JP5537070B2 - Hair conditioning composition - Google Patents

Description

  The present invention relates to a hair conditioning composition.

  Hair rinses, hair treatments, hair packs, hair masks, and the like are used as care measures for damaged hair. In these hair conditioning compositions, a cationic surfactant having a hair flexibility effect is blended as a main component, and higher alcohol, liquid paraffin, ester oil, sterols, lipids, silicones are used to further enhance the conditioning effect. A peptide or protein derived from oil, shellfish, fish, silk, plant, seaweed or the like or a derivative thereof is blended. It is known that these conditioning effects can be obtained by physical adhesion, charge adsorption, or penetration of these components onto the hair surface even after rinsing with hot water or water in use.

  Conventionally, sterols have been blended in many cosmetics and compositions regardless of the site of use because of their excellent usability. In recent years, among sterols, phytosterol, which is a plant-derived sterol, is more likely to be used than animal-derived cholesterol. Since these phytosterols have a molecular structure similar to cholesterol, which is a lipid contained in the living body, they are used for wet retention of skin and hair, improvement of skin quality, and hair quality. However, since the melting point of sterols is as high as 100 ° C. or higher and the miscibility and solubility with oil components are poor, in order to increase the miscibility and solubility in oil components at 80 ° C. or less, alkylene oxides such as ethylene oxide and propylene oxide are used. Cosmetics containing a phytosterol derivative to which is added (for example, Patent Document 1) are known. It is known that these phytosterol derivatives not only have a good feeling in use, but can be stably blended in cosmetics and compositions. In addition, hair cosmetics containing phytosterol derivatives to which ethylene oxide has been added (for example, Patent Documents 2 and 3) give a uniform feel from the tips of hairs to the roots with different degrees of damage, and further to hair that has undergone hair color treatment. It is known to prevent fading and give gloss. Moreover, not only hair cosmetics appropriately blended with an ester compound for the purpose of touch control (for example, Patent Document 4), but also hair cosmetics containing a mixture or a specific amount of various ester compounds combined in a specific ratio (for example, Patent Document 5) and hair treatment agents (for example, Patent Document 6) that enhance the permeability of lipid components formulated using two kinds of carboxylic acid diesters are known, and these are moist and excellent in hair. It is known to give a feeling of flexibility and non-stickiness.

Japanese Patent Publication No. 52-79031 JP 2003-176214 A JP 2007-8867 A JP 2002-187819 A JP 2005-239625 A JP 2007-1951 A

  However, in the conventional hair conditioning composition, the touch at the time of use is good, but the touch at the time of finishing is lowered, the hair feels moisturized and flexible, but stickiness occurs, and the feel to the root is good However, there were many cases where the effect on the hair ends was not sufficient.

  Therefore, the object of the present invention is to increase the feeling of use of the oil remaining on the surface or inside of the hair at the time of rinsing and finishing without reducing the advantages of conventional compositions and hair cosmetics, and even after finishing. Gives a moist feeling without stickiness and a feeling of unity at the ends of the hair, and even when used for a long period of time, it suppresses the spread of the ends of the hair and maintains a feeling of bundling up to the tips and a sticky feeling at the ends. An object of the present invention is to provide a hair conditioning composition capable of imparting a moist feeling with good feeling and a good feeling of slipping.

  Therefore, the present inventor has conducted various studies on components that have been conventionally used. First, when blended as an oil agent with various esters singly or in combination, moisturizing and flexibility are imparted, and there is an effect of suppressing stickiness and increasing permeability, but there is a feeling of hair bundle in the hand after drying. It is not satisfactory for the feeling of smoothness and smoothness of fingering, and the lasting moist feeling on the hair tip, but not for satisfying the realization of the sense of penetration that leads to the improvement of hair quality by the type of lipid to be penetrated and its derivatives. There wasn't.

  On the other hand, phytosterols added with ethylene oxide have a strong hydrophilicity of ethylene oxide, so the persistence on the hair surface after rinsing is reduced and the penetration effect into the hair is also reduced. In addition, the moist feeling of the hair ends after finishing was not satisfactory in terms of a moist feeling that lasted for a long period of time on the hair ends.

