JP5296500B2 - Hair conditioning composition - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a hair conditioning composition enhancing a feeling of use of residual oil, and impartment of suppleness and softness to the hair surface after rinsing and use, having a coherency feeling with suppressed spreading of hair tips by external damage, taking even irritation to mucosal membranes or safety of continuous use into consideration, and imparting the feeling of use of good finger combing with a lustrous and moist coating even onto the hair tips. <P>SOLUTION: The hair conditioning composition includes: (A) a branched polyglycerol-modified silicone represented by general formula (1) [wherein, R represents branched polyglycerol chain in which three or more glycerols or glycidols are bound, and at least one thereof is branched glycerol; and n represents an integer of 0-10,000]; (B) a fluorine-modified silicone represented by general formula (2) [wherein, R<SP>1</SP>to R<SP>3</SP>, R<SP>7</SP>, and R<SP>9</SP>to R<SP>12</SP>are selected from among hydroxy, 1-20C alkyl, and phenyl; R<SP>4</SP>and R<SP>5</SP>are selected from among 1-20C alkyl, and phenyl; R<SP>6</SP>is selected from among 1-20C fluorine-substituted hydrocarbon; R<SP>8</SP>is hydroxy; l is an integer of 0-20,000; m is an integer of 1-20,000; n is an integer of 0-2,000; and each siloxane unit is randomly polymerized]; and (C) an ester oil having &lt;40&deg;C melting point. <P>COPYRIGHT: (C)2010,JPO&amp;INPIT

Description

  The present invention is damaged by UV damage, permanents, coloring, excessive brushing and the heat of a hair dryer, which are external factors in daily life, and splits caused by cuticle damage, spread with dryness and dryness The present invention relates to a hair conditioning composition capable of imparting a feeling of unity to a tender hair tip and a good feeling of use as a finger coated with glossy moisture.

  Invasive care measures for excessively damaged hair include hair rinses, hair treatments, hair packs, hair masks, etc., and these hair conditioning compositions contain a cationic surfactant as the main component. In order to further enhance the conditioning effect, peptides or proteins derived from higher alcohol, liquid paraffin, ester oil, dimethylpolysiloxane, shellfish, fish, silk, plants, etc., or their derivatives are blended to form a composition. It is known that the conditioning effect described above can be obtained by physical adhesion, charge adsorption, or permeation of these components on the hair surface even after rinsing with hot water or water in use.

Conventionally, a mixture of oils containing various esters in a specific ratio and hair cosmetics containing a specific amount (for example, see Patent Document 1) have been disclosed. It has been shown to give a feeling of gender and non-stickiness. Also, hair cosmetics containing diester oils and silicone derivatives of fatty acid diglycerin and saturated dibasic acid, ester oils such as esters of dimer linoleic acid and amino-modified silicone and / or sulfonic acid-modified silicone (for example, patents) Reference 2 and Patent Document 3) are disclosed, and even though an ester oil agent having a high water retention ability that tends to remain on the surface of the hair during rinsing during use is used, the finish feels supple and moist. It has been shown to give a non-sticky finish. In addition, hair cosmetics containing non-volatile silicone oils such as dimethylpolysiloxane, modified silicones and silicone gums are frequently used in hair cosmetics because they are excellent in combing hair improvement and split hair prevention effects. (For example, refer to Patent Document 4 and Patent Document 5). Furthermore, a hair cosmetic technology that contains a branched polyglycerol-modified silicone and a forming component having a melting point of 40 ° C. or more, has excellent blending stability, and is excellent in hair protection / modification (for example, patents) is also disclosed. Reference 6).
Furthermore, as a means to improve hair conditioning properties, it consists of 1 agent containing inorganic oxides and inorganic salts that generate heat when mixed with water and 2 agents containing water, and by mixing 1 agent and 2 agents at the time of use There are many such as those using the generated reaction heat (for example, see Patent Document 7), those using a continuous method of using the second agent after the first agent is washed after use (for example, see Patent Document 8), etc. A formulation is disclosed.

