CN112076108A - Children hair cleaning product containing bionic phospholipid structure conditioning agent - Google Patents
Children hair cleaning product containing bionic phospholipid structure conditioning agent Download PDFInfo
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- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
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- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/368—Carboxylic acids; Salts or anhydrides thereof with carboxyl groups directly bound to carbon atoms of aromatic rings
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/55—Phosphorus compounds
- A61K8/553—Phospholipids, e.g. lecithin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
- A61K2800/5922—At least two compounds being classified in the same subclass of A61K8/18
Abstract
The invention discloses a children hair cleaning product containing a bionic phospholipid structure conditioner, which comprises the following components: 10-15 parts by mass of an anionic surfactant, 2-5 parts by mass of a zwitterionic surfactant, 1-3 parts by mass of a nonionic surfactant, 0.05-0.2 part by mass of a high-molecular polymer cation conditioner, 1-2 parts by mass of a small-molecular cation conditioner, 0-0.5 part by mass of emulsified silicone oil, 0.5-1.5 parts by mass of a thickening agent, 0.01-0.05 part by mass of a chelating agent, 0.05-0.1 part by mass of a pH regulator, 0.1-0.3 part by mass of a preservative, 0.05-0.2 part by mass of essence, 3-5 parts by mass of bionic phospholipid and the balance of deionized water. The bionic phospholipid provided by the invention has excellent conditioning performance, excellent performance in dry and wet combing, high mild degree and good skin friendliness, improves the performance of children hair cleaning products, and improves the comfort of children in use and after use; reduces the stimulation of the surfactant to the skin of children, and is suitable for children to use for a long time.
Description
Technical Field
The invention relates to the technical field of personal care products, in particular to a children hair cleaning product containing a bionic phospholipid structure conditioner.
Background
The age stage of children is generally considered to be 3-12 years old, and is between infants and teenagers, and the skin and hair structures of children are more mature than those of infants, but are still greatly different from those of adults. Mainly, although the skin barrier function is basically developed completely, the skin is still thin, sensitive and fragile, and the influence on an external stimulus source cannot be effectively resisted. On the other hand, sweat gland secretion is large due to rapid metabolism, but sebaceous gland potency is relatively low in adults, that is, sebum secretion is not large. Children's hair is generally fine, soft, and dry.
Based on the skin and hair characteristics of children, the children's hair cleansing product does not need excessive sebum removal, so that on one hand, the children have less sebum, and on the other hand, a proper amount of sebum can help to maintain the skin barrier, so that the children's hair cleansing product does not need strong cleansing capability. Meanwhile, in view of the comfort needs of children, there is a need to further improve the performance of children's hair cleansing products, which may be added with functional additives capable of providing conditioning, moisturizing, lubricating, and shine to the hair. Ingredients that provide the above-mentioned functions to the hair, most commonly cationic polymer-based and silicone-based products. The cationic polymer conditioner mainly comprises cationic guar gum, cationic cellulose, polyquaternium and the like; the silicone oil has many kinds, but all have the functions of stable structure, low surface tension and smoothness. Cationic polymers and silicone oils are commonly used in a hair cleansing product formula in a matching way, and mainly the cationic polymers are adsorbed on hair in a washing process, and are diluted to form a flocculation gel, and the flocculation gel wraps silicone oil to deposit on the hair, so that a silicone oil protective layer is formed on the surface of the hair, and the synergistic effect of the cationic polymers and the silicone oil endows the hair cleansing product with better hair drying and hair wetting combing effects.
Despite the many advantages of cationic polymers and silicone-based products, both tend to build up on the hair, giving the hair a heavy and greasy feel. Therefore, products capable of improving the defect of the combination of the two are increasingly highlighted.
The bionic phospholipid is a substance simulating natural phospholipid from the structure, the molecular structure is an amphiprotic molecule, one end of the amphiprotic molecule is a hydrophilic nitrogen or phosphorus-containing head, the other end of the amphiprotic molecule is a hydrophobic (oleophilic) long alkyl chain, the hydrophilic group is formed by phosphate ester salt, and according to the structure of the phosphate ester salt, namely according to the number of esterification participated by three-OH in phosphoric acid, the phosphate ester surfactant can be divided into monoester, diester and triester. The bionic phospholipid has different application performances according to different ester structures, namely different proportions of monoester, diester and triester, and the monoester and the salt thereof have good emulsification and solubilization capacities and good cleaning capacity on sebum; the diester and triester and their salts have lower detergency than monoester, but have good conditioning effect and antistatic ability. Bionic phospholipids have been used in personal care products, such as applications with publication numbers CN201810012189.4, CN201810011238.2, etc., which relate to products such as hair care, bath, etc., but in these published data, there is less disclosure on the structure of bionic phospholipids, and meanwhile, there is less application of bionic phospholipid conditioners in children's hair cleansing products.
Disclosure of Invention
The invention aims to overcome the technical defects and provide a children hair cleaning product containing a bionic phospholipid structure conditioner.
In order to solve the problems, the technical scheme of the invention is as follows: a children hair cleaning product containing bionic phospholipid structure conditioning agent comprises the following components: 10-15 parts by mass of an anionic surfactant, 2-5 parts by mass of a zwitterionic surfactant, 1-3 parts by mass of a nonionic surfactant, 0.05-0.2 part by mass of a high-molecular polymer cation conditioner, 1-2 parts by mass of a small-molecular cation conditioner, 0-0.5 part by mass of emulsified silicone oil, 0.5-1.5 parts by mass of a thickening agent, 0.01-0.05 part by mass of a chelating agent, 0.05-0.1 part by mass of a pH regulator, 0.1-0.3 part by mass of a preservative, 0.05-0.2 part by mass of essence, 3-5 parts by mass of bionic phospholipid and the balance of deionized water.
