JP5086522B2 - Hair cosmetics - Google Patents
Hair cosmetics Download PDFInfo
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- JP5086522B2 JP5086522B2 JP2004321808A JP2004321808A JP5086522B2 JP 5086522 B2 JP5086522 B2 JP 5086522B2 JP 2004321808 A JP2004321808 A JP 2004321808A JP 2004321808 A JP2004321808 A JP 2004321808A JP 5086522 B2 JP5086522 B2 JP 5086522B2
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
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Description
本発明は毛髪化粧料に関し、さらに詳しくは傷んだ髪をケアし、べたつきやごわつきを感じることのないリンス、トリートメントなどの毛髪化粧料に関する。 The present invention relates to a hair cosmetic, and more particularly to a hair cosmetic such as a rinse or treatment that cares for damaged hair and does not feel sticky or stiff.
従来、毛髪化粧料において傷んだ髪をケアし、まとまりを良くし、また適度なしっとり感を付与する為に、各種油分や水溶性高分子等が適宜配合されてきた。
しかしながら炭化水素油、エステル油といった油剤を使用した場合には仕上がりが重くなり、べたつきが生じる傾向にあった。また水溶性高分子などの保湿剤を配合した場合は、使用時のうるおい感には効果があるが時間の経過と共にごわつきを生じる傾向にある。このように毛髪用の保湿剤も種類によっては満足のいく使用感を得る事が出来なかった。そこで傷んだ髪をケアし、べたつきやごわつきを感じることのない毛髪化粧料の開発が望まれていた。
かかる欠点を解決するために開発された技術として、特定のアミノ酸系両性界面活性剤と、保湿剤としての植物由来保湿剤、尿素系保湿剤または糖系保湿剤とを配合した毛髪化粧料が知られている（特許文献１参照）。
また、セット力を有する頭髪化粧料では、特定の高重合ポリエチレングリコールと、油剤と、非イオン性界面活性剤と、水溶性アルコールとを配合することにより、べたつかず、髪にしなやかさを与える頭髪化粧料が得られている（特許文献２参照）。
Conventionally, various oils, water-soluble polymers, and the like have been appropriately blended in order to care for damaged hair in hair cosmetics, improve unity, and impart a moderate moist feeling.
However, when oil agents such as hydrocarbon oils and ester oils are used, the finish becomes heavy and tends to be sticky. In addition, when a moisturizing agent such as a water-soluble polymer is blended, there is an effect on moisture feeling at the time of use, but there is a tendency to become stiff as time passes. Thus, depending on the type of humectant for hair, a satisfactory feeling of use could not be obtained. Therefore, it has been desired to develop a hair cosmetic that cares for damaged hair and does not feel sticky or stiff.
As a technique developed to solve such drawbacks, hair cosmetics containing a specific amino acid amphoteric surfactant and a plant-derived moisturizer, urea moisturizer or sugar moisturizer as a moisturizer are known. (See Patent Document 1).
In addition, in hair cosmetics having a set power, the hair which is not sticky and gives hair suppleness by blending a specific highly polymerized polyethylene glycol, an oil agent, a nonionic surfactant and a water-soluble alcohol. Cosmetics have been obtained (see Patent Document 2).
しかしながら、上記特許文献１の毛髪化粧料は、しっとりしすぎべたべたするという問題がある。また特許文献２の頭髪化粧料は、ごわつきやパサツキを与えてしまうという問題がある。 However, the hair cosmetic of Patent Document 1 has a problem that it is too moist and sticky. Moreover, the hair cosmetics of patent document 2 have the problem of giving a wrinkle and rustling.
そこで本発明は、傷んだ髪をケアし、べたつきやごわつきを感じることがなく、櫛通りのよい毛髪化粧料を提供することを目的とする。 SUMMARY OF THE INVENTION An object of the present invention is to provide a hair cosmetic composition that can care for damaged hair and does not feel sticky or stiff, so that it can be easily combed.
本発明は、カチオン性界面活性剤と、エリスリトール、ジグリセリン、１，３−ブチレングリコールおよびプロピレングリコールから選ばれる多価アルコールおよび／または糖アルコールとを配合し、多価アルコールおよび／または糖アルコールの合計配合量が１０〜５０質量％であることを特徴とする毛髪化粧料である。 The present invention comprises a cationic surfactant and a polyhydric alcohol and / or sugar alcohol selected from erythritol, diglycerin, 1,3-butylene glycol and propylene glycol, and the polyhydric alcohol and / or sugar alcohol The total amount of the hair cosmetic is 10 to 50% by mass.
