CN109512703A - A kind of hair is first supported washes product systems afterwards - Google Patents
A kind of hair is first supported washes product systems afterwards Download PDFInfo
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- CN109512703A CN109512703A CN201811632110.4A CN201811632110A CN109512703A CN 109512703 A CN109512703 A CN 109512703A CN 201811632110 A CN201811632110 A CN 201811632110A CN 109512703 A CN109512703 A CN 109512703A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
- A61K8/4913—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having five membered rings, e.g. pyrrolidone carboxylic acid
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
- A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/925—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of animal origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/002—Preparations for repairing the hair, e.g. hair cure
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/88—Two- or multipart kits
- A61K2800/884—Sequential application
Abstract
The present invention relates to a kind of hair-washing hair-care compositions, in particular to a kind of first to protect the hair care washed afterwards, hair-washing composition.The present invention includes that first feeding two independent hairs of conditioning composition and second chamber hair-washing composition wash shield composition to first chamber, wherein: first chamber first supports conditioning composition (A) by cation opsonizing agent, cationic surfactant, the composition such as class ceramide；Second chamber (B) hair-washing composition is by anionic surfactant, amphoteric surfactant, amino oxide type nonionic surfactant and cationic conditioning polymer composition.The dry and wet hair conditioning of the balanced hair of present invention energy, enhances the toughness of hair, conditioning durability and permeability, and hair is avoided frequently to wash injury caused by shield accumulation.
Description
Technical field
The present invention relates to a kind of hair-washing hair-care composition, in particular to a kind of hair first protects the composition washed afterwards.
Background technique
The development of shampoo technology and people are using the habit of product, demand and constantly innovate closely related, the eighties
International corporation is closed 1 shampoo (being commonly called as the shampoo of silicone oil using dimethyl silicone polymer for the first time) introducing China 2 and agitated
The high speed development for protecting market is washed by China, and 2 technologies closing 1 cleaning plus improving have brought much easy to use.
Wash the age that hair products enter subdivision today after 30 years.Various hair films, hair essence, aerosol type shield
Hair, foam-like wash hair care, scalp cleaning and maintenance, and clean type hair conditioner product etc. emerges one after another, more than the various selections of people
Ground.In short, people in daily hair-washing hair-care program often first with 2 close 1 shampoos clean hairs, after wash shield with hair conditioner again
Mode referred to as first has one's hair wash and uses hair conditioner afterwards, and first washes and protect two product compounding systems usually all cation and silicone oil tune afterwards
Ingredient is managed, there is good dry/wet experience effect for long hair user, but there may be improve excessive ask for long-time service
Topic, such as using silicone oil and cationic Accumulation Phenomenon is easy to produce after of long duration, this accumulation causes to wash shield conditioning performance to be in now
Drop trend and permeability is bad, in fact it could happen that hair heavy feeling, conditioning and it is submissive not persistently, just want to replace after using for a period of time
Phenomena such as new shampoo thought.
In addition, washing shield market in Japanese popular passing to China without silicon hair washing product and theory and become China in recent years
In subdivision most.There are many advantages of no silicone oil washes shield for example, system can accomplish transparent, can clean scalp and hair, make
It is more salubrious and penetrating etc. with rear hair but unique the disadvantage is that cannot achieve ideal dry and wet conditioning effect, particularly with length
Hair user.
The present invention is washed and is taken care of hair using a kind of " first protect and wash afterwards " technical approach by a large amount of formula application study discovery,
Feature are as follows: hair precuring conditioner is first used before hair washing, the active constituent (LipidBonding) in " first supporting conditioning composition "
Inside energy rapid osmotic hair and the lipid being lost due to hair washing because taking place frequently is supplemented, (hair is dry rear) hair internal penetration is stayed after hair washing
The hair precuring active constituent stayed returns to hair surface and forms hydrophobicity protective film and play the role of submissive and conditioning.This head
Hair first support wash afterwards product systems can equilibrium hair wash shield hair conditioning, enhance the toughness of hair, lasting hair conditioning and permeability, keep away
Exempt from hair and excessively wash injury caused by shield accumulation, this technology is also known as " prewashing pro-shampoo " or " first support and wash afterwards " technology.
Summary of the invention
Cleaning composition after first being supported the object of the present invention is to provide a kind of hair.