JP-A-2005-239625 JP 2004-59530 A JP-A-2005-213163 Japanese Patent No. 3449886 JP 2000-290145 A Japanese Patent No. 3946681 Japanese Patent No. 3817058 JP 2006-124278 A

However, when various esters are contained as a single or a combination of oils, they have the effect of giving moist flexibility and suppressing stickiness, but they are satisfactory in the feeling of unity and coating of the hair ends after drying. It wasn't going to be good. In addition, although the use of modified silicone as an oil agent has high adsorptivity to hair, there are concerns about irritation to the mucous membrane and safety depending on the repeated use and content, and it also gives a feeling of glossiness and unity after drying. Was not satisfactory. Non-volatile silicone oils such as dimethylpolysiloxane, modified silicone and silicone gum remain on the hair surface and are effective against slipperiness, squeaking, and hairiness. On the other hand, there are also problems such as causing the spread of hair tips and the obstruction of supple fingering. Furthermore, when a forming component (ester oil, paraffin, petrolatum, etc.) having a melting point of 40 ° C. or higher is washed away and contained in a hair treatment, the gel aggregate mainly comprises a cationic surfactant, a higher alcohol and water. Inhibits the excellent slimy feeling of the skin, inhibits the characteristics of the silicone derivatives that are formulated to improve the feel, does not provide a glossy moist feeling to the hair tip, smooth finger goodness There is a problem to do.
In the use of a multi-drug system intended for conditioning, it is impossible to physically make it one agent because an exothermic reaction is not caused until use as in Patent Document 7, and its safety and invasion are not possible. There is a problem of stability of the formulation such as reduced reactivity in storage, or the mechanism of action of 1 agent and 2 agents is different as in Patent Document 8, and when the application step is divided into 2 agents, the processing time is long. For example, sufficient satisfaction in terms of simplicity could not be obtained.

  In the above circumstances, the present invention increases the feeling of use of the residual oil on the hair surface after rinsing and use, without further reducing the advantages of conventional compositions and hair cosmetics, and further increases the flexibility and flexibility. There is a sense of unity that suppresses the spread of the hair tips due to external damage, and the hair tips are glossy and moisturized even during continuous use in consideration of irritation to the mucous membrane and safety of continuous use. There has been a demand for a hair conditioning composition that can give a good feeling of use according to the finger. That is, the object of the present invention is to satisfy and provide these problems.

  As a result of diligent research in view of the above circumstances, the inventors have obtained a combination of a branched polyglycerol-modified silicone and an ester oil having a melting point of 40 ° C. or higher, or a combination of non-volatile silicone oils such as dimethylpolysiloxane and silicone gum. By limiting the composition of the ester oil agent having a melting point of less than 40 ° C. and the fluorine-modified silicone, the suppleness and flexibility are imparted and the unity feeling of the bristles is further enhanced and The present invention has been completed by finding out that it is possible to impart a good feeling of use as a finger coated with glossy moisture.

That is, the present invention contains (A) a branched polyglycerol-modified silicone represented by the following general formula (1), (B) a fluorine-modified silicone represented by the following general formula (2), and (C) a melting point of 40. The present invention relates to a hair conditioning composition characterized by containing an ester oil agent at a temperature of less than 0 ° C. Moreover, the hair conditioning composition is a combination of cosmetics containing one or two of the above components (A), (B), and (C), and immediately before use, the components (A) to (C) A multi-drug hair conditioning composition that is used in combination of three types is also the present invention, and the above-mentioned (A) component, (B) component, and (C) component are combined with a cosmetic that contains one or two types, respectively. And the hair conditioning method which combines three types of (A)-(C) component just before use also becomes this invention.
[Wherein R represents a branched polyglycerol chain in which three or more glycerol groups or glycidol groups are bonded, and at least one of them is a branched glycerol group, and n represents an integer of 0 to 10,000.]
[However, in the above general formula, R ^{1 to} R ³ , R ⁷ , R ^{9 to} R ¹² are selected from a hydroxyl group, an alkyl group having 1 to 20 carbon atoms, and a phenyl group, and R ⁴ and R ⁵ are carbon numbers. R ⁶ is selected from a fluorine-substituted hydrocarbon group having 1 to 20 carbon atoms, R ⁸ is a hydroxyl group, l is an integer of 0 to 20000, m is 1 to 20 An integer of 20000, n is an integer of 0 to 2000, and each siloxane unit is randomly polymerized]

  The hair conditioning composition of the present invention has a sense of unity that suppresses the spread of damaged hair peculiar to damaged hair, suppleness and flexibility up to the hair tip even in continuous use, and a finger-like coating coated with glossy moisture A feeling of use can be imparted and the blending stability is excellent.

