JP2006131585A - Hair cosmetic - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To obtain a hair cosmetic that restores hair damage. <P>SOLUTION: The hair cosmetic comprises (A) a 6-10C dicarboxylic acid diester and (B) one or more kinds of sterol esters having ≤1,500 molecular weight. Especially the diester of the component (A) is diethyl sebacate and/or diisopropyl sebacate and the component (B) is a sterol ester composed of one or more kinds of carboxylic acids selected from a 1-30C carboxylic acid, dimer acid and trimer acid and an alcohol containing at least one kind of a sterol. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

  The present invention can efficiently repair hair damage containing (A) a dicarboxylic acid diester having 6 to 10 carbon atoms and (B) one or more sterol esters having a molecular weight of 1500 or less. It relates to hair cosmetics.

Although sterols exist in hair, it is known that these lipids are lost from hair by being damaged by chemical treatment such as permanent wave treatment or hair dyeing treatment. For the purpose of repairing these hair damages, it is considered effective to use sterols, sterol esters and the like. In Japanese Patent Laid-Open No. 2003-267840, N
-It has been proposed that stearoyl phytosphingosine, cholesterol, vegetable squalane and phytosteryl isostearate are included to solve the above problems. However, the inclusion of N-stearoylphytosphingosine, cholesterol, vegetable squalane and phytosteryl isostearate proposed in these publications has not been sufficient.
JP 2003-267840 A

  An object of the present invention is to provide a hair cosmetic capable of repairing hair damage.

As a result of intensive studies to solve the above problems, the present inventors have found that the above problems can be solved by combining a diester of a dicarboxylic acid having 6 to 10 carbon atoms and a sterol ester, thereby completing the present invention. It was. That is, the present invention provides a hair cosmetic containing (A) a dicarboxylic acid diester having 6 to 10 carbon atoms and (B) one or more sterol esters having a molecular weight of 1500 or less.

  By combining a diester of a dicarboxylic acid having 6 to 10 carbon atoms and a sterol ester having a molecular weight of 1500 or less, a hair cosmetic having a hair damage repair effect can be obtained.

The diester of a C6-C10 dicarboxylic acid used in the present invention is a low-viscosity ester oil that can be produced by esterifying a C6-C10 dicarboxylic acid and an alcohol according to a conventional method. Examples of the dicarboxylic acid having 6 to 10 carbon atoms constituting the ester include adipic acid (hexanedioic acid), pimelic acid (heptanedioic acid), which are linear saturated dicarboxylic acids,
Suberic acid (octanedioic acid), azelaic acid (nonanedioic acid), sebacic acid (decanedioic acid)
Branched chain saturated dicarboxylic acids such as 3-methylpentanedioic acid, 2,4-diethylpentanedioic acid, etc .; 1,4-, 1,3-, or 1,2 saturated saturated dicarboxylic acids containing a ring structure −
Cyclohexanedicarboxylic acid, etc .; aromatic dicarboxylic acids such as terephthalic acid, isophthalic acid, phthalic acid, etc. are mentioned. From the viewpoint of touch, safety, availability, and hair damage repair effect when used as a diester, Branched saturated dicarboxylic acids are preferred. Among these, sebacic acid and adipic acid are particularly preferable, and sebacic acid is most preferable. Examples of the alcohol constituting the ester include methanol, ethanol, propanol, butanol, hexanol, octanol, decanol, dodecanol; isopropyl alcohol,
Isobutyl alcohol, 2-butanol, isopentyl alcohol, 2-ethyl hexanol, 2-butyl octanol; saturated monohydric alcohols including linear, branched, or ring structures such as cyclohexane methanol are preferred as diesters. In view of the feel, safety, availability, and hair damage repairing effect, straight or branched lower alcohols having 1 to 4 carbon atoms are more preferable, and ethanol and isopropyl alcohol are particularly preferable. Particularly preferred esters as diesters of 6 to 10 carbon dicarboxylic acids used in the present invention include diethyl sebacate, diisopropyl sebacate, diisopropyl adipate, and the like, with diethyl sebacate and diisopropyl sebacate being most preferred. These can be produced by esterification according to a conventional method, but are also commercially available.

  The sterol ester having a molecular weight of 1500 or less used in the present invention is a sterol ester composed of a carboxylic acid and an alcohol containing at least one sterol. As the carboxylic acid constituting the sterol ester, monovalent, divalent, or trivalent carboxylic acid can be used, and it may have a hydroxyl group as a substituent. Preferred carboxylic acids in the present invention are C 1-30 carboxylic acids, dimer acids, and trimer acids. Examples of these include monovalent carboxylic acids (monocarboxylic acids) such as acetic acid, propionic acid, butanoic acid, pentanoic acid, hexanoic acid, heptanoic acid, octanoic acid, nonanoic acid, decane, which are monovalent linear saturated carboxylic acids. Acid, undecanoic acid, lauric acid (dodecanoic acid), tridecanoic acid, myristic acid (tetradecanoic acid), pentadecanoic acid, palmitic acid (hexadecanoic acid), stearic acid (octadecanoic acid), arachic acid (icosanoic acid), behenic acid (docosan) Acid); monovalent linear unsaturated carboxylic acid undecylenic acid, palmitooleic acid, oleic acid, linoleic acid, linolenic acid, eicosapentaenoic acid, docosahexaenoic acid; monovalent branched saturated carboxylic acid isobutanoic acid, neopentanoic acid , Isohexanoic acid, isoheptanoic acid, 2-ethylhexanoic acid, iso Long obtained by fractionating anoic acid, isodecanoic acid, neodecanoic acid, 2-butyloctanoic acid, isomyristic acid, 2-hexyldecanoic acid, methyl branched isostearic acid, 2-heptylundecanoic acid, 2-octyldodecanoic acid, lanolin fatty acid Chain branched fatty acid; mono-branched unsaturated carboxylic acid methyl-branched isooleic acid; monovalent aromatic carboxylic acid benzoic acid: monovalent hydroxycarboxylic acid glycolic acid, lactic acid, 2-hydroxybutanoic acid Long-chain α-hydroxy fatty acid obtained by fractionating hydroxyoctanoic acid, 2-hydroxypalmitic acid, 12-hydroxystearic acid, ricinoleic acid, lanolin fatty acid; macadamia nut oil fatty acid, soybean oil fatty acid that is a monovalent carboxylic acid derived from natural products Rapeseed oil fatty acid, sunflower oil fatty acid, olive Animal fatty acids such as oil fatty acid, coconut oil fatty acid, hydrogenated coconut oil fatty acid, castor oil fatty acid, hydrogenated castor oil fatty acid, lanolin fatty acid; amino acids glycine, alanine, sarcosine, valine, leucine, isoleucine, serine, threonine, Examples include cysteine, cystine, methionine, lysine, arginine, phenylalanine, tyrosine, histidine, tryptophan, proline, oxyproline, and N-acylamino acid derivatives such as N-lauroyl derivatives thereof. Divalent carboxylic acids (dicarboxylic acids) include succinic acid (butanedioic acid), glutaric acid (pentanedioic acid), adipic acid (hexanedioic acid), 3-methylpentanedioic acid, pimelic acid (heptanedioic acid), Suberic acid (octanedioic acid), 1,4-cyclohexanedicarboxylic acid, 1,3-cyclohexanedicarboxylic acid, 1,2-cyclohexanedicarboxylic acid, terephthalic acid, isophthalic acid, phthalic acid, azelaic acid (nonanedioic acid), 2 , 4-Diethylpentanedioic acid, sebacic acid (decanedioic acid), dodecanedioic acid, tridecanedioic acid, hexadecanedioic acid, octadecanedioic acid, icosanedioic acid, isodocosanedioic acid, dimer acid, hydrogenated dimer acid, malic acid And tartaric acid. Examples of the trivalent carboxylic acid (tricarboxylic acid) include trimer acid, citric acid, trimellitic acid, aspartic acid, and glutamic acid, which are by-products of dimer acid. These carboxylic acids may be a mixture of two or more, but from the viewpoint of touch, availability, hair damage repair effect, etc., acetic acid, butanoic acid, nonanoic acid, 2-ethylhexanoic acid, stearic acid, isostearic acid Oleic acid, lanolin fatty acid, hard lanolin fatty acid, soft lanolin fatty acid, long chain branched fatty acid, long chain α-hydroxy fatty acid, macadamia nut fatty acid, 12-hydroxystearic acid, dimer acid, trimer acid, N-lauroyl-L-glutamic acid, etc. Is preferred.

