JP2008201727A - Hair color conditioning composition - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a hair color conditioning composition having good dyeing property and color fastness and excellent usability and minimizing the damage of the hair. <P>SOLUTION: A hair color conditioning composition composed of a first agent containing a reducing agent and an alkali agent and a second agent containing an oxidizing agent is compounded with a specific hydroxyether amine compound or its quaternary ammonium salt and a specific Gemini cationic surfactant. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

  The present invention is a composition for adjusting the color of hair, more specifically, for use in a hair treatment aimed at adjusting the color of hair, such as, for example, decolorization treatment or hair coloring treatment of hair. It is invention regarding the composition of this.

  In the oxidative hair dye, the hair dyeing is performed by causing the oxidative dye to permeate into the hair and performing oxidative polymerization in the hair to form a pigment and dye it. This oxidative hair dye is usually composed of an oxidation dye such as paraphenylenediamine or toluene-2,5-diamine sulfate, a first agent mainly composed of an alkaline agent such as ammonia or monoethanolamine, hydrogen peroxide, etc. And a second agent mainly composed of an oxidizing agent.

  Further, in the case of a hair bleaching agent, unlike an oxidative hair dye, a feature of one constitution is that an oxidative dye is not blended with the first agent. The agent (booster) can be mixed at the time of use.

  These hair color adjusting compositions (hair dye compositions and hair bleaching agent compositions) are prepared so as to be alkaline when used (mixed), and are incorporated into the composition by swelling hair. This facilitates the penetration of the substances in the hair and promotes the release of oxygen during the nascent stage from the oxidant. This nascent oxygen decomposes and decolorizes the melanin pigment in the hair, and when the hair color adjusting composition is an oxidative hair dye, oxidatively polymerizes the oxidative dye contained in the first agent, This produces a pigment.

  However, the hair dye composition and the hair bleaching composition are strong in the action of the alkaline agent and the oxidizing agent, so the influence on the hair is great, causing damage to the hair, losing a smooth feel, being crusty, There is a strong tendency to become worried. Such hair damage is accumulated by repeated dyeing or decoloring, and is particularly noticeable at the hair ends where the number of treatments increases.

  Furthermore, there is a tendency that the strength of the hair decreases due to hair damage and the dyeing fastness (the degree to which the dyed color lasts) deteriorates. The deterioration of dyeing fastness means that the dyed color fades early and the color immediately after dyeing does not last for a long time.

  Particularly recently, since the demand for hair dyeing and decolorization of hair is increasing, interest in hair feel and damage by hair dyes and decoloring agents is increasing.

As a method for solving such a problem, a specific alkaline agent is blended (Patent Document 1), a combination of a cationic surfactant and 8-oxyquinoline as an oxidizing agent (Patent Document 2), a specific non-chemical agent. Attempts have been made to combine ionic surfactants and specific quaternary ammonium salts (Patent Document 3), and combinations of amino acids, protein hydrolysates, amino-modified silicones (Patent Documents 4 to 6). However, it cannot be said that a sufficient effect has been recognized.
Japanese Patent Laid-Open No. 10-45547 JP-A-11-193224 JP 2001-2537 A JP 7-330559 A JP-A-7-330560 JP 2004-175748 A JP 2004-323495 A U.S. Pat. No. 4,734,277 U.S. Pat. No. 4,764,306 U.S. Pat. No. 4,812,263

  Accordingly, an object of the present invention is to provide a hair color adjustment composition (hair dye composition and hair, which has good dyeability and fastness to dyeing, and has excellent usability and minimizes hair damage. A depigmenting agent composition).

  As a result of intensive investigations in view of the above problems, the present inventors have incorporated a specific surfactant into the hair color adjustment composition, that is, the hair dye composition and the hair bleaching composition. The present inventors have found that the above problems can be solved and have completed the present invention.

  That is, this invention contains the following component (A) and / or (B) in the composition for hair color adjustment containing the 1st agent containing an alkaline agent and the 2nd agent containing an oxidizing agent. The present invention provides a hair color adjusting composition (hereinafter also referred to as the present composition).

(A) A hydroxy ether amine compound represented by the following formula (I) or a quaternary ammonium salt thereof represented by the following formula (II).

[In the formulas (I) and (II), R ¹ , R ² , R ³ and R ⁴ are each an alkyl group having 1 to 3 carbon atoms, or a hydroxyalkyl group thereof, or represented by the following general formula (III): And at least one of R ^{1 to} R ³ is a group represented by the following general formula (III). X represents a halogen atom or an organic sulfur acid group having 1 or 2 carbon atoms. ]

[In the formula (III), R ⁵ is a linear or branched alkyl group, alkenyl group or hydroxyalkyl group having 6 to 24 carbon atoms, and the bond number n is an integer of 1 to 5. ]

(B) A gemini-type cationic activator represented by the following formula (IV).

[In the formula (IV), R ⁶ and R ⁷ are linear or branched saturated or unsaturated alkyl groups having 5 to 25 carbon atoms, and R ⁸ , R ⁹ , R ¹⁰ and R ¹¹ are respectively It is a C1-C5 alkyl group, Y represents a halogen atom or a C1-C2 organic sulfur acid group. ]

  In the present invention, the “hair color adjusting composition” refers to a “hair dye composition” used in a treatment for positively imparting color to hair, and a “hair bleaching” used in a treatment for decolorizing hair. It is a conceptual composition that combines the “agent composition”. Both the “hair dye composition” and the “hair depigmenting composition” use an alkaline agent in the first agent to swell the hair and penetrate the substance contained in the composition into the hair. It is common in the principle of facilitating and using an oxidizing agent in the second agent to promote the release of nascent oxygen and decolorize the melanin pigment in the hair.

  According to the present invention, a hair color adjusting composition (a hair dye composition and a hair bleaching agent composition) having good dyeability and fastness to dyeing, excellent use feeling, and minimizing hair damage. ) Is provided.

[Ingredients of this composition]
As described above, the present composition exhibits its effect by containing the component (A) and / or (B).

Ingredient (A)
Component (A) is a hydroxy ether amine compound represented by the above general formula (I) or a quaternary ammonium salt thereof represented by the general formula (II).

  Component (A) can be produced by a known production method (for example, Patent Document 7), and a commercially available product can also be used (for example, kachinal SHPA-80: N- ( 2-Hydroxy-3-stearoxypropyl-N, N-dimethylamine (manufactured by Toho Chemical Industries).

In these general formulas (I) and (II), examples of the alkyl group having 1 to 3 carbon atoms that R ^{1 to} R ⁴ can take include a methyl group, an ethyl group, a propyl group, and an isopropyl group. Examples of the hydroxyalkyl group include a methoxy group, an ethoxy group, a propoxy group, and an isopropoxy group.