  Therefore, we focused on phytosterols added with propylene oxide, but those with a large number of added moles of propylene oxide have higher hydrophobicity and higher persistence on the hair surface. The phytosterol derivative molecular weight is not satisfactory, and the penetration effect into the hair is also reduced, and it is still not satisfactory in terms of a long-lasting moist feeling on the hair end It was a thing.

  Therefore, the present inventor further investigated that, by combining polyoxypropylene phytosterol with a small number of added moles of propylene oxide and a dicarboxylic acid ester, and adding a specific silicone compound thereto, the moisturizing feeling and the unity of the hair ends are combined. It has been found that a hair conditioning composition capable of giving a feeling of feeling and giving a feeling of smooth fingering to the end of the hair can be obtained, and the present invention has been completed.

  That is, the present invention provides at least one selected from (A) polyoxypropylene phytosterols having 1 to 10 added moles of propylene oxide, (B) dicarboxylic acid esters, (C) polyglycerol-modified silicones and fluorine-modified silicones. A hair conditioning composition containing a seed silicone compound is provided.

The hair conditioning composition of the present invention imparts a feeling of hair bundle that suppresses the spread of the hair ends peculiar to damaged hair, and also provides a durable moist feeling without sticking to the hair tips after use and a good feeling of slipping fingers. They can also be used for long-term continuous use.
Therefore, the hair conditioning composition of the present invention is damaged by UV damage, perm, coloring, excessive brushing and hair dryer heat, which are daily external factors, resulting from lipid spillage and cuticle damage inside the hair. Gives the splitting of hair, the feeling of unity of the hair tip that spreads with dryness and dryness, the lasting moistness without stickiness even after use, and the smoothness of the tip of the hair.

  Hereinafter, the configuration of the present invention will be described in detail.

The polyoxypropylene phytosterol having an addition mole number of propylene oxide of component (A) used in the hair conditioning composition of the present invention is 1 to 10, which is more hydrophobic than ethylene oxide adduct and has high persistence on hair, Moreover, since the addition mole number is 1 to 10 and low polymerization, the molecular weight is small and the effect of penetrating into the hair is high, so it is possible to maintain a durable touch on the hair. These may be used singly or in combination of two or more of the different moles of propylene oxide within the above range. The number of moles of propylene oxide added is more preferably from 3 to 7, and particularly preferably from 3 to 5, from the viewpoint of penetrability and persistence into the hair and good slipperiness when finished.
In addition, phytosterol includes β-sitosterol, campesterol, stigmasterol, glassicasterol, and the like. In the present invention, these may be used alone or as a mixture.

  The content of the component (A) in the hair conditioning composition of the present invention is preferably 0.01 to 5% by mass from the feeling of penetrating into the hair and following the finish, and the hair ends after use are not sticky. It is more preferably 0.1 to 3% by mass from the viewpoint of moisture with a long lasting feeling and good sliding. Also in the combination of two or more types of component (A), it is desirable that the content is within the above range. Within these ranges, favorable effects can be obtained in terms of the penetration into the hair and the stickiness of the hair surface.

The dicarboxylic acid ester that is the component (B) used in the hair conditioning composition of the present invention acts as a penetration promoting component that further increases the penetration of the component (A) into the hair.
The dicarboxylic acid ester is not particularly limited as long as it is an ester of dicarboxylic acid, and includes dimer linoleic acid mixture fatty acid ester, acidic amino acid diester, dibasic acid ester and the like. Here, as the mixed fatty acid ester of dimerlinolinic acid, dimerlinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl) “Plandool-H” (manufactured by Nippon Seika Co., Ltd.), dimerlinolinic acid dimerlinino Railbis (behenyl / isostearyl / phytosteryl) “Plandool-G” (manufactured by Nippon Seika Co., Ltd.) and the like can be mentioned. As diesters of acidic amino acids, N-lauroyl-L-glutamate di (phytosteryl 2-octyldodecyl) “Erudu PS-203” (manufactured by Ajinomoto Co.), N-lauroyl-L-glutamate di (phytosteryl behenyl 2-octyl) Dodecyl) “El Dew PS-306” (manufactured by Ajinomoto Co., Inc.). Examples of dibasic acid esters include diesters of fatty acid diglycerin and dibasic acids and diesters of dibasic acids. Diesters of fatty acid diglycerin and dibasic acids include diglyceryl adipate mixed fatty acid diesters. (Trade name: SOFTISAN645 [manufactured by SASOL Germany]), diglyceryl sebacic acid mixed fatty acid diester, and the like. As the diester of dibasic acid, alkyl having 1 to 12 carbon atoms of dibasic acid having 2 to 18 carbon atoms. An ester or an alkoxyalkyl ester having 4 to 12 carbon atoms is preferred. Here, the dibasic acid having 2 to 18 carbon atoms includes a linear or branched saturated or unsaturated dibasic acid which may be substituted with a hydroxy group.