Cleaning composition after hair of the invention is first supported washes shield composition comprising two independent hairs, first dry before having one's hair wash
Send out or the hair that drenches on use (A) first to support conditioning composition, had one's hair wash again with (B) hair-washing composition later；
(A) first support conditioning composition includes in addition to cosmetically acceptable carrier:
I) feeding conditioning composition weight 0.05% to 10% of taking the lead cation opsonizing agent, the cation opsonizing agent be spermaceti
Base triethyl ammonium dimethyl silicone polymer PEG-8 succinate and acrylamido propyl trimethyl ammonium chloride/acrylamide copolymerization
Object,
II) feeding conditioning composition weight 0.05% to 10% of taking the lead cationic surfactant, the cationic surface is living
Property agent be selected from PEG-2 olein methyl ammonium, cocotrimonium chloride, hexadecyltrimethylammonium chloride, tristearin
Base trimethyl ammonium chloride, behenyl base trimethyl ammonium chloride, double stearyldimethylammonium chlorides or stearamidopropyl dimethylamine
It is at least one；
III) feeding conditioning composition weight 0.5% to 10% of taking the lead 8 to 22 carbon atoms saturation linear chain or branched chain
Long-chain alcohol C14-22Fatty alcohol mixture, the fatty alcohol mixture are C14Alcohol: C16-18Alcohol: C22Alcohol is with the ratio of weight ratio 2:1:0.5
Mixing；
IV) feeding conditioning composition weight 0.1% to 10% of taking the lead class ceramide, such ceramide be cetyl
Hydroxyproline palmitamide；
V) feeding conditioning composition weight 1% to 30% of taking the lead liquid lanolin, the liquid lanolin is at 20-25 DEG C
For mobility liquid；
(B) hair-washing composition includes in addition to cosmetically acceptable carrier:
I) account for the anionic surfactant of hair-washing composition weight 1% to 40%；
II) account for the amphoteric surfactant of hair-washing composition weight 1% to 10%；The amphoteric surfactant is cocounut oil
At least one of base both sexes sodium acetate and Cocoamidopropyl betaine,
III) the amino oxide type nonionic surfactant of hair-washing composition weight 0.1% to 5% is accounted for,
IV) cationic conditioning polymer of hair-washing composition weight 0.05% to 10% is accounted for, which is the sun
Ion conditioning polymer is cationic guar polymer and acrylamido propyl trimethyl ammonium chloride/acrylamide copolymer.
Cleaning composition after hair of the present invention is first supported, wherein the cetyl triethyl ammonium dimethyl silicone polymer PEG-8 amber
Amber acid esters and acrylamido propyl trimethyl ammonium chloride/acrylamide copolymer weight ratio are 2:1 to 1:2.
Cleaning composition after hair of the present invention is first supported, wherein the cationic surfactant is double stearyl dimethyl chlorinations
Ammonium.
Cleaning composition after hair of the present invention is first supported, wherein the anionic surfactant is alkyl sulfate salt, alkyl
Polyoxyethylene ether sulfate, glycerine monofatty ester sulfate, alkylsulfonate, N- acylsarcosine salt, N- acyl glutamate,
At least one of alkyl phosphate salt.
Cleaning composition after invention hair of the present invention is first supported, wherein the amphoteric surfactant is cocamidopropyl propyl amide beet
Alkali.
Cleaning composition after hair of the present invention is first supported, wherein the amino oxide type nonionic surfactant is lauryl
Amine oxide, cocamidopropyl propyl amide amine oxide and decyl amine oxide at least one therein.
Cleaning composition after hair of the present invention is first supported, wherein the cationic guar polymer and acrylamide propyl front three
Ammonium chloride/acrylamide copolymer weight ratio is 1:5 to 1:10.
Compared with prior art, the invention has the following advantages that
Cleaning composition after hair of the present invention is first supported passes through the hair rapid osmotic of " hair first supports conditioning composition " before hair washing
The hair precuring active constituent that hair internal penetration is resident (after hair is dry) after effect and hair washing returns to hair surface and is formed
Hydrophobicity protection membrane property realizes hair precuring maintenance and nourishes the effect of conditioning.The dry and wet hair conditioning of the balanced hair of energy, increases
The toughness of strong hair, conditioning durability and permeability avoid hair from frequently washing injury caused by shield accumulation.
Specific embodiment
Component selection of the invention and effect are described in detail below.
