CN106420407A - Child silicone-oil-free shampoo with vegetable oil and fat replacing silicone oil - Google Patents
Child silicone-oil-free shampoo with vegetable oil and fat replacing silicone oil Download PDFInfo
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- CN106420407A CN106420407A CN201610770982.1A CN201610770982A CN106420407A CN 106420407 A CN106420407 A CN 106420407A CN 201610770982 A CN201610770982 A CN 201610770982A CN 106420407 A CN106420407 A CN 106420407A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/735—Mucopolysaccharides, e.g. hyaluronic acid; Derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/34—Free of silicones
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Abstract
The invention discloses child silicone-oil-free shampoo with vegetable oil and fat replacing silicone oil. The child silicone-oil-free shampoo is prepared from the following raw materials through a common method for preparing cream, and the raw materials comprise, by weight, 5-25% of anionic surfactant, 1-10% of ampholytic surfactant, 0.1-2% of positive ion conditioning agent, 0.05-2% of vegetable oil and fat, 0.05-0.2% of viscosity modifier, 0.05-2% of wetting agent, 0.01-0.05% of chelating agent, 0.05-0.2% of essence, 0.05-0.2% of anti-corrosive agent and the balance water. The vegetable oil and fat are adopted for replacing the silicone oil which is widely applied to shampoo in the prior art, so that sedimentation of the silicon oil on hair is eliminated, the phenomena of oily hair and withered and yellow hair are reduced, and meanwhile biological degradation is effectively achieved.
Description
Technical field
The present invention relates to a kind of hair washing for child water, specifically a kind of children's no silicone oil hair washing substituting silicone oil with vegetable fat
Water.
Background technology
No silicone oil is declared gradually to enter into the visual field of consumer, becomes one new trend in Asia hair care product market.Silicon
Oil has very high molecule flexibility and weaker inter-molecular attraction, and its surface energy is low, and spreadability is splendid, has good preventing
Aqueous energy and filming performance, these characteristics make silicone oil can form the hydrophobic membrane of densification on hair shaft so that head with uniform fold
Deliver face flat smooth, consumer easily realizes its outstanding conditioning performance, be a kind of very high personal care articles of cost performance
Conventional raw material.But children's hair quality is thin, if too high silicone oil deposition, hair can be caused to subside, hair follicle blocks, Long-Time Service can make
Hair becomes withered, is unfavorable for the health of hair of children and scalp.Additionally, silicone oil is not degradable, easily environment is caused serious
Pollution.
It is known that hair is dry being mainly made up of the keratin not having vital activity, therefore its own lacks reparation work(
Energy.Dry it is divided into epidermal area, cortical layer and medullary substance layer from outside to inside.Epidermal area is mainly by multi-layer cellular such as fish scale-shaped arrangement
Become, mainly negatively charged, intact hair quality is also very hydrophobic simultaneously.Therefore, from formula angle analysis, add vegetable fat easily
It is attached on dry, hair forming layer protecting film and is not easy washed away, decreasing the friction between hair thus carrying
High conditioning performance.Hydrophilic plant grease can provide the hair conditioning of grease sense, play an important role, carry in terms of substituting silicone oil
The high smoothness of hair, increases texture and the hair conditioning of hair, and improves the glossiness of hair.Therefore research and develop one kind to plant
Children's no silicone oil shampoo that thing grease substitutes silicone oil is the research purpose of the present invention.
Content of the invention
It is an object of the invention to provide a kind of children's no silicone oil shampoo substituting silicone oil with vegetable fat.
Technical scheme is as follows：
A kind of children's no silicone oil shampoo substituting silicone oil with vegetable fat, described children no silicone oil shampoo is with weight by following
The method that the raw material routine of amount percentage configuration prepares creme is prepared from：
Anion surfactant 5～25%
Amphoteric surfactant 1～10%
Cation opsonizing agent 0.1～2%
Vegetable fat 0.05～2%
Viscosity modifier 0.05～0.2%
NMF 0.05～2%
Chelating agent 0.01～0.05%
Essence 0.05～0.2%
Preservative 0.05～0.2%
Water surplus.
