CN109044857A - A kind of no silicone oil shampoo conditioner composition, without silicone oil shampoo and preparation method thereof - Google Patents

A kind of no silicone oil shampoo conditioner composition, without silicone oil shampoo and preparation method thereof Download PDF

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Publication number
CN109044857A
CN109044857A CN201811122564.7A CN201811122564A CN109044857A CN 109044857 A CN109044857 A CN 109044857A CN 201811122564 A CN201811122564 A CN 201811122564A CN 109044857 A CN109044857 A CN 109044857A
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content
silicone oil
conditioner composition
oil shampoo
shampoo
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CN109044857B (en
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陈凤凤
杨成
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Shanghai Fulai biological High Tech Co.,Ltd.
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Jiangnan University
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/85Polyesters
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/06Emulsions
    • A61K8/068Microemulsions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31Hydrocarbons
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • A61K8/345Alcohols containing more than one hydroxy group
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37Esters of carboxylic acids
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39Derivatives containing from 2 to 10 oxyalkylene groups
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/442Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/63Steroids; Derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/02Preparations for cleaning the hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/30Characterized by the absence of a particular group of ingredients
    • A61K2800/34Free of silicones
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59Mixtures
    • A61K2800/592Mixtures of compounds complementing their respective functions

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
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  • Birds (AREA)
  • Epidemiology (AREA)
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  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Cosmetics (AREA)

Abstract

The invention discloses a kind of no silicone oil shampoo conditioner composition, without silicone oil shampoo and preparation method thereof, it includes, alkylamide propyl dimethylamine, O-3-P, polyglycereol ester emulsifying agent, wherein, by percentage to the quality, the alkylamide propyl diformazan amine content is 5~8%, the O-3-P content is 4~10%, the polyglycereol esters emulsifier content is 5~6%.Conditioner composition property prepared by the present invention is stablized, and for that hair can be made to have good cardability, anti-winding, antistatic and glossiness in no silicone oil shampoo.