  Hereinafter, the configuration of the present invention will be described in detail.

The (A) branched polyglycerol-modified silicone contained in the hair conditioning composition of the present invention comprises a branched polyglycerol via linking groups containing oxyphenylene groups at both ends of the dimethylpolysiloxane represented by the following general formula (1). A known compound having at least one glycerol chain bonded thereto, which has one or more functional groups selected from the group consisting of a hydroxy group, a carboxy group, an amino group, an imino group, a mercapto group, and an epoxy group, It can be produced by a generally known method such as the method described in JP-A-2004-339244 in which 2,3-epoxy-1-propanol is added and graft polymerization is carried out in the presence of an acidic or basic catalyst. . As a commercially available product, “Sofcare GS-G” (manufactured by Kao Co., Ltd.) and the like can give a glossy, moist and coherent effect as a raw material that can illustrate good results.
[Wherein R represents a branched polyglycerol chain in which three or more glycerol groups or glycidol groups are bonded, and at least one of them is a branched glycerol group, and n represents an integer of 0 to 10,000.]

Among these, the bonding position of the oxygen atom and trimethylene group bonded to the phenylene group is not particularly limited, and may be any of the ortho position, the meta position, and the para position. Examples of branched glycerol groups are represented by the following general formula (3), glycerol groups are represented by general formulas (4) and (5), and glycidol groups are represented by general formula (6).

  The viscosity at 30 ° C. of the (A) branched polyglycerol-modified silicone contained in the hair conditioning composition of the present invention is preferably 10,000 to 500,000 mPa · s, and can give a supple finish. From 20,000 to 100,000 mPa · s is particularly preferable. In addition, the viscosity said here means what was measured by the cosmetics raw material reference | standard and viscosity measuring method 2nd method using the Brookfield type | mold viscosity meter.

  Furthermore, it is preferable to contain 0.001 to 2.0% by mass of the (A) branched polyglycerol-modified silicone having adsorbability due to its high affinity for the hair surface. % By mass is more preferable, and 0.01 to 0.5% by mass is most preferable.

The (B) fluorine-modified silicone represented by the following general formula (2) used in the present invention has a structure in which a linear siloxane main chain is modified with a hydroxyl group and a fluorine-substituted hydrocarbon group, and is flexible. It is characterized by giving an effect with a feeling of slipping.
[However, in the above general formula, R ^{1 to} R ³ , R ⁷ , R ^{9 to} R ¹² are selected from a hydroxyl group, an alkyl group having 1 to 20 carbon atoms, and a phenyl group, and R ⁴ and R ⁵ are carbon numbers. R ⁶ is selected from a fluorine-substituted hydrocarbon group having 1 to 20 carbon atoms, R ⁸ is a hydroxyl group, l is an integer of 0 to 20000, m is 1 to 20 An integer of 20000, n is an integer of 0 to 2000, and each siloxane unit is randomly polymerized]

Among each unit, R ^{1 to} R ⁵ , R ⁷ and R ^{9 to} R ¹² are preferable because a methyl group can be produced most inexpensively, and R ⁶ is preferably a fluorinated alkyl group, particularly a trifluoropropyl group. It is preferable because the intermediate raw material is easily available. R ⁸ is a hydroxyl group, and (B) the hydroxyl group is contained in the fluorine-modified silicone, which is effective for reducing the squeaky feeling of hair. Therefore, even when n = 0, it is preferable that at least one of R ^{1 to} R ³ , R ⁷ and R ^{10 to} R ¹² is a hydroxyl group. From the viewpoint of reducing the squeaky feeling, it is most preferable that R ¹ , R ⁸ and R ¹⁰ are hydroxyl groups. The smaller the values of l, m and n, the lower the viscosity, and the higher the value, the higher the viscosity. The property of the component (B) is a liquid property when the value of l + m + n is about several tens, and when the value increases, it passes through a viscous liquid and becomes solid when the value is tens of thousands.