In addition, in the group represented by the general formula (III) that can be taken by R ^{1 to} R ^4, the linear or branched alkyl group having 6 to 24 carbon atoms that R ⁵ can take is limited in this range. Although not, for example, hexyl group, heptyl group, octyl group, nonyl group, decyl group, undecyl group, lauryl group, tridecyl group, myristyl group, pentadecyl group, palmityl group, heptadecyl group, stearyl group, nonadecyl group, Examples include icosyl group, behenyl group, tricosyl group, tetracosyl group and the like. The alkenyl group is not limited in this range, but examples thereof include a myristoyl group, a palmitoyl group, an oleyl group, and a linoleyl group. Further, the hydroxyalkyl group is not limited to this range, but hexyloxy group, heptyloxy group, octyloxy group, nonyloxy group, decyloxy group, undecyloxy group, lauryloxy group, tridecyloxy group. Group, myristyloxy group, pentadecyloxy group, palmityloxy group, heptadecyloxy group, threallyloxy group, nonadecyloxy group, icosyloxy group, behenyloxy group, tricosyloxy group, tetracosyloxy group, etc. .

  Examples of the halogen atom which X in the quaternary ammonium salt (II) can take include a fluorine atom, a chlorine atom, a bromine atom or an iodine atom. Examples of the organic sulfur acid group having 1 or 2 carbon atoms include a sulfomethyl group and a sulfoethyl group.

  Component (A) can contain one or more of a hydroxy ether amine compound or a quaternary ammonium salt derived from the above formulas (I) and (II) in the present composition.

Ingredient (B)
Component (B) is a gemini-type cationic activator represented by the above general formula (IV). The linear or branched saturated or unsaturated alkyl group having 5 to 25 carbon atoms that R ⁶ and R ⁷ can take is not particularly limited, and examples thereof include the alkyl groups exemplified above for R ^{1 to} R ^4. Or an alkenyl group (an alkyl group or alkenyl group having 6 to 24 carbon atoms: accordingly, R ⁶ and R ⁷ have a carbon atom number in the range of 5 to 25. Examples of 5 carbon atoms include Examples of the pentyl group and 25 include, but are not limited to, a pentacosyl group, and a stearyl group or a behenyl group is particularly preferable. R ⁸ , R ⁹ , R ¹⁰ and R ¹¹ which are alkyl groups having 1 to 5 carbon atoms are, in particular, methyl groups, ethyl groups or propyl groups which are alkyl groups having 1 to 3 carbon atoms. It is preferable that Examples of the halogen atom that Y can take include a fluorine atom, a chlorine atom, a bromine atom, and an iodine atom. Examples of the organic sulfur acid group having 1 or 2 carbon atoms include a sulfomethyl group and a sulfoethyl group.

  The cationic activator (IV) can be produced according to the production method disclosed in US Patent Publications (US; 4734277, 4764306, 4812263: Patent Documents 8 to 10).

  Component (B) may contain one or more gemini-type cationic activators derived from the above formula (IV) in the present composition.

Ingredients Used in Hair Color Adjustment Composition As described above, the present composition comprises at least a first agent that improves the infiltration of the component into the hair and a second agent that decolorizes the melanin pigment in the hair. It is a “multiple dosage form” hair composition.

  The component (A) and / or (B) described above can be contained in any or all of the respective agents of the present composition (typically, the first agent and the second agent).

  The content of the component (A) in the present composition is preferably about 0.01 to 10.0% by mass, particularly 0.05 to 5.0% by mass, based on the total mass of each agent constituting the present composition. Is preferred. Moreover, about 0.01-10.0 mass% is preferable with respect to the total mass of each agent which comprises this composition, and content of the component (B) in this composition is 0.05-5.0 especially. Mass% is preferred. Moreover, when combining this component (A) and (B) in this composition, both components are combined and 0.01-10.0 mass% with respect to the total mass of each agent of this composition. The degree is preferable, and 0.05 to 5.0% by mass is particularly preferable.

  In any combination pattern of the above components (A) and / or (B), the compounding amount of the component is less than 0.01% by mass with respect to the total mass of each agent constituting the composition. It becomes difficult to fully exhibit the desired effect of the present invention in terms of dyeing and decoloring, and further in terms of usability. If the amount exceeds 10.0% by mass, the feel of use of the composition tends to be poor. Become.

(A) First agent (i) common component Regardless of whether the present composition is a hair dye composition or a hair bleaching agent composition, an alkaline agent is blended in the first agent. By blending the alkaline agent, the infiltration of the components of the composition into the hair can be improved. Examples of the alkali agent that can be blended in the first agent of the present composition include ammonia and salts thereof; alkanolamines such as monoethanolamine, isopropanolamine, 2-amino-2-methylpropanol, and 2-aminobutanol and salts thereof An alkanediamine such as 1,3-propanediamine and a salt thereof; and carbonates such as guanidine carbonate, sodium carbonate, potassium carbonate, sodium bicarbonate, potassium bicarbonate, and the like. Among these alkali agents, ammonia and its salt, alkanolamine and its salt are preferable. More specifically, ammonium carbonate and ammonium hydrogen carbonate are preferable as the ammonium salt, and monoethanolamine is preferable as the alkanolamine.

  These alkali agents can be used by selecting one kind, or two or more kinds can be used in combination. The blending amount can be selected according to the specific mode and purpose of the present composition, other blending components, etc., but generally the hair color imparting effect (hair dyeing effect or decoloring effect) Is preferably in the range of 0.05 to 15.0% by mass with respect to the total mass of each agent constituting the composition, and is particularly preferably 0% as a range in which hair damage and scalp irritation can be reduced. 2 to 5.0% by mass is preferable.

(Ii) When the present composition is a hair dye composition When the present composition is a hair dye composition, an oxidation dye intermediate and / or a direct dye is blended in the first agent. When this composition is a hair dye composition, such a dye is a direct component of hair dyeing, and is an essential blending component together with the above component (A) and / or (B). When the present composition is a hair bleaching agent composition, such a dye is not necessary.

  Oxidative dye intermediates are roughly classified into precursors that develop color by their own oxidation and couplers that have various color tones depending on the combination of the precursors. In the first component of the composition, both of these are blended. be able to. Examples of the precursor include paraphenylenediamine, toluene-2,5-diamine, 2-chloro-paraphenylenediamine, N-methoxyethyl-paraphenylenediamine, and N, N-bis (2-hydroxyethyl) -paraphenylenediamine. 2- (2-hydroxyethyl) -paraphenylenediamine, 2,6-dimethyl-paraphenylenediamine, 4,4'-diaminodiphenylamine, 1,3-bis (N- (2-hydroxyethyl) -N- ( 4-aminophenyl) amino) -2-propanol, PEG-3,3,2'-paraphenylenediamine, paraaminophenol, paramethylaminophenol, 3-methyl-4-aminophenol, 2-aminomethyl-4-amino Phenol, 2- (2-hydroxyethylaminomethyl) -4-aminophenol, orthoaminophenol, 2-amino-5-methylphenol, 2-amino-6-methylphenol, 2-amino-5-aceta Dophenol, 3,4-diaminobenzoic acid, 5-aminosalicylic acid, 2,4,5,6-tetraaminopyrimidine, 2,5,6-triamino-4-hydroxypyrimidine, 4,5-diamino-1- ( 4'-chlorobenzyl) pyrazole, 4,5-diamino-1-hydroxyethylpyrazole and salts thereof.

