampoo, reduce cleaning Excitant of the composition to scalp.Shampoo of the present invention can effectively cleaning and nourishing hair and scalp, make hair clearly elegant Submissive, being not in that scalp is difficult after having one's hair wash breathes freely, greasy thick and heavy phenomenon, while can promote natural on-off cycles of hair growth with strong root of hair again, Alopecia is reduced, slows down the generation of white hair.

Embodiment

To better illustrate the object, technical solutions and advantages of the present invention, below in conjunction with specific embodiment to the present invention It is described further.

Embodiment 1

A kind of embodiment of the ginseng and Chinese angelica root of the present invention without silicone oil shampoo, includes the preparation of following weight percentage Raw material：The mixture 8% of ginseng extract and angelica extract, assign fat agent 3%, antiseptic substitute 0.5%, hair conditioner 2%th, cation opsonizing agent 0.6%, surfactant 25%, thickener 3%, essence 0.8%, pH adjusting agent 0.1% and surplus Deionized water.

The weight ratio of the ginseng extract and angelica extract is：Ginseng extract：Angelica extract=1:1

The tax fat agent is monoolein, PPG-3 Octyl Ethers, PEG-55 propylene glycol oleates and PEG-7 glycerine coconut palms The mixture of oleate；The monoolein, PPG-3 Octyl Ethers, PEG-55 propylene glycol oleates and PEG-7 glycerine cocounut oil The weight ratio of acid esters is：Monoolein：PPG-3 Octyl Ethers：PEG-55 propylene glycol oleates：PEG-7 glyceryl cocoates =5:4:3:2.

The antiseptic substitute is the mixture of decoyl hydroximic acid, parahydroxyacet-ophenone, glycerine octanoic acid fat and butanediol.

The hair conditioner is cocodimonium hydroxypropyl base hydrolyzed wheat keratin, Hydrolyzed Collagen and panthenol Mixture；The weight ratio of the cocodimonium hydroxypropyl base hydrolyzed wheat keratin, Hydrolyzed Collagen and panthenol is： Cocodimonium hydroxypropyl base hydrolyzed wheat keratin：Hydrolyzed Collagen：Panthenol=1:1:1.

The cation opsonizing agent is Polyquaternium-10, behenyl base trimethyl ammonium chloride, cation guar gum and polyquaternary amine The mixture of salt -7；The Polyquaternium-10, behenyl base trimethyl ammonium chloride, the weight of cation guar gum and polyquaternium -7 Measuring ratio is：Polyquaternium-10：Behenyl base trimethyl ammonium chloride：Cation guar gum：Polyquaternium -7=1:1:1:1.

The surfactant is laureth sodium sulfovinate, laruyl alcohol sodium sulfovinate and cocounut oil acyl methyl taurine sodium Mixture；The weight ratio of the laureth sodium sulfovinate, laruyl alcohol sodium sulfovinate and cocounut oil acyl methyl taurine sodium is： Laureth sodium sulfovinate：Laruyl alcohol sodium sulfovinate：Cocounut oil acyl methyl taurine sodium=3:2:1.

The thickener is cocamidopropyl methyl betaine and coconut oleoyl amine MEA mixture；The cocamidopropyl Methyl betaine and coconut oleoyl amine MEA weight ratio are：Cocamidopropyl methyl betaine：Coconut oleoyl amine MEA=2:1.

The pH adjusting agent is citric acid.

A kind of embodiment of the preparation method of ginseng extract described in the present embodiment, comprises the following steps：First ginseng Clean up, ginseng be then milled to 60~80 mesh, add 8 times of the Extraction solvent ethanol that weight is ginseng or Radix Angelicae Sinensis, 40~60 DEG C rapidly are warming up to, with 30~60min of ultrasonic echography, ultrasonic power is 150~200W, filters to take filtrate, i.e., Obtain ginseng extract.

