CN107349117A - A kind of compound amino acid composition and without silicone oil conditioner shampoo - Google Patents
A kind of compound amino acid composition and without silicone oil conditioner shampoo Download PDFInfo
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- CN107349117A CN107349117A CN201710451395.0A CN201710451395A CN107349117A CN 107349117 A CN107349117 A CN 107349117A CN 201710451395 A CN201710451395 A CN 201710451395A CN 107349117 A CN107349117 A CN 107349117A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
- A61K8/4913—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having five membered rings, e.g. pyrrolidone carboxylic acid
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/34—Free of silicones
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
Abstract
The invention discloses a kind of compound amino acid and add this compound amino acid without silicon conditioner shampoo.It is proposed that one kind using compound amino acid as conditioner, reduces the new shampoo of cationic polymer addition, reach a kind of high conditioning, do not return oil, deposit low effect, be adapted to long term consumer to use.The compound amino acid is made up of the composition of following percentage by weight：L serines 0.1% ~ 5%, L glycine 0.2% ~ 3%, L alanine 1% ~ 5%, L aspartic acids 0.1% ~ 5%, L valines 0.1% ~ 5%, L arginine 1% ~ 2%, L isoleucines 0.3% ~ 1%, L leucines 0.1% ~ 2%, L glutamic acid 0. 1% ~ 1%, L proline 1% ~ 3%, sodium lactate 0.5% ~ 10%, citric acid 0.2% ~ 0.5%, 1,3 butanediol 20%`30%, glycerine 1% ~ 5%, surplus are water;Described no its component of silicon conditioner shampoo and content are：10% 30% surfactant, 0.1% 3% compound amino acid, 0.05% 1% cation opsonizing agent, 0.01 0.5% essence, 0.1 0.5% preservative, 0.01 1% PH conditioning agents, surplus is water.
Description
Technical field
The invention belongs to daily cosmetics technical field, in particular it relates to a kind of compound amino acid composition and compound ammonia
Base acid is without silicone oil conditioner shampoo.
Background technology
Silicone oil shampoo is to use silicone oil（Dimethyl silicone polymer class）For the shampoo of main conditioner, due to silicone oil have it is excellent
Different conditioning performance, hair scale piece can be filled up after contacting hair, make the sensation that hair is smooth, therefore be widely used in shampoo
In.But silicone oil this material itself is not soluble in water, there is chemical inertness, it is long-term use of, easily cause hair follicle blocking, scalp
Itch, or even alopecia." no silicone oil " scalp care buds out into popularity abroad already as a kind of life style of health.
In Japan, 59% people receives no silicone oil scalp care idea；In America and Europe, this numeral has reached 63%；Make without silicone oil shampoo
For the new concept of Chinese personal nursing in recent years, pursued at home by increasing consumer.Adjusted without silicone oil shampoo
There is certain limitation in terms of rationality, cationic polymer addition is big, easily causes deposition.The present invention proposes one kind with compound ammonia
Base acid is conditioner, reduces the new shampoo of cationic polymer addition, reaches a kind of high conditioning, does not return oil, low deposition.
The content of the invention
The first object of the present invention is to provide a kind of compound amino acid composition, and said composition has hair conditioning to hair
Energy.
Another object of the present invention is to provide a kind of above-mentioned compound amino acid composition preparation method.
It is still another object of the present invention to provide containing above-mentioned compound amino acid composition without silicone oil conditioner shampoo and system
Preparation Method.Overcome the deficiencies in the prior art, solve the limitation of existing no silicone oil shampoo, reduce the addition of cationic polymer
Amount, reach and do not deposit clearly, high hair conditioning, do not return after oily effect.
The present invention is in order to realize above-mentioned first purpose, and present invention employs following technical scheme：A kind of compound amino acid group
Compound, it is characterised in that be made up of each component of following percentage by weight：Serine 0.1% ~ 5%, L- glycine 0.2% ~ 3%,
ALANINE 1% ~ 5%, L-Aspartic acid 0.1% ~ 5%, Valine 0.1% ~ 5%, L-arginine 1% ~ 2%, ILE 0.3% ~
1%th, L-Leu 0.1% ~ 2%, Pidolidone 0. 1% ~ 1%, L-PROLINE 1% ~ 3%, sodium lactate 0.5% ~ 10%, citric acid 0.2% ~
0.5%, 1,3-BDO 20%`30%, glycerine 1% ~ 5%, surplus are water.
