JP4331625B2 - Hair cosmetics - Google Patents

Description

The present invention provides (A) a diester of a dicarboxylic acid having 6 to 10 carbon atoms and (B) a sterol,
The present invention relates to a hair cosmetic that can repair hair damage efficiently, containing one or more selected from the group consisting of ceramides and anteiso branched fatty acids.

Lipids such as sterols, ceramides, and anteiso-branched fatty acids are present in the hair, but these lipids are lost from the hair when damaged by chemical treatment such as permanent wave treatment or hair dyeing treatment. It has been known. For the purpose of repairing these hair damages, it is considered effective to use sterols, ceramides, anteiso branched fatty acids and the like. However, sterols, ceramides, anteiso branched fatty acids and the like are difficult to be formulated due to poor solubility, and lipids cannot be sufficiently supplied to the inside of the hair, and the repair effect is insufficient. On the other hand, Japanese Patent Application Laid-Open No. 2003-267840 proposes that N-stearoyl phytosphingosine, cholesterol, plant squalane and phytosteryl isostearate can be used to solve the above problems. . However, it is not sufficient to add N-stearoyl phytosphingosine, cholesterol, vegetable squalane and phytosteryl isostearate proposed in these publications, and N-stearoyl phytosphingosine during storage is not sufficient. There are problems such as the precipitation of cholesterol,
Moreover, since these lipids cannot be replenished enough to the inside of hair, it has not been said that it is still sufficient.
JP 2003-267840 A

An object of the present invention is to provide a hair cosmetic that can efficiently replenish sterols, ceramides, anteiso-branched fatty acids and the like into the hair and repair hair damage.

As a result of intensive studies to solve the above problems, the present inventors have solved the above problems by combining diesters of 6 to 10 carbon dicarboxylic acids with sterols, ceramides, and anteiso branched fatty acids. And the present invention was completed. That is,
The present invention provides a hair cosmetic containing (A) one or more selected from the group consisting of a diester of a dicarboxylic acid having 6 to 10 carbon atoms and (B) a sterol, ceramide, and an anteiso branched fatty acid. To do.

According to the present invention, it is possible to obtain a hair cosmetic that can efficiently supply sterols, ceramides, anteiso branched fatty acids, and the like into the hair to repair hair damage.

The diester of a C6-C10 dicarboxylic acid used in the present invention is a low-viscosity ester oil that can be produced by esterifying a C6-C10 dicarboxylic acid and an alcohol according to a conventional method. Examples of the dicarboxylic acid having 6 to 10 carbon atoms constituting the ester include adipic acid (hexanedioic acid), pimelic acid (heptanedioic acid), which are linear saturated dicarboxylic acids,
Suberic acid (octanedioic acid), azelaic acid (nonanedioic acid), sebacic acid (decanedioic acid)
Branched chain saturated dicarboxylic acids such as 3-methylpentanedioic acid, 2,4-diethylpentanedioic acid, etc .; 1,4-, 1,3-, or 1,2 saturated saturated dicarboxylic acids containing a ring structure −
Cyclohexanedicarboxylic acid, etc .; aromatic dicarboxylic acids such as terephthalic acid, isophthalic acid, phthalic acid, etc. are mentioned. From the viewpoint of touch, safety, availability, and hair damage repair effect when used as a diester, Branched saturated dicarboxylic acids are preferred, and sebacic acid is particularly preferred. As alcohol which comprises this ester, methanol, ethanol, propanol, butanol, hexanol, octanol, decanol, dodecanol; isopropyl alcohol, isobutyl alcohol, 2-butanol, isopentyl alcohol, 2-ethylhexanol, 2-butyloctanol; cyclohexane Saturated monohydric alcohols containing a straight chain, branched chain, or ring structure such as methanol are preferred, but carbon from the touch, safety, availability, and hair damage repairing effect when used as a diester A linear or branched lower alcohol having 1 to 4 is more preferable, and ethanol and isopropyl alcohol are particularly preferable. Examples of particularly preferable diesters of 6 to 10 carbon dicarboxylic acids used in the present invention include diethyl sebacate, diisopropyl sebacate, diisopropyl adipate and the like, and diethyl sebacate and diisopropyl sebacate are most preferable. These can be produced by esterification according to a conventional method, but are also commercially available.

Examples of the sterols used in the present invention include cholesterol, dihydrocholesterol, lanosterol, dihydrolanosterol; sterols such as β-sitosterol, campesterol, stigmasterol, brassicasterol, and phytosterol that is a mixture thereof. Cholesterol and phytosterol are preferable from the viewpoint of damage repair effect and the like, and cholesterol is particularly preferable. Examples of ceramides used in the present invention include natural ceramides (types 1, 2, 3, 4, 5, 6), hydroxyceramides, pseudoceramides, glycosphingolipids, and the like. 2, 3, 4
5, 6) are preferred. Examples of the anteiso branched fatty acid used in the present invention include 18-methyleicosanoic acid, lanolin fatty acid, and long chain branched fatty acid (12 to 31) obtained from lanolin, all of which are preferred.

According to the present invention, (A) one or more selected from the group consisting of a diester of a dicarboxylic acid having 6 to 10 carbon atoms and (B) a sterol, a ceramide, and an anteiso branched fatty acid is used as a hair cosmetic. By containing, it has an effect of efficiently repairing hair damage.

The hair cosmetics in the present invention include oil shampoo, cream shampoo, conditioning shampoo, dandruff shampoo, hair color shampoo, rinse-in shampoo, etc .; rinse, treatment, leave-on treatment, hair essence, hair pack, hair oil, hair Foam, hair mousse, hair spray, hair mist, hair wax, hair gel, water grease, set lotion, color lotion, hair liquid, pomade, tic, hair cream, hair blow, split hair coat, hair oil, permanent wave agent, oxidative hair dye , Hair bleach, hair color pre-treatment, hair color after-treatment, perm pre-treatment, perm after-treatment, hair mani Interview A, it can be exemplified hair tonic or the like. 6 to 1 carbon
The blending amount of the diester of 0 dicarboxylic acid into the hair cosmetic is generally 0.01 to 99.99.
99% by weight, preferably 0.1 to 50% by weight, more preferably 0.5 to 20% by weight, and the amount of sterols, ceramides, and anteiso branched fatty acids to be added to the hair cosmetic is generally Is 0.001 to 50% by weight, preferably 0.05 to 20% by weight, more preferably 0.1 to 10% by weight. The compounding ratio of the component (A) and the component (B) is (A) of the component (B).
) (B) :( A) = 1: 1 from the solubility with respect to a component and the favorable hair damage repair effect.
˜1: 1000 (weight ratio) is preferable, and (B) :( A) = 1: 10 to 1: 100 (weight ratio) is particularly preferable. If the blending amount is within this range, hair damage can be repaired efficiently.