The above-mentioned dimer acid is a known dibasic acid obtained by an intermolecular polymerization reaction of unsaturated fatty acids, and its industrial production process is almost standardized in the industry. For example, dimer acid and / or its lower alcohol ester is It is obtained by dimerizing an unsaturated fatty acid having 11 to 22 carbon atoms or a lower alcohol ester thereof with a clay catalyst or the like. The dimer acid obtained industrially is mainly composed of a dibasic acid having about 36 carbon atoms, but contains an arbitrary amount of trimer acid and monomer acid depending on the degree of purification. In general, dimer acid content exceeding 70% by weight and dimer acid content increased to 90% or more by molecular distillation are in circulation. In addition, although a double bond remains after the dimerization reaction, a dimer acid that is further hydrogenated to improve oxidation stability, that is, a hydrogenated dimer acid is also on the market. Any dimer acid currently in circulation can be used in the present invention, but hydrogenated dimer acid is more preferable from the viewpoint of oxidation stability. In addition, those derived from animal fats and oils and vegetable oils are distributed among these dimer acids, but those derived from vegetable oils and fats are more preferable. As such dimer acid, for example, PRIPOL 1006, 1009, 1015, 1025, etc. of Unikema are commercially available. The trimer acid used in the present invention is preferably obtained as a byproduct of the production of the dimer acid described above and hydrogenated from the viewpoint of stability.

On the other hand, as the alcohol constituting the sterol ester used in the present invention, it is essential to contain at least one kind of sterol.
Preferred examples include dihydrocholesterol, lanosterol, dihydrolanosterol; β-sitosterol, campesterol, stigmasterol, brassicasterol, and phytosterols (plant sterols) that are a mixture thereof, particularly cholesterol and at least β-sitosterol. The phytosterol (plant sterol) to contain is preferable. The alcohol constituting the sterol ester may contain an alcohol other than the monovalent or divalent sterols in addition to the sterols. As alcohols other than sterols, monohydric alcohols such as lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, aralkyl alcohol, behenyl alcohol, 2-ethylhexyl alcohol, 2-hexyldecanol, methyl branched isostearyl alcohol, 2-heptyl alcohol Undecanol, 2-octyldodecanol; dimer diol which is a dihydric alcohol, 1,10-decanediol, and the like. The sterol ester used in the present invention is an ester composed of the above-mentioned carboxylic acid and alcohol, and can be obtained by esterification reaction of the corresponding carboxylic acid and alcohol, or extraction from natural fats and oils. Examples of particularly preferred specific examples of the sterol ester having a molecular weight of 1500 or less used in the present invention include macadamia nut oil fatty acid cholesteryl (YOFCO MAC / manufactured by Nippon Seika Co., Ltd.), macadamia nut oil fatty acid phytosteryl (YOFCO MAS / manufactured by Nippon Seika Co., Ltd.). Cholesteryl isostearate, phytosteryl isostearate, cholesteryl oleate, phytosteryl oleate, cholesteryl 12-hydroxystearate, phytosteryl 12-hydroxystearate, long-chain branched fatty acid cholesteryl (YOFCO CLE-NH / manufactured by Nippon Seika Co., Ltd.), long Chain α-hydroxy fatty acid cholesteryl, soft lanolin fatty acid cholesteryl (YOFCO CLE-S / manufactured by Nippon Seika Co., Ltd.), hard lanolin fatty acid cholesteryl (YOFCO CLE- H / Nippon Seika Co., Ltd.), cholesteryl acetate, cholesteryl butanoate, cholesteryl nonanoate, cholesteryl 2-ethylhexanoate, phytosteryl 2-ethylhexanoate, cholesteryl stearate, phytosteryl stearate, dimerinolinoleic acid di (isostearyl) / Phytosteryl) (LUSPLAN PI-DA / manufactured by Nippon Seika Co., Ltd.), dimer linoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl) (Plandool-H, Plandool-S / manufactured by Nippon Seika Co., Ltd.), dimer Linoleic acid (phytosteryl / behenyl) (Plandool-PB / Nippon Seika Co., Ltd.), N-lauroyl-L-glutamate di (cholesteryl / behenyl / octyldodecyl) (Eldu CL-301 / Ajinomoto Co.), N- Uroyl-L-glutamate di (cholesteryl / octyldodecyl) (Eldu CL-202 / Ajinomoto Co.), N-lauroyl-L-glutamate di (phytosteryl / behenyl / octyldodecyl) (Erdu PS-304 / Ajinomoto Co.) N-lauroyl-L-glutamate di (phytosteryl / octyldodecyl) (Eldu PS-203 / manufactured by Ajinomoto Co., Inc.) and the like.

The hair cosmetics in the present invention include oil shampoo, cream shampoo, conditioning shampoo, dandruff shampoo, hair color shampoo, rinse-in shampoo, etc .; rinse, treatment, leave-on treatment, hair essence, hair pack, hair oil, hair Foam, hair mousse, hair spray, hair mist, hair wax, hair gel, water grease, set lotion, color lotion, hair liquid, pomade, tic, hair cream, hair blow, split hair coat, hair oil, permanent wave agent, oxidative hair dye , Hair bleach, hair color pre-treatment, hair color after-treatment, perm pre-treatment, perm after-treatment, hair mani Interview A, it can be exemplified hair tonic or the like. 6 to 1 carbon
The blending amount of the diester of 0 dicarboxylic acid into the hair cosmetic is generally 0.01 to 99.99.
99% by weight, preferably 0.1 to 50% by weight, more preferably 0.5 to 20% by weight, and the amount of sterols, ceramides, and anteiso branched fatty acids to be added to the hair cosmetic is generally Is 0.001 to 50% by weight, preferably 0.05 to 20% by weight, more preferably 0.1 to 10% by weight. The compounding ratio of the component (A) and the component (B) is (A) of the component (B)
) (B) :( A) = 1: 1 from the solubility with respect to a component and the favorable hair damage repair effect.
˜1: 1000 (weight ratio) is preferable, and (B) :( A) = 1: 10 to 1: 100 (weight ratio) is particularly preferable. If the blending amount is within this range, hair damage can be repaired efficiently.

In addition to the above, the hair cosmetics of the present invention, other than those mentioned above, are usually added to the hair cosmetics, such as oils, surfactants, moisturizers, thickeners / gels, and the like. Agent,
Antioxidants, preservatives, bactericides, chelating agents, pH adjusters / acids / alkalis, solvents, reducing agents /
Oxidizing agents, ultraviolet absorbers, anti-inflammatory agents, refreshing agents, antihistamines, astringents, stimulants, hair-restoring agents, vitamins and derivatives thereof, hydroxy acids, enzymes, nucleic acids, hormones, sugars and derivatives thereof, Inorganic powders, polymer powders, fragrances, pigments and the like can be blended.