The present invention is of the invention in order to realize that it is a kind of using above-mentioned compound amino acid composition preparation method that above-mentioned another object provides
Employ following technical scheme：
Preparation method：Sodium lactate, L-arginine, water are added main emulsification pot by S1, and stirring and dissolving will be water-soluble with appropriate citric acid
Liquid pH value is adjusted to 9.5-11.0, and is heated to 40-50 DEG C；Between 40-50 DEG C of S2 constant temperature, it is different bright to sequentially add Pidolidone, L-
Propylhomoserin, L-Leu, Serine, L- glycine, ALANINE, L-Aspartic acid, Valine, L-PROLINE are fast, and speed is stirred
After mixing dissolving, continue constant temperature stirring 30min；Solution pH value is adjusted to 5.5-6.5 by S3 with appropriate citric acid, add butanediol and
Glycerine, stir, filter to obtain micro- transparent amino acid composition of Huang.
The present invention uses to realize that above-mentioned a further object provides a kind of compound amino acid without silicone oil conditioner shampoo, the present invention
Following technical scheme：Characterized in that, it is made up of each component of following percentage by weight：
10%-30% surfactant；
0.1%-3% compound amino acid；
0.05%-1% cation opsonizing agent；
0.01-0.5 essence；
0.1-0.5% preservative；
0.01-1% PH conditioning agents；
Surplus is water.
The surfactant is nonionic surfactant, unethoxylated anion surfactant and amino acid
The one or more of surfactant.
Preferably, described nonionic surfactant is C8-C14 APGs, C8-C14 APGs have table
Face tension force is low, and foaming abundancy is stable, the premium properties such as soil release performance, compatibility are strong；The surfactant of APG class is for example commercially available
APG100, APG200, APG301, be LG the trade mark；APG100：It is 8 to 10 that a kind of APG, wherein alkyl, which include carbochain,
Scope, characteristic：Low carbon chain, surface tension is high, and foaming is fast, foam highest, washes and washes one's hair the most refreshing sense of foam；Low carbon chain, infiltration, profit
Wet performance is good；APG200：A kind of APG, wherein alkyl include the scope that carbochain is 12 to 14, and thickening properties are good, surface
Power is low, and foam is closely knit, washes and washes one's hair the slight film sense of tool；14 high carbon chains, emulsifiability is good, and fouling performance is removed with stronger；APG301
A kind of APG, wherein alkyl include the scope that carbochain is 8 to 14, characteristic：Average carbon chain number is 11.5 ± 0.1, average poly-
Right is 1.4, and thickening properties are good, will not viscosity reduction, beneficial to thicken other table live body systems；Surface tension is placed in the middle, and foam height occupies
In；C8, C14 APG degreasing power are weaker, most gently, can prepare the homogeneous product of clear easily in each system.
Preferably, the unethoxylated anion surfactant is sodium alkyl benzene sulfonate, and alkylsulfonate, alkene
Sulfonated hydrocarbon, fatty acid hydroxyl group acetate, acyl glutamate, alkyl phosphate, one kind in fatty alcohol sulfosuccinate ester
Or it is a variety of, the preferred ammonium lauryl sulfate of the present invention, strengthen foamed elastic and foam stability, there is cooperative effect to foaming properties,
The excitant that traditional table is lived is reduced simultaneously, makes product gentleer.
Preferably, the amino acid surfactant is that sodium cocoyl glycinate, cocounut oil acyl glycine potassium, lauroyl are sweet
One or more in propylhomoserin sodium, lauroyl glycine potassium, myristoyl glycine sodium.Preferably cocounut oil acyl glycine of the invention
Sodium, sodium cocoyl glycinate rinse soon, and skin sense is good, easily generate smooth and rich springy foam, are slided using back cutaneous sense
It is refreshing.