In addition to the above, the hair cosmetics of the present invention, other than those mentioned above, are usually added to the hair cosmetics, such as oils, surfactants, moisturizers, thickeners / gels, and the like. Agent,
Antioxidants, preservatives, bactericides, chelating agents, pH adjusters / acids / alkalis, solvents, reducing agents /
Oxidizing agents, ultraviolet absorbers, anti-inflammatory agents, refreshing agents, antihistamines, astringents, stimulants, hair-restoring agents, vitamins and derivatives thereof, hydroxy acids, enzymes, nucleic acids, hormones, sugars and derivatives thereof, Inorganic powders, polymer powders, fragrances, pigments and the like can be blended.

Examples of these additives include oils and fats, hydrocarbon oils such as liquid paraffin, squalane, hydrogenated polyisobutene; palm oil, palm oil, palm kernel oil, safflower oil, olive oil, castor oil, avocado oil, sesame oil , Tea oil, evening primrose oil, wheat germ oil, macadamia nut oil, hazelnut oil, kukui nut oil, rosehip oil, meadow foam oil, persic oil, tea tree oil, peppermint oil, corn oil, rapeseed oil, sunflower oil, wheat germ oil, Vegetable oils such as linseed oil, cottonseed oil, soybean oil, peanut oil, rice bran oil, cacao butter, shea butter, hydrogenated palm oil, hydrogenated castor oil, jojoba oil, hydrogenated jojoba oil; beef fat, milk fat, horse fat, Animal fats and oils such as egg yolk oil, mink oil, turtle oil, whale wax, lanolin, orange luffy oil; liquid lanolin, reduced ras Lanolins such as phosphorus, adsorption purified lanolin, lanolin acetate, liquid lanolin acetate, hydroxy lanolin, polyoxyethylene lanolin, lanolin fatty acid, hard lanolin fatty acid, lanolin alcohol, lanolin alcohol acetate, acetic acid (cetyl lanolyl) ester; cetyl octanoate , Octyl palmitate, octyl dodecyl myristate, hexyl decyl myristate, oleyl oleate, octyl dodecyl oleate, lanolin fatty acid octyl dodecyl, hexyl decyl octanoate, isononyl isononanoate, isotridecyl isononanoate, isosteyl neopentanoate, isodecyl neopentanoate , Octyldodecyl neodecanoate, ethyl oleate, ethyl avocado oil fatty acid, isopropyl palmitate, isopropyl myristate , Fatty acid esters such as isopropyl isostearate, lanolin fatty acid isopropyl and dioctyl succinate; oxyacid esters such as cetyl lactate and diisostearyl malate; glyceryl trioctanoate, glyceryl trioleate, glyceryl triisostearate, tri (capryl) Capric acid) glyceryl, hydrogenated rosin glyceryl (hydrogenated ester gum), pentaocteric ester tetraoctanoate, hydrogenated rosin pentaerythrityl, propylene glycol dioleate, neopentyl glycol dioctanoate, 2-butyl-2-dioctanoate Ethyl-1,3-propanediol, (hydroxystearic acid / stearic acid / rosinic acid) dipentaerythrityl, diglyceryl diisostearate, polytetraisostearate Polyhydric alcohol fatty acid esters such as glyceryl; dimer dilinoleic acid dimer dilinoleyl, dimer dilinoleic acid di (isostearyl / phytosteryl), dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl), dimer Linoleic acid (phytosteryl / behenyl), dimer linoleic acid (dimerdiol / phytosteryl / behenyl / isostearyl), dimer dilinoleate diisostearyl, dimer dilinoleate diisopropyl, diisostearate dimer dilinoleyl, dimer di nore water Dimer acid or dimer such as rosin-added rosin condensate, dimer acid hydrogenated castor oil, hydroxyalkyl dimer linoleyl ether, dimer acid, hydrogenated dimer acid, dimer diol Derivatives of diols; cholesteryl acetate, cholesteryl nonanoate, cholesteryl stearate, cholesteryl isostearate, cholesteryl oleate, phytosteryl oleate, di-N-lauroyl-L-glutamate (cholesteryl / behenyl / octyldodecyl), N-lauroyl-L- Glutamate di (cholesteryl / octyldodecyl), N-lauroyl-L-glutamate di (phytosteryl / behenyl / octyldodecyl), N-lauroyl-L-glutamate di (phytosteryl / octyldodecyl), cholesteryl 12-hydroxystearate, 12- Phytosteryl hydroxystearate, macadamia nut oil fatty acid cholesteryl, macadamia nut oil fatty acid phytosteryl, phytosteryl isostearate, Sterol esters such as lanolin fatty acid cholesteryl, hard lanolin fatty acid cholesteryl, long chain branched fatty acid cholesteryl, long chain α-hydroxy fatty acid cholesteryl; petrolatum, solid paraffin, candelilla wax, carnauba wax, rice wax, waxy wax, beeswax , Montan wax, ozokerite, ceresin, paraffin wax, microcrystalline wax, petrolatum, Fischer-Tropsch wax, polyethylene wax, ethylene
Waxes such as propylene copolymer; phospholipids such as phosphatidylcholine, phosphatidylethanolamine, phosphatidylinositol, sphingomyelin, phosphatidic acid, lysolecithin; phospholipid derivatives such as hydrogenated soybean phospholipid, hydrogenated egg yolk phospholipid; perfluoro Polyethers; As higher alcohols, myristyl alcohol, cetanol, stearyl alcohol, cetostearyl alcohol, aralkyl alcohol, behenyl alcohol, oleyl alcohol, isostearyl alcohol, octyldodecanol, hexyl decanol, jojoba alcohol, chimyl alcohol, batyl alcohol, etc. Alcohol derivatives; lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, behenic acid, Ndeshiren acid, 12-hydroxystearic acid, palmitoleic acid, oleic acid, linoleic acid, linolenic acid, erucic acid, docosahexaenoic acid,
Higher fatty acids such as eicosapentaenoic acid, isohexadecanoic acid, anteisohenicosanoic acid and salts thereof; coconut oil fatty acid monoethanolamide, coconut oil fatty acid diethanolamide,
Fatty acid alkanolamides such as lauric acid monoethanolamide, lauric acid diethanolamide, palmitic acid monoethanolamide, palmitic acid diethanolamide, low viscosity dimethylpolysiloxane, high viscosity dimethylpolysiloxane, cyclic dimethylsiloxane (decamethylcyclopentasiloxane) , Methylphenyl polysiloxane, diphenyl polysiloxane, silicone resin, silicone rubber, amino modified polysiloxane, cation modified polysiloxane, polyether modified polysiloxane, polyglycerin modified polysiloxane, sugar modified polysiloxane, alkyl modified polysiloxane, fatty acid modified Examples thereof include silicones such as polysiloxane and fluorine-modified polysiloxane.