As a refinement, the anionic surfactant is preferably a sulfate salt, such as sodium laureth sulfate, ammonium laureth sulfate, MEA salt of laureth sulfate, MIPA salt of laureth sulfate, TEA salt of laureth sulfate, TIPA salt of laureth sulfate; or phosphate salts, such as potassium lauryl phosphate, sodium lauryl phosphate, potassium laureth phosphate, sodium lauryl phosphate, potassium C12-13 phosphate; or amino acid salts such as sodium lauroyl sarcosinate, potassium cocoyl glycinate, sodium lauroyl glutamate, sodium cocoyl glutamate, potassium cocoyl glutamate, disodium cocoyl glutamate, TEA cocoyl glutamate, sodium lauroyl alanine, sodium cocoyl alanine, sodium lauroyl methyl taurate, sodium cocoyl methyl taurate; or N-fatty acyl hydrolyzed protein salts, such as one or more of potassium cocoyl hydrolyzed oat protein, sodium cocoyl hydrolyzed wheat protein, potassium cocoyl hydrolyzed soy protein, sodium cocoyl hydrolyzed soy protein, TEA cocoyl hydrolyzed collagen, potassium palmitoyl hydrolyzed wheat protein, potassium lauroyl hydrolyzed soy protein, TEA lauroyl hydrolyzed collagen, potassium lauroyl hydrolyzed collagen, and sodium lauroyl hydrolyzed collagen.
As an improvement, the zwitterionic surfactant is preferably of the betaine type, more preferably caprylyl/caprylamidopropyl betaine, cocoyl betaine, cocamidopropyl betaine, lauramidopropyl betaine, myristyl betaine, myristamidopropyl betaine, palmamidopropyl betaine, palm kernel oil amidopropyl betaine, oleamidopropyl betaine, erucamidopropyl hydroxysultaine, behenyl betaine, isostearamidopropyl betaine, cocoyl/oleamidopropyl betaine, lauramidopropyl hydroxysultaine, cocamidopropyl hydroxysultaine, cocoyl/oleamidopropyl betaine, oleyl betaine, oleamidopropyl betaine, babassu oleamidopropyl betaine, soybean oleamidopropyl betaine, shea butter amidopropyl betaine, One or at least two of wheat germ oleamidopropyl betaine and undecenamidopropyl betaine.
As an improvement, the nonionic surfactant is preferably an alkyl glycoside, more preferably one or at least two of lauryl glucoside, coco glucoside, myristyl glucoside, octyl/decyl glucoside, C12-18 alkyl glucoside, C12-20 alkyl glucoside, C8-14 alkyl glucoside, and xylitol-based glucoside.
As an improvement, the high molecular polymer cation conditioner is preferably one or at least two of polyquaternium-10, guar gum hydroxypropyl trimethyl ammonium chloride, locust bean gum hydroxypropyl trimethyl ammonium chloride, tara hydroxypropyl trimethyl ammonium chloride, cassia gum hydroxypropyl trimethyl ammonium chloride, hydrogenated starch hydrolysate hydroxypropyl trimethyl ammonium chloride and glucan hydroxypropyl trimethyl ammonium chloride; the small-molecular cationic conditioner is preferably one or at least two of distearoyloxyethyldimethylammonium chloride, dipalmitoyloxyethyldimethylammonium chloride and ricinoleic acid amidopropyl trimethylammonium chloride.
As an improvement, the emulsified silicone oil is preferably emulsified silicone oil by a nonionic surfactant or an anionic surfactant, and the obtained silicone oil emulsion comprises polydimethylsiloxane with emulsifying viscosity of 30-150 million centipoise by using C12-14 alkanol polyether-3, C12-14 alkanol polyether-5, C12-14 alkanol polyether-7, C12-14 alkanol polyether-9, sodium laureth sulfate and ammonium laureth sulfate as emulsifying agents, and preferably the polydimethylsiloxane with emulsifying viscosity of 50 million centipoise by using ammonium laureth sulfate.
As a modification, the thickening agent is preferably one or at least two of acrylic acid (ester) copolymer, styrene/acrylic acid (ester) copolymer, carbomer TEA salt, carbomer sodium and carbomer potassium; the chelating agent is preferably one or at least two of phytic acid, sodium phytate, EDTA disodium, EDTA tetrasodium, sodium glucoheptonate, etidronic acid and sodium citrate; the pH regulator is preferably one or at least two of lactic acid, phosphoric acid, citric acid, hydrochloric acid, glycolic acid, propionic acid and fruit acid; the preservative is preferably one or at least two of phenoxyethanol, 1, 2-hexanediol, 1, 2-pentanediol, sodium benzoate, sodium lactate, p-anisic acid and glyceryl caprylate; the essence is commercially available cosmetic grade essence.
As an improvement, the bionic phospholipid structure conditioner has the following structure:
the R group carboxyl structure preferably consists of a C12-C16 saturated alkyl chain structure and a C18 unsaturated alkyl chain structure, and the mass ratio of the two is 1: 1; the C12-C16 saturated alkyl chain structure comprises one or at least two of a lauric acid structure, a coconut oil acid structure, a myristic acid structure and a palmitic acid structure, and when the number of the saturated alkyl chain structures is two or more, the mass ratio of the components is the same; the C18 unsaturated alkyl chain structure comprises one or at least two of an oleic acid structure, a linoleic acid structure and a linolenic acid structure, and when the number of the structures is two or more, the mass ratio of the components is the same; in the bionic phospholipid structure, when x is 1, y is 2, z is 1, and the bionic phospholipid structure is a phosphate monoester structure; when x is 2, y is 1, z is 2, and the structure is phosphoric acid diester; when x is 3, y is 0, z is 3, a phosphotriester structure; in the bionic phospholipid structure, the proportion of monoester to diester to triester is (10-20) to (70-90) to (0-10); in the bionic phospholipid structure, the proportion of the monoester, the diester and the triester can be obtained by adjusting a synthesis process.
The preparation method of the children hair cleaning product containing the bionic phospholipid structure conditioning agent comprises the following steps:
(1) adding a certain amount of deionized water into a stirring kettle, adding a chelating agent, 80% by mass of a pH regulator and a high molecular polymer cation conditioner, stirring until the chelating agent, the pH regulator and the high molecular polymer cation conditioner are completely dissolved, adding an anionic surfactant, a zwitterionic surfactant and a nonionic surfactant, stirring until the mixture is uniform, heating to 80-85 ℃, and preserving heat for 30-45 min;
(2) stirring and cooling, adding a small molecular cation conditioner and bionic phospholipid when the temperature is reduced to 55-60 ℃, and stirring uniformly;
(3) and (3) continuing stirring and cooling, adding the thickening agent and the emulsified silicone oil when the temperature is reduced to 45-55 ℃, adjusting the pH by using the rest 20% of the pH adjusting agent in parts by mass, finally adding the essence and the preservative, standing and defoaming to obtain the children hair cleaning product containing the bionic phospholipid structure conditioning agent.
