JP5275581B2 - Hair bleaching or dyeing composition - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a two-pack type hair-bleaching or dyeing composition hardly causing irritating smell of ammonia, providing excellent touch feeling at rinsing after shampoo washing, and also having excellent preservation stability. <P>SOLUTION: The hair-bleaching or dyeing composition is used by mixing the first agent containing an alkali agent with the second agent containing hydrogen peroxide. The second agent contains the following components (A) and (B), and is regulated so that the molar ratio (A)/(B) of the components (A) to (B) in the second agent may satisfy the expression: 2&le;(A)/(B)&le;20, the emulsified particle diameter (volume averaged diameter) of the second agent may be 20-150 &mu;m, and the viscosity of the second agent may be &le;4,000 Pa s: (A) a 16-22C higher alcohol; and (B) a surfactant. <P>COPYRIGHT: (C)2009,JPO&amp;INPIT

Description

  The present invention relates to a hair bleaching or dyeing composition used by mixing a first agent containing an alkali agent and a second agent containing hydrogen peroxide.

  For the decolorization and dyeing of hair, two-component permanent hair dyes and decoloring agents comprising a first agent containing an alkaline agent and a second agent containing an oxidizing agent such as hydrogen peroxide are widely used. . The alkaline agent of the first agent is blended in order to activate the action of the oxidizing agent to promote oxidative degradation of melanin granules in the hair, decolorize the hair, and obtain a bright color tone.

  Conventionally, ammonia is generally used as an alkaline agent. Ammonia is an alkaline agent excellent in obtaining good hair dyeing power and decoloring power, but has a problem of having an irritating odor. Therefore, various proposals have been made to suppress the irritating odor during the treatment. For example, an emulsified composition for hair decolorization or hair dye which has reduced the irritating odor and irritation to the skin by sufficiently reducing the average emulsified particle size of the first agent containing ammonia has been proposed (Patent Literature). 1). However, this has a problem in the feeling of rinsing after shampoo washing.

  The first and second agent dosage forms of the two-component hair bleaching agent and hair coloring agent include those having a high viscosity such as cream or paste, and those having a low viscosity such as liquid or emulsion. A dosage form having a low viscosity has the advantage of being easy to mix as compared with a dosage form having a high viscosity, but generally has a drawback that the stimulating odor of ammonia is strong and the emulsion stability of the agent is poor. For this reason, the dosage form with a low viscosity has generally achieved emulsion stability by controlling the emulsion particles to be small. However, when the particle size is made small, the feeling after rinsing does not last long.

JP 2002-226342 A

  Accordingly, an object of the present invention is to provide a two-component hair decoloring or dyeing composition that has a little irritating odor of ammonia, has an excellent feel when rinsed after shampoo washing, and also has excellent storage stability. .

  Surprisingly, the inventor makes the emulsion particle diameter and viscosity of the second agent within a certain range, and adjusts the ratio of the higher alcohol and the surfactant in the second agent within a certain range. It was found that the ammonia volatilization amount was reduced, the touch was improved, and the storage stability was also improved.

That is, the present invention is a hair bleaching or dyeing composition used by mixing a first agent containing an alkaline agent and a second agent containing hydrogen peroxide, wherein the second agent comprises the following components ( A) and (B)
(A) Higher alcohol having 16 to 22 carbon atoms
(B) A surfactant is contained, the molar ratio of the component (A) to the component (B) in the second agent is 2 ≦ (A) / (B) ≦ 20, and the emulsion particle size of the second agent ( The present invention provides a hair bleaching or dyeing composition having a volume average diameter) of 20 to 150 μm and a viscosity of the second agent of 4000 mPa · s.

  The hair bleaching or dyeing composition of the present invention has a small ammonia-stimulated odor during use, is excellent in the feel during rinsing after shampoo washing, and is excellent in the storage stability of the second agent.

<< Second Agent >>
[Component (A): Higher alcohol]
Examples of the higher alcohol having 16 to 22 carbon atoms of the component (A) include linear or branched saturated or unsaturated aliphatic alcohols, specifically, cetyl alcohol, stearyl alcohol, behenyl alcohol, isostearyl alcohol. Oleyl alcohol, 2-hexyldecanol, 2-octyldodecanol and the like. Of these, saturated higher alcohols, specifically cetyl alcohol, stearyl alcohol, behenyl alcohol, and 2-octyldodecanol are preferred.