Surfactants include fatty acid salts, alkyl sulfate esters, alkyl benzene sulfonates, polyoxyethylene alkyl sulfates, polyoxyethylene fatty amine sulfates, acyl N-methyl taurates, alkyl ether phosphates, alkyl ethers. Anionic surfactants such as sulfonates and N-acyl amino acid salts; polyoxyethylene alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene alkyl ether sorbitan fatty acid partial ester, polyoxyethylene hydrogenated castor oil, polyvalent Nonionic surfactants such as alcohol fatty acid partial esters, polyglycerin fatty acid esters, polyoxyethylene fatty acid esters, alkyldimethylamine oxides, alkyl polyglycosides, alkyl glucosides; Cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, stearyltrimethylammonium bromide, behenyltrimethylammonium chloride, distearyldimethylammonium chloride, dicocoyldimethylammonium chloride, dicetyldimethylammonium chloride, ethyl lanolin sulfate fatty acid amidopropylethyldimethylammonium Long-chain branched fatty acid amidopropyl ethyl dimethyl ammonium, stearic acid amidopropyl dimethylamine, stearic acid amidoethyl diethylamine, lanolin fatty acid amidopropyl dimethylamine, long chain branched fatty acid amidopropyl dimethylamine etc. fatty acid amidoamine salt, short chain polyoxyethylene alkyl Such as amines and their salts or quaternary salts, benzalkonium chloride Amphoteric surfactants such as alkyldimethylaminoacetic acid betaine, alkylamidodimethylaminoacetic acid betaine, 2-alkyl-N-carboxy-N-hydroxyimidazolinium betaine; polyvinyl alcohol, sodium alginate, starch derivatives, Examples thereof include polymer surfactants such as tragacanth gum and acrylic acid / alkyl methacrylate copolymers;

Examples of humectants include propylene glycol, glycerin, 1,3-butanediol, 3-
Polyhydric alcohols such as methyl-1,3-butanediol, sodium hyaluronate, citrate, urea, lactic acid bacteria culture solution, yeast extract, eggshell membrane protein, submandibular gland mucin, hypotaurine, sesameignan glycoside, Betaine, chondroitin sulfate, glutathione, polyethylene glycol, sorbitol, carbitol, sodium lactate, sodium 2-pyrrolidone-5-carboxylate, albumin, trimethylglycine; collagen, gelatin, elastin, collagen degrading peptide, elastin degrading peptide, keratin degrading peptide Protein peptides such as conchiolin degrading peptide, silk proteolytic peptide, soybean proteolytic peptide, wheat proteolytic peptide, casein degrading peptide and derivatives thereof; arginine, serine, glycine, threonine, Amino acids such as glutamic acid, cysteine, methionine, leucine, and tryptophan; animal and plant extract components such as placenta extract, aerustin, collagen, aloe extract, hamamelis water, loofah water, chamomile extract, licorice extract, and comfrey extract It can be illustrated.

As a thickener and gelling agent, guar gum, quince seed gum, xanthan gum, carrageenan, alginic acid, tragacanth gum, starch derivative, sodium carboxymethylcellulose, carboxyvinyl polymer, acrylic acid / methacrylic acid ester copolymer,
Acrylic acid / alkyl methacrylate copolymer, polyvinyl alcohol, polyvinylpyrrolidone, amphoteric methacrylate copolymer, cationized cellulose, nitrocellulose; 12-hydroxystearic acid and its salts, dextrin fatty acid ester, silicic anhydride, metal Examples include soaps, organically modified clay minerals, sucrose fatty acid esters, fructooligosaccharide fatty acid esters, and the like.

Examples of the antioxidant include vitamin E (tocopherol) and / or its derivative, vitamin C (ascorbic acid) and / or its derivative, BHT, BHA, propyl gallate and the like. Examples of preservatives include p-hydroxybenzoic acid esters, phenoxyethanol, 1,2-pentanediol, 1,2-hexanediol, quaternary ammonium salts and the like. Examples of the bactericides include trichlorocarbanide, zinc pyrithione, benzalkonium chloride, benzethonium chloride, chlorhexidine, halocarban, hinokitiol, phenol, isopropylphenol, and photosensitizers. Examples of chelating agents include edetate, phytic acid, phosphonic acids, polyamino acids and the like. Examples of pH adjusters / acids / alkalis include citric acid, lactic acid, glycolic acid, succinic acid, hydrochloric acid, monoethanolamine, diethanolamine, triethanolamine, arginine, sodium hydroxide, potassium hydroxide, aqueous ammonia, etc. Can do. Examples of the solvents include lower alcohols such as ethanol and 2-propanol; acetone, ethyl acetate, ethylene glycol monoethyl ether, and the like. Examples of the reducing agent include thioglycolic acid, cysteine, cysteamine and the like. Examples of the oxidizing agent include aqueous hydrogen peroxide, ammonium persulfate, and sodium bromate.

Examples of ultraviolet absorbers include benzophenone derivatives, paraaminobenzoic acid derivatives, paramethoxycinnamic acid derivatives, salicylic acid derivatives, urocanic acid, urocanic acid ethyl, 4-te
Examples thereof include rt-butyl-4′-methoxydibenzoylmethane, 2- (2′-hydroxy-5′-methylphenyl) benzotriazole, methyl anthranilate, rutin and derivatives thereof. Examples of the anti-inflammatory agent include glycyrrhizic acid and its derivatives, guaiazulene, hydrocortisone acetate, prednisone, salicylic acid derivatives and the like. Examples of the refreshing agent include menthol and methyl salicylate. Examples of the antihistamine include diphedramine hydrochloride, chlorpheniramine maleate, glycyrrhetinic acid derivatives and the like. Examples of the astringent include citric acid, tartaric acid, lactic acid, aluminum sulfate / potassium sulfate, and tannic acid. Examples of the stimulant include cantalis tincture, ginger tincture, chili pepper tincture, benzyl nicotinate and the like. Hair growth medicines include assembly extract, cephalanthin, vitamin E
And derivatives thereof, γ-oryzanol, capsicum tincture, ginger tincture, cantharis tincture, nicotinic acid benzyl ester, allantoin, photosensitive element 301, photosensitive element 401, and the like.

Vitamins and their derivatives include vitamin A, vitamin B group, vitamin D, vitamin E, pantothenic acid, biotin and the like; ascorbyl stearate, ascorbyl palmitate, ascorbyl dipalmitate, ascorbyl magnesium phosphate, ascorbine Examples thereof include vitamin derivatives such as sodium acid, tocopherol nicotinate, tocopherol acetate, tocopherol linoleate, and tocopherol ferulate. α-hydroxy acids and derivatives thereof include lactic acid, glycolic acid, fruit acid,
Examples thereof include hydroxycapric acid, long chain α-hydroxy fatty acid, long chain α-hydroxy fatty acid cholesteryl and the like. Examples of enzymes include lysozyme chloride, papain, pancreatin, protease, and the like. Examples of nucleic acids include adenosine triphosphate disodium. Examples of hormones include estradiol, estrone, ethinyl estradiol, cortisone, hydrocortisone, prednisone and the like. Sugars and derivatives thereof include cyclodextrin, β-glucan, chitin, chitosan, glucose, trehalose, pectin, arabinogalactan,
Examples include dextrin, dextran, glucosylethyl methacrylate polymer or copolymer.