  Among these, a low molecular weight dicarboxylic acid ester having a molecular weight of 500 or less is preferred from the viewpoint of penetration into the hair and the effect of promoting penetration of the component (A) into the hair. Specific examples of such dicarboxylic acid esters include, for example, succinic acid diesters such as diethoxyethyl succinate and dioctyl succinate, adipic acid diesters such as diisopropyl adipate, diisobutyl adipate and diethoxyethyl adipate, Sebacic acid diesters such as diethyl sebacate, diisopropyl sebacate, and dioctyl sebacate are good, and among them, sebacic acid diesters can impart an excellent effect on penetrating feeling, rinsing feeling, and feeling after fingering after finishing. Furthermore, diethyl sebacate is mentioned as the most preferable sebacate diester from the feeling of use.

  As content of (B) component in the hair conditioning composition of this invention, (A) / (B) (mass ratio) is 1/5-5/1 with respect to content of the said (A) component. When it is within the range, it is preferable from the viewpoint of penetrating into the hair, feeling of stickiness, and feeling of moisturization with persistence, and it is more preferable that (A) / (B) is in the range of 1/3 to 3/1. .

  The (C1) polyglycerol-modified silicone used in the hair conditioning composition of the present invention is preferably a silicone in which a branched polyglycerol chain is bonded to a silicon atom of dimethylpolysiloxane via a linking group, and further, both ends of dimethylpolysiloxane. A compound in which at least one branched polyglycerol chain is bonded to each other via a linking group containing an oxyphenylene group is preferable. As the polyglycerol-modified silicone, a compound represented by the following general formula (1) is more preferable.

[Wherein, R represents a branched polyglycerol chain in which three or more glycerol groups or glycidol groups are bonded, and at least one of them is a branched glycerol group, and p represents an integer of 0 to 10,000.]

  Among these, the bonding position of the oxygen atom and trimethylene group bonded to the phenylene group is not particularly limited, and may be any of the ortho position, the meta position, and the para position. Examples of branched glycerol groups are represented by the following general formula (3), glycerol groups are represented by general formulas (4) and (5), and glycidol groups are represented by general formula (6).

  The viscosity of the polyglycerol-modified silicone at 30 ° C. is preferably 10,000 to 500,000 mPa · s, and 20,000 to 100,000 mPa · s from the viewpoint that a supple finish feeling can be imparted. Particularly preferred. In addition, the viscosity said here means what was measured by the cosmetics raw material reference | standard and viscosity measuring method 2nd method using the Brookfield type | mold viscosity meter.

  The (C1) polyglycerol-modified silicone is described in JP-A-2004-339244, for example, one or more functional groups selected from the group consisting of a hydroxy group, a carboxy group, an amino group, an imino group, a mercapto group, and an epoxy group. In general, a method described in JP-A-2004-339244, which is produced by adding 2,3-epoxy-1-propanol to a silicone having a group in the presence of an acidic or basic catalyst and graft-polymerizing it, etc. It can be produced by known methods. As a commercial product, “Sofcare GS-G” (manufactured by Kao Co., Ltd.) is a raw material that can be used to exemplify good results, with a glossy, moisturizing effect, improved finger-feeling, and reduced spread of hair tips. Can be granted.

  (C1) Polyglycerol-modified silicone has high adsorptivity due to its high affinity for the hair surface. The content of the polyglycerol-modified silicone in the hair conditioning composition of the present invention is preferably 0.001 to 2% by mass, more preferably 0.005 to 1% by mass from the feeling after washing, and 0.01 to 0.5%. Mass% is particularly preferred.

