CN102525846B - Hair care composition and preparation method thereof - Google Patents
Hair care composition and preparation method thereof Download PDFInfo
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- CN102525846B CN102525846B CN201110452085.3A CN201110452085A CN102525846B CN 102525846 B CN102525846 B CN 102525846B CN 201110452085 A CN201110452085 A CN 201110452085A CN 102525846 B CN102525846 B CN 102525846B
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- care composition
- hair care
- hair
- lactate
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- 210000004209 hair Anatomy 0.000 title claims abstract description 186
- 239000000203 mixture Substances 0.000 title claims abstract description 120
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims abstract description 74
- 239000003093 cationic surfactant Substances 0.000 claims abstract description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 claims abstract description 27
- 150000007824 aliphatic compounds Chemical class 0.000 claims abstract description 18
- ODHCTXKNWHHXJC-VKHMYHEASA-M 5-oxo-L-prolinate Chemical compound [O-]C(=O)[C@@H]1CCC(=O)N1 ODHCTXKNWHHXJC-VKHMYHEASA-M 0.000 claims abstract description 16
- 229940071139 pyrrolidone carboxylate Drugs 0.000 claims abstract description 14
- 239000008367 deionised water Substances 0.000 claims abstract description 9
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 9
- 239000008365 aqueous carrier Substances 0.000 claims description 39
- 238000002156 mixing Methods 0.000 claims description 39
- ODHCTXKNWHHXJC-VKHMYHEASA-N 5-oxo-L-proline Chemical class OC(=O)[C@@H]1CCC(=O)N1 ODHCTXKNWHHXJC-VKHMYHEASA-N 0.000 claims description 36
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 36
- 229940001447 lactate Drugs 0.000 claims description 28
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 27
- 150000001875 compounds Chemical class 0.000 claims description 27
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 25
- 229920001296 polysiloxane Polymers 0.000 claims description 23
- 229920006395 saturated elastomer Polymers 0.000 claims description 23
- 229940079889 pyrrolidonecarboxylic acid Drugs 0.000 claims description 22
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims description 21
- 150000003839 salts Chemical class 0.000 claims description 20
- 229910021645 metal ion Inorganic materials 0.000 claims description 17
- 125000004432 carbon atom Chemical group C* 0.000 claims description 16
- 229940045920 sodium pyrrolidone carboxylate Drugs 0.000 claims description 16
- HYRLWUFWDYFEES-UHFFFAOYSA-M sodium;2-oxopyrrolidine-1-carboxylate Chemical compound [Na+].[O-]C(=O)N1CCCC1=O HYRLWUFWDYFEES-UHFFFAOYSA-M 0.000 claims description 16
- 229920000289 Polyquaternium Polymers 0.000 claims description 15
- 229920002907 Guar gum Polymers 0.000 claims description 14
- 125000002091 cationic group Chemical group 0.000 claims description 14
- 229920003086 cellulose ether Polymers 0.000 claims description 14
- 239000000665 guar gum Substances 0.000 claims description 14
- 229960002154 guar gum Drugs 0.000 claims description 14
- 235000010417 guar gum Nutrition 0.000 claims description 14
- 150000001412 amines Chemical class 0.000 claims description 12
- 239000004310 lactic acid Substances 0.000 claims description 12
- 235000014655 lactic acid Nutrition 0.000 claims description 12
- 239000011734 sodium Substances 0.000 claims description 12
- 239000001540 sodium lactate Substances 0.000 claims description 12
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 claims description 11
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 claims description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims description 10
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 claims description 10
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical group C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 claims description 9
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 9
- 239000000194 fatty acid Substances 0.000 claims description 9
- 229930195729 fatty acid Natural products 0.000 claims description 9
- 150000004665 fatty acids Chemical class 0.000 claims description 9
- 229940005581 sodium lactate Drugs 0.000 claims description 9
- 235000011088 sodium lactate Nutrition 0.000 claims description 9
- 150000001298 alcohols Chemical class 0.000 claims description 7
- YSJGOMATDFSEED-UHFFFAOYSA-M behentrimonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C YSJGOMATDFSEED-UHFFFAOYSA-M 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- FQCSIUSICFAMDD-UHFFFAOYSA-N 2-oxopyrrolidine-1-carboxylic acid;sodium Chemical compound [Na].OC(=O)N1CCCC1=O FQCSIUSICFAMDD-UHFFFAOYSA-N 0.000 claims description 5
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 claims description 5
- IUMSDRXLFWAGNT-UHFFFAOYSA-N Dodecamethylcyclohexasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 IUMSDRXLFWAGNT-UHFFFAOYSA-N 0.000 claims description 5
- 239000004166 Lanolin Substances 0.000 claims description 5
- 235000021314 Palmitic acid Nutrition 0.000 claims description 5
- 235000021355 Stearic acid Nutrition 0.000 claims description 5
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 claims description 5
- 229940073639 ceteareth-6 Drugs 0.000 claims description 5
- 229960000541 cetyl alcohol Drugs 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 5
- 229940093629 isopropyl isostearate Drugs 0.000 claims description 5
- 229940039717 lanolin Drugs 0.000 claims description 5
- 235000019388 lanolin Nutrition 0.000 claims description 5
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 claims description 5
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 5
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 5
- 239000004006 olive oil Substances 0.000 claims description 5
- 235000008390 olive oil Nutrition 0.000 claims description 5
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 5
- 239000003755 preservative agent Substances 0.000 claims description 5
- 230000002335 preservative effect Effects 0.000 claims description 5
- NEOZOXKVMDBOSG-UHFFFAOYSA-N propan-2-yl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OC(C)C NEOZOXKVMDBOSG-UHFFFAOYSA-N 0.000 claims description 5
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 5
- 239000008117 stearic acid Substances 0.000 claims description 5
- 229940012831 stearyl alcohol Drugs 0.000 claims description 5
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 claims description 5
- 150000003893 lactate salts Chemical class 0.000 claims description 4
- 238000005303 weighing Methods 0.000 claims description 4
- JVTAAEKCZFNVCJ-REOHCLBHSA-M (S)-lactate Chemical compound C[C@H](O)C([O-])=O JVTAAEKCZFNVCJ-REOHCLBHSA-M 0.000 claims description 3
- JVTAAEKCZFNVCJ-UWTATZPHSA-N D-lactic acid Chemical compound C[C@@H](O)C(O)=O JVTAAEKCZFNVCJ-UWTATZPHSA-N 0.000 claims description 3
- 239000003205 fragrance Substances 0.000 claims description 3
- 125000005210 alkyl ammonium group Chemical group 0.000 claims description 2
- 235000019270 ammonium chloride Nutrition 0.000 claims description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims 1
- WXQWKYFPCLREEY-UHFFFAOYSA-N azane;ethanol Chemical compound N.CCO.CCO.CCO WXQWKYFPCLREEY-UHFFFAOYSA-N 0.000 claims 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 230000003750 conditioning effect Effects 0.000 abstract description 22
- 230000014759 maintenance of location Effects 0.000 abstract description 13
- 239000000126 substance Substances 0.000 abstract description 11
- 206010019049 Hair texture abnormal Diseases 0.000 abstract description 7
- 230000003766 combability Effects 0.000 abstract 1
- 230000003020 moisturizing effect Effects 0.000 description 39
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 36
- 239000003795 chemical substances by application Substances 0.000 description 22
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 21
- 210000003491 skin Anatomy 0.000 description 21
- 235000011187 glycerol Nutrition 0.000 description 16
- -1 polydimethylsiloxanes Polymers 0.000 description 16
- 238000003756 stirring Methods 0.000 description 11
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 239000000178 monomer Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 229920006317 cationic polymer Polymers 0.000 description 5
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 5
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 5