Inorganic powders include mica, talc, kaolin, montmorillonite, sericite, kaolinite, calcium carbonate, bengara, yellow iron oxide, black iron oxide, ultramarine, bitumen, carbon black, titanium dioxide, zinc oxide, alumina, silica. Examples include fumed silica, mica titanium, fish scale foil, boron nitride, photochromic pigment, synthetic fluorine phlogopite, fine particle composite powder, gold, aluminum, etc. can do. As polymer powder, starch, nylon powder, polyethylene powder, polymethyl methacrylate, polyethylene terephthalate / polymethyl methacrylate laminated powder, etc., and
These assertion-treated powders can be exemplified.

Examples of the fragrance include limonene, linanol, citral, β-ionone, benzyl benzoate, indole, eugenol, auranthiol, geraniol, rilal, damascon, benzyl acetate, jasmine lactone, galac solid, essential oil and the like. As pigments, natural pigments such as β-carotene, calsamine, rutin, cochineal, chlorophyll; legal pigments, basic dyes, lakes, organic pigments; p-phenylenediamine,
Examples include toluene-2,5-diamine, m-phenylenediamine, o-, m-, or oxidative dye intermediates such as p-aminophenol and resorcin.

In addition, other components used in known cosmetics, pharmaceuticals, foods and the like can be appropriately blended as long as the effects of the present invention are not impaired.

As the dosage form of the hair cosmetic of the present invention, an oil-in-water (O / W) type, a water-in-oil (W / O) type, W /
O / W type, O / W / O type emulsified cosmetics, oily cosmetics, solid cosmetics, liquid cosmetics, kneaded cosmetics, stick cosmetics, volatile oil cosmetics, powder cosmetics , Jelly cosmetics, gel cosmetics, paste cosmetics, emulsified polymer cosmetics, sheet cosmetics, mist cosmetics, spray cosmetics and the like. The cosmetic of the present invention can be produced according to a usual method.

EXAMPLES Hereinafter, although this invention is demonstrated in detail using an Example, this invention is not limited to these Examples.

Example 1, Comparative Examples 1 and 2 Hair rupture strength recovery effect by hair cosmetics Hair cosmetics having the compositions of Example 1, Comparative Examples 1 and 2 and Table 1 were prepared by a conventional method (Table 1). Healthy black hair was subjected to permanent treatment once with a commercially available permanent wave treating agent and twice with a commercially available two-component oxidative hair dye to prepare four bundles of 50 damaged hairs. After immersing in 30 g of each hair cosmetic of Example 1, Comparative Example 1 and 2 and treating at 40 ° C. for 30 minutes, it was washed with 5% aqueous solution of laureth sulfate and washed with water. The remaining one bundle was untreated hair as a comparative control. After leaving it to stand at room temperature of 25 ° C. and humidity of 45% for 18 hours, 20 hairs were collected and the hair strength was measured with a pulling tester (Rheometer / Fudo Kogyo Co., Ltd.). The measurement results are shown in Table 2. Further, the hair cosmetic was stored at 40 ° C. or 25 ° C. for 18 hours, and the presence or absence of precipitation of cholesterol was visually confirmed.

(result)
As shown in Table 2, when treated with the hair cosmetic composition of Example 1 in which cholesterol was dissolved in diethyl sebacate, the hair breaking strength was restored to the level of untreated (normal hair). on the other hand,
In the treatment of Comparative Example 1 in which cholesterol is dissolved in cetyl octoate and Comparative Example 2 of only diethyl sebacate not containing cholesterol, the hair breaking strength is hardly recovered, so that the hair cosmetic of the present invention is useful. I understood. As a result of visual confirmation of the appearance of the hair cosmetic stored at 25 ° C. for 18 hours, the hair cosmetic of Example 1 in which cholesterol was dissolved in diethyl sebacate was transparent, whereas cetyl octanoate In Comparative Example 1 in which cholesterol was dissolved, cholesterol was precipitated and precipitated. Therefore, it was found that the use of diethyl sebacate can improve the stability of cholesterol blending.

Example 2 Treatment A treatment having the following formulation was prepared. This treatment was a treatment capable of repairing hair damage.
Component Blending amount (% by weight)
--------------------------------
1 Diethyl sebacate 1.0
2 Cholesterol 0.1
3 Steartrimonium chloride (63%) 2.0
4 Behentrimonium chloride (80%) 0.6
5 Glyceryl stearate (SE) 2.0
6 Steerless-10 0.8
7 Cetanol 7.0
8 Isopropyl myristate 1.5
9 Chloromethacrylic acid choline ester polymer / di (caprylic acid / capric acid) propylene glycol (Ciba Specialty Chemicals, Salcare SC96)
1.0
10 Methylparaben 0.2
11 Citric acid appropriate amount
12 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. No. 12 was heated to about 80 ° C. 10 was added and dissolved (part A). No. in a separate container.
1-9 were added, and it heated and dissolved (part B). Gradually add Part A to Part B and mix evenly.
No. at room temperature. 10 to pH 4.5-5.0.

Example 3 Mild Shampoo A mild shampoo having the following formulation was prepared. This shampoo had good foaming, and was not stiff from the time of rinsing until after drying, thereby suppressing the feeling of damage.
Component Blending amount (% by weight)
--------------------------------
1 Diethyl sebacate 0.5
2 Cholesterol 0.05
3 Cocoyl methyl methyl taurine Na (30%) 30.0
4 Cocamidopropyl betaine (30%) 20.0
5 Laureth-12 Na acetate (30%) 5.0
6 1,3-Butylene glycol 1.0
7 Cocamide MEA 2.0
8 Glycol distearate 1.5
9 Polyquaternium-10 0.8
10 Cationic NH (Nippon Seika Co., Ltd.) 0.5
11 Sodium benzoate 0.4
12 Phenoxyethanol 0.2
13 Methylparaben 0.2
14 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. 1 to 8 were heated to about 80 ° C. and dissolved (part A). No. in a separate container. 9-14 about 8
Heated to 0 ° C. to dissolve (Part B). While stirring Part B into Part A, they were gradually added and mixed uniformly, and then rapidly cooled.

Example 4 Hair Shampoo A hair shampoo having the following formulation was prepared. This shampoo was able to give a light and slippery feeling by suppressing the hair stiffness.
Component Blending amount (% by weight)
--------------------------------
1 Diisopropyl adipate 0.5
2 YOFCO FA-NH (Nippon Seika Co., Ltd.) 0.05
3 Plandool-H (Nippon Seika Co., Ltd.) 1.5
4 Sodium cocoyl glutamate (30%) 40.0
5 Olefin (C14-16) sulfonic acid Na solution (37%) 10.0
6 Lauramide MIPA 4.5
7 Dioleic acid PEG-120 methyl glucose 2.0
8 SIMULGEL EG (made by SEPPIC) 3.0
9 Methylparaben 0.2
10 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. No. 10 is heated to about 80 ° C. 9 was added and dissolved (part A). No. in a separate container. 1
˜7 was added, heated and dissolved (part B). Gradually add Part A to Part B and mix evenly. 8 was added.