A kind of embodiment of the preparation method of angelica extract described in the present embodiment, comprises the following steps：First Radix Angelicae Sinensis Clean up, ginseng is then milled to 60~80 mesh, add Extraction solvent, be rapidly warming up to 40~60 DEG C, use ultrasonic wave 30~60min of ultrasound, ultrasonic power are 150~200W, filter to take filtrate, produce angelica extract.

A kind of embodiment of preparation method of the ginseng and Chinese angelica root described in the present embodiment without silicone oil shampoo, comprises the following steps：

(1) laureth sodium sulfovinate, laruyl alcohol sodium sulfovinate and cocounut oil acyl methyl taurine sodium, are added 80~85 DEG C deionized water in, be well mixed, add coconut oleoyl amine MEA, behenyl base trimethyl ammonium chloride, Polyquaternium-10 and sun Cationic guar (Polyquaternium-10 and cation guar gum are scattered with the cold water of ten times of weight before addition), mixing Uniformly, component A is obtained；

(2) component A, is cooled to 40~45 DEG C, adds mixture, the oil of ginseng extract and angelica extract thereto Sour monoglyceride, PPG-3 Octyl Ethers, PEG-55 propylene glycol oleates, PEG-7 glyceryl cocoates and polyquaternium -7, mixing Uniformly, component B is obtained；

(3) component B, is cooled to less than 42 DEG C, adds cocodimonium hydroxypropyl base hydrolyzed wheat angle egg thereto In vain, hydrolytic collagen, panthenol, essence and antiseptic substitute, it is well mixed, adjusts pH value, adds thickener, adjust to target and stick Degree, produces the ginseng and Chinese angelica root without silicone oil shampoo.

Embodiment 2

A kind of embodiment of the ginseng and Chinese angelica root of the present invention without silicone oil shampoo, the present embodiment it is different from embodiment 1 it Place is only that the difference of the weight ratio of ginseng extract and angelica extract, ginseng extract described in the present embodiment and Radix Angelicae Sinensis extraction The weight ratio of thing is：Ginseng extract：Angelica extract=2:1.

Ginseng extract, angelica extract and ginseng and Chinese angelica root described in the present embodiment preparation method and reality without silicone oil shampoo It is identical to apply example 1.

Embodiment 3

A kind of embodiment of the ginseng and Chinese angelica root of the present invention without silicone oil shampoo, the present embodiment it is different from embodiment 1 it Place is only that the difference of the weight ratio of ginseng extract and angelica extract, ginseng extract described in the present embodiment and Radix Angelicae Sinensis extraction The weight ratio of thing is：Ginseng extract：Angelica extract=3:1.

Embodiment 4

A kind of embodiment of the ginseng and Chinese angelica root of the present invention without silicone oil shampoo, the present embodiment it is different from embodiment 1 it Place is only that the difference of the weight ratio of ginseng extract and angelica extract, ginseng extract described in the present embodiment and Radix Angelicae Sinensis extraction The weight ratio of thing is：Ginseng extract：Angelica extract=4:1.

Embodiment 5

A kind of embodiment of the ginseng and Chinese angelica root of the present invention without silicone oil shampoo, the present embodiment it is different from embodiment 1 it Place is only that the difference of the weight ratio of ginseng extract and angelica extract, ginseng extract described in the present embodiment and Radix Angelicae Sinensis extraction The weight ratio of thing is：Ginseng extract：Angelica extract=5:1.

Embodiment 6

A kind of embodiment of the ginseng and Chinese angelica root of the present invention without silicone oil shampoo, includes the preparation of following weight percentage Raw material：The mixture 5% of ginseng extract and angelica extract, assign fat agent 1%, antiseptic substitute 0.01%, hair conditioning Agent 0.2%, cation opsonizing agent 0.1%, surfactant 22%, thickener 0.1%, essence 0.8%, pH adjusting agent 0.1% With the deionized water of surplus.