Preferably, described cation opsonizing agent is one in polyquaternium -5, polyquaternium -7, Polyquaternium-10
Kind is a variety of.The preferred Polyquaternium-10 of the present invention, Polyquaternium-10 has the characteristics of high hair conditioning, low deposition, is a tool
There is the cationic cellulose polymer of superior water solubility and adsorption capacity, with anion, cation, nonionic and amphion
Surfactant has a good compatibility, and excitant is low；The unique cationic properties of Polyquaternium-10 can repair impaired hair
Protein matrix, keep hair to moisten, assign the superior carding property of hair and glossy smooth sensation；The water of Polyquaternium-10
Solution can rapidly diffuse into skin keratin layer surface and form gas permeability, prosthetic protective film without excess accumulation.As
Macromolecule cation conditioner, compatibility is good, also has good thickening power to shampoo.
Preferably, described preservative is one kind in methyl hydroxybenzoate, Nipasol, imidazolidinyl urea, Phenoxyethanol
Or several, the preferred Phenoxyethanol of the present invention.
Preferably, described PH conditioning agents are citric acid, sodium citrate, potassium hydroxide, sodium hydroxide, lactic acid, lactic acid
One or several kinds in sodium, optimization citric acid of the present invention.
Compared with prior art, the present invention has the advantages that：
Compound amino acid of the present invention, it is the inspiration obtained by human hair and skin texture.Hair it is main into
It is keratin to divide, and is made up of each amino acid, the damage of keratin, hair can be caused short-tempered, dry, matt；Human body skin
Cuticula in a kind of material with water retention be present, its main component is also amino acid, primarily serve keep skin water
Profit health, prevents skin from becoming dry, sensitive effect.By designing a amino acid complex, have with hair and scalp
Compatibility, as conditioner, apply in without silicon conditioner shampoo, no sedimentary effect, and there is the effect of moisturizing, it is clear using sensation
Refreshing non-greasy.Compound amino acid of the present invention is the APG with C8 ~ C14 without silicon conditioner shampoo, dodecyl sulphate
Ammonium, sodium cocoyl glycinate are mixed surfactant, and compound amino acid and a small amount of cation Polyquaternium-10 are conditioner,
Whole system is without using silicone oil, and using a small amount of cation opsonizing agent to reduce deposition, while it is " multiple to add raw material newly developed
Close amino acid " conditioner is used as, reach a kind of high conditioning, do not return oil, the effect of low deposition, be adapted to long term consumer to use.
Brief description of the drawings
Fig. 1 is embodiment 4-7 and the wet comb property test result figure of the hair of commercial shampoos；
Fig. 2 is embodiment 4-7 and the dry comb property test result figure of the hair of commercial shampoos.
Embodiment
The present invention is made with reference to specific embodiment and further being elaborated, these embodiments are only given
For illustrative purposes, limitation of the invention can not be interpreted as, only for reference and explanation uses, and does not form special to the present invention
The limitation of sharp protection domain.The present invention is made with reference to specific embodiment and further being elaborated.
Embodiment 1
A kind of compound amino acid composition, count by weight percentage, its raw material composition and content are as follows：Serine 1.5%,
L- glycine 1.0%, ALANINE 2.5%, L-Aspartic acid 3.0%, Valine 2.5%, L-arginine 1.2%, ILE
0.6%th, L-Leu 01.5%, Pidolidone 0.4%, L-PROLINE 1.8%, sodium lactate 7.0%, citric acid 0.25%, 1,3- fourths two
Alcohol 23.0%, glycerine 4.0%, surplus are water.
The preparation method and technology of above-mentioned compound amino acid composition is as follows：
Sodium lactate, L-arginine, water are added main emulsification pot by S1, stirring and dissolving, are adjusted aqueous ph value with a small amount of citric acid
To 10, and it is heated to 45 DEG C；45 DEG C of S2 constant temperature, add Pidolidone, ILE, L-Leu, L- silks one by one in order
After propylhomoserin, L- glycine, ALANINE, L-Aspartic acid, Valine, the quick stirring and dissolving of L-PROLINE, continue constant temperature and stir
Mix 30min；Solution pH value is adjusted 6.0 by S3 with appropriate citric acid, adds butanediol and glycerine, stirring and dissolving, centrifugal filtration obtain
Micro- transparent compound amino acid composition of Huang.
