CN106176285A - A kind of be applicable to that child uses have one's hair wash bath composition and preparation method thereof without silicon - Google Patents

A kind of be applicable to that child uses have one's hair wash bath composition and preparation method thereof without silicon Download PDF

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Publication number
CN106176285A
CN106176285A CN201610717699.2A CN201610717699A CN106176285A CN 106176285 A CN106176285 A CN 106176285A CN 201610717699 A CN201610717699 A CN 201610717699A CN 106176285 A CN106176285 A CN 106176285A
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Prior art keywords
silicon
bath composition
applicable
hair
hair washing
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CN201610717699.2A
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Inventor
周敬
陈萍
梁园园
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YUMEIJING GROUP CO Ltd TIANJIN
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YUMEIJING GROUP CO Ltd TIANJIN
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Priority to CN201610717699.2A priority Critical patent/CN106176285A/en
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86Polyethers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • A61K8/737Galactomannans, e.g. guar; Derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/10Washing or bathing preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/02Preparations for cleaning the hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54Polymers characterized by specific structures/properties
    • A61K2800/542Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5426Polymers characterized by specific structures/properties characterized by the charge cationic

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

The invention provides a kind of be applicable to that child uses without silicon hair washing bath composition and preparation method thereof, the raw material of described hair washing bath composition includes without silicon conditioning ingredients, gentleness surfactant, thickening agent, preservative, tax ester agent, acid-base modifier and water.Not silicate-containing oil in this hair washing bath composition, it is suitable for child to use, the conditioning ingredients without silicon wherein added, by the synergism of cationic polymer, adsorbable in electronegative hair surface, hydrophobic carbochain (18 alkyl) in structure external source can supplement natural 18 MEA that hair hair scale sheet outermost layer loses, it is provided that the more preferable hydrophobicity of hair, thus improves carding property.