The weight ratio of the ginseng extract and angelica extract is：Ginseng extract：Angelica extract=3:1

The tax fat agent is monoolein, PPG-3 Octyl Ethers, PEG-55 propylene glycol oleates and PEG-7 glycerine coconut palms The mixture of oleate；The monoolein, PPG-3 Octyl Ethers, PEG-55 propylene glycol oleates and PEG-7 glycerine cocounut oil The weight ratio of acid esters is：Monoolein：PPG-3 Octyl Ethers：PEG-55 propylene glycol oleates：PEG-7 glyceryl cocoates =1:10:10:10.

The hair conditioner is cocodimonium hydroxypropyl base hydrolyzed wheat keratin, Hydrolyzed Collagen and panthenol Mixture；The weight ratio of the cocodimonium hydroxypropyl base hydrolyzed wheat keratin, Hydrolyzed Collagen and panthenol is： Cocodimonium hydroxypropyl base hydrolyzed wheat keratin：Hydrolyzed Collagen：Panthenol=1:3:3.

The cation opsonizing agent is Polyquaternium-10, behenyl base trimethyl ammonium chloride, cation guar gum and polyquaternary amine The mixture of salt -7；The Polyquaternium-10, behenyl base trimethyl ammonium chloride, the weight of cation guar gum and polyquaternium -7 Measuring ratio is：Polyquaternium-10：Behenyl base trimethyl ammonium chloride：Cation guar gum：Polyquaternium -7=3:1:1:1.

The surfactant is laureth sodium sulfovinate, laruyl alcohol sodium sulfovinate and cocounut oil acyl methyl taurine sodium Mixture；The weight ratio of the laureth sodium sulfovinate, laruyl alcohol sodium sulfovinate and cocounut oil acyl methyl taurine sodium is： Laureth sodium sulfovinate：Laruyl alcohol sodium sulfovinate：Cocounut oil acyl methyl taurine sodium=3:3:1.

The thickener is cocamidopropyl methyl betaine and coconut oleoyl amine MEA mixture；The cocamidopropyl Methyl betaine and coconut oleoyl amine MEA weight ratio are：Cocamidopropyl methyl betaine：Coconut oleoyl amine MEA=1:2.

The pH adjusting agent is citric acid.

Embodiment 7

A kind of embodiment of the ginseng and Chinese angelica root of the present invention without silicone oil shampoo, includes the preparation of following weight percentage Raw material：The mixture 10% of ginseng extract and angelica extract, assign fat agent 5%, antiseptic substitute 0.3%, hair conditioning Agent 4%, cation opsonizing agent 1.5%, surfactant 48%, thickener 10%, essence 0.8%, pH adjusting agent 0.1% and remaining The deionized water of amount.

The tax fat agent is monoolein, PPG-3 Octyl Ethers, PEG-55 propylene glycol oleates and PEG-7 glycerine coconut palms The mixture of oleate；The monoolein, PPG-3 Octyl Ethers, PEG-55 propylene glycol oleates and PEG-7 glycerine cocounut oil The weight ratio of acid esters is：Monoolein：PPG-3 Octyl Ethers：PEG-55 propylene glycol oleates：PEG-7 glyceryl cocoates =10:1:3:2.

The hair conditioner is cocodimonium hydroxypropyl base hydrolyzed wheat keratin, Hydrolyzed Collagen and panthenol Mixture；The weight ratio of the cocodimonium hydroxypropyl base hydrolyzed wheat keratin, Hydrolyzed Collagen and panthenol is： Cocodimonium hydroxypropyl base hydrolyzed wheat keratin：Hydrolyzed Collagen：Panthenol=3:1:2.

The cation opsonizing agent is Polyquaternium-10, behenyl base trimethyl ammonium chloride, cation guar gum and polyquaternary amine The mixture of salt -7；The Polyquaternium-10, behenyl base trimethyl ammonium chloride, the weight of cation guar gum and polyquaternium -7 Measuring ratio is：Polyquaternium-10：Behenyl base trimethyl ammonium chloride：Cation guar gum：Polyquaternium -7=2:1:3:1.