Example 5 Hair bleaching agent (2 agent type)
A hair bleaching agent (two-part formulation) having the following formulation was prepared. This hair depigmenting agent (two-component type) was a depigmenting agent that, when applied to the hair, suppressed damage to the hair and imparted a good feel such as flexibility and slippage to the hair.
(1 agent)
Component Blending amount (% by weight)
--------------------------------
1 Diisopropyl sebacate 0.5
2 YOFCO FA-NH (Nippon Seika Co., Ltd.) 0.05
3 Polyoxyethylene oleyl ether 52.0
4 Ammonia water (25%) 25.5
5 Cetrimonium chloride (30%) 10.0
6 Ethanol 10.0
7 Purified water Total amount of 100 --------------------------------
(Preparation method)
Each component was stirred and mixed uniformly.
(2 agents)
Component Blending amount (% by weight)
--------------------------------
1 Hydrogen peroxide solution 17.0
2 Cetrimonium chloride (30%) 10.0
3 Cetanol 3.0
4 Seth-2 1.0
5 Seths-20 1.0
6 Na pyrophosphate 0.1
7 Diethylenetriaminepentaacetic acid 0.1
8 Citric acid appropriate amount
9 Purified water Total amount of 100 --------------------------------
(Preparation method)
Each component was mixed uniformly, and the pH was adjusted to 3.5 to 4.0 with citric acid.
(Mixing ratio)
1 agent: 2 agents = 1: 7

Example 6 Hair depigmenting agent (3-agent type)
A hair bleaching agent (three-part formulation) having the following formulation was prepared using the composition for producing a cosmetic according to the present invention.
In addition, 1 agent and 2 agents of Example 12 were used for 1 agent and 2 agents. This hair bleaching agent (three-component formula) was a bleaching agent that, when applied to the hair, suppressed damage to the hair and imparted a good feel to the hair such as flexibility and slipping.
(3 agents)
Component Blending amount (% by weight)
--------------------------------
1 Ammonium persulfate 65.0
2 Sodium carbonate 35.0
--------------------------------
(Preparation method)
Each component was mixed uniformly.
(Mixing ratio)
1 agent: 2 agents: 3 agents = 3: 6: 1

Example 7 Oxidative hair dye An oxidative hair dye having the following formulation was prepared. This oxidative hair dye was an oxidative hair dye capable of imparting a good feel such as flexibility and slipperiness to the hair by treating the hair.
(1 agent)
Component Blending amount (% by weight)
--------------------------------
1 Diethyl sebacate 0.5
2 Cholesterol 0.02
3 Cetrimonium chloride (25%) 24.0
4 Cetanol 9.0
5 Octyldecanol 9.0
6 Monoethanolamine 3.8
7 Ammonia water 2.0
8 Myristyl sulfate Na 1.5
9 Ores-20 1.4
10 Toluene-2,5-diamine hydrochloride 1.0
11 Resorcin 1.0
12 Metaaminophenol 0.5
13 Paraaminophenol 0.2
14 Orthoaminophenol 0.1
15 Ascorbic acid 0.2
16 Fragrance 0.1
17 Purified water Total amount of 100 --------------------------------
(Preparation method)
Each component was mixed uniformly.
(2 agents)
Component Blending amount (% by weight)
--------------------------------
1 Hydrogen peroxide solution 17.0
2 Cetrimonium chloride (25%) 10.0
3 Cetanol 3.0
4 Ores-2 1.0
5 Ores-20 1.0
6 Na pyrophosphate 0.1
7 Diethylenetriaminepentaacetic acid 0.1
8 Citric acid (50%) appropriate amount
9 Purified water Total amount of 100 --------------------------------
(Preparation method)
Each component was mixed uniformly and the pH was adjusted to 3.5-4.0 with citric acid.
(Mixing ratio)
1 agent: 2 agents = 1: 1

Example 8 Acid hair dye The acid hair dye of the following prescription was prepared. This acidic hair dye was an acidic hair dye capable of imparting a good feel such as flexibility and slipperiness to the hair by performing treatment on the hair.
Component Blending amount (% by weight)
--------------------------------
1 Diisopropyl sebacate 0.5
2 Cholesterol 0.1
3 N-methylpyrrolidone 15.0
4 Benzyl alcohol 8.0
5 Citric acid 1.0
6 Brown 201 0.13
7 Black 401 No. 0.05
8 Purified water Total amount of 100 --------------------------------
(Preparation method)
Each component was mixed uniformly.

Example 9 Cysteine permanent agent A cysteine permanent agent having the following formulation was prepared. This cysteine-based permanent agent is a permanent agent that can impart good touches such as damage suppression, flexibility, and a feeling of slipping, and can maintain wave formation by performing treatment on hair.
(1 liquid)
Component Blending amount (% by weight)
--------------------------------
1 Diethyl sebacate 0.5
2 YOFCO FA-NH (Nippon Seika Co., Ltd.) 0.02
3 Monoethanolamine 4.5
4 L-cysteine hydrochloride 3.2
5 Acetylcysteine 2.5
6 Ores-20 2.0
7 Ammonium thioglycolate solution (50%) 1.9
8 PEG-20 sorbitan cocoate 1.0
9 Ammonia water (28%) 0.3
10 Purified water Total amount of 100 --------------------------------
(Preparation method)
Each component was stirred and mixed uniformly.
(2 liquids)
Component Blending amount (% by weight)
--------------------------------
1 Diisopropyl sebacate 0.5
2 YOFCO FA-NH (Nippon Seika Co., Ltd.) 0.1
3 Sodium benzoate 0.2
4 Edetic acid 2Na 0.1
5 Diammonium phosphate 0.1
6 Emmacol TS-703 (Sanei Chemical Co., Ltd.) 2.0
7 Stearyltrimonium chloride (50%) 2.0
8 Na bromate 10.0
9 Emacol NZ (manufactured by Sanei Chemical Co., Ltd.) 4.0
10 Ores-20 3.0
11 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. Take most of 10 and heat to about 60 ° C. No. 1 to 3 were added and dissolved.
4 was added and dissolved. Then No. Add 5 and 6 and heat, dissolve and slowly cool to 40 ° C
No. 7-9 was added and made uniform. The remaining No. 10 was added, mixed uniformly and cooled.