Examples of these additives include oils and fats, hydrocarbon oils such as liquid paraffin, squalane, hydrogenated polyisobutene; palm oil, palm oil, palm kernel oil, safflower oil, olive oil, castor oil, avocado oil, sesame oil , Tea oil, evening primrose oil, wheat germ oil, macadamia nut oil, hazelnut oil, kukui nut oil, rosehip oil, meadow foam oil, persic oil, tea tree oil, peppermint oil, corn oil, rapeseed oil, sunflower oil, wheat germ oil, Vegetable oils such as linseed oil, cottonseed oil, soybean oil, peanut oil, rice bran oil, cacao butter, shea butter, hydrogenated palm oil, hydrogenated castor oil, jojoba oil, hydrogenated jojoba oil; beef fat, milk fat, horse fat, Animal fats and oils such as egg yolk oil, mink oil, turtle oil, whale wax, lanolin, orange luffy oil; liquid lanolin, reduced ras Lanolins such as phosphorus, adsorption purified lanolin, lanolin acetate, liquid lanolin acetate, hydroxy lanolin, polyoxyethylene lanolin, lanolin fatty acid, hard lanolin fatty acid, lanolin alcohol, lanolin alcohol acetate, acetic acid (cetyl lanolyl) ester; cetyl octanoate , Octyl palmitate, octyl dodecyl myristate, hexyl decyl myristate, oleyl oleate, octyl dodecyl oleate, lanolin fatty acid octyl dodecyl, hexyl decyl octanoate, isononyl isononanoate, isotridecyl isononanoate, isosteyl neopentanoate, isodecyl neopentanoate , Octyldodecyl neodecanoate, ethyl oleate, ethyl avocado oil fatty acid, isopropyl palmitate, isopropyl myristate , Fatty acid esters such as isopropyl isostearate, lanolin fatty acid isopropyl and dioctyl succinate; oxyacid esters such as cetyl lactate and diisostearyl malate; glyceryl trioctanoate, glyceryl trioleate, glyceryl triisostearate, tri (capryl) Capric acid) glyceryl, hydrogenated rosin glyceryl (hydrogenated ester gum), pentaocteric ester tetraoctanoate, hydrogenated rosin pentaerythrityl, propylene glycol dioleate, neopentyl glycol dioctanoate, 2-butyl-2-dioctanoate Ethyl-1,3-propanediol, (hydroxystearic acid / stearic acid / rosinic acid) dipentaerythrityl, diglyceryl diisostearate, polytetraisostearate Polyhydric alcohol fatty acid esters such as glyceryl; dimer dilinoleate dimer dilinoleyl, dimer dilinoleate diisostearyl, dimer dilinoleate diisopropyl, diisostearate dimer dilinoleyl, dimer dilinoleyl hydrogenated rosin condensate, Dimer acid hydrogenated castor oil, hydroxyalkyl dimer dilinoleyl ether, dimer acid, hydrogenated dimer acid, dimer diol and other dimer acid diol derivatives; N-lauroyl-L-glutamate di (cholesteryl / behenyl / octyldodecyl) ), N-lauroyl-L-glutamate di (cholesteryl / octyldodecyl),
N-lauroyl-L-glutamate di (phytosteryl / behenyl / octyldodecyl)
Amino acid esters such as N-lauroyl-L-glutamic acid di (phytosteryl / octyldodecyl); petroleum jelly, solid paraffin, candelilla wax, carnauba wax, rice wax, waxy wax, beeswax, montan wax, ozokerite, ceresin,
Waxes such as paraffin wax, microcrystalline wax, petrolatum, Fischer-Tropsch wax, polyethylene wax, ethylene / propylene copolymer; phospholipids such as phosphatidylcholine, phosphatidylethanolamine, phosphatidylinositol, sphingomyelin, phosphatidic acid, lysolecithin; hydrogenation Phospholipid derivatives such as soybean phospholipid and hydrogenated egg yolk phospholipid; perfluoropolyether; as higher alcohols, myristyl alcohol, cetanol, stearyl alcohol, cetostearyl alcohol, aralkyl alcohol, behenyl alcohol, oleyl alcohol, isostearyl alcohol , Octyldodecanol, hexyl decanol, jojoba alcohol, chimil al Alcohol derivatives such as lauric acid, batyl alcohol; lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, behenic acid, undecylenic acid, 12-hydroxystearic acid, palmitooleic acid, oleic acid, linoleic acid, linolenic acid Higher fatty acids such as erucic acid, docosahexaenoic acid, eicosapentaenoic acid, isohexadecanoic acid, anteisohenicosanoic acid and salts thereof; coconut oil fatty acid monoethanolamide, coconut oil fatty acid diethanolamide, lauric acid monoethanolamide,
Fatty acid alkanolamides such as lauric acid diethanolamide, palmitic acid monoethanolamide, palmitic acid diethanolamide, low viscosity dimethylpolysiloxane, high viscosity dimethylpolysiloxane, cyclic dimethylsiloxane (decamethylcyclopentasiloxane), methylphenylpolysiloxane, Diphenyl polysiloxane, silicone resin, silicone rubber, amino-modified polysiloxane, cation-modified polysiloxane, polyether-modified polysiloxane, polyglycerin-modified polysiloxane, sugar-modified polysiloxane, alkyl-modified polysiloxane, fatty acid-modified polysiloxane, fluorine-modified polysiloxane Silicones such as siloxane can be exemplified.

Surfactants include fatty acid salts, alkyl sulfate esters, alkyl benzene sulfonates, polyoxyethylene alkyl sulfates, polyoxyethylene fatty amine sulfates, acyl N-methyl taurates, alkyl ether phosphates, alkyl ethers. Anionic surfactants such as sulfonates and N-acyl amino acid salts; polyoxyethylene alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene alkyl ether sorbitan fatty acid partial ester, polyoxyethylene hydrogenated castor oil, polyvalent Nonionic surfactants such as alcohol fatty acid partial esters, polyglycerin fatty acid esters, polyoxyethylene fatty acid esters, alkyldimethylamine oxides, alkyl polyglycosides, alkyl glucosides; Cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, stearyltrimethylammonium bromide, behenyltrimethylammonium chloride, distearyldimethylammonium chloride, dicocoyldimethylammonium chloride, dicetyldimethylammonium chloride, ethyl lanolin sulfate fatty acid amidopropylethyldimethylammonium Long-chain branched fatty acid amidopropyl ethyl dimethyl ammonium, stearic acid amidopropyl dimethylamine, stearic acid amidoethyl diethylamine, lanolin fatty acid amidopropyl dimethylamine, long chain branched fatty acid amidopropyl dimethylamine etc. fatty acid amidoamine salt, short chain polyoxyethylene alkyl Such as amines and their salts or quaternary salts, benzalkonium chloride Amphoteric surfactants such as alkyldimethylaminoacetic acid betaine, alkylamidodimethylaminoacetic acid betaine, 2-alkyl-N-carboxy-N-hydroxyimidazolinium betaine; polyvinyl alcohol, sodium alginate, starch derivatives, Examples thereof include polymer surfactants such as tragacanth gum and acrylic acid / alkyl methacrylate copolymers;

Examples of humectants include propylene glycol, glycerin, 1,3-butanediol, 3-
Polyhydric alcohols such as methyl-1,3-butanediol, sodium hyaluronate, citrate, urea, lactic acid bacteria culture solution, yeast extract, eggshell membrane protein, submandibular gland mucin, hypotaurine, sesameignan glycoside, Betaine, chondroitin sulfate, glutathione, polyethylene glycol, sorbitol, carbitol, sodium lactate, sodium 2-pyrrolidone-5-carboxylate, albumin, trimethylglycine; collagen, gelatin, elastin, collagen degrading peptide, elastin degrading peptide, keratin degrading peptide Protein peptides such as conchiolin degrading peptide, silk proteolytic peptide, soybean proteolytic peptide, wheat proteolytic peptide, casein degrading peptide and derivatives thereof; arginine, serine, glycine, threonine, Amino acids such as glutamic acid, cysteine, methionine, leucine, and tryptophan; animal and plant extract components such as placenta extract, aerustin, collagen, aloe extract, hamamelis water, loofah water, chamomile extract, licorice extract, and comfrey extract It can be illustrated.

As a thickener and gelling agent, guar gum, quince seed gum, xanthan gum, carrageenan, alginic acid, tragacanth gum, starch derivative, sodium carboxymethylcellulose, carboxyvinyl polymer, acrylic acid / methacrylic acid ester copolymer,
Acrylic acid / alkyl methacrylate copolymer, polyvinyl alcohol, polyvinylpyrrolidone, amphoteric methacrylate copolymer, cationized cellulose, nitrocellulose; 12-hydroxystearic acid and its salts, dextrin fatty acid ester, silicic anhydride, metal Examples include soaps, organically modified clay minerals, sucrose fatty acid esters, fructooligosaccharide fatty acid esters, and the like.

