JP2006315987A - Hair cosmetic - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a hair cosmetic having hair-protecting effects, conditioning effects and the like superior to those of the conventional one. <P>SOLUTION: The hair cosmetic contains (A) 0.01-10.0 mass% of one or more kinds of Gemini cationic surfactants represented by general formula (I) [wherein, R<SP>1</SP>and R<SP>2</SP>are each a straight chain or branched 5-25C saturated or unsaturated alkyl group; R<SP>3</SP>, R<SP>4</SP>, R<SP>5</SP>and R<SP>6</SP>are each a 1-5C alkyl group; and X is a halogen atom or a short-chain sulfate ion group] based on the hair cosmetic, and (B) 10.0-50.0 mass% of one or more kinds of polyhydric alcohols and/or saccharides based on the hair cosmetic. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

  The present invention relates to hair cosmetics, and in particular, to hair cosmetics excellent in hair protecting effects, conditioning effects, and the like.

  Conventionally, as a quaternary ammonium organic acid salt used as a raw material for hair treatment agents such as hair rinses, it is a quaternary ammonium salt having a long chain alkyl group, and carboxylic acid, sulfonic acid, phosphoric acid is used as a counter ion. Although what has it is known (Unexamined-Japanese-Patent No. 8-208443 etc.), the damage of the hair by such a component has been a problem.

  In addition, various oils and water-soluble polymers have been appropriately blended in hair cosmetics for the purpose of caring for damaged hair, improving unity, and imparting a moderate moist feeling.

  However, when oil agents such as hydrocarbon oils and ester oils are used in hair cosmetics, the finish becomes heavy and tends to be sticky. In addition, when a moisturizing agent such as a water-soluble polymer is blended, there is an effect on moisture feeling at the time of use, but a tendency to become stiff with the passage of time is recognized. Thus, even when a moisturizing agent for hair was used, a satisfactory feeling of use could not always be obtained. Therefore, it has been desired to develop a hair cosmetic that takes care of damaged hair and does not feel sticky or stiff.

  As a technique developed to solve such drawbacks, hair cosmetics containing a specific amino acid amphoteric surfactant and a plant-derived moisturizer, urea moisturizer or sugar moisturizer as a moisturizer are known. (See Patent Document 1).

In addition, in hair cosmetics having a set power, the hair that is not sticky and gives hair suppleness by blending a specific highly polymerized polyethylene glycol, an oil agent, a nonionic surfactant, and a water-soluble alcohol. Cosmetics have been obtained (see Patent Document 2).
JP 2000-86453 A JP 2003-26545 A

  In general, when existing hair cosmetics are used, although they have excellent flexibility with respect to hair, there are aspects in which sufficient effects are not obtained with respect to smoothness and moistness. In addition, the quaternary ammonium salt may cause problems with irritation to hair and scalp and biodegradability. Furthermore, the hair cosmetic composition of Patent Document 1 has a problem that it is recognized that it is too moist and has a sticky feeling. Moreover, the hair cosmetics of the said patent document 2 have the problem that it may give a wrinkle and puffiness.

  Therefore, a problem to be solved by the present invention is to provide a hair cosmetic that is superior in hair protection effect, conditioning effect, and the like as compared with the prior art.

  As a result of the study by the present inventors, it has been clarified that the above-mentioned problems can be solved by blending a specific gemini-type cationic active agent and a saccharide and / or a polyhydric alcohol into a hair cosmetic, and the present invention has been completed. It came to.

That is, this invention is invention which provides the hair cosmetics (henceforth this hair cosmetics) containing the following component (A) and (B).
(A) 0.01-10.0 mass% of 1 or more types of gemini type | mold cationic activator (henceforth cation activator (I)) represented with general formula (I) with respect to hair cosmetics. .

[Wherein R ¹ and R ² are linear or branched saturated or unsaturated alkyl groups having 5 to 25 carbon atoms, and R ³ , R ⁴ , R ⁵ and R ⁶ are each a carbon atom number. 1 to 5 alkyl groups, and X is a halogen atom or a short-chain sulfate ion group. ]
(B) 10.0-50.0 mass% of 1 or more types of a polyhydric alcohol and / or saccharides with respect to hair cosmetics.