- 239000002453 shampoo Substances 0.000 description 5
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 4
- 239000004909 Moisturizer Substances 0.000 description 4
- 239000002537 cosmetic Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 230000003699 hair surface Effects 0.000 description 4
- 230000001333 moisturizer Effects 0.000 description 4
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 4
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 229940087291 tridecyl alcohol Drugs 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 238000009736 wetting Methods 0.000 description 4
- 208000001840 Dandruff Diseases 0.000 description 3
- 208000003251 Pruritus Diseases 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000000969 carrier Substances 0.000 description 3
- 230000001143 conditioned effect Effects 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 125000004122 cyclic group Chemical group 0.000 description 3
- 238000004945 emulsification Methods 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 230000007794 irritation Effects 0.000 description 3
- 230000007803 itching Effects 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 230000000379 polymerizing effect Effects 0.000 description 3
- 210000004761 scalp Anatomy 0.000 description 3
- 229920002545 silicone oil Polymers 0.000 description 3
- KIUKXJAPPMFGSW-DNGZLQJQSA-N (2S,3S,4S,5R,6R)-6-[(2S,3R,4R,5S,6R)-3-Acetamido-2-[(2S,3S,4R,5R,6R)-6-[(2R,3R,4R,5S,6R)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylic acid Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 KIUKXJAPPMFGSW-DNGZLQJQSA-N 0.000 description 2
- KVZLHPXEUGJPAH-BXRBKJIMSA-N (2s)-2-oxidanylpropanoic acid Chemical group C[C@H](O)C(O)=O.C[C@H](O)C(O)=O KVZLHPXEUGJPAH-BXRBKJIMSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- KVZLHPXEUGJPAH-QRLADXQJSA-N C([C@H](O)C)(=O)O.C([C@H](O)C)(=O)O Chemical compound C([C@H](O)C)(=O)O.C([C@H](O)C)(=O)O KVZLHPXEUGJPAH-QRLADXQJSA-N 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 2
- 239000004902 Softening Agent Substances 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 230000002421 anti-septic effect Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 210000000795 conjunctiva Anatomy 0.000 description 2
- PXEDJBXQKAGXNJ-QTNFYWBSSA-L disodium L-glutamate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](N)CCC([O-])=O PXEDJBXQKAGXNJ-QTNFYWBSSA-L 0.000 description 2
- 230000003648 hair appearance Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000003906 humectant Substances 0.000 description 2
- 229920002674 hyaluronan Polymers 0.000 description 2
- 229960003160 hyaluronic acid Drugs 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 235000013923 monosodium glutamate Nutrition 0.000 description 2
- 231100000956 nontoxicity Toxicity 0.000 description 2
- 230000009965 odorless effect Effects 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 229940073490 sodium glutamate Drugs 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 229920003169 water-soluble polymer Polymers 0.000 description 2
- 230000037303 wrinkles Effects 0.000 description 2
- 201000004384 Alopecia Diseases 0.000 description 1
- SNPLKNRPJHDVJA-ZETCQYMHSA-N D-panthenol Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCCO SNPLKNRPJHDVJA-ZETCQYMHSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 208000032140 Sleepiness Diseases 0.000 description 1
- 206010041349 Somnolence Diseases 0.000 description 1
- XWMGYUIDSBAERU-UHFFFAOYSA-N [Cl-].C(CCCCCCCCCCC)C([NH+](C)C)CCCCCCCCCCCC Chemical compound [Cl-].C(CCCCCCCCCCC)C([NH+](C)C)CCCCCCCCCCCC XWMGYUIDSBAERU-UHFFFAOYSA-N 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000037308 hair color Effects 0.000 description 1
- 230000003676 hair loss Effects 0.000 description 1
- 231100000344 non-irritating Toxicity 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 229940101267 panthenol Drugs 0.000 description 1
- 235000020957 pantothenol Nutrition 0.000 description 1
- 239000011619 pantothenol Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 210000000434 stratum corneum Anatomy 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
The invention relates to the field of daily chemicals and in particular relates to a hair care composition and a preparation method thereof. The hair care composition comprises lactate, pyrrolidone carboxylate, amino-modified siloxane, volatile siloxane and a water-containing carrier; and the water-containing carrier comprises a cationic surfactant, an aliphatic compound, deionized water and other components. The composition disclosed by the invention can provide good moisture retention and excellent conditioning property for hair, such as combability of wet and dry hair and the like.
Description
Technical Field
The invention relates to the field of daily chemicals, and particularly relates to a hair care composition and a preparation method thereof.
Background
People in modern society pay more attention to appearance, pursue fashion and beauty, and the personalized hair color and style are also the targets that fashion people strive to pursue, however, hair is usually damaged by a plurality of factors: including rinsing, drying, heating, combing, styling, perming, dyeing, improper use of shampoos, and exposure to various elements, all of which tend to cause loss of protein, natural oils, other natural moisturizing conditioning components, and wear and loss of hair scales, thus leaving the hair in an unhealthy condition of dryness, roughness, dullness, and the like. Therefore, having a hair care product that restores healthy shine to the hair has become a luxury for many consumers with somnolence.
Various solutions have been developed to address the above problems, including the use of two-in-one hair care, the use of hair conditioners such as rinse-off or leave-on hair care compositions. Although convenient to use, the two-in-one hair care composition has limited moisturizing and conditioning effects on hair, especially damaged hair, because the two-in-one hair care composition is a shampoo, and the main effect is hair cleaning, while the existing rinse-off and leave-on hair care compositions generally have the possibility of enabling the hair to become harder, drier and dull after long-term use by mixing a hair conditioning compound into the hair care composition despite the addition of a conditioning component for conditioning the hair.
The use of conventional cationic surfactants, fatty compounds, polydimethylsiloxanes, silicones and glycerine, propylene glycol etc. as hair conditioning agents is well known in the art, as proposed by the company P & G in CN1098901 at the end of the last century by formulating hair care compositions with non-volatile silicone fluids, non-volatile spreading agents and suitable carriers, and it was later found that with such compositions over time, the hair becomes greasy, messy and poorly conditioned with excessive deposition of volatile silicone etc. ingredients on the hair. In patent CN102138882A, didodecyltrimethylammonium chloride and the like are selected as cationic surfactants, silicone oil conditioning, panthenol and the like are selected for moisturizing, but the moisturizing performance of the compositions is limited, and the compositions are easy to irritate hair and cause scalp itching and dandruff.
Disclosure of Invention
The invention provides a hair care composition and a preparation method thereof, which can improve the moisture retention and conditioning performance of the hair care composition.
The present invention provides a hair care composition comprising a lactate salt, a pyrrolidone carboxylate salt, an amino-modified silicone, a volatile silicone, an aqueous carrier;
the weight of the lactate accounts for 0.01-10% of the total weight of the hair care composition;
the weight of the pyrrolidone carboxylic acid salt accounts for 0.01-10% of the total weight of the hair care composition;
the weight of the amino modified siloxane accounts for 0.01-10% of the total weight of the hair care composition;
the weight of the volatile siloxane accounts for 0.01-20% of the total weight of the hair care composition;
the weight of the aqueous carrier is 20-90% of the total weight of the hair care composition.
The main components of two natural skin moisturizing factors (NMF) of lactate and pyrrolidone carboxylate are compounded, and the moisturizing effect is better than that of the conventional moisturizing agent represented by glycerol.