Compared with the prior art, the invention has the advantages that: the bionic phospholipid provided by the invention has a specially designed carbon chain and reasonable structures of mono-ester, di-ester and tri-ester, has superior conditioning performance compared with the commercial bionic phospholipid, is excellent in dry and wet combing, high in mild degree and good in skin affinity, and is suitable for children hair cleaning products; the formula can partially replace the use of high-molecular cationic polymers in the formula, so that the dryness and roughness caused by the accumulation of the cationic polymers on hair are reduced, the performance of the children hair cleaning product is improved, and the comfort of children in use and after use is improved; the product can be used in children hair cleaning products without silicone oil, has good esterification effect, can also be used in formula systems containing silicone oil, and can reduce the dosage of emulsified silicone oil; the children hair cleaning product containing the bionic phospholipid has the advantages that the mild degree of the formula is greatly improved due to the synergistic stimulation reducing effect of the bionic phospholipid, the stimulation of the surfactant to the skin of children is reduced, and the children hair cleaning product is suitable for long-term use by children.
Detailed Description
The present invention is further described below by way of specific examples, but the present invention is not limited to only the following examples. Variations, combinations, or substitutions of the invention, which are within the scope of the invention or the spirit, scope of the invention, will be apparent to those of skill in the art and are within the scope of the invention.
Example one
The children hair cleaning product containing the bionic phospholipid structure conditioner mainly comprises the following components in percentage by mass:
10 parts by mass of sodium laureth sulfate, 5 parts by mass of cocamidopropyl betaine, 3 parts by mass of C8-14 alkyl glucoside, 0.05 part by mass of guar hydroxypropyl trimethyl ammonium chloride, 1.5 parts by mass of ricinoleic acid amidopropyl trimethyl ammonium chloride, 0.5 part by mass of silicone emulsion, 0.5 part by mass of acrylic acid (ester) copolymer, 0.01 part by mass of sodium glucoheptonate, 0.05 part by mass of lactic acid, 0.3 part by mass of sodium benzoate, 0.05 part by mass of essence, 5 parts by mass of biomimetic phospholipid, and 74.04 parts by mass of deionized water.
Wherein the bionic phospholipid consists of coconut oil acid bionic phospholipid and linoleic acid bionic phospholipid, the proportion of the monoester, the diester and the triester is 10:80:10, namely, 0.5 part by mass of the monoester, 4 parts by mass of the diester and 0.5 part by mass of the triester in the added bionic phospholipid.
The preparation method of the children hair cleaning product containing the bionic phospholipid structure conditioner comprises the following steps:
(1) adding 74.04 parts by mass of deionized water into a stirring kettle, adding 0.01 part by mass of sodium glucoheptonate, 0.04 part by mass of lactic acid and 0.05 part by mass of guar hydroxypropyl trimethyl ammonium chloride, stirring until the sodium glucoheptonate, the lactic acid and the guar hydroxypropyl trimethyl ammonium chloride are completely dissolved, adding 10 parts by mass of sodium laureth sulfate, 5 parts by mass of cocamidopropyl betaine and 3 parts by mass of C8-14 alkyl glucoside, stirring uniformly, heating to 80 ℃, and keeping the temperature for 45 min;
(2) stirring and cooling, when the temperature is reduced to 55 ℃, adding 5 parts by mass of bionic phospholipid, and stirring uniformly;
(3) and (2) continuing stirring and cooling, when the temperature is reduced to 45 ℃, adding 0.5 part by mass of acrylic acid (ester) copolymer and 0.5 part by mass of emulsified silicone oil, adjusting the pH value by 0.01 part by mass of lactic acid, adding 0.05 part by mass of essence and 0.3 part by mass of sodium benzoate, standing and defoaming to obtain the children hair cleaning product I containing the bionic phospholipid structure conditioner.
Example two
The children hair cleaning product containing the bionic phospholipid structure conditioner mainly comprises the following components in percentage by mass:
12 parts by mass of sodium laureth sulfate, 4 parts by mass of cocamidopropyl betaine, 2.5 parts by mass of coco glucoside, 0.08 part by mass of guar hydroxypropyl trimethyl ammonium chloride, 1.2 parts by mass of ricinoleic acid amidopropyl trimethyl ammonium chloride, 0.4 part by mass of silicone emulsion, 0.8 part by mass of acrylic acid (ester) copolymer, 0.02 part by mass of disodium EDTA, 0.05 part by mass of citric acid, 0.3 part by mass of phenoxyethanol, 0.05 part by mass of essence, 5 parts by mass of biomimetic phospholipid, and 73.6 parts by mass of deionized water.
Wherein the bionic phospholipid consists of coconut oil acid bionic phospholipid and linoleic acid bionic phospholipid, the proportion of the monoester, the diester and the triester is 10:80:10, namely, 0.5 part by mass of the monoester, 4 parts by mass of the diester and 0.5 part by mass of the triester in the added bionic phospholipid.
The preparation method of the children hair cleaning product containing the bionic phospholipid structure conditioner comprises the following steps:
(1) adding 73.6 parts by mass of deionized water into a stirring kettle, adding 0.02 part by mass of disodium EDTA, 0.04 part by mass of citric acid and 0.08 part by mass of guar hydroxypropyl trimethyl ammonium chloride, stirring until the materials are completely dissolved, adding 12 parts by mass of sodium laureth sulfate, 4 parts by mass of cocamidopropyl betaine and 2.5 parts by mass of C8-14 alkyl glucoside, stirring uniformly, heating to 85 ℃, and keeping the temperature for 40 min;
(2) stirring and cooling, when the temperature is reduced to 55 ℃, adding 5 parts by mass of bionic phospholipid, and stirring uniformly;
(3) and (2) continuing stirring and cooling, when the temperature is reduced to 45 ℃, adding 0.8 part by mass of acrylic acid (ester) copolymer and 0.4 part by mass of emulsified silicone oil, adjusting the pH value by 0.01 part by mass of citric acid, adding 0.05 part by mass of essence and 0.3 part by mass of phenoxyethanol, standing and defoaming to obtain a children hair cleaning product II containing the bionic phospholipid structure conditioner.
EXAMPLE III
The children hair cleaning product containing the bionic phospholipid structure conditioner mainly comprises the following components in percentage by mass:
13 parts by mass of ammonium laureth sulfate, 3 parts by mass of lauramidopropyl betaine, 2 parts by mass of coco glucoside, 0.1 part by mass of polyquaternium-10, 1 part by mass of distearoyloxyethyl dimethyl ammonium chloride, 0.3 part by mass of silicone emulsion, 1 part by mass of acrylic acid (ester) copolymer, 0.03 part by mass of disodium EDTA, 0.08 part by mass of citric acid, 0.4 part by mass of phenoxyethanol, 0.1 part by mass of essence, 4 parts by mass of biomimetic phospholipid, and 74.99 parts by mass of deionized water.