Example 10 Thioglycolic acid-based permanent agent A thioglycolic acid-based permanent agent having the following formulation was prepared. This thioglycolic acid-based permanent agent was a permanent agent that gave hair a feeling of slipping and softness when applied to the hair.
(1 liquid)
Component Blending amount (% by weight)
--------------------------------
1 Diethyl sebacate 1.0
2 Cholesterol 0.1
3 Polyquaternium-22 2.0
4 Monoethanolamine 1.0
5 Ammonia water (28%) 1.0
6 PEG-50 hydrogenated castor oil 0.2
7 Ammonium bicarbonate 2.0
8 Phosphoric acid 2Na 0.5
9 Ammonium thioglycolate aqueous solution (50%) 11.5
10 Cysteine 1.5
11 EDTA-4Na 0.15
12 Hydroxide Na 0.25
13 Polyquaternium-10 0.1
14 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. No. 14 in most of No. 12 is dissolved, and then No. 12 is dissolved. No. 13 was added in small portions and dissolved. 9 to 11 were added and dissolved (part A). No. in a separate container. Take the rest of No. 13, 7, 8 was added and heated and dissolved (part B). No. in a separate container. Add 1-6, about 5
Warm to 0 ° C. and dissolve (part C). Part B was added to part A and mixed uniformly, then part C was gradually added and mixed uniformly.
(2 liquids)
Two liquids of Example 16 were used.

Example 11 Straight Perm Agent (Cation Type)
One part and two parts of a straight perm agent (cation type) having the following formulation were prepared. This straight perm agent was able to hold the hair firmly during the treatment, and was excellent in slipperiness after washing.
(1 liquid)
Component Blending amount (% by weight)
--------------------------------
1 Diisopropyl sebacate 0.5
2 Ceramide 2 0.01
3 Cetanol 5.0
4 Steartrimonium chloride 2.4
5 Seths-20 2.4
6 TRIBEHENIN PEG-20 ESTERS 2.0
7 Seth-6 0.8
8 Lauric acid monoisopropanolamide 0.8
9 PEG-60 hydrogenated castor oil 0.4
10 Ammonium thioglycolate solution (50%) 13.5
11 Monoethanolamine 1.7
12 Polyquaternium-6 1.3
13 Hydrolyzed soy protein 1.0
14 EDTA-4Na 0.1
15 Ammonia water (28%) 1.1
16 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. Most of 16 were warmed to about 80 ° C. (Part A). No. in a separate container. 1 to 9 were added and heated to dissolve (Part B). No. in a separate container. No.15, no. 10-14 was added and dissolved uniformly (part C). Part B was added to part A, mixed and stirred, and part C was added at about 45 ° C. and mixed uniformly. After cooling to room temperature, no. 15 was added.
(2 liquids)
Component Blending amount (% by weight)
--------------------------------
1 Diethyl sebacate 1.5
2 YOFCO FA-NH (Nippon Seika Co., Ltd.) 0.2
3 Cetanol 5.0
4 Emacor VT-20 (manufactured by Sanei Chemical Co., Ltd.) 5.0
5 Dimethicone (200cst) 2.0
5 Trioctanoin 2.0
7 Octyldecanol 0.6
8 SETES-20 0.5
9 Diammonium phosphate 0.2
10 Sodium benzoate 0.15
11 Na bromate 8.0
12 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. 1-8 were added, it heated at about 70 degreeC, and it was made to melt | dissolve (A part). No. in a separate container. No. 12 was taken and heated to about 70 ° C. 9, 10 was added and dissolved (part B). N in a separate container
o. Take the remainder of 12 and heat to about 60 ° C. 11 was added and dissolved (part C). About 7
B part was added to A part at 0 degreeC, and it stirred until the viscosity became high. The mixture was cooled to 60 ° C., and part C was added with stirring and mixed uniformly. After the temperature dropped to about 50 ° C., it was rapidly cooled.

Example 12 Curling Agent A curling agent having the following formulation was produced. By using this curl agent 1 and 2 on the hair,
It was able to curl with good flexibility, slipperiness, moist texture, and good finish.
(1 liquid)
Component Blending amount (% by weight)
------------------------------
1 Cysteamine hydrochloride 2.0
2 DL cysteine 0.4
3 Monoethanolamine 0.9
4 Ammonia water (28%) 0.5
5 POE (20) Palm oil fatty acid sorbitan 0.5
6 Fragrance 0.1
7 Diallylammonium chloride / acrylic acid copolymer 1.0
8 Emacor VT-20 (manufactured by Sanei Chemical Co., Ltd.) 3.0
9 Ores-20 0.5
10 Ores-50 0.2
11 Diisopropyl sebacate 0.5
12 YOFCO FA-NH (Nippon Seika Co., Ltd.) 0.02
13 Lanolin fatty acid octyldodecyl 0.3
14 Sorbitan stearate 0.2
15 Edetic acid 4Na (tetrahydrate) 0.1
16 Ammonium phosphate 0.5
17 Purified water Total amount of 100 ---------------------------------
(Preparation method)
No. No. 17 in part (20%) 1 to 3 was added and dissolved, and No. 1 was previously stored in a separate container.
No. 16 in part (10%) What was melt | dissolved by adding 15 and 16 was added at about 40 degreeC, and it was made to melt | dissolve uniformly (A part). In another container, no. The remainder of 17 was heated to about 75 ° C. (Part B)
. In another container 8-14 was taken and heated to about 75 ° C. to dissolve (Part C). B in part C
After adding part and emulsifying and stirring and mixing well, it was cooled to 40 ° C. and part A was added and stirred uniformly. Next, no. No. 7 was added and stirred. Nos. 5 and 6 were added. 4 was added, and the mixture was stirred and mixed uniformly to adjust the pH to 9.0 to 9.5, thereby obtaining the target curling agent 1 solution.
(2 liquids)
Component Blending amount (% by weight)
----------------------------------
1 EDTA-2Na 0.1
2 Na bromate 4.0
3 Ammonium phosphate 0.5
4 Quaternium-33 (Nippon Seika Co., Ltd. Cationic NH) 2.0
5 Cetrimonium chloride (30%) 1.0
6 Ores-50 0.2
7 Dimethicone copolyol 0.5
8 Sodium benzoate 0.15
9 Purified water Total amount of 100 -----------------------------------
(Preparation method)
No. 4-7 were heated to about 80 ° C. and dissolved (part A). In another container Part of 9 (7
0%) and no. 1 and 8 were added and heated to about 80 ° C. to dissolve (Part B). In another container, no. No. 9 and No. 9 A few were added and heated to about 50 ° C. to dissolve (Part C). B in part A
Part is added, mixed and stirred uniformly to emulsify, and when it reaches 40 ° C., part C is added and mixed well.
The target curling agent 2 liquid was obtained by adjusting the pH to 6.5 to 6.8 at room temperature.