The surfactant is laureth sodium sulfovinate, laruyl alcohol sodium sulfovinate and cocounut oil acyl methyl taurine sodium Mixture；The weight ratio of the laureth sodium sulfovinate, laruyl alcohol sodium sulfovinate and cocounut oil acyl methyl taurine sodium is： Laureth sodium sulfovinate：Laruyl alcohol sodium sulfovinate：Cocounut oil acyl methyl taurine sodium=5:2:1.

The thickener is cocamidopropyl methyl betaine and coconut oleoyl amine MEA mixture；The cocamidopropyl Methyl betaine and coconut oleoyl amine MEA weight ratio are：Cocamidopropyl methyl betaine：Coconut oleoyl amine MEA=6:1.

The pH adjusting agent is citric acid.

Embodiment 8

A kind of embodiment of the ginseng and Chinese angelica root of the present invention without silicone oil shampoo, includes the preparation of following weight percentage Raw material：The mixture 6% of ginseng extract and angelica extract, assign fat agent 4%, antiseptic substitute 0.2%, hair conditioner 3%th, cation opsonizing agent 1%, surfactant 35%, thickener 5%, essence 0.8%, pH adjusting agent 0.1% and surplus Deionized water.

The tax fat agent is monoolein, PPG-3 Octyl Ethers, PEG-55 propylene glycol oleates and PEG-7 glycerine coconut palms The mixture of oleate；The monoolein, PPG-3 Octyl Ethers, PEG-55 propylene glycol oleates and PEG-7 glycerine cocounut oil The weight ratio of acid esters is：Monoolein：PPG-3 Octyl Ethers：PEG-55 propylene glycol oleates：PEG-7 glyceryl cocoates =1:4:3:10.

The hair conditioner is cocodimonium hydroxypropyl base hydrolyzed wheat keratin, Hydrolyzed Collagen and panthenol Mixture；The weight ratio of the cocodimonium hydroxypropyl base hydrolyzed wheat keratin, Hydrolyzed Collagen and panthenol is： Cocodimonium hydroxypropyl base hydrolyzed wheat keratin：Hydrolyzed Collagen：Panthenol=1:1:3.

The cation opsonizing agent is Polyquaternium-10, behenyl base trimethyl ammonium chloride, cation guar gum and polyquaternary amine The mixture of salt -7；The Polyquaternium-10, behenyl base trimethyl ammonium chloride, the weight of cation guar gum and polyquaternium -7 Measuring ratio is：Polyquaternium-10：Behenyl base trimethyl ammonium chloride：Cation guar gum：Polyquaternium -7=1:1:2:3.

The surfactant is laureth sodium sulfovinate, laruyl alcohol sodium sulfovinate and cocounut oil acyl methyl taurine sodium Mixture；The weight ratio of the laureth sodium sulfovinate, laruyl alcohol sodium sulfovinate and cocounut oil acyl methyl taurine sodium is： Laureth sodium sulfovinate：Laruyl alcohol sodium sulfovinate：Cocounut oil acyl methyl taurine sodium=1:1:3.

The thickener is cocamidopropyl methyl betaine and coconut oleoyl amine MEA mixture；The cocamidopropyl Methyl betaine and coconut oleoyl amine MEA weight ratio are：Cocamidopropyl methyl betaine：Coconut oleoyl amine MEA=3:2.

The pH adjusting agent is citric acid.

Embodiment 9

A kind of embodiment of the ginseng and Chinese angelica root of the present invention without silicone oil shampoo, includes the preparation of following weight percentage Raw material：The mixture 8% of ginseng extract and angelica extract, assign fat agent 3%, antiseptic substitute 0.6%, hair conditioner 2%th, cation opsonizing agent 1.2%, surfactant 30%, thickener 4%, essence 0.8%, pH adjusting agent 0.1% and surplus Deionized water.