  Examples of couplers include metaphenylenediamine, 2,4-diaminophenoxyethanol, 2-amino-4- (2-hydroxyethylamino) anisole, 2,4-diamino-5-methylphenetole, 2,4- Diamino-5- (2-hydroxyethoxy) toluene, 2,4-dimethoxy-1,3-diaminobenzene, 2,6-bis (2-hydroxyethylamino) toluene, 2,4-diamino-5-fluorotoluene, 1,3-bis (2,4-diaminophenoxy) propane, metaaminophenol, 2-methyl-5-aminophenol, 2-methyl-5- (2-hydroxyethylamino) phenol, 2,4-dichloro-3 -Aminophenol, 2-chloro-3-amino-6-methylphenol, 2-methyl-4-chloro-5-aminophenol, N-cyclopentyl-metaaminophenol, 2-methyl-4-methoxy-5- (2 -Hydroxyethylamino) phenol, 2-methyl-4-fluoro-5- Minophenol, resorcin, 2-methylresorcin, 4-chlororesorcin, 1-naphthol, 1,5-dihydroxynaphthalene, 1,7-dihydroxynaphthalene, 2,7-dihydroxynaphthalene, 2-isopropyl-5-methylphenol, 4 -Hydroxyindole, 5-hydroxyindole, 6-hydroxyindole, 7-hydroxyindole, 6-hydroxybenzomorpholine, 3,4-methylenedioxyphenol, 2-bromo-4,5-methylenedioxyphenol, 3,4 -Methylenedioxyaniline, 1- (2-hydroxyethyl) amino-3,4-methylenedioxybenzene, 2,6-dihydroxy-3,4-dimethylpyridine, 2,6-dimethoxy-3,5-diaminopyridine 2,3-diamino-6-methoxypyridine, 2-methylamino-3-amino-6-methoxypyridine, 2-amino-3-hydroxypyridine, 2,6-diaminopyridine and the like And the like salts and the like of.

  The compounding amount of the oxidation dye intermediate is preferably 0.01 to 5.0% by mass with respect to the total mass of each agent constituting the composition alone or in combination of two or more. 0.1-4.0 mass% is suitable.

  It is also possible to mix | blend a dye directly with this composition 1st agent. Specifically, examples of the direct dye include nitro dyes, disperse dyes, and basic dyes. Examples of the nitro dye include 2-nitro-paraphenylenediamine, 2-amino-6-chloro-4-nitrophenol, 3-nitro-parahydroxyethylaminophenol, 4-nitro-orthophenylenediamine, 4-amino- 3-Nitrophenol, 4-hydroxypropylamino-3-nitrophenol, HC Blue No.2, HC Orange No.1, HC Red No.1, HC Yellow No.2, HC Yellow No.4, HC Yellow No. 5, HC Red No. 3, N, N-bis- (2-hydroxyethyl) -2-nitro-paraphenylenediamine and the like. Examples of disperse dyes include Disperse Violet 1, Disperse Blue 1, Disperse Black 9, and the like. Examples of the basic dye include Basic Blue 99, Basic Brown 16, Basic Brown 17, Basic Red 76, Basic Red 51, Basic Yellow 57, Basic Yellow 87, Basic Orange 31 and the like.

  The blending amount of the direct dye is preferably 0.01 to 5.0% by mass, particularly 0%, based on the total mass of each agent constituting the composition, alone or in combination of two or more. .1 to 3.0% by mass is preferable.

(B) 2nd agent An oxidizing agent is mix | blended with the 2nd agent of this composition. As described above, the oxidizing agent has a function of promoting decolorization of the melanin pigment in the hair, and exhibits an effect of determining the coloring effect of the oxidizing dye intermediate in the hair dye composition.

  The oxidizing agent is not particularly limited, and a wide variety of known oxidizing agents that can be used in the hair color adjusting composition can be used. For example, hydrogen peroxide, hydrogen peroxide salt (sodium hydrogen peroxide, etc.), peroxide salt (ammonium peroxide, potassium peroxide, etc.), persulfate, perborate (sodium perborate, ammonium perborate) , Potassium perborate, etc.), bromate (sodium bromate, etc.), periodate, urea peroxide, percarbonate (sodium percarbonate, etc.). 0.1-12.0 mass% is suitable for the compounding quantity of an oxidizing agent individually or in combination of 2 or more types with respect to the total mass of each agent which comprises this composition, and especially the same 0 0.1 to 12.0% by mass is preferable, and 0.5 to 9.0% by mass is extremely preferable, and 1.0 to 6.0% by mass is most preferable.

  In particular, among the above oxidizing agents, a third agent generally referred to as a persulfate such as ammonium persulfate or a booster can be incorporated when the present composition is a hair bleaching composition. The third agent in this case (usually a solid dosage form) can be used to further promote the hair decoloring effect.

(C) Components that can be blended in each agent In addition to the components (A) and / or (B) described above, examples of components that can be blended in each component of the present composition include the following. .

  In the composition, a higher alcohol can be contained in any or all of the respective agents constituting the composition from the viewpoint of improvement in feel and stability. These have the effect of forming a structure with a surfactant to prevent separation and improving the feel during rinsing.

  As the higher alcohol, those having 8 to 22 carbon atoms, particularly 16 to 22 carbon atoms are preferable. Specifically, cetyl alcohol, stearyl alcohol, cetostearyl alcohol, aralkyl alcohol, behenyl alcohol, isostearyl alcohol, oleyl alcohol, 2 -Hexyl decanol, 2-octyl dodecanol and the like, and mixtures thereof.

  The blending amount of the higher alcohol is preferably from 0.01 to 20.0% by mass based on the total mass of each agent constituting the composition, alone or in combination of two or more, and particularly the same 0 0.1-10.0 mass% is suitable.

  In the composition, a surfactant is included in addition to the cationic surfactant (IV) in any or all of the components constituting the composition as long as the intended effect of the present invention is not impaired. be able to. Specifically, nonionic surfactants, anionic surfactants, cationic surfactants, and amphoteric surfactants are preferred, with nonionic surfactants and cationic surfactants being particularly preferred.

  Specific examples of the nonionic surfactant include, for example, POE alkyl ethers, POE alkyl phenyl ethers, POE / POP alkyl ethers, POE fatty acids, POE sorbitan fatty acid esters, POE castor oil, POE hydrogenated castor oil POE sorbitol tetrafatty acid ester, glycerin fatty acid ester, sorbitan fatty acid ester, polyglycerin fatty acid ester, sucrose fatty acid ester, alkyl polyglycoside, N-alkyldimethylamine oxide, POE propylene glycol fatty acid ester, and the like. Among these, POE alkyl ethers, POE alkyl phenyl ethers, POE / POP alkyl ethers, POE sorbitan fatty acid esters and the like are preferable, and POE alkyl ethers are more preferable because they are strong against acids and alkali agents. Specific examples of POE alkyl ethers include POE lauryl ether, POE cetyl ether, POE stearyl ether, and POE behenyl ether.

  Specific examples of the cationic activator include, for example, alkyl trimethyl ammonium chloride, lauryl trimethyl ammonium chloride, cetyl trimethyl ammonium chloride, stearyl trimethyl ammonium chloride, stearyl trimethyl ammonium bromide, lauryl trimethyl ammonium bromide, dialkyl dimethyl ammonium chloride, ethyl sulfate. And quaternary ammonium salts such as lanolin fatty acid aminopropylethyldimethylammonium, cetyltrimethylammonium saccharin, stearyltrimethylammonium saccharin, behenyltrimethylammonium chloride, and behenyltrimethylammonium bromide.