First support conditioning composition (A)
Hair of the present invention, which first supports first to support to contain in conditioning composition in rear cleaning composition (A), accounts for conditioner weight 0.05-
10% cation opsonizing agent advanced optimizes as 0.05-5%, and re-optimization is that cation opsonizing agent described in 0.05-3%. is whale
Cerul triethyl ammonium dimethyl silicone polymer PEG-8 succinate and acrylamido propyl trimethyl ammonium chloride/acrylamide are total
Polymers, wherein cetyl triethyl ammonium dimethyl silicone polymer PEG-8 succinate is a kind of very mild cationic conditioning
Agent and tax rouge agent, can be used for the conditioning of scalp and hair and will not generate the irritation such as trade mark
S-PF Biosil Technologies,Inc.；Acrylamido propyl trimethyl ammonium chloride/acrylamide copolymer is selected from sub- assorted
Blue trade mark N-DurHanceTMAA2000 is a kind of intermediate molecular weight (ten thousand Da of 10-20) high charge density (charge density 2.0meq/
G) conditioner is transparency liquid, always measures 19-21%, pH3.5-4.5 admittedly, in hair precuring, which can closely inhale
It is attached to the hair surface with negative electrical charge, hydrophobic protective film is formed, is used together and plays with liquid lanolin with class ceramide
Infiltration and collaboration maintenance effect.
(A) described in cleaning composition first supports described in conditioning composition two cation opsonizing agents after hair of the present invention is first supported
Weight ratio are as follows: cetyl triethyl ammonium dimethyl silicone polymer PEG-8 succinate: acrylamido propyl trimethyl ammonium chloride/
Acrylamide copolymer is equal to 2:1 to 1:2.
(A) described in cleaning composition, which first supports to contain in conditioning composition, after hair of the present invention is first supported accounts for conditioner weight 0.05-
10% cationic surfactant advanced optimizes as 0.05-8%, re-optimization 0.05-5%, the cation surface activating
Agent is double stearyldimethylammonium chlorides, plays the role of antistatic and stable emulsifying system.
(A) described in cleaning composition, which first supports to contain in conditioning composition, after hair of the present invention is first supported accounts for composition weight 0.5%-
The long-chain alcohol C14-22 fatty alcohol mixture of the linear chain or branched chain of the saturation of 10% 8 to 22 carbon atoms, fatty alcohol mixing
Object is C14 alcohol: C16-18 alcohol: C22 alcohol is mixed with the ratio of weight ratio 2:1:0.5, the C14-22 fatty alcohol mixture and institute
It states cationic surfactant and forms liquid crystal system, play the role of moisturizing, assign rouge and stabilising system.
(A) described in cleaning composition is first supported in conditioning composition and is accounted for composition weight 0.1-10%'s after hair of the present invention is first supported
Class ceramide advanced optimizes as 0.1-8%, re-optimization 0.1-4%.There is the trip of 7 seed types in human skin cuticula
From ceramide, wherein Cer NS is the main constituents of skin and hair, Cer NS as it is a kind of it is main at
Correct hair natural brightness in present hair cell membrane complex is separated, toughness and flexibility play the role of putting into.But with year
The increase in age or increasing with hair damage degree, the Cer NS in hair show the trend successively decreased.In practical makeup
In product application process, the macromolecular structure fusing point of Cer NS itself is very high, and dissolubility is very poor, uses and is extremely difficult to mesh
's.It can be considered to select to be known as class ceramide using a kind of substance similar with Cer NS chemical structure to be mended
It fills.
Cleaning composition (A) is first supported in conditioning composition after hair of the present invention is first supported, and the class ceramide is cetyl
Hydroxyproline palmitamide has absorption, tightening and the effect repaired to hair azelon.Cetyl hydroxyproline palm
Amide and liquid lanolin and cation opsonizing agent cetyl triethyl ammonium dimethyl silicone polymer PEG-8 succinate and propylene
Amidopropyltrimonium chloride/acrylamide copolymer has synergistic effect, increases class ceramide and plays rouge on hair
Matter binding and damage maintenance (drawing virtue LipidBonding technology) effect.
Cleaning composition (A) is first supported in conditioning composition after hair of the present invention is first supported, and the class ceramide is cetyl
Hydroxyproline palmitamide, molecular formula: C37H71NO4For white solid powder, 45~55 DEG C of fusing point, active matter >=90% is one
The bionical lipid of kind, has good adsorptivity and damage maintenance on hair, adsorbs and binds with hair natural lipid
Effect, to increase the toughness of hair.
(A) described in cleaning composition first supports the liquid that composition weight 1-30% is accounted in conditioning composition after hair of the present invention is first supported
Body lanolin advanced optimizes as 2-20%, re-optimization 3-15%.
