CN104856895B - A kind of without silicon shampoo and preparation method thereof - Google Patents
A kind of without silicon shampoo and preparation method thereof Download PDFInfo
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Abstract
The invention discloses a kind of without silicon shampoo and preparation method thereof, the present invention includes inulin 0.5 ~ 5%, Vegetable oil lipoprotein 0.2 ~ 5%, solubilizing agent 0.2 ~ 2%, thickening agent 0.2 ~ 2%, sodium laureth sulfate 3 ~ 8%, cocamido propyl betaine 3 ~ 8%, alkyl polyglucoside 1 ~ 5%, sodium cocoyl glycinate 1 ~ 5%, tetrasodium ethylenediamine tetraacetate 0.05 ~ 0.5%, citric acid 0.05 ~ 0.5%, preservative 0.2 ~ 1%, essence 0.2 ~ 1% and water 58 ~ 90% without silicon shampoo.The present invention is non-stimulated without silicon shampoo gentleness, and while cleaning hair, effective hair conditioning, after cleaning, hair is glossy, a softer and smoother touch.
Description
Technical field
The invention belongs to daily use chemicals articles for washing technical field, be specifically related to a kind of without silicon shampoo and preparation method thereof.
Background technology
It is former that shampoo typically contains primary surfactant, auxiliary surfactant, conditioner, smooth dose, shampoo and essence etc.
Material.Smooth dose refers generally to the full-bodied silicon compound of some high molecular, and they absorption, each hair surface, are formed the most suitable
Sliding thin film, makes hair smooth.In shampoo, conventional silicon compound has polydimethylsiloxane, amido silicon oil, Huan Jia at present
Radical siloxanes etc., when our hair-washing hair-care, these silicon-containing compounds can fill up the gap between hair scale sheet, and people can be allowed to feel
Hair sense of touch is the most smooth.
However as growth in the living standard, the safety of cosmetics of everyday use is the most increasingly paid close attention to by people, in shampoo
Silicon compound although hair can be allowed smooth, but due to the water-fast characteristic of these silicon-containing compounds, be wrapped in hair and
Silicon on scalp is less susceptible to be cleaned, enrichment the most year in year out, these silicon-containing compounds can make hair by
Gradually losing elasticity, scalp clogging of pores, cause scalp oxygen flow not enough, hair papilla gradually atrophy, scalp just starts to occur itching, very
Phenomenon to alopecia.The problem that whether other infringement healths are existed for the silicon-containing compound in shampoo, although at present
Not yet obtain authoritative department to confirm, but have and suggest that the shampoo of best different brands changes and use, it is to avoid same silicone oil exists
Deposit on hair, but such way also cannot avoid the wind that the silicon-containing compound in shampoo may be potential to health
Danger, therefore people are sought for the shampoo of not silicate-containing oil, but the most on the market in shampoo component list more than ninety percent all
Having " polydimethylsiloxane ", the shampoo of silicate-containing oil is not the most several.
Patent documentation CN 104473790 A discloses a kind of without silicon shampoo, and it includes alkylpolyoxyethylene sulfur
Acid sodium, cocamido propyl betaine, cocinic acid, diglycollic amide, glycol stearate, cellulose quaternary ammonium salt, Fructus Citri Limoniae
Acid, sodium chloride, shredding, essence, disodium EDTA and water.Though this shampoo not silicate-containing oil, but containing cation
Surfactant cellulose quaternary ammonium salt is bigger to skin irritation.
In shampoo, surfactant plays regulatory role, and makes the electrostatic in hair minimize so that hair is prone to combing, easily
In unclamping, and it is that the combing of wet hair and dry hair is easy and smooth and easy.Meanwhile, shampoo requires to have high spumescence, low
Degreasing power, the micelle structure etc. of low zest, the easily higher system viscosity of formation, the selection of such Surfactant is just
There is certain restriction.The zest of the cationic polymers such as cationic surfactant such as guar gum quaternary ammonium salt, polyquaternary ammonium salt is big,
Biological degradability is poor, and owing to hair and dirt are the most electronegative, this will make dirt-removing power be deteriorated, attachment is tight
Weight.Cationic polymer can show the eutrophication to surface water simultaneously, and this is owing to their nitrogen content is with a large amount of
Annual can wash, at cosmetic, the cationic polymer that compositions uses and cause.Therefore, have a kind of trend to limit sun from
Sub-polymer can be washed compositions at cosmetic and use.Accordingly, people just seek cosmetic can wash compositions middle-jiao yang, function of the spleen and stomach from
The substitute of sub-polymer, specific saccharide and glycocalix are open, such as sucrose, alginate, inulin, guar gum etc..