Description

A kind of be applicable to that child uses have one's hair wash bath composition and preparation method thereof without silicon
Technical field
The invention belongs to cosmetics of everyday use field, particularly to a kind of be applicable to child use without silicon hair washing bath composition And preparation method thereof.
Background technology
It is former that shampoo typically contains primary surfactant, auxiliary surfactant, conditioner, smooth dose, shampoo and essence etc. Material.Smooth dose refers generally to the full-bodied silicon compound of some high molecular, and they absorption, each hair surface, are formed the most suitable Sliding thin film, makes hair smooth.At present, conventional in shampoo silicon compound has polydimethylsiloxane, amido silicon oil, Huan Jia Radical siloxanes etc., when our hair-washing hair-care, these silicon-containing compounds can fill up the gap between hair scale sheet, and people can be allowed to feel Hair sense of touch is the most smooth.
However as growth in the living standard, the safety of cosmetics of everyday use is the most increasingly paid close attention to by people, the silicon in shampoo Although compound can allow hair smooth, but due to the water-fast characteristic of these silicon-containing compounds, it is wrapped in hair and scalp On silicon be less susceptible to be cleaned, enrichment the most year in year out, these silicon-containing compounds can make hair gradually lose Losing elasticity, scalp clogging of pores, cause scalp oxygen flow not enough, hair papilla gradually atrophy, scalp just starts to occur itching, the most de- The phenomenon sent out.
Summary of the invention
It is an object of the invention to provide a kind of be applicable to child use without silicon hair washing bath composition, described in be applicable to Virgin use without silicon hair washing bath composition.
It is an object of the invention to be achieved through the following technical solutions:
A kind of be applicable to child use without silicon have one's hair wash bath composition, described in be applicable to child use without silicon hair washing shower group The raw material of compound includes without silicon conditioning ingredients, gentle surfactant, thickening agent, preservative, essence, wetting agent, tax ester agent, acid Alkali regulator and water, the ratio of weight and number of each raw material is:
The 1-4 of conditioning ingredients without silicon
Gentle surfactant 20-40
Thickening agent 0.5-4
Preservative 0.5-1
Essence 0.1-0.5
Wetting agent 2-5
Compose ester agent 1-3
Acid-base modifier 1-5
Water 43-76.
Further, described conditioning ingredients without silicon be oleth-5 phosphate ester, guar hydroxypropyltrimonium ammonium chloride, The mixture of one or more in inulin.
Further, described gentle surfactant is lauryl alcohol sulfosuccinate disodium, cocamidopropyl propyl amide Radix Betae Alkali, lauryl glucoside, lauryl both sexes sodium acetate, cocos nucifera oil acyl both sexes base oxalic acid disodium, sodium cocoamphoacetate, pungent Acyl/caprinoyl aminopropyl glycine betaine, cocos nucifera oil acyl Sodium L-alaninate, lauroyl Herba bromi japonici amino acid sodium, cocoyl Fructus Mali pumilae amino acid sodium, In cocoyl glucoside, C8-16 alkyl polyglucoside, sodium cocoyl glutamate, sodium lauroyl glutamate, sodium cocoyl glycinate The mixture of one or more.
Further, described thickening agent be acrylate/polyoxyethylene (20) octadecanol ether metacrylic acid ester copolymer, Acrylate/C10-30 alkyl acrylate cross-linked polymer, acrylate/behenyl alcohol polyethers-25 methacrylate, coconut palm The mixture of one or more in oleamide DEA.
Further, described preservative is Methylisothiazolinone, methylchloroisothiazandnone, double (methylol) imidazolidine One or more mixture in base urea, DMDM Hydantoin, imidazolidinyl urea.
Further, described wetting agent is one or more in glycerol, propylene glycol, butanediol, trehalose, xylitol Mixture.
Further, described acid-base modifier is sodium hydrate aqueous solution.
Further, described tax ester agent is olein, C12-15 alcohol lactate, PEG-7 glyceryl cocoate, glycerol The mixture of one or more in ether bar bar Fructus Perillae oil, castor oil-base maleate.
Further, described conditioning ingredients without silicon be oleth-5 phosphate ester, guar hydroxypropyltrimonium ammonium chloride, The compositions of inulin, the weight fraction ratio of each raw material is:
Oleth-5 phosphate ester 1-3
Guar hydroxypropyltrimonium ammonium chloride 0.2
Inulin 0.6-0.8.
The described preparation method being applicable to the bath composition of having one's hair wash without silicon that child uses, described preparation method include with Lower step:
1) guar hydroxypropyltrimonium ammonium chloride is uniformly dispersed in 1:10 ratio with water, adds oleth-5 phosphate ester and stir Mix uniformly, and be heated to 75 DEG C-80 DEG C;
2), after stirring and dissolving, add the water of whole raw material components gross weight 30%-40%, system temperature be reduced to 70-75 DEG C Celsius Degree adds gentle surfactant, wetting agent stirs to being completely dissolved, and is subsequently adding thickening agent and stirs to being uniformly dissolved;
3) starting cooling after stirring, equitemperature is down to 50 DEG C, adds and composes fat agent, acid-base modifier, inulin, preservative, perfume (or spice) Essence;
4) supply remaining moisture, mix homogeneously, obtain and described have one's hair wash bath composition without silicon.
The present invention having the beneficial effect that compared to existing technology
1, of the present invention be applicable to child use without silicon have one's hair wash bath composition, not silicate-containing oil, be suitable for child use, lead to Cross interpolation and replace silicone oil, the conditioning ingredients without silicon wherein added oleth-5 phosphate ester without silicon conditioning ingredients, pass through cation The synergism of polymer, adsorbable in electronegative hair surface, the hydrophobic carbochain (18 alkyl) in structure can external source be mended Fill the natural 18-MEA of hair hair scale sheet outermost layer loss, it is provided that the more preferable hydrophobicity of hair, thus improve carding property;
2, of the present invention be applicable to child use without silicon hair washing bath composition, the conditioning ingredients without silicon wherein added melon That glue hydroxypropyl-trimethyl ammonium chloride, is the cationic polymer of synthesis, shows splendid wet cardability and do in formula Cardability, derives from reproducible natural melon glue, its low-molecular-weight and the characteristic of optimization charge density, it is possible to provide splendid Skinfeel;
3, of the present invention be applicable to child use without silicon hair washing bath composition, the conditioning ingredients without silicon wherein added chrysanthemum Powder is the white powder to yellow, can substitute for cationic polymer, non-stimulated, and avirulence is biodegradable.
Detailed description of the invention
Embodiment 1
A kind of be applicable to child use without silicon have one's hair wash bath composition, described in be applicable to child use without silicon hair washing shower group The raw material of compound includes without silicon conditioning ingredients, gentle surfactant, thickening agent, preservative, essence, wetting agent, tax ester agent, acid Alkali regulator and water, the ratio of weight and number of each raw material is:
The 1-4 of conditioning ingredients without silicon
Gentle surfactant 20-40
Thickening agent 0.5-4
Preservative 0.5-1
Essence 0.1-0.5
Wetting agent 2-5
Compose ester agent 1-3
Acid-base modifier 1-5
Water 43-76.
Further, described conditioning ingredients without silicon be oleth-5 phosphate ester, guar hydroxypropyltrimonium ammonium chloride, The mixture of one or more in inulin.
Further, described gentle surfactant is lauryl alcohol sulfosuccinate disodium, cocamidopropyl propyl amide Radix Betae Alkali, lauryl glucoside, lauryl both sexes sodium acetate, cocos nucifera oil acyl both sexes base oxalic acid disodium, sodium cocoamphoacetate, pungent Acyl/caprinoyl aminopropyl glycine betaine, cocos nucifera oil acyl Sodium L-alaninate, lauroyl Herba bromi japonici amino acid sodium, cocoyl Fructus Mali pumilae amino acid sodium, In cocoyl glucoside, C8-16 alkyl polyglucoside, sodium cocoyl glutamate, sodium lauroyl glutamate, sodium cocoyl glycinate The mixture of one or more.
Further, described thickening agent is hydroxypropyl methyl cellulose, hydroxyethyl cellulose, acrylate/polyoxyethylene (20) octadecanol ether metacrylic acid ester copolymer, acrylate/C10-30 alkyl acrylate cross-linked polymer, acrylate The mixing of one or more in/behenyl alcohol polyethers-25 methacrylate, hydroxypropyl starch phosphate, coconut oleoyl amine DEA Thing.