  These surfactants may be blended singly or in combination of two or more by selecting the blending amount according to need.

  In the composition, a conditioning component that is generally used can be blended in any or all of the agents constituting the composition, as long as the effects of the present invention are not impaired. Examples of the conditioning component include silicones and cationic polymers.

  Specific examples of silicones include dimethylpolysiloxane, methylphenylpolysiloxane, methylcyclopolysiloxane, polyether modified silicone, amino modified silicone, betaine modified silicone, alkyl modified silicone, alkoxy modified silicone, fluorine modified silicone, perfluoroalkyl. Examples thereof include polyoxyalkylene-modified silicone and dimethylpolysiloxane having a hydroxy end group. These components may be blended singly or in combination of two or more. As for the degree of polymerization of silicones, generally, those having a number average degree of polymerization of 1000 or less have good emulsion stability, and highly polymerized silicones of 1000 or more can obtain a good feel.

  Cationic polymers refer to polymers having a cationic group or a group that can be ionized to a cationic group, and also include amphoteric polymers that are cationic as a whole. That is, as the cationic polymer, an aqueous solution containing an amino group or an ammonium group in the side chain of the polymer chain or containing a diallyl quaternary ammonium salt as a structural unit, such as a cationized cellulose derivative, a cationic starch, a cationization Examples include guar gum derivatives, diallyl quaternary ammonium salt polymers or copolymers, and quaternized polyvinylpyrrolidone derivatives.

  Specific examples of the polymer or copolymer of diallyl quaternary ammonium salt include dimethyldiallylammonium chloride polymer (Polyquaternium-6, such as Marquat 100; ONDEO Nalco), dimethyldiallylammonium chloride / acrylic acid copolymer (polyquaternium). -22, such as Marquat 280, 295; ONDEO Nalco), and dimethyldiallylammonium chloride / acrylamide copolymer (Polyquaternium-7, such as Marquat 550; ONDEO Nalco).

  The above-described conditioning component may be blended alone or in combination with two or more of each agent constituting the composition. The larger the amount, the higher the effect. However, when the amount is too large, the stability becomes poor, and a tendency to cause a decrease in the viscosity of the agent alone or during mixing appears. From these points, the blending amount of the conditioning component is preferably 0.001 to 20.0% by mass with respect to the total mass of each agent constituting the composition, and further 0.01 to 10.0%. % By mass, particularly 0.05 to 5.0% by mass is preferred.

  In the present composition, water or an organic solvent is used as a medium in each agent. Examples of organic solvents include lower alcohols such as ethanol and 2-propanol, aromatic alcohols such as benzyl alcohol and benzyloxyethanol, polyols such as propylene glycol, 1,3-butanediol, diethylene glycol, and glycerin, ethyl cellosolve, Examples thereof include cellosolves such as butyl cellosolve and benzyl cellosolve, and carbitols such as ethyl carbitol and butyl carbitol.

  In the case of a typical two-agent type, the pH at 25 ° C. of the present composition is preferably 7 to 12 for the first agent and 2 to 5 for the second agent. -From the point of a hair dyeing effect and skin irritation, 8-11 are preferable. As the pH adjuster, in addition to the above alkaline agents, inorganic acids (hydrochloric acid, phosphoric acid, etc.), organic acids (citric acid, glycolic acid, lactic acid, etc.), hydrochlorides (monoethanolamine hydrochloride, etc.), phosphates ( Monopotassium dihydrogen phosphate, disodium monohydrogen phosphate, etc.).

  In addition to the above components, other components usually used as cosmetic raw materials can be added to the composition. Such optional components include hydrocarbons, animal and vegetable fats and oils, higher fatty acids, components, natural or synthetic polymers, ethers, protein derivatives, hydrolyzed proteins, amino acids, preservatives, chelating agents, stabilizers. , Antioxidants, plant extracts, herbal extracts, vitamins, fragrances, pigments, UV absorbers.

[Specific form of the present composition]
This composition is a two-component type comprising a first agent containing an alkaline agent and a second agent containing an oxidizing agent such as hydrogen peroxide, as well as the currently used oxidative hair dye or decoloring agent. In addition, in the case of a hair bleaching composition, it is typically provided as a three-part type in which a powdery oxidant composed of a granulated product such as persulfate is further combined as the third agent. It is an aspect. That is, this composition is provided as a multi-component hair composition. This composition can exhibit the desired effect by using these individual agents mixed at the time of use. For example, when the present composition is a two-agent type, the mixing ratio of the first agent and the second agent is generally about 1: 1 to 1: 2 (mass ratio).

The dosage forms of the first agent and the second agent can be, for example, liquid, emulsion, cream, gel, paste, mousse, etc., and can also be aerosol. It is desirable that the first agent and the second agent (the third agent in the case of the three-agent type) are mixed and applied to the hair so that the viscosity becomes difficult to spill, and a B-type rotational viscometer at 25 ° C. It is preferable that the viscosity measured by (Bismetron VHS type, manufactured by Shibaura System Co., Ltd.) is in the range of 2000 to 100,000 mm ² / s. Here, the viscosity is a value after rotating for 1 minute using a No. 4 rotor.

  Hereinafter, the present invention will be specifically described by way of examples of the present invention, but the present invention is not limited thereto.

[Test example]
In this example, in order to verify the effects of the present invention, test products (Examples and Comparative Examples) of the present composition were prepared by a conventional method, and the following tests were performed.

  This test was conducted on a dye composition and a hair bleaching composition. Tables 1 to 4 show the prescriptions and test results of the test products.

  Among these tables, Tables 1 and 2 (Class A) disclose prescriptions and test results for test products using a hydroxy ether amine compound and a hydroxy ether amine quaternary ammonium salt as blending components. . Further, Table 1 (Examples A1 to A10, Comparative Examples A1 to A7) shows examples of hair dye compositions, and Table 2 (Examples A11 to A20, Comparative Examples A8 to A14) shows hair bleaching compositions. It is the disclosed table | surface about the example of.

  Moreover, Tables 3-4 (B classification) have disclosed the prescription and test result about the test article which uses the Gemini type | mold cationic activator as a compounding component. Further, Table 3 (Examples B11 to B20, Comparative Examples B8 to B14) is a table disclosed for examples of hair dye compositions, and Table 4 is a table for examples of hair bleaching agent compositions.

  Hereinafter, the contents of the tests conducted in this test example are (1) those performed in common in the dye composition and the hair bleaching composition, (2) those performed only in the dye composition, ( 3) Disclosed separately for hair depigmenting agent compositions.

