JP4625893B1 - Hair treatment agent - Google Patents

Abstract

[Problem] To provide a hair treatment agent having sufficient quick-drying property while maintaining a treatment effect such as imparting flexibility and good fingering (sliding property of hair) to hair.
SOLUTION: A first agent containing an A component (an anionic thickener excluding a polysaccharide-based one) and a B component (ethanol), and a C component (average polymerization degree = 800 or higher) A two-component system characterized in that a polymerized dimethicone or a highly polymerized dimethiconol having an average degree of polymerization of 800 or more) and a second agent containing a D component (cationic surfactant) are prepared at the time of use and applied to hair. Hair treatment agent.
[Selection figure] None

Description

  The present invention relates to a hair treatment agent, and more particularly, to a hair treatment agent that is less sticky to hair, can replenish treatment ingredients effective for the hair, and is quick-drying and not washed off.

  Hair is chemically damaged by the use of a permanent agent, a hair coloring agent, or the like, or physically damaged by the use of a hair dryer or the like. Therefore, conventionally, hair cosmetics such as hair treatments are used to moisturize damaged hair or prevent damage to hair. Especially recently, damage to hair has been overlapped by hair color treatment and perm treatment, and problems such as “hair is caught (not good for fingering)”, “coarse” and “hair become stiff” are increasing. . Therefore, various cosmetics for hair (hair treatment) have been developed for the purpose of imparting smoothness and luster to hair.

  In general, there are two types of hair treatments: “washing hair treatment” and “hair treatment that does not wash away” (hereinafter sometimes referred to as “leave-on treatment”). For example, as an example of the leave-on treatment, there is a cosmetic for hair disclosed in Patent Document 1.

JP 2009-51817 A

  Specifically, the cosmetics for hair disclosed in the above-mentioned Patent Document 1 are hair blended with hydrocarbons (specifically paraffins), silicones (specifically amino-modified silicones) and various vegetable oils. Cosmetics (leave on treatment).

  As described above, the leave-on treatment has an advantage that it can replenish moisture to a variety of hair damages such as hair drying because it does not wash away treatment components effective for the hair.

  On the other hand, there are many cases where users use leave-on treatments after applying shampoo to wet hair after removing moisture from the towel with a towel, etc., and then drying the hair with a hair dryer or the like. . For this reason, quick-drying was required for leave-on treatments.

  However, the cosmetics for hair (leave-on treatment) disclosed in Patent Document 1 cannot obtain sufficient effects for both the treatment effect and the quick-drying property.

  The present invention has been made in view of the above circumstances, and the object of the present invention is to maintain a treatment effect such as imparting flexibility and good fingering (sliding property of hair) to the hair, and sufficient. The object is to provide a hair treatment agent having quick drying properties.

In order to achieve the above object, the present invention has the following features. That is, the first invention contains the component A (an anionic thickener excluding a polysaccharide having a skeleton, a water-soluble polymer containing a vinyl group in the main chain ) and the component B (ethanol). First component, component C (highly polymerized dimethicone having an average degree of polymerization in the range of 800 to 3000 or highly polymerized dimethiconol having an average degree of polymerization in the range of 800 to 3000), component D (cationic surfactant) and F A two-part leave-on hair treatment agent characterized by being prepared on use with a second agent containing a component (cyclomethicone) and applied to hair.

A second invention is a leave-on hair treatment agent according to the first invention, wherein the second agent further contains an E component (amino-modified silicone).

A third invention is a first invention comprising an A component (a water-soluble polymer that is an anionic thickener excluding a polysaccharide having a skeleton and contains a vinyl group in the main chain ) and a B component (ethanol). 1 component, component C (highly polymerized dimethicone having an average degree of polymerization in the range of 800 to 3000 or highly polymerized dimethiconol having an average degree of polymerization in the range of 800 to 3000), component D (cationic surfactant), component E ( Amino-modified silicone) and a second agent containing any three components among the four components of F component (cyclomethicone), and the remaining one component among the four components, that is, C component, D component, E component, A three-part leave-on type hair treatment agent characterized by being prepared at the time of use with the third agent containing the remaining one component not contained in the second agent among the F components, and applied to the hair It is.