Description

A kind of no silicone oil shampoo conditioner composition, without silicone oil shampoo and its preparation Method
Technical field
The invention belongs to shampoo composite technical fields, and in particular to a kind of no silicone oil shampoo conditioner composition, Without silicone oil shampoo and preparation method thereof.
Background technique
Shampoo has silicone oil shampoo and without silicone oil shampoo, there is silicone oil by point being divided into whether there is or not silicone oil currently on the market Shampoo because silicon impermeability itself and other inertia, cause a series of scalp problems, and silicone oil is difficult to drop in itself Solution is also not environmentally.In recent years, hair washing industry focuses on the theory of nursing scalp, thus starts without silicone oil shampoo prevailing.However without silicon After oil wash shampoo washes hair, hair can dry and astringent difficult combing, it is lackluster, to do one it is transparent without silicone oil shampoo, improve The selection of agent is even more difficulty.
It is mostly currently on the market transparent system without silicone oil shampoo, in order to there is good cardability to add a large amount of macromolecule Quaternary ammonium salt conditioner has when having one's hair wash although washing in the rear short time has preferable cardability and rinses not clean sense, excessive high score Sub- polymer deposits make hair have heavy feeling on hair, are easily stained with ash even stimulation scalp, cause itching of the scalp and dandruff.Cause This, needs to develop a conditioner composition that can nurse scalp and moisten hair, have fine cardability, comfort.
Summary of the invention
The purpose of this section is to summarize some aspects of the embodiment of the present invention and briefly introduce some preferable implementations Example.It may do a little simplified or be omitted to avoid our department is made in this section and the description of the application and the title of the invention Point, the purpose of abstract of description and denomination of invention it is fuzzy, and this simplification or omit and cannot be used for limiting the scope of the invention.
In view of above-mentioned technological deficiency, the present invention is proposed.
Therefore, as one aspect of the present invention, the present invention overcomes the deficiencies in the prior art, provides a kind of nothing Silicone oil shampoo conditioner composition.
In order to solve the above technical problems, the present invention provides the following technical scheme that a kind of no silicone oil shampoo conditioner group Close object comprising, alkylamide propyl dimethylamine, O-3-P, polyglycereol ester emulsifying agent, wherein with quality Percentages, the alkylamide propyl diformazan amine content is 5~8%, the O-3-P content be 4~ 10%, the polyglycereol esters emulsifier content is 5~6%.
A kind of preferred embodiment as no silicone oil shampoo conditioner composition of the present invention: the alkylamide third Base dimethylamine includes cocoamidopropyl dimethylamine amine, and by percentage to the quality, the cocoamidopropyl dimethylamine amine content is 7.5%.
A kind of preferred embodiment as no silicone oil shampoo conditioner composition of the present invention: the polyglycereol esters Emulsifier includes Natrulon H-10 laurate, and by percentage to the quality, the Natrulon H-10 laurate content is 6%.
A kind of preferred embodiment as no silicone oil shampoo conditioner composition of the present invention: with mass percent Meter, the O-3-P content are 5%.
A kind of preferred embodiment as no silicone oil shampoo conditioner composition of the present invention: further including camellia seed Oil, phytosterol, saualane, hexylene glycol, wherein by percentage to the quality, the camellia seed oil content is 6~8%, the plant Object sterol content is 2~3%, the saualane content is 3~5%, the hexylene glycol content is 6%, and surplus is water.
A kind of preferred embodiment as no silicone oil shampoo conditioner composition of the present invention: the no silicone oil hair washing Water conditioner composition is micro emulsion composition.
As another aspect of the present invention, the present invention overcomes the deficiencies in the prior art, provides a kind of no silicone oil Shampoo.
In order to solve the above technical problems, the present invention provides the following technical scheme that a kind of no silicone oil shampoo, in which: packet Including any conditioner composition of claim 1~6, the mass percentage of the conditioner composition is 14~ 16%.