Inulin is mainly derived from plant, is to be contained in the protoplasm of cell with colloid form, and its molecule is about by 31 β-D-
Fructofuranose and 1 ~ 2 pyrans inulin residue are polymerized, and by β-2 between residue of fructose, 1-is bonded, and fructose is polymeric
Mixture, in nonionic.Compared with cationic polymer, there is non-stimulated, avirulence, the advantage such as biodegradable.
Patent documentation CN 1889924 A discloses a kind of cosmetic containing inulin-type levan can wash compositions, should
Washing compositions contains 0.10 ~ 10%, and the inulin-type levan of preferably 0.5 ~ 5%, most preferably 1 ~ 3% is (to wash composition total weight
The percentage by weight of dry), inulin-type levan is inulin and fructo-oligosaccharide in that patent.This patent research is sent out
The use of existing inulin-type levan can substitute tradition cosmetic completely can wash the cationic polymer in compositions.But,
In actual application, the raw material type of shampoo is the most, and inulin might not produce synergism with it, and therefore having must
Research and develop a kind of with inulin replacement cationic polymer, and effectively cleaning and the shampoo without silicon of hair conditioning.
Summary of the invention
It is an object of the invention to provide a kind of without silicon shampoo, its not silicate-containing oil, it is to avoid owing to silicone oil gathers, make hair
Collapse patch, dimness, tarnish, not cation-containing copolymer, it is to avoid the problem that scalp irritates and causes head pruritus.
The present invention is by the following technical programs to realize above-mentioned purpose, a kind of without silicon shampoo, including following weight hundred
The component of proportion by subtraction meter: inulin 0.5 ~ 5%, Vegetable oil lipoprotein 0.2 ~ 5%, solubilizing agent 0.2 ~ 2%, thickening agent 0.2 ~ 2%, laureth sulfur
Acid esters sodium 3 ~ 8%, cocamido propyl betaine 3 ~ 8%, alkyl polyglucoside 1 ~ 5%, sodium cocoyl glycinate 1 ~ 5%, ethylenediamine tetrem
Acid four sodium 0.05 ~ 0.5%, citric acid 0.05 ~ 0.5%, preservative 0.2 ~ 1%, essence 0.2 ~ 1% and water 58 ~ 90%.As the present invention
Preferred embodiment, the present invention is made up of the component of following percentage by weight meter without silicon shampoo: inulin 3%, Vegetable oil lipoprotein
4%, solubilizing agent 1.5%, thickening agent 1.2%, sodium laureth sulfate 5%, cocamido propyl betaine 6%, alkyl polyglucoside
2%, sodium cocoyl glycinate 3%, tetrasodium ethylenediamine tetraacetate 0.2%, citric acid 0.2%, preservative 0.5%, essence 0.8% and water
72.6%。
Further, the one during described Vegetable oil lipoprotein is almond oil, macadamia nut oil or a combination thereof.
Further, described Vegetable oil lipoprotein is the compositions of almond oil and macadamia nut oil, described almond oil and macadamia nut oil
Weight ratio is (1 ~ 3): (2 ~ 5)；Described almond oil further preferably is 2:5 with the weight ratio of macadamia nut oil.
Further, the one during described solubilizing agent is PEG-60 castor oil hydrogenated, polysorbate-20 or a combination thereof；
It is preferably PEG-60 castor oil hydrogenated.
Further, described thickening agent is PEG-120 methyl dioleate.
Further, the one during described preservative is phenoxyethanol, Methylisothiazolinone or a combination thereof.
Further, described preservative is the compositions of phenoxyethanol and Methylisothiazolinone, described phenoxyethanol
It is 9:1 with the weight ratio of Methylisothiazolinone.