  According to the present invention, an excellent hair protection effect, an excellent conditioning effect, and a hair cosmetic excellent in the sustainability of these effects are provided.

  As described above, the present hair cosmetic is a hair cosmetic comprising the cationic active agent (I) as the component (A) and the polyhydric alcohol and / or saccharide as the component (B) as essential components. is there.

[ Ingredient (A) ]
In the cationic active agent (I), a linear or branched alkyl group having a saturated or unsaturated carbon atoms 5 to 25, R ¹ and R ² are, in particular, suitably a stearyl group or behenyl group is there. R ³ , R ⁴ , R ⁵ and R ⁶ which are alkyl groups having 1 to 5 carbon atoms are particularly preferably a methyl group, an ethyl group or a propyl group. Examples of the halogen atom that X can take include a fluorine atom, a chlorine atom, a bromine atom, and an iodine atom. Examples of the short-chain sulfate ion group include a methyl sulfate ion group or an ethyl sulfate ion group.

  The cationic activator (I) can be produced according to the production method disclosed in US Patent Publications (US; 4734277, 4764306, 4812263).

  One or more cationic surfactants (I) can be combined in the present hair cosmetic composition.

  The compounding quantity of cationic surfactant (I) in this hair cosmetics is 0.01-10.0 mass% with respect to hair cosmetics, Preferably it is 0.1-5.0 mass%. When the blending amount is less than 0.01% by mass with respect to the hair cosmetic, it is insufficient for exerting the intended effect of the present invention, and when it exceeds 10.0% by mass, the use of the hair cosmetic is performed. There is a tendency to feel less.

[ Ingredient (B) ]
As described above, when the component (B) is a polyhydric alcohol, examples thereof include dipropylene glycol, propylene glycol, ethylene glycol, glycerin, diglycerin, isoprene glycol, 1,3-butylene glycol, and polyethylene glycol. be able to. Among these, glycerin or diglycerin can be mentioned as a suitable polyhydric alcohol.

  In addition, when the component (B) is a saccharide, sugar alcohols such as xylitol, sorbitol, mannitol, inositol and maltitol, and reducing sugars such as glucose, lactose, fructose and sucrose can be exemplified. Of these saccharides, sorbitol, glucose or sucrose is preferred.

  Furthermore, when selecting either a polyhydric alcohol or saccharide, the tendency for selecting saccharide is recognized.

  As the component (B), one or more of the above polyhydric alcohol and / or saccharide can be used.

  10.0-50.0 mass% is suitable with respect to hair cosmetics, and, as for the compounding quantity of the component (B) in this hair cosmetic, 15.0-40.0 mass% is especially suitable. When the blending amount of this component (B) is less than 10.0% by mass with respect to the hair cosmetic, it becomes difficult to improve the combability of the hair, and when it exceeds 50.0% by mass, the hair The tendency to give stickiness to becomes stronger.

[ Selective ingredients ]
<Quaternary ammonium salt>
The hair cosmetic composition of the present invention further improves the adsorptivity to hair by adding one or more quaternary ammonium salts represented by the following general formula (II), and imparts smoothness and luster to the hair. And it is possible to improve the combing path.

(NR ⁷ R ⁸ ₃ ) ⁺ Y ⁻ (II)
[Wherein R ⁷ is divided by an alkyl group having 8 to 22 carbon atoms, a hydroxyalkyl group having 8 to 22 carbon atoms, an alkyl ether group having 8 to 22 carbon atoms, or an ester group or an amide group. R ⁸ is independently an alkyl group having 8 to 22 carbon atoms or an alkenyl group, and each R ⁸ is independently an alkyl group having 1 to 4 carbon atoms, a hydroxyalkyl group having 1 to 4 carbon atoms, or a benzyl group. Yes, Y is a halogen atom or a short-chain sulfate ion group having 1 to 2 carbon atoms (methyl sulfate ion group, ethyl sulfate ion group). ]

Examples of the alkyl group having 8 to 22 carbon atoms that R ⁷ can take include a cetyl group, a stearyl group, and a behenyl group. Examples of the hydroxyalkyl group having 8 to 22 carbon atoms include 12-hydroxystearyl group. Examples of the alkyl ether group having 8 to 22 carbon atoms include a stearoxypropyl group. Further, preferable examples of the alkyl group or alkenyl group having 8 to 22 carbon atoms separated by an ester group or an amide group include a stearamidopropyl group and a beheramidopropyl group. Particularly preferred R ⁷ includes a stearyl group or a behenyl group.