When the property of the component (B) fluorine-modified silicone is solid, volatile silicone such as cyclic silicone, dimethylpolysiloxane, methylphenylpolysiloxane of 1 × 10 ⁻⁴ m ² / s or less at room temperature, light flow It is preferable to use by dissolving or dispersing the solid component (B) using at least one liquid compound such as isoparaffin, liquid-modified fluorine-modified silicone, perfluoropolyether, and lower alcohol at room temperature. In this case, the concentration of the component (B) is preferably in the range of 5 to 70% by mass with respect to the concentration of the solution. Furthermore, when mixing or dispersing, it is preferable to mix using a mill, such as a roller mill, an attritor, or an extrusion kneader, a mixer, or a kneader.

The fluorine-modified silicone of component (B) is fluoroalkylmethyldichlorosilane (F (CF ₂ ) _a C ₂ H ₄ SiMeCl ₂ [wherein Me is a methyl group] in the presence of an organic solvent such as acetonitrile or methyl acetate. , A is an integer of 2 or more]) and zinc oxide are reacted, and a protic acid such as water and hydrochloric acid is added to the resulting reaction mixture and stirred, and the production method described in JP-A-5-86196 It can be produced according to a known production method.

  In the hair conditioning composition of the present invention, the fluorine-modified silicone as the component (B) is preferably contained in an amount of 0.001 to 2.0% by mass, more preferably 0.05 to 1.0% by mass from the feeling after washing. , 0.01 to 0.5% by mass is most preferable.

  (C) The ester oil agent having a melting point of less than 40 ° C. used in the hair conditioning composition of the present invention is hexa (hydroxystearic acid / isostearic acid) dipentaerythryl, olefinic acid phytosteryl, (ethylhexanoic acid / stearic acid / Adipic acid) Glyceryl and dimerlinoleic acid mixed fatty acid esters, etc. are mentioned, but dimerlinoleic acid mixed fatty acid ester excellent in gloss and water retention due to adhesion to the hair surface is preferred.

  The dimer linoleic acid in the present invention is a dibasic acid ester obtained by polymerization of two molecules of unsaturated fatty acid, and the mixture constituting the ester group part of the mixed fatty acid is oleyl alcohol, stearyl alcohol, behenyl alcohol, lauryl. Some are derived from higher alcohols such as alcohol and linoleyl alcohol, and unsaturated alcohols composed of cholesterol-like phytosterols. Such dimerlinoleic acid mixture fatty acid esters include dimerlinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl) “Plandool-L” (manufactured by Nippon Seika Co., Ltd.), dimerlinoleic acid dimerlinoleyl. Bis (behenyl / isostearyl / phytosteryl) “Plandool-G” (manufactured by Nippon Seika Co., Ltd.) can give a glossy, moist feeling and a feeling of unity of the hair tips as a raw material that can illustrate good results.

  (C) The ester oil agent having a melting point of less than 40 ° C. contained in the hair conditioning composition of the present invention is preferably a dimerlinoleic acid mixture fatty acid ester having excellent gloss and water retention due to adhesion to the hair surface, and 0.001 It is preferable to contain -6.0 mass%, it is still more preferable to contain 0.01-5.0 mass% from the slippery touch after drying, and 0.1-3.0 mass% is the most preferable.

  The (A) branched polyglycerol-modified silicone, (B) fluorine-modified silicone, and (C) an ester oil having a melting point of less than 40 ° C. constituting the hair conditioning composition of the present invention are prepared in advance as (A), (B), ( If component C) is contained in the same composition, it is preferable because it is uniformly dispersed. For example, a composition containing component (A) and component (C) and a composition containing component (B) , A method of simply mixing in the palm of the user or in a separate container when used, a composition containing (A) component and (C) component, (B) component and (C) component A method of simply mixing the composition containing the composition after application, and then applying to the hair, or (A), (B), and (C) each of the three compositions separately contained for easy mixing. Three components are divided into multiple agents, such as later applied to hair. It may be a method for the mixing to three components at the time of use. In this way, according to the simple mixing at the time of use, by applying to the hair in a non-uniform state, the hair or the tip of the hair is prevented from spreading due to damage, and the suppleness and flexibility as a feeling of use, the hair tip is glossy Gives a good feeling of use as a finger coated with moisture.