4th invention contains the A component (The water-soluble polymer which is an anionic thickener except the thing which uses polysaccharide as a skeleton, and contains a vinyl group in a principal chain ), and B component (ethanol) A second agent containing one component, component C (highly polymerized dimethicone having an average degree of polymerization in the range of 800 to 3000 or highly polymerized dimethiconol having an average degree of polymerization in the range of 800 to 3000) and component F (cyclomethicone). 4 prepared by use of an agent, a third agent containing a D component (cationic surfactant), and a fourth agent containing an E component (amino-modified silicone). It is a leave-on hair treatment agent of a pharmaceutical formula.

  In a fifth aspect of the present invention based on any one of the first to fourth aspects of the present invention, the component A (anionic thickener excluding those having a polysaccharide skeleton) is a carboxyvinyl polymer, (acrylic acid / acrylic It is characterized by containing at least one selected from the group consisting of (alkyl acid) copolymers and (acrylates / alkyl acrylate) crosspolymers, or salts thereof.

  According to a sixth invention, in any one of the second to fourth inventions, the sum of the weight value of the D component (cationic surfactant) and the weight value of the E component (amino-modified silicone) is It is characterized by exceeding the weight value of (anionic thickener excluding those having polysaccharide as a skeleton).

  ADVANTAGE OF THE INVENTION According to this invention, the hair treatment agent which has sufficient quick-drying property can be provided, hold | maintaining the treatment effect of giving the softness | flexibility and the fingering goodness (slidability of hair) to hair. In other words, the hair treatment agent of the present invention has a treatment effect such as giving the hair flexibility and good fingering (sliding property of the hair). Assuming a case where the hair is applied to wet hair in a state where the hair is removed and the hair is dried with a hair dryer or the like, the use of the hair treatment agent of the present invention also has a very effective effect of shortening the time for drying the hair.

  The hair treatment agent according to the present invention comprises an anionic thickener, alcohols, a polysiloxane derivative, and a cationic surfactant as essential components.

  As a result of intensive studies, the present applicant has formed an electrical bond between the anionic thickener and the cationic surfactant blended in the hair treatment agent, thereby forming a strong film on the hair. In addition to providing flexibility to the hair, it has been found that the cohesiveness of the hair is improved.

  In addition, the alcohol blended in the hair treatment agent improves the drying property of the hair treatment agent after application to hair (shortening the drying time of the hair coated with the hair treatment agent), that is, quick drying. In addition to the above, the present inventors have also found that the polysiloxane derivative blended in the hair treatment agent can impart flexibility to the hair and can also impart slipperiness to the hair.

  The hair treatment agent according to the present invention may be a two-component hair treatment agent, for example, by dividing the essential components of the hair treatment agent into a first agent and a second agent, respectively. For example, the first agent may contain an anionic thickener and alcohols, while the second agent may contain a polysiloxane derivative and a cationic surfactant. The hair treatment agent comprising the first agent and the second agent is prepared at the time of use of the first agent and the second agent, that is, the first agent and the second agent immediately before being applied to the hair. Mix and apply the mixture to the hair.

  Hereinafter, the present invention will be described in detail with reference to Examples and Comparative Examples. However, these descriptions do not limit the present invention. Accordingly, it goes without saying that various improvements and modifications can be made without departing from the scope of the present invention.

  In other words, the hair treatment agent according to the present invention only needs to contain the above-mentioned essential components, and is not limited to the two-component type described above, and may be a multi-component type. For example, as a three-component hair treatment agent in which the first agent-containing component is an anionic thickener and alcohols, the second agent-containing component is a polysiloxane derivative, and the third agent-containing component is a cationic surfactant. Also good. In the following description, as an example, the first agent and the second agent are used as a two-component hair treatment agent, and the first agent-containing component is an anionic thickener and alcohols. An example in which the second agent-containing component is a polysiloxane derivative and a cationic surfactant will be described.