  Examples of the (C2) fluorine-modified silicone include a silicone having a linear siloxane main chain as a skeleton and a fluorine-substituted hydrocarbon group bonded thereto, and further having a linear siloxane main chain as a skeleton. Silicone in which a hydroxyl group and a fluorine-substituted hydrocarbon group are bonded to each other is preferable. The fluorine-modified silicone has an effect of imparting flexibility and slipperiness to the hair and suppressing the spread of the hair ends after finishing.

  As the (C2) fluorine-modified silicone, those represented by the following general formula (2) are particularly preferred.

[Wherein, R ^{1 to} R ³ , R ⁷ and R ^{9 to} R ¹² represent a group selected from a hydroxyl group, an alkyl group having 1 to 20 carbon atoms, and a phenyl group, and R ⁴ and R ⁵ represent carbon numbers. A group selected from 1 to 20 alkyl groups and a phenyl group, R ⁶ represents a group selected from a fluorine-substituted hydrocarbon group having 1 to 20 carbon atoms, R ⁸ represents a hydroxyl group, and l represents 0 to 20000. An integer of 1 to 20000, n represents an integer of 0 to 2000, and each siloxane unit is randomly polymerized.

Among each unit, R ^{1 to} R ⁵ , R ⁷ and R ^{9 to} R ¹² are preferable because a methyl group can be produced most inexpensively, and R ⁶ is preferably a fluorinated alkyl group, and more preferably a fluorinated C ₁ — A C ₆ alkyl group is preferable, and a trifluoropropyl group is particularly preferable because an intermediate raw material is easily available. R ⁸ is a hydroxyl group, and is effective in reducing the squeaky sensation of hair due to the hydroxyl group contained in the fluorine-modified silicone. Therefore, even when n = 0, it is preferable that at least one of R ^{1 to} R ³ , R ⁷ and R ^{10 to} R ¹² is a hydroxyl group. From the viewpoint of reducing the squeaky feeling, it is most preferable that R ¹ , R ⁸ and R ¹⁰ are hydroxyl groups. The smaller the values of l, m and n, the lower the viscosity, and the higher the value, the higher the viscosity. The property of fluorine-modified silicone is a liquid property when the value of l + m + n is about several tens, and when the value increases, it passes through a viscous liquid and becomes solid when the value is tens of thousands.

(C2) When the property of the fluorine-modified silicone is solid, volatile silicone such as cyclic silicone, dimethylpolysiloxane of 1 × 10 ⁻⁴ m ² / s or less at room temperature, methylphenylpolysiloxane, light liquid isoparaffin, It is preferable to use the fluorine-modified silicone in a solid state dissolved or dispersed in one or more liquid compounds such as fluorine-modified silicone, perfluoropolyether, and lower alcohol that are liquid at room temperature. The concentration at this time is preferably in the range of 5 to 70% by mass with respect to the concentration of the solution. Furthermore, when mixing or dispersing, it is preferable to mix using a mill, such as a roller mill, an attritor, or an extrusion kneader, a mixer, or a kneader.

(C2) Fluorine-modified silicone is fluoroalkylmethyldichlorosilane (F (CF ₂ ) _a C ₂ H ₄ SiMeCl ₂ [wherein Me is a methyl group, in the presence of an organic solvent such as acetonitrile or ethyl acetate; Is an integer of 2 or more]) and zinc oxide, and the resulting reaction mixture is added with a protonic acid such as water and hydrochloric acid and stirred, and the production method described in JP-A-5-86196, It can manufacture according to a well-known manufacturing method.

  The content of the fluorine-modified silicone in the hair conditioning composition of the present invention is preferably 0.001 to 2% by mass, more preferably 0.005 to 1% by mass, and 0.01 to 0.5% by mass from the feeling after washing. % Content is particularly preferred.

  Further, (C1) polyglycerol-modified silicone and (C2) fluorine-modified silicone may be used alone or in combination of two or more, but it is particularly preferable to use both in combination.