(1) Common test As a common test mentioned above, the sensory test about hair damage and smoothness was done.
(Test method)
The first agent and the second agent prepared based on Examples and Comparative Examples disclosed in Tables 1 to 4 were mixed at a mass ratio of 1: 1, and the mixture was applied to a hair bundle of 20 g of human black hair, It was allowed to stand at room temperature for 30 minutes, washed and air dried. For each hair bundle, eight expert panels evaluated the feel of hair damage (damage), the smoothness of hair, and the like. The criteria for evaluation are as follows.
<Hair damage evaluation criteria>
◎: 7 or more subjects who answered that the hair was not damaged ○: 5 to 6 subjects who answered that the hair was not damaged Δ: Normal 3 to 4 subjects who said that the hair was not damaged ×: 2 subjects or less who answered that the hair was not damaged <Evaluation criteria for smoothness of hair>
◎: 7 or more subjects who answered that the hair was smooth ○: 5 or more subjects who answered that the hair was smooth Δ: 3 to 4 subjects who answered that the hair was smooth No more than 2 people: No more than 2 subjects who answered that their hair was smooth

(2) Test performed only on the dye composition (a) Dye test A dye test was performed on a hair dye composition in which an oxidation dye was blended with the first agent. The 1st agent and 2nd agent which were prepared based on prescription of the example and comparative example which were shown in Tables 1-2 were mixed by mass ratio of 1: 1, and the mixed liquid was applied to the hair bundle of 20g of human white hair. Then, it was allowed to stand at room temperature for 30 minutes, washed, and air-dried. About each hair | bristle bundle, the 8 expert panel observed the dyeing | staining state by visual observation. The evaluation criteria are as follows.
<Evaluation criteria for dyeability>
◎: 7 or more subjects who answered good dyeability ○: Good 5-6 subjects who answered good dyeability △: Normal 3-4 subjects who answered that dyeability was good ×: Bad No more than 2 subjects who answered that the staining was good

(B) Dye fastness test As in the above dyeability test, the test product of the dye composition (Examples and Comparative Examples shown in Tables 1 and 3) was applied to a hair bundle of 20 g of human white hair. The sample was allowed to stand at room temperature for 30 minutes, washed and air-dried. Thereafter, one of the two hair bundles was washed with a commercially available shampoo and air-dried 30 times repeatedly. The hair bundles subjected to shampoo treatment and the hair bundles not subjected to shampoo treatment were visually observed by 8 professional panels for each hair bundle. The evaluation criteria are as follows.
<Evaluation criteria for dyeing fastness>
◎: 7 or more subjects who answered that color fading was less than that of hair bundles that did not have shampoo treatment ○: 5 to 6 subjects that said that fading was less than hair strands that did not undergo shampoo treatment △ : 3 to 4 subjects who answered that there was less discoloration compared to normal hair bundles without shampoo treatment ×: 2 or less subjects who said that there was less discoloration compared to hair bundles without shampoo treatment

(3) Tests performed only on the hair bleaching agent composition Only the hair bleaching agent composition was subjected to the following bleaching test.
(Test method)
A decolorization test was conducted on a hair decolorant composition disclosed in Tables 2 and 4 and containing no oxidation dye in the first agent. The 1st agent and 2nd agent which were prepared based on the Example and the comparative example were mixed by mass ratio of 1: 1, and the liquid mixture was apply | coated to the hair bundle of 20g human hair black hair, and it was left to stand at room temperature for 30 minutes. And then air dried. About each hair | bristle bundle, the 8 expert panel observed the decoloring state by visual observation. The evaluation criteria are as follows.
<Decolorization evaluation criteria>
◎: 7 or more subjects who answered that decolorization was good ○: 5-6 subjects who answered that decolorization was good △: 3-4 subjects who answered that depilation was good ×: Bad Less than 2 subjects answered that depigmentation is good

(4) Preparation of test products According to the conventional method, the first agent of each test product is prepared as a creamy formulation by emulsifying oil components with a surfactant and then adding dyes, stabilizers, alkali agents, etc. in order. did. The second agent was prepared as a creamy formulation by emulsifying the oily component with a surfactant and then sequentially adding an oxidizing agent, a stabilizer and the like.

  About these test goods, about the dyeing | staining composition, the test was done according to said test procedure and method (1) and (2). The test results are also shown in Tables 1 and 3. Moreover, about the hair bleaching agent composition, it tested according to said test procedure and method (1) and (3). The test results are also shown in Tables 2 and 4. The unit of prescription in the table is all mass%.

The hydroxy ether amine compound (1) used in Table 1 and Table 2 is a hydroxy ether amine compound in which the component (A) is represented by the general formula (I), and R ^{1 in} the formula is A hydroxy ether amine compound (I) having the general formula (III), wherein R ⁵ is C ₁₈ H ₃₇ , n is 1, and R ² and R ³ are both methyl groups; ). The hydroxy ether amine quaternary ammonium salt (2) is a quaternary ammonium salt of a hydroxy ether amine compound in which the component (A) is represented by the general formula (II), and R ^{1 in} the formula is A group of general formula (III), in which R ⁵ is C ₁₈ H ₃₇ , n is 1, R ² , R ³ and R ⁴ are all methyl groups, Is a quaternary ammonium salt (II) of a hydroxy ether amine compound in which is a chlorine atom. These can be easily produced by a technique already disclosed, but commercially available products were obtained from Toho Chemical Industries.

Further, the gemini cation activator (1) used in Tables 3 and 4 is a gemini cation activator in which the component (B) is represented by the general formula (IV), and R in the formula ⁶ and R ⁷ are C ₁₈ H ₃₇ , R ^{8 to} R ¹¹ are methyl groups, and Y is a chlorine atom. The gemini-type cation activator (2) is a gemini-type cation activator in which the component (B) is represented by the general formula (IV), in which R ⁶ and R ⁷ are C ₁₂ H ₂₅ Yes, R ^{8 to} R ¹¹ are methyl groups, and Y is a chlorine atom. These can be easily produced by a technique already disclosed, but commercially available products were obtained from Toho Chemical Industries.
(5) Test example prescription and test results

  From Table 1, the following became clear. That is, among the present compositions used by blending the component (A), the hair dye compositions (Examples A1 to A10) are excellent in dyeability and dyeing fastness, have very little hair damage, and hair. It was found to be excellent in conditioning effect and very smooth. On the other hand, Comparative Examples A1 to A7 were inferior in dyeability, dyeing fastness, hair damage, and smoothness, and the object of the present invention could not be achieved.

  From Table 2, the following became clear. That is, among the present compositions used by blending the component (A), the hair decoloring compositions (Examples A11 to A20) are excellent in depigmenting properties, have very little hair damage, and have a hair conditioning effect. It was found to be excellent and very smooth. On the other hand, in Comparative Examples A8 to A14, decolorization property, hair damage, and smoothness were inferior, and the object of the present invention could not be achieved.

  From Table 3, the following became clear. That is, among the present compositions used by blending the component (B), the hair dye compositions (Examples B1 to B10) are excellent in dyeability and dyeing fastness, have very little hair damage, and hair. It was found to be excellent in conditioning effect and very smooth. On the other hand, Comparative Examples B1 to B7 were inferior in dyeability, dyeing fastness, hair damage, and smoothness, and the object of the present invention could not be achieved.

  From Table 4, the following became clear. That is, among the present compositions used by blending the component (A), the hair decoloring compositions (Examples B10 to B20) are excellent in depigmenting properties, have very little hair damage, and have a hair conditioning effect. It was found to be excellent and very smooth. On the other hand, in Comparative Examples B8 to B14, decolorization property, hair damage, and smoothness were inferior, and the object of the present invention could not be achieved.