Preferred examples of R ⁸ include a methyl group, an ethyl group, a propyl group, a hydroxymethyl group, and a hydroxyethyl group. Y is preferably a chlorine atom or a bromine atom.

  Specific examples of the quaternary ammonium salt (II) include cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, behenyltrimethylammonium chloride, behenyldimethylhydroxyethylammonium chloride, stearyldimethylbenzylammonium chloride, cetyltriethylammonium methyl. A sulfate etc. can be mentioned. Among these, stearyltrimethylammonium chloride, behenyltrimethylammonium chloride, stearyldimethylbenzylammonium chloride, or a mixture thereof is particularly preferable.

<Hair repair component>
By blending hair repair ingredients such as lecithin, hydrolyzed protein and its derivatives, amino acids (glutamic acid, arginine, glycine, alanine, serine, proline, leucine, isoleucine, etc.), vitamins, ceresin, etc. Furthermore, it is possible to obtain a hair cosmetic that is excellent in the effect of repairing and protecting hair and that lasts for a long time.

  In addition to the above-mentioned components, the present hair cosmetics further include a surfactant (excluding those described above), liquid paraffin within a quantitative and qualitative range that does not impair the effects of the present invention depending on the purpose. Oils such as squalane, lanolin derivatives, higher alcohols, various ester oils, avocado oil, palm oil, beef tallow, jojoba oil, polyalkylene glycol polyether and its carboxylic acid oligoester compounds, terpene hydrocarbon oils, ultraviolet absorbers, Resins such as UV scattering agent, acrylic resin, silicone resin, polyvinylpyrrolidone; protein or proteolysate such as soy protein, gelatin, collagen, silk fibroin, elastin; preservative such as ethyl paraben, butyl paraben; biotin, pantothene Activators such as acid derivatives; γ-oryzanol, sodium dextran sulfate, and bitami Blood circulation promoters such as E derivatives and nicotinic acid derivatives; Antiseborrheic agents such as sulfur and thianthol; Diluents such as ethanol, isopropanol and tetrachlorodifluoroethane; Thickeners such as carboxyvinyl polymer; Drugs, perfumes and coloring agents , May be blended as necessary.

  The dosage form of the present hair cosmetic is arbitrary, and may be any of solubilization system, emulsification system, powder dispersion system, oil-water two-layer system, oil-water-powder three-layer system, and the like. These dosage forms can be prepared using conventional methods.

  Further, the present hair cosmetic means any cosmetic used for hair, so-called hair treatment such as shampoo, so-called hair cleansing agent, hair rinse, hair conditioner, hair treatment, hair pack, hair spray, styling agent, etc. It contains a wide range of agents. Moreover, the usage form may include any of those that are applied to the hair and thoroughly rinsed after rinsing, and those that are not washed off.

  Hereinafter, the present invention will be described more specifically with reference to examples. However, the present invention is not limited to these examples. About a compounding quantity, mass% is shown unless there is particular notice.

  The following cationic activator (I) used in this example was produced by the method described in the above-mentioned publication (US; 4734277, 4764306, 4812263) and used in this example.

<Cationic activator (I)>
(1) Gemini-type cationic activator 1
[R ¹ and R ² = C ₁₈ H ₃₇ , R ³ , R ⁴ , R ⁵ and R ⁶ = CH ₃ , X = Cl]

(2) Gemini-type cationic activator 2
[R ¹ and R ² = C ₁₂ H ₂₅ , R ³ , R ⁴ , R ⁵ and R ⁶ = CH ₃ , X = Cl]

(3) Gemini type cationic activator 3
[R ¹ and R ² = C ₁₆ H ₃₃ , R ³ , R ⁴ , R ⁵ and R ⁶ = CH ₃ , X = Cl]

(4) Gemini type cationic activator 4
[R ¹ and R ² = C ₂₂ H ₄₅ , R ³ , R ⁴ , R ⁵ and R ⁶ = CH ₃ , X = Cl]