The amino modified siloxane and the volatile siloxane are used in a composite way, can be effectively deposited on hair, and have good film forming property and good hand feeling after washing.
Can provide hair with more excellent moisture retention and conditioning effect.
The weight of said lactate salt is preferably 0.1% to 2% of the total weight of said hair care composition;
and/or the presence of a gas in the gas,
the lactate preferably comprises L- (+) -lactate or D- (-) -lactate or a mixture of both; preferably Na including lactic acid+、K+、Cu2+、Fe2+、Fe3+One or more metal ion salts or triethanolamine salt of lactic acid, preferably monovalent metal ion salt of lactic acid, and more preferably sodium lactate.
The lactate is L- (+) -lactate (L-lactate) or D- (-) -lactate (D-lactate) or their mixture, preferably Na-lactate+、K+、Cu2+、Fe2+、Fe3+One or more metal ion salts or triethanolamine salt of lactic acid, preferably monovalent metal ion salt of lactic acid, especially Na of lactic acid+And (3) salt.
The addition amount of lactate is as follows: the weight of the hair care composition accounts for 0.01-10% of the total weight of the hair care composition, such as: 0.01%, 0.05%, 0.1%, 0.2%, 0.4%, 0.6%, 0.65%, 0.8%, 1%, 1.5%, 2%, 3%, 5%, 7%, 8%, 9%, 10% or a range between any two of these values, preferably 0.1% to 10%, more preferably 0.1% to 5%, especially 0.1% to 2%.
Sodium lactate with molecular formula C3H5NaO3It is colorless or almost colorless transparent liquid, and can be mixed with water, ethanol, and glycerol. It is a natural moisturizing factor in human skin stratum corneum, is widely used as moistening agent of skin care products, can form a hydrated film with other chemical components to prevent skin moisture from volatilizing and enable skin to be in a state of being in a normal stateThe product is easy to be wetted, and wrinkles are prevented; compared with other moisturizing agents, the moisturizing agent is less influenced by humidity change, and can play a role in high-efficiency moisturizing under low-temperature and low-humidity states.
The pyrrolidone carboxylic acid salt is preferably present in an amount of 0.1% to 2% by weight of the total hair care composition;
and/or the presence of a gas in the gas,
the pyrrolidone carboxylic acid salt preferably comprises L- (+) -pyrrolidone carboxylic acid salt or D- (-) -pyrrolidone carboxylic acid salt or a mixture of both; more preferably Na including pyrrolidone carboxylic acid+、K+、Cu2+、Fe2+、Fe3+One or more metal ion salts of pyrrolidone carboxylic acid or triethanolamine salt of pyrrolidone carboxylic acid, preferably monovalent metal ion salt of pyrrolidone carboxylic acid, more preferably sodium pyrrolidone carboxylic acid.
The pyrrolidone carboxylic acid salt is selected from L- (+) -pyrrolidone carboxylic acid salt (i.e. levorotatory pyrrolidone carboxylic acid salt) or D- (-) -pyrrolidone carboxylic acid salt (i.e. dextrorotatory pyrrolidone carboxylic acid salt) or their mixture, preferably Na of pyrrolidone carboxylic acid+、K+、Cu2+、Fe2+、Fe3+One or more metal ion salts of pyrrolidone carboxylic acid or triethanolamine salt of pyrrolidone carboxylic acid, more preferably monovalent metal ion salts of pyrrolidone carboxylic acid salt, especially sodium pyrrolidone carboxylic acid.
The addition amount of the pyrrolidone carboxylate is as follows: the weight of the hair care composition accounts for 0.01-10% of the total weight of the hair care composition, such as: 0.01%, 0.05%, 0.1%, 0.2%, 0.4%, 0.6%, 0.65%, 0.8%, 1%, 1.5%, 2%, 3%, 5%, 7%, 8%, 9%, 10% or a range between any two of these values, preferably 0.1% to 10%, more preferably 0.1% to 5%, especially 0.1% to 2%.
Sodium pyrrolidone carboxylate (PCA-Na), also known as pyroglutamic sodium glutamate, is colorless, odorless, transparent and slightly salty liquid, is a main component of Natural Moisturizing Factors (NMF) in skin, has a very strong moisturizing effect, has far stronger efficacy than glycerin, propylene glycol, sorbitol and the like, is equivalent to hyaluronic acid, has good synergy with other moisturizing agents, and has good effect when being mixed for use. The amount used in cosmetics is generally from 1% to 10%. The sodium pyrrolidone carboxylate has very low viscosity, does not have the heavy sticky feeling of other humectants such as glycerin, has very good safety, does not irritate eye conjunctiva at high concentration, and is very safe to skin. In cosmetics, sodium pyrrolidone carboxylate is mainly used as a moisturizing agent, a conditioning agent and a softening agent for skin and hair, and can make skin wet, soft and elastic and make hair glossy and antistatic.
The weight of the amino-modified silicone is preferably 0.5-5% of the total weight of the hair care composition;
and/or the presence of a gas in the gas,
the molecular weight of the amino-modified siloxane is preferably 200-1000000, more preferably 500-400000;
and/or the presence of a gas in the gas,
the amine value of the amino-modified siloxane is 0.05 to 0.8, preferably 0.1 to 0.5.
The amino modified siloxane comprises amino modified siloxane emulsion and/or large-particle-size amino modified siloxane; the weight of the amino-modified silicone of the present invention is 0.1% to 10% of the total weight of the hair care composition, such as: 0.1%, 0.2%, 0.4%, 0.5%, 0.6%, 0.65%, 0.8%, 1%, 1.5%, 2%, 3%, 5%, 7%, 8%, 9%, 10%, or a range between any two of these values, preferably 1% to 8%, more preferably 0.5% to 5%; the molecular weight of the amino-modified siloxane of the present invention is 200-1000000, such as: 200. 350, 500, 700, 1000, 5000, 10000, 50000, 100000, 300000, 400000, 700000, 1000000 or a range between any two of these, preferably 500-400000.
The amine number of the amino-modified silicone is 0.05 to 0.8, such as: 0.05, 0.08, 0.1, 0.2, 0.4, 0.5, 0.8 or a range between any two of these values, preferably 0.1 to 0.5, it being noted that: the amine number is the number of milligrams of perchloric acid and equivalent sodium hydroxide required to neutralize 1 gram of basic amine. Because of the low amine value, moderate molecular weight and low volatile siloxane molecular weight of the amino modified siloxane, the amino modified siloxane can not be excessively deposited on the hair after long-term use, and the hair can not become more greasy and easy to dirty.
The amino modified siloxane has low surface tension, strong polarity of amino on a side chain and positive charge, can interact with the hair surface with negative charge, and is very firmly adsorbed on the hair surface, so that the friction coefficient between hairs is reduced, and the hairs are endowed with good smoothness, flexibility and washability; and the exposed oily groups make the hair hydrophobic and easy to dry, can increase the gloss and the antistatic property of the hair, thereby having the function of improving and repairing the hair quality, and the siloxane compound can provide smooth feeling and softness on the dry hair.
The volatile siloxane preferably comprises a polydimethylsiloxane having an average of about 4 to 5 repeating units per molecule, preferably: one or more of octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane and dodecamethylcyclohexasiloxane;
and/or the presence of a gas in the gas,
the weight of the volatile silicone is preferably 0.5% to 10% of the total weight of the hair care composition.