Further, described preservative is Methylisothiazolinone, methylchloroisothiazandnone, double (methylol) imidazolidine The mixture of one or more in base urea, DMDM Hydantoin, imidazolidinyl urea.
Further, described wetting agent is one or more in glycerol, propylene glycol, butanediol, trehalose, xylitol Mixture.
Further, described acid-base modifier is sodium hydrate aqueous solution.
Further, described tax ester agent is olein, C12-15 alcohol lactate, PEG-7 glyceryl cocoate, glycerol The mixture of one or more in ether bar bar Fructus Perillae oil, castor oil-base maleate.
Further, described conditioning ingredients without silicon be oleth-5 phosphate ester, guar hydroxypropyltrimonium ammonium chloride, The compositions of inulin, the weight fraction ratio of each raw material is:
Oleth-5 phosphate ester 1-3
Guar hydroxypropyltrimonium ammonium chloride 0.2
Inulin 0.6-0.8.
The described preparation method being applicable to the bath composition of having one's hair wash without silicon that child uses, described preparation method include with Lower step:
1) guar hydroxypropyltrimonium ammonium chloride is uniformly dispersed in 1:10 ratio with water, adds oleth-5 phosphate ester and stir Mix uniformly, and be heated to 75 DEG C-80 DEG C;
2), after stirring and dissolving, add the water of whole raw material components gross weight 30%-40%, system temperature be reduced to 70-75 DEG C Celsius Degree adds gentle surfactant, wetting agent stirs to being completely dissolved, and is subsequently adding thickening agent and stirs to being uniformly dissolved;
3) starting cooling after stirring, equitemperature is down to 50 DEG C, adds and composes fat agent, acid-base modifier, inulin, preservative, perfume (or spice) Essence;
4) supply remaining moisture, mix homogeneously, obtain and described have one's hair wash bath composition without silicon.
Unit of weight used by the present embodiment is kilogram, it is also possible to for gram;
Each raw material described in the present embodiment is on market the conventional products sold;
In the present embodiment, each described raw material can in the ratio range be given flexible combination, enumerate the most one by one at this.
Embodiment 2
The present embodiment is the preferred version on the basis of embodiment 1, and the present embodiment is without the weight of each raw material in silicon hair washing bath composition The amount information such as score ratio and manufacturer thereof is as shown in the table:
The described preparation method without silicon hair washing bath composition, comprises the following steps:
1) dispersible cationic guar hydroxypropyltrimonium chloride, addition oleth-5 phosphate ester stirring in deionized water Uniformly, and be heated to 75-80 DEG C;
2) stirring is to being uniformly dissolved, and adds the water of whole raw material components gross weight 30%-40%, and system temperature is reduced to 70-75 DEG C Adding B phase component, stirring, to dissolving, is subsequently adding C phase component, and stirring is to being uniformly dissolved;
3) starting cooling after stirring, equitemperature is down to 50 DEG C, adds D phase component,
4) supply moisture, get product.
Embodiment 3
The present embodiment is the preferred version on the basis of embodiment 1, and the present embodiment is without the weight of each raw material in silicon hair washing bath composition The amount information such as score ratio and manufacturer thereof is as shown in the table, and preparation method is with reference to embodiment 2:
Embodiment 4
The present embodiment is the preferred version on the basis of embodiment 1, and the present embodiment is without the weight of each raw material in silicon hair washing bath composition The amount information such as score ratio and manufacturer thereof is as shown in the table, and preparation method is with reference to embodiment 2:
Carding property is tested:
Instrument: Hair setting instrument, child's topknot: long 15cm, heavy, combing power is evaluated, and the combing power used is the least, shows comb Reason effect is the best, and the combing power used is the biggest, and carding effect is the poorest.
To embodiment 2-4 provide without silicon hair washing bath composition, carried out combing power test respectively, its result is such as Shown in following table.
Embodiment 2 Embodiment 3 Embodiment 4
Dry comb combing power 495 453 387
Wet comb combing power 1487 1346 1268