(5) Gemini type cationic activator 5
[R ¹ and R ² = C ₁₈ H ₃₇ , R ³ , R ⁴ , R ⁵ and R ⁶ = CH ₃ , X = Br]

(6) Gemini-type cationic activator 6
^{[R 1} and _{^{R 2 = C 18 H 37,}} R 3, R 4, R 5 and _{^{R 6 = CH 3, X =}} CH 3 S0 4]

(7) Gemini type cationic activator 7
[R ¹ and R ² = C ₁₈ H ₃₇ , R ³ , R ⁴ , R ⁵ and R ⁶ = CH ₃ , X = C ₂ H ₅ SO ₄ ]

(8) Gemini type cationic activator 8
[R ¹ and R ² = C ₃₀ H ₆₁ , R ³ , R ⁴ , R ⁵ and R ⁶ = CH ₃ , X = Cl]

(9) Gemini type cationic activator 9
[R ¹ and R ² = C ₆ H ₁₃ , R ³ , R ⁴ , R ⁵ and R ⁶ = CH ₃ , X = Cl]

[Test Example] Combability of hair and conditioning effect Hair cosmetics comprising the respective formulation components shown in Tables 1 to 4 below were prepared by a conventional method. About the obtained hair cosmetics, the following method and criteria were used to evaluate (1) the combing property of the hair when rinsing and the combing property of the hair after drying, and (2) each sample A sensory test on the conditioning effect was conducted by a specialized panelist after use.

(1) Combability test <Method>
A hair bundle consisting of about 1000 human hairs was prepared, and each sample was applied thereto, followed by rinsing for about 2 minutes, and the combing at that time was evaluated (combability during rinsing). The temperature of the shower water at the time of rinsing is 40 ° C., and the flow rate of the shower is 20 g / sec.

  After finishing the rinsing step and the combing test, the hair bundle was dried by applying hot air from a dryer, and the combing test was performed again (combability of hair after drying).

  The combing property of the hair after rinsing and after drying is evaluated by using a combing tester (manufactured by Techno Hashimoto) as a comb-passing tester and using the catching force when the hair and comb of the hair bundle are caught as an index. The load applied to the hair bundle was detected.

  Based on the numerical values thus obtained, the combing ability was determined according to the following evaluation criteria. The obtained results are also shown in Tables 1 to 4.

<Evaluation criteria>
(Double-circle): It is 0.8 or less on the basis of the value obtained in Comparative Example 1 (1.0).
○: More than 0.8 and 0.95 or less.
Δ: Above 0.95 to 1.0 or less.
X: More than 1.0.

(2) Sensory test by panelists (conditioning effect)
After applying each sample to the hair of 20 professional panelists, rinse with a shower (the temperature of the shower water at the time of rinsing is 40 ° C, the flow rate of the shower is 20 g / sec) for about 2 minutes, and after drying with a dryer The following criteria were used to evaluate 1) the moist feeling of the hair (no roughness) and 2) softness (no roughness). The obtained results are collectively shown in Tables 1 to 4.

<Evaluation criteria for moist feeling>
◎: More than 17 out of 20 responded that they feel moist.
○: 13 to 16 out of 20 responded that they had a moist feeling.
Δ: 8 to 12 out of 20 responded that they had a moist feeling.
×: 7 or less of 20 responded that they had a moist feeling.

<Evaluation criteria for softness>
◎: More than 17 out of 20 responded that they feel moist.
○: 13 to 16 out of 20 responded that they had a moist feeling.
Δ: 8 to 12 out of 20 responded that they had a moist feeling.
×: 7 or less of 20 responded that they had a moist feeling.

  Tables 1-2 fixed the kind and compounding quantity of cation activator (I) (Gemini type cation activator 1), and various saccharides and polyhydric alcohol were mix | blended within the prescription | regulation of this invention with respect to this. The result of having evaluated about the combing property of an Example is shown (Examples 1-19).

  As a result, good combing properties and a good conditioning effect were observed for all the examples. In addition, when the example using the equivalent saccharide | sugar and a polyhydric alcohol was compared, the tendency for the result of the saccharide | sugar to be favorable was recognized.