A kind of preferred embodiment as no silicone oil shampoo of the present invention: further including, EDTA-2Na, guar gum hydroxypropyl Ammonium chloride, sodium lauroyl sarcosine, cocounut oil acyl hydroxypropyl glycine betaine, sodium chloride, PEG-120 methyl ester, Phenoxyethanol, Wherein, by percentage to the quality, the EDTA-2Na content is 0.1%, the guar gum hydroxypropyl ammonium chloride content is 0.2%, the sodium lauroyl sarcosine content is 30%, the cocounut oil acyl hydroxypropyl glycine betaine content is 10%, the chlorination Sodium content is 0.5%, the PEG-120 methyl ester content is 2%, the Phenoxyethanol content is 0.7%.
As another aspect of the present invention, the present invention overcomes the deficiencies in the prior art, provides described without silicon The preparation method of oil wash shampoo.
In order to solve the above technical problems, the present invention provides the following technical scheme that the preparation of the no silicone oil shampoo Method comprising,
Guar gum hydroxypropyl ammonium chloride is added to the water after dispersion completely, sodium lauroyl sarcosine, EDTA-2Na stirring is added Dispersed-heated is to 80 DEG C;
The conditioner composition and PEG-120 methyl ester is added, is cooled to 50 DEG C after mixing evenly;
Remaining component is added, discharges after being stirred into microemulsion formulation.
Beneficial effects of the present invention: the cationic alkaline surfactant (cocoamidopropyl dimethylamine amine) that the present invention selects Can be very good to be combined together with O-3-P, thus can not only play the role of solubilized grease but also have it is antistatic, The cardability effect of anti-winding;Natrulon H-10 laurate can emulsify natural grease well, with cocoamidopropyl dimethylamine amine Synergistic effect is played with O-3-P, improves cardability, anti-winding, antistatic and glossiness;Camellia seed oil, plant steroid Alcohol, which can not only moisten scalp, can also repair impaired hair, moisten hair glossy;Saualane is nonpolar grease addition Can not only there be reparation hair in composition, moisten the effect of hair, moreover it is possible to which preventing microemulsion from Ostwald ripening occurs can Keep the stability of microemulsion emulsion droplet;Hexylene glycol not only provides moisture-keeping function in composition, can also provide solubilized and anti- Rotten effect.The reasonable combination of reasonable mixture ratio of components of the invention, the selection of each component and constituent mass ratio makes the tune of this product Rationality effect is extremely significant.
Detailed description of the invention
In order to illustrate the technical solution of the embodiments of the present invention more clearly, required use in being described below to embodiment Attached drawing be briefly described, it should be apparent that, drawings in the following description are only some embodiments of the invention, for this For the those of ordinary skill of field, without any creative labor, it can also be obtained according to these attached drawings other Attached drawing.Wherein:
Fig. 1 is prepared for blank control group, using 2 conditioner of embodiment, using commercial conditioner 1, using commercial conditioner 2 The wet comb property test of the hair without silicone oil shampoo;
Fig. 2 is prepared for blank control group, using 2 conditioner of embodiment, using commercial conditioner 1, using commercial conditioner 2 The dry comb property test of the hair without silicone oil shampoo.
Fig. 3 is to carry out half without silicone oil shampoo and certain commercially available two shampoo of brand to containing embodiment 1 and embodiment 2 Head test result figure.
Specific embodiment
In order to make the foregoing objectives, features and advantages of the present invention clearer and more comprehensible, right combined with specific embodiments below A specific embodiment of the invention is described in detail.
In the following description, numerous specific details are set forth in order to facilitate a full understanding of the present invention, but the present invention can be with Implemented using other than the one described here other way, those skilled in the art can be without prejudice to intension of the present invention In the case of do similar popularization, therefore the present invention is not limited by the specific embodiments disclosed below.