  The higher alcohols can be used alone or in combination of two or more. The content of the component (A) in the second agent is preferably 0.01 to 6% by mass, more preferably 0.1 to 5% by mass, and particularly preferably 0.5 to 4% by mass from the viewpoint of the stability of the second agent.

[Component (B): Surfactant]
The surfactant of component (B) is contained to make the second agent an oil-in-water emulsion composition. As the surfactant, from the viewpoint of emulsion stability, a nonionic surfactant, for example, an alkoxylated (eg, ethoxylated or propoxylated) higher alcohol having a linear or branched alkyl group having 12 to 24 carbon atoms, specifically Specifically, polyoxyethylene (2 to 40 mol) alkyl ether and the like are preferable. In consideration of the touch surface, it is preferable to use a cationic surfactant such as mono long chain alkyltrimethylammonium salt and dilong chain alkyldimethylammonium salt in combination. Here, as the mono long-chain alkyltrimethylammonium salt, stearyltrimethylammonium chloride and behenyltrimethylammonium chloride are preferable from the viewpoint of feel and emulsification performance.

  Surfactant can be used individually or in combination of 2 or more types. The content of the component (B) in the second agent is preferably 0.01 to 16% by mass, more preferably 0.1 to 12% by mass, and particularly preferably 0.2 to 8% by mass from the viewpoint of the stability of the second agent.

  The molar ratio of component (A) to component (B) in the second agent is 2 ≦ (A) / (B from the viewpoint of reducing the ammonia-stimulating odor during use and improving the storage stability of the second agent. ) ≦ 20, preferably 3 ≦ (A) / (B) ≦ 15, particularly 4 ≦ (A) / (B) ≦ 10.

〔hydrogen peroxide〕
The second agent contains hydrogen peroxide. The content of hydrogen peroxide in the second agent is preferably from 0.1 to 12% by mass, more preferably from 0.5 to 9% by mass, particularly from the viewpoint of sufficient decolorization / dyeing effect and reduction of hair damage and scalp irritation. 1-6 mass% is preferable.

[Other optional ingredients]
In addition to the above components, other components that are usually used as cosmetic raw materials can be added to the second agent. Such optional components include pH adjusters, hydrocarbons, silicones, animal and vegetable oils, higher fatty acids, natural or synthetic polymers, ethers, protein derivatives, hydrolyzed proteins, amino acids, preservatives, Chelating agents, stabilizers, antioxidants, animal and plant extracts, herbal extracts, vitamins, fragrances, and UV absorbers.

[Emulsified particle diameter of second agent]
The emulsified particle diameter (volume average diameter) of the second agent is adjusted to 20 to 150 μm from the point of touch (softness) at the time of rinsing after shampoo washing and the storage stability of the second agent. A thickness of 25 to 100 μm, particularly 30 to 80 μm is preferable.

<< First Agent >>
〔dye〕
When the composition of the present invention is a hair bleaching composition, it contains no dye, and when it is a hair dyeing composition, the first agent contains an oxidation dye intermediate or a direct dye.

(Oxidized dye intermediate)
As the oxidation dye intermediate, known precursors and couplers usually used in hair dyes can be used. Examples of the precursor include paraphenylenediamine, toluene-2,5-diamine, 2-chloro-paraphenylenediamine, N-methoxyethyl-paraphenylenediamine, N, N-bis (2-hydroxyethyl) -paraphenylenediamine, 2- (2-hydroxyethyl) -paraphenylenediamine, 2,6-dimethyl-paraphenylenediamine, 4,4'-diaminodiphenylamine, 1,3-bis (N- (2-hydroxyethyl) -N- (4 -Aminophenyl) amino) -2-propanol, PEG-3,3,2'-paraphenylenediamine, paraaminophenol, paramethylaminophenol, 3-methyl-4-aminophenol, 2-aminomethyl-4-aminophenol , 2- (2-hydroxyethylaminomethyl) -4-aminophenol, orthoaminophenol, 2-amino-5-methylphenol, 2-amino-6-methylphenol, 2-amino-5-acetami Phenol, 3,4-diaminobenzoic acid, 5-aminosalicylic acid, 2,4,5,6-tetraaminopyrimidine, 2,5,6-triamino-4-hydroxypyrimidine, 4,5-diamino-1- (4 '-Chlorobenzyl) pyrazole, 4,5-diamino-1-hydroxyethylpyrazole and salts thereof.