  First, the first agent will be described. The first agent-containing component is an anionic thickener and alcohols. The anionic thickener used in the first agent of the hair treatment agent according to the present invention is preferably a polymer having an anionic group, and particularly preferably one excluding those having a polysaccharide as a skeleton. Specific examples include water-soluble vinyl polymers, water-soluble acrylic acid polymers, and salts thereof. In particular, carboxyvinyl polymer is suitable as the water-soluble vinyl polymer, and (acrylic acid / alkyl acrylate) copolymer and (acrylates / alkyl acrylate) crosspolymer, sodium polyacrylate, etc. are suitable as the water-soluble acrylic acid polymer. .

  In addition to the above-mentioned anionic thickener, the first agent of the hair treatment agent according to the present invention is mixed with alcohols in order to destabilize the emulsion system of the second agent described later. As a result, the emulsification system of the second agent becomes unstable, so that an anionic thickener blended in the first agent and an electrical surfactant between the cationic surfactant blended in the second agent Bond formation is promoted, a firm film is formed on the hair, and the polysiloxane derivative blended in the second agent effectively adheres to the hair surface, so that the hair is given flexibility. In addition, the alcohol which can acquire the above-mentioned effect should just be mix | blended with the 1st agent. For example, as alcohols, methanol, ethanol, isopropanol, benzyl alcohol and the like can be mentioned, and ethanol is preferable in consideration of safety.

  In addition, the concentration of alcohols in the hair treatment agent, that is, the concentration of alcohols in the hair treatment agent after the first agent and the second agent are prepared at the time of use is set to 2% by weight to 25% by weight. . The reason for this is as follows. That is, if the alcohol concentration in the hair treatment agent is less than 2% by weight, the quick drying property of the hair after the hair treatment agent is applied to the hair is impaired. On the other hand, if it exceeds 25% by weight, the degreasing power (removal of oil from the hair) becomes strong, itching occurs in the hair, and the slipperiness of the hair deteriorates.

  Further, the first agent has an alkali (for example, arginine, sodium hydroxide) as a pH adjuster of the first agent in addition to the first agent-containing component in a quantitative and qualitative range that does not impair the effects of the present invention. , Triethanolamine, etc.), acids (for example, phosphoric acid, citric acid, lactic acid, glycolic acid, etc.) may be added, and pigments, fragrances, and the like may be appropriately blended as necessary.

  Next, the second agent will be described. Although the said 2nd agent containing component will not be specifically limited if there exists an effect of this invention, A polysiloxane derivative, a cationic surfactant, etc. are mentioned.

  For example, examples of the polysiloxane derivative as the second agent-containing component include highly polymerized dimethicone, highly polymerized dimethiconol, and amino-modified silicone.

  The highly polymerized dimethicone represented by the following general formula (1) and the highly polymerized dimethiconol represented by the following general formula (2) are particularly effective in improving the slipperiness (handing property) of hair.

  The average polymerization degree n of each of the highly polymerized dimethicone and the highly polymerized dimethiconol is n = 800 or more, more preferably n = 1000 to 3000. This is because if the average degree of polymerization n is less than n = 800, the expected effect (slidability of hair) cannot be obtained sufficiently.

  On the other hand, amino-modified silicones are particularly effective in imparting flexibility to hair, such as aminoethylaminopropylmethylsiloxane / dimethylsiloxane copolymers, aminoethylaminopropylsiloxane / dimethylsiloxane copolymers, and aminomodified silicones. And emulsions containing the same. In addition, since an anionic thickener is mix | blended with the 1st agent mentioned above, if an amino modified silicone is mix | blended with the 2nd agent, an anionic thickener and an amino modified silicone will be electrically combined. As a result, a firm film is formed on the hair to give the hair flexibility, and the cohesiveness of the hair is improved.