Present invention also offers the preparation method of above-mentioned shampoo without silicon, comprise the following steps:
(1) solubilizing agent, Vegetable oil lipoprotein and essence being mixed, stir to obtain mixed liquor, standby；
(2) take the water of component weight 25 ~ 35%, add thickening agent, be warming up to 70 ~ 75 DEG C and stir to being completely dissolved, continue
Adding the water of component weight 25 ~ 35%, system temperature is down to 55 ~ 60 DEG C, adds sodium laureth sulfate, coconut oleoyl amine
CAB, alkyl polyglucoside, sodium cocoyl glycinate, stirring, to being completely dissolved, obtains liquid one, standby；
(3) separately take the water of component weight 15 ~ 25%, after addition inulin stirs, add the liquid one of step (2), stir
Mix uniformly, obtain liquid two；
(4) in step (3) liquid two, add step (1) mixed liquor, stir, add ethylenediaminetetraacetic acid four
Sodium, citric acid, preservative and water, stir.
Compared with prior art, present invention have an advantage that
1) present invention replaces the cationic polymer such as guar gum, polyquaternary ammonium salt with natural inulin, with natural plant grease generation
For silicone oil, use the gentle surfactant conduct such as cocamido propyl betaine, alkyl polyglucoside, sodium laureth sulfate
Cleansing, is a kind of gentleness shampoo without silicone oil non-stimulated, not cation-containing copolymer.Its not silicate-containing oil, thus without
There is silicone oil to gather, the filthy dust in air will not be adsorbed, make hair collapse patch, dull, greasy, tarnish；Not cation
Polymer, will bring scalp to irritate and the problem that causes head pruritus.
2) each component of the present invention and proportioning thereof are worked in coordination with, and have fine and smooth abundant foam, effectively cleaning hair but do not hinder scalp,
Hair is had and well nurses one's health nursing role, can obviously reduce hair wet comb resistance and holding and improve hair gloss, after using
Scalp is light, hair is full, glossy, a softer and smoother touch, hair without tangle.
Detailed description of the invention
Further describe the present invention below by way of detailed description of the invention, but the present invention is not limited only to following example.?
In the scope of the present invention or without departing from present disclosure, spirit and scope, to shampoo without silicon of the present invention
And preparation method thereof carry out being suitably modified, replacing the component that effect is identical, be apparent to those skilled in the art
, they are considered as being included within the scope of the present invention.
Each component in the present invention is conventional commercial product, and such as, the inulin in embodiment is purchased from the celestial graceful trade in Guangzhou
Company NATULIN NC100；Almond oil refines Semen pruni armeniacae oil CROPURE SWEET ALMOND purchased from standing grain major company；Macadamia nut oil is purchased
Macadimia nut seed oil is refined from standing grain major company；Alkyl polyglucoside is purchased from Kening Co., Ltd APG 1200.
Embodiment 1, the present invention are without silicon shampoo and preparation thereof
Formula: inulin 30g, Vegetable oil lipoprotein (almond oil is 2:5 with the weight ratio of macadamia nut oil) 40g, PEG-60 hydrogenated castor
Oil 15g, PEG-120 methyl dioleate 12g, sodium laureth sulfate 50g, cocamido propyl betaine 60g,
Alkyl polyglucoside 20g, sodium cocoyl glycinate 30g, tetrasodium ethylenediamine tetraacetate 2g, citric acid 2g, preservative (phenoxyethanol and first
The weight ratio of base isothiazolone is 9:1) 5g, essence 8g, water 726g.
Preparation: PEG-60 castor oil hydrogenated, Vegetable oil lipoprotein and essence are mixed by (1), and stir to obtain mixed liquor, standby；
(2) take the water of component weight 30%, add PEG-120 methyl dioleate, be warming up to 70 DEG C of stirrings to complete
CL, continuously adds the water of component weight 30%, and system temperature is down to 55 DEG C, adds sodium laureth sulfate, cocos nucifera oil
Amido propyl betaine, alkyl polyglucoside, sodium cocoyl glycinate, stirring, to being completely dissolved, obtains liquid one, standby；
(3) separately take the water of component weight 20%, after addition inulin stirs, add the liquid one of step (2), stirring
Uniformly, liquid two is obtained；
(4) in step (3) liquid two, add step (1) mixed liquor, stir, add ethylenediaminetetraacetic acid four
Sodium, citric acid, preservative and water, stir.