  Examples of couplers include metaphenylenediamine, 2,4-diaminophenoxyethanol, 2-amino-4- (2-hydroxyethylamino) anisole, 2,4-diamino-5-methylphenetole, and 2,4-diamino. -5- (2-hydroxyethoxy) toluene, 2,4-dimethoxy-1,3-diaminobenzene, 2,6-bis (2-hydroxyethylamino) toluene, 2,4-diamino-5-fluorotoluene, 1 , 3-Bis (2,4-diaminophenoxy) propane, metaaminophenol, 2-methyl-5-aminophenol, 2-methyl-5- (2-hydroxyethylamino) phenol, 2,4-dichloro-3- Aminophenol, 2-chloro-3-amino-6-methylphenol, 2-methyl-4-chloro-5-aminophenol, N-cyclopentyl-metaaminophenol, 2-methyl-4-methoxy-5- (2- Hydroxyethylamino) phenol, 2-methyl-4-fluoro-5-a Nophenol, resorcin, 2-methylresorcin, 4-chlororesorcin, 1-naphthol, 1,5-dihydroxynaphthalene, 1,7-dihydroxynaphthalene, 2,7-dihydroxynaphthalene, 2-isopropyl-5-methylphenol, 4 -Hydroxyindole, 5-hydroxyindole, 6-hydroxyindole, 7-hydroxyindole, 6-hydroxybenzomorpholine, 3,4-methylenedioxyphenol, 2-bromo-4,5-methylenedioxyphenol, 3,4 -Methylenedioxyaniline, 1- (2-hydroxyethyl) amino-3,4-methylenedioxybenzene, 2,6-dihydroxy-3,4-dimethylpyridine, 2,6-dimethoxy-3,5-diaminopyridine 2,3-diamino-6-methoxypyridine, 2-methylamino-3-amino-6-methoxypyridine, 2-amino-3-hydroxypyridine, 2,6-diaminopyridine and these Salts and the like.

  Two or more precursors and couplers may be used in combination, and the content of each of the precursor and the coupler is preferably 0.01 to 5% by mass, particularly preferably 0.1 to 4% by mass in the total composition.

(Direct dye)
Examples of direct dyes include acid dyes, nitro dyes, disperse dyes, and basic dyes. Examples of acid dyes include Blue No. 1, Purple No. 401, Black No. 401, Orange No. 205, Red No. 227, Red No. 106, Yellow No. 203, Acid Orange 3, etc., and nitro dyes include 2-nitro -p-phenylenediamine, 2-amino-6-chloro-4-nitrophenol, 3-nitro-p-hydroxyethylaminophenol, 4-nitro-o-phenylenediamine, 4-amino-3-nitrophenol, 4- Hydroxypropylamino-3-nitrophenol, HC Blue No.2, HC Orange No.1, HC Red No.1, HC Yellow No.2, HC Yellow No.4, HC Yellow No.5, HC Red No.3 N, N-bis- (2-hydroxyethyl) -2-nitro-p-phenylenediamine and the like, and disperse dyes include Disperse Violet 1, Disperse Blue 1, Disperse Black 9 and the like. Basic dyes such as Basic Blue 99 and Basic Kuburaun 16, Basic Brown 17, Basic Red 76, Basic Red 51, Basic Yellow 57, Basic Yellow 87, Basic Orange 31, and the like.

  Two or more direct dyes may be used in combination, or may be used in combination with an oxidation dye intermediate. Moreover, the content is 0.001-5 mass% in all compositions, and 0.01-3 mass% is especially preferable.