  Table 3 shows the results of evaluation of the combing property of the examples in which the sugar alcohol (sorbitol) within the specified amount of the present invention and various cationic activators (I) were blended within the specified amount of the present invention. (Examples 20 to 32). In any of the examples, good combing property and good conditioning effect were recognized. Moreover, about the example (Examples 30-32) which added the quaternary ammonium salt, the further favorable result was obtained with both the combing property and the conditioning effect.

In Table 4, the prescriptions of various comparative examples that deviate from the provisions of the present invention and the evaluation of the combing property of these comparative examples are shown (Comparative Examples 1 to 11). As a result, even if the blending amount of saccharide and / or polyhydric alcohol is less than the specified amount (Comparative Examples 1, 3, 7), a large amount (Comparative Examples 2, 4, 5, 6), good combability It became clear that the conditioning effect could not be obtained. It is also clear that even if the amount of the cationic activator (I) is less than the specified amount (Comparative Example 8) and a large amount (Comparative Example 9), good combability and conditioning effect cannot be obtained. became. Further, when the gemini type cationic activator is outside the specified range of the present invention (when the molecular weights of R ¹ and R ² are too large and too small: Comparative Examples 10 and 11), the blending amount is as specified. However, it was also found that the combing property and the conditioning effect were inferior.

  Below, the formulation example of this invention is disclosed as an Example. The hair cosmetics of these formulation examples were evaluated as “の” in the above criteria in terms of combing property and conditioning effect (moist feeling and softness of the hair after drying) after rinsing and drying. It was. In addition, as for the cation activator (I) used by the following formulation example, all were manufactured according to the manufacturing method mentioned above.

[Example 33] Hair mist
Compounding component amount (% by mass)
(1) Dimethylpolysiloxane (6cs) 1.0
(2) Ethanol 5.0
(3) Stearyl alcohol 0.1
(4) Behenyl alcohol 0.2
(5) Sucrose 12.0
(6) Dipropylene glycol 1.0
(7) 1,3-butylene glycol 1.0
(8) Gemini-type cationic activator 0.5
(In general formula (I), R ¹ and R ² are stearyl groups, R ³ , R ⁴ , R ⁵ and R ⁶ are methyl groups, and X is a chlorine atom)
(9) Vinylpyrrolidone / N N-dimethylaminoethyl methacrylic acid copolymer 2.5
(10) paraoxybenzoic acid ester appropriate amount (11) purified water residue (12) perfume appropriate amount <production method>
The oil layer mixed with (1) to (8) and the aqueous layer mixed with (9) to (11) are dissolved by heating, and the former is added to the latter to emulsify. (12) is added to make uniform.

[Example 34] Hair cream
Compounding component amount (% by mass)
(1) Volatile isoparaffin 10.0
(2) Dimethylpolysiloxane (6cs) 2.0
(3) Sorbitol 20.0
(4) Polyethylene glycol 6000 1.0
(5) Polyglyceryl diisostearate 0.5
(6) Sodium hydroxide 0.06
(7) Phenoxyethanol appropriate amount (8) edetate trisodium appropriate amount (9) carrageenan 0.5
(10) Dimethyl distearyl ammonium hectorite 0.5
(11) Gemini-type cationic activator 0.2
(In general formula (I), R ¹ and R ² are behenyl groups, R ³ , R ⁴ , R ⁵ and R ⁶ are methyl groups, and X is a chlorine atom)
(12) Stearyl alcohol 1.0
(13) Carboxyvinyl polymer 0.5
(14) Highly polymerized dimethylpolysiloxane 2.0
(15) Purified water Residual (16) Perfume appropriate amount <Production method>
(1) to (5) and (10) to (14) are mixed and homogenized, and the mixture of (6) to (9) is added and emulsified. After adding (16), neutralize in (15) and further stir to make uniform.

[Example 35] Hair spray
Compounding component amount (% by mass)
(1) Ethanol 10.0
(2) Sucrose 15.0
(3) Behenyl alcohol 1.0
(4) Gemini type cationic activator 0.1
(In general formula (I), R ¹ and R ² are myristyl groups, R ³ , R ⁴ , R ⁵ and R ⁶ are methyl groups, and X is a chlorine atom)
(5) Yuka Former SM 10.0
(6) Polyoxyethylene / methylpolysiloxane copolymer 1.0
(7) Volatile isoparaffin 5.0
(8) Highly polymerized dimethylpolysiloxane 1.0
(9) Purified water 5.0
(10) Perfume appropriate amount (11) LPG residue <Production method>
(3) to (9) are mixed and the mixture of (1) to (2) is added and emulsified. After adding (9) and making uniform, it fills a container with (11).