Described anion surfactant is laureth sulfuric ester ammonium, laureth sodium sulfovinate, laruyl alcohol gather
One of ether sulfosuccinates disodium, laurate sodium taurocholate or two kinds.
Described amphoteric surfactant is Cocoamidopropyl betaine, dodecanamide propyl hydroxy sulfo lycine, palm
One of amido propyl betaine or two kinds.
Described cation opsonizing agent is ricinoleic acid amide hydroxypropyltrimonium chloride, melon glue Hydroxyproyl Trimethyl chlorination
One of ammonium, soybean oil base trimethyl ammonium chloride, polyquaternium -7, Polyquaternium-10, polyquaternium -52 or two kinds.
Described vegetable fat is Butyrospermum parkii fruit fatty oil, olive oil, Queensland nut seed oil, sunflower oil, PPG-3 are pungent
One of base ether or two kinds.
Described viscosity modifier is sodium chloride, hydroxypropyl cellulose, carboxymethylcellulose calcium, polyvinylpyrrolidone, PEG-
One of 120 methyl dioleates or two kinds.
Described chelating agent is one of disodium ethylene diamine tetraacetate, tetrasodium ethylenediamine tetraacetate, sodium glucoheptonate or two
Kind.
Described NMF is Sodium Hyaluronate or glycerine or Natrulon H-10.
Preservative is using DMDMH or methylisothiazolinone or iodine propilolic alcohol butyl mephenesin Carbamate.
Described anion surfactant is laureth sulfuric ester ammonium.
Described amphoteric surfactant is Cocoamidopropyl betaine.
Described cation opsonizing agent is ricinoleic acid amide hydroxypropyltrimonium chloride, guar hydroxypropyltrimonium chlorination
One of ammonium or two kinds.
Described vegetable fat is one of Butyrospermum parkii fruit fatty oil, PPG-3 Octyl Ether or two kinds.
Described viscosity modifier is one of sodium chloride, PEG-120 methyl dioleate or two kinds.
Described chelating agent is one of sodium glucoheptonate, disodium ethylene diamine tetraacetate or two kinds.
Compared with prior art, the present invention has advantages below：
The present invention is substituted in the silicone oil being widely used at present in shampoo using the vegetable fat of natural origin, eliminates silicone oil
Hair deposits, decreases the fuel-displaced phenomenon with withered and yellowish hairs of hair, also efficiently solve biodegradable problem simultaneously.
The children of the present invention no silicone oil shampoo foaming abundancy, stable, product property milder, safer health, effectively
Protection hair of children and scalp health, can significantly improve smoothness, wet thin property, dry comb property and the glossiness of product simultaneously, prevent
Hair follicle blocks, and solves the problems, such as that scalp hair oil and hair are easily withered and yellow.
Hydrophilic plant grease can provide the hair conditioning of grease sense, plays an important role in terms of substituting silicone oil, improves
The smoothness of hair, increases texture and the hair conditioning of hair, and improves the glossiness of hair.
Specific embodiment
For the ease of it will be appreciated by those skilled in the art that being described in further detail to the present invention by the following examples, but
The present invention is not limited only to this.
Following vegetable fat mixtures is by the rich mixture of Butyrospermum parkii fruit fatty oil and the preparation of PPG-3 Octyl Ether,
And with Butyrospermum parkii fruit fatty oil 50%, the ratio of PPG-3 Octyl Ether 50% mixes.
Embodiment one：
A kind of children's no silicone oil shampoo substituting silicone oil with vegetable fat, described children no silicone oil shampoo is with weight by following
The method that the raw material routine of amount percentage configuration prepares creme is prepared from：
Laureth sulfuric ester ammonium 12%
Cocoamidopropyl betaine 3%
Ricinoleic acid amide hydroxypropyltrimonium chloride 0.4%
Vegetable fat mixture 1%
PEG-120 methyl dioleate 0.15%
Sodium Hyaluronate 0.1%
Sodium glucoheptonate 0.02%
Essence 0.3%
Methylisothiazolinone 0.1%
Water 82.93%.