Examples of the antioxidant include vitamin E (tocopherol) and / or its derivative, vitamin C (ascorbic acid) and / or its derivative, BHT, BHA, propyl gallate and the like. Examples of preservatives include p-hydroxybenzoic acid esters, phenoxyethanol, 1,2-pentanediol, 1,2-hexanediol, quaternary ammonium salts and the like. Examples of the bactericides include trichlorocarbanide, zinc pyrithione, benzalkonium chloride, benzethonium chloride, chlorhexidine, halocarban, hinokitiol, phenol, isopropylphenol, and photosensitizers. Examples of chelating agents include edetate, phytic acid, phosphonic acids, polyamino acids and the like. Examples of pH adjusters / acids / alkalis include citric acid, lactic acid, glycolic acid, succinic acid, hydrochloric acid, monoethanolamine, diethanolamine, triethanolamine, arginine, sodium hydroxide, potassium hydroxide, aqueous ammonia, etc. Can do. Examples of the solvents include lower alcohols such as ethanol and 2-propanol; acetone, ethyl acetate, ethylene glycol monoethyl ether, and the like. Examples of the reducing agent include thioglycolic acid, cysteine, cysteamine and the like. Examples of the oxidizing agent include aqueous hydrogen peroxide, ammonium persulfate, and sodium bromate.

Examples of ultraviolet absorbers include benzophenone derivatives, paraaminobenzoic acid derivatives, paramethoxycinnamic acid derivatives, salicylic acid derivatives, urocanic acid, urocanic acid ethyl, 4-te
Examples thereof include rt-butyl-4′-methoxydibenzoylmethane, 2- (2′-hydroxy-5′-methylphenyl) benzotriazole, methyl anthranilate, rutin and derivatives thereof. Examples of the anti-inflammatory agent include glycyrrhizic acid and its derivatives, guaiazulene, hydrocortisone acetate, prednisone, salicylic acid derivatives and the like. Examples of the refreshing agent include menthol and methyl salicylate. Examples of the antihistamine include diphedramine hydrochloride, chlorpheniramine maleate, glycyrrhetinic acid derivatives and the like. Examples of the astringent include citric acid, tartaric acid, lactic acid, aluminum sulfate / potassium sulfate, and tannic acid. Examples of the stimulant include cantalis tincture, ginger tincture, chili pepper tincture, benzyl nicotinate and the like. Hair growth medicines include assembly extract, cephalanthin, vitamin E
And derivatives thereof, γ-oryzanol, capsicum tincture, ginger tincture, cantharis tincture, nicotinic acid benzyl ester, allantoin, photosensitive element 301, photosensitive element 401, and the like.

Vitamins and their derivatives include vitamin A, vitamin B group, vitamin D, vitamin E, pantothenic acid, biotin and the like; ascorbyl stearate, ascorbyl palmitate, ascorbyl dipalmitate, ascorbyl magnesium phosphate, ascorbine Examples thereof include vitamin derivatives such as sodium acid, tocopherol nicotinate, tocopherol acetate, tocopherol linoleate, and tocopherol ferulate. α-hydroxy acids and derivatives thereof include lactic acid, glycolic acid, fruit acid,
Examples thereof include hydroxycapric acid, long chain α-hydroxy fatty acid, long chain α-hydroxy fatty acid cholesteryl and the like. Examples of enzymes include lysozyme chloride, papain, pancreatin, protease, and the like. Examples of nucleic acids include adenosine triphosphate disodium. Examples of hormones include estradiol, estrone, ethinyl estradiol, cortisone, hydrocortisone, prednisone and the like. Sugars and derivatives thereof include cyclodextrin, β-glucan, chitin, chitosan, glucose, trehalose, pectin, arabinogalactan,
Examples include dextrin, dextran, glucosylethyl methacrylate polymer or copolymer.

Inorganic powders include mica, talc, kaolin, montmorillonite, sericite, kaolinite, calcium carbonate, bengara, yellow iron oxide, black iron oxide, ultramarine, bitumen, carbon black, titanium dioxide, zinc oxide, alumina, silica. Examples include fumed silica, mica titanium, fish scale foil, boron nitride, photochromic pigment, synthetic fluorine phlogopite, fine particle composite powder, gold, aluminum, etc. can do. As polymer powder, starch, nylon powder, polyethylene powder, polymethyl methacrylate, polyethylene terephthalate / polymethyl methacrylate laminated powder, etc., and
These assertion-treated powders can be exemplified.

Examples of the fragrance include limonene, linanol, citral, β-ionone, benzyl benzoate, indole, eugenol, auranthiol, geraniol, rilal, damascon, benzyl acetate, jasmine lactone, galac solid, essential oil and the like. As pigments, natural pigments such as β-carotene, calsamine, rutin, cochineal, chlorophyll; legal pigments, basic dyes, lakes, organic pigments; p-phenylenediamine,
Examples include toluene-2,5-diamine, m-phenylenediamine, o-, m-, or oxidative dye intermediates such as p-aminophenol and resorcin.

In addition, other components used in known cosmetics, pharmaceuticals, foods and the like can be appropriately blended as long as the effects of the present invention are not impaired.

As the dosage form of the hair cosmetic of the present invention, an oil-in-water (O / W) type, a water-in-oil (W / O) type, W /
O / W type, O / W / O type emulsified cosmetics, oily cosmetics, solid cosmetics, liquid cosmetics, kneaded cosmetics, stick cosmetics, volatile oil cosmetics, powder cosmetics , Jelly cosmetics, gel cosmetics, paste cosmetics, emulsified polymer cosmetics, sheet cosmetics, mist cosmetics, spray cosmetics and the like. The cosmetic of the present invention can be produced according to a usual method.

EXAMPLES Hereinafter, although this invention is demonstrated in detail using an Example, this invention is not limited to these Examples.

Examples 1 and 2, Comparative Examples 1, 2, and 3 Using hair cosmetics Hair cosmetics having the composition shown in Table 1 were prepared by a conventional method (Table 1).

Measurement of the effect of restoring the hair breaking strength Permanent treatment of healthy black hair with a commercially available permanent wave treatment agent twice and with a commercial two-component oxidative hair dye twice, and a bundle of 50 damaged hairs 5 bundles were made. Example 1,
2. After dipping in 30 g of each hair cosmetic composition of Comparative Examples 1, 2, and 3, treated at 40 ° C. for 30 minutes, washed with 5% aqueous solution of laureth sulfate and washed with water. The remaining one bundle was untreated hair as a comparative control. After leaving at room temperature 25 ° C. and humidity 45% for 18 hours, 20 hairs were collected and the hair strength was measured with a tensile tester (Rheometer NRM-2005J Fudo Kogyo Co., Ltd.). The measurement results are shown in Table 2. It was.

マカデミアナッツ脂肪酸フィトステリル：
ＹＯＦＣＯ ＭＡＳ（日本精化製） 分子量６８０
長鎖分岐脂肪酸コレステリル ：
ＹＯＦＣＯ ＣＬＥ-ＮＨ（日本精化製） 分子量６８０

Macadamia nut fatty acid phytosteryl:
YOFCO MAS (Nippon Seika Co., Ltd.) Molecular weight 680
Long-chain branched fatty acid cholesteryl:
YOFCO CLE-NH (Nippon Seika Co., Ltd.) Molecular weight 680

(result)
As shown in Table 2, the hair cosmetic of Example 1 in which macadamia nut fatty acid phytosteryl was dissolved in diisopropyl sebacate, and the hair cosmetic of Example 2 in which long-chain branched fatty acid cholesteryl was dissolved in diethyl sebacate When treated, the hair breaking strength is restored. On the other hand, in the treatment of Comparative Example 1 in which macadamia nut fatty acid phytosteryl was dissolved in trioctanoin, Comparative Example 2 in which long-chain branched fatty acid cholesteryl was dissolved in cetyl octanoate, and Comparative Example 3 in which only diethyl sebacate containing no sterol ester was used. Since the hair breaking strength hardly recovered, it was found that the hair cosmetic of the present invention is useful.