(Alkaline agent)
The first agent contains an alkali agent. Alkaline agents such as ammonia and salts thereof; alkanolamines such as monoethanolamine, isopropanolamine, 2-amino-2-methylpropanol and 2-aminobutanol and salts thereof; alkanediamines such as 1,3-propanediamine and the like Salts: carbonates such as guanidine carbonate, sodium carbonate, potassium carbonate, sodium hydrogen carbonate, potassium hydrogen carbonate and the like. These alkaline agents may be used in combination of two or more, and the content thereof is 0.05 to 0.05 in the total composition from the viewpoint of sufficient hair dyeing / bleaching effect and reduction of hair damage and scalp irritation. 15 mass% is preferable, 0.1-10 mass% is further more preferable, and 0.2-5 mass% is especially preferable.

  Of the above alkaline agents, ammonia, alkanolamines and salts thereof are preferred. As the ammonium salt, ammonium carbonate and ammonium hydrogen carbonate are preferable, and as the alkanolamine and its salt, monoethanolamine and its salt are preferable. Furthermore, the content of these is most preferably in the following range. The sum of the content (X) when ammonia and its salt in all compositions are converted as ammonia and the content (Y) when monoethanolamine and its salt are converted as monoethanolamine is sufficient. From the viewpoint of hair / bleaching effect and reduction of hair damage, scalp stimulation, and olfactory stimulation, it is preferably 0.05 to 15% by mass, more preferably 0.1 to 10% by mass, particularly 0.2 to 5% by mass in the total composition. % Is preferred. The mass ratio of X / Y is preferably 0.01: 1 to 2: 1, more preferably 0.02: 1 to 1: 1, and particularly preferably 0.05: 1 to 0.5: 1.

[Cationic polymer]
The first agent of the decoloring or dyeing composition of the present invention preferably further contains a cationic polymer in order to give an excellent feeling of use. The cationic polymer refers to a polymer having a cationic group or a group that can be ionized into a cationic group, and includes an amphoteric polymer that becomes cationic as a whole. That is, as the cationic polymer, an aqueous solution containing an amino group or an ammonium group in the side chain of the polymer chain or containing a diallyl quaternary ammonium salt as a structural unit, such as a cationized cellulose derivative, a cationic starch, a cationization Examples include guar gum derivatives, diallyl quaternary ammonium salt polymers or copolymers, and quaternized polyvinylpyrrolidone derivatives. Among these, diallyl quaternary ammonium salt is included as a structural unit particularly in terms of softness during shampooing, smoothness and ease of fingering, ease of packing during drying and moisturizing effect, and stability of the agent. Polymers, quaternized polyvinyl pyrrolidone derivatives, and cationized cellulose derivatives are preferable, diallyl quaternary ammonium salt polymers or copolymers, and cationized cellulose derivatives are more preferable, diallyl quaternary ammonium salt polymers or copolymers. Most preferred.

  As the skeleton of the diallyl quaternary ammonium salt polymer, one represented by the following general formula (1) or (2) is preferable.

[In the formula, R ¹ and R ² may be the same or different, and are a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, an aryl group (such as a phenyl group), a hydroxyalkyl group, an amidoalkyl group, a cyanoalkyl group, an alkoxy group. Represents an alkyl group or a carboalkoxyalkyl group, R ³ and R ⁴ may be the same or different, each represents a hydrogen atom, an alkyl group having 1 to 3 carbon atoms or a phenyl group, and An ⁻ represents an anion (chloride ion, Bromide ion, iodide ion, sulfate anion, sulfonate anion, methyl sulfate anion, phosphate anion, nitrate anion, etc.). ]

  Examples of the monomer constituting the copolymer with the diallyl quaternary ammonium salt include acrylic acid, methacrylic acid or salts thereof, and acrylamide, and acrylic acid, methacrylic acid or salts thereof are particularly preferable. A copolymer of acrylic acid, methacrylic acid or a salt thereof and a diallyl quaternary ammonium salt has a high constituent ratio of diallyl quaternary ammonium salt, and becomes a cationic polymer as a whole.

  Specific examples of the polymer or copolymer of diallyl quaternary ammonium salt include dimethyldiallylammonium chloride polymer (polyquaternium-6, such as Marquat 100; Nalco), dimethyldiallylammonium chloride / acrylic acid copolymer (polyquaternium- 22, for example, Marquat 280, 295; Nalco), dimethyldiallylammonium chloride / acrylamide copolymer (Polyquaternium-7, for example, Marquat 550; Nalco), and the like. Among these, Marcoat 280, 295 are preferred.