  In addition to the effects of the use of conditioning that are listed above, the multi-drug formula creates beauty and cuteness by directing the fun of using the product and changing the color of the formulation. It can also create effects such as directing. In considering the multi-drug type, considering the cost, the labor of mixing work, etc., the 2-drug type is preferable. Further, each composition as a multi-drug may be housed in a separate container and taken out and mixed, but it is preferable that each composition is housed in a container of a type that can be discharged simultaneously. As an example in which two agents can be discharged simultaneously, two tubes as shown in FIG. 1 may be accommodated in a larger tube, and two agents may be discharged simultaneously by a single pressing operation. A container of a type that is accommodated in two aerosols and is simultaneously discharged (in this case, simply mixed and discharged from one place) by pressing a take-out button can be preferably used.

  The hair conditioning composition of the present invention can further contain other components as long as the effects of the present invention are not impaired. As such components, anionic surfactants, amphoteric surfactants, nonionic surfactants, cationic surfactants, plant extracts, vitamins, alcohols, oils other than the above, pearling agents, moisturizing ingredients, A fragrance | flavor, a pigment | dye, a ultraviolet absorber, antioxidant, a disinfectant, an anti-inflammatory agent, antiseptic | preservative, etc. are mentioned.

  Hereinafter, the present invention will be described in detail with reference to examples, but the present invention is not limited thereto.

Three components of (A) a branched polyglycerol-modified silicone contained in the hair conditioning composition of the present invention and (B) a fluorine-modified silicone and (C) an ester oil having a melting point of less than 40 ° C. are contained in the same composition. The compositions contained in were prepared according to conventional methods with the formulations shown in Table 1 and evaluated as follows. For the component (B), the following (B1) and (B2) were used.
(B1)
In the following general formula (2), R ¹ , R ⁸ and R ¹⁰ are hydroxyl groups, R ^{2 to} R ⁵ , R ⁷ , R ⁹ , R ¹¹ and R ¹² are methyl groups, R ⁶ is a trifluoropropyl group, l = 10, m = 5, n = 10 (where l, m, n are central values, and the actual polymer has a distribution).
(B2)
In the following general formula (2), R ¹ and R ¹⁰ are hydroxyl groups, R ^{2 to} R ⁵ , R ⁷ , R ¹¹ and R ¹² are methyl groups, R ⁶ is a trifluoropropyl group, l = 3400, m = 150, n = 0 (where l and m are central values, and the actual polymer has a distribution).

<Compounding stability evaluation method>
The hair conditioning composition was stored at 45 ° C. for 3 months, and changes in appearance (separation of components, turbidity, discoloration, etc.) were visually observed and evaluated according to the following criteria.
○: Separation of components, turbidity, and discoloration are not observed.
X: Separation of components, turbidity, and discoloration are observed.

<Sensory test evaluation for feel evaluation>
Hair finish test after use (half-head method)
The panel (20 persons) washed the hair with a 20% aqueous solution of POE (3) sodium lauryl ether sulfate, and then divided the head hair into left and right halves, and applied the hair conditioning composition shown below as one control, and the examples and Each of the hair conditioning compositions shown in the comparative examples was applied and rinsed at the same time, then the hair was dried, and the right and left hairs were glossy, the hairs were moist, the hairs were coherent, and the hairs were well-coated. Sensory evaluation was performed on the finished feeling. Further, the same operation as described above was performed once a day, and the sensory evaluation was performed according to the above items for the finish of the hair after continuous use for one week.

Control (hair conditioning composition) (mass%)
・ Cetanol 5.0
・ Behenic acid dimethylaminopropylamide 2.0
(Product name: Kachinal BMPA [manufactured by Toho Chemical Industry Co., Ltd.])
・ Lactic acid 0.8
・ Concentrated glycerin 2.0
Paraffin 1.0
・ Highly polymerized dimethylpolysiloxane emulsion 2.0
(Product name: KM-902 [manufactured by Shin-Etsu Chemical Co., Ltd.])
・ Phenoxyethanol 0.2
・ Ion exchange water

The standard of evaluation was set as follows (set by the number of people who answered that it was better than the control).
4: 18 or more people who answered good 3: 15 or more people who answered good, less than 18 2: 11 or more people who answered good, less than 15 1: 10 people who answered good Below

Examples 1-12, Comparative Examples 1-7

  As is clear from Table 1, in the examples satisfying the configuration of the present invention, good results were obtained in all items. On the other hand, the comparative example lacking any of the configurations of the present invention was inferior in any of the evaluation items and could not satisfy the object of the present invention.