Wherein the bionic phospholipid consists of lauric acid bionic phospholipid and oleic acid bionic phospholipid, the proportion of the monoester, the diester and the triester is 20:80:0, namely, 0.8 part by mass of the monoester and 3.2 parts by mass of the diester are added into the bionic phospholipid, and the bionic phospholipid does not contain triester.
The preparation method of the children hair cleaning product containing the bionic phospholipid structure conditioner comprises the following steps:
(1) adding 74.99 parts by mass of deionized water into a stirring kettle, adding 0.03 part by mass of EDTA disodium, 0.064 part by mass of citric acid and 0.1 part by mass of polyquaternium-10, stirring until the mixture is completely dissolved, adding 13 parts by mass of ammonium laureth sulfate, 3 parts by mass of lauramidopropyl betaine and 2 parts by mass of coco glucoside, stirring until the mixture is uniform, heating to 82 ℃, and keeping the temperature for 45 min;
(2) stirring and cooling, when the temperature is reduced to 50 ℃, adding 4 parts by mass of bionic phospholipid, and stirring uniformly;
(3) and (3) continuing stirring and cooling, when the temperature is reduced to 45 ℃, adding 1 part by mass of acrylic acid (ester) copolymer and 0.3 part by mass of emulsified silicone oil, adjusting the pH value by 0.016 part by mass of citric acid, adding 0.1 part by mass of essence and 0.4 part by mass of phenoxyethanol, standing and defoaming to obtain the children hair cleaning product III containing the bionic phospholipid structure conditioner.
Example four
The children hair cleaning product containing the bionic phospholipid structure conditioner mainly comprises the following components in percentage by mass:
14 parts by mass of potassium laureth phosphate, 3 parts by mass of lauramidopropyl betaine, 1.5 parts by mass of C8-14 alkyl glucoside, 0.15 part by mass of polyquaternium-10, 0.8 part by mass of distearoyloxyethyldimethylammonium chloride, 0.2 part by mass of silicone emulsion, 1.2 parts by mass of styrene/acrylic acid (ester) copolymer, 0.04 part by mass of sodium glucoheptonate, 0.1 part by mass of lactic acid, 0.4 part by mass of phenoxyethanol, 0.1 part by mass of essence, 4 parts by mass of bionic phospholipid, 74.51 parts by mass of deionized water
Wherein the bionic phospholipid consists of lauric acid bionic phospholipid and oleic acid bionic phospholipid, the proportion of the monoester, the diester and the triester is 20:80:10, namely, 0.8 part by mass of the monoester and 3.2 parts by mass of the diester are added into the bionic phospholipid, and the bionic phospholipid does not contain triester.
The preparation method of the children hair cleaning product containing the bionic phospholipid structure conditioner comprises the following steps:
(1) adding 74.51 parts by mass of deionized water into a stirring kettle, adding 0.04 part by mass of sodium glucoheptonate, 0.08 part by mass of lactic acid and 0.15 part by mass of polyquaternium-10, adding 14 parts by mass of potassium laureth phosphate, 3 parts by mass of lauramidopropyl betaine and 1.5 parts by mass of C8-14 alkyl glucoside, stirring uniformly, heating to 80 ℃, and keeping the temperature for 45 min;
(2) stirring and cooling, when the temperature is reduced to 53 ℃, adding 4 parts by mass of bionic phospholipid, and stirring uniformly;
(3) and (3) continuing stirring and cooling, when the temperature is reduced to 40 ℃, adding 1.2 parts by mass of styrene/acrylic acid (ester) copolymer and 02 parts by mass of emulsified silicone oil, adjusting the pH by 0.02 part by mass of lactic acid, adding 0.1 part by mass of essence and 0.4 part by mass of phenoxyethanol, standing and defoaming to obtain a children hair cleaning product IV containing the bionic phospholipid structure conditioner.
EXAMPLE five
The children hair cleaning product containing the bionic phospholipid structure conditioner mainly comprises the following components in percentage by mass:
15 parts by mass of potassium cocoyl hydrolyzed oat protein, 2 parts by mass of cocamidopropyl hydroxysultaine, 1.5 parts by mass of C12-18 alkyl glucoside, 0.18 part by mass of guar hydroxypropyl trimethyl ammonium chloride, 0.5 part by mass of dipalmitoyloxyethyl dimethyl ammonium chloride, 1.5 parts by mass of styrene/acrylic acid (ester) copolymer, 0.05 part by mass of sodium phytate, 0.12 part by mass of hydrochloric acid, 0.5 part by mass of sodium benzoate, 0.2 part by mass of essence, 3 parts by mass of bionic phospholipid, 75.45 parts by mass of deionized water
Wherein the bionic phospholipid consists of myristic acid bionic phospholipid and linolenic acid bionic phospholipid, the proportion of the monoester, the diester and the triester is 15:80:5, namely 0.45 part by mass of the monoester, 2.4 parts by mass of the diester and 0.15 part by mass of the triester in the added bionic phospholipid.
The preparation method of the children hair cleaning product containing the bionic phospholipid structure conditioner comprises the following steps:
(1) adding 75.45 parts by mass of deionized water into a stirring kettle, adding 0.05 part by mass of sodium phytate, 0.096 part by mass of hydrochloric acid and 0.18 part by mass of guar hydroxypropyl trimethyl ammonium chloride, stirring until completely dissolving, adding 15 parts by mass of potassium cocoyl hydrolyzed oat protein, 2 parts by mass of cocamidopropyl hydroxysultaine and 1.5 parts by mass of C12-18 alkyl glucoside, stirring uniformly, heating to 80 ℃, and keeping the temperature for 40 min;
(2) stirring and cooling, when the temperature is reduced to 55 ℃, adding 3 parts by mass of bionic phospholipid, and stirring uniformly;
(3) and (3) continuing stirring and cooling, when the temperature is reduced to 45 ℃, adding 1.5 parts by mass of styrene/acrylic acid (ester) copolymer, adjusting the pH value by using 0.024 parts by mass of hydrochloric acid, adding 0.2 part by mass of essence and 0.5 part by mass of sodium benzoate, standing and defoaming to obtain the children hair cleaning product V containing the bionic phospholipid structure conditioner.