The tax fat agent is monoolein, PPG-3 Octyl Ethers, PEG-55 propylene glycol oleates and PEG-7 glycerine coconut palms The mixture of oleate；The monoolein, PPG-3 Octyl Ethers, PEG-55 propylene glycol oleates and PEG-7 glycerine cocounut oil The weight ratio of acid esters is：Monoolein：PPG-3 Octyl Ethers：PEG-55 propylene glycol oleates：PEG-7 glyceryl cocoates =1:1:5:10.

The hair conditioner is cocodimonium hydroxypropyl base hydrolyzed wheat keratin, Hydrolyzed Collagen and panthenol Mixture；The weight ratio of the cocodimonium hydroxypropyl base hydrolyzed wheat keratin, Hydrolyzed Collagen and panthenol is： Cocodimonium hydroxypropyl base hydrolyzed wheat keratin：Hydrolyzed Collagen：Panthenol=1:2:3.

The cation opsonizing agent is Polyquaternium-10, behenyl base trimethyl ammonium chloride, cation guar gum and polyquaternary amine The mixture of salt -7；The Polyquaternium-10, behenyl base trimethyl ammonium chloride, the weight of cation guar gum and polyquaternium -7 Measuring ratio is：Polyquaternium-10：Behenyl base trimethyl ammonium chloride：Cation guar gum：Polyquaternium -7=1:1:1:2.

The surfactant is laureth sodium sulfovinate, laruyl alcohol sodium sulfovinate and cocounut oil acyl methyl taurine sodium Mixture；The weight ratio of the laureth sodium sulfovinate, laruyl alcohol sodium sulfovinate and cocounut oil acyl methyl taurine sodium is： Laureth sodium sulfovinate：Laruyl alcohol sodium sulfovinate：Cocounut oil acyl methyl taurine sodium=1:1:2.

The pH adjusting agent is citric acid.

Embodiment 10

Ginseng and Chinese angelica root in described to embodiment 1~9 carries out Physico-chemical tests without silicone oil shampoo, and gained Testing index is such as Under：

1st, character detects

1~9 ginseng and Chinese angelica root of embodiment is that viscosity is suitable without silicone oil shampoo, is had good stability, fragrant fan People, silk profit is smooth, fine and smooth uniform coffee-like shampoo.

2nd, pH value detects

To 1~9 ginseng and Chinese angelica root of embodiment without silicone oil hair washing water sampling, determined with pH meter, determined with pH meter, measure pH It is worth for 5.5~6.5.

3rd, viscosity number detects

To 1~9 ginseng and Chinese angelica root of embodiment without silicone oil hair washing water sampling, determined with viscosimeter, measure viscosity number 10000 ~12000.

4th, Detection of Stability

To 1~9 ginseng and Chinese angelica root of embodiment without silicone oil hair washing water sampling, it is encapsulated in transparence cosmetic bottle, divides Be not placed in quartz lamp illumination, -15 DEG C, 5 DEG C, 25 DEG C, under 48 DEG C of experiment conditions, to outward appearance, fragrance, pH value, viscosity and other Project carries out the continuance test of 3 months by a definite date, sees whether bleed, layering, separation, precipitation, discoloration, peculiar smell, demulsification etc. occur Bad phenomenon, testing result show that the bad result of the above is not appeared in test process, illustrates that it has good stability.

5th, centrifugation detection

To 1~9 ginseng and Chinese angelica root of embodiment without silicone oil hair washing water sampling, it is encapsulated in centrifuge tube in 3000r/ 30min is centrifuged under min, sees whether not dispersion component occur.Testing result shows not dispersion component do not occur, illustrate it Combination is good.

6th, anaphylaxis is stimulated to detect

To 1~9 ginseng and Chinese angelica root of embodiment without silicone oil have one's hair wash water sampling, it is applied in right amount volunteer (18-58 year, 30 people) 30min is observed on the back of the hand, see whether it phenomena such as redness, dermexanthesis, foaming occurs, observation indicate that, do not have bad Symptom occurs, and illustrates that this product will not produce stimulation and allergy sex chromosome mosaicism to skin.