  Next, the cationic surfactant that is the second agent-containing component will be described. The cationic surfactant is blended for the purpose of eliminating stiffness and itching on the hair treated with the hair treating agent. Further, as described above, the thickener containing the first agent is anionic, so that the thickener and the cationic surfactant form an electrical bond, like the amino-modified silicone, In addition to forming a firm film on the hair and giving the hair flexibility, it is possible to obtain the effect that the cohesiveness of the hair is improved.

  Specific examples of the cationic surfactant include, for example, stearyltrimethylammonium chloride, behenyltrimethylammonium chloride, stearyltrimethylammonium bromide, distearyldimethylammonium chloride, behenyldimethylamine, stearyldimethylamine, stearoxypropyldimethylamine, stearate. Examples include loxyhydroxypropyldimethylamine, stearic acid dimethylaminopropylamide, behenic acid dimethylaminopropylamide, and the like.

  In the present invention, in one or both of the first agent and the second agent, that is, in a quantitative and qualitative range that does not impair the effects of the present invention, in addition to the essential components, in the hair treatment agent. In addition, volatile silicones (for example, cyclomethicone which is one of cyclic silicones) may be appropriately blended in order to promote quick drying of the hair treatment agent.

  Further, in the present invention, in one or both of the first agent and the second agent, that is, in a quantitative and qualitative range that does not impair the effects of the present invention, in addition to the essential components, in the hair treatment agent. In addition, in order to improve the emulsion stability of the hair treatment agent, nonionic surfactants (for example, polyglycerin fatty acid esters, polyoxyethylene sorbitan fatty acid esters, polyoxyethylene alkyl ethers, etc.), anionic surfactants (for example alkyl alkyls) Sulfates, polyoxyethylene alkyl ether sulfates, alkyl sulfosuccinates, alkyl ether carboxylates, N-acyl glutamates, etc., amphoteric surfactants (eg alkylamidopropyl betaines, alkyl betaines, imidazolinium betaines) Etc.) may be added as appropriate, and the viscosity of the hair treatment agent may be adjusted. Higher alcohols for (e.g. cetanol, etc. alkenyl alcohol to base), oil (such as paraffin, such as liquid paraffin) may be appropriately blended.

  Further, in the present invention, in one or both of the first agent and the second agent, that is, in a quantitative and qualitative range that does not impair the effects of the present invention, in addition to the essential component, in the hair treatment agent. In addition, nonionic polymers (for example, guar gum, polyethylene glycol, glucomannan, polyacrylic acid amide, hydroxyethyl cellulose, etc.), anionic polymers (for example, xanthan gum, carrageenan, etc.) as viscosity modifiers and feel improvers for the above hair treatment agents , Cationic polymers (eg cationized cellulose, cationized guar gum, cationized keratin, cationized chitosan, diallyl quaternary ammonium salt homopolymer, diallyl quaternary ammonium salt / acrylamide copolymer, quaternization Polyvinylpyrrolidone derivatives ((dimethylacrylamide / meta Ethyltrimonyl chloride))), etc.), etc.) may be blended as appropriate, and esters (eg, isopropyl palmitate, isononyl isononanoate, diisopropyl adipate), polysiloxane to give a moist feeling to the hair Derivatives (for example, polyether-modified silicone, alkyl-modified silicone, phenyl-modified silicone, fluorine-modified silicone, etc.) may be appropriately blended. If necessary, moisturizers, PPTs, plant extracts, preservatives, antioxidants, ultraviolet absorbers, chelating agents, solvents, pH adjusters, deodorants, pigments and fragrances may be appropriately blended. Good.

  In addition, the polysiloxane derivative mix | blended with a 2nd agent may be mix | blended in a 2nd agent individually by 1 type or in combination of 2 or more types as appropriate. That is, the polysiloxane derivative to be blended in the second agent may be highly polymerized dimethicone and / or highly polymerized dimethiconol, or may contain amino-modified silicone in addition to the highly polymerized dimethicone and / or highly polymerized dimethiconol. For example, the first agent-containing component may be an anionic thickener and alcohols, the second agent-containing component may be highly polymerized dimethicone and / or highly polymerized dimethiconol, and the third agent-containing component may be amino-modified silicone. That is, it is possible to make a four-agent hair treatment agent together with the fourth agent containing a cationic surfactant as a component.