Volatile silicones include cyclic volatile low molecular weight polydimethylsiloxanes, preferably polydimethylcyclosiloxanes having an average of about 4 to 5 repeat units per molecule, such as: one or more of octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane and dodecamethylcyclohexasiloxane. Boiling at about 35-250 ℃ under atmospheric pressure. From 0.01% to 20%, preferably from 0.01% to 10%, more preferably from 0.5% to 10%,
volatile silicones are generally colorless, transparent, thin liquids, low molecular weight, and volatile. The hair shampoo has the advantages of easy emulsification, no toxicity, no irritation, good compatibility, accelerated hair dryness, and easy combing and luster increase.
The aqueous carrier preferably comprises a cationic surfactant, an aliphatic compound and deionized water;
wherein,
the cationic surfactant preferably comprises quaternary ammonium salts containing 12 to 22 carbon atoms, preferably alkyl ammonium chlorides containing 12 to 22 carbon atoms, more preferably: one or more of behenyl trimethyl ammonium chloride, octadecyl trimethyl ammonium chloride and octadecyl tertiary amine cations;
the aliphatic compound preferably comprises a saturated straight-chain alcohol or a saturated branched-chain alcohol containing 8 to 22 carbon atoms or a derivative thereof, and/or a fatty acid containing 8 to 22 carbon atoms or a derivative thereof; preferably: the saturated linear alcohol or derivative thereof includes: one or more of cetyl alcohol, stearyl alcohol, ceteareth-6, PPG-15 stearyl alcohol ether, said saturated branched alcohols and derivatives thereof including: one or more of lanolin alcohol, isostearyl alcohol, pentaerythritol tetraester and tridecyl alcohol polyether-6, wherein the fatty acid and its derivative comprises one or more of myristic acid, palmitic acid, stearic acid, monostearate, isopropyl isostearate and olive oil ester;
the weight of the aqueous carrier is preferably 50% to 90% of the total weight of the hair care composition.
The weight of the cationic surfactant is preferably 0.1-8% of the total weight of the hair care composition;
and/or the presence of a gas in the gas,
the weight of the fatty compound is preferably 0.1-10% of the total weight of the hair care composition.
The aqueous carrier preferably further comprises: one or more of cationic guar gum, polyquaternium and cellulose ether, wherein the cationic guar gum, the polyquaternium and the cellulose ether are water-soluble high molecular compounds, and the polyquaternium preferably comprises polyquaternium-4 and/or polyquaternium-10.
The aqueous carrier used in the present invention is selected from the group consisting of those which do not damage hair, do not adversely affect hair, and do not irritate the skin, and is used in the daily chemical field, and is commonly used in hair care compositions, and includes solvents (water), other carriers, or other carrier ingredients commonly used in hair care compositions.
The aqueous carrier is preferably present in an amount of from 20% to 90%, such as from 20%, 40%, 50%, 60%, 80%, 90% or a range between any two of these, preferably from 50% to 90%, by weight of the total hair care composition.
The solvent of the aqueous carrier is preferably deionized water, which does not irritate the skin and introduce other impurities.
The aqueous carrier used in the present invention further comprises a cationic surfactant and a fatty compound;
the content of the cationic surfactant is preferably 1% -8% of the total weight of the hair care composition, such as: 1%, 2%, 3%, 4%, 5%, 6%, 7%, 8%, or a range between any two values therein; the cationic surfactant is selected from quaternary ammonium salts including alkylammonium chlorides, the alkyl group containing from 12 to 22 carbon atoms, such as: one or more of behenyl trimethyl ammonium chloride, stearyl trimethyl ammonium chloride, and stearyl tertiary ammonium cation.
Wherein the aliphatic compound is selected from saturated straight-chain alcohol or saturated branched-chain alcohol containing 8-22 carbon atoms, and/or fatty acid containing 8-22 carbon atoms, and/or derivatives of any one of saturated branched-chain alcohol, saturated branched-chain alcohol and fatty acid, wherein the saturated straight-chain alcohol or derivatives thereof comprise: one or more of cetyl alcohol, stearyl alcohol, ceteareth-6, PPG-15 stearyl alcohol ether, said saturated branched alcohols and derivatives thereof including: lanolin alcohol, isostearyl alcohol, pentaerythritol tetraol, tridecyl alcohol polyether-6, and one or more of myristic acid, palmitic acid, stearic acid, monostearate, isopropyl isostearate, and olive oil ester.
The aqueous carrier contains, in addition to the cationic surfactant and the fatty compound, a cationic polymer comprising: one or more of cationic guar gum, polyquaternium (such as polyquaternium-4 and polyquaternium-10) and cellulose ether.
It should be noted that the cationic guar gum, polyquaternium and cellulose ether are all cationic polymers and water-soluble high molecular compounds, and the polymers mentioned herein shall include substances produced by polymerizing one monomer, substances produced by polymerizing two monomers, or substances produced by polymerizing multiple monomers, and naturally occurring polymers.
The hair care composition is preferably a "leave-on or rinse-off" conditioner.
The invention also provides a preparation method of the hair care composition, which comprises the following steps:
respectively weighing lactate, pyrrolidone carboxylate, amino modified siloxane, volatile siloxane and a water-containing carrier according to parts by weight;
preparing an aqueous carrier according to a set mode;
adding lactate at 60-75 deg.C and mixing;
adding amino modified siloxane at the temperature of 60-75 ℃ and mixing;
adding sodium pyrrolidone carboxylate at 40-50 deg.C and mixing;
adding volatile siloxane at 40-50 deg.C, and mixing.
The aqueous carrier preferably comprises: a water-soluble polymer compound, a cationic surfactant, and an aliphatic compound; then, said preparing an aqueous carrier in a set manner preferably comprises: putting the water-soluble high molecular compound into water and mixing; adding a surfactant and mixing at the temperature of 75-90 ℃; adding an aliphatic compound and mixing at a temperature of 75-90 ℃, wherein the water-soluble high molecular compound preferably comprises: one or more of cationic guar gum, polyquaternium, cellulose ether;
and/or the presence of a gas in the gas,
after the adding and mixing of the sodium pyrrolidone carboxylate at the temperature of 40 ℃ to 50 ℃ and after the adding and mixing of the volatile siloxane at the temperature of 40 ℃ to 50 ℃, the preparation method preferably further comprises: adding antiseptic and essence at 40-50 deg.C, and mixing.
The invention provides a hair care composition and a preparation method thereof, which can achieve the following beneficial effects:
the invention comprises the following steps: lactate, pyrrolidone carboxylate, amino modified siloxane and volatile siloxane, which can provide hair with more excellent moisture retention and conditioning. The moisturizing effect of the single moisturizing agent is several times that of the traditional glycerin and propylene glycol moisturizing agents, the moisturizing effect is better than that of the conventional moisturizing agent represented by glycerin, the moisturizing effect of the moisturizing agent is better than that of the conventional moisturizing agent represented by glycerin, the moisturizing agent can reduce the stimulation of a cationic surfactant to the scalp, reduce the phenomena of itching and scurf, and can play a very good conditioning effect on the hair, and the softness and the glossiness of the damaged hair are improved, which cannot be achieved by the traditional glycerin and propylene glycol moisturizing agent. The amino modified siloxane and the volatile siloxane are compounded with two types of conditioners with different molecular weights, so that damaged hair is conditioned, and the dryness, wet combing property, glossiness and softness of the hair are improved, so that the damaged hair is more effectively repaired. The hair care composition can be effectively deposited on hair, has good film forming property, good hand feeling after washing, smooth feeling when wetting hair, flexibility and moistening feeling when drying hair, and provides good moisture retention and excellent conditioning property, such as combing property of dry and wet hair.