Example 13 Pearl Shampoo A pearl shampoo having the following formulation was prepared. This shampoo was well foamed and maintained a smooth feel from rinsing to drying.
Component Blending amount (% by weight)
----------------------------------
A
Cocoyl Methyl Taurine Na (30%) 8.0
Cocamidopropyl betaine (30%) 5.0
Lauroylmethylalanine Na 5.0
Cocamide DEA 3.0
Polyoxyethylene cetostearyl ether 1.6
Ethylene glycol distearate2.0
Diethyl sebacate 0.5
Cholesterol 0.01

B
Quotanium-33 (Nippon Seika Co., Ltd. Cationic NH) 0.4
Citric acid appropriate amount
Purified water Total amount of 100 ----------------------------------
(Preparation method)
A and B (excluding citric acid) were each heated to about 80 ° C. and dissolved. B was gradually added to A and mixed uniformly, and citric acid of B was added and stirred for 1 minute and then cooled.

Example 14 Hair Shampoo A hair shampoo having the following formulation was prepared. This shampoo was well foamed and maintained a smooth feel from rinsing to drying.
Component Blending amount (% by weight)
----------------------------------
Sodium laureth sulfate (30%) 8.0
Cocoamphoacetate Na (40%) 5.0
Lauroyl-N-methyl-β-alanine sodium 5.0
1,3-butylene glycol 3.5
Fragrance, pigment, preservative Trace amount of diisopropyl sebacate 0.5
Cholesterol 0.01
Polyquaternium-10 0.25
Purified water Total amount of 100 ----------------------------------
(Preparation method)
All ingredients were mixed uniformly.

Example 15 Hair Shampoo A hair shampoo having the following formulation was prepared. This shampoo was well foamed and maintained a smooth feel from rinsing to drying.
Component Blending amount (% by weight)
----------------------------------
Lauryl sulfate triethanolamine (40%) 10.0
Cocamidopropyl betaine (30%) 2.8
Lauramide DEA 3.0
Diethyl sebacate 0.4
YOFCO FA-NH (Nippon Seika Co., Ltd.) 0.01
Citric acid 0.1
Blue No.1 trace fragrance 0.5
Purified water Total amount of 100 ----------------------------------
(Preparation method)
All ingredients were mixed uniformly.

Example 16 Hair Shampoo A hair shampoo having the following formulation was prepared. This shampoo was well foamed and maintained a smooth feel from rinsing to drying.
Component Blending amount (% by weight)
----------------------------------
N-lauroyl-N-methylalanine sodium 7.0
N-lauroylmethyl taurine sodium 3.5
Lauryldimethylaminoacetic acid betaine 5.0
Cocamidopropyl betaine (30%) 2.3
Diethyl sebacate 0.4
Phytosterol 0.01
Yellow No.4 trace fragrance 0.4
Purified water Total amount of 100 ----------------------------------
(Preparation method)
All ingredients were mixed uniformly.

Example 17 Hair Rinse A hair rinse having the following formulation was prepared. This rinsing imparted a moist feeling and gloss to the hair, and was able to impart smooth fingering.
Component Blending amount (% by weight)
----------------------------------
A
Cetrimonium chloride (30%) 5.2
Steartrimonium chloride (63%) 0.6
Cetanol 2.8
Octyldodecanol 4.7
Squalane 0.3
Diisopropyl sebacate 2.0
Ceramide 3 0.01
Ores-5 0.1
Setes-20 0.1
Myristyl sulfate Na 0.2
Cetyl sulfate Na 0.1
B
Citric acid 0.1
Purified water Total amount of 100 ----------------------------------
(Preparation method)
A and B (excluding citric acid) were each dissolved by heating to about 80 ° C. Part B was gradually added to part A and mixed uniformly, citric acid was added, and the mixture was stirred for 1 minute and then cooled.

Example 18 Hair Rinse A hair rinse having the following formulation was prepared. This rinsing imparted a moist feeling and gloss to the hair, and was able to impart smooth fingering.
Component Blending amount (% by weight)
----------------------------------
A
Behentrimonium chloride (80%) 2.0
Cetanol 3.0
Cyclomethicone 4.5
Diisopropyl sebacate 0.5
Cholesterol 0.03
Glyceryl stearate (SE) 1.0
B
Propylene glycol 3.0
Preservatives, pigments Trace fragrance 0.3
Purified water Total amount of 100 ----------------------------------
(Preparation method)
A and B (excluding fragrance) were mixed and dissolved at 75 ° C. After mixing part A and part B, after cooling,
A fragrance was added to produce.

Example 19 Leave-on treatment A leave-on treatment (for hair) having the following formulation was prepared. This leave-on treatment was able to give a soft and slippery feel to the hair with a light touch. Moreover, stability was also favorable.
Component Blending amount (% by weight)
--------------------------------
1 Diethyl sebacate 1.0
2 Cholesterol 0.1
3 Myristyl alcohol 5.0
4 Behenyl alcohol 1.0
5 Oleyl alcohol 1.0
6 Dimethylpropylamide stearate 2.0
7 Cocoamphoacetate Na (30%) 2.0
8 Glyceryl stearate 0.4
9 Myristic acid 0.6
10 Phenoxyethanol 0.4
11 Lactic acid 0.6
12 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. 1 to 10 were heated to about 80 ° C. and dissolved (part A). In another container 11, 12
And heated to about 80 ° C. to dissolve (Part B). Part B was gradually added to part A and mixed uniformly.

Example 20 Leave-on treatment A leave-on treatment (for hair) having the following formulation was prepared. This leave-on treatment was able to give a soft and slippery feel to the hair with a light touch. Moreover, stability was also favorable.
Component Blending amount (% by weight)
--------------------------------
1 Diisopropyl sebacate 4.0
2 YOFCO FA-NH (Nippon Seika Co., Ltd.) 0.4
3 Plandool-H (Nippon Seika Co., Ltd.) 0.5
4 Cetanol 5.0
5 Steartrimonium chloride (63%) 3.2
6 Behentrimonium chloride (80%) 1.0
7 Squalane 1.0
8 Glycerin 1.0
9 Methylparaben 0.1
10 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. 1 to 8 were heated to about 80 ° C. and dissolved (part A). In another container 9, 10 was taken and dissolved by heating to about 80 ° C. (Part B). Part B was gradually added to part A and mixed uniformly.

Example 21 Hair Essence A hair essence having the following formulation was prepared. This hair essence was refreshing and non-sticky and could give the hair a soft and slippery feel.
Component Blending amount (% by weight)
--------------------------------
1 Diisopropyl sebacate 1.0
2 Cholesterol 0.1
3 Plandool-H (Nippon Seika Co., Ltd.) 0.5
4 Cetanol 1.0
5 Steartrimonium chloride (63%) 0.8
6 Dicocodimonium chloride (75%) 2.8
7 Solves-60 tetraoleate 1.0
8 PEG-40 hydrogenated castor oil 0.2
9 Methylparaben 0.1
10 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. 1 to 8 were heated to about 80 ° C. and dissolved (part A). In another container 9, 10 was taken and dissolved by heating to about 80 ° C. (Part B). Part B was gradually added to part A and mixed uniformly.