  Three components of (A) a branched polyglycerol-modified silicone contained in the hair conditioning composition of the present invention and (B) a fluorine-modified silicone and (C) an ester oil having a melting point of less than 40 ° C. are contained in the same composition. The conditioning method used for simple mixing at the time of use was evaluated.

<Sensory test evaluation for feel evaluation>
Hair finish test after use (half-head method)
After the panel (20 persons) shampooed with 20% aqueous solution of POE (3) sodium lauryl ether sulfate, the hair was divided into left and right halves, and the formulation was the same as in Example 6 shown in Table 1, (A), A one-component composition prepared by blending the components (B) and (C) in the same composition and stirring uniformly was applied as a control. On the other hand, as shown in Table 2, (A), ( The B) and (C) components were divided into two agents, and a two-component composition that was simply mixed by the subject just before use was applied. In prescribing the two-component composition, attention was paid so as to obtain the same blending ratio as in Example 6 by simply mixing the two agents. After rinsing these at the same time, the hair is dried, and the following evaluation criteria are used to answer the glossiness of the left and right hair, the moistness of the hair tips, the cohesiveness of the hair tips, and the finish of the coating feeling that is good for the finger tips. And sensory evaluation of it. Further, the same operation as described above was performed once a day, and the sensory evaluation was performed according to the above items for the finish of the hair after continuous use for one week. The results are also shown in Table 2.

The evaluation criteria were set as follows, and the average value of the values answered from each panel was obtained.
2: Better than control (1 agent formula: Example 6) 1: Equivalent to control (1 agent formula: Example 6) 0: Control (1 agent formula: Example 6) is better

According to Table 2, the composition in which the components (A), (B), and (C) were divided into two agents and the test subject was simply mixed immediately before use was more controllable in the “feeling of good coding on the tips of the hair tips” ( It can be seen that it is judged better than the one-drug formula: Example 6). In Table 1, the comparative example lacking a part of the constitution of the present invention was also evaluated by dividing it into two agents. However, as shown in Table 1, a decrease in feel due to the lack of the constitution of the present invention appears as it is. There was no need to evaluate it.

Example 17 hairline (prescription ingredient) (mass%)
Behenyl alcohol 1.5
Cetanol 1.5
Octyldodecanol 1.0
1,3-butylene glycol 2.0
Polyoxyethylene cetyl ether 1.3
Stearyl trimonium chloride 1.6
Hydroxypropyltrimonium honey 0.1
(Product name: Honeycoat 50 [Arch Personal Products LP])
Camellia seed extract (trade name: Camellia extract [Maruzen Pharmaceutical Co., Ltd.]) 0.1
Bis (polyglyceryl-3oxyphenylpropyl) dimethicone 0.1
(Product name: Sofcare GS-G [manufactured by Kao Corporation]) (A)
Dimer linoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl) 0.5
(Product name: Plandool-L [Nippon Seika Co., Ltd.]) (C)
(B2) Component ... (B) 0.1
Highly polymerized dimethylpolysiloxane emulsion 1.0
(Product name: KM-902 [manufactured by Shin-Etsu Chemical Co., Ltd.])
Phenoxyethanol 0.3
Methylchloroisothiazolinone / methylisothiazolinone solution 0.05
(Kathon-CG [made by ROHM AND HAAS])
Perfume Appropriate amount of ion-exchanged water

  The hair rinse not only gives a feeling of unity of the hair after drying and gives a good feeling of fingering that is coated with glossy moisture on the hair, but also has a rich feeling and good fingering when rinsing Met. The blending stability was also good.