Detailed Description
The technical solutions of the embodiments of the present invention will be described clearly and completely with reference to the accompanying drawings, and it is to be understood that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The present invention provides a hair care composition comprising a lactate salt, a pyrrolidone carboxylate salt, an amino-modified silicone, a volatile silicone, an aqueous carrier;
the weight of the lactate accounts for 0.01-10% of the total weight of the hair care composition;
the weight of the pyrrolidone carboxylic acid salt accounts for 0.01-10% of the total weight of the hair care composition;
the weight of the amino modified siloxane accounts for 0.01-10% of the total weight of the hair care composition;
the weight of the volatile siloxane accounts for 0.01-20% of the total weight of the hair care composition;
the weight of the aqueous carrier is 20-90% of the total weight of the hair care composition.
The aqueous carrier is a general term of manufacturers of hair care compositions in the field of daily chemicals, and refers to the most basic components required to be contained in the hair care composition, including solvents (water), surfactants, fatty compounds, and the like.
The main components of two natural skin moisturizing factors (NMF) of lactate and pyrrolidone carboxylate are compounded, and the moisturizing effect is better than that of the conventional moisturizing agent represented by glycerol.
The amino modified siloxane and the volatile siloxane are used in a composite way, can be effectively deposited on hair, and have good film forming property and good hand feeling after washing.
Can provide hair with more excellent moisture retention and conditioning effect.
The hair care compositions of the present invention are leave-on or rinse-off hair care conditioners.
It is understood that "leave-on" refers to the use of the hair care composition directly on the hair and then removed without rinsing with water; by "rinse-off" is meant that the hair care composition is applied and then rinsed off with water.
The method comprises the following specific steps:
the hair care composition provided by the invention comprises the following components: lactate, pyrrolidone carboxylate, amino modified siloxane, volatile siloxane, aqueous carrier, and the like.
Wherein,
lactate:
the lactate is L- (+) -lactate (L-lactate) or D- (-) -lactate (D-lactate) or their mixture, preferably Na-lactate+、K+、Cu2+、Fe2+、Fe3+One or more metal ion salts or triethanolamine salt of lactic acid, preferably monovalent metal ion salt of lactic acid, especially Na of lactic acid+And (3) salt.
The addition amount of lactate is as follows: the weight of the hair care composition accounts for 0.01-10% of the total weight of the hair care composition, such as: 0.01%, 0.05%, 0.1%, 0.2%, 0.4%, 0.6%, 0.65%, 0.8%, 1%, 1.5%, 2%, 3%, 5%, 7%, 8%, 9%, 10% or a range between any two of these values, preferably 0.1% to 10%, more preferably 0.1% to 5%, especially 0.1% to 2%.
Sodium lactate with molecular formula C3H5NaO3It is colorless or almost colorless transparent liquid, and can be mixed with water, ethanol, and glycerol. It is a human skinThe natural moisturizing factor in the horny layer of the skin is widely used as a moisturizer of skin care products, can form a hydrated film with other chemical components to prevent the water of the skin from volatilizing, enables the skin to be in a relaxed and moist state and prevents wrinkles from generating; compared with other moisturizing agents, the moisturizing agent is less influenced by humidity change, and can play a role in high-efficiency moisturizing under low-temperature and low-humidity states.
Pyrrolidone carboxylic acid salt:
the pyrrolidone carboxylic acid salt is selected from L- (+) -pyrrolidone carboxylic acid salt (i.e. levorotatory pyrrolidone carboxylic acid salt) or D- (-) -pyrrolidone carboxylic acid salt (i.e. dextrorotatory pyrrolidone carboxylic acid salt) or their mixture, preferably Na of pyrrolidone carboxylic acid+、K+、Cu2+、Fe2+、Fe3+One or more metal ion salts of pyrrolidone carboxylic acid or triethanolamine salt of pyrrolidone carboxylic acid, more preferably monovalent metal ion salts of pyrrolidone carboxylic acid salt, especially sodium pyrrolidone carboxylic acid.
The addition amount of the pyrrolidone carboxylate is as follows: the weight of the hair care composition accounts for 0.01-10% of the total weight of the hair care composition, such as: 0.01%, 0.05%, 0.1%, 0.2%, 0.4%, 0.6%, 0.65%, 0.8%, 1%, 1.5%, 2%, 3%, 5%, 7%, 8%, 9%, 10% or a range between any two of these values, preferably 0.1% to 10%, more preferably 0.1% to 5%, especially 0.1% to 2%.
Sodium pyrrolidone carboxylate (PCA-Na), also known as pyroglutamic sodium glutamate, is colorless, odorless, transparent and slightly salty liquid, is a main component of Natural Moisturizing Factors (NMF) in skin, has a very strong moisturizing effect, has far stronger efficacy than glycerin, propylene glycol, sorbitol and the like, is equivalent to hyaluronic acid, has good synergy with other moisturizing agents, and has good effect when being mixed for use. The amount used in cosmetics is generally from 1% to 10%. The sodium pyrrolidone carboxylate has very low viscosity, does not have the heavy sticky feeling of other humectants such as glycerin, has very good safety, does not irritate eye conjunctiva at high concentration, and is very safe to skin. In cosmetics, sodium pyrrolidone carboxylate is mainly used as a moisturizing agent, a conditioning agent and a softening agent for skin and hair, and can make skin wet, soft and elastic and make hair glossy and antistatic.
Amino-modified siloxane:
the amino modified siloxane comprises amino modified siloxane emulsion and/or large-particle-size amino modified siloxane; the weight of the amino-modified silicone of the present invention is 0.1% to 10% of the total weight of the hair care composition, such as: 0.1%, 0.2%, 0.4%, 0.5%, 0.6%, 0.65%, 0.8%, 1%, 1.5%, 2%, 3%, 5%, 7%, 8%, 9%, 10%, or a range between any two of these values, preferably 1% to 8%, more preferably 0.5% to 5%; the molecular weight of the amino-modified siloxane of the present invention is 200-1000000, such as: 200. 350, 500, 700, 1000, 5000, 10000, 50000, 100000, 300000, 400000, 700000, 1000000 or a range between any two of these, preferably 500-400000.
The amine number of the amino-modified silicone is 0.05 to 0.8, such as: 0.05, 0.08, 0.1, 0.2, 0.4, 0.5, 0.8 or a range between any two of these values, preferably 0.1 to 0.5, it being noted that: the amine number is the number of milligrams of perchloric acid and equivalent sodium hydroxide required to neutralize 1 gram of basic amine. Because of the low amine value, moderate molecular weight and low volatile siloxane molecular weight of the amino modified siloxane, the amino modified siloxane can not be excessively deposited on the hair after long-term use, and the hair can not become more greasy and easy to dirty.
The amino modified siloxane has low surface tension, strong polarity of amino on a side chain and positive charge, can interact with the hair surface with negative charge, and is very firmly adsorbed on the hair surface, so that the friction coefficient between hairs is reduced, and the hairs are endowed with good smoothness, flexibility and washability; and the exposed oily groups make the hair hydrophobic and easy to dry, can increase the gloss and the antistatic property of the hair, thereby having the function of improving and repairing the hair quality, and the siloxane compound can provide smooth feeling and softness on the dry hair.