  Below, the formulation example of this composition is shown as an Example. The classification of A and B in each prescription example is in accordance with the classification described above based on essential blending components. In each formulation example, the dye composition was excellent in both dyeability and dyeing fastness, had little hair damage, and had a smooth hair finish. Further, the hair bleaching agent composition was excellent in hair bleaching performance, had little hair damage, and had a smooth hair finish. In addition, although the component (A) and (B) which were mentioned above in the following prescription example can be easily manufactured by the already published technique, the commercial item was obtained from Toho Chemical Industry Co., Ltd. and used.

[Example A21] Low odor cream hair color
(First Agent) Compounding amount (% by mass)
28% ammonia water 0.5%
Ammonium carbonate 2.0%
Monoethanolamine 2.0%
Isopropanolamine 1.0%
Paraphenylenediamine 1.5%
Resorcin 0.5%
Metaaminophenol 0.3%
Paraaminophenol 0.5%
2,4-Diaminophenoxyethanol 0.2%
Cetanol 7.0%
POE (12) cetyl ether 1.0%
POE (25) lauryl ether 1.0%
Hydroxy ether amine compound (I) 0.4%
(R ¹ = formula ^{(III) / R 5 = C} 22 H 45, R 2~3 = CH 3, n = 1)
Hydroxy ether amine quaternary ammonium salt (II) 2.5%
(R ¹ = Formula (III) / R ⁵ = C ₁₆ H ₃₃ , R ^2-4 = CH ₃ , n = 1, X = Cl)
Dimethyldiallylammonium chloride / acrylic acid copolymer solution 3.0%
(Product name: Marcote 280 [manufactured by Nalco])
Camellia oil 2.0%
Propylene carbonate 3.5%
Propylene glycol 3.0%
L-lysine 0.5%
Glycine 0.5%
Trehalose 0.5%
Silylated hydrolyzed wheat protein 2.0%
(Product name: Promois WG-SIG [Seiwa Kasei Co., Ltd.])
Water-soluble collagen solution 0.1%
(Product name: Neptigen N [made by Ichimaru Falcos])
Cationized honey derivative 0.1%
(Product name: Honey Coat 50 [made by ARCH)]
Yukinoshita extract 0.1%
(Product name: Yukinoshita Extract BG [Maruzen Pharmaceutical Co., Ltd.])
Anhydrous sodium sulfite 0.1%
Edetate tetrasodium 0.5%
Orange oil 0.1%
Limonene 0.1%
Fragrance 0.3%
Purified water balance 100.0

(Second agent)
35% hydrogen peroxide solution 16.0%
Cetanol 5.0%
Polyethylene glycol 400 4.0%
POE (2) nonylphenyl ether 1.0%
POE (15) cetyl ether 1.0%
Hydroxy ether amine compound (I) 1.5%
(R ¹ = formula ^{(III) / R 5 = C} 16 H 33, R 2~3 = CH 3, n = 1)
Citric acid 0.05%
Purified water balance 100.0

  The hair dye composition 1st agent and 2nd agent were prepared with the compounding composition of Example A21 according to the conventional method. As a result, the first agent had a viscosity of 14,000 mPa · s and a pH of 10.4, and the second agent had a viscosity of 12000 mPa · s and a pH of 4.1. When the 1st agent and the 2nd agent were mixed in the ratio of 1: 1, the liquid mixture with a viscosity of 13000 mPa * s and pH 10.0 at the time of mixing was obtained. When this mixed solution was used, it was confirmed that the dyeing property and dyeing fastness were excellent, the hair damage was extremely small, the hair conditioning effect was excellent, and the unpleasant odor derived from ammonia was also reduced.

[Example A22] Three-part decoloring agent (first agent) Blending amount (% by mass)
28% ammonia water 6.0%
Monoethanolamine 2.0%
Polyoxyalkylene modified silicone 0.5%
Amino-modified highly polymerized silicone 2.0%
Highly polymerized methylpolysiloxane 2.0%
Decamethylcyclopolysiloxane 2.0%
Dimethyldiallylammonium chloride / acrylamide copolymer solution 1.0%
(Product name: Marcote 550 [Nalco])
Cetanol 2.0%
Behenyl alcohol 4.0%
2-Octyldodecanol 1.0%
POE (2) oleyl ether 1.0%
POE (25) cetyl ether 2.0%
Distearyldimethylammonium chloride 1.0%
Hydroxyetheramine quaternary ammonium salt (II) 2.0%
(R ¹ = formula ^{(III) / R 5 = C} 18 H 37, R 2~4 = CH 3, n = 1, X = C 2 H 5 SO 4)
Fragrance 0.5%
Purified water balance 100.0

(Second agent)
35% hydrogen peroxide solution 17.0%
Dimethyldiallylammonium chloride / acrylic acid copolymer solution 1.0%
(Product name: Marcote 295 [Nalco])
Hydroxy ether amine compound (I) 0.5%
(R ¹ = formula ^{(III) / R 5 = C} 20 H 41, R 2~3 = CH 3, n = 1, X = Cl)
Phosphoric acid 0.2%
Hydroxyethanediphosphonic acid 0.2%
Phenoxyethanol 0.2%
Purified water balance 100.0

(Third agent)
Ammonium persulfate 25.0%
Potassium persulfate 20.0%
Sodium persulfate 7.5%
Anhydrous sodium metasilicate 20.0%
Silica anhydride 10.0%
Sodium silicate 11.0%
Sodium stearate 2.0%
Aluminum stearate 2.0%
Guar gum 1.0%
Carboxymethylcellulose 1.0%
Silica 0.5%
Total 100.0

The hair bleaching agent composition 1st agent, 2nd agent, and 3rd agent were prepared with the compounding composition as described in Example A22 according to a conventional method. As a result, the first agent of the decolorizer composition was a white liquid having a viscosity of 25,000 mPa · s, pH 10.8, the second agent was pH 3.6, and the third agent was powdery. When the 1st agent, the 2nd agent, and the 3rd agent were mixed in the ratio of 3: 6: 2, the liquid mixture with a viscosity of 10000 mPa * s and pH 10.6 at the time of mixing was obtained. When this mixed solution was used, it was confirmed that it was excellent in depigmentation, extremely little hair damage, and excellent in hair conditioning effects.
[Example A23] Aerosol hair color (first agent stock solution) Blending amount (% by mass)
28% ammonia water 5.5%
Ammonium carbonate 2.0%
Paraphenylenediamine 1.0%
Resorcin 0.5%
N, N'-bis (2-hydroxyethyl) -p-phenylenediamine 0.2%
Paraaminophenol 0.5%
2,4-Diaminophenoxyethanol 0.2%
Yellow 202 (2) 0.05%
Cetostearyl alcohol 8.0%
POE (20) cetyl ether 2.0%
POE (20) hydrogenated castor oil 3.0%
Behenyltrimethylammonium chloride 0.2%
Hydroxyetheramine quaternary ammonium salt (II) 2.0%
(R ¹ = Formula (III) / R ⁵ = C ₁₈ H ₃₇ , R ^2-4 = CH ₃ , n = 1, X = Br)
Dimethyldiallylammonium chloride / acrylic acid copolymer solution 3.0%
(Product name: Marcote 280 [manufactured by Nalco])
Highly polymerized methylpolysiloxane 1.0%
Petrolatum 2.0%
Light isoparaffin 3.0%
Sodium ascorbate 0.5%
Glycerol 3.0%
Urea 1.0%
Xylitol 0.5%
Cationized hydrolyzed wheat protein 0.4%
Marine collagen solution 0.1%
Acetylated hyaluronic acid 0.1%
Anhydrous sodium sulfite 0.1%
Hydroxyethane diphosphonic acid 0.5%
Fragrance 0.3%
Purified water balance 100.0