Embodiment 2, the present invention are without silicon shampoo and preparation thereof
Formula: inulin 5g, Vegetable oil lipoprotein (almond oil is 1:2 with the weight ratio of macadamia nut oil) 50g, PEG-60 castor oil hydrogenated
20g, PEG-120 methyl dioleate 2g, sodium laureth sulfate 60g, cocamido propyl betaine 30g, alkane
Base glucosides 50g, sodium cocoyl glycinate 10g, tetrasodium ethylenediamine tetraacetate 5g, citric acid 5g, preservative (phenoxyethanol and methyl
The weight ratio of isothiazolone is 9:1) 2g, essence 2g, water 759g.
Preparation: PEG-60 castor oil hydrogenated, Vegetable oil lipoprotein and essence are mixed by (1), and stir to obtain mixed liquor, standby；
(2) take the water of component weight 25%, add PEG-120 methyl dioleate, be warming up to 75 DEG C of stirrings to complete
CL, continuously adds the water of component weight 35%, and system temperature is down to 60 DEG C, adds sodium laureth sulfate, cocos nucifera oil
Amido propyl betaine, alkyl polyglucoside, sodium cocoyl glycinate, stirring, to being completely dissolved, obtains liquid one, standby；
(3) separately take the water of component weight 15%, after addition inulin stirs, add the liquid one of step (2), stirring
Uniformly, liquid two is obtained；
(4) in step (3) liquid two, add step (1) mixed liquor, stir, add ethylenediaminetetraacetic acid four
Sodium, citric acid, preservative and water, stir.
Embodiment 3, the present invention are without silicon shampoo and preparation thereof
Formula: inulin 50g, Vegetable oil lipoprotein (almond oil is 3:4 with the weight ratio of macadamia nut oil) 2g, polysorbate-20
2g, PEG-120 methyl dioleate 20g, sodium laureth sulfate 30g, cocamido propyl betaine 80g, alkane
Base glucosides 10g, sodium cocoyl glycinate 50g, tetrasodium ethylenediamine tetraacetate 1g, citric acid 1g, preservative (phenoxyethanol and methyl
The weight ratio of isothiazolone is 9:1) 9g, essence 10g, water 735g.
Preparation: polysorbate-20, Vegetable oil lipoprotein and essence are mixed by (1), and stir to obtain mixed liquor, standby；
(2) take the water of component weight 35%, add PEG-120 methyl dioleate, be warming up to 70 DEG C of stirrings to complete
CL, continuously adds the water of component weight 25%, and system temperature is down to 55 DEG C, adds sodium laureth sulfate, cocos nucifera oil
Amido propyl betaine, alkyl polyglucoside, sodium cocoyl glycinate, stirring, to being completely dissolved, obtains liquid one, standby；
(3) separately take the water of component weight 25%, after addition inulin stirs, add the liquid one of step (2), stirring
Uniformly, liquid two is obtained；
(4) in step (3) liquid two, add step (1) mixed liquor, stir, add ethylenediaminetetraacetic acid four
Sodium, citric acid, preservative and water, stir.
Embodiment 4, the present invention are without silicon shampoo and preparation thereof
Formula: inulin 30g, almond oil 40g, PEG-60 castor oil hydrogenated 15g, PEG-120 methyl dioleate
12g, sodium laureth sulfate 50g, cocamido propyl betaine 60g, alkyl polyglucoside 20g, sodium cocoyl glycinate
30g, tetrasodium ethylenediamine tetraacetate 5g, citric acid 4g, preservative (phenoxyethanol is 9:1 with the weight ratio of Methylisothiazolinone)
5g, essence 8g, water 721g.
Preparation: PEG-60 castor oil hydrogenated, almond oil and essence are mixed by (1), and stir to obtain mixed liquor, standby；
(2) take the water of component weight 30%, add PEG-120 methyl dioleate, be warming up to 70 DEG C of stirrings to complete
CL, continuously adds the water of component weight 30%, and system temperature is down to 55 DEG C, adds sodium laureth sulfate, cocos nucifera oil
Amido propyl betaine, alkyl polyglucoside, sodium cocoyl glycinate, stirring, to being completely dissolved, obtains liquid one, standby；
(3) separately take the water of component weight 20%, after addition inulin stirs, add the liquid one of step (2), stirring
Uniformly, liquid two is obtained；
(4) in step (3) liquid two, add step (1) mixed liquor, stir, add ethylenediaminetetraacetic acid four
Sodium, citric acid, preservative and water, stir.