7th, comprehensive using effect detection

Using opinion poll point system, the sample of four case study on implementation is tried out respectively by asking volunteer, and fill on probation Table carrys out overall merit its using effect.Volunteer (the 18-38,50 people of different age group is chosen respectively；38-58,50 people) conduct Object on probation, hair washing in every two days once, are used continuously three months, fill in table on probation after on probation and are scored.It is every in grade form Using effect total score is 5 points：5 points are best results, are represented very satisfied；4 points are preferable, are relatively satisfied with；3 points are to connect By；Less than the 3 points scopes for that cannot receive.Every using effect average situation is as shown in table 1.

1 embodiment of table, 1~9 ginseng and Chinese angelica root is without silicone oil shampoo items using effect average situation

Using effect	Cleannes	Compliance	Moisture retention	It is alimentary	Foaming abundancy degree	It is nonirritant
							Embodiment 1	4.92	4.80	4.86	4.82	4.92	5.00
Embodiment 2	4.90	4.88	4.84	4.76	4.89	5.00
							Embodiment 3	4.96	4.90	4.90	4.88	5.00	5.00
Embodiment 4	4.92	4.81	4.85	4.86	4.94	5.00
							Embodiment 5	4.90	4.80	4.85	4.80	4.86	5.00
Embodiment 6	4.78	4.80	4.80	4.71	4.72	5.00
							Embodiment 7	4.82	4.84	4.82	4.85	4.91	5.00
Embodiment 8	4.80	4.80	4.85	4.82	4.90	5.00
							Embodiment 9	4.85	4.80	4.87	4.83	4.94	5.00

Test result is as shown in table 1, the results showed that：1~9 ginseng and Chinese angelica root of embodiment is not only gentle without silicone oil shampoo It is non-stimulated, it is safe and healthy, there is preferable moisture retention and alimentary, foaming abundancy can take good care of head while deep clean Skin, long-term use can make hair quality it is shiny black it is submissive, gloss is beautiful, wherein feedback best results of embodiment 3.

Finally, it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention rather than the present invention is protected The limitation of scope is protected, although being explained in detail with reference to preferred embodiment to the present invention, one of ordinary skill in the art should Understand, technical scheme can be modified or equivalent substitution, without departing from the essence of technical solution of the present invention And scope.

Claims

1. a kind of ginseng and Chinese angelica root is without silicone oil shampoo, it is characterised in that includes the preparing raw material of following weight percentage：Ginseng The mixture 5~10% of extract and angelica extract and tax fat agent 1~5%；The tax fat agent is monoolein, PPG- At least one of 3 Octyl Ethers, PEG-55 propylene glycol oleates and PEG-7 glyceryl cocoates.

2. ginseng and Chinese angelica root as claimed in claim 1 is without silicone oil shampoo, it is characterised in that the tax fat agent is oleic acid list glycerine Ester, PPG-3 Octyl Ethers, the mixture of PEG-55 propylene glycol oleates and PEG-7 glyceryl cocoates；The oleic acid list glycerine Ester, PPG-3 Octyl Ethers, the weight ratio of PEG-55 propylene glycol oleates and PEG-7 glyceryl cocoates are：Monoolein： PPG-3 Octyl Ethers：PEG-55 propylene glycol oleates：PEG-7 glyceryl cocoate=1~10:1~10:1~10:1~10.

3. ginseng and Chinese angelica root as claimed in claim 1 is without silicone oil shampoo, it is characterised in that ginseng extract and the Radix Angelicae Sinensis extraction In the mixture of thing, the weight ratio of the ginseng extract and angelica extract is：Ginseng extract：Angelica extract=1~ 5:1。

4. ginseng and Chinese angelica root as claimed in claim 1 is without silicone oil shampoo, it is characterised in that shampoo also prepares original comprising following Material：Surfactant, cation opsonizing agent, hair conditioner, antiseptic substitute and thickener；The ginseng and Chinese angelica root is without silicone oil In the preparing raw material of shampoo, the weight percentage of the surfactant in the feed is 22~48%, the cation The weight percentage of conditioner in the feed is 0.1~1.5%, the weight percentage of the hair conditioner in the feed For 0.2~4%, the weight percentage of the antiseptic substitute in the feed is 0.01~0.5%, and the thickener is in original Weight percentage in material is 0.1~10%.