Claims (10)

1. one kind be applicable to child use without silicon have one's hair wash bath composition, it is characterised in that described in be applicable to child use Raw material without silicon hair washing bath composition includes without silicon conditioning ingredients, gentle surfactant, thickening agent, preservative, essence, guarantor Humectant, tax ester agent, acid-base modifier and water, the ratio of weight and number of each raw material is:
The 1-4 of conditioning ingredients without silicon
Gentle surfactant 20-40
Thickening agent 0.5-4
Preservative 0.5-1
Essence 0.1-0.5
Wetting agent 2-5
Compose ester agent 1-3
Acid-base modifier 1-5
Water 43-76.
The most according to claim 1 be applicable to child use without silicon hair washing bath composition, it is characterised in that described nothing Silicon conditioning ingredients is the mixed of one or more in oleth-5 phosphate ester, guar hydroxypropyltrimonium ammonium chloride, inulin Compound.
The most according to claim 1 be applicable to child use without silicon hair washing bath composition, it is characterised in that described temperature It is lauryl alcohol sulfosuccinate disodium, cocamido propyl betaine, lauryl glucoside, lauryl two with surfactant Property sodium acetate, cocos nucifera oil acyl both sexes base oxalic acid disodium, sodium cocoamphoacetate, decoyl/caprinoyl aminopropyl glycine betaine, coconut palm Oleoyl Sodium L-alaninate, lauroyl Herba bromi japonici amino acid sodium, cocoyl Fructus Mali pumilae amino acid sodium, cocoyl glucoside, C8-16 alkyl The mixture of one or more in glucosides, sodium cocoyl glutamate, sodium lauroyl glutamate.
The most according to claim 1 be applicable to child use without silicon hair washing bath composition, it is characterised in that described increasing Thick dose is hydroxypropyl methyl cellulose, hydroxyethyl cellulose, acrylate/polyoxyethylene (20) octadecanol ether metacrylic acid ester Copolymer, acrylate/C10-30 alkyl acrylate cross-linked polymer, acrylate/behenyl alcohol polyethers-25 metering system One or both mixture in acid esters, hydroxypropyl starch phosphate, coconut oleoyl amine DEA.
The most according to claim 1 be applicable to child use without silicon have one's hair wash bath composition, it is characterised in that described prevent Rotten agent is Methylisothiazolinone, methylchloroisothiazandnone, Bis(hydroxymethyl)imidazolidinyl urea, DMDM Hydantoin, imidazoles Ureine.
The most according to claim 1 be applicable to child use without silicon hair washing bath composition, it is characterised in that described Wetting agent is the mixture of one or more in glycerol, propylene glycol, butanediol, trehalose, xylitol.
The most according to claim 1 be applicable to child use without silicon hair washing bath composition, it is characterised in that described Acid-base modifier is sodium hydrate aqueous solution.
The most according to claim 1 be applicable to child use without silicon hair washing bath composition, it is characterised in that described tax Ester agent is olein, C12-15 alcohol lactate, PEG-7 glyceryl cocoate, glycerin ether bar bar Fructus Perillae oil, castor oil-base horse Carry out the mixture of one or more in acid esters.
The most according to claim 2 be applicable to child use without silicon hair washing bath composition, it is characterised in that described nothing Silicon conditioning ingredients is oleth-5 phosphate ester, guar hydroxypropyltrimonium ammonium chloride, the compositions of inulin, the weight of each raw material Amount score ratio is:
Oleth-5 phosphate ester 1-3
Guar hydroxypropyltrimonium ammonium chloride 0.2
Inulin 0.6-0.8.
10. the preparation being applicable to the bath composition of having one's hair wash without silicon that child uses as described in any one of claim 1-9 Method, it is characterised in that described preparation method comprises the following steps:
1) guar hydroxypropyltrimonium ammonium chloride is uniformly dispersed in 1:10 ratio with water, adds oleth-5 phosphate ester and stir Mix uniformly, and be heated to 75-80 DEG C;
2) after stirring and dissolving, adding the water of whole raw material components gross weight 30%-40%, system temperature is reduced to 70-75 degree Celsius Add gentle surfactant, thickening agent, wetting agent stirring to being completely dissolved;
3) starting cooling, equitemperature is down to 50 DEG C, adds and composes fat agent, acid-base modifier, insulated and stirred;
4) continuously add preservative, essence, inulin, supply remaining moisture, mix homogeneously, obtain described taking a shower without silicon hair washing Compositions.
CN201610717699.2A 2016-08-25 2016-08-25 A kind of be applicable to that child uses have one's hair wash bath composition and preparation method thereof without silicon Pending CN106176285A (en)