ここで、多価アルコールまたは糖アルコールのうちでは、糖アルコールであるものが好ましい。糖アルコールとしては、キシリトール、フルクトース、ソルビトール、マンニトール、イノシトール、グルコース、ラクトース、マルチトールまたはスクロースが挙げられる。 Here, among polyhydric alcohols or sugar alcohols, those that are sugar alcohols are preferred. Sugar alcohols include xylitol, fructose, sorbitol, mannitol, inositol, glucose, lactose, maltitol or sucrose.
本発明においてはさらに、下記式（１）、（２）または（３）で表される変性シリコーンのいずれか１種あるいは２種以上を配合することが好ましい。 In the present invention, it is preferable to further blend one or more of modified silicones represented by the following formula (1), (2) or (3).
（式中、ｍ＝３０〜５００、ｎ＝１〜１５、ａ＝０〜３０、ｂ＝５〜３０を示す。） (In the formula, m = 30 to 500, n = 1 to 15, a = 0 to 30, and b = 5 to 30 are shown.)
（式中、ｐ＝２０〜２００、ｑ＝１〜５、ｒ＝５〜１５を示す。） (In the formula, p = 20 to 200, q = 1 to 5, and r = 5 to 15 are shown.)
（式中、ｍ＋ｎ＝３０００〜１００００、ｎ／（ｍ＋ｎ）＝０．００１〜０．００５を示す。） (In the formula, m + n = 3,000 to 10,000 and n / (m + n) = 0.001 to 0.005 are shown.)
本発明の毛髪化粧料は、傷んだ髪をケアする効果に優れ、しかもべたつきやごわつきを感じることがなく、櫛通りのよいものである。 The hair cosmetic composition of the present invention is excellent in the effect of caring for damaged hair, and does not feel sticky or stiff, so that it is as good as a comb.
以下に、本発明の最良の実施の形態について説明する。
（カチオン性界面活性剤）
本発明に用いられるカチオン性界面活性剤としては、例えば塩化ステアリルトリメチルアンモニウム，塩化ベヘニルトリメチルアンモニウム，塩化ジステアリルジメチルアンモニウム等のアルキル４級アンモニウム塩、アルキルピリジニウム塩、あるいはアミン塩、塩化モノアルキルヒドロキシアルキルエーテルアンモニウム塩、ポリオキシプロピレンジエチルメチルアンモニウム塩、ジアルキルアミドプロピルメチルアミン塩、ヒドロキシプロピル-ビス-アルキルアンモニウム塩、ヒドロキシプロピル-ビス-アルキルアミドアンモニウム塩、ジアルキルアミドエチルエチルヒドロキシアンモニウム塩、アルキルジメチルベンジルアンモニウム塩等が用いられる。このうち特に、アルキル４級アンモニウム塩が好ましい。
The best mode of the present invention will be described below.
(Cationic surfactant)
Examples of the cationic surfactant used in the present invention include alkyl quaternary ammonium salts such as stearyltrimethylammonium chloride, behenyltrimethylammonium chloride, distearyldimethylammonium chloride, alkylpyridinium salts, amine salts, and monoalkylhydroxyalkyl chlorides. Ether ammonium salt, polyoxypropylene diethylmethylammonium salt, dialkylamidopropylmethylamine salt, hydroxypropyl-bis-alkylammonium salt, hydroxypropyl-bis-alkylamidoammonium salt, dialkylamidoethylethylhydroxyammonium salt, alkyldimethylbenzylammonium salt Salt or the like is used. Of these, alkyl quaternary ammonium salts are particularly preferred.
カチオン性界面活性剤の配合量は、毛髪化粧料全量中、０．０１〜１０質量％が好ましく、より好ましくは０．１〜４．０質量％である。０．０１質量％未満では、目的とする効果が得られない。１０質量％を超えて用いると、毛髪にべたつきを与えてしまう。 The blending amount of the cationic surfactant is preferably 0.01 to 10% by mass, more preferably 0.1 to 4.0% by mass in the total amount of the hair cosmetic. If it is less than 0.01% by mass, the intended effect cannot be obtained. If it is used in excess of 10% by mass, the hair will be sticky.