EXAMPLE six
The children hair cleaning product containing the bionic phospholipid structure conditioner mainly comprises the following components in percentage by mass:
15 parts by mass of potassium cocoyl hydrolyzed oat protein, 3 parts by mass of cocamidopropyl hydroxysultaine, 1 part by mass of C12-18 alkyl glucoside, 0.2 part by mass of guar hydroxypropyl trimethyl ammonium chloride, 1 part by mass of dipalmitoyloxyethyl dimethyl ammonium chloride, 1.5 parts by mass of styrene/acrylic acid (ester) copolymer, 0.05 part by mass of sodium phytate, 0.15 part by mass of hydrochloric acid, 0.5 part by mass of sodium benzoate, 0.2 part by mass of essence, 3 parts by mass of bionic phospholipid, and 74.4 parts by mass of deionized water
Wherein the bionic phospholipid consists of myristic acid bionic phospholipid and linolenic acid bionic phospholipid, the proportion of the monoester, the diester and the triester is 15:80:5, namely 0.45 part by mass of the monoester, 2.4 parts by mass of the diester and 0.15 part by mass of the triester in the added bionic phospholipid.
The preparation method of the children hair cleaning product containing the bionic phospholipid structure conditioner comprises the following steps:
(1) adding 74.4 parts by mass of deionized water into a stirring kettle, adding 0.05 part by mass of sodium phytate, 0.12 part by mass of hydrochloric acid and 0.2 part by mass of guar hydroxypropyl trimethyl ammonium chloride, stirring until the sodium phytate, the hydrochloric acid and the guar hydroxypropyl trimethyl ammonium chloride are completely dissolved, adding 15 parts by mass of potassium cocoyl hydrolyzed oat protein, 3 parts by mass of cocamidopropyl hydroxysultaine and 1 part by mass of C12-18 alkyl glucoside, stirring uniformly, heating to 85 ℃, and preserving heat for 40 min;
(2) stirring and cooling, when the temperature is reduced to 55 ℃, adding 3 parts by mass of bionic phospholipid, and stirring uniformly;
(3) and (3) continuing stirring and cooling, when the temperature is reduced to 45 ℃, adding 1.5 parts by mass of styrene/acrylic acid (ester) copolymer, adjusting the pH value by using 0.03 part by mass of hydrochloric acid, adding 0.2 part by mass of essence and 0.5 part by mass of sodium benzoate, standing and defoaming to obtain a children hair cleaning product VI containing the bionic phospholipid structure conditioner.
Comparative example 1
In the formula of the second embodiment, the replacement bionic phospholipid is commercially available cocamidopropyl PG-dimethyl ammonium chloride phosphate, the monoester content of the replacement bionic phospholipid is 100%, and the replacement bionic phospholipid has no diester or triester structure;
comparative example No. two
In the formula of the second embodiment, the replacement bionic phospholipid is commercially available linoleamide propyl PG-dimethyl ammonium chloride phosphate, the monoester content of the replacement bionic phospholipid is 100%, and the replacement bionic phospholipid has no diester or triester structure;
comparative example No. three
In the formulation of example two, no biomimetic phospholipids were added.
Efficacy testing
First, evaluation of Mild Properties
1. Chick embryo chorioallantoic membrane test (HET-CAM)
Method reference: 1. SN/T2329-2009 cosmetic eye-irritating, caustic chick embryo chorioallantoic membrane test; 2. liu Caiyun, et al, chick embryo chorioallantoic membrane test study on eye stimulation intensity [ J ] of different shampoos, essence, perfume, cosmetics, 2016 (05) period.
The above examples 1-6, comparative examples 1-3 and commercial children hair cleaning products 1-3 were prepared into 1% solutions with deionized water, the reaction time method was adopted in the experiment, 9-day-old chick embryos were exposed to the chorioallantoic membrane, 0.3ml of the solution to be tested was respectively absorbed and dropped on the chorioallantoic membrane surface, the time to start bleeding, vascular thawing and clotting within 5min was recorded, video recording and photographing were carried out during the period, and each sample was subjected to 6 parallel tests. Setting a negative control group (0.9% NaCl solution) and a positive control group (10mg/ml SDS solution), and judging the standard according to the standard requirement.
1.1 Scoring criteria
The IS method was used as a scoring criterion IS ═ [ (301-secH) × 5]/300+ [ (301-secL) × 7]/300+ [ (301-secC) × 9 ]/300.
Wherein:
secH (bleeding time), the mean time(s) to onset of bleeding observed on the allantoic membrane;
secL (vascular melting time), the average time(s) to onset of vascular melting observed on the allantoic membrane;
secC (clotting time) is the average time(s) to the onset of clotting observed on the allantoic membrane.
| Stimulation scoring | Stimulus classification |
| IS＜1 | Has no irritation |
| 1≤IS＜5 | Light irritation |
| 5≤IS＜9 | Moderate irritation |
| IS≥9 | Severe irritation |
1.2 evaluation results
| Sample (I) | IS value | Stimulus classification |
| Example 1 | 2.96 | Light irritation |
| Example 2 | 3.25 | Light irritation |
| Example 3 | 3.90 | Light irritation |
| Example 4 | 4.08 | Light irritation |
| Example 5 | 4.82 | Light irritation |
| Example 6 | 4.47 | Light irritation |
| Comparative example 1 | 4.87 | Light irritation |
| Comparative example 2 | 4.66 | Light irritation |
| Comparative example 3 | 5.24 | Moderate irritation |
| Commercial children's hair cleansing product 1 | 6.95 | Moderate irritation |
| Commercial children's hair cleansing product 2 | 9.38 | Moderate irritation |
| Commercial children's hair cleansing product 3 | 7.80 | Moderate irritation |
2. Cytofluorescein leakage assay (FLT)
Reference documents: 1. CN201611167524.5 a method for evaluating eye irritation by using mouse kidney cell system, huanan cooperative innovation research institute; 2. yangyu et al, preliminary research on fluorescein leakage test in place of the whole rabbit eye irritation test [ J ], journal of Chinese health inspection, 3 months 2007).
2.1 Experimental procedures
The method for evaluating eye irritation by using a mouse renal cell system strictly follows CN201611167524.5 by using mouse renal cells as experimental materials.
2.2. Scoring criteria
FL20(mg/100ml) as the concentration of the test substance causing leakage of 20% fluorescein after exposure to the test substance, FL was obtained from 4 hours20H4The test substance can be divided into 3 irritation levels, wherein FL20H4>15mg/100ml is non-eye-irritating, 3mg/100ml<FL20H4<15mg/100ml for moderate stimulation, FL20H4<3mg/100ml is severe stimulation.