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CN107648096A (en) * 2017-09-22 2018-02-02 拉芳家化股份有限公司 A kind of children's adacrya hair washing bath foam composition
CN107669551A (en) * 2017-10-31 2018-02-09 思拓科(上海)生物科技股份有限公司 Organic baby's shampoo used also as bath lotion and preparation method thereof
CN107693436A (en) * 2017-11-21 2018-02-16 郑生华 A kind of baby's soapberry protects shower cream and preparation method thereof again
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CN109044857A (en) * 2018-09-26 2018-12-21 江南大学 A kind of no silicone oil shampoo conditioner composition, without silicone oil shampoo and preparation method thereof
CN109288719A (en) * 2018-11-23 2019-02-01 广州市科能化妆品科研有限公司 A kind of mild shampoo composition and preparation method thereof
CN111184642A (en) * 2019-08-15 2020-05-22 杭州犇鑫科技有限公司 Two-in-one hair washing and bathing composition
CN111956522A (en) * 2020-09-22 2020-11-20 福建省梦娇兰日用化学品有限公司 Infant shampoo without silicone oil and preparation method thereof
CN112137951A (en) * 2020-10-23 2020-12-29 天津强微特生物科技有限公司 Silicone-oil-free transparent amino acid shampoo capable of strengthening hair and repairing scalp barrier and preparation method thereof
CN112426370A (en) * 2020-11-27 2021-03-02 天津郁美净集团有限公司 Washing composition with synergistic thickening and fat-endowing effects as well as preparation method and application thereof
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CN115414272A (en) * 2022-09-23 2022-12-02 广州天然国度生物科技有限公司 Girl bubble shampoo without irritation to eyes and preparation method thereof

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CN107198663A (en) * 2017-05-12 2017-09-26 广州市蔻妍化妆品有限公司 It is a kind of without silicone oil baby hair washing, two-in-one composition and preparation method thereof of taking a shower
CN107648096A (en) * 2017-09-22 2018-02-02 拉芳家化股份有限公司 A kind of children's adacrya hair washing bath foam composition
CN107669551A (en) * 2017-10-31 2018-02-09 思拓科(上海)生物科技股份有限公司 Organic baby's shampoo used also as bath lotion and preparation method thereof
CN107693436A (en) * 2017-11-21 2018-02-16 郑生华 A kind of baby's soapberry protects shower cream and preparation method thereof again
CN108403541A (en) * 2018-03-16 2018-08-17 柳州市奥康眼镜有限公司 A kind of antibacterial shampoo of plant source
CN108283583A (en) * 2018-03-27 2018-07-17 广州禾力生物科技有限公司 A kind of no silicoamino-acid shampoo and preparation method thereof
CN112638356A (en) * 2018-09-07 2021-04-09 莱雅公司 Cleaning compositions free of sodium chloride and sulfate based surfactants
CN109044857A (en) * 2018-09-26 2018-12-21 江南大学 A kind of no silicone oil shampoo conditioner composition, without silicone oil shampoo and preparation method thereof
CN109044857B (en) * 2018-09-26 2021-07-09 江南大学 Silicone-oil-free shampoo conditioner composition, silicone-oil-free shampoo and preparation method thereof
CN109288719A (en) * 2018-11-23 2019-02-01 广州市科能化妆品科研有限公司 A kind of mild shampoo composition and preparation method thereof
CN111184642A (en) * 2019-08-15 2020-05-22 杭州犇鑫科技有限公司 Two-in-one hair washing and bathing composition
CN111956522A (en) * 2020-09-22 2020-11-20 福建省梦娇兰日用化学品有限公司 Infant shampoo without silicone oil and preparation method thereof
CN112137951A (en) * 2020-10-23 2020-12-29 天津强微特生物科技有限公司 Silicone-oil-free transparent amino acid shampoo capable of strengthening hair and repairing scalp barrier and preparation method thereof
CN112426370A (en) * 2020-11-27 2021-03-02 天津郁美净集团有限公司 Washing composition with synergistic thickening and fat-endowing effects as well as preparation method and application thereof
CN115414272A (en) * 2022-09-23 2022-12-02 广州天然国度生物科技有限公司 Girl bubble shampoo without irritation to eyes and preparation method thereof
CN115414272B (en) * 2022-09-23 2023-09-15 广州天然国度生物科技有限公司 Female bubble shampoo without irritation in eyes and preparation method thereof

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Application publication date: 20161207