It is first supported in conditioning composition (A) described in cleaning composition after hair of the present invention is first supported, the liquid lanolin is in temperature
It is mobility liquid at 20-25 DEG C of degree, it is a kind of lanolin for removing wax, in skin care which, which is called wool oil,
Possess that preferable moisture retention is good and not viscosity in class product.Compared with common paste wool grease (about 35-45 DEG C of fusing point),
The fusing point of liquid lanolin is lower and between 20-25 DEG C, therefore liquid lanolin has better permeability on hair, can seep
It penetrates into and the hair lipid components being lost because repeatedly having one's hair wash is stored and supplemented into (cortex of hair layer) inside hair, when hair washing,
Being attached to the lipid components such as the extra liquid lanolin of hair surface can be washed off, and when hair is done, partial penetration is simultaneously resident
Precuring conditioning ingredients (lipid components such as liquid lanolin) inside hair start emersion and the hair surface after dry is formed
Film, to play the role of reducing friction, soft and conditioning hair.
The present invention, which first supports conditioning composition (A), to be one and is with double stearyldimethylammonium chloride cationic surfactants
Emulsifier, with liquid lanolin, class ceramide, cation opsonizing agent cetyl triethyl ammonium dimethyl silicone polymer PEG-8
Succinate and acrylamido propyl trimethyl ammonium chloride/acrylamide copolymer etc. are that the composition of lipid active constituent is formed
A kind of emulsion oil-in-water, the characteristic that there is hair to permeate and form a film for the active constituent of the lotion (draws virtue LipidBonding
Technology) and play the precuring maintenance effect of hair that is, played on hair wash before hair infiltration maintenance, wash rear hair film forming,
The effect nourished and improved.
It can also include many in conditioning composition that first chamber (A), which is first supported, in cleaning composition after hair of the present invention is first supported
Optional components, including chelating agent, pH adjusting agent, preservative, essence, pigment.The chelating agent accounts for composition weight
0.01% to 0.30%, the non-limiting example of the chelating agent has: ethylenediamine tetra-acetic acid, disodium ethylene diamine tetraacetate, second two
Four sodium of amine tetraacethyl etc., preferably disodium ethylene diamine tetraacetate；The non-limiting example of the pH adjusting agent has: citric acid, phosphoric acid,
Lactic acid etc., optimization citric acid, the pH of regulation system is 4.0 to 8.5, preferably 4.0 to 5.5；The preservative, essence, pigment
It chooses, meets the regulation of hygienic standards for cosmetics, select safe raw material.
Second chamber hair-washing composition (B)
Contain the yin for accounting for composition weight 1-40% after hair of the present invention is first supported in (B) hair-washing composition described in cleaning composition
Ionic surface active agent, the anionic surfactant are sldium lauryl sulfate or ethoxylated dodecyl alcohol sodium sulphate, institute
The active matter content for stating ethoxylated dodecyl alcohol sodium sulphate commercial product is 70%, and appearance is white or faint yellow paste
Object.The ethoxylated dodecyl alcohol sodium sulphate also has the characteristic of nonionic surfactant, still has in hard water preferable
Dirt-removing power.Preferred ethoxylated dodecyl alcohol sodium sulphate in the present invention.
Contain the moon for accounting for composition weight 8-15% after hair of the present invention is first supported in (B) hair-washing composition described in cleaning composition
Cinnamic alcohol polyethenoxy ether sodium sulfate.
Contain in (B) hair-washing composition described in cleaning composition after hair of the present invention is first supported and accounts for the two of composition weight 1-10%
Property surfactant；The amphoteric surfactant be in cocoyl both sexes sodium acetate and Cocoamidopropyl betaine at least
One kind, the cocoyl both sexes sodium acetate are colourless to yellowish clear viscous liquids, and the active matter content of commercial product is
30%, the Cocoamidopropyl betaine is colourless to yellowish transparency liquid, and the active matter content of commercial product is
30%, both there is brilliant mild cleaning capacity, the foaming properties of shampoo can be improved.Improve the quantity and foam of foam
Stability.The preferred Cocoamidopropyl betaine of the present invention.
Contain the coconut palm for accounting for composition weight 1-6% after hair of the present invention is first supported in (B) hair-washing composition described in cleaning composition
Oleamide propyl betaine；
Contain in (B) hair-washing composition described in cleaning composition after hair of the present invention is first supported and accounts for composition weight 0.1-5%'s
Amino oxide type nonionic surfactant, the amino oxide type nonionic surfactant are lauryl amine oxidation
Object, cocamidopropyl propyl amide amine oxide, at least one of decyl amine oxide, amino oxide type non-ionic surface of the present invention
The preferred cocamidopropyl propyl amide amine oxide of activating agent, also known as cocamidopropyl propyl amide amine oxide.Cocamidopropyl propyl amide amine oxide, Gu
Content 31-33%, pH value 6.5-8.5 are a kind of mild amino oxide type nonionic surfactants, rise in the present invention
It foams to collaboration, cleaning and the permeability for promoting hair.