Example 2 Treatment A treatment having the following formulation was prepared. This treatment was a treatment capable of repairing hair damage.
Component Blending amount (% by weight)
--------------------------------
1 Diethyl sebacate 1.0
2 Cholesterol 0.1
3 Phytosteryl oleate 0.2
4 Stealtrimonium chloride (63%) 2.0
5 Behentrimonium chloride (80%) 0.6
6 Glyceryl stearate (SE) 2.0
7 Steerless-10 0.8
8 Cetanol 7.0
9 Isodecyl neopentanoate 1.5
10 Chloromethacrylic acid choline ester polymer / di (caprylic acid / capric acid) propylene glycol (Ciba Specialty Chemicals, Salcare SC96)
1.0
11 Methylparaben 0.2
12 Citric acid appropriate amount
13 Hydrolyzed wheat protein 1.0
14 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. No. 14 was heated to about 80 ° C. 13 was added and dissolved (part A). No. in a separate container.
1 to 11 were added, heated and dissolved (part B). Gradually add Part A to Part B and mix evenly. 12 to pH 4.5-5.0.

Example 3 Mild Shampoo A mild shampoo having the following formulation was prepared. This shampoo had good foaming, and was not stiff from the time of rinsing until after drying, thereby suppressing the feeling of damage.
Component Blending amount (% by weight)
--------------------------------
1 Diethyl sebacate 0.5
2 Plandool-H (Nippon Seika) 0.01
3 Cocoyl methyl methyl taurine Na (30%) 30.0
4 Cocamidopropyl betaine (30%) 20.0
5 Laureth-12 Na acetate (30%) 5.0
6 1,3-Butylene glycol 1.0
7 Cocamide MEA 2.0
8 Glycol distearate 1.5
9 Polyquaternium-10 0.8
10 Cationic NH (Nippon Seika) 0.5
11 Sodium benzoate 0.4
12 Phenoxyethanol 0.2
13 Methylparaben 0.2
14 Hydrolyzed silk 0.5
15 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. 1 to 8 were heated to about 80 ° C. and dissolved (part A). No. in a separate container. 9-15 about 8
Heated to 0 ° C. to dissolve (Part B). While stirring Part B into Part A, they were gradually added and mixed uniformly, and then rapidly cooled.

Example 4 Hair Shampoo A hair shampoo having the following formulation was prepared. This shampoo was able to give a light and slippery feeling by suppressing the hair stiffness.
Component Blending amount (% by weight)
--------------------------------
1 Diisopropyl adipate 0.5
2 YOFCO MAS (Nippon Seika) 0.01
3 LUSPLAN PI-DA (Nippon Seika) 0.01
4 Sodium cocoyl glutamate (30%) 40.0
5 Olefin (C14-16) sulfonic acid Na solution (37%) 10.0
6 Lauramide MIPA 4.5
7 Dioleic acid PEG-120 methyl glucose 2.0
8 SIMULGEL EG (SEPPIC) 3.0
9 Methylparaben 0.2
10 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. No. 10 is heated to about 80 ° C. 9 was added and dissolved (part A). In a separate container 1
˜7 was added, heated and dissolved (part B). Gradually add Part A to Part B and mix evenly. 8 was added.

Example 5 Hair bleaching agent (2 agent type)
A hair bleaching agent (two-part formulation) having the following formulation was prepared. This hair bleaching agent (two-component type) was a bleaching agent capable of suppressing damage to the hair and giving the hair a good feel such as flexibility and slipping when applied to the hair.
(1 agent)
Component Blending amount (% by weight)
--------------------------------
1 Diisopropyl sebacate 0.5
2 YOFCO CLE-NH (Nippon Seika) 0.05
3 Polyoxyethylene oleyl ether 52.0
4 Ammonia water (25%) 25.5
5 Cetrimonium chloride (30%) 10.0
6 Ethanol 10.0
7 Purified water Total amount of 100 --------------------------------
(Preparation method)
Each component was stirred and mixed uniformly.
(2 agents)
Component Blending amount (% by weight)
--------------------------------
1 Hydrogen peroxide solution 17.0
2 Cetrimonium chloride (30%) 10.0
3 Cetanol 3.0
4 Seth-2 1.0
5 Seths-20 1.0
6 Na pyrophosphate 0.1
7 Diethylenetriaminepentaacetic acid 0.1
8 Citric acid appropriate amount
9 Purified water Total amount of 100 --------------------------------
(Preparation method)
Each component was mixed uniformly, and the pH was adjusted to 3.5 to 4.0 with citric acid.
(Mixing ratio)
1 agent: 2 agents = 1: 7

Example 6 Hair depigmenting agent (3-agent type)
A hair bleaching agent (three-part formulation) having the following formulation was prepared using the composition for producing a cosmetic according to the present invention.
In addition, 1 agent and 2 agents of Example 12 were used for 1 agent and 2 agents. This hair bleaching agent (three-component formula) was a bleaching agent that, when applied to hair, suppresses damage to the hair and gives the hair a good feel such as flexibility and slippage.
(3 agents)
Component Blending amount (% by weight)
--------------------------------
1 Ammonium persulfate 65.0
2 Sodium carbonate 35.0
--------------------------------
(Preparation method)
Each component was mixed uniformly.
(Mixing ratio)
1 agent: 2 agents: 3 agents = 3: 6: 1

Example 7 Oxidative hair dye An oxidative hair dye having the following formulation was prepared. This oxidative hair dye was an oxidative hair dye capable of imparting a good feel such as flexibility and slipperiness to the hair by treating the hair.
(1 agent)
Component Blending amount (% by weight)
--------------------------------
1 Diethyl sebacate 0.5
2 YOFCO MAC 0.02
3 Cetrimonium chloride (25%) 24.0
4 Cetanol 9.0
5 Octyldecanol 9.0
6 Monoethanolamine 3.8
7 Ammonia water 2.0
8 Myristyl sulfate Na 1.5
9 Ores-20 1.4
10 Toluene-2,5-diamine hydrochloride 1.0
11 Resorcin 1.0
12 Metaaminophenol 0.5
13 Paraaminophenol 0.2
14 Orthoaminophenol 0.1
15 Ascorbic acid 0.2
16 Fragrance 0.1
17 Hydrolyzed keratin 0.2
18 Purified water Total amount of 100 --------------------------------
(Preparation method)
Each component was mixed uniformly.
(2 agents)
Component Blending amount (% by weight)
--------------------------------
1 Hydrogen peroxide solution 17.0
2 Cetrimonium chloride (25%) 10.0
3 Cetanol 3.0
4 Ores-2 1.0
5 Ores-20 1.0
6 Na pyrophosphate 0.1
7 Diethylenetriaminepentaacetic acid 0.1
8 Citric acid (50%) appropriate amount
9 Purified water Total amount of 100 --------------------------------
(Preparation method)
Each component was mixed uniformly and the pH was adjusted to 3.5-4.0 with citric acid.
(Mixing ratio)
1 agent: 2 agents = 1: 1

Example 8 Acid hair dye The acid hair dye of the following prescription was prepared. This acidic hair dye was an acidic hair dye capable of imparting a good feel such as flexibility and slipperiness to the hair by performing treatment on the hair.
Component Blending amount (% by weight)
--------------------------------
1 Diisopropyl sebacate 0.5
2 Cholesteryl hydroxystearate 0.1
3 N-methylpyrrolidone 15.0
4 Benzyl alcohol 8.0
5 Citric acid 1.0
6 Brown 201 0.13
7 Black 401 No. 0.05
8 Purified water Total amount of 100 --------------------------------
(Preparation method)
Each component was mixed uniformly.