Embodiment two：
A kind of children's no silicone oil shampoo substituting silicone oil with vegetable fat, described children no silicone oil shampoo is with weight by following
The method that the raw material routine of amount percentage configuration prepares creme is prepared from：
Laureth sulfuric ester ammonium 12%
Cocoamidopropyl betaine 3%
Ricinoleic acid amide hydroxypropyltrimonium chloride 0.4%
Vegetable fat mixture 1.5%
PEG-120 methyl dioleate 0.15%
Sodium Hyaluronate 0.1%
Sodium glucoheptonate 0.02%
Essence 0.3%
Methylisothiazolinone 0.1%
Water 82.43%.
Embodiment three：
A kind of children's no silicone oil shampoo substituting silicone oil with vegetable fat, described children no silicone oil shampoo is with weight by following
The method that the raw material routine of amount percentage configuration prepares creme is prepared from：
Laureth sulfuric ester ammonium 12%
Cocoamidopropyl betaine 3%
Ricinoleic acid amide hydroxypropyltrimonium chloride 0.4%
Vegetable fat mixture 2%
PEG-120 methyl dioleate 0.15%
Sodium Hyaluronate 0.1%
Sodium glucoheptonate 0.02%
Essence 0.3%
Methylisothiazolinone 0.1%
Water 81.93%.
The preparation method of children's no silicone oil shampoo：Suitable quantity of water is added in retort, adds castor under slow stirring
Numb alkyd amidopropyltrimonium chloride is disperseed, and is heated with stirring to 80 DEG C, adds PEG-120 methyl two oleic acid
Ester, laureth sulfuric ester ammonium, Sodium Hyaluronate, sodium glucoheptonate, after stirring makes these materials be completely dispersed, are cooled to 50
DEG C about when add rich mixture, be finally cooled to 40 DEG C about add Cocoamidopropyl betaine, methylisothiozoline
Ketone and essence are it is ensured that finally obtain uniform mixture.
Experimental data
The mixture that draw above-described embodiment one, embodiment two and embodiment three and following prepared shampoo composite are carried out
Contrast test.
Shampoo composite 1：Butyrospermum parkii fruit fatty oil 1%（Formula accounting）Substituted plant rich mixture, other components are joined
Side is constant, and preparation method is identical with preparation method of the present invention；
Shampoo composite 2：PPG-3 Octyl Ether 1%（Formula accounting）Substituted plant rich mixture, other components formula is constant, system
Preparation Method is identical with preparation method of the present invention；
Shampoo composite 3：Dimethyl silicone polymer（Silicone oil）1%（Formula accounting）Substituted plant rich mixture, other components are joined
Side is constant, and preparation method is identical with preparation method of the present invention；
Shampoo composite 4：Dimethyl silicone polymer（Silicone oil）2%（Formula accounting）Substituted plant rich mixture, other components are joined
Side is constant, and preparation method is identical with preparation method of the present invention；
Shampoo composite 5：Dimethyl silicone polymer（Silicone oil）3%（Formula accounting）Substituted plant rich mixture, other components are joined
Side is constant, and preparation method is identical with preparation method of the present invention.
Glossiness, the evaluation of wet thin property, dry comb property and smoothness：
1st, evaluation method：Detection takes volunteer to try out, and is carried out by way of sensory evaluation.Volunteer is 8-12 year female
Child, can independently be tested.It is divided into 5 groups of people, every group of 10 people.
2nd, glossiness：By visual observation, glossy degree after so doing for the viewing head；
Wet comb：In hair wet clean process, combed by examination, experience the cardability of hair；
Dry comb property：After hair is done naturally, combed by examination, experience the cardability of hair；
Smoothness：Sent out by comforting contact, experience the smoothness of hair；
Mildness：Washed by examination, a little foam is penetrated into canthus and periphery, experiences the excitant whether composition brings eyes.
3rd, by shampoo composite 1-5, embodiment one to three are carried out with glossiness, wet thin property, dry comb property, smoothness are beaten
Point, total score is 5 points, 5 points of best result, minimum point 1 point.Evaluation cycle is 4 weeks.