Contain in (B) hair-washing composition described in cleaning composition after hair of the present invention is first supported and accounts for composition weight 0.5-3%'s
Cocamidopropyl propyl amide amine oxide.
After hair of the present invention is first supported in (B) hair-washing composition described in cleaning composition containing account for composition weight 0.05% to
5% cationic conditioning polymer, the cationic polymer are selected from: cationic cellulose polymer, cation guar gum are poly-
Close at least one of object and acrylamido propyl trimethyl ammonium chloride/acrylamide copolymer, preferred cationic guar gum and
Acrylamido propyl trimethyl ammonium chloride/acrylamide copolymer.It is described cation melon rubber be by melon rubber it is quaternized after
The product arrived, main component are melon rubber hydroxypropyltrimonium chloride, and a series of sun can be obtained according to the difference of degree of substitution
Ion melon rubber product, preferably degree of substitution are 0.1 to 0.2, nitrogen content 1.3-1.7%, for cationic melon of the invention
For glue under the conditions of 25 DEG C, the viscosity of 1% aqueous solution is 3500mPa.s to 4500mPa.s；The acrylamido propyl trimethyl
Ammonium chloride/acrylamide copolymer, the polymer are a kind of homopolymers based on acrylate, have brilliant hair affine
Power plays accurate deposition on damaged hair, but not accumulates, while can also be effectively improved the comb hair and hair care body of consumer
It tests, brings lasting hair reparation and conditioning effect, persistently repair damaged hair such as " fried hair " in a long time, " hair entangles
Twine " phenomena such as, so that hair is restored natural physiological property, i.e., keep the hydrophobicity of hair for a long time, with heretofore described class mind
Have the function of that Collaborative Nursing damaged hair promotes hair toughness through amide and liquid lanolin.
After hair of the present invention is first supported in (B) hair-washing composition described in cleaning composition containing account for composition weight 0.05% to
3.5% cationic conditioning polymer, the cationic conditioning polymer are cationic guar polymer and acrylamide third
Base trimethyl ammonium chloride/acrylamide copolymer, the cationic guar polymer and acrylamido propyl trimethyl chlorination
Ammonium/acrylamide copolymer weight ratio is 1:5 to 1:10.The cationic guar polymer and acrylamide propyl front three
Ammonium chloride/acrylamide copolymer, which is used in compounding, plays best hair conditioning and maintenance effect.
(B) hair-washing composition described in cleaning composition can also include other optional components after hair of the present invention is first supported, including
Pearling agent, viscosity-controlling agent, chelating agent, pH adjusting agent, preservative, pigment and fragrance etc..The pearling agent accounts for composition weight
0.05% to 3.0%, the non-limiting example of the pearling agent has: ethylene glycol stearate monoesters and ethylene glycol stearic acid are double
Ester, monostearate and palm acid propylene glycol ester and glyceride, stearic acid alkylolamide magnesium stearate, fine dispersion zinc oxide
And titanium dioxide, preferred ethylene glycol stearate.The viscosity-controlling agent accounts for the 0.1% to 5.0% of composition weight, described
The non-limiting example of viscosity-controlling agent has: sodium chloride, ammonium chloride, ETHANOLAMINE HYDROCHLORIDE, sodium sulphate, ammonium phosphate, ethoxy
Cellulose, hydroxypropyl cellulose, acrylic acid and long chain alkyl methacrylate copolymer, acrylates/tristearin alcohol ether -20/
Methacrylate copolymer, methyl glucosamine polyoxyethylene ether (120) dioleate etc..The chelating agent accounts for composition weight
0.01% to 0.30%, the non-limiting example of the chelating agent has: ethylenediamine tetra-acetic acid, disodium ethylene diamine tetraacetate, second
Versene-9, tetrasodium ethylenediamine tetraacetate etc., preferably disodium ethylene diamine tetraacetate；The pH adjusting agent it is non-limiting
Example has: citric acid, phosphoric acid etc., optimization citric acid, and the pH of regulation system is 5.0 to 8.0, preferably 5.5 to 6.5；The anti-corrosion
Agent, the selection of essence, pigment, meet the regulation of hygienic standards for cosmetics, select safe raw material.