  As the quaternized polyvinylpyrrolidone derivative, those represented by the following general formula (3) are preferable.

[Wherein, R ⁵ represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and R ⁶ , R ⁷ and R ⁸ may be the same or different, and represent a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, hydroxy An alkyl group, an amidoalkyl group, a cyanoalkyl group, an alkoxyalkyl group or a carboalkoxyalkyl group; B represents an oxygen atom or an imino group; r represents an integer of 1 to 10; Represents a number of ˜8000, and An ⁻ has the same meaning as described above. ]

  The molecular weight of the quaternized polyvinylpyrrolidone derivative used in the present invention is preferably 10,000 to 2,000,000, particularly preferably 50,000 to 1,500,000. Examples of commercially available products include Guff Coat 734, 755, and 755N (hereinafter referred to as IP Japan).

  As the cationized cellulose derivative, for example, those represented by the following general formula (4) are preferable.

[In the formula, G represents a residue of an anhydroglucose unit, f represents an integer of 50 to 20,000, and R ⁹ represents a substituent represented by the following general formula (5). ]

[Wherein R ¹⁰ and R ¹¹ represent an alkylene group having 2 or 3 carbon atoms, g represents an integer of 0 to 10, h represents an integer of 0 to 3, and i represents an integer of 0 to 10] , R ¹² represents an alkylene group having 1 to 3 carbon atoms or a hydroxyalkylene group, R ¹³ , R ¹⁴ and R ¹⁵ may be the same or different and each represents an alkyl group, aryl group or aralkyl group having up to 10 carbon atoms, Moreover, you may form the heterocyclic ring containing the nitrogen atom in a formula. An ^- has the same meaning as above. ]

  The cation substitution degree of the cationized cellulose derivative, that is, the average value of h per anhydroglucose unit is preferably 0.01 to 1, particularly 0.02 to 0.5. Moreover, the sum total of g + i is 1-3 on average. If the degree of cation substitution is less than 0.01, it is not sufficient and may exceed 1, but 1 or less is preferable from the viewpoint of reaction yield. The molecular weight of the cationized cellulose derivative used here is preferably 100,000 to 3,000,000. Commercially available products include Leo Guard G, GP (Lion), Polymer JR-125, JR-400, JR-30M, LR-400, LR-30M (Union Carbide). Can be mentioned. Examples of other cationized cellulose derivatives include hydroxyethyl cellulose dimethyl diallylammonium chloride, and examples of commercially available products include Cellcoat H-100 and L-200 (National Starch and Chemical Co., Ltd.).

  These cationic polymers may be used in combination of two or more, and the higher the content, the higher the effect. However, when the content is too large, the stability is poor and the viscosity of the agent alone or at the time of mixing is reduced. From these points, 0.001 to 20% by mass in the total composition is preferable, 0.01 to 10% by mass, particularly 0.05 to 5% by mass is preferable.

[Silicones]
Furthermore, the decoloring or dyeing composition of the present invention may contain silicones. Examples of such silicones include those shown below.

(1) Dimethylpolysiloxane Examples include those represented by the following general formula.
(CH ₃ ) ₃ SiO — [(CH ₃ ) ₂ SiO] _a -Si (CH ₃ ) ₃
[In formula, a shows the number of 3-20000. ]

(2) Amino-modified silicone Various amino-modified silicones can be used, but in particular, the average molecular weight of about 3000 to 100,000 is Amodimethicone, Aminoethylaminopropyl Dimethicone, or Aminopropyl Dimethicone. ) In the INCI Dictionary (US, International Cosmetic Ingredient Dictionary and Handbook) 10th edition is preferable. This amino-modified silicone is preferably used as an aqueous emulsion, and examples of commercially available products include SM 8704C (Toray Dow Corning), DC 929 (Dow Corning), KT 1989 (GE Toshiba). Although it does not specifically limit as N content, 0.01-1 mass% is preferable and 0.05-0.3 mass% is especially preferable.