  As described above, the hair treatment agent of the present invention is blended with an anionic thickener, alcohols, amino-modified silicone, and a cationic surfactant. Good unity. Moreover, since alcohol is mix | blended with the hair treatment agent of this invention, the dryness (dryness) of the hair after apply | coating the said hair treatment agent becomes favorable.

  Further, the hair treatment agent of the present invention is a hair treatment agent in a form in which the essential components are divided as described above, that is, in a multi-component form, and the essential components are mixed (prepared at the time of use) immediately before application to the hair. is there. Therefore, for example, creaming of the emulsion over time, coalescence of the emulsified particles, and the like can be prevented as compared with a form that is a single-component hair treatment agent that contains all the essential components. In addition, when the above essential components are divided into a multi-drug type as described above, the amount of the essential component in preparation for use is appropriately changed (for example, in the case of a two-drug type, either the first agent or the second agent) By increasing the amount on one side and preparing it at the time of use, the flexibility of the hair, the cohesiveness of the hair, and the slipperiness of the hair can be improved.

  Hereinafter, the present invention will be described in more detail based on examples and comparative examples. However, the present invention is not limited only to the examples of the present invention, and each component contained in a quantitative and qualitative range that does not impair the effects of the present invention. You may change the combination and compounding quantity of these.

<Preparation of sample>
According to the composition described in Table 1 to Table 5, each hair treatment agent of Examples 1 to 18 and Comparative Examples 1 to 5 was prepared at the time of use and subjected to the following evaluation. In addition, the evaluation result was written together in Table 1-Table 5, respectively. Moreover, unless otherwise indicated, the numerical value of Tables 1-5 is weight%.

<Test Example 1: Treatment effect and ease of handling hair treatment agent>
The first agent and the second agent in combinations as described in Tables 1 to 5 with 10 females in their 20s to 30s (hair length: semi-long hair to long hair) as panelists (Weight ratio 1: 1) was taken in the palm of the hand, the first agent and the second agent were mixed on the palm, and then applied to the hair. Each panelist used each hair treatment agent for 10 days, and evaluated the treatment effects (“hair flexibility” and “hair slipperiness”) based on the following scores. The ease of handling the hair treatment agent (“mixability of the first agent and the second agent”, “ease of application”) was also evaluated based on the following ratings. Specifically, each panel scored each evaluation item according to the following criteria.
+2 points: Very good +1 point: Slightly good -1 point: Slightly bad -2 points: Very bad

And in Table 1-Table 5, the total score of 10 panelists about each evaluation item was totaled, and it showed as follows as comprehensive evaluation (evaluation result) of each evaluation item.
◎: Total score of 15 points or more ○: Total score of 14 points or less to 7 points or more △: Total score of 6 points or less to 0 points or more ×: Total score of less than 0 points (total score is minus)
In addition, from the viewpoint of merchandise value, it is desired that the overall evaluation of each item is an evaluation of ○ or more.

<Test Example 2: Evaluation of quick drying property of hair treatment agent>
Each hair treatment agent listed in Table 2 was prepared at the time of use for 10 g of the hair bundle wiped off with a towel. Specifically, 0.5 g of hair treatment agent was added to the hair bundle (0.25 g of the first agent, 0.25 g of the second agent, that is, 1: 1 by weight ratio was applied, and the weight of the hair bundle was measured. Then, it was left in a thermostatic chamber at 50 ° C. for 15 minutes, and the weight of the hair bundle after being left was measured again. The hair bundle used was a human hair bundle (product number: BS-B3A) manufactured by Beaulux.