Embodiment 2
A kind of compound amino acid composition, count by weight percentage, its raw material composition and content are as follows：Serine 1.0%,
L- glycine 1.5%, ALANINE 1.3%, L-Aspartic acid 1.8%, Valine 1.2%, L-arginine 1.4%, ILE
0.4%th, L-Leu 1.1%, Pidolidone 0.6%, L-PROLINE 1.9%, sodium lactate 6.5%, citric acid 0.25%, 1,3-BDO
15%, glycerine 1.5%, surplus is water.
The preparation method and technology of above-mentioned compound amino acid composition is as follows：
Sodium lactate, L-arginine, water are added main emulsification pot by S1, stirring and dissolving, are adjusted to aqueous ph value with a small amount of citric acid
10.5, and it is heated to 48 DEG C；48 DEG C of S2 constant temperature, add Pidolidone, ILE, L-Leu, L- silks one by one in order
After propylhomoserin, L- glycine, ALANINE, L-Aspartic acid, Valine, the quick stirring and dissolving of L-PROLINE, continue constant temperature and stir
Mix 30min；Solution pH value is adjusted 6.2 by S3 with appropriate citric acid, adds butanediol and glycerine, stirring and dissolving, centrifugal filtration obtain
Micro- transparent compound amino acid composition of Huang.
Embodiment 3
A kind of compound amino acid composition, count by weight percentage, its raw material composition and content are as follows：Serine 4.5%,
L- glycine 2.4%, ALANINE 3.8%, L-Aspartic acid 2.9%, Valine 4.1%, L-arginine 1.4%, ILE
0.8%th, L-Leu 1.6%, Pidolidone 0.6%, L-PROLINE 2.4%, sodium lactate 6.5%, citric acid 0.3%, 1,3-BDO
23%, glycerine 1.9%, surplus is water.
The preparation method and technology of above-mentioned compound amino acid is as follows：
Sodium lactate, L-arginine, water are added main emulsification pot by S1, stirring and dissolving, are adjusted to aqueous ph value with a small amount of citric acid
9.8, and it is heated to 43 DEG C；43 DEG C of S2 constant temperature, add Pidolidone, ILE, L-Leu, L- silks one by one in order
After propylhomoserin, L- glycine, ALANINE, L-Aspartic acid, Valine, the quick stirring and dissolving of L-PROLINE, continue constant temperature and stir
Mix 30min；S3, by between solution pH value adjustment 5.6, is added butanediol and glycerine, stirring and dissolving, centrifuged with appropriate citric acid
Filter to obtain micro- transparent compound amino acid composition of Huang.
Comparative example 1
A kind of compound amino acid composition, count by weight percentage, its raw material composition and content are as follows：Serine 4.5%,
L- glycine 2.4%, ALANINE 3.8%, L-Aspartic acid 2.9%, Valine 4.1%, L-arginine 1.4%, ILE
0.8%th, L-Leu 1.6%, Pidolidone 0.6%, L-PROLINE 2.4%, sodium lactate 6.5%, citric acid 0.3%, 1,3-BDO
23%, glycerine 1.9%, surplus is water.
The preparation method and technology of above-mentioned compound amino acid composition is as follows：
Sodium lactate, L-arginine, water are added main emulsification pot by S1, stirring and dissolving, are adjusted to aqueous ph value with a small amount of citric acid
11.5, and it is heated to 70 DEG C；70 DEG C of S2 constant temperature, add Pidolidone, ILE, L-Leu, L- silks one by one in order
After propylhomoserin, L- glycine, ALANINE, L-Aspartic acid, Valine, the quick stirring and dissolving of L-PROLINE, continue constant temperature and stir
Mix 10min；S3, by between solution pH value adjustment 5.0, is added butanediol and glycerine, stirring and dissolving, centrifuged with appropriate citric acid
Filter to obtain micro- transparent compound amino acid composition of Huang.