2.3 evaluation results
| Sample (I) | FL20H4(mg/100ml) | Stimulus classification |
| Example 1 | 13.18 | Moderate stimulation |
| Example 2 | 14.26 | Moderate stimulation |
| Example 3 | 12.87 | Moderate stimulation |
| Example 4 | 12.01 | Moderate stimulation |
| Example 5 | 13.35 | Moderate stimulation |
| Example 6 | 12.62 | Moderate stimulation |
| Comparative example 1 | 12.44 | Moderate stimulation |
| Comparative example 2 | 12.01 | Moderate stimulation |
| Comparative example 3 | 10.23 | Moderate stimulation |
| Commercial children's hair cleansing product 1 | 11.23 | Moderate stimulation |
| Commercial children's hair cleansing product 2 | 10.75 | Moderate stimulation |
| Commercial children's hair cleansing product 3 | 12.38 | Moderate stimulation |
Conclusion of the gentleness evaluation: both the chick embryo chorioallantoic membrane test (HET-CAM) and the cytofluorescein leakage test (FLT) belong to animal substitution experiments, and the experimental results of the chick embryo chorioallantoic membrane test and the cytofluorescein leakage test are related to the animal experimental results, but the conclusions are not completely identical, and the chick embryo chorioallantoic membrane test and the cytofluorescein leakage test have guiding significance. Based on the results of the parallel tests of the two alternative methods, we can find that the children hair cleaning products containing the bionic phospholipid in the examples have lower irritation than the children hair cleaning products without the bionic phospholipid, with the commercial bionic phospholipid and the commercial children hair cleaning products, which indicates that the bionic phospholipid has the capability of synergistically reducing irritation to the surfactant in the hair cleaning products.
Second, Dry, Wet combing Performance evaluation
Evaluation was performed with the multifunctional hair test system MTT 175.
Testing the hair bundle: the non-chemically treated real hair (Asian hair) is selected, and each bundle of hair has weight of about 10g and length of about 32 cm.
1. Test method
(1) Soaking hair bundles in 3% sodium laureth sulfate aqueous solution for 30min, cleaning, naturally drying at room temperature, and measuring dry hair combing force before use;
(2) soaking in clear water, kneading, rinsing, and measuring wet combing force before use;
(3) treating the test hair bundles with 1.5mL of samples to be tested respectively, washing the control hair bundles with clean water by the same method, and measuring the combing force of wet hair after treatment;
(4) after all hair strands are naturally aired under the same condition, measuring the combing force of the dried hair after treatment;
(5) during combing, each bundle was combed 5 times in parallel for each measurement time.
(6) When calculating, the combing total work result of each sample at the measuring time is the average value of the combing total work of the 3 parallel hair bundles at the time.
2. Test results of the carding machine
| Sample (I) | Delta wet combing work | Delta dry combing work |
| Example 1 | -0.03670 | -0.02227 |
| Example 2 | -0.04134 | -0.03233 |
| Example 3 | -0.03326 | -0.02478 |
| Example 4 | -0.03078 | -0.02591 |
| Example 5 | -0.03924 | -0.03624 |
| Example 6 | -0.03576 | -0.03754 |
| Comparative example 1 | -0.02127 | -0.01128 |
| Comparative example 2 | -0.02478 | -0.02054 |
| Comparative example 3 | -0.00960 | -0.01178 |
| Commercial children's hair cleansing product 1 | -0.01160 | -0.01789 |
| Commercial children's hair cleansing product 2 | -0.01927 | -0.01682 |
| Commercial children's hair cleansing product 3 | -0.02231 | -0.02168 |
Evaluation conclusion of dry and wet combing performance: the children hair cleaning product containing the bionic phospholipid prepared in the embodiment is remarkably improved in the aspects of dry and wet combing performance; the conditioning performance is better compared with the commercial bionic phospholipid and the commercial children hair cleaning products, because the bionic phospholipid diester used in the method has high content and better performance in the aspects of ester endowing and conditioning.
Third, sensory evaluation
The evaluation of volunteers was carried out in ten dimensions of spreadability, foaming speed, foam richness, foam fineness, wet flushing softness, wet flushing smoothness, wet flushing cleanliness, dry softness, dry gloss, and dry comfort, and a 7-point rating (1 very disliked, 2 disliked, 3 relatively disliked, 4 general, 5 relatively liked, 6 liked, and 7 very liked) was given to a commercial children's hair cleansing product 1 as a control basis, and 4 points were given to the basis, and the sensory properties of the examples, control examples, and commercial children's hair cleansing products were examined.
The results are as follows:
sensory evaluation results show that the children hair cleaning product containing the bionic phospholipid prepared in the examples is excellent in sensory evaluation, and the bionic phospholipid has obvious esterification and conditioning effects in the formula.
Fourth, example formulation stability test
Sensory testing: visually observing the properties of the product to see whether the product is abnormal or not;
heat resistance test: putting the sample into an electric heating constant temperature incubator at the temperature of (40 +/-1) DEG C for 24 hours, and observing whether phenomena such as thinning, discoloration, layering, hardness change and the like exist after the temperature is recovered to judge the heat resistance of the sample;
cold resistance test: putting the sample into a refrigerator at the temperature of minus 5 to minus 10 +/-1 ℃ for 24 hours, and observing whether phenomena such as thinning, color change, layering, hardness change and the like exist after the room temperature is recovered to judge the cold resistance of the sample;
and (3) centrifugal test: and (3) placing the sample in a centrifuge, testing for 30min at the rotating speed of (2000-4000) r/min, and observing the separation and delamination conditions of the sample.
The results are as follows:
according to the formula stability investigation result, the children hair cleaning product containing the bionic phospholipid prepared in the example has good stability, and the compatibility of the bionic phospholipid formula is good under the recommended dosage addition, so that the stability of the formula system is not influenced.
The above embodiments are preferred embodiments of the present invention, but the present invention is not limited to the above embodiments, and any other changes, modifications, substitutions, combinations, and simplifications which do not depart from the spirit and principle of the present invention should be construed as equivalents thereof, and all such changes, modifications, substitutions, combinations, and simplifications are intended to be included in the scope of the present invention.