And it evaluated as follows by the weight difference of the hair | bristle bundle before and behind leaving a constant temperature room.
A: 1.5 g or more B: Less than 1.5 g to 1.0 g or more Δ: Less than 1.0 g to 0.5 g or more X: Less than 0.5 g Note that the larger the weight difference between the hair bundles before and after being left in the constant temperature room, the faster Good dryness.

(Examples 1 to 4 and Comparative Example 1)
According to the composition described in Table 1, the first agent and the second agent were prepared at the time of use, and each hair treatment agent was evaluated according to Test Example 1 described above.

  As can be seen from Table 1, all of Examples 1 to 4 are “softness of hair”, “slipability of hair”, “mixability of first agent and second agent”, “application of hair” Excellent effects were obtained with respect to “ease”. On the other hand, as seen in Comparative Example 1 of Table 1, the hair treatment agent in which the first agent does not contain an anionic thickener is good in both “hair flexibility” and “hair slipperiness”. The result could not be obtained. Furthermore, since the hair treatment agent in which the first agent does not contain an anionic thickener has a low viscosity, the mixing property between the first agent and the second agent is poor, as seen in Comparative Example 1 of Table 1. In addition, hair treatment agents that do not contain an anionic thickener in the first agent can also obtain good results for "mixability of the first and second agents" and "ease of application". I could not.

(Examples 5 to 6, Comparative Example 2)
According to the composition described in Table 2, the first agent and the second agent were prepared at the time of use, and each hair treatment agent was evaluated according to Test Example 1 and Test Example 2 described above.

  As seen in Table 2, all of Examples 5 to 6 were excellent in terms of “softness of hair”, “slidability of hair”, and “quick drying”. On the other hand, as seen in Comparative Example 2 in Table 2, when ethanol is not blended in the first agent, that is, when the hair treatment agent in which ethanol is not blended in the hair treatment agent is used, “softness of hair Good results could not be obtained for each of “ability”, “hair slipperiness” and “quick drying”.

(Examples 7 to 10, Comparative Example 3)
According to the composition described in Table 3, the first agent and the second agent were prepared at the time of use, and each hair treatment agent was evaluated according to Test Example 1 described above.

  As can be seen in Table 3, all of Examples 7 to 9 were excellent in terms of “hair flexibility” and “hair slipperiness”. On the other hand, as seen in Comparative Example 3 in Table 3, when at least one of the highly polymerized dimethicone and the highly polymerized dimethiconol is not blended in the second agent, “softness of hair”, particularly “slipability of hair” Could not get good results. From this, it can be seen that the highly polymerized dimethicone and the highly polymerized dimethiconol are particularly effective for the “hair slipperiness”. Further, as seen in Example 10 of Table 3, depending on the amount of highly polymerized dimethicone in the second agent, amino-modified silicone (specifically, aminoethylaminopropylmethylsiloxane / dimethylsiloxane copolymer) It was also found that good effects can be obtained with respect to “softness of hair” and “slipping property of hair” even if it is not blended in the second agent. In other words, it is sufficient that at least one of highly polymerized dimethicone and highly polymerized dimethiconol is blended in the second agent. Even if no amino-modified silicone is blended in the second agent, the highly polymerized dimethicone in the second agent and By appropriately adjusting the blending amount of the highly polymerized dimethiconol, good results can be obtained for “hair flexibility” and “hair slipperiness”.

(Examples 11 to 14, Comparative Example 4)
According to the composition described in Table 4, the first agent and the second agent were prepared at the time of use, and each hair treatment agent was evaluated according to Test Example 1 described above.