Example 22 Hair Foam A hair foam having the following formulation was prepared. This hair foam had a good feeling of use and setability that were smooth.
Component Blending amount (% by weight)
----------------------------------
(Stock solution formulation)
1 Acrylic resin alkanolamine solution (50%) 7.0
2 Yuka Former AM75W (Mitsubishi Chemical Corporation) 1.0
3 Appropriate amount of polyoxyethylene hydrogenated castor oil
4 Dimethicone 2.0
5 Diisopropyl sebacate 3.0
6 YOFCO FA-NH (Nippon Seika Co., Ltd.) 0.2
7 LUSPLAN PI-DA (Nippon Seika Co., Ltd.) 2.0
8 Glycerin 3.0
9 Ethanol 15.0
10 Preservative appropriate amount
11 Purified water Total amount of 100 ----------------------------------
(Filling prescription)
Stock solution 90.0
Petroleum liquefied gas 10.0
----------------------------------
(Preparation method)
No. Nos. 1, 3 to 10 were mixed evenly. 2 and 11 were added and mixed uniformly.
After filling this stock solution into a can, it was filled with gas.

Example 23 Moose A mousse having the following formulation was prepared. This mousse had a smooth feel and a light styling.
Component Blending amount (% by weight)
----------------------------------
(Stock solution formulation)
1 Diethyl sebacate 2.0
2 Cholesterol 0.1
2 Ethanol 5.0
3 Ores-20 1.0
4 Acrylic resin alkanolamine solution 2.0
5 Yuka Former AM75W (Mitsubishi Chemical Corporation) 1.0
6 Diethylaminoethylamide stearate 0.5
7 Pyrrolidone carboxylic acid 0.2
8 POE, POP-modified silicone 1.0
9 Preservatives and perfumes
10 Purified water Total amount of 100 ----------------------------------
(Production method)
Stir and mix each component uniformly.
The above-mentioned stock solution: petroleum liquefied gas was mixed at a ratio of 92: 8 to obtain an injection type mousse.

Example 24 Hair Cream A hair cream having the following formulation was prepared. This hair cream had setability, was not sticky, and was able to impart a good feel and smooth fingering as if it were slippery.
Component Blending amount (% by weight)
----------------------------------
A
Stearic acid 2.0
Lanolin 3.5
Paraffin wax 2.0
Liquid paraffin 28.0
Dimethicone 0.2
Glyceryl stearate (SE) 1.0
Sorbitan monostearate1.0
Polyoxyethylene cetyl ether 1.5
Diethyl sebacate 10.0
YOFCO FA-NH (Nippon Seika Co., Ltd.) 0.2
YOFCO MAS (Nippon Seika Co., Ltd.) 0.05
Preservative appropriate amount B
Triethanolamine 1.0
1,3-butylene glycol 3.0
Purified water Amount C totaling 100
Perfume proper amount ----------------------------------
(Production method)
A and B were each dissolved at about 80 ° C., then uniformly mixed and cooled (50 ° C.), C was added and mixed uniformly.

Example 25 Smooth mist A smooth mist having the following formulation was prepared. This smooth mist was non-sticky, had a light setting property, and was able to give a smooth feel to the hair and a smooth finger passage.
Component Blending amount (% by weight)
----------------------------------
Diethyl sebacate 1.0
Cholesterol 0.1
Dimethicone 0.4
Cetrimonium chloride (30%) 4.0
Ethanol 8.0
Purified water Total amount of 100 ----------------------------------
(Production method)
Each component was stirred and mixed uniformly.

Example 26 Hair wax A hair wax having the following formulation was prepared. This hair wax had good adhesion to hair, excellent setability and a feeling of hair bundle, was not sticky, and could give a glossy and good feel.
Component Blending amount (% by weight)
----------------------------------
1 LUSPLAN DD-DA5 (Nippon Seika Co., Ltd.) 3.6
2 Hydrogenated ester gum 0.4
3 Emmacol HW-4619 (Sanei Chemical Co., Ltd.) 5.0
4 Diisopropyl sebacate 4.0
5 YOFCO FA-NH (Nippon Seika Co., Ltd.) 0.2
6 Stearyl alcohol 4.0
7 12-Hydroxystearic acid 3.0
8 Dimethicone (50cs) 2.0
9 Squalane 1.0
10 Phenyldimethicone 0.5
11 Tocopherol 0.05
12 Hydroxide Na 0.3
13 Methylparaben 0.2
14 Purified water Total amount of 100 ----------------------------------
(Production method)
No. 1 to 11 are heated to about 80 ° C. and dissolved (part A). In another container 12-14
Is heated to about 80 ° C. and dissolved uniformly (Part B). Part B was gradually added to part A and mixed uniformly.

Example 27 Hair Tonic A hair tonic having the following formulation was prepared. This hair tonic was not sticky, prevented dandruff and itching, gave the hair a good feel and replenished nutrition.
Component Blending amount (% by weight)
----------------------------------
A
Diethyl sebacate 2.0
YOFCO FA-NH (Nippon Seika Co., Ltd.) 0.1
Menthol 0.05
Isopropyl methylphenol 0.1
Ethanol 60.0

B
1,3-butylene glycol 1.0
Pyridoxine hydrochloride 0.1
Purified water Total amount of 100 ----------------------------------
(Production method)
Both A and B were dissolved and made uniform at room temperature, and then B was added to A with stirring to make it uniform.

Example 28 Hair restorer A hair restorer having the following formulation was prepared. This hair restorer was able to prevent hair loss, dandruff and itching, and to replenish nutrients.
Component Blending amount (% by weight)
----------------------------------
Diisopropyl sebacate 0.5
Cholesterol 0.05
Menthol 0.1
Pepper tincture 0.5
Assembly extract 2.0
Ethanol 30.0
Preservative Appropriate amount of perfume Appropriate amount PPG-6 Decyltetradeces-30 0.3
Purified water Total amount of 100 ----------------------------------
(Production method)
Stir and mix each component uniformly.

According to the present invention, it is possible to obtain a hair cosmetic that can efficiently supply sterols, ceramides, anteiso branched fatty acids, and the like into the hair to repair hair damage.

Claims (4)

(A) Shampoo, rinse, treatment, leave-on-to-rement containing a diester of a straight or branched saturated dicarboxylic acid having 6 to 10 carbon atoms and a lower alcohol having 1 to 4 carbon atoms and (B) sterols , Hair essence, hair pack, hair oil, hair foam, hair mousse, hair spray, hair mist, hair wax, hair gel, water grease, set lotion, hair liquid, pomade, tic, hair cream, hair blow, split hair coat, hair color pretreatment, A hair cosmetic selected from hair color after treatment, perm pre-treatment, and perm after treatment, wherein the sterols are selected from cholesterol and phytosterols The hair cosmetic composition according to claim 1, wherein the component (A) is diethyl sebacate or / and diisopropyl sebacate. The hair cosmetic composition according to claim 1 or 2, wherein the component (B) is cholesterol. The hair cosmetic composition according to any one of claims 1 to 3, which is used for repairing hair damage.