In shampoo composite of the invention, exceptionally in addition to the above group, mended with water to aequum.
Application method
Cleaning composition after hair of the present invention is first supported, taken out before having one's hair wash it is appropriate first support conditioning composition (A) be applied to drying hair or
It on wet hair, is uniformly smeared from root of hair to hair tail, reuses hair-washing composition (B) cleaning hair.
First feeding rear washing procedure (A)+(B) therein can according to need (hair damage degree) and be repeated as many times, to reach
The deep layer needed nurses effect.Use the postocciput product 1-3 (A)+(B) hair damage phenomenon such as " drying ", " fried hair " or " tangling "
Deng also can be used alone (B) product after obtaining maintenance.
Embodiment
Here is the non-limiting example of shampoo composite of the invention.These embodiments be only given in order to illustrate
Purpose, limitation of the invention can not be interpreted as, can be with because without departing from the spirit and scope of the present invention
Many changes are carried out such as to the present invention, " first conserving class " such as deep layer maintenance hair film can be developed using the technology of washing after precuring, persistently
The hair-care essence etc. of conditioning performance, and " washing class afterwards " such as deep layer maintenance shampoo.What term " a small amount of substance " used referred to
It is those of optional substance, such as preservative, viscosity modifier, pH adjusting agent, fragrance, pigment, the selection of these a small amount of substances
It will change with the selected physics to prepare special component of the invention and chemical characteristic.
Prepare embodiment 1-10 and blank control embodiment
The method of suitable preparation embodiment 1-10 (A) is as follows:
Suitable quantity of water is added in reactor tank, disodium ethylene diamine tetraacetate is added, cetyl triethyl ammonium poly dimethyl silicon
Oxygen alkane-PEG-8 succinate, acrylamido propyl trimethyl ammonium chloride/acrylamide copolymer stir and are warming up to 80 DEG C,
C14 alcohol, C16-18 alcohol, C22 alcohol, class ceramide, liquid lanolin is added, and is warming up to 80 DEG C and is uniformly mixed, to all
With 2500rmp/min homogeneous 2 minutes after material dissolution, it is then evacuated to -0.02Mpa, homogeneous terminates to cool down, mixing speed tune
It to 30-35rpm/min, is evacuated to minimum, citric acid, preservative, essence, pigment etc. is added and continues to stir, it is ensured that obtains
Even lotion.
The method of suitable preparation embodiment 1-10 (B) is as follows:
Suitable quantity of water is added in reactor tank, guar gum is added under slow stirring and is dispersed, is being slowly stirred heating
To 60 DEG C to 80 DEG C, suitable citric acid is added and neutralizes.It is subsequently added into ethoxylated dodecyl alcohol sodium sulphate, cocamidopropyl propyl amide
Glycine betaine, cocamidopropyl propyl amide amine oxide, acrylamido propyl trimethyl ammonium chloride/acrylamide copolymer, ethylene glycol are stearic
Acid diester, disodium ethylene diamine tetraacetate (if using these substances) after so that these substances is completely dispersed dissolution, keep the temperature 30 points
Clock starts to cool down.Sodium chloride, citric acid, preservative, pigment, essence etc. are added when temperature is down to 50 DEG C or so to continue to stir,
Ensure to obtain uniform mixture.After all components are added, viscosity modifier and pH adjusting agent can be added as needed, adjust
The viscosity and pH for saving product are to suitable degree.A small amount of water optionally can finally be added to supply.
The preparation method of blank control embodiment is same as above.
Cleaning composition includes first to support conditioning composition (A) and hair-washing composition (B) after first supporting, in which:
First support conditioning composition (A) embodiment (1)-(5) table 1
Table 1
Hair-washing composition (B) embodiment (1)-(5) table 2
Table 2
First support conditioning composition (A) embodiment (6)-(10) table 3
Table 3
Hair-washing composition (B) embodiment (6)-(10) table 4
Table 4
Blank control embodiment of the present invention
First support conditioning composition (A)-blank control embodiment table 5
Table 5
Hair-washing composition (B)-blank control embodiment table 6
Table 6
Highly preferred embodiment of the present invention
Cleaning composition is made of first feeding conditioning composition (A) and hair-washing composition (B) after first supporting, in which:
First support conditioning composition (A) most preferred embodiment table 7
Table 7
Hair-washing composition (B) most preferred embodiment table 8
Table 8
Compliance test result
A hair tensile strength (toughness) test:
Hair tensile strength is a variable, can be used for determining maintenance effect of the hair after using product, the drawing of hair
Stretch the bigger good toughness for representing hair of intensity, be damaged after hair tensile strength it is more big, illustrate hair injury repair effect more
Good (being shown in Table 9)
Test method；
Instrument, using Instron INSTRON tensilometer.