Claims (10)
1. A children hair cleaning product containing a bionic phospholipid structure conditioner is characterized by comprising the following components: 10-15 parts by mass of an anionic surfactant, 2-5 parts by mass of a zwitterionic surfactant, 1-3 parts by mass of a nonionic surfactant, 0.05-0.2 part by mass of a high-molecular polymer cation conditioner, 1-2 parts by mass of a small-molecular cation conditioner, 0-0.5 part by mass of emulsified silicone oil, 0.5-1.5 parts by mass of a thickening agent, 0.01-0.05 part by mass of a chelating agent, 0.05-0.1 part by mass of a pH regulator, 0.1-0.3 part by mass of a preservative, 0.05-0.2 part by mass of essence, 3-5 parts by mass of bionic phospholipid and the balance of deionized water.
2. A children's hair cleansing product containing biomimetic phospholipid structure conditioning agent according to claim 1, characterized in that: the anionic surfactant is preferably sulfate salt, such as sodium laureth sulfate, ammonium laureth sulfate, MEA salt, MIPA salt, TEA salt, TIPA salt; or phosphate salts, such as potassium lauryl phosphate, sodium lauryl phosphate, potassium laureth phosphate, sodium lauryl phosphate, potassium C12-13 phosphate; or amino acid salts such as sodium lauroyl sarcosinate, potassium cocoyl glycinate, sodium lauroyl glutamate, sodium cocoyl glutamate, potassium cocoyl glutamate, disodium cocoyl glutamate, TEA cocoyl glutamate, sodium lauroyl alanine, sodium cocoyl alanine, sodium lauroyl methyl taurate, sodium cocoyl methyl taurate; or N-fatty acyl hydrolyzed protein salts, such as one or more of potassium cocoyl hydrolyzed oat protein, sodium cocoyl hydrolyzed wheat protein, potassium cocoyl hydrolyzed soy protein, sodium cocoyl hydrolyzed soy protein, TEA cocoyl hydrolyzed collagen, potassium palmitoyl hydrolyzed wheat protein, potassium lauroyl hydrolyzed soy protein, TEA lauroyl hydrolyzed collagen, potassium lauroyl hydrolyzed collagen, and sodium lauroyl hydrolyzed collagen.
3. A children's hair cleansing product containing biomimetic phospholipid structure conditioning agent according to claim 1, characterized in that: the zwitterionic surfactant is preferably of the betaine type, more preferably caprylyl/capramidopropyl betaine, cocobetaine, cocamidopropyl betaine, lauramidopropyl betaine, myristyl betaine, myristamamidopropyl betaine, palmamidopropyl betaine, oleamidopropyl betaine, erucamidopropyl hydroxysultaine, behenyl betaine, one or at least two of isostearamidopropyl betaine, cocoacylamino/oleamidopropyl betaine, lauramidopropyl hydroxysultaine, cocoamidopropyl hydroxysultaine, cocoacylamino/oleamidopropyl betaine, oleyl betaine, oleamidopropyl betaine, babassu oleamidopropyl betaine, soybean oleamidopropyl betaine, shea butter amidopropyl betaine, wheat germ oleamidopropyl betaine and undecenamidopropyl betaine.
4. A children's hair cleansing product containing biomimetic phospholipid structure conditioning agent according to claim 1, characterized in that: the nonionic surfactant is preferably an alkyl glycoside, more preferably one or at least two of lauryl glucoside, coco glucoside, myristyl glucoside, octyl/decyl glucoside, C12-18 alkyl glucoside, C12-20 alkyl glucoside, C8-14 alkyl glucoside, and xylitol-based glucoside.
5. A children's hair cleansing product containing biomimetic phospholipid structure conditioning agent according to claim 1, characterized in that: the high molecular polymer cation conditioner is preferably one or at least two of polyquaternium-10, guar gum hydroxypropyl trimethyl ammonium chloride, locust bean gum hydroxypropyl trimethyl ammonium chloride, tara hydroxypropyl trimethyl ammonium chloride, cassia gum hydroxypropyl trimethyl ammonium chloride, hydrogenated starch hydrolysate hydroxypropyl trimethyl ammonium chloride and glucan hydroxypropyl trimethyl ammonium chloride; the small-molecular cationic conditioner is preferably one or at least two of distearoyloxyethyldimethylammonium chloride, dipalmitoyloxyethyldimethylammonium chloride and ricinoleic acid amidopropyl trimethylammonium chloride.
6. A children's hair cleansing product containing biomimetic phospholipid structure conditioning agent according to claim 1, characterized in that: the emulsified silicone oil is preferably emulsified silicone oil with a nonionic surfactant or an anionic surfactant, and the obtained silicone oil emulsion is, for example, polydimethylsiloxane with emulsifying viscosity of 30-150 kilo-centipoise by using C12-14 alkanol polyether-3, C12-14 alkanol polyether-5, C12-14 alkanol polyether-7, C12-14 alkanol polyether-9, sodium lauryl polyether sulfate and ammonium lauryl polyether sulfate as emulsifying agents, and is preferably polydimethylsiloxane with emulsifying viscosity of 50 kilo-centipoise by using ammonium lauryl polyether sulfate.
7. A children's hair cleansing product containing biomimetic phospholipid structure conditioning agent according to claim 1, characterized in that: the thickening agent is preferably one or at least two of acrylic acid (ester) copolymer, styrene/acrylic acid (ester) copolymer, carbomer TEA salt, carbomer sodium and carbomer potassium; the chelating agent is preferably one or at least two of phytic acid, sodium phytate, EDTA disodium, EDTA tetrasodium, sodium glucoheptonate, etidronic acid and sodium citrate; the pH regulator is preferably one or at least two of lactic acid, phosphoric acid, citric acid, hydrochloric acid, glycolic acid, propionic acid and fruit acid; the preservative is preferably one or at least two of phenoxyethanol, 1, 2-hexanediol, 1, 2-pentanediol, sodium benzoate, sodium lactate, p-anisic acid and glyceryl caprylate; the essence is commercially available cosmetic grade essence.