  Ingredients (A), (B), (C) constituting the hair conditioning composition of the present invention are preliminarily composed of (A) + (B) + ((C1) and / or (C2)). If it is contained in the same composition, it is preferable because it is uniformly dispersed. For example, a composition (one agent) containing (A) + (B) + (C1) components and (A) + (B ) + (C2) component-containing composition (2 agents) mixed immediately before use, or (A) + (C2) component-containing composition (1 agent) and (B) component By mixing and using a composition containing 2 (2 agents) immediately before use, a unique feel due to a non-uniform feeling of mixing can be obtained, and further, the effect intended by the present invention can be achieved. it can. Examples of the method of mixing immediately before use include a method of simple mixing in the user's palm or another container and then applying to hair, or a method of using a container that simply mixes two agents at the time of discharge.

  The hair conditioning composition of the present invention can further contain other components as long as the effects of the present invention are not impaired. Such components include anionic surfactants, amphoteric surfactants, nonionic surfactants, cationic surfactants, polymers, cationized polymers, plant extracts, seaweed extracts, vitamins, amino acids, amino acid derivatives, Examples include alcohols, oils other than those described above, pearlizing agents, moisturizing ingredients, fragrances, pigments, ultraviolet absorbers, antioxidants, bactericides, anti-inflammatory agents, preservatives, and the like.

  The conditioning composition of the present invention may be either a rinse-off type after application to the hair or a non-wash-in type, but a rinse-type hair conditioning composition is particularly preferred.

Hereinafter, the present invention will be described in detail with reference to examples, but the present invention is not limited thereto. Examples 18 to 21 are reference examples.

The rinse-type hair conditioning composition of the present invention was produced in accordance with conventional methods with the formulations shown in Tables 1 and 2, and the following evaluations were performed. For the component (C2), the following fluorine-modified silicone was used as <C2>.
<C2>
In the general formula (2), R ¹ , R ⁸ and R ¹⁰ are hydroxyl groups, R ^{2 to} R ⁵ , R ⁷ , R ⁹ , R ¹¹ and R ¹² are methyl groups, R ⁶ is a trifluoropropyl group, l = 10, m = 5, n = 10 (where l, m, n are central values, and the actual polymer has a distribution).

<Sensory test evaluation for feel evaluation>
Hair finish test after use (half-head method)
After the panel (20 persons) shampooed with 20% aqueous solution of polyoxyethylene (3) sodium lauryl ether sulfate, the hair was divided into left and right halves, and on the other hand, a wash-type hair conditioning composition shown below was applied as a control, On the other hand, each of the rinse-type hair conditioning compositions shown in the Examples and Comparative Examples was applied and rinsed at the same time, and then the hair was dried, and the hair tips of the left and right hairs were united, the hair tips were not sticky, Sensory evaluation was performed for the moisturizing feeling and durability of the hair tips. Further, the same operation as described above was performed once a day, and the sensory evaluation was performed according to the above items for the finish of the hair after continuous use for one week.

Control (wash-in type hair conditioning composition) (% by mass)
・ Cetanol 5.0
・ Behentrimonium chloride 2.0
・ Concentrated glycerin 2.0
Paraffin 1.0
・ Highly polymerized dimethylpolysiloxane emulsion 2.0
(Product name: KM-902 [manufactured by Shin-Etsu Chemical Co., Ltd.])
・ Phenoxyethanol 0.2
・ Ion exchange water

The standard of evaluation was set as follows (set by the number of people who answered that it was better than the control).
4: 18 or more people who answered good 3: 15 or more people who answered good, less than 18 2: 11 or more people who answered good, less than 15 1: 10 people who answered good Below

Examples 1-12, Comparative Examples 1-11 (washing-type hair conditioning)

  As is apparent from Tables 1 and 2, in the examples satisfying the configuration of the present invention, good results were obtained in all items. On the other hand, in a comparative example in which any of the constitutions of the present invention or the component (A) of the present invention is replaced with a phytosterol derivative to which ethylene oxide is added or a propylene oxide having a large added mole number is added, The evaluation items were inferior, and the object of the present invention could not be satisfied in the continuous test.

  Hereinafter, Examples were produced according to a conventional method.