（多価アルコールおよび糖アルコール）
本発明に用いられる多価アルコールは、エリスリトール、ジグリセリン、１，３−ブチレングリコールおよびプロピレングリコールから選ばれるものである。その他の多価アルコール、例えばジプロピレングリコール、グリセリン、イソプレングリコールでは毛髪の櫛通り性を良くすることができない。
(Polyhydric alcohol and sugar alcohol)
The polyhydric alcohol used in the present invention is selected from erythritol, diglycerin, 1,3-butylene glycol and propylene glycol. Other polyhydric alcohols such as dipropylene glycol, glycerin, and isoprene glycol cannot improve the combability of hair.
本発明に用いられる糖アルコールとしては、例えばキシリトール、フルクトース、ソルビトール、マンニトール、イノシトール、グルコース、ラクトース、マルチトールまたはスクロース等が挙げられる。多価アルコールまたは糖アルコールのうち、好ましいものは糖アルコールであり、特に糖アルコールの中でもソルビトール、スクロースが好ましい。 Examples of the sugar alcohol used in the present invention include xylitol, fructose, sorbitol, mannitol, inositol, glucose, lactose, maltitol or sucrose. Among the polyhydric alcohols or sugar alcohols, preferred are sugar alcohols, and sorbitol and sucrose are particularly preferred among the sugar alcohols.
上記した特定の多価アルコールおよび／または糖アルコールの合計配合量は、毛髪化粧料全量中、１０〜５０質量％が好ましく、より好ましくは１５〜４０質量％である。１０質量％未満では、目的とする効果が得られない。５０質量％を超えて用いると、毛髪にべたつきを与えてしまう。 10-50 mass% is preferable in the total amount of hair cosmetics, and, as for the total compounding quantity of above-mentioned specific polyhydric alcohol and / or sugar alcohol, More preferably, it is 15-40 mass%. If it is less than 10% by mass, the intended effect cannot be obtained. If it is used in excess of 50% by mass, the hair will be sticky.
（変性シリコーン）
本発明においては、上記必須成分以外に、上記式（１）、（２）または（３）で表される変性シリコーンのいずれか１種あるいは２種以上をさらに配合することが望ましい。
(Modified silicone)
In the present invention, in addition to the essential components, it is desirable to further blend one or more of the modified silicones represented by the above formula (1), (2) or (3).
上記変性シリコーンの好ましい配合量は、０．１〜１０質量％である。０．１質量％以上で毛髪の櫛通り性が改善される。１０質量％を超えて用いると、毛髪にべたつきを与えてしまうという欠点がある。 A preferable blending amount of the modified silicone is 0.1 to 10% by mass. Combability of hair is improved at 0.1% by mass or more. When it exceeds 10 mass%, there exists a fault that it will give stickiness to hair.
（その他）
本発明の毛髪化粧料には、前記の必須成分以外に、本発明の目的をそこなわない範囲で、従来毛髪化粧料に慣用されている各種添加成分を、必要に応じて配合することができる。この添加成分としては、例えばアニオン性界面活性剤、ノニオン性界面活性剤、両性界面活性剤、高重合シリコーン化合物、クエン酸やコハク酸やリンゴ酸等の有機酸又はその塩、グリシンやアラニンやリジン等のアミノ酸、ビニル系のアニオン性ポリマー、カチオン性ポリマー、アクリル系の両性ポリマー、ノニオン性ポリマー、殺菌剤、高級アルコール、炭化水素、天然油脂、エステル油、着色料、香料、溶剤（例えばエタノールやカルビトール誘導体など）、エチレングリコールやグリセリン等の本発明成分以外の多価アルコール、脂肪酸等が挙げられる。これらの添加成分は１種用いてもよいし、２種以上を組み合わせて用いてもよく、また毛髪化粧料調製の適当な段階で配合してもよい。
(Other)
In the hair cosmetic composition of the present invention, in addition to the above essential components, various additive components conventionally used in hair cosmetic compositions can be blended as necessary within a range not detracting from the object of the present invention. . Examples of the additive component include anionic surfactants, nonionic surfactants, amphoteric surfactants, highly polymerized silicone compounds, organic acids such as citric acid, succinic acid and malic acid or salts thereof, glycine, alanine and lysine. Such as amino acids, vinyl anionic polymers, cationic polymers, acrylic amphoteric polymers, nonionic polymers, fungicides, higher alcohols, hydrocarbons, natural fats and oils, ester oils, coloring agents, fragrances, solvents (for example ethanol and Carbitol derivatives, etc.), polyhydric alcohols other than the components of the present invention such as ethylene glycol and glycerin, fatty acids and the like. These additive components may be used singly or in combination of two or more, and may be blended at an appropriate stage of hair cosmetic preparation.