[Example 36] Hair spray
Compounding component amount (% by mass)
(1) Sucrose 20.0
(2) Ethanol 5.0
(3) Yuka Former SM 12.0
(4) 2-alkyl-N-carboxymethyl-N-
Hydroxyethylimidazolium betaine 1.0
(5) Polyoxyethylene hydrogenated castor oil (60 EO) 0.5
(6) Gemini-type cationic activator 0.2
(In general formula (I), R ¹ and R ² are lauryl groups, R ³ , R ⁴ , R ⁵ and R ⁶ are methyl groups, and X is a chlorine atom)
(7) Stearyl alcohol 0.5
(8) paramethoxybenzoic acid ester appropriate amount (9) purified water residue (10) perfume appropriate amount (11) stock solution / propellant = 92/8 (LPG 0.43 MPa: DME = 80: 20)
<Manufacturing method>
(3) to (9) are mixed and the mixture of (1) to (2) is added and emulsified. After adding (10) and making it uniform, the container is filled together with (11).

[Example 37] Hair oil
Compounding component amount (% by mass)
(1) Light liquid isoparaffin 80.0
(2) 1,3-butylene glycol 14.5
(3) Methylphenylpolysiloxane 5.0
(4) Gemini type cationic activator 0.2
(In general formula (I), R ¹ and R ² are stearyl groups, R ³ , R ⁴ , R ⁵ and R ⁶ are methyl groups, and X is a chlorine atom)
(5) Perfume appropriate amount <Production method>
After mixing (1) to (3), add (4) to make uniform, and finally add (5).

[Example 38] Hair spray
Compounding component amount (% by mass)
(1) Volatile isoparaffin 16.0
(2) Dimethylpolysiloxane (6cs) 7.0
(3) Propylene glycol 15.0
(4) Ethanol appropriate amount (5) Purified water 2.0
(6) Poly (oxyethylene / oxypropylene) / methylpolysiloxane copolymer
4.0
(7) Gemini-type cationic activator 0.2
(In general formula (I), R ¹ and R ² are lauryl groups, R ³ , R ⁴ , R ⁵ and R ⁶ are methyl groups, and X is a chlorine atom)
(8) Perfume appropriate amount
(9) LPG residue <Production method>
(3) to (7) are mixed and the mixture of (1) to (2) is added and emulsified. After adding (8) and making it uniform, the container is filled together with (9).

[Example 39] Hair mousse (aerosol)
Compounding component amount (% by mass)
(1) Ethanol 5.0
(2) Dimethylpolysiloxane (6cs) 5.0
(3) Volatile isoparaffin 25.0
(4) 1,3-butylene glycol 25.0
(5) Isostearic acid 1.0
(6) Polyoxyethylene hydrogenated castor oil 1.0
(7) 2-alkyl-N-carboxymethyl 6.0
-N-hydroxyethylimidazolinium betaine (8) Phenoxyethanol appropriate amount (9) Purified water Residual (10) Gemini-type cationic activator 0.1
(In general formula (I), R ¹ and R ² are behenyl groups, R ³ , R ⁴ , R ⁵ and R ⁶ are methyl groups, and X is a chlorine atom)
(11) Perfume appropriate amount <Production method>
What mixed (1)-(3) and (11) is added to what mixed (4)-(10), and it emulsifies.

[Example 40] Hair cream
Compounding component amount (% by mass)
(1) Volatile isoparaffin 10.0
(2) Dimethylpolysiloxane (6cs) 1.0
(3) Ethanol 10.0
(4) 1,3-butylene glycol 15.0
(5) POE (14) POP (7) Dimethyl ether 1.0
(6) Isostearic acid 0.5
(7) Polyoxyethylene hydrogenated castor oil 0.1
(8) 2-alkyl-N-carboxymethyl
-N-hydroxyethylimidazolinium betaine 1.0
(9) Sodium hydroxide 0.3
(10) Carboxyvinyl polymer 0.8
(11) Appropriate amount of paraoxybenzoate (12) Gemini-type cationic activator 0.5
(In general formula (I), R ¹ and R ² are cetyl groups, R ³ , R ⁴ , R ⁵ and R ⁶ are methyl groups, and X is a chlorine atom)
(13) Trisodium edetate appropriate amount (14) Purified water Residue (15) Fragrance proper amount <Production method>
(5) to (13) are mixed and homogenized, and the mixture of (1) to (4) and (15) is added and emulsified. After adding (15), neutralize in (13) and further stir to make uniform.