Embodiment 5, the present invention are without silicon shampoo and preparation thereof
Formula: inulin 30g, macadamia nut oil 40g, PEG-60 castor oil hydrogenated 15g, PEG-120 methyl dioleate
12g, sodium laureth sulfate 50g, cocamido propyl betaine 60g, alkyl polyglucoside 20g, sodium cocoyl glycinate
30g, tetrasodium ethylenediamine tetraacetate 5g, citric acid 4g, preservative (phenoxyethanol is 9:1 with the weight ratio of Methylisothiazolinone)
5g, essence 8g, water 721g.
Preparation: PEG-60 castor oil hydrogenated, macadamia nut oil and essence are mixed by (1), and stir to obtain mixed liquor, standby；
(2) take the water of component weight 30%, add PEG-120 methyl dioleate, be warming up to 70 DEG C of stirrings to complete
CL, continuously adds the water of component weight 30%, and system temperature is down to 55 DEG C, adds sodium laureth sulfate, cocos nucifera oil
Amido propyl betaine, alkyl polyglucoside, sodium cocoyl glycinate, stirring, to being completely dissolved, obtains liquid one, standby；
(3) separately take the water of component weight 20%, after addition inulin stirs, add the liquid one of step (2), stirring
Uniformly, liquid two is obtained；
(4) in step (3) liquid two, add step (1) mixed liquor, stir, add ethylenediaminetetraacetic acid four
Sodium, citric acid, preservative and water, stir.
Comparative example 1,
Formula: Vegetable oil lipoprotein (almond oil is 2:5 with the weight ratio of macadamia nut oil) 70g, PEG-60 castor oil hydrogenated 15g,
PEG-120 methyl dioleate 12g, sodium laureth sulfate 50g, cocamido propyl betaine 60g, alkyl sugar
Glycosides 20g, sodium cocoyl glycinate 30g, tetrasodium ethylenediamine tetraacetate 2g, citric acid 2g, preservative (phenoxyethanol and the different thiophene of methyl
The weight ratio of oxazoline ketone is 9:1) 5g, essence 8g, water 726g.
Preparation method is with embodiment 1.
Comparative example 2,
Formula: inulin 70g, PEG-60 castor oil hydrogenated 15g, PEG-120 methyl dioleate 12g, lauryl alcohol are poly-
Ether sodium sulfovinate 50g, cocamido propyl betaine 60g, alkyl polyglucoside 20g, sodium cocoyl glycinate 30g, ethylenediamine tetrem
Acid four sodium 2g, citric acid 2g, preservative (phenoxyethanol is 9:1 with the weight ratio of Methylisothiazolinone) 5g, essence 8g, water
726g。
Preparation method is with embodiment 1.
Comparative example 3,
Formula: Polyquaternium-10 3g, Vegetable oil lipoprotein (almond oil is 2:5 with the weight ratio of macadamia nut oil) 40g, PEG-60 hydrogen
Change Oleum Ricini 15g, PEG-120 methyl dioleate 12g, sodium laureth sulfate 50g, cocamidopropyl propyl amide Radix Betae
Alkali 60g, alkyl polyglucoside 20g, sodium cocoyl glycinate 30g, tetrasodium ethylenediamine tetraacetate 2g, citric acid 2g, preservative (benzene oxygen second
The weight ratio of alcohol and Methylisothiazolinone is 9:1) 5g, essence 8g, water 753g.
Preparation method is with embodiment 1.
Test example one, the present invention without silicon shampoo on hair gloss and the impact of carding property
1, experiment material and instrument
The shampoo of the embodiment of the present invention 1 ~ 5, comparative example 1 ~ 3 preparation
Commercially available shampoo without silicon
Topknot is provided by beauty parlor
Vancometer: Germany BYK miniature glossometer A-4430
Tensiometer: Diastron Miniature Tensile Tester(DIA-STRON Limited England)
2, method of testing
2.1, topknot preparation and process
2.1.1 prepared by topknot:
With cord, the topknot of 25cm length is divided into 10g a branch of.Topknot is put in isopropanol and soak 10 minutes, make solvent remove
Go waxiness；Soaking 30 minutes in the 1.6% sodium laureth sulfate solution of 50 DEG C subsequently, soaking solution removes waxiness；With
Tap water rinses topknot to completely removing cleaning mixture；Topknot is placed in 10% lauryl sodium sulfate aqueous solution cleaning again；Finally
Rinsing topknot with tap water, electricity consumption dries up, and topknot is placed in room temperature to be treated second day to use.