Example 18 Hair conditioner (prescription ingredient) (mass%)
Stearyl alcohol 0.5
Cetanol 5.0
Behenic acid dimethylaminopropylamide 1.2
(Product name: Kachinar BMPA [manufactured by Toho Chemical Industry Co., Ltd.])
Stearic acid dimethylaminopropylamide 0.4
(Product name: Amidoamine MPS [manufactured by Nippon Surfactant])
Lactic acid 0.6
Behenyltrimethylammonium chloride 0.7
Concentrated glycerin 2.0
Paraffin 1.0
Hydroxypropyltrimonium honey 0.1
(Product name: Honeycoat 50 [Arch Personal Products LP])
Olive leaf extract 0.1
(Product name: Olive Leaf Extract BG [Maruzen Pharmaceutical Co., Ltd.])
Rose water 0.1
(Product name: Rose leaf extract [manufactured by Koei Kogyo Co., Ltd.])
Hydrolyzed conchiolin solution 0.1
(Product name: Pearl protein extract [Maruzen Pharmaceutical Co., Ltd.])
Bis (polyglyceryl-3oxyphenylpropyl) dimethicone 0.1
(Product name: Sofcare GS-G [manufactured by Kao Corporation]) (A)
Dimer linoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl) 0.5
(Product name: Plandool-L [Nippon Seika Co., Ltd.]) (C)
(B2) Component (B) 0.1
High polymerization dimethiconol emulsion 2.0
(Product name: XS65-C2173
[Momentive Performance Material Japan]
Methylparaben 0.1
Phenoxyethanol 0.2
Perfume Appropriate amount of ion-exchanged water

  The above hair conditioner not only provides a feeling of unity of the hair after drying and imparting a good feeling of fingering that is coated with glossy moisture on the hair tip, but also a rich feeling and goodness of fingering when rinsing It was good. The blending stability was also good.

Example 19 Hair mask (prescription ingredient) (mass%)
Cetanol 8.0
Behenyltrimethylammonium chloride 2.9
Concentrated glycerin 3.0
Citric acid appropriate amount Sodium citrate appropriate amount Diethyl sebacate 0.1
Grapefruit extract 0.1
(Product name: Grapefruit extract [Esperis)]
Hydrolyzed conchiolin solution 0.1
(Product name: Pearl protein extract [Maruzen Pharmaceutical Co., Ltd.])
Bis (polyglyceryl-3oxyphenylpropyl) dimethicone 0.1
(Product name: Sofcare GS-G [manufactured by Kao Corporation]) (A)
Dimer linoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl) 0.5
(Product name: Plandool-L [Nippon Seika Co., Ltd.]) (C)
(B2) Component (B) 0.1
Highly polymerized dimethylpolysiloxane emulsion 2.0
(Product name: KM-910 [manufactured by Shin-Etsu Chemical Co., Ltd.])
Methylparaben 0.1
Phenoxyethanol 0.2
Perfume Appropriate amount of ion-exchanged water

  The above-mentioned hair mask not only gives a feeling of unity of the hair after drying and imparts a good feeling of fingering that is coated with glossy moisture on the tip of the hair, but also has a rich feeling and good fingering when rinsing Met. The blending stability was also good.

Example 20 Hair Treatment (Non-washing type)
(Prescription ingredients) (mass%)
95 Synthetic unmodified alcohol 10.0
Concentrated glycerin 1.0
Liquid isoparaffin 5.0
Methyl polysiloxane 1.0
(Product name: L-45 [manufactured by Toray Dow Corning])
Jojoba oil 2.0
Polyoxyethylene hydrogenated castor oil 0.5
Polyoxyethylene oleyl ether 0.5
Triethanolamine Appropriate amount Carboxyvinyl polymer 0.3
Hydroxypropyltrimonium honey 0.1
(Product name: Honeycoat 50 [Arch Personal Products LP])
Bis (polyglyceryl-3oxyphenylpropyl) dimethicone 0.05
(Product name: Sofcare GS-G [manufactured by Kao Corporation]) (A)
Dimer linoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl) 0.5
(Product name: Plandool-L [Nippon Seika Co., Ltd.]) (C)
(B2) Component (B) 0.1
Diethyl sebacate 0.1
Highly polymerized dimethylpolysiloxane emulsion 0.1
(Product name: KM-910 [manufactured by Shin-Etsu Chemical Co., Ltd.])
Perfume Appropriate amount of ion-exchanged water

  The above hair treatment (type that does not wash away) is excellent in imparting a feeling of unity of the hair ends and a good feeling of fingering coated with glossy moisture on the ends of the hair, and also excellent in hair styling and a feeling of use. ing. The blending stability was also good.

The perfumes used in the compositions of the examples of the present invention are shown in Table 3 below.