(Second agent stock solution)
35% hydrogen peroxide solution 16.0%
Cetostearyl alcohol 8.0%
Hexylene glycol 4.0%
POE (40) behenyl ether 2.0%
POE (10) hydrogenated castor oil 3.0%
Stearyltrimethylammonium bromide 0.5%
Hydroxy ether amine compound (I) 1.5%
(R ¹ = formula ^{(III) / R 5 = C} 22 H 45, R 2~3 = CH 3, n = 1)
(PEG-150 / decyl alcohol / SMDI) copolymer 1.0%
(Product name: Aculin 44 [Rohm and Haas]
Red No. 227 0.05%
Phosphoric acid 0.3%
Disodium hydrogen phosphate 0.2%
Fragrance 0.1%
Purified water balance 100.0

  According to a conventional method, the hair dye composition first agent stock solution and the second agent stock solution were prepared with the formulation composition described in Example A23 and filled in an aerosol can at a ratio of propellant (LPG) and 93: 7, respectively. The first agent stock solution had a viscosity of 25000 mPa · s and pH 10.4, and the second agent stock solution had a viscosity of 24000 mPa · s and pH 4.4. When the mixture was discharged from the aerosol container and mixed, a mixed solution having a viscosity of 24,000 mPa · s and a pH of 9.8 was obtained. When this mixed solution was used, it was confirmed that it was easy to use, excellent in dyeability and dyeing fastness, extremely little hair damage, and excellent in hair conditioning effects.

[Example B21] Low odor cream hair color (first agent) Blending amount (% by mass)
28% ammonia water 0.5%
Ammonium carbonate 2.0%
Monoethanolamine 2.0%
Isopropanolamine 1.0%
Paraphenylenediamine 1.5%
Resorcin 0.5%
Metaaminophenol 0.3%
Paraaminophenol 0.5%
2,4-Diaminophenoxyethanol 0.2%
Cetanol 7.0%
POE (12) cetyl ether 1.0%
POE (25) lauryl ether 1.0%
Gemini cation-active agent ^{_{(R 6,7 = C 16 H 33}} , R 8~11 = CH 3, Y = Cl) 2.5%
Gemini-type cationic activator (R ^6,7 = C ₁₈ H ₃₇ , R ^8-11 = CH ₃ , Y = Cl) 0.5%
Behenyltrimethylammonium chloride 0.5%
Dimethyldiallylammonium chloride / acrylic acid copolymer solution 3.0%
(Product name: Marcote 280 [manufactured by Nalco])
Camellia oil 2.0%
Beeswax 0.5%
Propylene glycol 3.0%
L-Arginine 0.5%
Trimethylglycine 0.5%
Trehalose 0.5%
Silylated hydrolyzed wheat protein 2.0%
(Product name: Promois WG-SIG [Seiwa Kasei Co., Ltd.])
Water-soluble collagen solution 0.1%
(Product name: Neptigen N [made by Ichimaru Falcos])
Cationized honey derivative 0.1%
(Product name: Honey Coat 50 [made by ARCH)]
Yukinoshita extract 0.1%
(Product name: Yukinoshita Extract BG [Maruzen Pharmaceutical Co., Ltd.])
Sodium sulfite 0.1%
Edetate disodium 0.5%
Orange oil 0.1%
Limonene 0.1%
Fragrance 0.3%
Purified water balance 100.0

(Second agent)
35% hydrogen peroxide solution 16.0%
Cetanol 5.0%
Polyethylene glycol 400 4.0%
POE (2) nonylphenyl ether 1.0%
POE (15) cetyl ether 1.0%
Gemini-type cationic activator (R ^6,7 = C ₁₈ H ₃₇ , R ^8-11 = CH ₃ , Y = Cl) 1.5%
Citric acid 0.05%
Purified water balance 100.0

  The hair dye composition 1st agent and 2nd agent were prepared with the compounding composition as described in Example B21 according to a conventional method. As a result, the first agent had a viscosity of 15000 mPa · s and pH 10.7, and the second agent had a viscosity of 10000 mPa · s and pH 4.0. When the first agent and the second agent were mixed at a ratio of 1: 1, a mixed solution having a viscosity of 12000 mPa · s and a pH of 10.1 was obtained. When this mixed solution was used, it was confirmed that the dyeing property and dyeing fastness were excellent, the hair damage was extremely small, the hair conditioning effect was excellent, and the unpleasant odor derived from ammonia was also reduced.

[Example B22] Three-agent decoloring agent (first agent) Compounding amount (% by mass)
28% ammonia water 6.0%
Monoethanolamine 2.0%
Polyethyleneimine 0.1%
Polyoxyalkylene modified silicone 0.5%
Amino-modified highly polymerized silicone 2.0%
Highly polymerized methylpolysiloxane 2.0%
Decamethylcyclopolysiloxane 2.0%
Dimethyldiallylammonium chloride / acrylamide copolymer solution 1.0%
(Product name: Marcote 550 [Nalco])
Cetanol 2.0%
Behenyl alcohol 4.0%
POE (2) oleyl ether 1.0%
POE (25) cetyl ether 2.0%
Gemini-type cationic activator (R ^6,7 = C ₁₈ H ₃₇ , R ^8-11 = CH ₃ , Y = C ₂ H ₅ SO ₄ ) 2.0%
Fragrance 0.5%
Purified water balance 100.0

(Second agent)
35% hydrogen peroxide solution 17.0%
Dimethyldiallylammonium chloride / acrylic acid copolymer solution 1.0%
(Product name: Marcote 295 [Nalco])
Gemini type cation activator (R ^6,7 = C ₂₀ H ₄₁ , R ^8-11 = CH ₃ , Y = C ₂ H ₅ SO ₄ ) 0.2%
Distearyldimethylammonium chloride 0.1%
Phosphoric acid 0.2%
Hydroxyethanediphosphonic acid 0.2%
Phenoxyethanol 0.2%
Purified water balance 100.0

(Third agent)
Ammonium persulfate 25.0%
Potassium persulfate 20.0%
Sodium persulfate 7.5%
Anhydrous sodium metasilicate 20.0%
Silica anhydride 10.0%
Sodium silicate 11.0%
Sodium stearate 2.0%
Aluminum stearate 2.0%
Guar gum 1.0%
Carboxymethylcellulose 1.0%
Silica 0.5%
Total 100.0

  The hair bleaching agent composition 1st agent, 2nd agent, and 3rd agent were prepared with the compounding composition of Example B22 according to the conventional method. As a result, the decoloring agent first agent had a viscosity of 22,000 mPa · s, pH 11.0, the second agent was a white liquid having a pH of 3.3, and the third agent was powdery. When the 1st agent, the 2nd agent, and the 3rd agent were mixed in the ratio of 3: 6: 2, the liquid mixture with a viscosity of 8000 mPa * s and pH 10.8 at the time of mixing was obtained. When this mixed solution was used, it was confirmed that it was excellent in depigmentation, extremely little hair damage, and excellent in hair conditioning effects.