(3) Other silicones Other than the above, polyether-modified silicone, methylphenylpolysiloxane, fatty acid-modified silicone, alcohol-modified silicone, alkoxy-modified silicone, epoxy-modified silicone, fluorine-modified silicone, cyclic silicone, alkyl-modified silicone, etc. It is done.

  Two or more types of silicones may be used in combination, and the content thereof is preferably 0.01 to 10% by mass, more preferably 0.05 to 6% by mass, and particularly preferably 0.3 to 3% by mass in the total composition.

[Medium]
In the composition of the present invention, water and, if necessary, an organic solvent are used as a medium. Examples of organic solvents include lower alkanols such as ethanol and 2-propanol, aromatic alcohols such as benzyl alcohol and benzyloxyethanol, cellosolves such as ethyl cellosolve and butyl cellosolve, and carbitols such as ethyl carbitol and butyl carbitol. Is mentioned.

[Dosage form, viscosity, etc.]
The dosage form of the first agent can be, for example, liquid, emulsion, cream, gel, paste, mousse, etc., and can also be aerosol. The dosage form of the second agent can be, for example, liquid or emulsion.

  The viscosity of the second agent is set to 4000 mPa · s or less from the viewpoint of easy mixing with the first agent and ease of elongation of the agent when applied to the hair. The pressure is preferably 10 to 3000 mPa · s, particularly 50 to 2000 mPa · s. The viscosity of the second agent here is 50 g in a glass bottle No. 6 manufactured by Toyo Glass Co., Ltd., measured at 25 ° C with TVB-10M (Toki Sangyo Co., Ltd.). When the viscosity is less than 300 mPa · s, it is a rotor. When M2 is used at 60 rpm and 300 to 4000 mPa · s, the value after rotating for 1 minute at 30 rpm using rotor M3. When it exceeds 4000 mPa · s, it shall be the value measured by the measurement method in the next section.

  The mixture obtained by mixing the first agent and the second agent desirably has a viscosity that prevents the liquid from dripping when applied to the hair, and the viscosity measured at 25 ° C. is preferably 2000 to 30,000 mPa · s. Here, when the viscosity is 4000 mPa · s or less, it shall be measured by the measurement method described in the previous section. When the viscosity exceeds 4000 mPa · s, a B-type rotational viscometer with a helical stand (B8R viscometer, Toki Sangyo Co., Ltd. ) Use the rotor TC and set the value after rotating at 10 rpm for 1 minute.

[PH]
The pH (25 ° C.) of the composition of the present invention is preferably 8 to 12 for the first agent and 2 to 5 for the second agent. The total composition at the time of use (mixing) is decolorization / hair dyeing effect and skin. From the point of irritation, 8 to 12, particularly 8 to 10 is preferable. As a pH adjuster, in addition to the above alkaline agents, inorganic acids such as hydrochloric acid and phosphoric acid, organic acids such as citric acid, glycolic acid and lactic acid, hydrochlorides such as monoethanolamine hydrochloride, monopotassium dihydrogen phosphate, Examples thereof include phosphates such as disodium monohydrogen phosphate.

[Other optional ingredients]
In addition to the above components, other components that are usually used as cosmetic raw materials can be added to the composition of the present invention. Such optional components include higher alcohols and surfactants described as components of the second agent, hydrocarbons, animal and vegetable oils, higher fatty acids, natural or synthetic polymers, ethers, proteins Derivatives, hydrolyzed proteins, amino acids, preservatives, chelating agents, stabilizers, antioxidants, animal and plant extracts, herbal extracts, vitamins, fragrances, and UV absorbers.

[Treatment method]
In order to dye or decolorize hair using the composition of the present invention, for example, the first agent and the second agent of the composition of the present invention are mixed immediately before use, then applied to the hair, and left for a predetermined time, Rinse and dry. The application temperature to the hair is preferably 15 to 45 ° C., the application time is 3 to 45 minutes, more preferably 5 to 30 minutes, and particularly preferably 10 to 30 minutes.