本発明の毛髪化粧料は、例えばヘアトリートメント、シャンプー、ヘアリンス、ヘアコンディショナー、スタイリングフォームなどとして幅広く利用しうる。 The hair cosmetic composition of the present invention can be widely used, for example, as a hair treatment, shampoo, hair rinse, hair conditioner, styling foam and the like.
本発明について以下に実施例を挙げてさらに詳述するが、本発明はこれによりなんら限定されるものではない。配合量は特記しない限り質量％で示す。 The present invention will be described in more detail with reference to the following examples, but the present invention is not limited thereto. Unless otherwise specified, the amount is shown in mass%.
実施例１〜２２、比較例１〜７
下記表１〜表４に示した各処方成分よりなる毛髪化粧料を常法により調製した。得られた毛髪化粧料について、次の基準で、すすぎ時の毛髪の櫛通り性、乾燥後の毛髪の櫛通り性を評価した。
なお、実施例１〜１３、１５〜１９は、いずれも本発明に含まれない参考例である。
Examples 1 to 22 and Comparative Examples 1-7
Hair cosmetics comprising the respective formulation components shown in Tables 1 to 4 below were prepared by a conventional method. About the obtained hair cosmetics, the combability of the hair at the time of rinsing and the combability of the hair after drying were evaluated according to the following criteria.
In addition, Examples 1-13 and 15-19 are all reference examples which are not included in the present invention.
１．すすぎ時の毛髪の櫛通り性、乾燥後の毛髪の櫛通り性
櫛通り試験機としてコーミングテスター（テクノハシモト社製）を用い、次の方法で測定した。
ブリーチ毛髪と櫛が引っかかる事により毛髪束にかかる荷重を検出する。
上記で得られた数値を基に、次の評価基準で判定した。得られた測定数値、および判定を併せて表１〜表３に示す。
1. Combability of hair at the time of rinsing, combability of hair after drying A combing tester (manufactured by Technohashimoto Co.) was used as a comb-through tester, and measurement was performed by the following method.
The load applied to the hair bundle is detected when the bleached hair and the comb are caught.
Based on the numerical value obtained above, the determination was made according to the following evaluation criteria. The obtained measurement values and determinations are shown together in Tables 1 to 3.
（評価基準）
◎：比較例１を１．０とした時の値が０．８以下。
○：比較例１を１．０とした時の値が０．８超、０．９５以下。
△：比較例１を１．０とした時の実施例の値が０．９５超、１．０以下。
×：比較例１を１．０とした時の値が１．０超。
(Evaluation criteria)
A: The value when Comparative Example 1 is 1.0 is 0.8 or less.
A: The value when Comparative Example 1 is 1.0 is more than 0.8 and 0.95 or less.
(Triangle | delta): The value of the Example when the comparative example 1 is set to 1.0 is more than 0.95 and 1.0 or less.
X: The value when the comparative example 1 is 1.0 is more than 1.0.