Example 9 Cysteine permanent agent A cysteine permanent agent having the following formulation was prepared. This cysteine-based permanent agent is a permanent agent that can impart good touches such as damage suppression, flexibility, and a feeling of slipping, and can maintain wave formation by performing treatment on hair.
(1 liquid)
Component Blending amount (% by weight)
--------------------------------
1 Diethyl sebacate 0.5
2 CLE-NH (Nippon Seika) 0.02
3 Monoethanolamine 4.5
4 L-cysteine hydrochloride 3.2
5 Acetylcysteine 2.5
6 Ores-20 2.0
7 Ammonium thioglycolate solution (50%) 1.9
8 PEG-20 sorbitan cocoate 1.0
9 Ammonia water (28%) 0.3
10 Hydrolyzed collagen 0.2
10 Purified water Total amount of 100 --------------------------------
(Preparation method)
Each component was stirred and mixed uniformly.
(2 liquids)
Component Blending amount (% by weight)
--------------------------------
1 Diisopropyl sebacate 0.5
2 LUSPLAN PI-DA (Nippon Seika) 0.1
3 Sodium benzoate 0.2
4 Edetic acid 2Na 0.1
5 Diammonium phosphate 0.1
6 Emmacol TS-703 (Sanei Chemical) 2.0
7 Stearyltrimonium chloride (50%) 2.0
8 Na bromate 10.0
9 Emmacol NZ (Sanei Chemical) 4.0
10 Ores-20 3.0
11 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. Take most of 10 and heat to about 60 ° C. No. 1 to 3 were added and dissolved.
4 was added and dissolved. Then No. Add 5 and 6 and heat, dissolve and slowly cool to 40 ° C
No. 7-9 was added and made uniform. The remaining No. 10 was added, mixed uniformly and cooled.

Example 10 Thioglycolic acid-based permanent agent A thioglycolic acid-based permanent agent having the following formulation was prepared. This thioglycolic acid-based permanent agent was a permanent agent that gave hair a feeling of slipping and softness when applied to the hair.
(1 liquid)
Component Blending amount (% by weight)
--------------------------------
1 Diethyl sebacate 1.0
2 YOFCO MAS 0.1
3 Polyquaternium-22 2.0
4 Monoethanolamine 1.0
5 Ammonia water (28%) 1.0
6 PEG-50 hydrogenated castor oil 0.2
7 Ammonium bicarbonate 2.0
8 Phosphoric acid 2Na 0.5
9 Ammonium thioglycolate aqueous solution (50%) 11.5
10 Cysteine 1.5
11 EDTA-4Na 0.15
12 Hydroxide Na 0.25
13 Polyquaternium-10 0.1
14 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. No. 14 in the majority of No. 14 12 is dissolved, and then No. 12 is dissolved. No. 13 was added in small portions and dissolved. 9 to 11 were added and dissolved (part A). No. in a separate container. Take the rest of No. 13, 7, 8 was added and heated and dissolved (part B). No. in a separate container. Add 1-6, about 5
Warm to 0 ° C. and dissolve (part C). Part B was added to part A and mixed uniformly, then part C was gradually added and mixed uniformly.
(2 liquids)
Two liquids of Example 16 were used.

Example 11 Straight Perm Agent (Cation Type)
One part and two parts of a straight perm agent (cation type) having the following formulation were prepared. This straight perm agent was able to hold the hair firmly during the treatment, and was excellent in slipperiness after washing.
(1 liquid)
Component Blending amount (% by weight)
--------------------------------
1 Diisopropyl sebacate 0.5
2 Plandool-H 0.01
3 Cetanol 5.0
4 Steartrimonium chloride 2.4
5 Seths-20 2.4
6 TRIBEHENIN PEG-20 ESTERS 2.0
7 Seth-6 0.8
8 Lauric acid monoisopropanolamide 0.8
9 PEG-60 hydrogenated castor oil 0.4
10 Ammonium thioglycolate solution (50%) 13.5
11 Monoethanolamine 1.7
12 Polyquaternium-6 1.3
13 Hydrolyzed soy protein 1.0
14 EDTA-4Na 0.1
15 Ammonia water (28%) 1.1
16 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. Most of 16 were warmed to about 80 ° C. (Part A). No. in a separate container. 1 to 9 were added and heated to dissolve (Part B). No. in a separate container. No.15, no. 10-14 was added and dissolved uniformly (part C). Part B was added to part A, mixed and stirred, and part C was added at about 45 ° C. and mixed uniformly. After cooling to room temperature, no. 15 was added.
(2 liquids)
Component Blending amount (% by weight)
--------------------------------
1 Diethyl sebacate 1.5
2 Phytosteryl hydroxystearate (Nippon Seika) 0.2
3 Cetanol 5.0
4 Emmacol VT-20 (Sanei Chemical) 5.0
5 Dimethicone (200cst) 2.0
5 Trioctanoin 2.0
7 Octyldecanol 0.6
8 SETES-20 0.5
9 Diammonium phosphate 0.2
10 Sodium benzoate 0.15
11 Na bromate 8.0
12 Hydrolyzed wheat protein 0.2
13 Betaine 0.1
14 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. 1-8 were added, it heated at about 70 degreeC, and it was made to melt | dissolve (A part). No. in a separate container. No. 14 was taken and heated to about 70 ° C. 9, 10, 12, and 13 were added and dissolved (part B)
. No. in a separate container. Take the remainder of 12 and heat to about 60 ° C. 11 was added and dissolved (
C section). At about 70 ° C., part B was added to part A and stirred until the viscosity increased. The mixture was cooled to 60 ° C., and part C was added with stirring and mixed uniformly. After the temperature dropped to about 50 ° C., it was rapidly cooled.

Example 12 Curling Agent A curling agent having the following formulation was produced. By using this curl agent 1 and 2 on the hair,
It was able to curl with good flexibility, slipperiness, moist texture, and good finish.
(1 liquid)
Component Blending amount (% by weight)
---------------------------------
1 Cysteamine hydrochloride 2.0
2 DL cysteine 0.4
3 Monoethanolamine 0.9
4 Ammonia water (28%) 0.5
5 POE (20) Palm oil fatty acid sorbitan 0.5
6 Fragrance 0.1
7 Diallylammonium chloride / acrylic acid copolymer 1.0
8 Emmacol VT-20 (Sanei Chemical) 3.0
9 Ores-20 0.5
10 Ores-50 0.2
11 Diisopropyl sebacate 0.5
12 Cholesteryl isostearate 0.02
13 Lanolin fatty acid octyldodecyl 0.3
14 Sorbitan stearate 0.2
15 Edetic acid 4Na (tetrahydrate) 0.1
16 Ammonium phosphate 0.5
17 Glycine 0.1
18 Glutamic acid 0.2
19 Purified water Total amount of 100 ---------------------------------
(Preparation method)
No. No. 19 in part (20%) 1 to 3 was added and dissolved, and No. 1 was previously stored in a separate container.
No. 16 in part (10%) What was melt | dissolved by adding 15 and 16 was added at about 40 degreeC, and it was made to melt | dissolve uniformly (A part). In another container, no. The remainder of 17, 18, 19 was heated to about 75 ° C. (Part B). In another container 8-14 was taken and heated to about 75 ° C. to dissolve (Part C). After adding part B to part C and emulsifying and stirring and mixing well, it was cooled to 40 ° C. and part A was added and stirred uniformly. Next, no. No. 7 was added and stirred. Nos. 5 and 6 were added.
4 was added, and the mixture was stirred and mixed uniformly to adjust the pH to 9.0 to 9.5, thereby obtaining the target curling agent 1 solution.
(2 liquids)
Component Blending amount (% by weight)
----------------------------------
1 EDTA-2Na 0.1
2 Na bromate 4.0
3 Ammonium phosphate 0.5
4 Quotanium-33 (Nippon Seika Cationic NH) 2.0
5 Cetrimonium chloride (30%) 1.0
6 Ores-50 0.2
7 Dimethicone copolyol 0.5
8 Sodium benzoate 0.15
9 Serine 0.2
10 Purified water Total amount of 100 ----------------------------------
(Preparation method)
No. 4-7 were heated to about 80 ° C. and dissolved (part A). In another container Nos. 9 and 10 (70%) and no. 1 and 8 were added and heated to about 80 ° C. to dissolve (Part B). In another container, no. No. 10 and no. A few were added and heated to about 50 ° C. to dissolve (Part C). A
Part B is added to the part and mixed and stirred uniformly for emulsification. After reaching 40 ° C., part C is added and mixed well, and the pH is adjusted to 6.5 to 6.8 at room temperature. An agent 2 liquid was obtained.