Examples 1-5 and Comparative Examples 1-3
When the 1st agent shown in Table 1 and the 2nd agent shown in Table 2 were prepared, and the "storage stability" of this 2nd agent and the 1st agent and the 2nd agent were mixed and the decoloring process of hair was performed The “ammonia volatilization amount (intensity of irritating odor)”, “feel during agent rinsing (smoothness)” and “feel during shampoo rinsing (softness)” were evaluated according to the following methods. Table 2 shows the evaluation results and the viscosity of the second agent.

<Method for preparing second agent>
Water, 8-quinolinol sulfate and 1-hydroxyethane-1,1-diphosphonic acid are dissolved by heating at 70 ° C. To this, stearyl alcohol, stearyltrimethylammonium chloride and polyoxyethylene cetyl ether dissolved under heating at 70 ° C. are added with stirring. Cooling with stirring, hydrogen peroxide was added when the temperature reached 40 ° C., and finally the pH was adjusted with sodium hydroxide to prepare a second agent. The particle size was controlled by adjusting the stirring efficiency and time during blending.

<Viscosity measurement method>
50 g of the second agent is put into a glass bottle No. 6 manufactured by Toyo Glass Co., Ltd., and measured at 25 ° C. with TVB-10M (Toki Sangyo Co., Ltd.). When the viscosity is less than 300 mPa · s, the rotor M2 is used at 60 rpm, and when the viscosity is 300 to 4000 mPa · s, the rotor M3 is used at 30 rpm for 1 minute. When the pressure exceeds 4000 mPa · s, use a B-type rotational viscometer with a helical stand (B8R type viscometer, Toki Sangyo Co., Ltd.) rotor TC and take the value after rotating at 10 rpm for 1 minute.

<Evaluation method>
Ammonia volatilization amount
Weigh 2g of the first agent and 3g of the second agent in a petri dish with a diameter of 3.5cm and mix well. The petri dish is put into a beaker having a capacity of 2500 mL, covered, and stirred with a stirrer at 200 rpm for 1 minute. Insert the tip of a gas detector tube No. 3M ammonia (10-1000ppm) manufactured by GASTEC into the center of the top of the beaker and measure the amount of ammonia volatilization.

“Feeling of hair during agent rinsing (smoothness)”
4 g of the first agent and 6 g of the second agent were mixed well, applied to a black hair tress (hair color, 10 g of Mongoloid hair without permanent history), and left for 20 minutes. Thereafter, the smooth feel when rinsed with running water for 10 seconds was subjected to sensory evaluation in five stages.
5: Smooth 4: Slightly smooth 3: Cannot say 2: Slightly squeak 1: Squeak

"Hair feel (softness) during shampoo rinse"
4 g of the first agent and 6 g of the second agent were mixed well, applied to a black hair tress (hair color, 10 g of Mongoloid hair without permanent history), and left for 20 minutes. Thereafter, the sensation (softness of hair) at the time of rinsing with running water after rinsing with running water and washing with shampoo was subjected to sensory evaluation in five stages.
5: Soft 4: Slightly soft 3: Neither can be said 2: Slightly hard 1: Hard

"Storage stability"
The change in appearance when the second agent was stored at 40 ° C. for 1 month was observed with the naked eye and judged according to the following criteria.
○: The emulsified state is maintained. Δ: The appearance is uneven or slightly increased in viscosity compared to before storage. ×: The emulsified state is not maintained (separation or increased viscosity).

Claims (2)

A hair bleaching or dyeing composition used by mixing a first agent containing an alkaline agent and a second agent containing hydrogen peroxide, wherein the second agent comprises the following components (A) and (B )
(A) Higher alcohol 0.5-4% by mass
(B) Surfactant 0.2-8% by mass
The component (A) is stearyl alcohol, the component (B) is a polyoxyethylene (2 to 40 mol) alkyl ether having an alkyl group having 12 to 24 carbon atoms , stearyltrimethylammonium chloride and / or It consists of a combination with behenyltrimethylammonium chloride , the molar ratio of component (A) to component (B) in the second agent is 2 ≦ (A) / (B) ≦ 10, and the emulsification of the second agent A hair bleaching or dyeing composition having a particle diameter (volume average diameter) of 30 to 130 μm and a viscosity of the second agent of 50 to 2000 mPa · s.   The composition for hair bleaching or dyeing according to claim 1, wherein the first agent contains a cationic polymer.