[Example B23] Aerosol hair color (first agent stock solution) Compounding amount (mass%)
28% ammonia water 5.5%
Ammonium carbonate 2.0%
Paraphenylenediamine 1.0%
Resorcin 0.5%
N, N'-bis (2-hydroxyethyl) -p-phenylenediamine 0.2%
Paraaminophenol 0.5%
2,4-Diaminophenoxyethanol 0.2%
Yellow 202 (2) 0.05%
Cetostearyl alcohol 8.0%
POE (20) cetyl ether 2.0%
POE (20) hydrogenated castor oil 3.0%
Gemini-type cationic activator (R ^6,7 = C ₁₈ H ₃₇ , R ^8-11 = CH ₃ , Y = Br) 2.0%
Dimethyldiallylammonium chloride / acrylic acid copolymer solution 3.0%
(Product name: Marcote 280 [manufactured by Nalco])
Highly polymerized methylpolysiloxane 1.0%
Petrolatum 2.0%
Light isoparaffin 3.0%
Benzyloxyethanol 0.5%
Sodium ascorbate 0.5%
Glycerol 3.0%
Urea 1.0%
Maltitol 0.5%
Cationized hydrolyzed wheat protein 0.4%
Marine collagen solution 0.1%
Acetylated hyaluronic acid 0.1%
Anhydrous sodium sulfite 0.1%
Hydroxyethane diphosphonic acid 0.5%
Fragrance 0.3%
Purified water balance 100.0

(Second agent stock solution)
35% hydrogen peroxide solution 16.0%
Cetostearyl alcohol 8.0%
Hexylene glycol 4.0%
POE (40) behenyl ether 2.0%
POE (10) hydrogenated castor oil 3.0%
Gemini-type cationic activator (R ^6,7 = C ₁₈ H ₃₇ , R ^8-11 = CH ₃ , Y = Br) 1.5%
(PEG-150 / stearyl alcohol / SMDI) copolymer 1.0%
(Product name: Aculin 46 [Rohm and Haas]
Red No. 227 0.05%
Phosphoric acid 0.3%
Disodium hydrogen phosphate 0.2%
Phenacetin 0.1%
Fragrance 0.1%
Purified water balance 100.0

  According to a conventional method, the hair dye composition first agent stock solution and the second agent stock solution were prepared according to a conventional method with the composition described in Example B23, and each was filled in an aerosol can at a ratio of propellant (LPG) and 93: 7. The first agent stock solution had a viscosity of 23,000 mPa · s and pH 10.5, and the second agent stock solution had a viscosity of 22000 mPa · s and pH 3.6. When the mixture was discharged from the aerosol container and mixed, a mixed solution having a viscosity of 20000 mPa · s and a pH of 9.5 was obtained. When this mixed solution was used, it was confirmed that it was easy to use, excellent in dyeability and dyeing fastness, extremely little hair damage, and excellent in hair conditioning effects.

[Example B24] Premium cream hair color
(First Agent) Compounding amount (% by mass)
HC RED BN 0.3%
40% henna leaf extract 5.0%
Ammonium carbonate 2.0%
Monoethanolamine 2.0%
Isopropanolamine 1.0%
Paraphenylenediamine 1.5%
Resorcin 0.5%
Metaaminophenol 0.3%
Paraaminophenol 0.5%
2,4-Diaminophenoxyethanol 0.2%
28% ammonia water 8.0%
Stearyl alcohol 8.0%
Palm oil fatty acid monoethanolamide 4.5%
Glyceryl stearate (SE) 1.3%
Hydroxy ether amine quaternary ammonium salt (II) 2.5%
(R ¹ = Formula (III) / R ⁵ = C ₁₆ H ₃₃ , R ^2-4 = CH ₃ , n = 1, X = Cl)
Gemini-type cationic activator (R ^6,7 = C ₁₈ H ₃₇ , R ^8-11 = CH ₃ , Y = Cl) 2.0%
Coconut oil fatty alcohol polyglycol ether 4.0%
Sodium lauryl sulfate 1.0%
Oleic acid 2.0%
1,2-propanediol 1.5%
Polyether-modified silicone 1.5%
Panthenol 0.8%
Glycine 0.5%
Trehalose 0.5%
Anhydrous sodium sulfite 0.1%
Edetate tetrasodium 0.5%
Orange oil 0.1%
Limonene 0.1%
Fragrance 0.3%
Purified water balance 100.0

(Second agent)
35% hydrogen peroxide solution 16.0%
Cetanol 5.0%
Polyethylene glycol 400 4.0%
POE (2) nonylphenyl ether 1.0%
POE (15) cetyl ether 1.0%
Hydroxy ether amine compound (I) 1.5%
(R ¹ = formula ^{(III) / R 5 = C} 16 H 33, R 2~3 = CH 3, n = 1)
Gemini-type cationic activator (R ^6,7 = C ₁₂ H ₂₅ , R ^8-11 = CH ₃ , Y = Cl) 2.0%
Citric acid 0.05%
Purified water balance 100.0

  The hair dye composition 1st agent and 2nd agent were prepared in accordance with the conventional method by the mixing | blending composition of Example B24. The dyeability and dyeing fastness of the first agent and the second agent were excellent, the hair damage was extremely small, and the hair conditioning effect was excellent.

Claims (4)

In the hair color adjusting composition containing the first agent containing the alkaline agent and the second agent containing the oxidizing agent, the composition contains the following components (A) and / or (B), Composition for adjusting hair color.
(A) A hydroxy ether amine compound represented by the following formula (I) or a quaternary ammonium salt thereof represented by the following formula (II).
@ 0017
@ 0018
[In the formulas (I) and (II), R ¹ , R ² , R ³ and R ⁴ are each an alkyl group having 1 to 3 carbon atoms, or a hydroxyalkyl group thereof, or represented by the following general formula (III): And at least one of R ^{1 to} R ³ is a group represented by the following general formula (III). X represents a halogen atom or an organic sulfur acid group having 1 or 2 carbon atoms. ]
@ 0019
[In the formula (III), R ⁵ is a linear or branched alkyl group, alkenyl group or hydroxyalkyl group having 6 to 24 carbon atoms, and the bond number n is an integer of 1 to 5. ]
(B) A gemini-type cationic activator represented by the following formula (IV).
@ 0020
[In the formula (IV), R ⁶ and R ⁷ are linear or branched saturated or unsaturated alkyl groups having 5 to 25 carbon atoms, and R ⁸ , R ⁹ , R ¹⁰ and R ¹¹ are respectively It is a C1-C5 alkyl group, Y represents a halogen atom or a C1-C2 organic sulfur acid group. ] The hair color adjusting composition according to claim 1, wherein the composition is a hair dye composition containing an oxidation dye intermediate and / or a direct dye in the first agent. The composition for hair color adjustment according to claim 1, wherein the composition is a hair bleaching agent composition which does not contain an oxidative dye intermediate and a direct dye in the first agent. The composition for hair color adjustment according to claim 3, wherein the composition is a hair bleaching agent composition containing a third agent containing persulfates.