2.1.2 topknot processes:
Take 45 bundle topknots, be divided into 9 groups, first use glossometer to measure the gloss index of 9 groups of topknots respectively, determining that 9 groups are sent out
Gloss index zero difference under 95% confidence of bundle, re-uses testing sample.
9 groups of topknots use embodiment 1 ~ 5, comparative example 1 ~ 3 and commercially available shampoo without silicon to process respectively, after topknot moistening,
Often bundle topknot uses 2g shampoo to process, and uses finger (band latex glove) tow sides to rub hair washing bundle 2 minutes.At glass beaker
Middle preparation 2000ml tap water, is immersed in the water the topknot of process, clockwise stirring 2 minutes, and taking-up finger is by unnecessary water
Extrusion, after natural drying, surveys its cardability, and often bundle topknot is combed three times, comb 27 times altogether of 9 bundles, therefrom obtains average combing power.
2.2, cardability measures
Tensiometer computer shows three parameters: slope, young's modulus, area under curve.By comparing below trade-off curve
Long-pending as weighing foundation, often bundle topknot repeats to survey 3 times, averages, and result is recorded in table 1 below.
2.3, gloss measures
Use glossometer to measure the front glossiness of washing of 9 groups of topknots, and process with shampoo, the gloss after natural airing
Degree.Often bundle topknot repeats to survey 3 times, averages, and often group topknot is averaged again, and result is recorded in table 2 below.
3, experimental result
The each shampoo of table 1 comb wet on hair affects result
The each shampoo of table 2 affects result to hair gloss
From upper Tables 1 and 2, by contrast, the average combing power of embodiment 1 ~ 3 is relatively low, and after hair washing, gloss keeps percentage
Rate, more than 100%, illustrates that embodiment 1 ~ 3 shampoo can effectively reduce wet comb resistance, makes hair smooth, improves hair gloss brightness,
Its effect is significantly better than commercially available shampoo without silicon；Wherein the average combing power with embodiment 1 is minimum, and gloss keeps percentage rate
Height, illustrates that embodiment 1 each component synergism is strong, good to the conditioning effect of hair.
The Vegetable oil lipoprotein of embodiment 4 and embodiment 5 is only the one in almond oil and macadamia nut oil, its average combing power and light
Pool keeps percentage rate to be the most slightly weaker than embodiment 1 ~ 3, illustrates that almond oil and macadamia nut oil exist certain synergism, and both make in combination
With better.
Comparative example 1 does not only contain inulin containing Vegetable oil lipoprotein, and comparative example 2 is only imitated without Vegetable oil lipoprotein, its hair conditioning containing inulin
Fruit, all not as good as embodiment 1 ~ 3, illustrates that inulin of the present invention and Vegetable oil lipoprotein exist fine synergism.Comparative example 3 with polyquaternary ammonium salt-
10 substitute inulin, and other components are with embodiment 1, but its effect is substantially not as embodiment 1, and inulin and each component of the present invention are described
Synergism strong.
Test example two, the present invention test without the zest of silicon shampoo
According to irritation test in cosmetics health specification (2007 editions), the shampoo of embodiment 1 is carried out skin
Reaction scoring, concrete operations are as follows:
1, laboratory animal: healthy white rabbit 3, female, 1.8 ~ 2.2kg, skin zero damage.
2, experimental procedure:
24h before test, cuts off the hair of experiment spinal column both sides, white rabbit back, does not damage epidermis, be respectively 3cm about unhairing scope
×3cm.Take tested material (i.e. the shampoo of embodiment 1) 0.5g to be added on 4 layers of gauze of 2.5cm × 2.5cm, be affixed on side skin
Skin, after covering with one layer of oilpaper, with immobilization with adhesive tape, opposite side is blank.Remove tested material after closing 4h, and wash with clear water
Go to remain tested material, in removing after tested material 1,24,48h observe the reaction of recipient site local skin, with matched group position pair
Than rear scoring.Put top average according to each observing time, evaluate this tested material rank to animal skin stimulus intensity.
Experimental result: in test, each observing time puts top average ＜ 0.5, belongs to nonirritant.Therefore embodiment 1 nothing
Silicon shampoo formula is gentle, nothing irritates, and is prevented effectively from the problem causing head pruritus owing to scalp irritates.