Example 13 Washing-type hair treatment (prescription ingredient) (mass%)
Stearyl alcohol 6.5
Cetanol 0.5
Polyoxypropylene (5) Phytosterol (A) 0.5
Diethyl sebacate (B) 1.0
Concentrated glycerin 1.0
Propylene glycol 2.0
Behenamidopropyldimethylamine 1.0
Hydroxypropyltrimonium honey 0.1
(Product name: Honeycoat 50 [Arch Personal Products LP])
Hydrolyzed conchiolin solution 0.1
(Product name: Pearl protein extract [Maruzen Pharmaceutical Co., Ltd.])
Hydrolyzed collagen solution 0.1
(Product name: Promois WU-32R [manufactured by Seiwa Kasei Co., Ltd.])
Hydrolyzed silk solution 0.1
(Product name: Fibroin solution [KB Seiren])
Dimer linoleic acid (phytosteryl / isostearyl /
Cetyl / stearyl / behenyl) 0.5
(Product name: Plandool-L [made by Nippon Seika Co., Ltd.])
Bisdiglyceryl polyacyl adipate-2 0.5
(Product name: Softizan 649 [manufactured by SASOL])
Lauroyl glutamate di (phytosteryl / octidodecyl) 0.1
(Product name: L-Du PS-203 [manufactured by Ajinomoto Co., Inc.])
Highly polymerized dimethylpolysiloxane emulsion 2.0
(Product name: KM-902 [Shin-Etsu Chemical Co., Ltd.])
Bis (polyglyceryl-3oxyphenylpropyl) dimethicone 0.1
(Product name: Sofcare GS-G [manufactured by Kao Corporation]) (C1)
<C2> (C2) 0.1
Lactic acid 0.4
Methylparaben 0.1
Phenoxyethanol 0.2
Perfume Appropriate amount of ion-exchanged water

  The above-mentioned washing-type hair treatment not only excels in providing a feeling of unity of the hair after drying, a persistent moist feeling and a slippery finger feeling on the hair tip, but also a rich feeling and no stickiness when rinsing The fingering was good.

Example 14 Washing-type hair treatment (prescription ingredient) (mass%)
Stearyl alcohol 6.5
Cetanol 0.5
Polyoxypropylene (5) Phytosterol (A) 0.5
Diethyl sebacate (B) 1.0
Concentrated glycerin 1.0
Propylene glycol 2.0
Behenamidopropyldimethylamine 0.5
Behentrimonium chloride 0.5
Paraffin 1.0
Hydroxypropyltrimonium honey 0.1
(Product name: Honeycoat 50 [Arch Personal Products LP])
Hydrolyzed conchiolin solution 0.1
(Product name: Pearl protein extract [Maruzen Pharmaceutical Co., Ltd.])
Hydrolyzed collagen solution 0.1
(Product name: Promois WU-32R [manufactured by Seiwa Kasei Co., Ltd.])
Hydrolyzed silk solution 0.1
(Product name: Fibroin solution [KB Seiren])
Olive oil 0.1
Hydrolyzed wheat protein 0.1
(Product name: GLUADIN WLM [manufactured by Cognis Japan])
Hydrolyzed wheat powder 0.1
(Product name: Promois WG [Seiwa Kasei Co., Ltd.])
Bis (polyglyceryl-3oxyphenylpropyl) dimethicone 0.1
(Product name: Sofcare GS-G [manufactured by Kao Corporation]) (C1)
<C2> (C2) 0.1
Lactic acid 0.2
Methylparaben 0.1
Phenoxyethanol 0.2
Perfume Appropriate amount of ion-exchanged water

  The above-mentioned rinse-type hair treatment not only excels in providing a feeling of unity of the hair after drying, a moist feeling without stickiness on the hair tip, and a feeling of slippery fingering, but also a rich feeling during rinsing and a finger without stickiness The streets were good.

Example 15 Wash-type hair conditioner (prescription ingredient) (mass%)
Stearyl alcohol 0.5
Cetanol 5.0
Behenamidopropyldimethylamine 1.2
Stearamidopropyldimethylamine 0.4
Lactic acid 0.6
Behentrimonium chloride 0.2
Concentrated glycerin 2.0
Paraffin 1.0
Polyoxypropylene (5) Phytosterol (A) 0.5
Diethyl sebacate (B) 1.0
Bis (polyglyceryl-3oxyphenylpropyl) dimethicone 0.1
(Product name: Sofcare GS-G [manufactured by Kao Corporation]) (C1)
<C2> (C2) 0.1
Methylparaben 0.1
Phenoxyethanol 0.2
Perfume Appropriate amount of ion exchange water

  The above-mentioned rinse-type hair conditioner not only excels in providing a feeling of unity of the hair after drying, a moisturizing feeling without stickiness on the hair tip, and a smooth sliding feeling, but also a soft finger when rinsing The streets were good.