8. A children's hair cleansing product containing biomimetic phospholipid structure conditioning agent according to claim 1, characterized in that: the bionic phospholipid structure conditioner has the following structure:
9. a children's hair cleansing product containing biomimetic phospholipid structure conditioning agent according to claim 9, characterized in that: the R group carboxyl structure preferably consists of a C12-C16 saturated alkyl chain structure and a C18 unsaturated alkyl chain structure, and the mass ratio of the two is 1: 1; the C12-C16 saturated alkyl chain structure comprises one or at least two of a lauric acid structure, a coconut oil acid structure, a myristic acid structure and a palmitic acid structure, and when the number of the saturated alkyl chain structures is two or more, the mass ratio of the components is the same; the C18 unsaturated alkyl chain structure comprises one or at least two of an oleic acid structure, a linoleic acid structure and a linolenic acid structure, and when the number of the structures is two or more, the mass ratio of the components is the same; in the bionic phospholipid structure, when x is 1, y is 2, z is 1, and the bionic phospholipid structure is a phosphate monoester structure; when x is 2, y is 1, z is 2, and the structure is phosphoric acid diester; when x is 3, y is 0, z is 3, a phosphotriester structure; in the bionic phospholipid structure, the proportion of monoester to diester to triester is (10-20) to (70-90) to (0-10); in the bionic phospholipid structure, the proportion of the monoester, the diester and the triester can be obtained by adjusting a synthesis process.
10. The method for manufacturing the children hair cleansing product containing the bionic phospholipid structure conditioning agent according to claim 1 is characterized by comprising the following steps:
(1) adding a certain amount of deionized water into a stirring kettle, adding a chelating agent, 80% by mass of a pH regulator and a high molecular polymer cation conditioner, stirring until the chelating agent, the pH regulator and the high molecular polymer cation conditioner are completely dissolved, adding an anionic surfactant, a zwitterionic surfactant and a nonionic surfactant, stirring until the mixture is uniform, heating to 80-85 ℃, and preserving heat for 30-45 min;
(2) stirring and cooling, adding a small molecular cation conditioner and bionic phospholipid when the temperature is reduced to 55-60 ℃, and stirring uniformly;
(3) and (3) continuing stirring and cooling, adding the thickening agent and the emulsified silicone oil when the temperature is reduced to 45-55 ℃, adjusting the pH by using the rest 20% of the pH adjusting agent in parts by mass, finally adding the essence and the preservative, standing and defoaming to obtain the children hair cleaning product containing the bionic phospholipid structure conditioning agent.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112851706A (en) * | 2020-12-31 | 2021-05-28 | 广州增城潮徽生物技术有限公司 | Oil-based bionic phospholipid, preparation method and application thereof in personal cleaning products |
| CN112932991A (en) * | 2020-12-31 | 2021-06-11 | 广州增城潮徽生物技术有限公司 | Phospholipid composition, preparation method thereof and scalp care solution containing same |
| CN113730298A (en) * | 2021-07-26 | 2021-12-03 | 广东卡迪娜实业有限公司 | Silicon-free shampoo conditioning composition containing biomimetic phospholipids |
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Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102525832A (en) * | 2010-11-15 | 2012-07-04 | 强生消费者公司 | Polyglyceryl compounds and compositions |
| CN102552063A (en) * | 2010-12-21 | 2012-07-11 | 强生消费者公司 | Compositions comprising polyglyceryl nonionic surfactants |
| CN107281048A (en) * | 2017-08-10 | 2017-10-24 | 佛山市润欣洗涤用品有限公司 | One kind is without silicone oil herbal treatment shampoo and preparation method thereof |
| CN109172480A (en) * | 2018-10-23 | 2019-01-11 | 南通季德胜科技有限公司 | A kind of antipruritic leaves shampoo of anti-mite and preparation process |
| US20190216698A1 (en) * | 2018-01-18 | 2019-07-18 | Nohbo, LLC | Hygiene product pod and methods of using same |
| CN110123663A (en) * | 2019-05-16 | 2019-08-16 | 菏泽龙池生物科技有限公司 | A kind of shampoo and preparation method thereof cleaning scalp grease |
| CN110368329A (en) * | 2019-08-22 | 2019-10-25 | 广州亦妆生物科技有限公司 | A kind of homogeneous care composition of not silicate-containing oil |
| CN111407697A (en) * | 2020-04-14 | 2020-07-14 | 广东润洁日化有限公司 | Group of anti-dandruff compositions |
-
2020
- 2020-09-11 CN CN202010951506.6A patent/CN112076108A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102525832A (en) * | 2010-11-15 | 2012-07-04 | 强生消费者公司 | Polyglyceryl compounds and compositions |
| CN102552063A (en) * | 2010-12-21 | 2012-07-11 | 强生消费者公司 | Compositions comprising polyglyceryl nonionic surfactants |
| CN107281048A (en) * | 2017-08-10 | 2017-10-24 | 佛山市润欣洗涤用品有限公司 | One kind is without silicone oil herbal treatment shampoo and preparation method thereof |
| US20190216698A1 (en) * | 2018-01-18 | 2019-07-18 | Nohbo, LLC | Hygiene product pod and methods of using same |
| CN109172480A (en) * | 2018-10-23 | 2019-01-11 | 南通季德胜科技有限公司 | A kind of antipruritic leaves shampoo of anti-mite and preparation process |
| CN110123663A (en) * | 2019-05-16 | 2019-08-16 | 菏泽龙池生物科技有限公司 | A kind of shampoo and preparation method thereof cleaning scalp grease |
| CN110368329A (en) * | 2019-08-22 | 2019-10-25 | 广州亦妆生物科技有限公司 | A kind of homogeneous care composition of not silicate-containing oil |
| CN111407697A (en) * | 2020-04-14 | 2020-07-14 | 广东润洁日化有限公司 | Group of anti-dandruff compositions |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112851706A (en) * | 2020-12-31 | 2021-05-28 | 广州增城潮徽生物技术有限公司 | Oil-based bionic phospholipid, preparation method and application thereof in personal cleaning products |
| CN112932991A (en) * | 2020-12-31 | 2021-06-11 | 广州增城潮徽生物技术有限公司 | Phospholipid composition, preparation method thereof and scalp care solution containing same |
| CN112851706B (en) * | 2020-12-31 | 2024-04-26 | 广州增城潮徽生物技术有限公司 | Grease-based bionic phospholipid, preparation method and application thereof in personal cleaning products |
| CN113730298A (en) * | 2021-07-26 | 2021-12-03 | 广东卡迪娜实业有限公司 | Silicon-free shampoo conditioning composition containing biomimetic phospholipids |
| CN114177122A (en) * | 2021-12-22 | 2022-03-15 | 福建省梦娇兰日用化学品有限公司 | Mild and comfortable children shampoo shower gel and preparation method thereof |
| CN114796018A (en) * | 2022-05-12 | 2022-07-29 | 苏州绿叶日用品有限公司 | Silicon-free shampoo and preparation method thereof |
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Application publication date: 20201215 |