Volatile siloxane:
volatile silicones include cyclic volatile low molecular weight polydimethylsiloxanes, preferably polydimethylcyclosiloxanes having an average of about 4 to 5 repeat units per molecule, such as: one or more of octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane and dodecamethylcyclohexasiloxane. Boiling at about 35-250 ℃ under atmospheric pressure. From 0.01% to 20%, preferably from 0.01% to 10%, more preferably from 0.5% to 10%,
volatile silicones are generally colorless, transparent, thin liquids, low molecular weight, and volatile. The hair shampoo has the advantages of easy emulsification, no toxicity, no irritation, good compatibility, accelerated hair dryness, and easy combing and luster increase.
An aqueous carrier:
the aqueous carrier used in the present invention is selected from the group consisting of those which do not damage hair, do not adversely affect hair, and do not irritate the skin, and is used in the daily chemical field, and is commonly used in hair care compositions, and includes solvents (water), other carriers, or other carrier ingredients commonly used in hair care compositions.
The aqueous carrier is preferably present in an amount of from 20% to 90%, such as from 20%, 40%, 50%, 60%, 80%, 90% or a range between any two of these, preferably from 50% to 90%, by weight of the total hair care composition.
The solvent of the aqueous carrier is preferably deionized water, which does not irritate the skin and introduce other impurities.
The aqueous carrier used in the present invention further comprises a cationic surfactant and a fatty compound;
the content of the cationic surfactant is preferably 1% -8% of the total weight of the hair care composition, such as: 1%, 2%, 3%, 4%, 5%, 6%, 7%, 8%, or a range between any two values therein; the cationic surfactant is selected from quaternary ammonium salts including alkylammonium chlorides, the alkyl group containing from 12 to 22 carbon atoms, such as: one or more of behenyl trimethyl ammonium chloride, stearyl trimethyl ammonium chloride, and stearyl tertiary ammonium cation.
Wherein the aliphatic compound is selected from saturated straight-chain alcohol or saturated branched-chain alcohol containing 8-22 carbon atoms, and/or fatty acid containing 8-22 carbon atoms, and/or derivatives of any one of saturated branched-chain alcohol, saturated branched-chain alcohol and fatty acid, wherein the saturated straight-chain alcohol or derivatives thereof comprise: one or more of cetyl alcohol, stearyl alcohol, ceteareth-6, PPG-15 stearyl alcohol ether, said saturated branched alcohols and derivatives thereof including: lanolin alcohol, isostearyl alcohol, pentaerythritol tetraol, tridecyl alcohol polyether-6, and one or more of myristic acid, palmitic acid, stearic acid, monostearate, isopropyl isostearate, and olive oil ester.
The aqueous carrier contains, in addition to the cationic surfactant and the fatty compound, a cationic polymer comprising: one or more of cationic guar gum, cellulose ether and polyquaternium (such as polyquaternium-4 and polyquaternium-10), wherein the cationic guar gum, the polyquaternium and the cellulose ether are water-soluble high molecular compounds.
It should be noted that the present invention herein refers to cationic guar gum, polyquaternium, cellulose ether as cationic polymers, and the references herein to polymers shall include materials resulting from the polymerization of one monomer, materials resulting from the polymerization of two monomers, or materials resulting from the polymerization of multiple monomers, as well as naturally occurring polymers.
The invention also provides a preparation method of the hair care composition, which comprises the following steps:
step 101, respectively weighing lactate, pyrrolidone carboxylate, amino modified siloxane, volatile siloxane and a water-containing carrier according to parts by weight;
102, preparing an aqueous carrier according to a set mode;
the setting method may be a method for preparing an aqueous carrier in various conventional hair care compositions (conditioners).
103, adding lactate at the temperature of 60-75 ℃ and mixing;
104, adding amino modified siloxane at the temperature of 60-75 ℃ and mixing;
105, adding sodium pyrrolidone carboxylate at the temperature of 40-50 ℃ and mixing;
step 106, adding volatile siloxane and mixing at a temperature of 40 ℃ to 50 ℃.
Wherein, the order of step 103 and step 104 can be exchanged; the order of steps 105 and 106 may be reversed.
The aqueous carrier preferably comprises: a water-soluble polymer compound, a cationic surfactant, and an aliphatic compound; then, said preparing an aqueous carrier in a set manner preferably comprises: putting the water-soluble high molecular compound into water and mixing; adding a cationic surfactant and mixing at the temperature of 75-90 ℃; adding an aliphatic compound and mixing at a temperature of 75-90 ℃, wherein the water-soluble high molecular compound comprises: one or more of cationic guar gum, polyquaternium, cellulose ether;
and/or the presence of a gas in the gas,
after the adding and mixing of the sodium pyrrolidone carboxylate at the temperature of 40 ℃ to 50 ℃ and after the adding and mixing of the volatile siloxane at the temperature of 40 ℃ to 50 ℃, the preparation method preferably further comprises: adding antiseptic and essence at 40-50 deg.C, and mixing.
Next, the present invention will be described in detail by way of a specific example 1 for the preparation of the hair care composition of the present invention:
step 201, respectively weighing lactate, pyrrolidone carboxylate, amino modified siloxane, volatile siloxane and a water-containing carrier according to parts by weight;
wherein the lactate is present in an amount of 0.01% to 10%, preferably 0.1% to 10%, more preferably 0.1% to 5%, especially 0.1% to 2% by weight of the total hair care composition. Wherein the lactate comprises L- (+) -lactate or D- (-) -lactate or a mixture of both; preferably Na including lactic acid+、K+、Cu2+、Fe2+、Fe3+One or more metal ion salts or triethanolamine salt of lactic acid, especially sodium lactate, with molecular formula C3H5NaO3。
The pyrrolidone carboxylic acid salt is present in an amount of from 0.01% to 10%, preferably from 0.1% to 10%, more preferably from 0.1% to 5%, especially from 0.1% to 2% by weight of the total hair care composition. Wherein the pyrrolidone carboxylic acid salt is selected from L- (+) -pyrrolidone carboxylic acid salt (i.e. levorotatory pyrrolidone carboxylic acid salt) or D- (-) -pyrrolidone carboxylic acid salt (i.e. dextrorotatory pyrrolidone carboxylic acid salt) or their mixture, preferably Na of pyrrolidone carboxylic acid+、K+、Cu2+、Fe2+、Fe3+One or more metal ion salts of pyrrolidone carboxylic acid or triethanolamine salt of pyrrolidone carboxylic acid, more preferably monovalent metal ion salts of pyrrolidone carboxylic acid salt, especially sodium pyrrolidone carboxylic acid.
The content of the amino-modified siloxane is 0.1-10%, preferably 0.5-5% of the total weight of the hair care composition, the amino-modified siloxane comprises amino-modified siloxane emulsion and/or amino-modified siloxane with large particle size, the molecular weight of the amino-modified siloxane is about 200-1000000, preferably 500-400000, and the amine value of the amino-modified siloxane is 0.05-0.8, preferably 0.1-0.5.
Volatile silicones are present in amounts of 0.01% to 20%, preferably 0.01% to 10%, more preferably 0.5% to 10% by weight of the total hair care composition, and include cyclic volatile low molecular weight polydimethylsiloxanes, preferably polydimethylcyclosiloxanes having an average of about 4 to 5 repeating units per molecule, such as: one or more of octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane and dodecamethylcyclohexasiloxane.
The aqueous carrier is 20% to 90%, preferably 50% to 90% of the total weight of the hair care composition.