Topknot processing: taking about 10 grams of topknot sample several (Asia hairs), carry out 3 bleachings, spare.
Test program:
(1) then topknot is used with conditioning composition (A) sample rubbing (using finger tripe sequence from top to bottom) 30 seconds is first supported
Topknot is placed under 25 degrees Celsius and 60%RH relative humidity afterwards deposits in triplicate by shampoo composite (B) sample wash 30 seconds
Put it is spare, topknot a part that the bleaching is crossed be used for naked survey, do not use any sample of the present invention, directly test drawing force
Equal numerical value, another part are used to test drawing force using after sample of the present invention (containing blank control sample) processing.
(2) hair for handling above-mentioned (1) well is placed in INSTRON instrument test, tests the yield strength of hair, stretches by force
Degree and hairs break function, each data are the test results based on 30 hairs and are averaged.Finally obtain each embodiment
The tensile strength average value (kPa) of corresponding hair, finally with blank control and calculate tensile strength increase percentage.
The calculation method of hair tensile strength (kPa) value added (%) is as follows:
Hair tensile strength (kPa) value added (%)={ each embodiment processes the average tensile strength (kPa)-of hair
Bleaching crosses hair (without using any implementation grain processing) average tensile strength (kPa) } the excessive hair of/bleaching (do not make
With any implementation grain processing) average tensile strength (kPa) Ⅹ 100
Table 9
The result of table 9: bleaching topknot either handles using blank control embodiment of the present invention or uses the present invention real
After applying example (1)-(10) processing, the tensile strength of hair has different degrees of promotion.But blank control embodiment is processed
Hair tensile strength value added to the handled hair tensile strength value added crossed of embodiment (10), is said far below embodiment (1)
Bright practical embodiments of the present invention, which first support the technology of washing afterwards, has the function of the toughness for significantly increasing hair and elasticity, the increasing of hair toughness
Be by force it is relevant by the value added of the tensile strength of hair, illustrate the embodiment of the present invention first support wash afterwards system to hair have repair
Multiple effect.The effect for integrating embodiment 8 is best.
B hair after backwashing hair conditioning and permeability clinical trial
Select 50 volunteers, women, the neat shoulder of hair or excessively shoulder.
After backwashing hair conditioning and permeability refer to " not tangling, submissive, not thick and heavy, submissive effect is protected for hair after repeatedly hair washing
It is long to hold the time " it the sensory evaluations of four options and is counted according to scoring.
One group of volunteer uses 8 product of embodiment and respectively at the 1st day, the 7th day, the 14th day according to the order washed afterwards is first supported
Sensory evaluation table was filled in the 30th day, finally summarizes the evaluation result of each period；Meanwhile another group of volunteer then according to
First have one's hair wash after using hair conditioner mode using commercial product wash shield and respectively at the 1st day, the 7th day,
It fills in sensory evaluation table within 14th day and the 30th day, finally summarizes evaluation result (the used city of each period
Selling contrast sample is respectively that famous brand name 2 closes 1 type shampoo with treatment and hair conditioner), it the results are shown in Table 10.
Very good: four options obtain full marks；
It is good: wherein to obtain full marks there are three option；
It is medium: wherein to obtain full marks there are two option；
Invalid: wherein four options do not obtain full marks or only one of which option obtains full marks.
Table 10
According to 10 statistical result of table, volunteer uses embodiment 8 the 1st day, is counted within the 7th day, the 14th day and the 30th day
Sensory evaluation (including not tangling, submissive, not thick and heavy, the submissive effect retention time is long) display there is good effect, and press
According to the routine use frequency using after first supporting and washing product afterwards, the 7th day to the 30th day after backwashing hair conditioning and permeability effects is relatively more flat
, do not occur the trend that apparent effect is successively decreased, illustrate embodiment 8 to wash after shield is first supported cleaning composition that in hair to wash shield conditioning lasting
Property, performance is good in terms of washing the harmonious and anti-cumulative bad of shield.Conversely, the 30th day accounting of the invalid percentage of commercially available contrast sample
Very high, invalid percentage highest accounts for 70%, it is bad to illustrate that commercially available contrast sample washes shield rear after backwashing persistence of long duration, and in city
In tune find volunteer reaction permeability it is bad account for it is relatively high.