Comparative example 2
A kind of compound amino acid composition, count by weight percentage, its raw material composition and content are as follows：Serine 8.0%,
L- glycine 4.5%, L-Aspartic acid 7.1%, Valine 5.5%, L-arginine 0.2%, ILE 0.1%, L-Leu
3.5%th, L-PROLINE 0.7%, sodium lactate 14%, citric acid 1.0%, glycerine 16%, surplus are water.
The preparation method and technology of above-mentioned compound amino acid is as follows：
Sodium lactate, L-arginine, water are added main emulsification pot by S1, stirring and dissolving, are adjusted aqueous ph value with a small amount of citric acid
To 10, and it is heated to 45 DEG C；45 DEG C of S2 constant temperature, add Pidolidone, ILE, L-Leu, L- silks one by one in order
After propylhomoserin, L- glycine, ALANINE, L-Aspartic acid, Valine, the quick stirring and dissolving of L-PROLINE, continue constant temperature and stir
Mix 30min；Solution pH value is adjusted 6.0 by S3 with appropriate citric acid, adds butanediol and glycerine, stirring and dissolving, centrifugal filtration obtain
Micro- transparent compound amino acid composition of Huang.
Comparative example 3
A kind of compound amino acid composition, count by weight percentage, its raw material composition and content are as follows：Serine 8.0%,
L- glycine 4.5%, ALANINE 6.3%, L-Aspartic acid 7.1%, Valine 5.5%, L-arginine 0.2%, ILE
0.1%th, L-Leu 3.5%, Pidolidone 2.3%, L-PROLINE 0.7%, sodium lactate 14%, citric acid 1.0%, 1,3-BDO
8%, glycerine 16%, surplus is water.
The preparation method and technology of above-mentioned compound amino acid composition is as follows：
Sodium lactate, L-arginine, water are added main emulsification pot by S1, stirring and dissolving, are adjusted to aqueous ph value with a small amount of citric acid
10, and it is heated to 45 DEG C；45 DEG C of S2 constant temperature, add Pidolidone, ILE, L-Leu, L- silk ammonia one by one in order
After acid, L- glycine, ALANINE, L-Aspartic acid, Valine, the quick stirring and dissolving of L-PROLINE, continue constant temperature stirring
30min；Solution pH value is adjusted 6.0 by S3 with appropriate citric acid, adds butanediol and glycerine, stirring and dissolving, centrifugal filtration obtain micro-
Yellow transparent compound amino acid composition.
Embodiment 4-7
A kind of compound amino acid is without silicone oil conditioner shampoo, and count by weight percentage, its raw material composition and content are as follows：
The compound amino acid of table 1 forms without silicone oil conditioner shampoo formula
The preparation method of a kind of compound amino acid without silicone oil conditioner shampoo comprises the following steps：S1 is by corresponding main cooker and behaviour
Make instrument, container etc. to clean up and sterilize standby；Ammonium lauryl sulfate and appropriate water are added main cooker by S2, are risen under stirring
For temperature to 78 DEG C, stirring homogenous disperse is uniform；S3 stirrings are lower to add the finely dispersed Polyquaternium-10 aqueous solution, and homogenous disperse is equal
It is even, 15min is incubated, and defoam；S4 is cooled to less than 45 DEG C, and C8 ~ C14 APGs, the sweet ammonia of cocounut oil acyl are sequentially added under stirring
Sour sodium, appropriate water is supplemented, be dispersed with stirring uniformly；S5 adds compound amino acid composition, is dispersed with stirring uniformly；Add suitable
Preservative, the essence of amount；S6 adds citric acid, adjusts to suitable pH value；Cross 120 mesh filter clothes after S7 PH are qualified to take the dish out of the pot, with clear
The wash clean and container disinfected is held, wait defoam complete and micro- inspection it is qualified after it is filling.
Embodiment 8
Compound amino acid composition and compound amino acid prepared by embodiment 1 ~ 7 and comparative example 1 ~ 2 is without the steady of silicone oil conditioner shampoo
Qualitative detection, including heat resistant test, low temperature resistant test, centrifugal test, test result are shown in Table 2.
Heat resistant test：Sample is put into 24h in the electro-heating standing-temperature cultivator of (40 scholar 1) DEG C, seen whether after recovering room temperature
There is phenomena such as thinning, discoloration, layering and firmness change, with the heat resistance of judgement sample.