5. ginseng and Chinese angelica root as claimed in claim 4 is without silicone oil shampoo, it is characterised in that the antiseptic substitute is decoyl hydroxyl Oxime acid, parahydroxyacet-ophenone, the mixture of glycerine octanoic acid fat and butanediol.

6. ginseng and Chinese angelica root as claimed in claim 4 is without silicone oil shampoo, it is characterised in that the hair conditioner is cocoyl two At least one of ammonium methyl Hydroxypropyl Hydrolyzed Wheat keratin, Hydrolyzed Collagen and panthenol；Preferably, the hair conditioning Agent is the mixture of cocodimonium hydroxypropyl base hydrolyzed wheat keratin, Hydrolyzed Collagen and panthenol；The cocoyl The weight ratio of Dimethyl Ammonium Hydroxypropyl Hydrolyzed Wheat keratin, Hydrolyzed Collagen and panthenol is：Cocodimonium hydroxypropyl Base hydrolyzed wheat keratin：Hydrolyzed Collagen：Panthenol=1~3:1~3:1~3.

7. ginseng and Chinese angelica root as claimed in claim 4 is without silicone oil shampoo, it is characterised in that the cation opsonizing agent is polyquaternary amine At least one of salt -10, behenyl base trimethyl ammonium chloride, cation guar gum and polyquaternium -7；Preferably, it is described sun from Sub- conditioner is the mixture of Polyquaternium-10, behenyl base trimethyl ammonium chloride, cation guar gum and polyquaternium -7；Institute The weight ratio for stating Polyquaternium-10, behenyl base trimethyl ammonium chloride, cation guar gum and polyquaternium -7 is：Polyquaternium- 10：Behenyl base trimethyl ammonium chloride：Cation guar gum：Polyquaternium -7=1~3:1~3:1~3:1~3.

8. ginseng and Chinese angelica root as claimed in claim 4 is without silicone oil shampoo, it is characterised in that the surfactant is lauroyl two Property base diethyl acid disodium, laruyl alcohol sulfosuccinate disodium, tallow fatty acid sodium, laureth sodium sulfovinate, laruyl alcohol sulfuric acid At least one of ester sodium, cocounut oil acyl methyl taurine sodium and Cocoamidopropyl betaine；Preferably, the surfactant For the mixture of laureth sodium sulfovinate, laruyl alcohol sodium sulfovinate and cocounut oil acyl methyl taurine sodium；The laruyl alcohol gathers The weight ratio of ether sodium sulfovinate, laruyl alcohol sodium sulfovinate and cocounut oil acyl methyl taurine sodium is：Laureth sodium sulfovinate：Month Cinnamic alcohol sodium sulfovinate：Cocounut oil acyl methyl taurine sodium=3~5:2~3:1~2.

9. ginseng and Chinese angelica root as claimed in claim 4 is without silicone oil shampoo, it is characterised in that the thickener is cocamidopropyl first The mixture of base glycine betaine and coconut oleoyl amine MEA；The weight ratio of the cocamidopropyl methyl betaine and coconut oleoyl amine MEA For：Cocamidopropyl methyl betaine：Coconut oleoyl amine MEA=1~3:0.5~2.

10. a kind of preparation method of the ginseng and Chinese angelica root as any one of claim 1~9 without silicone oil shampoo, its feature exist In comprising the following steps：

(1), surfactant is added in 80~85 DEG C of deionized water, is well mixed, adds cation opsonizing agent, mixed Uniformly, component A is obtained；

(3) component B, is cooled to less than 42 DEG C, adds hair conditioner, essence and antiseptic substitute thereto, mixing is equal It is even, pH value is adjusted, thickener is added, adjusts to target viscosity, produce the ginseng and Chinese angelica root without silicone oil shampoo.