Claims (6)
1. cleaning composition after a kind of hair is first supported first supports conditioning composition and second chamber hair washing combination comprising first chamber
Two independent hairs of object wash shield composition, in which:
It is composed of the following components that first chamber (A) first supports conditioning composition: in addition to cosmetically acceptable carrier, include:
I) feeding conditioning composition weight 0.05% to 10% of taking the lead cation opsonizing agent, the cation opsonizing agent be cetyl three
Ethyl ammonium dimethyl silicone polymer PEG-8 succinate and acrylamido propyl trimethyl ammonium chloride/acrylamide copolymer；
II) feeding conditioning composition weight 0.05% to 10% of taking the lead cationic surfactant, the cationic surfactant
Selected from PEG-2 olein methyl ammonium, cocotrimonium chloride, hexadecyltrimethylammonium chloride, stearyl three
Ammonio methacrylate, behenyl base trimethyl ammonium chloride, double stearyldimethylammonium chlorides or stearamidopropyl dimethylamine are at least
It is a kind of；
III) feeding conditioning composition weight 0.5% to 10% of taking the lead C8-22Saturation linear chain or branched chain long-chain alcohol and C14-22
Fatty alcohol mixture, and the fatty alcohol mixture is C14Alcohol: C16-18Alcohol: C22Alcohol is mixed with the ratio of weight ratio 2:1:0.5；
IV) feeding conditioning composition weight 0.1% to 10% of taking the lead class ceramide, such ceramide be cetyl hydroxyl dried meat
Propylhomoserin palmitamide；
V) feeding conditioning composition weight 1% to 30% of taking the lead liquid lanolin, the liquid lanolin is in 20-25 DEG C of Shi Weiliu
Dynamic property liquid；
Second chamber (B) hair-washing composition includes in addition to cosmetically acceptable carrier:
I) account for the anionic surfactant of hair-washing composition weight 1% to 40%；
II) account for the amphoteric surfactant of hair-washing composition weight 1% to 10%；The amphoteric surfactant is cocoyl two
Property at least one of sodium acetate or Cocoamidopropyl betaine,
III) account for the amino oxide type nonionic surfactant of hair-washing composition weight 0.1% to 5%；
IV) cationic conditioning polymer of hair-washing composition weight 0.05% to 10% is accounted for, which is the cation
Conditioning polymer is cationic guar polymer and acrylamido propyl trimethyl ammonium chloride/acrylamide copolymer；
Conditioning composition is first first supported using hair in drying hair or the hair drenched before hair washing, is washed again with hair-washing composition later
Hair.
2. according to claim 1 first support rear cleaning composition, wherein cetyl triethyl ammonium dimethyl silicone polymer PEG-8
Succinate and acrylamido propyl trimethyl ammonium chloride/acrylamide copolymer weight ratio are 2:1 to 1:2.
3. according to claim 1 first support rear cleaning composition, wherein cationic surfactant is double stearyl dimethyls
Ammonium chloride.
4. according to claim 1 first support rear cleaning composition, wherein anionic surfactant is alkyl sulfate salt, alkane
Base polyoxyethylene ether sulfate, glycerine monofatty ester sulfate, alkylsulfonate, N- acylsarcosine salt, N- acyl glutamic acid
At least one of salt, alkyl phosphate salt.
5. according to claim 1 first support rear cleaning composition, wherein amphoteric surfactant is cocamidopropyl propyl amide beet
Alkali.
6. according to claim 1 first support rear cleaning composition, wherein cationic guar polymer and acrylamide propyl
Trimethyl ammonium chloride: the weight ratio of acrylamide copolymer is 1:5 to 1:10.
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| CN111053706A (en) * | 2020-02-17 | 2020-04-24 | 澳宝化妆品（惠州）有限公司 | Self-heating pre-wash hair care composition |
| CN111228168A (en) * | 2020-01-15 | 2020-06-05 | 拉芳家化股份有限公司 | A nourishing liquid containing repairing hair for treating alopecia |
| CN116139042A (en) * | 2023-02-24 | 2023-05-23 | 华熙生物科技股份有限公司 | Hair treatment composition |
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| CN111228168A (en) * | 2020-01-15 | 2020-06-05 | 拉芳家化股份有限公司 | A nourishing liquid containing repairing hair for treating alopecia |
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| CN116139042A (en) * | 2023-02-24 | 2023-05-23 | 华熙生物科技股份有限公司 | Hair treatment composition |
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