The solvent in the aqueous carrier is preferably deionized water, non-irritating, and does not introduce other impurities, and is present in an amount of 20% to 90%, preferably 50% to 90%, by weight of the hair care composition. The cationic surfactant is preferably present in the aqueous carrier in an amount of from 1% to 8% by weight of the total hair care composition and is selected from quaternary ammonium salts, such as behenyltrimethylammonium chloride, octadecyltrimethylammonium chloride, octadecyltriethylammonium cations, and the like. The aliphatic compound in the aqueous carrier is selected from saturated linear or branched alcohols containing 8 to 22 carbon atoms, and/or fatty acids containing 8 to 22 carbon atoms, and/or derivatives thereof, wherein the saturated linear alcohols or derivatives thereof include: one or more of cetyl alcohol, stearyl alcohol, ceteareth-6, PPG-15 stearyl alcohol ether, said saturated branched alcohols and derivatives thereof including: lanolin alcohol, isostearyl alcohol, pentaerythritol tetraol, tridecyl alcohol polyether-6, and one or more of myristic acid, palmitic acid, stearic acid, monostearate, isopropyl isostearate, and olive oil ester. The aqueous carrier also contains a cationic polymer comprising: one or more of cationic guar gum, polyquaternium (such as polyquaternium-4 and polyquaternium-10) and cellulose ether.
Step 202, adding a water-soluble high molecular compound in a water-containing carrier into deionized water, stirring and mixing;
the water-soluble high molecular compound and the deionized water are fully mixed, and the mixing speed is increased.
The water-soluble high molecular compound comprises various high molecular compounds with good water solubility in an aqueous carrier, wherein the water-soluble high molecular compounds comprise one or more of cationic guar gum, polyquaternium and cellulose ether.
Step 203, heating to 75-90 ℃, adding the behenyl trimethyl ammonium chloride cationic surfactant at a constant temperature, stirring and mixing;
since the cationic surfactant has the best solubility and the best performance at a temperature of 75 ℃ to 90 ℃, it is necessary to first raise the temperature and then add the cationic surfactant at a desired temperature.
The temperature is preferably 83 DEG C
Step 204, adding the hexadecanol/octadecanol aliphatic compound at the constant temperature of 75-90 ℃, stirring and mixing;
since the aliphatic compound has the best solubility and the best performance at a temperature of 75 ℃ to 90 ℃, it is necessary to first raise the temperature and then add the aliphatic compound at a desired temperature.
The temperature is preferably 83 DEG C
Wherein, the addition of the cationic surfactant or the aliphatic compound at the temperature of 60-75 ℃ does not affect the care effect of the hair care composition, and the sequence of the step 203 and the step 204 can be changed.
Step 205, stirring at a constant temperature of 75-90 ℃ for about 30 minutes;
stirring at constant temperature can promote the dissolution and sufficient emulsification of the cationic surfactant, the aliphatic compound and the water-soluble high molecular compound in the deionized water.
Step 206, cooling to 60-75 ℃, adding sodium lactate at constant temperature, stirring and mixing;
since sodium lactate exhibits the best solubility and performance at a temperature of 60 ℃ to 75 ℃, it is necessary to first lower the temperature and then add sodium lactate at the desired temperature.
Step 207, adding amino modified siloxane at the constant temperature of 60-75 ℃, stirring and mixing;
since the amino-modified silicone has the best solubility and the best performance at a temperature of 60 ℃ to 75 ℃, the temperature needs to be reduced first, and then the amino-modified silicone is added at a required temperature.
Wherein step 206 and step 207 can be reversed since neither the addition of sodium lactate first nor the addition of the amino-modified silicone first at a temperature of 60 ℃ to 75 ℃ affects the conditioning effect of the hair care composition.
Step 208, continuously cooling to 40-50 ℃, adding the sodium pyrrolidone carboxylate at constant temperature, stirring and mixing;
since the solubility of sodium pyrrolidone carboxylate is best and the performance is best at a temperature of 40 ℃ to 50 ℃, it is necessary to first lower the temperature and then add sodium pyrrolidone carboxylate at a desired temperature.
The temperature is preferably 50 ℃.
Step 209, adding volatile siloxane at the constant temperature of 40-50 ℃, stirring and mixing;
since the solubility of the volatile siloxane is best and the performance is best at temperatures between 40 ℃ and 50 ℃, it is necessary to first cool and then add the volatile siloxane at the desired temperature.
The temperature is preferably 50 ℃.
Wherein, the addition of the sodium pyrrolidone carboxylate or the volatile siloxane at the temperature of 50-60 ℃ does not affect the care effect of the hair care composition, so that the steps 208 and 209 can be exchanged.
Step 210, cooling to 40-50 ℃, adding a preservative at a constant temperature, stirring and mixing;
the preservative is a preservative commonly used in the field of daily chemicals, and the invention is not further limited.
The temperature is preferably 40 ℃.
Step 211, adding essence at the constant temperature of 40-50 ℃, stirring and mixing;
the variety of fragrances added depends on the particular variety of hair care compositions, including: essence capable of emitting various plant fragrances.
The temperature is preferably 40 ℃.
And 212, discharging.
To this end, the hair care composition is prepared through steps 201 to 212.
The method of use of the present invention is that the present invention may be in the form of a leave-on or wash-off conditioner. To use the rinse-off conditioner of the present invention, the hair is rinsed by wetting and then the water and conditioner are applied to the hair simultaneously.
Conditioning of the hair can be carried out on wet or dry hair separately from shampooing. The present invention may be a leave-on conditioner, typically applied to the hair with the fingers. Mainly comprises the following steps:
(A) cleaning hair with shampoo;
(B) applying to said hair an effective amount of a hair care composition of the present invention for a period of 2 to 5 minutes, said effective amount generally ranging from 1 to 30 grams, preferably from 5 to 20 grams;
(C) rinsing the hair care composition from the hair with water.
Can be repeated as many times as necessary to achieve the sought care efficacy.
As follows, the present invention will be described in detail with reference to the constituent structures of hair care compositions by six specific examples (specific example 2 to specific example 7), and further, with reference to the performance comparison of six hair care compositions by specific example (specific example 8).
It should be noted that: all percentages are percentages of the component by total weight of the hair care composition.
Table one example 2 to example 7
Specific example 8:
in this example, examples 2 to 7 were compared with each other by four criteria of wet combing, dry smoothness and hair moisture retention.
The hair conditioning efficacy evaluation of examples 2 to 7 was conducted by a human sensory evaluation method, and the hair was tested for dry and wet combing properties, softness and moisture retention, respectively. The prepared hair care compositions were individually distributed to test populations (50 individuals each) for comparative use. When a tester uses the samples, the hair is washed according to the same method, each sample is used for two weeks, the tester combines the daily hair care composition experience and scores according to the own feeling, the scoring standard adopts 5 grades, the higher the score is, the better the dry and wet hair combing property, the softness and the moisture retention are, the larger the proportion of each section evaluating person to the total person number is, and the more objective the evaluating conclusion is. The sensory evaluation test results are shown in the following table.
Evaluation of Using Effect of compositions for Hair conditioner
In the table, it is understood that the use effect of example 2 is inferior to that of example 3 because the volatile silicone oil is added to example 3; in example 5, the amino modified silicone oil 2 is added, so that the wet hair combing property, the dry hair softness, the moisture retention and the like are obviously better than those in example 4; compared with example 6, example 5 adds 1% more sodium pyrrolidone carboxylate, so that the advantage in the moisture retention test is remarkable.