Example 16 Wash-type hair mask (prescription ingredient) (mass%)
Stearyl alcohol 0.5
Cetanol 7.0
Behenamidopropyldimethylamine 1.0
Lactic acid 0.4
Behentrimonium chloride 1.0
Concentrated glycerin 2.0
Polyoxypropylene (5) Phytosterol (A) 0.5
Diethyl sebacate (B) 1.0
Bis (polyglyceryl-3oxyphenylpropyl) dimethicone 0.1
(Product name: Sofcare GS-G [manufactured by Kao Corporation]) (C1)
<C2> (C2) 0.1
Panax ginseng extract 0.5
Soy protein hydrolyzate (trade name: Promois WS [manufactured by Seiwa Kasei Co., Ltd.]) 0.1
Seaweed extract 0.5
L-alanine 0.1
L-ascorbic acid disodium sulfate 0.1
Methylparaben 0.1
Phenoxyethanol 0.2
Perfume Appropriate amount of ion-exchanged water

  The rinse-type hair mask is not only excellent in providing a feeling of unity of the hair after drying, a durable moist feeling without sticking to the hair tip, and a good feeling of slipping through the fingers, but also a finger that slides when rinsing The streets were good.

Example 17 Washing-type hair treatment (prescription component) with simultaneous use of two agents
(1 agent formulation) (mass%)
Stearyl alcohol 0.5
Cetanol 5.0
Behenamidopropyldimethylamine 1.0
Behentrimonium chloride 1.0
Lactic acid 0.4
Dipropylene glycol 2.0
Polyoxypropylene (5) Phytosterol (A) 0.5
Diethyl sebacate (B) 1.0
Bis (polyglyceryl-3oxyphenylpropyl) dimethicone 0.2
(Product name: Sofcare GS-G [manufactured by Kao Corporation]) (C1)
Methylparaben 0.1
Phenoxyethanol 0.2
Perfume Appropriate amount of ion-exchanged water Residue (2 agent formulation) (mass%)
Stearyl alcohol 0.5
Cetanol 5.0
Behenamidopropyldimethylamine 1.0
Behentrimonium chloride 1.0
Lactic acid 0.4
Dipropylene glycol 2.0
Polyoxypropylene (5) Phytosterol (A) 0.5
Diethyl sebacate (B) 1.0
<C2> (C2) 0.2
Methylparaben 0.1
Phenoxyethanol 0.2
Perfume Appropriate amount of ion-exchanged water

  In the above-mentioned washing-type hair treatment with simultaneous use of two agents, the same amount of one agent and two agents were simultaneously applied to the hair after shampooing. Not only is it excellent in providing a feeling of unity of the hair ends after drying, a persistent moist feeling without stickiness on the hair ends, and a smooth finger-feeling feeling, but also in the uneven feel of the two agents during application There was a feature.

Example 18 Out bath treatment mist (component name) (mass%)
Ethanol 15.0
Glycerin 2.0
Dipropylene glycol 2.0
1,3-butylene glycol 0.5
Dimethicone 0.2
Aminopropyl dimethicone 0.05
Behentrium chloride 0.5
Behenyl alcohol 0.05
Polyoxypropylene (5) Phytosterol (A) 0.1
Diethyl sebacate (B) 0.1
Bis (polyglyceryl-3oxyphenylpropyl) dimethicone 0.1
(Product name: Sofcare GS-G [manufactured by Kao Corporation]) (C1)
<C2> (C2) 0.1
Phenoxyethanol 0.2
Fragrance 0.05
Water residue

Example 19 Out bath treatment milk (component name) (mass%)
Glycerin 1.0
Propylene glycol 5.0
1,3-butylene glycol 2.0
Dimethicone 0.4
Polysilicone-13 0.1
Polyoxypropylene (5) Phytosterol (A) 0.2
Diethyl sebacate (B) 0.2
Bis (polyglyceryl-3oxyphenylpropyl) dimethicone 0.1
(Product name: Sofcare GS-G [manufactured by Kao Corporation]) (C1)
<C2> (C2) 0.1
Sucrose stearate 2.0
Carbomer 0.4
Triethanolamine 0.35
Sodium edetate 0.01
Phenoxyethanol 0.3
Ethanol 8.0
Fragrance 0.1
Water residue