Example 13 Pearl Shampoo A pearl shampoo having the following formulation was prepared. This shampoo was well foamed and maintained a smooth feel from rinsing to drying.
Component Blending amount (% by weight)
----------------------------------
A
Cocoyl Methyl Taurine Na (30%) 8.0
Cocamidopropyl betaine (30%) 5.0
Lauroylmethylalanine Na 5.0
Cocamide DEA 3.0
Polyoxyethylene cetostearyl ether 1.6
Ethylene glycol distearate2.0
Diethyl sebacate 0.5
Cholesterol 0.01
Plandool-H (Nippon Seika) 0.01

B
Quotanium-33 (Nippon Seika Cationic NH) 0.4
Citric acid appropriate amount
Produce 400 (Ajinomoto Co., Inc.) 2.0
Purified water Total amount of 100 ----------------------------------
(Preparation method)
A and B (excluding citric acid) were each heated to about 80 ° C. and dissolved. B was gradually added to A and mixed uniformly, and citric acid of B was added and stirred for 1 minute and then cooled.

Example 14 Hair Shampoo A hair shampoo having the following formulation was prepared. This shampoo was well foamed and maintained a smooth feel from rinsing to drying.
Component Blending amount (% by weight)
----------------------------------
Sodium laureth sulfate (30%) 8.0
Cocoamphoacetate Na (40%) 5.0
Lauroyl-N-methyl-β-alanine sodium 5.0
1,3-butylene glycol 3.5
Fragrance, pigment, preservative Trace amount of diisopropyl sebacate 0.5
LUSPLAN PB-DA (Nippon Seika) 0.1
Phytosterol 0.01
Polyquaternium-10 0.25
Royal Jelly 0.1
Purified water Total amount of 100 ----------------------------------
(Preparation method)
All ingredients were mixed uniformly.

Example 15 Hair Shampoo A hair shampoo having the following formulation was prepared. This shampoo was well foamed and maintained a smooth feel from rinsing to drying.
Component Blending amount (% by weight)
----------------------------------
Lauryl sulfate triethanolamine (40%) 10.0
Cocamidopropyl betaine (30%) 2.8
Lauramide DEA 3.0
Diethyl sebacate 0.4
El Dew PS-304 (Ajinomoto Co.) 0.01
Citric acid 0.1
Alanine 0.1
Leucine 0.2
Betaine 0.1
Blue No.1 trace fragrance 0.5
Purified water Total amount of 100 ----------------------------------
(Preparation method)
All ingredients were mixed uniformly.

Example 16 Hair Shampoo A hair shampoo having the following formulation was prepared. This shampoo was well foamed and maintained a smooth feel from rinsing to drying.
Component Blending amount (% by weight)
----------------------------------
N-lauroyl-N-methylalanine sodium 7.0
N-lauroylmethyl taurine sodium 3.5
Lauryldimethylaminoacetic acid betaine 5.0
Cocamidopropyl betaine (30%) 2.3
Diethyl sebacate 0.4
Cholesteryl nonanoate 0.01
Aspartic acid 0.2
Hydrolyzed keratin 0.1
Cationized oligosaccharide 0.1
Yellow No.4 trace fragrance 0.4
Purified water Total amount of 100 ----------------------------------
(Preparation method)
All ingredients were mixed uniformly.

Example 17 Hair Rinse A hair rinse having the following formulation was prepared. This rinsing imparted a moist feeling and gloss to the hair, and was able to impart smooth fingering.
Component Blending amount (% by weight)
----------------------------------
A
Cetrimonium chloride (30%) 5.2
Steartrimonium chloride (63%) 0.6
Cetanol 2.8
Octyldodecanol 4.7
Squalane 0.3
Diisopropyl sebacate 2.0
YOFCO MAC (Nippon Seika) 0.5
Erdu CL-301 (Ajinomoto Co.) 0.2
Phytosteryl oleate 0.4
Ores-5 0.1
Setes-20 0.1
Myristyl sulfate Na 0.2
Cetyl sulfate Na 0.1
B
Polyquaternium-39 0.2
Lipidure C (Nippon Yushi Co., Ltd.) 0.4
Hydrolyzed collagen 0.2
Citric acid 0.1
Purified water Total amount of 100 ----------------------------------
(Preparation method)
A and B (excluding citric acid) were each dissolved by heating to about 80 ° C. Part B was gradually added to part A and mixed uniformly, citric acid was added, and the mixture was stirred for 1 minute and then cooled.

Example 18 Hair Rinse A hair rinse having the following formulation was prepared. This rinsing imparted a moist feeling and gloss to the hair, and was able to impart smooth fingering.
Component Blending amount (% by weight)
----------------------------------
A
Behentrimonium chloride (80%) 2.0
Cetanol 3.0
Cyclomethicone 4.5
Diisopropyl sebacate 0.5
Cholesterol 0.03
YOFCO CLE-H (Nippon Seika) 0.6
Phytosteryl stearate 0.4
Glyceryl stearate (SE) 1.0
B
Propylene glycol 3.0
Betaine 0.2
Glycine 0.1
Hydrolyzed silk 0.1
Preservatives, pigments Trace fragrance 0.3
Purified water Total amount of 100 ----------------------------------
(Preparation method)
A and B (excluding fragrance) were mixed and dissolved at 75 ° C. After mixing part A and part B, after cooling,
A fragrance was added to produce.

Example 19 Leave-on treatment A leave-on treatment (for hair) having the following formulation was prepared. This leave-on treatment was able to give a soft and slippery feel to the hair with a light touch. Moreover, stability was also favorable.
Component Blending amount (% by weight)
--------------------------------
A
Diisopyropyl adipate 1.0
Cholesterol 0.1
Plandool-H (Nippon Seika) 0.5
Plandool-PB (Nippon Seika) 0.2
Myristyl alcohol 5.0
Behenyl alcohol 1.0
Oleyl alcohol 1.0
Stearic acid dimethylpropylamide 2.0
Cocoamphoacetate Na (30%) 2.0
Glyceryl stearate 0.4
Myristic acid 0.6
Phenoxyethanol 0.4
B
Hydrolyzed keratin 0.01
Hydrolyzed silk 0.01
Lactic acid 0.6
Purified water Total amount of 100 --------------------------------
(Preparation method)
Part A was heated to about 80 ° C. and dissolved. Part B was taken in another container, and part B was gradually added to A part dissolved by heating to about 80 ° C. and mixed uniformly.

Example 20 Leave-on treatment A leave-on treatment (for hair) having the following formulation was prepared. This leave-on treatment was able to give a soft and slippery feel to the hair with a light touch. Moreover, stability was also favorable.
Component Blending amount (% by weight)
--------------------------------
1 Diisopropyl sebacate 4.0
2 YOFCO MAS (Nippon Seika) 0.4
3 Plandool-H (Nippon Seika) 0.5
4 Cetanol 5.0
5 Steartrimonium chloride (63%) 3.2
6 Behentrimonium chloride (80%) 1.0
7 Squalane 1.0
8 Glycerin 1.0
9 Hydrolyzed conchiolin 0.1
10 Methylparaben 0.1
11 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. 1 to 8 were heated to about 80 ° C. and dissolved (part A). In another container 9 to 11 were taken and heated to about 80 ° C. to dissolve (Part B). Part B was gradually added to part A and mixed uniformly.