The hair care composition and the preparation method thereof provided by the invention can achieve the following beneficial effects:
the invention provides a hair care composition and a preparation method thereof, which can achieve the following beneficial effects:
the invention comprises the following steps: lactate, pyrrolidone carboxylate, amino modified siloxane and volatile siloxane, which can provide hair with more excellent moisture retention and conditioning. The moisturizing performance of a single raw material is several times that of the traditional glycerin and propylene glycol moisturizers, the moisturizing effect is better than that of the conventional moisturizers represented by glycerin, the moisturizing effect on hair is achieved, the irritation of a cationic surfactant to scalp can be reduced, the phenomena of itching and scurf can be reduced, a good conditioning effect can be achieved on hair, and the softness and glossiness of damaged hair can be improved, which cannot be achieved by the traditional glycerin and propylene glycol moisturizers. The amino modified siloxane and the volatile siloxane are compounded with two types of conditioners with different molecular weights, so that damaged hair is conditioned, and the dryness, wet combing property, glossiness and softness of the hair are improved, so that the damaged hair is more effectively repaired. The hair care composition can be effectively deposited on hair, has good film forming property, good hand feeling after washing, smooth feeling when wetting hair, flexibility and moistening feeling when drying hair, and better moisture retention, conditioning and combing properties when drying hair and wetting hair.
The various embodiments provided by the invention can be combined with each other in any way according to the needs, and the technical solution obtained by the combination is also within the scope of the invention.
It will be apparent to those skilled in the art that various changes and modifications may be made in the present invention without departing from the spirit and scope of the invention. Thus, if such modifications and variations of the present invention fall within the scope of the claims of the present invention and their equivalents, the present invention also encompasses these modifications and variations.
Claims (12)
1. A hair care composition comprising a lactate salt, pyrrolidone carboxylate, an amino-modified silicone, a volatile silicone, an aqueous carrier, a fragrance, a preservative;
the weight of the lactate accounts for 0.1-2% of the total weight of the hair care composition;
the weight of the pyrrolidone carboxylic acid salt accounts for 0.1-2% of the total weight of the hair care composition;
the weight of the amino modified siloxane accounts for 0.1-3% of the total weight of the hair care composition;
the weight of the volatile siloxane accounts for 0.5-10% of the total weight of the hair care composition;
the weight of the aqueous carrier accounts for 80-90% of the total weight of the hair care composition;
the lactate is one or two metal ion salts of Na + and K + of lactic acid;
the pyrrolidone carboxylate is one or two metal ion salts of Na + and K + of the pyrrolidone carboxylic acid or triethanol ammonium salt of the pyrrolidone carboxylic acid;
the amine value of the amino modified siloxane is 0.05-0.4;
the volatile siloxane includes: one or two of decamethylcyclopentasiloxane and dodecamethylcyclohexasiloxane;
the aqueous carrier includes: water-soluble high molecular compound, cationic surfactant, aliphatic compound and deionized water.
2. The hair care composition of claim 1,
the lactate comprises L- (+) -lactate or D- (-) -lactate or a mixture of both.
3. The hair care composition of claim 2, wherein the lactate is sodium lactate.
4. The hair care composition of claim 1,
the pyrrolidone carboxylic acid salt comprises L- (+) -pyrrolidone carboxylic acid salt or D- (-) -pyrrolidone carboxylic acid salt or a mixture of the two.
5. The hair care composition of claim 4, wherein the salt of pyrrolidone carboxylic acid is sodium pyrrolidone carboxylic acid.
6. The hair care composition of claim 1,
the molecular weight of the amino modified siloxane is 10000-300000;
and/or the presence of a gas in the gas,
the amine value of the amino modified siloxane is 0.05-0.2.
7. A hair care composition according to any of claims 1 to 6,
the cationic surfactant comprises quaternary ammonium salt containing 12-22 carbon atoms;
the aliphatic compound includes a saturated straight-chain alcohol or a saturated branched-chain alcohol having 8 to 22 carbon atoms, and/or a fatty acid having 8 to 22 carbon atoms.
8. The hair care composition of claim 7,
the cationic surfactant comprises alkyl ammonium chloride containing 12-22 carbon atoms;
the saturated linear alcohol or derivative thereof includes: one or more of cetyl alcohol, stearyl alcohol, ceteareth-6, PPG-15 stearyl alcohol ether, said saturated branched alcohols and derivatives thereof including: one or more of lanolin alcohol, isostearyl alcohol, pentaerythritol tetraester and tridecyl polyether-6, and the fatty acid and the derivative thereof comprise one or more of myristic acid, palmitic acid, stearic acid, isopropyl isostearate and olive oil ester.
9. The hair care composition of claim 8,
the cationic surfactant comprises one or more of behenyl trimethyl ammonium chloride and octadecyl trimethyl ammonium chloride.
10. The hair care composition of claim 7,
the weight of the cationic surfactant accounts for 0.1-8% of the total weight of the hair care composition; and/or the presence of a gas in the gas,
the weight of the aliphatic compound accounts for 0.1-10% of the total weight of the hair care composition; and/or the presence of a gas in the gas,
the aqueous carrier further comprises: one or more of cationic guar gum, polyquaternium and cellulose ether, wherein the cationic guar gum, the polyquaternium and the cellulose ether are water-soluble high molecular compounds.
11. The hair care composition of claim 7,
the hair care composition is a "leave-on or rinse-off" conditioner.
12. A process for the preparation of a hair care composition according to any of claims 1 to 11 comprising the steps of:
respectively weighing lactate, pyrrolidone carboxylate, amino modified siloxane, volatile siloxane and a water-containing carrier according to parts by weight;
preparing an aqueous carrier according to a set mode;
adding lactate at 60-75 deg.C and mixing;
adding amino modified siloxane at the temperature of 60-75 ℃ and mixing;
adding sodium pyrrolidone carboxylate at 40-50 deg.C and mixing;
adding volatile siloxane at 40-50 deg.C and mixing;
adding preservative and essence at 40-50 deg.C, and mixing;
the preparation of the aqueous carrier according to the set mode comprises the following steps: putting the water-soluble high molecular compound into water and mixing; adding a cationic surfactant and mixing at the temperature of 75-90 ℃; adding an aliphatic compound and mixing at a temperature of 75-90 ℃, wherein the water-soluble high molecular compound comprises: one or more of cationic guar gum, polyquaternium and cellulose ether.
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| CN103655435B (en) * | 2013-04-28 | 2015-08-26 | 钱臻 | A kind of biofermentation hair conditioner and preparation method thereof |
| CN103735428B (en) * | 2013-12-31 | 2015-04-08 | 广州市白云区大荣精细化工有限公司 | Keratin hair conditioner and preparation method thereof |
| CN106265347B (en) * | 2016-09-19 | 2019-01-15 | 拉芳家化股份有限公司 | A kind of Haircare composition and its application based on marine bioactivity object |
| CN106420398A (en) * | 2016-11-22 | 2017-02-22 | 郑州兰茜生物工程有限公司 | Leave-on waterborne spraying type hair conditioner and preparation method thereof |
| CN107468532A (en) * | 2017-08-04 | 2017-12-15 | 澳宝化妆品（惠州）有限公司 | A kind of translucent Haircare composition |
| CN107625658A (en) * | 2017-09-29 | 2018-01-26 | 澳宝化妆品（惠州）有限公司 | One kind washes Haircare composition and preparation method thereof |
| CN118021656A (en) * | 2024-02-27 | 2024-05-14 | 广东顶度生物科技有限公司 | Preparation method of modified siloxane emulsion and shampoo containing modified siloxane emulsion |
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