Low temperature resistant test：Sample is put into（- 5--10) 1 DEG C of DEG C scholar refrigerator in 24h, recover room temperature after seen whether
Phenomena such as thinning, discoloration, layering and firmness change, with the cold tolerance of judgement sample.
Centrifugal test：Sample is placed in a centrifuge, with (2000-4000) r/min speed test 30min, observes sample
The separation of product, layering situation.
The embodiment 1 ~ 7 of table 2 and comparative example 1 ~ 3 prepare the Detection of Stability of product
From the Detection of Stability knot of compound amino acid composition and compound amino acid without silicone oil conditioner shampoo described in the embodiment 8 of table 2
Fruit shows that compound amino acid composition of the invention and compound amino acid have good stability without silicone oil conditioner shampoo.
Embodiment 9
Hair setting performance test of the embodiment 4-7 compound amino acid without silicone oil conditioner shampoo and a commercial shampoos
Prepare some topknots of equal length (50cm) and weight (about 16g)：First, cleaned twice with 40 DEG C of running water, point
Wet comb performance and dry comb performance are not tested；3g is weighed respectively is tested shampoo Samples EXAMPLE 4-7 and commercial shampoos, rubbing to place
It is uniform to foam on topknot after reason, 5 minutes are stood, topknot is rinsed with running water, until non-foam, it is unnecessary to be combed with comb
Moisture, the wet comb performance of topknot after being handled on Dia-stron MTT175 tension testers, is drawn with 300mm/min speed
Stretch topknot, measure record numerical value；The dry comb performance of test：3g is weighed respectively is tested shampoo Samples EXAMPLE 4-7 and commercial shampoos,
Rubbing is uniform to foam on the topknot to after handling, and stands 5 minutes, and topknot is rinsed with running water, until non-foam, and dry,
The dry comb performance of topknot is determined on Dia-stron MTT175 tension testers, with 300mm/min speed tensile topknot,
Measure record numerical value；Test to reduce the measurement error brought because topknot is different, same topknot retest 3 times, make even
Average.
The wet comb performance inventory table of the hair of table 3
The dry comb performance inventory table of the hair of table 4
Show from Hair setting the performance test results of the compound amino acid without silicone oil conditioner shampoo described in table 3-4 embodiments 9, this hair
Bright compound amino acid is compared without silicone oil conditioner shampoo with commercial shampoos, there is good hair conditioning, and softness nourishes hair, hair
Carding property more preferably.
Embodiment 10
Compound amino acid described in embodiment 4-7 is estimated without silicone oil conditioner shampoo and commercial shampoos using effect valency, and appraisal procedure is such as
Under：50 testers are convened to carry out the compound amino acid described in embodiment 4-7 without silicone oil conditioner shampoo and commercial shampoos
Test, testing time are 2 weeks, a hair are cleaned every 1 day, according to the use feeling of tester, according to foam situation, wet comb
Sense, dry comb sense, wash after sense, it is dry after feel and is assessed, fraction divides with reference to 1-10, wherein 1 point is fraction minimum, 10 points are fraction
Peak, record assessment result.
The test man of table 5 tries out evaluation table
From described in the embodiment 10 of table 5, compound amino acid shows without silicone oil conditioner shampoo using effect evaluation result, contains the present invention
Compound amino acid is without silicone oil conditioner shampoo compared with commercial shampoos, and foaming characteristic is good, and use feeling is more excellent, and it is good to wash rear carding property
It is good.
With general explanation, embodiment and experiment in the present invention, the present invention is described in detail, but
On the basis of the present invention, it can be made some modifications or improvements, this will be apparent to those skilled in the art.Cause
This, these modifications or improvements, belong to the scope of protection of present invention without departing from theon the basis of the spirit of the present invention.