実施例２３；ヘアコンディショナー
塩化ベヘニルトリメチルアンモニウム ２．０ 質量％
ステアリルアルコール ５．０
スクロース １５．０
変性シリコーン １．０
（前記式（１）中、ｍ＝５０、ｎ＝５、ａ＝０、ｂ＝５の化合物）
防腐剤 適量
香料 適量
精製水 残量
Example 23; hair conditioner behenyltrimethylammonium chloride 2.0% by mass
Stearyl alcohol 5.0
Sucrose 15.0
Modified silicone 1.0
(In the formula (1), m = 50, n = 5, a = 0, b = 5 compound)
Preservative Appropriate amount Perfume Appropriate amount Purified water remaining
実施例２６；ヘアコンディショナー
塩化ベヘニルトリメチルアンモニウム ２．０ 質量％
ステアリルアルコール ５．０
スクロース １５．０
変性シリコーン ２．０
（前記式（１）中、ｍ＝４００、ｎ＝１０、ａ＝２４、ｂ＝２４の化合物）
変性シリコーン １．０
（前記式（３）中、ｍ＝１００００、ｎ＝１０の化合物）
防腐剤 適量
香料 適量
精製水 残量
Example 26; hair conditioner behenyltrimethylammonium chloride 2.0% by weight
Stearyl alcohol 5.0
Sucrose 15.0
Modified silicone 2.0
(In the formula (1), m = 400, n = 10, a = 24, b = 24 compound)
Modified silicone 1.0
(In the formula (3), m = 10000, n = 10 compound)
Preservative Appropriate amount Perfume Appropriate amount Purified water remaining
実施例２７；ヘアミスト
ジメチルポリシロキサン １．０ 質量％
エタノール ５．０
ステアリルアルコール ０．１
ベヘニルアルコール ０．２
スクロース １２．０
ジプロピレングリコール １．０
１，３−ブチレングリコール １．０
塩化アルキルトリメチルアンモニウム（７７％） ０．５
ビニルピロリドン・Ｎ Ｎ−ジメチルアミノエチルメタクリル酸共重合体 ２．５
パラオキシ安息香酸エステル 適量
精製水 残余
香料 適量
Example 27; Hair mist 1.0% by weight dimethylpolysiloxane
Ethanol 5.0
Stearyl alcohol 0.1
Behenyl alcohol 0.2
Sucrose 12.0
Dipropylene glycol 1.0
1,3-butylene glycol 1.0
Alkyltrimethylammonium chloride (77%) 0.5
Vinylpyrrolidone / N N-dimethylaminoethyl methacrylic acid copolymer 2.5
Paraoxybenzoic acid ester Appropriate amount Purified water Residue Perfume
実施例２９；ヘアスプレー
エタノール １０．０ 質量％
スクロース １５．０
ベヘニルアルコール １．０
塩化アルキルトリメチルアンモニウム（７７％） ０．１
ユカフィーマーＳＭ １０．０
ポリオキシエチレン・メチルポリシロキサン共重合体 １．０
揮発性イソパラフィン ５．０
高重合ジメチルポリシロキサン １．０
精製水 残余
香料 適量
Example 29; hair spray ethanol 10.0% by mass
Sucrose 15.0
Behenyl alcohol 1.0
Alkyltrimethylammonium chloride (77%) 0.1
Yuka Femer SM 10.0
Polyoxyethylene / methylpolysiloxane copolymer 1.0
Volatile isoparaffin 5.0
Highly polymerized dimethylpolysiloxane 1.0
Purified water Residue Fragrance Appropriate amount
実施例３０；ヘアスプレー
スクロース ２０．０ 質量％
エタノール ５．０
ユカフォーマーＳＭ １２．０
２−アルキル−Ｎ−カルボキシメチル−Ｎ−
ヒドロキシエチルイミダゾニウムベタイン １．０
ポリオキシエチレン硬化ヒマシ油（６０Ｅ．Ｏ．） ０．５
塩化アルキルトリメチルアンモニウム ０．２
ステアリルアルコール ０．５
パラメトキシ安息香酸エステル 適量
精製水 残余
香料 適量
原液／噴射剤＝９２／８（Ｌ．Ｐ．Ｇ．０．４３ＭＰａ:ＤＭＥ＝８０：２０）
Example 30; hair spray sucrose 20.0% by mass
Ethanol 5.0
Yuka Former SM 12.0
2-alkyl-N-carboxymethyl-N-
Hydroxyethylimidazolium betaine 1.0
Polyoxyethylene hydrogenated castor oil (60 EO) 0.5
Alkyltrimethylammonium chloride 0.2
Stearyl alcohol 0.5
Paramethoxybenzoic acid ester Appropriate amount Purified water Residue Perfume Appropriate amount Stock solution / propellant = 92/8 (LPG 0.43 MPa: DME = 80: 20)
Claims (2)
（式中、ｍ＝３０〜５００、ｎ＝１〜１５、ａ＝０〜３０、ｂ＝５〜３０を示す。）
（式中、ｐ＝２０〜２００、ｑ＝１〜５、ｒ＝５〜１５を示す。）
（式中、ｍ＋ｎ＝３０００〜１００００、ｎ／（ｍ＋ｎ）＝０．００１〜０．００５を示す。） Furthermore, any 1 type, or 2 or more types of the modified silicone represented by following formula (1), (2) or (3) are mix | blended, The hair cosmetics of Claim 1 characterized by the above-mentioned.
(In the formula, m = 30 to 500, n = 1 to 15, a = 0 to 30, and b = 5 to 30 are shown.)
(In the formula, p = 20 to 200, q = 1 to 5, and r = 5 to 15 are shown.)