[Example 41] Hair cream
Compounding component amount (% by mass)
(1) Liquid paraffin 5.0
(2) Vaseline 2.0
(3) Dimethylpolysiloxane (6cs) 5.0
(4) Cetanol 4.0
(5) Stearyl alcohol 1.0
(6) Gemini-type cationic activator 0.2
(In general formula (I), R ¹ and R ² are stearyl groups, R ³ , R ⁴ , R ⁵ and R ⁶ are methyl groups, and X is a methyl sulfate ion)
(7) 1,3-butylene glycol 10.0
(8) Polyoxyethylene / polyoxypropylene dimethyl ether 2.0
(9) Polyoxypropylene glyceryl ether 2.0
(10) Polyoxyethylene glyceryl isostearate 2.0
(11) Lipophilic glyceryl monostearate 2.0
(12) Polymer JR-400 ^TM (manufactured by Toho Chemical Industry Co., Ltd.) 0.5
(13) Hydrolyzed wheat protein 0.1
(14) Paraoxybenzoic acid ester appropriate amount (15) Purified water Residue (16) Fragrance appropriate amount <Production method>
The oil phases (1) to (6) and the aqueous phases (7) to (15) are dissolved and mixed by heating, and (16) is added to the oil phase to make it uniform. Mix and emulsify.

[Example 42] Hair cream
Compounding component amount (% by mass)
(1) Liquid paraffin 10.0
(2) Petrolatum 3.0
(3) Dimethylpolysiloxane (6cs) 2.0
(4) Propylene glycol 5.0
(5) Polyoxypropylene (40) butyl ether 2.0
(6) Gemini type cationic activator 0.05
(In general formula (I), R ¹ and R ² are stearyl groups, R ³ , R ⁴ , R ⁵ and R ⁶ are methyl groups, and X is a chlorine atom)
(7) Tetra-2-ethylhexanoic acid pentaerythritol 3.0
(8) Polyoxyethylene hydrogenated castor oil 2.0
(9) Potassium hydroxide 0.1
(10) Carboxyvinyl polymer 0.3
(11) Hydroxyethyl polyacrylate
-Acryloyldimethyltaurine sodium copolymer 0.1
(12) Purified water Residue (13) Perfume appropriate amount <Production method>
The mixture of (1) to (7) and (13) is added to the mixture of (8) to (11) and emulsified. (11) is added to make uniform, then neutralized with (12), and further stirred to make uniform.

[Example 43] Hair lotion
Compounding component amount (% by mass)
(1) Light isoparaffin 15.0
(2) Dimethyl silicone 6.0
(3) Sorbitol 20.0
(4) Polyoxyethylene (60 mol) hydrogenated castor oil esthetic 2.0
(5) Titanium oxide sol 10.0
(6) Ethanol 15.0
(7) Gemini-type cationic activator 0.5
(In general formula (I), R ¹ and R ² are stearyl groups, R ³ , R ⁴ , R ⁵ and R ⁶ are methyl groups, and X is a bromine atom)
(8) Purified water Residue (9) Perfume appropriate amount <Production method>
A mixture of (1) to (2) and (9) is added to (4) to (8) and emulsified.

[Example 44] Hair mist
Compounding component amount (% by mass)
(1) Dimethylpolysiloxane (6cs) 1.0
(2) Ethanol 5.0
(3) Stearyl alcohol 0.1
(4) Behenyl alcohol 0.2
(5) Glycerin 20.0
(6) Dipropylene glycol 1.0
(7) 1,3-butylene glycol 1.0
(8) Alkyltrimethylammonium chloride (77%) 0.5
(9) Gemini-type cationic activator 0.5
(In general formula (I), R ¹ and R ² are stearyl groups, R ³ , R ⁴ , R ⁵ and R ⁶ are methyl groups, and X is a chlorine atom)
(10) Vinylpyrrolidone
N, N-dimethylaminoethyl methacrylic acid copolymer 2.5
(11) Arginine 0.1
(12) Lecithin 0.1
(13) Octyl methoxycinnamate 0.1
(14) Paraoxybenzoic acid ester appropriate amount (15) Purified water Residue (16) Fragrance appropriate amount <Production method>
The oil phase mixed with (1) to (4) and the aqueous phase mixed with (5) to (15) are heated and dissolved, and the former is added to the latter and emulsified. Add (16) to make uniform.