  As can be seen from Table 4, in all of Examples 11 to 14, good effects were obtained with respect to “softness of hair” and “slidability of hair”. Moreover, as can be seen from Examples 11 to 13 and Example 14 in Table 4, the total amount of amino-modified silicone and cationic surfactant in the hair treatment agent exceeds the amount of anionic thickener. In this case, particularly excellent effects were obtained with respect to “hair flexibility” and “hair slipperiness”. That is, the sum of the weight percent value of the amino-modified silicone compounded in the second agent and the weight percent value of the cationic surfactant is the weight percent of the anionic thickener compounded in the first agent. If it exceeds the value, particularly excellent effects can be obtained with respect to “softness of hair” and “slidability of hair”. On the other hand, as seen in Comparative Example 4 in Table 4, when the highly polymerized dimethicone, the highly polymerized dimethiconol, and the amino-modified silicone are not blended in the second agent, “hair flexibility”, “hair slipperiness” “Both did not get good results.

(Examples 15 to 18, Comparative Example 5)
According to the composition described in Table 5, the first agent and the second agent were prepared at the time of use, and each hair treatment agent was evaluated according to Test Example 1 described above.

  As can be seen from Table 5, all of Examples 15 to 18 were excellent in terms of “hair flexibility” and “hair slipperiness”. In particular, as can be seen from Example 15 to Example 17 and Example 18 in Table 5, when using stearyltrimethylammonium chloride or stearyltrimethylammonium bromide as the cationic surfactant, "softness of hair" A particularly excellent effect is obtained with respect to “hair slipperiness”. On the other hand, as seen in Comparative Example 5 in Table 5, when a cationic surfactant is not blended in the second agent, good results are obtained for “hair flexibility” and “hair slipperiness”. I could not.

  The hair treatment agent according to the present invention maintains a treatment effect such as imparting flexibility and good fingering (slidability of hair) to the hair, and has a sufficient quick-drying property, and does not wash away (treatment) It can utilize suitably for etc.

Claims (6)

A first agent containing an A component and a B component;
A two-part leave-on hair treatment agent, wherein a second agent containing a C component, a D component and an F component is prepared at the time of use and applied to the hair.
Component A: An anionic thickener and a water-soluble polymer containing a vinyl group in the main chain (excluding those based on polysaccharides)
B component: ethanol C component: highly polymerized dimethicone having an average degree of polymerization in the range of 800 to 3000 or highly polymerized dimethiconol having an average degree of polymerization in the range of 800 to 3000 D component: cationic surfactant F component: cyclomethicone The leave-on hair treatment agent according to claim 1, wherein the second agent further contains an E component.
E component: amino-modified silicone A first agent containing an A component and a B component;
A second agent containing any three of the four components C component, D component, E component, and F component;
A three-part leave-on type hair treatment agent, wherein the third component containing the remaining one component among the four components is prepared at the time of use and applied to the hair.
Component A: An anionic thickener and a water-soluble polymer containing a vinyl group in the main chain (excluding those based on polysaccharides)
B component: ethanol C component: highly polymerized dimethicone having an average degree of polymerization in the range of 800 to 3000 or highly polymerized dimethiconol having an average degree of polymerization in the range of 800 to 3000 D component: cationic surfactant E component: amino-modified silicone F Ingredient: Cyclomethicone A first agent containing an A component and a B component;
A second agent containing a C component and an F component;
A third agent containing a component D;
A four-component leave-on hair treatment agent, wherein a fourth agent containing an E component is prepared at the time of use and applied to the hair.
Component A: An anionic thickener and a water-soluble polymer containing a vinyl group in the main chain (excluding those based on polysaccharides)
B component: ethanol C component: highly polymerized dimethicone having an average degree of polymerization in the range of 800 to 3000 or highly polymerized dimethiconol having an average degree of polymerization in the range of 800 to 3000 D component: cationic surfactant E component: amino-modified silicone F Ingredient: Cyclomethicone The component A contains at least one selected from the group consisting of carboxyvinyl polymer, (acrylic acid / alkyl acrylate) copolymer, (acrylates / alkyl acrylate) crosspolymer, or salts thereof. The leave-on hair treatment agent according to any one of claims 1 to 4, wherein:   The leave-on hair according to any one of claims 2 to 4, wherein the sum of the weight value of the D component and the weight value of the E component exceeds the weight value of the A component. Processing agent.