Example 21 Hair Essence A hair essence having the following formulation was prepared. This hair essence was refreshing and non-sticky and could give the hair a soft and slippery feel.
Component Blending amount (% by weight)
--------------------------------
1 Diisopropyl sebacate 1.0
2 Cholesterol 0.1
3 Erdu CL-202 (Ajinomoto) 0.2
4 Plandool-S (Nippon Seika) 0.2
5 Cetanol 1.0
6 Steartrimonium chloride (63%) 0.8
7 Dicocodimonium chloride (75%) 2.8
8 Solveste tetraoleate-60 1.0
9 PEG-40 hydrogenated castor oil 0.2
10 Produce 400 (Ajinomoto Co., Inc.) 2.0
11 Methylparaben 0.1
12 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. 1 to 9 were heated to about 80 ° C. and dissolved (Part A). In another container 10-12 were taken and heated to about 80 ° C. to dissolve (Part B). Part B was gradually added to part A and mixed uniformly.

Example 22 Hair Foam A hair foam having the following formulation was prepared. This hair foam had a good feeling of use and setability that were smooth.
Component Blending amount (% by weight)
----------------------------------
(Stock solution formulation)
1 Acrylic resin alkanolamine solution (50%) 7.0
2 Yuka Former AM75W (Mitsubishi Chemical Corporation) 1.0
3 Appropriate amount of polyoxyethylene hydrogenated castor oil
4 Dimethicone 2.0
5 Diisopropyl sebacate 3.0
6 YOFCO CLE-S (Nippon Seika) 0.2
7 LUSPLAN PI-DA (Nippon Seika) 2.0
8 Glycerin 3.0
9 Ethanol 15.0
10 Preservative appropriate amount
11 Purified water Total amount of 100 ----------------------------------
(Filling prescription)
Stock solution 90.0
Petroleum liquefied gas 10.0
----------------------------------
(Preparation method)
No. Nos. 1, 3 to 10 were mixed evenly. 2 and 11 were added and mixed uniformly.
After filling this stock solution into a can, it was filled with gas.

Example 23 Moose A mousse having the following formulation was prepared. This mousse had a smooth feel and a light styling.
Component Blending amount (% by weight)
----------------------------------
(Stock solution formulation)
1 Diethyl sebacate 2.0
2 Cholesterol 0.1
3 YOFCO MAC (Nippon Seika) 0.1
4 Ethanol 5.0
5 Ores-20 1.0
6 Acrylic resin alkanolamine solution 2.0
7 Yuka Former AM75W (Mitsubishi Chemical Corporation) 1.0
8 Diethylaminoethylamide stearate 0.5
9 Pyrrolidone carboxylic acid 0.2
10 POE, POP-modified silicone 1.0
11 Preservatives and perfumes
12 Hydrolyzed wheat protein 0.5
13 Purified water Total amount of 100 ----------------------------------
(Production method)
Stir and mix each component uniformly.
The above-mentioned stock solution: petroleum liquefied gas was mixed at a ratio of 92: 8 to obtain an injection type mousse.

Example 24 Hair Cream A hair cream having the following formulation was prepared. This hair cream had setability, was not sticky, and was able to impart a good feel and smooth fingering as if it were slippery.
Component Blending amount (% by weight)
----------------------------------
A
Stearic acid 2.0
Lanolin 3.5
Erdu PS-203 (Ajinomoto) 0.5
Plandool-H (Nippon Seika) 0.5
Phytosterol 0.1
Paraffin wax 2.0
Liquid paraffin 28.0
Dimethicone 0.2
Glyceryl stearate (SE) 1.0
Sorbitan monostearate1.0
Polyoxyethylene cetyl ether 1.5
Diisopropyl adipate 10.0
FA-NH (Nippon Seika) 0.2
YOFCO MAS (Nippon Seika) 0.05
Preservative appropriate amount B
Glycine 0.1
Betaine 0.2
Alanine 0.1
Triethanolamine 1.0
1,3-butylene glycol 3.0
Purified water Amount C totaling 100
Perfume proper amount ----------------------------------
(Production method)
A and B were each dissolved at about 80 ° C., then uniformly mixed and cooled (50 ° C.), C was added and mixed uniformly.

Example 25 Smooth mist A smooth mist having the following formulation was prepared. This smooth mist was non-sticky, had a light setting property, and was able to give a smooth feel to the hair and smooth touch.
Component Blending amount (% by weight)
----------------------------------
Diethyl sebacate 1.0
Cholesterol 0.1
YOFCO CLE-NH 0.2
Dimethicone 0.4
Cetrimonium chloride (30%) 4.0
Ethanol 8.0
Purified water Total amount of 100 ----------------------------------
(Production method)
Each component was stirred and mixed uniformly.

Example 26 Hair wax A hair wax having the following formulation was prepared. This hair wax had good adhesion to the hair and was excellent in setability and hair bundle feeling, was not sticky and could give a glossy and good feel.
Component Blending amount (% by weight)
----------------------------------
1 LUSPLAN DD-DA5 (Nippon Seika) 3.6
2 Hydrogenated ester gum 0.4
3 Emmacol HW-4619 (Sanei Chemical) 5.0
4 Diisopropyl adipate 4.0
5 YOFCO MAC (Nippon Seika) 0.2
6 Stearyl alcohol 4.0
7 12-Hydroxystearic acid 3.0
8 Dimethicone (50cs) 2.0
9 Squalane 1.0
10 Phenyldimethicone 0.5
11 Tocopherol 0.05
12 Hydroxide Na 0.3
13 Methylparaben 0.2
14 Purified water Total amount of 100 ----------------------------------
(Production method)
No. 1 to 11 are heated to about 80 ° C. and dissolved (part A). In another container 12-14
Is heated to about 80 ° C. and dissolved uniformly (Part B). Part B was gradually added to part A and mixed uniformly.

Example 27 Hair Tonic A hair tonic having the following formulation was prepared. This hair tonic was not sticky, prevented dandruff and itching, gave the hair a good feel and replenished nutrition.
Component Blending amount (% by weight)
----------------------------------
A
Diethyl sebacate 2.0
LUSPLAN PI-DA (Nippon Seika) 0.1
Menthol 0.05

Isopropyl methylphenol 0.1
Ethanol 60.0
B
1,3-butylene glycol 1.0
Pyridoxine hydrochloride 0.1
Purified water Total amount of 100 ----------------------------------
(Production method)
Both A and B were dissolved and made uniform at room temperature, and then B was added to A with stirring to make it uniform.

Example 28 Hair restorer A hair restorer having the following formulation was prepared. This hair restorer was able to prevent hair loss, dandruff and itching, and to replenish nutrients.
Component Blending amount (% by weight)
----------------------------------
Diisopropyl sebacate 0.5
Cholesterol 0.05
Phytosteryl oleate 0.1
Menthol 0.1
Pepper tincture 0.5
Assembly extract 2.0
Ethanol 30.0
Preservative Appropriate amount of perfume Appropriate amount PPG-6 Decyltetradeces-30 0.3
Pro Dew 400 (Ajinomoto Co.) 0.1
Lipidure PMB (Nippon Yushi Co., Ltd.) 0.5
Purified water Total amount of 100 ----------------------------------
(Production method)
Stir and mix each component uniformly.

  According to the present invention, a hair cosmetic capable of repairing hair damage can be obtained.

Claims (5)

  (A) A hair cosmetic composition containing one or more diesters of a dicarboxylic acid having 6 to 10 carbon atoms and (B) a sterol ester having a molecular weight of 1500 or less. The hair cosmetic according to claim 1, wherein the dicarboxylic acid diester is a lower alcohol ester having 1 to 4 carbon atoms. The hair cosmetic composition according to claim 1 or 2, wherein the diester of dicarboxylic acid is diethyl sebacate or / and diisopropyl sebacate. The component (B) is a sterol ester composed of one or more carboxylic acids selected from carboxylic acids having 1 to 30 carbon atoms, dimer acids and trimer acids, and alcohols containing at least one sterol. The hair cosmetic composition according to any one of claims 1 to 3. The hair cosmetic composition according to any one of claims 1 to 4, wherein the sterols are cholesterol or / and a plant sterol containing at least β-sitosterol.