  According to the present invention, it is excellent in prescription blending stability, prevents the hair or hair ends from spreading due to damage, gives a feeling of use as suppleness and flexibility, and a good feeling of fingering with a glossy and moist coating on the hair ends. Therefore, it is possible to provide a hair conditioning composition that can be expected to have a feeling of use and a finish that has never been seen before.

An example of a container that discharges two agents simultaneously (tube type) Another example of a container that discharges two agents simultaneously (aerosol type; simple mixing)

Claims (5)

An ester oil containing (A) a branched polyglycerol-modified silicone represented by the following general formula (1), (B) a fluorine-modified silicone represented by the following general formula (2), and (C) a melting point of less than 40 ° C. A hair conditioning composition comprising a hair conditioning composition.

[Wherein R represents a branched polyglycerol chain in which three or more glycerol groups or glycidol groups are bonded, and at least one of them is a branched glycerol group, and n represents an integer of 0 to 10,000.]


[However, in the above general formula, R ^{1 to} R ³ , R ⁷ , R ^{9 to} R ¹² are selected from a hydroxyl group, an alkyl group having 1 to 20 carbon atoms, and a phenyl group, and R ⁴ and R ⁵ are carbon numbers. R ⁶ is selected from a fluorine-substituted hydrocarbon group having 1 to 20 carbon atoms, R ⁸ is a hydroxyl group, l is an integer of 0 to 20000, m is 1 to 20 An integer of 20000, n is an integer of 0 to 2000, and each siloxane unit is randomly polymerized . When n = 0 , at least one R of R ^{1 to} R ³ , R ⁷ and R ^{10 to} R ¹² is It is a hydroxyl group. The hair conditioning composition according to claim 1, wherein the component (C) is a mixture fatty acid ester of dimer linoleic acid. Represented by the following general formula (1) (A) branched polyglycerol-modified silicone and the following general formula (2) shown by (B) Fluorine-modified silicone and (C) 1 or a melting point less than 40 ° C. ester oil respectively or A multi-condition hair conditioning composition characterized by combining two kinds of cosmetics and using three kinds in combination immediately before use.

[Wherein R represents a branched polyglycerol chain in which three or more glycerol groups or glycidol groups are bonded, and at least one of them is a branched glycerol group, and n represents an integer of 0 to 10,000.]


[However, in the above general formula, R ^{1 to} R ³ , R ⁷ , R ^{9 to} R ¹² are selected from a hydroxyl group, an alkyl group having 1 to 20 carbon atoms, and a phenyl group, and R ⁴ and R ⁵ are carbon numbers. R ⁶ is selected from a fluorine-substituted hydrocarbon group having 1 to 20 carbon atoms, R ⁸ is a hydroxyl group, l is an integer of 0 to 20000, m is 1 to 20 An integer of 20000, n is an integer of 0 to 2000, and each siloxane unit is randomly polymerized. When n = 0 , at least one R of R ^{1 to} R ³ , R ⁷ and R ^{10 to} R ¹² is It is a hydroxyl group. The hair conditioning composition according to claim 3, wherein the multi-drug formula is a two-drug formula. Represented by the following general formula (1) (A) branched polyglycerol-modified silicone and the following general formula (2) shown by (B) Fluorine-modified silicone and (C) 1 or a melting point less than 40 ° C. ester oil respectively or A hair conditioning method characterized by combining two kinds of cosmetics and using them in combination of three kinds immediately before use.

[Wherein R represents a branched polyglycerol chain in which three or more glycerol groups or glycidol groups are bonded, and at least one of them is a branched glycerol group, and n represents an integer of 0 to 10,000.]


[However, in the above general formula, R ^{1 to} R ³ , R ⁷ , R ^{9 to} R ¹² are selected from a hydroxyl group, an alkyl group having 1 to 20 carbon atoms, and a phenyl group, and R ⁴ and R ⁵ are carbon numbers. R ⁶ is selected from a fluorine-substituted hydrocarbon group having 1 to 20 carbon atoms, R ⁸ is a hydroxyl group, l is an integer of 0 to 20000, m is 1 to 20 An integer of 20000, n is an integer of 0 to 2000, and each siloxane unit is randomly polymerized. When n = 0 , at least one R of R ^{1 to} R ³ , R ⁷ and R ^{10 to} R ¹² is It is a hydroxyl group.