4th, evaluation result see table shown in 1：
Table 1 test evaluation table divides
| Evaluation index | Shampoo composite 1 | Shampoo composite 2 | Shampoo composite 3 | Shampoo composite 4 | Shampoo composite 5 | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Glossiness | 3.5 | 3.7 | 3.9 | 4.2 | 4.5 | 4.1 | 4.2 | 4.4 |
| Wet comb | 3.2 | 3.3 | 3.8 | 4.1 | 4.6 | 4.1 | 4.3 | 4.5 |
| Dry comb property | 3.0 | 3.2 | 3.8 | 4.3 | 4.5 | 4.2 | 4.4 | 4.4 |
| Smoothness | 3.2 | 3.3 | 4.3 | 4.5 | 4.8 | 4.2 | 4.3 | 4.6 |
As can be seen from the above table：Silicone oil shampoo composite 3,4,5, show than the more superior glossiness of composition 1,2, wet dredge
Property, dry comb property and smoothness, the satisfaction of wherein shampoo composite 5 is highest.When the group in shampoo is divided into formulation Example
First, two, three when hence it is evident that showing rich mixture more preferably glossiness, wet thin property, the dry comb property and smooth than one-component
Degree, wherein embodiment 3 show the satisfaction close with high content silicon oil shampoo composite 5.This with vegetable fat substituted for silicon
Children's no silicone oil shampoo of oil can efficiently and effectively reach glossiness, the purpose of wet thin property, dry comb property and smoothness.And
These compositions and formulation Example, during examination is washed, all do not have the phenomenon of Ocular irritation, indicate this no silicone oil hair washing
The selected equal safety and Health of each raw material in water, does not stimulate.
In sum：Substituted in the silicone oil being widely used at present in shampoo using vegetable fat, eliminate silicone oil and exist
Deposit on hair, cause the fuel-displaced phenomenon with withered and yellowish hairs of hair, efficiently solve biodegradable problem.One kind is with vegetable oil
Fat substitutes children's no silicone oil shampoo of silicone oil, foaming abundancy, stable, product property milder, safer health, effective protection
Hair of children and scalp health, can significantly improve glossiness, wet thin property, dry comb property and the smoothness of product simultaneously.
The foregoing is only presently preferred embodiments of the present invention, all impartial changes done according to scope of the present invention patent with
Modify, all should belong to the covering scope of the present invention.
Claims (15)
1. a kind of with vegetable fat substitute silicone oil children's no silicone oil shampoo it is characterised in that：Described children no silicone oil hair washing
Water is to be prepared from by the method that following raw materials configuring in proportion by weight percentage routine prepares creme：
Anion surfactant 5～25%
Amphoteric surfactant 1～10%
Cation opsonizing agent 0.1～2%
Vegetable fat 0.05～2%
Viscosity modifier 0.05～0.2%
NMF 0.05～2%
Chelating agent 0.01～0.05%
Essence 0.05～0.2%
Preservative 0.05～0.2%
Water surplus.
2. according to claim 1 a kind of with vegetable fat substitute silicone oil children's no silicone oil shampoo it is characterised in that：
Described anion surfactant is laureth sulfuric ester ammonium, laureth sodium sulfovinate, laureth sulfo group amber
One of amber acid esters disodium, laurate sodium taurocholate or two kinds.
3. according to claim 1 a kind of with vegetable fat substitute silicone oil children's no silicone oil shampoo it is characterised in that：
Described amphoteric surfactant is Cocoamidopropyl betaine, dodecanamide propyl hydroxy sulfo lycine, palmitamide propyl group
One of glycine betaine or two kinds.
4. according to claim 1 a kind of with vegetable fat substitute silicone oil children's no silicone oil shampoo it is characterised in that：
Described cation opsonizing agent is ricinoleic acid amide hydroxypropyltrimonium chloride, guar hydroxypropyltrimonium chloride, soybean
One of oil base trimethyl ammonium chloride, polyquaternium -7, Polyquaternium-10, polyquaternium -52 or two kinds.
5. according to claim 1 a kind of with vegetable fat substitute silicone oil children's no silicone oil shampoo it is characterised in that：
Described vegetable fat is Butyrospermum parkii fruit fatty oil, olive oil, Queensland nut seed oil, sunflower oil, in PPG-3 Octyl Ether
One or two.