Secondly, " one embodiment " or " embodiment " referred to herein, which refers to, may be included at least one realization side of the invention A particular feature, structure, or characteristic in formula." in one embodiment " that different places occur in the present specification not refers both to The same embodiment, nor the individual or selective embodiment mutually exclusive with other embodiments.
Embodiment 1:
Conditioner composition of the present invention includes following mass percent component:
Raw material Mass percent/%
Cocoamidopropyl dimethylamine amine 7.5
O-3-P 5
Natrulon H-10 laurate 6
Camellia seed oil 6
Phytosterol 2
Saualane 3
Hexylene glycol 6
Water Surplus
Embodiment 2:
Conditioner composition of the present invention includes following mass percent component:
Raw material Mass percent/%
Stearamidopropyl dimethylamine 8
O-3-P 4
Natrulon H-10 laurate 5
Camellia seed oil 8
Phytosterol 2
Saualane 5
Hexylene glycol 6
Water Surplus
Embodiment 3:
Conditioner composition of the present invention includes following mass percent component:
Embodiment 4:
Conditioner composition of the present invention includes following mass percent component:
Raw material Mass percent/%
Cocoamidopropyl dimethylamine amine 5
O-3-P 8
Natrulon H-10 stearate 5
Camellia seed oil 8
Phytosterol 3
Saualane 5
Hexylene glycol 6
Water Surplus
Embodiment 5:
The present invention is using conditioner composition without silicone oil shampoo formula:
Examples 1 to 4 conditioner composition is added separately to the present invention without in silicone oil shampoo, conditioner group will be not added Close object without silicone oil shampoo as blank control.
The present invention without silicone oil shampoo the preparation method is as follows:
1) guar gum hydroxypropyl ammonium chloride is added to the water the completely rear addition sodium lauroyl sarcosine of dispersion, EDTA-2Na is stirred Dispersed-heated is mixed to 80 DEG C;
2) conditioner composition of Examples 1 to 4 and PEG-120 methyl ester are added in 1) and are stirred evenly respectively After be cooled to 50 DEG C;
3) remaining each raw material is added, discharges after being stirred into microemulsion formulation.
Conditioner composition containing Examples 1 to 4 without silicone oil shampoo appearance and stability test:
The conditioner composition containing Examples 1 to 4 is placed in 48 DEG C of baking oven without silicone oil shampoo respectively, refrigerator -15 DEG C, alternate cycles are placed within 24 hours, are tested one month.
Occurring during the preparation process without silicone oil shampoo for conditioner composition containing embodiment 4 is muddy, and one month The conditioner composition containing Examples 1 to 5 does not have significant change without silicone oil shampoo appearance afterwards, there is no because Ovshinsky it is ripe Change and turbid phenomenon occurs.
Conditioner composition containing Examples 1 to 3 without silicone oil shampoo brbble test:
It is measured according to GB/T7462-94.It takes 2g sample to be put into 800mL beaker, 80g standard hard water (hardness is added It is 0.342g/L with calcium carbonate) and 718g deionized water, 40 DEG C are heated to, thermostatical water bath is opened simultaneously, makes water temperature stability At 40 DEG C.Successively tested inside pipe wall 3 times using deionized water and prepare liquid rinse.It is in close state piston, is carefully pipetted It is concordant with testing tube 50mL graduation mark to make liquid level, while foam being avoided to generate for 50mL prepare liquid.200mL is drawn with pipette to wait for Liquid is surveyed, pipette is placed in fixator, keeps the cross section of pipette and testing tube in 90 °.It has been in pipette piston rapidly Full opening state, it is ensured that prepare liquid flows down naturally vertically.It is released completely to prepare liquid, reads instantaneous foam height at once.Weight It multiple the above experiment 2 times, is averaged.Using be not added conditioner composition without silicone oil shampoo as blank control.
Influence of the conditioner composition of 1 Examples 1 to 3 of table to shampoo foaming properties
Seen from table 1, the conditioner composition of embodiment 1 does not influence the original foam of shampoo, adjusts containing embodiment 1 Manage the best without silicone oil shampoo foaming properties of agent composition.Embodiment 2,3 all has apparent defoaming effect.
No silicone oil hair washing water-wet comb and dry comb performance compare:
Choose it is above-mentioned containing 1 conditioner composition of embodiment without silicone oil shampoo, the blank pair of conditioning composition is not added The wet comb of hair and dry comb property test are carried out respectively according to 2 kinds of commercially available no silicone oil shampoos, as a result such as Fig. 1,2, it can from figure Out, when dry and wet is combed, the frictional force that comb generates in carding process is below blank and commercially available washes the shampoo of embodiment 1 Better than commercially available respectively without silicone oil shampoo, conditioner composition of the present invention has bright for shampoo, i.e. the shampoo cardability containing embodiment 1 Aobvious improvement carding effect.
No silicone oil shampoo (half a head test) trial effect evaluation:
To 20 volunteers's (random) to containing embodiment 1 and embodiment 2 without silicone oil shampoo and certain commercially available brand two Money shampoo carries out half a head test.Half a head test be hair washing when or so half a head simultaneously wash two kinds of shampoos, while experience washing Different feeling when hair and after hair washing.Specific evaluation index such as table 2.Evaluation result is shown in Table 3 and Fig. 3.It can be seen that embodiment 1 is component Shampoo, not only there is good dry and wet cardability, also there is good antistatic, glossiness and moisten degree.
Half a head test evaluation index of the table 2 without silicone oil shampoo
The evaluation marking result of 3 four kinds of shampoos of table
Evaluation index Embodiment 1 Blank Commercial shampoos 1 Commercial shampoos 1
The abundant degree of foam 5 5 5 5
The sliding sense of hair when bath 4.5 2 3 3
Submissive sense when wet process 4 2.5 3.5 3
Submissive sense when drying hair 4.5 2.8 3.2 3.4
Hair gloss when drying hair 4.5 3 4.2 3.6
Antistatic property when drying hair 4.6 2.6 3 3.5
Moisture feeling when drying hair 4.8 3 4 4.2
The cationic alkaline surfactant (cocoamidopropyl dimethylamine amine) and -3 phosphoric acid of oleth that the present invention selects Ester can be very good to be combined together, to can not only play the role of solubilized grease but also have the cardability of antistatic, anti-winding to imitate Fruit;Natrulon H-10 laurate can emulsify natural grease well, with -3 phosphoric acid of cocoamidopropyl dimethylamine amine and oleth Ester plays synergistic effect, improves cardability, anti-winding, antistatic and glossiness;Camellia seed oil, phytosterol can not only moisten head Skin can also repair impaired hair, moisten hair glossy;Saualane is that nonpolar grease addition not only may be used in composition To there is reparation hair, the effect of hair is moistened, moreover it is possible to which microemulsion emulsion can be kept by preventing microemulsion from Ostwald ripening occurs The stability of drop;Hexylene glycol not only provides moisture-keeping function in composition, can also provide solubilising and corrosion-resistant effect.Of the invention The reasonable combination of reasonable mixture ratio of components, the selection of each component and constituent mass ratio makes the hair conditioning effect of this product extremely significant.
The research of the invention finds that the present invention utilizes cocoamidopropyl dimethylamine amine in conjunction with O-3-P, association With Natrulon H-10 laurate by grease and camellia seed oil, phytosterol solubilising wherein, form stable clear microemulsion body System, cocoamidopropyl dimethylamine amine and hair form good Electrostatic Absorption, when cleaning hair with the shampoo containing this micro emulsion, Cation is adsorbed on hair with the grease and nutrition of package, make hair not only there is hair conditioning but also moisten it is glossy, it is cardability, anti- Winding, antistatic effect are significant.
Conditioner composition property prepared by the present invention is stablized, and for that hair can be made to have well in no silicone oil shampoo Cardability, anti-winding, antistatic and glossiness.
It should be noted that the above examples are only used to illustrate the technical scheme of the present invention and are not limiting, although referring to preferable Embodiment describes the invention in detail, those skilled in the art should understand that, it can be to technology of the invention Scheme is modified or replaced equivalently, and without departing from the spirit and scope of the technical solution of the present invention, should all be covered in this hair In bright scope of the claims.