Below it is only the preferred embodiment of the present invention, it is noted that it is right that above-mentioned preferred implementation is not construed as
The restriction of the present invention, protection scope of the present invention should be as the criterion with claim limited range.For the art
For those of ordinary skill, without departing from the spirit and scope of the present invention, it is also possible to make some improvement and modification, these change
Enter and modify and also should be regarded as protection scope of the present invention.
Claims (1)
1. the preparation method without silicon shampoo, it is characterised in that comprise the following steps:
(1) solubilizing agent, Vegetable oil lipoprotein and essence being mixed, stir to obtain mixed liquor, standby；
(2) take component weight 25～the water of 35%, add thickening agent, be warming up to 70～75 DEG C and stir to being completely dissolved, continue
Adding component weight 25～the water of 35%, system temperature is down to 55～60 DEG C, adds sodium laureth sulfate, cocos nucifera oil acyl
Amine CAB, alkyl polyglucoside, sodium cocoyl glycinate, stirring, to being completely dissolved, obtains liquid one, standby；
(3) separately take component weight 15～the water of 25%, after addition inulin stirs, add the liquid one of step (2), stirring
Uniformly, liquid two is obtained；
(4) in step (3) liquid two, add step (1) mixed liquor, stir, add tetrasodium ethylenediamine tetraacetate, lemon
Lemon acid, preservative and water, stir；
Described shampoo without silicon is made up of the component of following percentage by weight meter: inulin 3%, Vegetable oil lipoprotein 4%, solubilizing agent
1.5%, thickening agent 1.2%, sodium laureth sulfate 5%, cocamido propyl betaine 6%, alkyl polyglucoside 2%, coconut palm
Oleoyl Glycine sodium 3%, tetrasodium ethylenediamine tetraacetate 0.2%, citric acid 0.2%, preservative 0.5%, essence 0.8%, water
72.6%；
Described Vegetable oil lipoprotein is the compositions of almond oil and macadamia nut oil, and described almond oil is 2:5 with the weight ratio of macadamia nut oil；
Described thickening agent is PEG-120 methyl dioleate；
Described preservative is the compositions of phenoxyethanol and Methylisothiazolinone, described phenoxyethanol and Methylisothiazolinone
Weight ratio be 9:1.
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| CN108709958A (en) * | 2018-06-29 | 2018-10-26 | 珠海伊斯佳科技股份有限公司 | A kind of evaluation method of hair product compliance |
| CN109172403A (en) * | 2018-10-12 | 2019-01-11 | 安徽创领化妆品科技有限公司 | A kind of no silicone oil amino acid shampoo and preparation method thereof |
| CN112263499B (en) * | 2020-11-27 | 2023-05-23 | 佛山市南海东方澳龙制药有限公司 | Animal flavor wave with antibacterial function and preparation method thereof |
| CN113384494B (en) * | 2021-07-15 | 2022-04-22 | 南京泛成生物科技有限公司 | Natural conditioner composition for hair and preparation method and application thereof |
| CN113730298A (en) * | 2021-07-26 | 2021-12-03 | 广东卡迪娜实业有限公司 | Silicon-free shampoo conditioning composition containing biomimetic phospholipids |
| CN114452233A (en) * | 2022-03-28 | 2022-05-10 | 杭州悦萱堂化妆品有限公司 | Oil-control anti-dandruff shampoo |
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| US7157413B2 (en) * | 2002-07-08 | 2007-01-02 | L'oreal | Detergent cosmetic compositions comprising an anionic surfactant, an amphoteric, cationic, and/or nonionic surfactant, and a polysacchardie, and use thereof |
| EP1541117A1 (en) * | 2003-12-12 | 2005-06-15 | Tiense Suikerraffinaderij N.V. | Cosmetic rinse-off compositions comprising inulin-type fructan |
| CN104224575B (en) * | 2014-09-12 | 2017-07-18 | 广州市天吻娇颜化妆品有限公司 | It is a kind of transparent without silicone oil hair-washing composition and preparation method thereof |
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Effective date of registration: 20170912 Address after: 510000 No. 1 North Park Road, Pearl Industrial Zone, Conghua District, Guangdong, Guangzhou Patentee after: One Tian (Guangzhou) living health products Co., Ltd. Address before: 510931 Guangzhou Province, Conghua Mingzhu Industrial Zone, Albert Road, No. 8, No. Patentee before: Walch (Guangzhou) Daily Articles Co., Ltd. |