(In the formula, m + n = 3,000 to 10,000 and n / (m + n) = 0.001 to 0.005 are shown.)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004321808A JP5086522B2 (en) | 2004-11-05 | 2004-11-05 | Hair cosmetics |
| CN2005800368879A CN101048127B (en) | 2004-11-05 | 2005-11-02 | Hair cosmetic |
| PCT/JP2005/020491 WO2006049311A1 (en) | 2004-11-05 | 2005-11-02 | Hair cosmetic composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004321808A JP5086522B2 (en) | 2004-11-05 | 2004-11-05 | Hair cosmetics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2007112716A JP2007112716A (en) | 2007-05-10 |
| JP5086522B2 true JP5086522B2 (en) | 2012-11-28 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004321808A Expired - Fee Related JP5086522B2 (en) | 2004-11-05 | 2004-11-05 | Hair cosmetics |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP5086522B2 (en) |
| CN (1) | CN101048127B (en) |
| WO (1) | WO2006049311A1 (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4837544B2 (en) * | 2005-12-21 | 2011-12-14 | ホーユー株式会社 | Method for suppressing decrease in dyeability or decolorization in dyeing process or decoloring process after decoloring, and fiber treatment composition |
| JP4837543B2 (en) * | 2005-12-21 | 2011-12-14 | ホーユー株式会社 | Method for stabilizing the color tone of dyed fibers |
| JP4825141B2 (en) * | 2007-01-15 | 2011-11-30 | ホーユー株式会社 | Hair treatment composition and hair treatment method |
| JP4993633B2 (en) * | 2009-06-25 | 2012-08-08 | 株式会社 資生堂 | Hair cosmetics |
| WO2016208307A1 (en) * | 2015-06-22 | 2016-12-29 | 花王株式会社 | Hair treatment agent |
| JP6990044B2 (en) * | 2017-05-26 | 2022-01-12 | 花王株式会社 | Hair treatment method |
| FR3073399B1 (en) * | 2017-11-10 | 2020-07-17 | Manon Haulet | COSMETIC HAIR DRYING PROCESS |
| EP3902513A4 (en) * | 2018-12-28 | 2022-10-12 | Henkel AG & Co. KGaA | Solid hair conditioning composition |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6379813A (en) * | 1986-09-22 | 1988-04-09 | Shiseido Co Ltd | Transparent gelatinous hair treating agent composition |
| JPH06122614A (en) * | 1992-05-28 | 1994-05-06 | Shiseido Co Ltd | Hair cosmetic |
| JPH0753333A (en) * | 1993-08-10 | 1995-02-28 | Kao Corp | Hair cosmetic |
| JPH107532A (en) * | 1996-06-14 | 1998-01-13 | Kose Corp | Hair-conditioning composition |
| GB9704050D0 (en) * | 1997-02-27 | 1997-04-16 | Unilever Plc | Hair treatment composition |
| JPH10298149A (en) * | 1997-04-24 | 1998-11-10 | Lion Corp | Dispersion of quaternary ammonium salt at high concentration and its preparation |
| JP2001342120A (en) * | 2000-03-30 | 2001-12-11 | Shiseido Co Ltd | Hair dye, immobilizing agent of hair dye and method for dyeing hair |
| JP2002145733A (en) * | 2000-11-07 | 2002-05-22 | Shiseido Co Ltd | Solid water-in-oil type emulsion cosmetic |
| JP2004143091A (en) * | 2002-10-24 | 2004-05-20 | Kose Corp | Hair cosmetic |
| JP4199552B2 (en) * | 2003-01-31 | 2008-12-17 | 株式会社コーセー | Hair cosmetics |
| JP2006083130A (en) * | 2004-09-17 | 2006-03-30 | Lion Corp | Hair cosmetic and its manufacturing method |
-
2004
- 2004-11-05 JP JP2004321808A patent/JP5086522B2/en not_active Expired - Fee Related
-
2005
- 2005-11-02 CN CN2005800368879A patent/CN101048127B/en active Active
- 2005-11-02 WO PCT/JP2005/020491 patent/WO2006049311A1/en active Application Filing
Also Published As
| Publication number | Publication date |
|---|---|
| CN101048127A (en) | 2007-10-03 |
| JP2007112716A (en) | 2007-05-10 |
| CN101048127B (en) | 2011-01-05 |
| WO2006049311A1 (en) | 2006-05-11 |
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