6. a kind of children's no silicone oil shampoo substituting silicone oil with vegetable fat according to claim 1, its feature exists
In：Described viscosity modifier is sodium chloride, hydroxypropyl cellulose, carboxymethylcellulose calcium, polyvinylpyrrolidone, PEG-120 first
One of base glucose dioleate or two kinds.
7. according to claim 1 a kind of with vegetable fat substitute silicone oil children's no silicone oil shampoo it is characterised in that：
Described chelating agent is one of disodium ethylene diamine tetraacetate, tetrasodium ethylenediamine tetraacetate, sodium glucoheptonate or two kinds.
8. according to claim 1 a kind of with vegetable fat substitute silicone oil children's no silicone oil shampoo it is characterised in that：
Described NMF is Sodium Hyaluronate or glycerine or Natrulon H-10.
9. according to claim 1 a kind of with vegetable fat substitute silicone oil children's no silicone oil shampoo it is characterised in that：
Preservative is using DMDMH or methylisothiazolinone or iodine propilolic alcohol butyl mephenesin Carbamate.
10. a kind of children's no silicone oil shampoo substituting silicone oil with vegetable fat according to claim 2, its feature exists
In：Described anion surfactant is laureth sulfuric ester ammonium.
A kind of 11. children's no silicone oil shampoos substituting silicone oil with vegetable fat according to claim 3, its feature exists
In：Described amphoteric surfactant is Cocoamidopropyl betaine.
A kind of 12. children's no silicone oil shampoos substituting silicone oil with vegetable fat according to claim 4, its feature exists
In：Described cation opsonizing agent is ricinoleic acid amide hydroxypropyltrimonium chloride, in guar hydroxypropyltrimonium ammonium chloride
One or two.
A kind of 13. children's no silicone oil shampoos substituting silicone oil with vegetable fat according to claim 5, its feature exists
In：Described vegetable fat is one of Butyrospermum parkii fruit fatty oil, PPG-3 Octyl Ether or two kinds.
A kind of 14. children's no silicone oil shampoos substituting silicone oil with vegetable fat according to claim 6, its feature exists
In：Described viscosity modifier is one of sodium chloride, PEG-120 methyl dioleate or two kinds.
A kind of 15. children's no silicone oil shampoos substituting silicone oil with vegetable fat according to claim 7, its feature exists
In：Described chelating agent is one of sodium glucoheptonate, disodium ethylene diamine tetraacetate or two kinds.
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107184406A (en) * | 2017-05-11 | 2017-09-22 | 曾万祥 | One kind is planted extraction without anti-corrosion ginger without silicone oil shampoo and preparation method thereof |
| CN107375053A (en) * | 2017-06-16 | 2017-11-24 | 曾万祥 | A kind of ginseng and Chinese angelica root is without silicone oil shampoo and preparation method thereof |
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| CN107603789A (en) * | 2017-09-01 | 2018-01-19 | 拉芳家化股份有限公司 | A kind of conditioning-type solid-state hair soap |
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| CN109757099A (en) * | 2017-09-05 | 2019-05-14 | 拉芳家化股份有限公司 | It is a kind of containing Rhizoma Zingiberis zerumbet petal extract without silicon shampoo |
| CN109864933A (en) * | 2019-04-20 | 2019-06-11 | 福建省梦娇兰日用化学品有限公司 | A kind of hair of children cleaning compositions of not silicate-containing oil and preparation method thereof |
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Cited By (16)
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| WO2018152718A1 (en) * | 2017-02-23 | 2018-08-30 | Beiersdorf Daily Chemical (Wuhan) Co. Ltd. | Silicone-free shampoo composition |
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| CN109757099A (en) * | 2017-09-05 | 2019-05-14 | 拉芳家化股份有限公司 | It is a kind of containing Rhizoma Zingiberis zerumbet petal extract without silicon shampoo |
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| CN109864933A (en) * | 2019-04-20 | 2019-06-11 | 福建省梦娇兰日用化学品有限公司 | A kind of hair of children cleaning compositions of not silicate-containing oil and preparation method thereof |
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| CN115813820A (en) * | 2022-12-14 | 2023-03-21 | 福建省梦娇兰日用化学品有限公司 | Double-layer shampoo shower gel containing grease and preparation method thereof |
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