Claims (9)

1. a kind of no silicone oil shampoo conditioner composition, it is characterised in that: including alkylamide propyl dimethylamine, oleyl alcohol are poly- - 3 phosphate of ether, polyglycereol ester emulsifying agent, wherein by percentage to the quality, the alkylamide propyl diformazan amine content is 5 ~8%, the O-3-P content is 4~10%, the polyglycereol esters emulsifier content is 5~6%.
2. as described in claim 1 without silicone oil shampoo conditioner composition, it is characterised in that: the alkylamide propyl two Methylamine includes cocoamidopropyl dimethylamine amine, and by percentage to the quality, the cocoamidopropyl dimethylamine amine content is 7.5%.
3. as claimed in claim 1 or 2 without silicone oil shampoo conditioner composition, it is characterised in that: the polyglycereol esters Emulsifier includes Natrulon H-10 laurate, and by percentage to the quality, the Natrulon H-10 laurate content is 6%.
4. as claimed in claim 1 or 2 without silicone oil shampoo conditioner composition, it is characterised in that: by percentage to the quality, The O-3-P content is 5%.
5. as claimed in claim 1 or 2 without silicone oil shampoo conditioner composition, it is characterised in that: further include camellia seed Oil, phytosterol, saualane, hexylene glycol, wherein by percentage to the quality, the camellia seed oil content is 6~8%, the plant Object sterol content is 2~3%, the saualane content is 3~5%, the hexylene glycol content is 6%, and surplus is water.
6. as claimed in claim 1 or 2 without silicone oil shampoo conditioner composition, it is characterised in that: the no silicone oil hair washing Water conditioner composition is micro emulsion composition.
7. a kind of no silicone oil shampoo, it is characterised in that: described including any conditioner composition of claim 1~6 The mass percentage of conditioner composition is 14~16%.
8. as claimed in claim 7 without silicone oil shampoo, it is characterised in that: further include EDTA-2Na, guar gum hydroxypropyl chlorine Change ammonium, sodium lauroyl sarcosine, cocounut oil acyl hydroxypropyl glycine betaine, sodium chloride, PEG-120 methyl ester, Phenoxyethanol, In, by percentage to the quality, the EDTA-2Na content is 0.1%, the guar gum hydroxypropyl ammonium chloride content is 0.2%, The sodium lauroyl sarcosine content is 30%, the cocounut oil acyl hydroxypropyl glycine betaine content is 10%, the sodium chloride content For 0.5%, the PEG-120 methyl ester content be 2%, the Phenoxyethanol content is 0.7%.
9. the preparation method without silicone oil shampoo described in claim 7 or 8, it is characterised in that: including,
Guar gum hydroxypropyl ammonium chloride is added to the water the completely rear addition sodium lauroyl sarcosine of dispersion, EDTA-2Na is dispersed with stirring It is heated to 80 DEG C;
The conditioner composition and PEG-120 methyl ester is added, is cooled to 50 DEG C after mixing evenly;
Remaining component is added, discharges after being stirred into microemulsion formulation.
CN201811122564.7A 2018-09-26 2018-09-26 Silicone-oil-free shampoo conditioner composition, silicone-oil-free shampoo and preparation method thereof Active CN109044857B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109512703A (en) * 2018-12-29 2019-03-26 拉芳家化股份有限公司 A kind of hair is first supported washes product systems afterwards
CN114099362A (en) * 2021-09-03 2022-03-01 太和康美(北京)中医研究院有限公司 Shampoo containing phytosterol and phytosterol ester and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1198561C (en) * 2000-07-12 2005-04-27 莱雅公司 Transparent gel form foamed cleaning composition
WO2012175686A2 (en) * 2011-06-24 2012-12-27 L'oreal Compositions containing an amine or a phospholipid, a nonionic surfactant, and a phosphate ester for lifting color and/or imparting shine onto keratinous substrates
CN104546548A (en) * 2014-12-31 2015-04-29 陈扬 Translucent silicone-free hair care composition and method for preparing hair care composition
CN106176285A (en) * 2016-08-25 2016-12-07 天津郁美净集团有限公司 A kind of be applicable to that child uses have one's hair wash bath composition and preparation method thereof without silicon
CN106420462A (en) * 2016-10-14 2017-02-22 千亿达(天津)科技有限公司 Scalp nourishing care shampoo and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1198561C (en) * 2000-07-12 2005-04-27 莱雅公司 Transparent gel form foamed cleaning composition
WO2012175686A2 (en) * 2011-06-24 2012-12-27 L'oreal Compositions containing an amine or a phospholipid, a nonionic surfactant, and a phosphate ester for lifting color and/or imparting shine onto keratinous substrates
CN104546548A (en) * 2014-12-31 2015-04-29 陈扬 Translucent silicone-free hair care composition and method for preparing hair care composition
CN106176285A (en) * 2016-08-25 2016-12-07 天津郁美净集团有限公司 A kind of be applicable to that child uses have one's hair wash bath composition and preparation method thereof without silicon
CN106420462A (en) * 2016-10-14 2017-02-22 千亿达(天津)科技有限公司 Scalp nourishing care shampoo and preparation method thereof

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
柏芳青: "《聚甘油脂肪酸酯非离子表面活性剂的研究进展》", 《网络财富》 *
梁少华: "《植物油料资源综合利用》", 31 October 2009 *
熊昌云: "《茶叶深加工与综合利用》", 31 December 2014 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109512703A (en) * 2018-12-29 2019-03-26 拉芳家化股份有限公司 A kind of hair is first supported washes product systems afterwards
CN109512703B (en) * 2018-12-29 2021-10-15 拉芳家化股份有限公司 Hair is fostered earlier and is washed product system afterwards
CN114099362A (en) * 2021-09-03 2022-03-01 太和康美(北京)中医研究院有限公司 Shampoo containing phytosterol and phytosterol ester and preparation method thereof

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