[Example 45] Rinse
Compounding component amount (% by mass)
(1) Dimethylpolysiloxane (6cs) 10.0
(2) Hardened rapeseed oil alcohol 3.0
(3) Cetanol 1.5
(4) Sucrose 20.0
(5) Cetyl 2-ethylhexanoate 2.0
(6) Alkyltrimethylammonium chloride 1.5
(7) Gemini-type cationic activator 1.0
(In general formula (I), R ¹ and R ² are stearyl groups, R ³ , R ⁴ , R ⁵ and R ⁶ are methyl groups, and X is a chlorine atom)
(8) Sorbitol 2.0
(9) Glutamic acid 0.5
(10) Arginine 0.1
(11) Glycine 0.1
(12) Citric acid 0.01
(13) Tocopherol acetate 0.05
(14) Paraoxybenzoic acid ester appropriate amount (15) Phenoxyethanol appropriate amount (16) Hydroxyethyl cellulose 0.05
(17) Purified water Residue (18) Perfume appropriate amount <Production method>
Mix water-soluble components other than (15) and dissolve by heating to make uniform. The oil-soluble component is mixed with this and heated and dissolved, and then emulsified. Add (15) and (18) to make uniform, then cool.

[Example 46] Hair conditioner
Compounding component amount (% by mass)
(1) Isopentyldiol 5.0
(2) Sorbitol 15.0
(3) Dimethicone (1 million cSt) 1.5
(4) Dimethicone (20 cSt) 2.0
(5) Stearyl alcohol 3.0
(6) Behenyl alcohol 2.0
(7) Gemini-type cationic activator 2.0
(In general formula (I), R ¹ and R ² are stearyl groups, R ³ , R ⁴ , R ⁵ and R ⁶ are methyl groups, and X is a chlorine atom)
(8) Cetyl isooctanoate 1.0
(9) Arginine 0.01
(10) PEG-90M 0.02
(11) Stearyl dihydroxypropyl dimonium oligosaccharide 0.05
(12) Citric acid 0.07
(13) Phenoxyethanol appropriate amount (14) Blended fragrance Appropriate amount (15) Soybean lecithin 0.1
(16) Hydrolyzed wheat protein / hydrolyzed wheat starch 0.02
(17) N-lauroyl glutamic acid
Di (phytosteryl / 2-octyldodecyl) 0.1
(18) Purified water residue <Production method>
Mix water-soluble components other than (15) and dissolve by heating to make uniform. The oil-soluble component is mixed with this and heated and dissolved, and then emulsified. Add (15) and (18) to make uniform, then cool.

Claims (2)

A hair cosmetic containing the following components (A) and (B).
(A) 0.01-10.0 mass% of 1 or more types of gemini type | mold cationic activator represented by general formula (I) with respect to hair cosmetics.
[Wherein R ¹ and R ² are linear or branched saturated or unsaturated alkyl groups having 5 to 25 carbon atoms, and R ³ , R ⁴ , R ⁵ and R ⁶ are each a carbon atom number. 1 to 5 alkyl groups, and X is a halogen atom or a short-chain sulfate ion group. ]
(B) 10.0-50.0 mass% of 1 or more types of a polyhydric alcohol and / or saccharides with respect to hair cosmetics. In the hair cosmetic composition, the polyhydric alcohol constituting the component (B) is selected from the group consisting of dipropylene glycol, propylene glycol, ethylene glycol, glycerin, diglycerin, isoprene glycol and 1,3-butylene glycol. The hair cosmetic composition according to claim 1, wherein the saccharide is one or more selected from the group consisting of xylitol, fructose, sorbitol, mannitol, inositol, glucose, lactose, maltitol and sucrose.