Claims (5)
1. a kind of compound amino acid composition, it is characterised in that be made up of each component of following percentage by weight：Serine
0.1% ~ 5%, L- glycine 0.2% ~ 3%, ALANINE 1% ~ 5%, L-Aspartic acid 0.1% ~ 5%, Valine 0.1% ~ 5%, L- essences
Propylhomoserin 1% ~ 2%, ILE 0.3% ~ 1%, L-Leu 0.1% ~ 2%, Pidolidone 0. 1% ~ 1%, L-PROLINE 1% ~ 3%, breast
Sour sodium 0.5% ~ 10%, citric acid 0.2% ~ 0.5%, 1,3-BDO 20%`30%, glycerine 1% ~ 5%, surplus are water.
2. compound amino acid composition according to claim 1, it is characterised in that by each component of following percentage by weight
Composition：：Serine 1% ~ 3%, L- glycine 1% ~ 2%, ALANINE 2% ~ 3.5%, L-Aspartic acid 1% ~ 4%, Valine 1% ~
3%th, L-arginine 1.2% ~ 1.8%, ILE 0.5% ~ 0.8%, L-Leu 0.5% ~ 1.5%, Pidolidone 0. 3% ~
0.8%th, L-PROLINE 1.5% ~ 2.5%, sodium lactate 0.5% ~ 10%, citric acid 0.2% ~ 0.5%, 1,3-BDO 20%`30%, glycerine
1% ~ 5%, surplus is water.
3. according to the compound amino acid described in claim 1 and 2, it is characterised in that by following preparation method：S1 by sodium lactate,
L-arginine, water add main emulsification pot, stirring and dissolving, aqueous ph value are adjusted into 9.5-11.0 with appropriate citric acid, and heat
To 40-50 DEG C；Between 40-50 DEG C of S2 constant temperature, Pidolidone, ILE, L-Leu, Serine, L- are sequentially added
Glycine, ALANINE, L-Aspartic acid, Valine, L-PROLINE are fast, after fast stirring and dissolving, continue constant temperature stirring
30min；Solution pH value is adjusted to 5.5-6.5 by S3 with appropriate citric acid, is added butanediol and glycerine, is stirred, filter micro-
Yellow transparent compound amino acid composition.
4. a kind of compound amino acid is without silicone oil conditioner shampoo, it is characterised in that contains the compound amino acid group described in claim 1
Compound.
5. a kind of compound amino acid according to claim 4 is without silicone oil conditioner shampoo, it is characterised in that by following weight hundred
Divide each component composition of ratio：
10%-30% surfactant；
0.1%-3% compound amino acid；
0.05%-1% cation opsonizing agent；
0.01-0.5 essence；
0.1-0.5% preservative；
0.01-1% PH conditioning agents
Surplus is water.
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| CN201710451395.0A CN107349117A (en) | 2017-06-15 | 2017-06-15 | A kind of compound amino acid composition and without silicone oil conditioner shampoo |
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| CN110327248A (en) * | 2019-08-05 | 2019-10-15 | 广州优敏泉生物科技有限公司 | A kind of composition and manufacture craft of no silicone oil conditioning hair |
| WO2023232894A1 (en) * | 2022-06-01 | 2023-12-07 | L'oreal | Aqueous cosmetic composition comprising 1-8% of amino acids and at least 3% of hydroxylated polycarboxylic acids, and cosmetic treatment process |
| WO2023232770A1 (en) * | 2022-06-01 | 2023-12-07 | L'oreal | Hair treatment method for limiting the calcium content of the hair |
| WO2023232768A1 (en) * | 2022-06-01 | 2023-12-07 | L'oreal | Hair treatment method comprising the application of a composition comprising amino acids and hydroxylated (poly)carboxylic acids, followed by washing the hair, and use as a pre-shampoo |
| FR3136159A1 (en) * | 2022-06-01 | 2023-12-08 | L'oreal | Cosmetic composition one or more amino acids, one or more (poly) hydroxylated C2-C8 carboxylic acids and one or more salts of (poly) hydroxylated C2-C8 carboxylic acids, and cosmetic treatment method |
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| FR3136162A1 (en) * | 2022-06-01 | 2023-12-08 | L'oreal | Hair treatment process comprising the application of a composition comprising amino acids and hydroxylated (poly)carboxylic acids, followed by washing the hair, and use as a pre-shampoo |
| FR3136167A1 (en) * | 2022-06-01 | 2023-12-08 | L'oreal | Hair treatment process to limit the calcium content of hair |
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