Example 20 Out bath treatment cream (ingredient name) (mass%)
Cetostearyl alcohol 1.5
Steartrimonium chloride 0.2
Propylene glycol 1.0
Dipropylene glycol 1.5
Dimethicone 1.5
Phenyltrimethicone 0.5
Sodium lauryl sulfate 2.0
Macadamia nut fatty acid phytosteryl 1.3
Polyoxypropylene (5) Phytosterol (A) 1.0
Diethyl sebacate (B) 1.0
Bis (polyglyceryl-3oxyphenylpropyl) dimethicone 0.1
(Product name: Sofcare GS-G [manufactured by Kao Corporation]) (C1)
<C2> (C2) 0.1
PEG-10 hydrogenated castor oil 0.7
Hydroxypropyl methylcellulose 0.3
Sodium benzoate 0.2
Phenoxyethanol 0.5
Fragrance 0.3
Water residue

Example 21 Out bath treatment oil (component name) (mass%)
Diethylhexyl succinate 5.0
Polyoxypropylene (5) Phytosterol (A) 1.0
Diethyl sebacate (B) 1.0
Bis (polyglyceryl-3oxyphenylpropyl) dimethicone 0.1
(Product name: Sofcare GS-G [manufactured by Kao Corporation]) (C1)
<C2> (C2) 0.1
Dimethiconol 0.5
Dimethicone 2.0
Walnut seed oil 0.1
Ethylhexyl methoxycinnamate 0.05
Camellia oil 0.1
Fragrance 0.3
Cyclomethicone remaining

Table 3 shows the fragrances used in the compositions of the examples of the present invention.

  The present invention can be used for unprecedented use because it can provide a durable moistness without stickiness on the tip of the hair that spreads due to damage, and a smooth feeling to the tip of the finger that is slippery to the tip of the hair. It is possible to provide a hair conditioning composition that can be expected to have a feeling of finishing and finishing.

Claims (6)

(A) Polyoxypropylene phytosterol having an addition mole number of propylene oxide of 1 to 10 : 0.01 to 5% by mass , (B) dicarboxylic acid ester, (C) (C1) In the following general formula (1) Branched polyglycerol-modified silicone : 0.001 to 2 % by mass and (C2) fluorine-modified silicone represented by the following general formula (2) : at least one silicone compound selected from 0.001 to 2% by mass A rinse-type hair conditioning composition comprising:

[Wherein, R represents a branched polyglycerol chain in which three or more glycerol groups or glycidol groups are bonded, and at least one of them is a branched glycerol group, and p represents an integer of 0 to 10,000.]

[Wherein, R ^{1 to} R ³ , R ⁷ and R ^{9 to} R ¹² represent a group selected from a hydroxyl group, an alkyl group having 1 to 20 carbon atoms, and a phenyl group, and R ⁴ and R ⁵ represent carbon numbers. A group selected from 1 to 20 alkyl groups and a phenyl group, R ⁶ represents a fluorine-substituted hydrocarbon group having 1 to 20 carbon atoms, R ⁸ represents a hydroxyl group, l is an integer of 0 to 20000, m Is an integer from 1 to 20000, n is an integer from 0 to 2000, and each siloxane unit is randomly polymerized.   (B) The hair conditioning composition according to claim 1, wherein the dicarboxylic acid ester is a sebacic acid diester.   (B) The hair conditioning composition according to claim 1 or 2, wherein the dicarboxylic acid ester is diethyl sebacate. The ratio [(A) / (B)] of the content of the component (A) and the component (B) is in the range of 1/5 to 5/1 by mass ratio. Hair conditioning composition. The hair conditioning composition according to any one of claims 1 to 4, wherein the component (C1) and the component (C2) are used in combination. The hair conditioning composition according to any one of claims 1 to 5, wherein the polyoxypropylene phytosterol of component (A) has 3 to 7 moles of propylene oxide added.